JP5485266B2 - アイオノマー組成物を含む成形品 - Google Patents
アイオノマー組成物を含む成形品 Download PDFInfo
- Publication number
- JP5485266B2 JP5485266B2 JP2011511891A JP2011511891A JP5485266B2 JP 5485266 B2 JP5485266 B2 JP 5485266B2 JP 2011511891 A JP2011511891 A JP 2011511891A JP 2011511891 A JP2011511891 A JP 2011511891A JP 5485266 B2 JP5485266 B2 JP 5485266B2
- Authority
- JP
- Japan
- Prior art keywords
- ionomer
- ionomer composition
- less
- acid copolymer
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000554 ionomer Polymers 0.000 title claims description 84
- 239000000203 mixture Substances 0.000 title claims description 78
- 229920001577 copolymer Polymers 0.000 claims description 47
- 239000002253 acid Substances 0.000 claims description 37
- 239000002243 precursor Substances 0.000 claims description 30
- 238000000465 moulding Methods 0.000 claims description 15
- 238000012360 testing method Methods 0.000 claims description 15
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 13
- 239000004711 α-olefin Substances 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 6
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 5
- 230000003472 neutralizing effect Effects 0.000 claims description 5
- 229910001415 sodium ion Inorganic materials 0.000 claims description 5
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 4
- 239000000047 product Substances 0.000 description 51
- 238000000034 method Methods 0.000 description 34
- 238000002347 injection Methods 0.000 description 18
- 239000007924 injection Substances 0.000 description 18
- 238000001746 injection moulding Methods 0.000 description 18
- 238000001816 cooling Methods 0.000 description 16
- 150000002500 ions Chemical class 0.000 description 15
- 229910021645 metal ion Inorganic materials 0.000 description 11
- 230000003287 optical effect Effects 0.000 description 11
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 10
- 150000001412 amines Chemical class 0.000 description 9
- -1 ethylene, propylene, 1-butene Chemical class 0.000 description 9
- 239000010410 layer Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 229920001223 polyethylene glycol Polymers 0.000 description 8
- 239000006096 absorbing agent Substances 0.000 description 7
- 239000004611 light stabiliser Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000002537 cosmetic Substances 0.000 description 6
- 239000012760 heat stabilizer Substances 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 238000000071 blow moulding Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 125000002843 carboxylic acid group Chemical group 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 3
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 description 2
- 229960004419 dimethyl fumarate Drugs 0.000 description 2
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- 125000000687 hydroquinonyl group Chemical class C1(O)=C(C=C(O)C=C1)* 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 2
- 229920001427 mPEG Polymers 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000010583 slow cooling Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- BWDSMNCMUXDKJM-UHFFFAOYSA-N 1-docosoxydocosane 2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC BWDSMNCMUXDKJM-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- CPPDFKVVKLWZHE-UHFFFAOYSA-N 2-methylprop-2-enoic acid;phenoxybenzene Chemical compound CC(=C)C(O)=O.C=1C=CC=CC=1OC1=CC=CC=C1 CPPDFKVVKLWZHE-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 description 1
- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 description 1
- WWJLCYHYLZZXBE-UHFFFAOYSA-N 5-chloro-1,3-dihydroindol-2-one Chemical compound ClC1=CC=C2NC(=O)CC2=C1 WWJLCYHYLZZXBE-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- HAVDCTUCZNKAHY-UHFFFAOYSA-N CC(=C)C(O)=O.CCCCCCCCCc1ccc(Oc2ccc(CCCCCCCCC)cc2)cc1 Chemical compound CC(=C)C(O)=O.CCCCCCCCCc1ccc(Oc2ccc(CCCCCCCCC)cc2)cc1 HAVDCTUCZNKAHY-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- KGEKLUUHTZCSIP-UHFFFAOYSA-N Isobornyl acetate Natural products C1CC2(C)C(OC(=O)C)CC1C2(C)C KGEKLUUHTZCSIP-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- RRAQGPNOVYEVCW-UHFFFAOYSA-N OC(=O)C=C.C1=CC(CCCCCCCCC)=CC=C1OC1=CC=C(CCCCCCCCC)C=C1 Chemical compound OC(=O)C=C.C1=CC(CCCCCCCCC)=CC=C1OC1=CC=C(CCCCCCCCC)C=C1 RRAQGPNOVYEVCW-UHFFFAOYSA-N 0.000 description 1
- CRHWZQHMAWOVCS-UHFFFAOYSA-N OC(=O)C=C.CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC Chemical compound OC(=O)C=C.CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC CRHWZQHMAWOVCS-UHFFFAOYSA-N 0.000 description 1
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical class NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical group OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000001940 [(1R,4S,6R)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Substances 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- OGBVRMYSNSKIEF-UHFFFAOYSA-L benzyl-dioxido-oxo-$l^{5}-phosphane Chemical compound [O-]P([O-])(=O)CC1=CC=CC=C1 OGBVRMYSNSKIEF-UHFFFAOYSA-L 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000005266 diarylamine group Chemical group 0.000 description 1
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- IEPRKVQEAMIZSS-AATRIKPKSA-N diethyl fumarate Chemical compound CCOC(=O)\C=C\C(=O)OCC IEPRKVQEAMIZSS-AATRIKPKSA-N 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- DUDCYUDPBRJVLG-UHFFFAOYSA-N ethoxyethane methyl 2-methylprop-2-enoate Chemical compound CCOCC.COC(=O)C(C)=C DUDCYUDPBRJVLG-UHFFFAOYSA-N 0.000 description 1
- DOMLXBPXLNDFAB-UHFFFAOYSA-N ethoxyethane;methyl prop-2-enoate Chemical compound CCOCC.COC(=O)C=C DOMLXBPXLNDFAB-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- JYGFTBXVXVMTGB-UHFFFAOYSA-N indolin-2-one Chemical compound C1=CC=C2NC(=O)CC2=C1 JYGFTBXVXVMTGB-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical group CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- LCDOENXNMQXGFS-UHFFFAOYSA-N phenoxybenzene;prop-2-enoic acid Chemical compound OC(=O)C=C.C=1C=CC=CC=1OC1=CC=CC=C1 LCDOENXNMQXGFS-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical group OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- KRLHYNPADOCLAJ-UHFFFAOYSA-N undecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCOC(=O)C(C)=C KRLHYNPADOCLAJ-UHFFFAOYSA-N 0.000 description 1
- RRLMGCBZYFFRED-UHFFFAOYSA-N undecyl prop-2-enoate Chemical compound CCCCCCCCCCCOC(=O)C=C RRLMGCBZYFFRED-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
