CN103917593A - 形成离聚物-聚烯烃共混物的含水分散体的方法 - Google Patents
形成离聚物-聚烯烃共混物的含水分散体的方法 Download PDFInfo
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- CN103917593A CN103917593A CN201280054477.7A CN201280054477A CN103917593A CN 103917593 A CN103917593 A CN 103917593A CN 201280054477 A CN201280054477 A CN 201280054477A CN 103917593 A CN103917593 A CN 103917593A
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- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 229920006029 tetra-polymer Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C08L23/0876—Salts thereof, i.e. ionomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/54—Aqueous solutions or dispersions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/290,415 US8841379B2 (en) | 2011-11-07 | 2011-11-07 | Method to form an aqueous dispersion of an ionomer-polyolefin blend |
| US13/290,415 | 2011-11-07 | ||
| PCT/US2012/058304 WO2013070340A1 (en) | 2011-11-07 | 2012-10-01 | Method to form an aqueous dispersion of an ionomer-polyolefin blend |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103917593A true CN103917593A (zh) | 2014-07-09 |
Family
ID=47049363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280054477.7A Pending CN103917593A (zh) | 2011-11-07 | 2012-10-01 | 形成离聚物-聚烯烃共混物的含水分散体的方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US8841379B2 (enExample) |
| EP (1) | EP2776502B1 (enExample) |
| JP (1) | JP2014532807A (enExample) |
| CN (1) | CN103917593A (enExample) |
| WO (1) | WO2013070340A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020504215A (ja) * | 2017-01-11 | 2020-02-06 | ダウ グローバル テクノロジーズ エルエルシー | 多層構造体に使用するポリマーブレンドおよびそれを含む多層構造体 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130225021A1 (en) * | 2012-02-29 | 2013-08-29 | E.I. Du Pont De Nemours And Company | Highly viscous ionomer-poly(vinylalcohol) coatings |
| BR112014033115B1 (pt) | 2012-07-03 | 2021-02-02 | Hercules Incorporated | composição em pó seco compreendendo pós de polímero solúveis em água e método de produção da mesma |
| US20150203704A1 (en) | 2014-01-22 | 2015-07-23 | E I Du Pont De Nemours And Company | Alkali metal-magnesium ionomer compositions |
| US20150203615A1 (en) | 2014-01-22 | 2015-07-23 | E I Du Pont De Nemours And Company | Alkali metal-zinc ionomer compositions |
| US10696771B2 (en) | 2015-03-26 | 2020-06-30 | Performance Materials Na, Inc. | Method of incorporating ethylene copolymers into latex |
| EP3898830B1 (en) | 2018-12-20 | 2022-11-02 | Dow Global Technologies LLC | Aqueous ionomeric dispersions, and methods thereof |
| WO2022115378A1 (en) * | 2020-11-25 | 2022-06-02 | Dow Global Technologies Llc. | Polymer blends having increased temperature resistance |
| WO2025049135A1 (en) * | 2023-08-30 | 2025-03-06 | Dow Global Technologies Llc | Aqueous polyolefin dispersions with ionomer dopants and methods of production thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996007677A1 (en) * | 1994-09-09 | 1996-03-14 | Chevron Chemical Company | Water dispersible ethylene ionomers |
| US20100055273A1 (en) * | 2008-08-26 | 2010-03-04 | E.I. Du Pont De Nemours And Company | Gas permeable membrane |
Family Cites Families (195)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE434497A (enExample) | 1938-06-07 | |||
| US4076698A (en) | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
| NO126663L (enExample) | 1957-01-09 | |||
| NL126914C (enExample) | 1961-08-14 | 1900-01-01 | ||