- B32B2437/02—Gloves, shoes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2535/00—Medical equipment, e.g. bandage, prostheses, catheter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C08L23/0876—Neutralised polymers, i.e. ionomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Laminated Bodies (AREA)
Description
本願は、2008年5月30日に出願した米国仮特許出願第61/130,382号の、米国特許法第120条に基づく優先権を主張するものであり、その出願はそのまま参照することにより本明細書中に組み込まれる。
アイオノマー組成物を溶融する工程;
溶融アイオノマー組成物を型に流し込むことによって射出成形品を成形する工程;
射出成形品がその形を保持するようになるまで、型内で冷却する工程;
型から射出成形品を取り出す工程;および
射出成形品を室温((22+3)℃)、またはそれより低い温度に冷却する工程
を含むことができる。
メルトフローレート
メルトフローレート(MFRまたはMI)は、ASTM Standard No.D−1238に従い、190℃、荷重2.16kgで測定した。
Model 150−6 HPM射出成形機(Taylor’s Industrial Services(Mount Gilead,OH)より入手可能)にアイオノマー樹脂を供給して、125×75×3mm(薄肉試験片)および125×45×20mm(厚肉試験片)の寸法の矩形状射出成形試験片を作製した。アイオノマーの溶融温度は130℃〜200℃の範囲であり、型を約10℃の温度に維持した。成形サイクルタイムは約90秒とした。成形片を型から取り出し、周囲条件下で室温(約22+3℃)にまで冷却して、薄肉および厚肉の両試験片を得た。厚肉試験片では、「空冷」冷却速度は、離型後の最初の1時間は約0.3℃/分と推定され、その後では、速度は約0.1℃/分になると推定された。
HunterLab ColorQuest XEヘーズメーター(Hunter Associates Laboratory,Inc.、(Reston、VA))を使用し、ASTM D1003−07に従って、「空冷」および「徐冷」の薄肉試験片のヘーズ値を3mmの厚さ方向で測定した。
厚肉試験片の透明度を目視検査により決定した。試験片を1(最高の透明度)から3(最低の透明度)までの相対尺度で順位付けを行った。
NETSTAL 1 Synergy 1750H−460成形機によりアイオノマーを射出成形して、長尺片(180mm×27mm×2mm)からなる部品を得た。ポリマーの溶融温度は130〜200℃の範囲であった。型の温度をおよそ20℃に維持し、サイクルタイムをおよそ40秒とした。試験片を室温でおよそ10℃/分の速度で冷却した。
・ ION Aは、15重量%のメタクリル酸共重合残基を含むエチレンとメタクリル酸の共重合体である。ナトリウムイオン源を使用して56%の水準にまでION Aを中和した。MFRは0.9g/10分であった。前駆体酸共重合体のMFRは60g/10分であった。
・ ION Bは、19重量%のメタクリル酸共重合残基を含むエチレンとメタクリル酸の共重合体である。ナトリウムイオン源を使用して37%の水準にまでION Bを中和した。MFRは2.6g/10分であった。前駆体酸共重合体のMFRは60g/10分であった。
・ ION Cは、21.7重量%のメタクリル酸共重合残基を含むエチレンとメタクリル酸の共重合体である。ナトリウムイオン源を使用して25%の水準にまでION Bを中和した。MFRは1.8g/10分であった。前駆体酸共重合体のMFRは23g/10分であった。
上に挙げたアイオノマーから、上記成形方法により、薄肉および厚肉の射出成形試験片を作製した。これらの試験片のヘーズおよび透明度を上記のようにして測定した。結果を表1に示す。
*注:応力亀裂試験において、「ION C」で使用したアイオノマーは、酸濃度が21〜23%で、前駆体酸共重合体のメルトインデックスは245g/10分以下であった。陽イオンはナトリウムであり、中和度またはメルトインデックスは、上で定義したION Cとほぼ同じであった。
次に、本発明の態様を示す。
1. 3.0mm以上の最小厚さを有する、アイオノマー組成物を含む成形品であって;
前記アイオノマー組成物は、前駆体酸共重合体を部分的に中和することによって製造されるアイオノマーを含み、かつ
前記前駆体酸共重合体は、2〜10個の炭素を有するα−オレフィン共重合単位と、前駆体酸共重合体の全重量に対して約19.5〜約30重量%の、3〜8個の炭素を有するα,β−エチレン型不飽和カルボン酸共重合単位を含み;
前記前駆体酸共重合体は、ASTM D−1238による190℃、荷重2.16kgでの測定で、約350g/10分以下のメルトフローレート(MFR)を有し;
前記前駆体酸共重合体の全カルボン酸含有量の約5%〜約90%が中和され、
前記アイオノマーは、ASTM D−1238による190℃、荷重2.16kgでの測定で、約25g/10分以下のMFRを有し;かつ
前記アイオノマー組成物を溶融し、この溶融したアイオノマー組成物を板状試験片に成形し、この溶融アイオノマー組成物を0.1℃/分以下の速度で(22±3)℃以下の温度にまで冷却することによって作製される厚さ3.0mmの板状試験片について、ASTM−1003 ASTM D1003により測定されるアイオノマー組成物のヘーズが、0.7〜13.5である成形品。
2. 前記アイオノマーが、ナトリウム、リチウム、マグネシウム、亜鉛、カルシウム、およびこれらの2種以上のイオンの組み合わせからなる群より選択される少なくとも1種の金属陽イオンを含むか;または前記前駆体酸共重合体が、約20〜約25重量%の、3〜8個の炭素を有するα,β−エチレン型不飽和カルボン酸共重合単位を含むか;またはASTM D−1238により190℃、荷重2.16kgで測定される前記前駆体酸共重合体のMFRが約60g/10分以下で、かつ前記アイオノマーのMFRが約5g/10分以下であるか;または前記前駆体酸共重合体の全カルボン酸含有量の約20%〜約50%が中和される上記1に記載の成形品。
3. 前記前駆体酸共重合体の全カルボン酸含有量の約20%〜約35%が中和され、かつ前記金属イオンが実質的にナトリウム陽イオンからなる上記1または2に記載の成形品。
4. 実質的に前記アイオノマー組成物からなり、かつ最小厚さと最大厚さが約3〜約100mmの範囲である上記1〜3のいずれか一項に記載の成形品。
5. 多層構造の形態を有し、前記多層構造の少なくとも1層が前記アイオノマー組成物から実質的に構成される上記1〜4のいずれか一項に記載の成形品。
6. シート、容器、蓋もしくは栓、トレー、医療機器または器具、ハンドル、ノブ、プッシュボタン、装飾用品、パネル、コンソールボックス、または靴の部品である上記1〜5のいずれか一項に記載の成形品。
7. 化粧品容器である上記1〜6のいずれか一項に記載の成形品。
8. 前記容器が、前記アイオノマー組成物から実質的に構成される少なくとも1層を含む多層構造を有する上記7に記載の成形品。
9. 前記アイオノマー組成物から実質的に構成される1層以上の層が、少なくとも約3mmの最小厚さを有する上記8に記載の成形品。
10. 押出成形、ブロー成形、圧縮成形および射出成形からなる群より選択される方法によって製造される上記1〜9のいずれか一項に記載の成形品。
11. コインジェクションモールド法およびオーバーモールド法からなる群より選択される方法によって製造される上記1〜10のいずれか一項に記載の成形品。
Claims (1)
- 3.0mm以上の最小厚さを有する、アイオノマー組成物を含む成形品であって;
前記アイオノマー組成物は、前駆体酸共重合体を部分的に中和することによって製造されるアイオノマーを含み、かつ
前記前駆体酸共重合体は、2〜10個の炭素を有するα−オレフィン共重合単位と、前駆体酸共重合体の全重量に対して19.5〜30重量%の、3〜8個の炭素を有するα,β−エチレン型不飽和カルボン酸共重合単位を含み;
前記前駆体酸共重合体は、ASTM D−1238による190℃、荷重2.16kgでの測定で、30g/10分以下のメルトフローレート(MFR)を有し;
前記前駆体酸共重合体の全カルボン酸含有量の20%〜35%がナトリウムイオン含有陽イオンで中和され、
前記アイオノマーは、ASTM D−1238による190℃、荷重2.16kgでの測定で、5g/10分以下のMFRを有し;かつ
前記アイオノマー組成物を溶融し、この溶融したアイオノマー組成物を板状試験片に成形し、この溶融アイオノマー組成物を0.1℃/分以下の速度で(22±3)℃以下の温度にまで冷却することによって作製される厚さ3.0mmの板状試験片について、ASTM−1003 ASTM D1003により測定されるアイオノマー組成物のヘーズが、0.7〜13.5である成形品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13038208P | 2008-05-30 | 2008-05-30 | |
US61/130,382 | 2008-05-30 | ||
PCT/US2009/045814 WO2009158140A1 (en) | 2008-05-30 | 2009-06-01 | Molded articles comprising ionomer compositions |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2011524918A JP2011524918A (ja) | 2011-09-08 |
JP2011524918A5 JP2011524918A5 (ja) | 2012-07-12 |
JP5485266B2 true JP5485266B2 (ja) | 2014-05-07 |
Family
ID=41347750
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2011511891A Active JP5485266B2 (ja) | 2008-05-30 | 2009-06-01 | アイオノマー組成物を含む成形品 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20090297747A1 (ja) |
EP (1) | EP2288499B1 (ja) |
JP (1) | JP5485266B2 (ja) |
KR (1) | KR20110014680A (ja) |
CN (1) | CN102046373B (ja) |
BR (1) | BRPI0909612A2 (ja) |
WO (1) | WO2009158140A1 (ja) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010051523A1 (en) | 2008-10-31 | 2010-05-06 | E. I. Du Pont De Nemours And Company | High-clarity ionomer compositions and articles comprising the same |
EP2376549B1 (en) | 2008-12-30 | 2013-12-25 | E. I. du Pont de Nemours and Company | High-clarity blended ionomer compositions and articles comprising the same |
CN102325812A (zh) | 2008-12-31 | 2012-01-18 | 纳幕尔杜邦公司 | 具有低雾度和高耐湿性的离聚物组合物以及包含该组合物的制品 |
US8907022B2 (en) | 2011-09-01 | 2014-12-09 | E I Du Pont De Nemours And Company | Method to form an aqueous dispersion of an ionomer |
US8841379B2 (en) | 2011-11-07 | 2014-09-23 | E I Du Pont De Nemours And Company | Method to form an aqueous dispersion of an ionomer-polyolefin blend |
US20130149930A1 (en) | 2011-12-12 | 2013-06-13 | E I Du Pont De Nemours And Company | Methods to form an ionomer coating on a substrate |
US20130225021A1 (en) | 2012-02-29 | 2013-08-29 | E.I. Du Pont De Nemours And Company | Highly viscous ionomer-poly(vinylalcohol) coatings |
US9085123B2 (en) | 2012-02-29 | 2015-07-21 | E I Du Pont De Nemours And Company | Ionomer-poly(vinylalcohol) coatings |
CN104136556A (zh) | 2012-02-29 | 2014-11-05 | 纳幕尔杜邦公司 | 离聚物-聚(乙烯醇)共混物和涂料 |
US20150203704A1 (en) | 2014-01-22 | 2015-07-23 | E I Du Pont De Nemours And Company | Alkali metal-magnesium ionomer compositions |
US11358747B2 (en) * | 2019-04-29 | 2022-06-14 | The Procter & Gamble Company | Low opacity thermoformed container having longitudinal seam |
EP3988296A4 (en) | 2019-06-24 | 2023-07-19 | Japan Polyethylene Corporation | RESIN FOR FILM CAST BODY, AND MOLDED ARTICLE COMPRISING SUCH RESIN |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL8600251A (nl) * | 1986-02-01 | 1987-09-01 | Stamicarbon | Werkwijze voor het vervaardigen van een meerlaagse kunststof houder. |