| NL129542C (enExample) | 1961-08-31 | 1900-01-01 | ||
| US3296172A (en) | 1963-02-28 | 1967-01-03 | Du Pont | Preparing aqueous polymer dispersions in presence of polar liquids |
| US3338739A (en) | 1964-03-17 | 1967-08-29 | Du Pont | Ionic copolymer coated with vinylidene chloride copolymer |
| US3355319A (en) | 1964-03-17 | 1967-11-28 | Du Pont | Self-supporting film with a heat-sealable coating of an ionic copolymer of an olefin and carboxylic acid with metal ions distributed throughout |
| US3321819A (en) | 1964-12-24 | 1967-05-30 | Union Carbide Corp | Process for sizing and desizing textile fibers |
| US3356629A (en) | 1964-12-28 | 1967-12-05 | Dow Chemical Co | Method for preparing aqueous dispersions of high molecular weight olefin polymers |
| US3389109A (en) | 1965-07-26 | 1968-06-18 | Dow Chemical Co | Method for preparing aqueous dispersions of ethylene copolymers |
| US3674896A (en) | 1966-07-28 | 1972-07-04 | Union Carbide Corp | Bonding with ammonium polymer salts |
| CA849081A (en) | 1967-03-02 | 1970-08-11 | Du Pont Of Canada Limited | PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES |
| US3553178A (en) | 1967-09-07 | 1971-01-05 | Gulf Research Development Co | Carbon dioxide as an ethylene polymer coagulant |
| GB1243303A (en) | 1968-05-17 | 1971-08-18 | Du Pont | Copolymer dispersions |
| US3562196A (en) | 1968-07-11 | 1971-02-09 | Du Pont | Olefin polymer dispersion preparation using oils and waxes as antifoams |
| US3896065A (en) | 1968-09-03 | 1975-07-22 | Du Pont | Substrates coated with stable pigmented ethylene copolymer dispersions |
| US3798194A (en) | 1968-10-07 | 1974-03-19 | Dow Chemical Co | Preparation of latexes by direct dispersion of acidic organic polymers into aqueous alkaline media containing certain alkanols |
| US3644258A (en) | 1969-03-19 | 1972-02-22 | Dow Chemical Co | Method of preparing high-solids latexes of olefin polymers |
| US3904569A (en) | 1972-10-26 | 1975-09-09 | Continental Can Co | Metal coating compositions prepared from aqueous dispersions of carboxylic acid resin and an aliphatic polyamine |
| US3823108A (en) | 1972-10-30 | 1974-07-09 | Du Pont | Aqueous ethylene terpolymer hydrosol dispersions |
| CA1033233A (en) | 1973-11-15 | 1978-06-20 | Emil Scharf | Process for surface-sizing paper |
| US3932368A (en) | 1973-11-21 | 1976-01-13 | Eastman Kodak Company | Powder coating composition comprising a particulate form of a carboxylated polyolefin |
| JPS50135141A (enExample) | 1973-11-26 | 1975-10-27 | ||
| US3872039A (en) | 1974-02-01 | 1975-03-18 | Dow Chemical Co | Cellulosic materials internally sized with low molecular weight copolymers of alpha, beta-ethylenically unsaturated hydrophobic monomers and ammoniated carboxylic acid comonomers |
| US3899389A (en) | 1974-02-01 | 1975-08-12 | Dow Chemical Co | Cellulosic materials internally sized with copolymers of alpha beta-ethylenically unsaturated hydrophobic monomers and ammoniated carboxylic acid comonomers |
| US4181566A (en) | 1974-08-15 | 1980-01-01 | The Dow Chemical Company | Cellulosic materials internally sized with ammoniated acid copolymers and epihalohydrin/alkylamine reaction products |
| US4136069A (en) | 1975-07-18 | 1979-01-23 | Eastman Kodak Company | Hot melt sizing compositions and fibrous articles sized therewith |
| JPS5842207B2 (ja) | 1975-07-22 | 1983-09-17 | 三井化学株式会社 | ポリオレフインソセイブツノ スイセイブンサンエキノセイゾウホウホウ |