DE3635334C3 (de) * | 1986-10-17 | 1997-04-03 | Guenter Richter | Vorrichtung zur diskontinuierlichen Herstellung mehrschichtiger, coextrudierter, schlauchartiger Vorformlinge aus thermoplastischem Kunststoff für das Blasformen |
US4944906A (en) * | 1988-10-11 | 1990-07-31 | Spirex Corporation | Methods of injection molding and extruding wet hygroscopic ionomers |
DE69025000T2 (de) * | 1989-05-30 | 1996-09-19 | Kuraray Co | Mehrschichtige Struktur |
US6220972B1 (en) * | 1993-04-28 | 2001-04-24 | Spalding Sports Worldwide, Inc. | Golf ball with multi-layer cover |
US5631328A (en) * | 1993-10-27 | 1997-05-20 | Chevron Chemical Company | Low-haze ionomers of copolymers of alpha-olefins, carboxylic acid esters, and optional comonomers, and processes for making and acidifying these ionomers |
WO1995011929A1 (en) * | 1993-10-27 | 1995-05-04 | Chevron Chemical Company | Low-haze ionomers of copolymers of alpha-olefins, carboxylic acid esters, and optional comonomers, and processes for making and acidifying these ionomers |
JPH09108007A (ja) * | 1995-10-24 | 1997-04-28 | Du Pont Mitsui Polychem Co Ltd | カウンター材料 |
US5902869A (en) * | 1996-03-22 | 1999-05-11 | E. I. Du Pont De Nemours And Company | Thermally stable ethylene/acid copolymers |
US5788890A (en) * | 1996-04-04 | 1998-08-04 | E. I. Du Pont De Nemours And Company | Injection molding process |
US6613406B1 (en) * | 1996-08-13 | 2003-09-02 | Neocork Technologies, Llc | Multilayer synthetic stopper |
US5763062A (en) * | 1996-11-08 | 1998-06-09 | Artistic Glass Products Company | Ionomer resin films and laminates thereof |
US5789475A (en) * | 1997-02-18 | 1998-08-04 | E. I. Du Pont De Nemours And Company | Adipic acid modified-ionomers having improved properties and processability |
US5973046A (en) * | 1997-02-18 | 1999-10-26 | E. I. Du Pont De Nemours And Company | Modified-ionomers having improved properties and processability |
WO1998038227A1 (en) * | 1997-02-28 | 1998-09-03 | E.I. Du Pont De Nemours And Company | New ionomers based on copolymers of ethylene with both mono- and dicarboxylic acids and polyamide blends containing these ionomers |
US6207761B1 (en) * | 1999-03-18 | 2001-03-27 | A. Schulman, Inc. | Ionomer/rubber/polyolefin blend and uses thereof |
JP2001011256A (ja) * | 1999-06-30 | 2001-01-16 | Du Pont Mitsui Polychem Co Ltd | 着色重合体組成物及びその用途 |
DE19940706A1 (de) * | 1999-08-27 | 2001-03-08 | Schott Glas | Verschließbarer Glasbehälter mit einem umspritzten Kunststoffüberzug und Verfahren zu seiner Herstellung |
US20040161623A1 (en) * | 2001-03-29 | 2004-08-19 | Domine Joseph D | Ionomer laminates and articles formed from ionomer laminates |
US20020175136A1 (en) * | 2001-05-23 | 2002-11-28 | Bouix Herve F. | Plastic over-molded bottle |
JP2004083820A (ja) * | 2002-08-29 | 2004-03-18 | Du Pont Mitsui Polychem Co Ltd | 射出成形体 |
US20050129888A1 (en) * | 2003-12-10 | 2005-06-16 | Kwon Hyuk T. | Process for making cosmetic containers having a transparent thermoplastic outer wall |
EP2374837B1 (en) * | 2004-10-29 | 2016-07-20 | E. I. du Pont de Nemours and Company | Thermoplastic resin compositions suitable for use in transparent laminates |