| US4173669A (en) | 1977-09-09 | 1979-11-06 | Asahi-Dow Limited | Aqueous dispersion for coating and coated articles |
| JPS554027A (en) | 1978-06-23 | 1980-01-12 | Fuji Photo Film Co Ltd | Photographic base |
| JPS5598242A (en) | 1979-01-17 | 1980-07-26 | Mitsui Petrochem Ind Ltd | Preparing aqueous dispersion |
| US4336210A (en) | 1980-11-10 | 1982-06-22 | National Distillers & Chemical Corp. | Process for the preparation of finely divided thermoplastic resin |
| US4329305A (en) | 1980-11-10 | 1982-05-11 | National Distillers & Chemical Corp. | Process for regulating the particle size distribution of self-dispersing ionically crosslinked thermoplastic polymer |
| US4440908A (en) | 1980-11-10 | 1984-04-03 | National Distillers And Chemical Corporation | Finely divided ionomer coated thermoplastic resin |
| US4400440A (en) | 1981-01-02 | 1983-08-23 | Allied Paper Incorporated | Electrostatic paper base and method of making the same |
| US4540736A (en) | 1982-05-17 | 1985-09-10 | Allied Corporation | Temporary protective coating composition of ethylene and acrylic acid and a base |
| JPS5968753A (ja) | 1982-10-13 | 1984-04-18 | Fuji Photo Film Co Ltd | 電子写真製版材料用支持体 |
| DE3580428D1 (de) | 1984-07-25 | 1990-12-13 | Mitsui Petrochemical Ind | Waessrige dispersion und verfahren zu ihrer herstellung. |
| US4950541A (en) | 1984-08-15 | 1990-08-21 | The Dow Chemical Company | Maleic anhydride grafts of olefin polymers |
| JPS61266420A (ja) * | 1985-05-21 | 1986-11-26 | Mitsui Petrochem Ind Ltd | 水性分散組成物 |
| CA1236613A (en) | 1985-06-27 | 1988-05-10 | Chun S. Wong | Process for the grafting of monomers onto polyolefins |
| JPH06872B2 (ja) * | 1985-12-13 | 1994-01-05 | 三菱油化株式会社 | エチレン共重合体水性分散液 |
| US4978707A (en) | 1986-04-24 | 1990-12-18 | Mitsui Petrochemical Industries, Ltd. | Aqueous dispersion and process for preparation thereof |
| GB8626353D0 (en) | 1986-11-04 | 1986-12-03 | Du Pont Canada | Grafting of monomers onto polymers |
| US5194509A (en) | 1986-11-20 | 1993-03-16 | Basf Aktiengesellschaft | Peroxide-free grafting of homopolymers and copolymers of ethylene having densities equal to or greater than 0.930 g/cm3, and use of the graft copolymers for the preparation of ionomers of adhesion promoters |
| US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| US5075769A (en) | 1987-03-03 | 1991-12-24 | Polaroid Corporation | Video identification card system |
| JPS649338A (en) | 1987-07-01 | 1989-01-12 | Mitsubishi Electric Corp | Drop test method for ic card |
| US5082697A (en) | 1988-02-17 | 1992-01-21 | The Dow Chemical Company | Polymer salt complex for fiber or fabric treatment |
| US5231106A (en) | 1988-05-18 | 1993-07-27 | Novo Nordisk A/S | Azacyclic carboxylic acid derivatives and their preparation and use |
| US4888394A (en) | 1988-06-15 | 1989-12-19 | Phillips Petroleum Company | Process to graft stereoregular polymers of branched, higher alpha-olefins and compositions thereof |
| KR920005384B1 (ko) | 1988-11-21 | 1992-07-02 | 미쓰이세끼유 가가꾸고오교오 가부시끼 가이샤 | 변성 폴리올레핀입자 및 그의 제조방법 |
| NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
| US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| JP2521820B2 (ja) | 1989-09-21 | 1996-08-07 | 三井・デュポンポリケミカル株式会社 | アイオノマ―組成物 |
| US5244969A (en) | 1990-01-10 | 1993-09-14 | Sumitomo Rubber Industries, Ltd. | Golf ball |
| PL166690B1 (pl) | 1990-06-04 | 1995-06-30 | Exxon Chemical Patents Inc | Sposób wytwarzania polimerów olefin PL |
| US5028674A (en) | 1990-06-06 | 1991-07-02 | E. I. Du Pont De Nemours And Company | Methanol copolymerization of ethylene |
| US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| JP2868862B2 (ja) | 1990-08-10 | 1999-03-10 | 三井・デュポンポリケミカル株式会社 | オレフィン重合体組成物 |
| US5160484A (en) | 1990-09-28 | 1992-11-03 | Cranston Print Works Company | Paper saturant |
| JP2958102B2 (ja) | 1990-11-16 | 1999-10-06 | 中央理化工業株式会社 | 樹脂水性分散液の製造方法 |
| US5155157A (en) | 1990-12-27 | 1992-10-13 | E. I. Du Pont De Nemours And Company | Compositions useful in the manufacture of golfballs |
| US5206279A (en) | 1991-01-25 | 1993-04-27 | The Dow Chemical Company | Method of preparing aqueous dispersions of ethylene/α,β-unsaturated carboxylic acid interpolymers |
| US5591806A (en) | 1991-05-20 | 1997-01-07 | Dominion Chemical Company | High solids ethylene acrylic acid aqueous dispersions and methods of producing same |
| JP3275211B2 (ja) | 1991-05-20 | 2002-04-15 | ザ ダウ ケミカル カンパニー | 付加重合触媒の製造方法 |
| US5430111A (en) | 1991-05-20 | 1995-07-04 | Dominion Chemical Company | High solids ethylene acrylic acid aqueous dispersions and methods of producing same |
| US5847053A (en) | 1991-10-15 | 1998-12-08 | The Dow Chemical Company | Ethylene polymer film made from ethylene polymer blends |
| US5783638A (en) | 1991-10-15 | 1998-07-21 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
| US6316549B1 (en) | 1991-10-15 | 2001-11-13 | The Dow Chemical Company | Ethylene polymer fiber made from ethylene polymer blends |
| US5368304A (en) | 1993-04-28 | 1994-11-29 | Lisco, Inc. | Low spin golf ball |
| US5688869A (en) | 1991-10-15 | 1997-11-18 | Lisco, Inc. | Golf ball cover compositions |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| US5677383A (en) | 1991-10-15 | 1997-10-14 | The Dow Chemical Company | Fabricated articles made from ethylene polymer blends |
| JP2916310B2 (ja) | 1991-11-01 | 1999-07-05 | 住友ゴム工業株式会社 | ツーピースゴルフボール |
| ZA926584B (en) | 1991-11-04 | 1993-03-08 | Rheox Int | Antisettling agents for aqueous coating compositions. |
| KR100253826B1 (ko) | 1991-12-30 | 2000-04-15 | 그레이스 스티븐 에스. | 에틸렌 공중합체의 중합방법 |
| WO1993014132A1 (en) | 1992-01-06 | 1993-07-22 | The Dow Chemical Company | Improved catalyst composition |
| US5445893A (en) | 1992-01-30 | 1995-08-29 | W.R. Grace & Co.-Conn | pH control polymer |
| US5550177A (en) | 1992-02-28 | 1996-08-27 | The United States Of America As Represented By The Secretary Of Agriculture | Starch and poly (ethlene-co-acrylic acid) pastes and gels, and method for their making |
| US5374696A (en) | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
| US5330788A (en) | 1992-08-10 | 1994-07-19 | Henkel Corporation | Temporary coating system |
| US5420220A (en) | 1993-03-25 | 1995-05-30 | Mobil Oil Corporation | LLDPE films |
| BR9405715A (pt) | 1993-01-29 | 1995-11-28 | Dow Chemical Co | Processo para preparar um composição de interpolímero de etileno/a-olefina e composição de interpolímero de etileno/a-olefina |
| US6448341B1 (en) | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
| US5346963A (en) | 1993-04-28 | 1994-09-13 | The Dow Chemical Company | Graft-modified, substantially linear ethylene polymers and methods for their use |
| US5470993A (en) | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
| US5409765A (en) | 1993-08-04 | 1995-04-25 | Fiberweb North America, Inc. | Nonwoven webs made from ionomers |
| US5744250A (en) | 1993-12-29 | 1998-04-28 | E. I. Du Pont De Nemours And Company | Adhesion compositions for multilayer structures |
| AU3408395A (en) | 1994-08-25 | 1996-03-14 | Eastman Chemical Company | Maleated high acid number high molecular weight polypropylene of low color |
| US7408007B2 (en) | 1994-08-25 | 2008-08-05 | Eastman Chemical Company | Maleated high acid number high molecular weight polypropylene of low color |
| US5542677A (en) | 1994-12-20 | 1996-08-06 | Lisco, Inc. | Golf ball cover compositions |
| JPH0940924A (ja) | 1995-07-26 | 1997-02-10 | Sekisui Chem Co Ltd | 表面保護フィルム |
| US5869575A (en) | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
| US6159608A (en) | 1995-09-28 | 2000-12-12 | Saint-Gobain Performance Plastics Corporation | Thermoplastic interlayer film |
| US5993604A (en) | 1995-12-05 | 1999-11-30 | The Dow Chemical Company | Internally sized articles and method for making same |
| WO1997022754A1 (en) | 1995-12-05 | 1997-06-26 | The Dow Chemical Company | Method for externally sizing fibrous materials |
| JPH09175592A (ja) | 1995-12-26 | 1997-07-08 | Du Pont Mitsui Polychem Co Ltd | 電子部品包装用カバーテープ |
| US6545091B1 (en) | 1996-01-25 | 2003-04-08 | E. I. Du Pont De Nemours & Co. | Adhesive compositions based on blends of grafted metallocene catalyzed and non-grafted conventional polyethylenes |
| JPH106640A (ja) | 1996-06-24 | 1998-01-13 | Du Pont Mitsui Polychem Co Ltd | インクジェット記録用材料 |
| JP3599912B2 (ja) | 1996-08-26 | 2004-12-08 | 三井・デュポンポリケミカル株式会社 | 重合体組成物 |
| JPH1060186A (ja) | 1996-08-26 | 1998-03-03 | Du Pont Mitsui Polychem Co Ltd | 非帯電性成形品の製造方法 |
| JP3356376B2 (ja) | 1996-10-02 | 2002-12-16 | 株式会社テクノスタット工業 | 防錆・帯電防止性熱可塑性樹脂成形品 |
| JP3878268B2 (ja) | 1997-01-16 | 2007-02-07 | 三井・デュポンポリケミカル株式会社 | 防塵性積層体 |
| JPH10316872A (ja) | 1997-05-21 | 1998-12-02 | Ntn Corp | 帯電防止・潤滑性樹脂組成物 |
| CN1237189A (zh) | 1997-06-20 | 1999-12-01 | 三井化学株式会社 | 水分散液组合物及其制备方法、以及防锈剂、防锈处理方法和防锈处理金属制品 |
| WO1999010276A1 (en) | 1997-08-25 | 1999-03-04 | E.I. Du Pont De Nemours And Company | Silicate-containing composite material |
| JP3985881B2 (ja) | 1997-10-15 | 2007-10-03 | 三井・デュポンポリケミカル株式会社 | 高周波融着性積層体 |
| JPH11147288A (ja) | 1997-11-17 | 1999-06-02 | Sun A Kaken Co Ltd | 帯電防止性積層フィルム |
| JPH11158332A (ja) | 1997-11-27 | 1999-06-15 | Mitsui Chem Inc | 水性分散体組成物およびその製造方法 |
| JPH11291406A (ja) | 1998-04-09 | 1999-10-26 | Sun A Kaken Co Ltd | 内装用表面材 |
| JP3926486B2 (ja) | 1998-08-21 | 2007-06-06 | 三井・デュポンポリケミカル株式会社 | 透明性に優れた高周波融着性樹脂組成物 |
| WO2000044801A1 (en) | 1999-01-29 | 2000-08-03 | E.I. Du Pont De Nemours And Company | Aqueous dispersions of low mfi ethylene-copolymers |
| JP4205807B2 (ja) | 1999-02-25 | 2009-01-07 | 三井・デュポンポリケミカル株式会社 | 水性分散体組成物及びその製法 |
| JP2000328046A (ja) | 1999-05-18 | 2000-11-28 | Du Pont Mitsui Polychem Co Ltd | 帯電防止用水性分散液及びその利用 |
| US6518365B1 (en) | 1999-07-28 | 2003-02-11 | E. I. Du Pont De Nemours And Company | High melt swell polymer |
| JP2001355185A (ja) * | 2000-01-24 | 2001-12-26 | Mitsui Chemicals Inc | 繊維処理剤 |
| JP2001206953A (ja) * | 2000-01-28 | 2001-07-31 | Du Pont Mitsui Polychem Co Ltd | 水性分散液 |
| JP2001206998A (ja) * | 2000-01-31 | 2001-07-31 | Du Pont Mitsui Polychem Co Ltd | ペースト状水性分散液及びその用途 |
| US6852792B1 (en) | 2000-04-13 | 2005-02-08 | E. I. Du Pont De Nemours And Company | Coating composition containing a low MFI ethylene acrylic acid copolymer |
| JP4669598B2 (ja) | 2000-06-29 | 2011-04-13 | 三井・デュポンポリケミカル株式会社 | 非帯電性アイオノマー組成物及びその用途 |
| US6500888B2 (en) | 2000-12-27 | 2002-12-31 | E. I. Du Pont De Nemours And Company | Surface treatment of ethylene based polymer pellets to improve blocking resistance |
| JP5225524B2 (ja) | 2001-02-09 | 2013-07-03 | 三井・デュポンポリケミカル株式会社 | アイオノマー樹脂組成物及びその用途 |
| JP2003291283A (ja) | 2001-07-04 | 2003-10-14 | Du Pont Mitsui Polychem Co Ltd | 積層体 |
| JP4197901B2 (ja) | 2001-07-04 | 2008-12-17 | 三井・デュポンポリケミカル株式会社 | 積層体 |
| JP2003026868A (ja) | 2001-07-18 | 2003-01-29 | Showa Packs Kk | ポリエチレン系樹脂組成物 |
| JP2004217759A (ja) | 2003-01-14 | 2004-08-05 | Du Pont Mitsui Polychem Co Ltd | 高周波融着性に優れた樹脂組成物及びその用途 |
| DE10326630A1 (de) | 2003-06-11 | 2005-01-05 | Basf Ag | Verwendung wässriger Dispersionen, enthaltend Ethylencopolymerwachse |
| US7763676B2 (en) | 2003-08-25 | 2010-07-27 | Dow Global Technologies Inc. | Aqueous polymer dispersions and products from those dispersions |
| US8158711B2 (en) | 2003-08-25 | 2012-04-17 | Dow Global Technologies Llc | Aqueous dispersion, its production method, and its use |
| TW200517426A (en) | 2003-08-25 | 2005-06-01 | Dow Global Technologies Inc | Aqueous dispersion, its production method, and its use |
| US7803865B2 (en) | 2003-08-25 | 2010-09-28 | Dow Global Technologies Inc. | Aqueous dispersion, its production method, and its use |
| US7947776B2 (en) | 2003-08-25 | 2011-05-24 | Dow Global Technologies Llc | Aqueous dispersion, its production method, and its use |
| JP4389066B2 (ja) | 2003-08-29 | 2009-12-24 | 三井化学株式会社 | 水分散型防錆塗料用組成物 |
| JP4389067B2 (ja) | 2003-08-29 | 2009-12-24 | 三井化学株式会社 | 水分散型防錆塗料用組成物 |
| US7470736B2 (en) | 2004-05-03 | 2008-12-30 | Michelman, Inc. | Primer coating for enhancing adhesion of liquid toner to polymeric substrates |
| JP4651320B2 (ja) | 2004-07-14 | 2011-03-16 | 三井・デュポンポリケミカル株式会社 | 積層体 |
| US7279513B2 (en) | 2004-11-19 | 2007-10-09 | Nalco Company | Preparation of neutralized ethylene-acrylic acid polymer dispersions and use in printing media for improvement of digital toner adhesion |
| JP2008544885A (ja) | 2005-07-07 | 2008-12-11 | ダウ グローバル テクノロジーズ インコーポレイティド | 長繊維強化熱可塑性コンセントレート及びその製造方法 |
| WO2007008633A2 (en) | 2005-07-07 | 2007-01-18 | Dow Global Technologies Inc. | Electrically conductive long fiber thermoplastic concentrate and method for its preparation |
| JP4871573B2 (ja) | 2005-11-17 | 2012-02-08 | 三井・デュポンポリケミカル株式会社 | カリウムアイオノマー配合樹脂組成物からなる発泡フィルム又はシート |
| US7816458B2 (en) | 2005-11-22 | 2010-10-19 | E. I. Du Pont De Nemours And Company | Aqueous dispersions containing ionomer resins and rust-preventive ionomeric coatings made therefrom |
| US7528080B2 (en) | 2005-12-15 | 2009-05-05 | Dow Global Technologies, Inc. | Aqueous polyolefin dispersions for textile impregnation |
| US7678231B2 (en) | 2005-12-15 | 2010-03-16 | Dow Global Technologies, Inc. | Process for increasing the basis weight of sheet materials |
| US7879188B2 (en) | 2005-12-15 | 2011-02-01 | Kimberly-Clark Worldwide, Inc. | Additive compositions for treating various base sheets |
| US7879189B2 (en) | 2005-12-15 | 2011-02-01 | Kimberly-Clark Worldwide, Inc. | Additive compositions for treating various base sheets |
| US8043713B2 (en) | 2005-12-15 | 2011-10-25 | Dow Global Technologies Llc | Compositions and aqueous dispersions |
| US8444811B2 (en) | 2005-12-15 | 2013-05-21 | Kimberly-Clark Worldwide, Inc. | Process for increasing the basis weight of sheet materials |
| JP5349052B2 (ja) | 2005-12-15 | 2013-11-20 | ダウ グローバル テクノロジーズ エルエルシー | 添加剤組成物を含有する改良セルロース物品 |
| US7842163B2 (en) | 2005-12-15 | 2010-11-30 | Kimberly-Clark Worldwide, Inc. | Embossed tissue products |
| US7807023B2 (en) | 2005-12-15 | 2010-10-05 | Kimberly-Clark Worldwide, Inc. | Process for increasing the basis weight of sheet materials |
| US7820010B2 (en) | 2005-12-15 | 2010-10-26 | Kimberly-Clark Worldwide, Inc. | Treated tissue products having increased strength |
| US7879191B2 (en) | 2005-12-15 | 2011-02-01 | Kimberly-Clark Worldwide, Inc. | Wiping products having enhanced cleaning abilities |
| US7837832B2 (en) | 2005-12-15 | 2010-11-23 | Dow Global Technologies, Inc. | Additive compositions for treating various base sheets |
| US7837831B2 (en) | 2005-12-15 | 2010-11-23 | Kimberly-Clark Worldwide, Inc. | Tissue products containing a polymer dispersion |
| US7803249B2 (en) | 2005-12-15 | 2010-09-28 | Dow Global Technologies Inc. | Wiping products with controlled lint properties |
| US7803250B2 (en) | 2005-12-15 | 2010-09-28 | Dow Global Technologies, Inc. | Wiping products having enhanced cleaning abilities |
| US20070137811A1 (en) | 2005-12-15 | 2007-06-21 | Kimberly-Clark Worldwide, Inc. | Premoistened tissue products |
| US7883604B2 (en) | 2005-12-15 | 2011-02-08 | Kimberly-Clark Worldwide, Inc. | Creping process and products made therefrom |
| US20070243331A1 (en) | 2006-02-17 | 2007-10-18 | Dow Global Technologies Inc. | Heat sealable compositions from aqueous dispersions |
| JP2007302764A (ja) | 2006-05-10 | 2007-11-22 | Du Pont Mitsui Polychem Co Ltd | 透湿性材料 |
| JP4925035B2 (ja) | 2006-05-10 | 2012-04-25 | 三井・デュポンポリケミカル株式会社 | 透湿性積層体 |
| US8916640B2 (en) | 2006-07-06 | 2014-12-23 | Dow Global Technologies Llc | Blended polyolefin dispersions |
| US8785531B2 (en) | 2006-07-06 | 2014-07-22 | Dow Global Technologies Llc | Dispersions of olefin block copolymers |
| JP5535630B2 (ja) | 2006-09-11 | 2014-07-02 | ダウ グローバル テクノロジーズ エルエルシー | レジンコーテッドサンドに用いられるポリオレフィン分散技術 |
| US8581094B2 (en) | 2006-09-20 | 2013-11-12 | Dow Global Technologies, Llc | Electronic device module comprising polyolefin copolymer |
| US20080115825A1 (en) | 2006-09-20 | 2008-05-22 | Patel Rajen M | Electronic Device Module Comprising an Ethylene Multi-Block Copolymer |
| US8476326B2 (en) | 2006-09-22 | 2013-07-02 | Dow Global Technologies Llc | Fibrillated polyolefin foam |
| US20080118728A1 (en) | 2006-10-20 | 2008-05-22 | Dow Global Technologies Inc. | Aqueous dispersions disposed on glass-based fibers and glass-containing substrates |
| CA2667457A1 (en) | 2006-10-25 | 2008-05-02 | Dow Global Technologies Inc. | Polyolefin dispersions, froths, and foams |
| US20080132628A1 (en) | 2006-11-30 | 2008-06-05 | Karlheinz Hausmann | Antistatic styrenic polymer compositions and articles therefrom |
| JP4948997B2 (ja) | 2006-12-04 | 2012-06-06 | 株式会社テクノスタット工業 | 非帯電性包装用フィルム |
| US7785443B2 (en) | 2006-12-07 | 2010-08-31 | Kimberly-Clark Worldwide, Inc. | Process for producing tissue products |
| JP2008273998A (ja) | 2007-01-23 | 2008-11-13 | Du Pont Mitsui Polychem Co Ltd | 電子部品搬送用成形体 |
| US7588662B2 (en) | 2007-03-22 | 2009-09-15 | Kimberly-Clark Worldwide, Inc. | Tissue products containing non-fibrous polymeric surface structures and a topically-applied softening composition |
| JP2009035699A (ja) | 2007-08-03 | 2009-02-19 | Du Pont Mitsui Polychem Co Ltd | アイオノマー組成物およびその用途 |
| JP5514724B2 (ja) | 2007-09-14 | 2014-06-04 | ダウ グローバル テクノロジーズ エルエルシー | 被覆高分子微粒子、及び高分子微粒子を被覆する方法 |
| JP2009084324A (ja) | 2007-09-27 | 2009-04-23 | Du Pont Mitsui Polychem Co Ltd | 難燃性樹脂材料 |
| BRPI0816042A2 (pt) | 2007-09-28 | 2020-08-11 | Dow Global Technologies Inc. | dispersão aquosa, método para formar uma dispersão aquosa, espuma, método para formar uma espuma, artigo baseado em celulose, processo para formar um artigo, fibra revestida , composição de toner, método para formar uma camada sobre um substrato e método para preparar um concentrado de fibras longas |
| JP5330727B2 (ja) | 2007-10-04 | 2013-10-30 | 三井・デュポンポリケミカル株式会社 | 樹脂発泡層を有する積層体 |
| JP2009091426A (ja) | 2007-10-05 | 2009-04-30 | Unitika Ltd | 水性分散体、その製造法および積層体 |
| WO2009055275A2 (en) | 2007-10-25 | 2009-04-30 | Dow Global Technologies Inc. | Polyolefin dispersion technology used for porous substrates |
| US10793738B2 (en) | 2007-11-15 | 2020-10-06 | Dow Global Technologies Llc | Coating composition, a coated article, and method of forming such articles |
| EP2207847B1 (en) * | 2007-11-16 | 2012-11-14 | E. I. du Pont de Nemours and Company | Multilayer articles containing bimodal ionomer compositions |
| CN101889032B (zh) | 2007-12-07 | 2012-10-24 | 三井-杜邦聚合化学株式会社 | 离聚物、含有该离聚物的树脂组合物、由该组合物形成的未拉伸膜、片材或成型体、以及具有该未拉伸膜层的层合体 |
| JP2009138139A (ja) | 2007-12-07 | 2009-06-25 | Du Pont Mitsui Polychem Co Ltd | オレフィン系重合体延伸フイルム |
| US8129032B2 (en) | 2008-02-01 | 2012-03-06 | Exxonmobil Oil Corporation | Coating compositions, coated substrates and hermetic seals made therefrom having improved low temperature sealing and hot tack properties |
| JP5485266B2 (ja) | 2008-05-30 | 2014-05-07 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | アイオノマー組成物を含む成形品 |
| US20100272898A1 (en) | 2009-04-23 | 2010-10-28 | E. I. Du Pont De Nemours And Company | Method for preparing a selectively permeable protective structure |
| CN102639610B (zh) | 2009-11-12 | 2015-09-02 | 阿克佐诺贝尔国际涂料股份有限公司 | 含水聚合物分散体 |
| EP2507031B1 (en) | 2009-12-04 | 2018-03-28 | Union Carbide Chemicals & Plastics Technology LLC | Extruder screw system and process for producing an aqueous dispersion |
| WO2011087478A1 (en) | 2009-12-22 | 2011-07-21 | Dow Global Technologies Inc. | Reducing impurities in ethylene |
-
2011
- 2011-11-07 US US13/290,415 patent/US8841379B2/en active Active
-
2012
- 2012-10-01 WO PCT/US2012/058304 patent/WO2013070340A1/en not_active Ceased
- 2012-10-01 EP EP12775577.5A patent/EP2776502B1/en not_active Not-in-force
- 2012-10-01 JP JP2014541064A patent/JP2014532807A/ja active Pending
- 2012-10-01 CN CN201280054477.7A patent/CN103917593A/zh active Pending
-
2014
- 2014-08-19 US US14/462,974 patent/US20140357779A1/en not_active Abandoned
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996007677A1 (en) * | 1994-09-09 | 1996-03-14 | Chevron Chemical Company | Water dispersible ethylene ionomers |
| US20100055273A1 (en) * | 2008-08-26 | 2010-03-04 | E.I. Du Pont De Nemours And Company | Gas permeable membrane |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020504215A (ja) * | 2017-01-11 | 2020-02-06 | ダウ グローバル テクノロジーズ エルエルシー | 多層構造体に使用するポリマーブレンドおよびそれを含む多層構造体 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2014532807A (ja) | 2014-12-08 |
| US20140357779A1 (en) | 2014-12-04 |
| US20130116373A1 (en) | 2013-05-09 |
| EP2776502B1 (en) | 2016-04-06 |
| EP2776502A1 (en) | 2014-09-17 |
| US8841379B2 (en) | 2014-09-23 |
| WO2013070340A1 (en) | 2013-05-16 |
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