US7445683B2 (en) * | 2005-11-30 | 2008-11-04 | E. I. Du Pont De Nemours And Company | Thermoplastic resin compositions suitable for use in laminated safety glass |
US20070289693A1 (en) * | 2006-06-15 | 2007-12-20 | Anderson Jerrel C | Thermoplastic resin compositions suitable for use in transparent laminates |
CN101489774B (zh) * | 2006-07-19 | 2012-07-11 | 三井-杜邦聚合化学株式会社 | 合成树脂中空体 |
US20080044666A1 (en) * | 2006-08-17 | 2008-02-21 | Anderson Jerrel C | Amine-neutralized ethylene acid copolymers, shaped articles and laminates produced therefrom |
US8802778B2 (en) * | 2008-04-03 | 2014-08-12 | Bridgestone Sports Co., Ltd. | Golf ball material, golf ball and method for preparing golf ball material |
WO2010051523A1 (en) * | 2008-10-31 | 2010-05-06 | E. I. Du Pont De Nemours And Company | High-clarity ionomer compositions and articles comprising the same |
CN102325812A (zh) * | 2008-12-31 | 2012-01-18 | 纳幕尔杜邦公司 | 具有低雾度和高耐湿性的离聚物组合物以及包含该组合物的制品 |
-
2009
- 2009-06-01 WO PCT/US2009/045814 patent/WO2009158140A1/en active Application Filing
- 2009-06-01 JP JP2011511891A patent/JP5485266B2/ja active Active
- 2009-06-01 KR KR1020107029477A patent/KR20110014680A/ko active IP Right Grant
- 2009-06-01 BR BRPI0909612A patent/BRPI0909612A2/pt not_active IP Right Cessation
- 2009-06-01 US US12/475,737 patent/US20090297747A1/en not_active Abandoned
- 2009-06-01 CN CN200980120018.2A patent/CN102046373B/zh active Active
- 2009-06-01 EP EP09770675A patent/EP2288499B1/en active Active
Also Published As
Publication number | Publication date |
---|---|
KR20110014680A (ko) | 2011-02-11 |
WO2009158140A1 (en) | 2009-12-30 |
JP2011524918A (ja) | 2011-09-08 |
BRPI0909612A2 (pt) | 2017-05-23 |
EP2288499A1 (en) | 2011-03-02 |
US20090297747A1 (en) | 2009-12-03 |
CN102046373B (zh) | 2015-09-16 |
EP2288499B1 (en) | 2012-11-28 |
CN102046373A (zh) | 2011-05-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5485266B2 (ja) | アイオノマー組成物を含む成形品 | |
KR102274719B1 (ko) | 에틸렌 산 공중합체, 그의 이오노머, 및 포장 필름과 사출 성형된 물품에서의 그의 용도 | |
JP5840496B2 (ja) | 高透明度のアイオノマー組成物及びそれを含む物品 | |
JP5587336B2 (ja) | 曇り度が低く防水性の高いアイオノマー組成物及びそれを含む物品 | |
JP2012507611A5 (ja) | ||
JP5712141B2 (ja) | 高透明度のブレンドイオノマー組成物およびそれを含む物品 | |
JP2011524918A5 (ja) | ||
JP5135190B2 (ja) | プロピレン系樹脂組成物およびそれを用いた多層シート | |
JP2013515159A (ja) | バイモーダルイオノマー組成物のメルトフローを増加させる方法 | |
JPH04345656A (ja) | 二重オーブン可能トレイを熱成形する際に使用するのに適したポリエステル組成物 | |
JPH0819246B2 (ja) | 容器成形用ポリエステルフィルム | |
US20160076727A1 (en) | Light emitting diode lighting device and housing | |
JP2006117776A (ja) | ポリプロピレン系樹脂組成物 | |
JP2015178572A (ja) | 成形体 | |
JP2015193712A (ja) | 樹脂組成物及び食品包装フィルム | |
JP2015178244A (ja) | 射出ブロー成形体 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120528 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20120528 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130530 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130619 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20130816 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20130823 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20131217 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140120 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140219 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5485266 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |