CN102484245A - 铅蓄电池用负极板的制造方法以及铅蓄电池 - Google Patents
铅蓄电池用负极板的制造方法以及铅蓄电池 Download PDFInfo
- Publication number
- CN102484245A CN102484245A CN2010800290324A CN201080029032A CN102484245A CN 102484245 A CN102484245 A CN 102484245A CN 2010800290324 A CN2010800290324 A CN 2010800290324A CN 201080029032 A CN201080029032 A CN 201080029032A CN 102484245 A CN102484245 A CN 102484245A
- Authority
- CN
- China
- Prior art keywords
- carbon
- coating layer
- lead
- plate
- negative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/14—Electrodes for lead-acid accumulators
- H01M4/16—Processes of manufacture
- H01M4/20—Processes of manufacture of pasted electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0438—Processes of manufacture in general by electrochemical processing
- H01M4/044—Activating, forming or electrochemical attack of the supporting material
- H01M4/0445—Forming after manufacture of the electrode, e.g. first charge, cycling
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0438—Processes of manufacture in general by electrochemical processing
- H01M4/045—Electrochemical coating; Electrochemical impregnation
- H01M4/0452—Electrochemical coating; Electrochemical impregnation from solutions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/14—Electrodes for lead-acid accumulators
- H01M4/16—Processes of manufacture
- H01M4/22—Forming of electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
- H01M4/623—Binders being polymers fluorinated polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Dispersion Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
本发明提供一种铅蓄电池用负极板的制造方法,其是在负极活性物质填充板的表面上具有碳混合剂包覆层的结构的负极板的课题即防止该负极活性物质填充板与该碳混合剂包覆层的界面剥离、提高低下的急速放电特性的铅蓄电池用负极板的制造方法。在负极活性物质填充板的表面的至少一部分上,形成由具有导电性的第一碳材料和具有电容器容量和/或赝电容器容量的第二碳材料构成的两种碳材料至少与粘结剂混合而成的碳混合剂的包覆层之后,在经过从该负极活性物质填充板向该碳混合剂包覆层内移动中使足够的铅离子生成的工序之后,进行化成或者初次充电,将该碳混合剂包覆层与负极板的相互界面的至少一部分通过析出铅连接而一体化。
Description
技术领域
本发明涉及利用PSOC反复急速充放电的适用于混合式汽车用途或风车等产业用的铅蓄电池用负极板的制造方法以及铅蓄电池。
背景技术
目前,在日本特表2007-506230号公报中提出了一种铅蓄电池用负极板,该负极板通过以负极活性物质填充板作为主体,在其表面上形成选自具有导电性的炭黑等第一碳材料和具有电容器容量(capacitance)和/或赝电容器容量(pseudocapacitance)的活性炭等第二碳材料的至少两种碳材料与粘结剂混合而成的碳混合剂(carbon-mix)的包覆层(coating layer),即使利用PSOC反复急速充放电也能够利用电容器的机能大幅度延长寿命。
现行技术文献
专利文献
专利文献1:日本特表2007-506230号公报
发明内容
发明所要解决的课题
然而,在上述专利文献1中提出的负极板中,负极与具有电容器机能的多孔的碳混合剂包覆层即该碳包覆层与其下面的负极板主体的结合由于是该碳包覆层中含有的机械的锚定效果的结合,因此在之后对该负极板进行化成工序或初次充电工序等铅蓄电池的制造工序中,该碳混合剂包覆层容易从负极的表面剥离,另外,与此同时,该碳混合剂包覆层没有充分发挥机能,结果在低温中急速放电性能等劣化,存在着不能得到期待的性能的问题。
本发明在于:解决上述的课题,提供不产生该碳混合剂包覆层与负极板主体的界面剥离且导电性提高的铅蓄电池用负极板的制造方法和提高在低温中的急速放电性能的铅蓄电池。
解决课题的方法
如权利要求1所述,本发明提供铅蓄电池用负极板的制造方法,其特征在于:在负极活性物质填充板的表面的至少一部分上,形成由具有导电性的第一碳材料和具有电容器容量和/或赝电容器容量的第二碳材料构成的两种碳材料与粘结剂混合而成的碳混合剂的包覆层之后,经过从该负极活性物质填充板向该碳混合剂包覆层内移动中使足够的铅离子生成的工序之后,进行化成或初次充电,使铅析出,通过析出的铅将该碳混合剂包覆层与负极板的界面的至少一部分连接而一体化。
并且,如权利要求2所述,本发明提供铅蓄电池,其特征在于:该铅蓄电池具备利用权利要求1所述的制造方法制造的负极板。
发明效果
根据权利要求1涉及的发明,可以制造:所制造的该负极板主体与该碳混合剂包覆层的相互界面部分或者全面地通过析出的铅一体结合的、具有耐剥离性的坚固且导电性提高、并且使电池特性提高的铅蓄电池用负极板。
根据权利要求2涉及的发明,铅蓄电池由于使用具有上述的耐剥离性、且导电性提高的负极板作为负极,因此使利用PSOC的低温急速放电性能提高。
具体实施方式
下面详细叙述本发明的实施例。
在本发明的铅蓄电池用负极板的制造中,与以往同样,作为起始原料,在铅或者铅合金的多孔集电板上填充由铅黄和硫酸等的捏合液构成的负极活性物质原料之后,按照常规方法,使用负极活性物质填充板作为制造原材料,该负极活性物质填充板是由经熟化处理而成的负极熟化板构成的负极活性物质填充板或由将上述负极活性物质原料填充板或负极熟化板经化成处理而成的负极化成板构成的负极活性物质填充板。
根据本发明,首先第一个方面,在加热干燥所述负极活性物质填充板之后,在其至少表面的一部分上涂布碳混合剂,形成其包覆层。详细而言,在其整个两表面上、或者其整个单面上、或者其两面或单面的一部分上涂布碳混合剂,形成其包覆层。
该碳混合剂由确保导电性的第一碳材料和确保电容器容量和/或赝电容器容量的第二碳材料至少与粘结剂的混合物构成。
然而,将在该负极活性物质填充板的表面形成该碳混合剂包覆层的填充板在该填充板为负极熟化板时直接进行化成处理,接着进行初次充电处理,在为负极化成板时进行初次充电处理,在制造各表面被多孔的碳混合剂包覆层包覆的铅蓄电池用负极板时,在任何情况下,负极活性物质填充板和碳混合剂包覆层的相互界面的粘结因为不过是利用粘结剂的机械性锚定的结合而已,因此,在化成处理或初次充电处理中,在其界面上产生剥离而无法进行良好的化成处理或初次充电处理,成为导电性或电容器容量下降的负极板,作为以其为负极的铅蓄电池的情形,判明了导致急速放电特性的劣化或使用寿命的缩短。
为了解决上述课题,本发明是:将在负极活性物质填充板的上面形成碳混合剂包覆层而成的填充板在进行这些化成处理或初次充电处理之前,作为将该碳混合剂包覆层和该负极活性物质填充板的结合一体化的方法,是在电解液浸渍下实施引起从负极活性物质填充板向该碳混合剂包覆层内移动扩散足够的铅离子的处理之后,进行化成处理或初次充电处理,由此可以制造在该碳混合剂包覆层与该负极活性物质填充板的界面上通过析出的铅而一体结合的、无剥离且导电性提高的铅蓄电池用负极板。
作为本发明特征的铅离子的生成方法和之后的铅析出方法,在使用负极化成板作为该负极活性物质填充板时,在负极的表面上形成碳混合剂包覆层之后,在空气中干燥,以碳混合剂包覆层为多孔的包覆层,同时使负极活性物质氧化,这样,然后在注入电解液时容易生成铅离子。并且,延长电解液注入后的浸渍时间,这样,更大量的铅离子向多孔的碳混合剂包覆层内的流入扩散更加容易进行。而且,通过之后的充电处理进行铅的析出而使上述的一体化。并且,另外负极活性物质的活化工序从放电开始,这样,使铅离子生成,接着通过充电使铅析出也是有效的。
附带说一下,如果对以往的缺少碳混合剂包覆层的负极熟化板首先进行例如上述的放电处理,则在其后的充电过程中溶解的铅离子在负极表面上以枝晶状析出,容易引起短路。相对于此,由于本发明的负极具有碳混合剂包覆层,该碳混合剂包覆层捕获铅离子,因此不引起短路。
而且,在本发明的负极板的制造过程中,由于被混入该碳混合剂包覆层的活性炭等的第二碳材料捕捉的铅离子可以抑制与硫酸离子的反应,因此硫酸铅的结晶难以成长,负极板主体与该碳混合剂包覆层的相互界面成为难以引起硫酸盐化的环境。对碳混合剂包覆层内部以及外表面也产生同样的环境。结果,如后述可知,可以制造负极板主体与碳混合剂包覆层通过铅结合的、无界面剥离的坚固且使铅蓄电池在低温中的急速放电特性提高的负极板。
该碳混合剂的混合组成由第一碳材料5~70重量份、第二碳材料20~80重量份以及粘结剂1~20重量份、增粘剂0~10重量份、短纤维状补强材料0~16重量份按照期望混合进行调制。
第一碳材料对确保导电性是必要的,可以是乙炔黑或炉黑等炭黑、科琴黑(Ketjenblack)、石墨等,选择使用其中至少一种。
该第一碳材料的混合量少于5重量份时,则无法确保导电性,导致电容器容量的下降,如果超过70重量份,则导电效果饱和。更优选的量为10~60重量份。
第二碳材料对确保作为电容器和/或赝电容器的容量是必要的,可以是活性炭、炭黑、石墨等,选择使用其中至少一种。混合量少于20重量份时,则电容器容量不足,如果超过80重量份,则第一碳材料的相对比例减少,使容量降低,更优选的量为30~70重量份。
粘结剂对将第一和第二碳材料之间结合以及将这些碳材料与构成铅电池的负极表面结合以确保电连接,同时对包覆层维持多孔的状态是必要的。作为粘结剂可以是聚氯丁二烯、SBR、PTFE、PVDF等,少于1重量份时,则结合变得不充分,如果超过20重量份,则结合效果饱和,同时作为绝缘体使导电性降低。更优选的量为5~15重量份。
增粘剂对将碳混合剂调制成糊状是有用的,水性的糊状可以是CMC或MC等纤维素衍生物、聚丙烯酸盐、聚乙烯醇等,有机类可以是NMP等。使用增粘剂时,干燥残留量(乾燥残分)如果超过10重量份,则合剂的导电性受损,因此干燥残留量优选在该重量份以下。
在将碳混合剂调制为糊状而在负极活性物质填充板上涂布形成其包覆层时,短纤维状补强材料对抑制因干燥而引起的龟裂的发生是有用的。其材质只要是碳、玻璃、PET、聚酯纤维等可以在硫酸酸性中稳定即可,粗度优选直径20μm以下,长度优选0.1mm~4mm。混合量如果超过16重量份,则碳材料或粘结剂的相对混合比例下降,使性能受损,同时使导电性也降低,因此混合量优选在该重量份以下。
相对于构成铅蓄电池的负极活性物质重量100重量份,碳混合剂的量优选为1~15重量份。少于1重量份时,则无法充分得到包覆的效果,如果超过15重量份,则包覆层的厚度增厚,效果饱和。更优选的碳混合剂的量为3~10重量份。多孔的碳混合剂包覆层的孔隙率优选为40%~90%。少于40%时。则电解液的移动受到阻碍,导致放电性能的下降。如果超过90%,则电容器机能效果饱和,同时厚度增厚,导致难以设计。更优选的孔隙率为50~80%。
本发明的进一步详细的实施例如下所示。
实施例1
采用公知的方法,制造用于阀控式铅蓄电池的以往的正极化成板和负极化成板。然后,在除了该负极化成板的耳部的整个两面上涂布由如下表1所示的混合组成构成的糊状碳混合剂,使以干燥重量换算为铅的填充活性物质重量的5重量%,形成其包覆层之后,在空气中于60℃下干燥1小时,形成多孔的碳混合剂包覆层,同时使铅负极活性物质氧化。此时的碳混合剂包覆层的孔隙率为75%。这样制造的负极板与采用公知的方法制造的正极板通过AGM隔板叠层,装配极板组,并将其收纳于电槽内,在正极容量限制下,装配了5小时额定容量为10Ah、2V的铅蓄电池。另外,放入隔离物使极板组的压力调制成50kPa。
接着,将溶解硫酸铝·18水盐(30g/l)的比重1.30的硫酸水溶液作为电解液注入之后,直接在1A下进行20小时充电,然后在2A下放电到电池电压达到1.75V为止。然后,再次在1A下进行15小时的充电和在2A下放电至电池电压1.75V为止,在测定5小时额定容量时,该电池的容量为10Ah。
表1
实施例2
注入实施例1中的电解液后,在1A下进行20小时充电之前,进行1小时浸渍。除此之外,与实施例同样地制造铅蓄电池。
实施例3
将在实施例1中的负极化成板的整个两面上涂布的铅糊状碳混合剂包覆层的干燥在非氧化性的气氛中、例如在氮气氛中于60℃下进行1小时,以防止负极活性物质的氧化,与实施例1同样地装配铅蓄电池,向其中注入电解液之后,在实施例1的1A下进行20小时的充电之前,在1A下进行30小时放电,除此之外,与实施例1同样地制造铅蓄电池。
实施例4
采用公知的方法制造用于阀控式铅蓄电池的正极熟化板和负极熟化板。并且,对该负极熟化板在其整个两面上涂布该碳混合剂,使以干燥重量换算为负极活性物质重量的5重量%,形成该碳混合剂的包覆层之后,注入电解液后,在1A下充电20小时之前,进行1小时浸渍,除此之外,与实施例1同样地进行处理,制造铅蓄电池。
比较例1
将负极化成板上涂布形成的糊状碳混合剂的干燥在非氧化性的氮气氛中于60℃下干燥1小时,除此之外,与实施例1同样地进行处理,制造铅蓄电池。
低温急速放电试验
对上述实施例1~4的各铅蓄电池以及比较例1的铅蓄电池进行如下PSOC低温急速放电试验。即,将完全充电的铅蓄电池在2A下放电2.5小时成为SOC 50%之后,在-30℃下放置16小时,然后在150A下放电10秒,测定第10秒的电压。另外,实验结束之后,将各铅蓄电池解体,检查碳混合剂包覆层和负极板主体的界面有无剥离。其结果示于下表2。
表2
电池电压 | 界面剥离 | |
实施例1 | 1.35V | 无 |
实施例2 | 1.45V | 无 |
实施例3 | 1.25V | 无 |
实施例4 | 1.40V | 无 |
比较例1 | 1.05V | 有 |
由表2可知,本发明实施例1~4的铅蓄电池即使在低PSOC且极低温化下进行急速放电也可以抑制电压的下降。如各实施例1~4所述,这是在化成或者初次放电前对负极附近的铅离子进行过剩的处理的结果,之后的充电中负极活性物质填充板和碳混合剂包覆层通过其相互界面上析出的铅结合而一体化,因此可以防止界面剥离,其结果是导电性提高,电压下降得到抑制,该包覆层作为电容器的机能良好。另一方面,不进行该操作的比较例1电压的下降显著,且该界面间发生了剥离。
需要说明的是,对在负极活性物质填充板的整个单面上、或者两面或单面的一部分上涂布干燥上述碳混合剂而形成碳混合剂包覆层的填充板与实施例1~4同样地在化成或者初次充电之前,进行铅离子生成处理时,也能够制造无界面剥离的负极,同时使铅蓄电池的低温急速放电特性提高。
Claims (2)
1.铅蓄电池用负极板的制造方法,其特征在于:在负极活性物质填充板的表面的至少一部分上,形成由具有导电性的第一碳材料和具有电容器容量和/或赝电容器容量的第二碳材料构成的两种碳材料与粘结剂混合而成的碳混合剂的包覆层之后,在经过从该负极活性物质填充板向该碳混合剂包覆层内移动中使足够的铅离子生成的工序之后,进行化成或者初次充电,使铅析出,该碳混合剂包覆层与负极板的界面的至少一部分通过析出铅连接而一体化。
2.铅蓄电池,其特征在于:该铅蓄电池具备通过权利要求1所述的制造方法制造的负极板。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009-104825 | 2009-04-23 | ||
JP2009104825 | 2009-04-23 | ||
PCT/JP2010/055479 WO2010122873A1 (ja) | 2009-04-23 | 2010-03-19 | 鉛蓄電池用負極板の製造法及び鉛蓄電池 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102484245A true CN102484245A (zh) | 2012-05-30 |
CN102484245B CN102484245B (zh) | 2015-11-25 |
Family
ID=43010996
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201080029032.4A Expired - Fee Related CN102484245B (zh) | 2009-04-23 | 2010-03-19 | 铅蓄电池用负极板的制造方法以及铅蓄电池 |
Country Status (8)
Country | Link |
---|---|
US (1) | US9450232B2 (zh) |
EP (1) | EP2424011A4 (zh) |
JP (1) | JP5680528B2 (zh) |
KR (1) | KR20120027260A (zh) |
CN (1) | CN102484245B (zh) |
CA (1) | CA2759689A1 (zh) |
MX (1) | MX340874B (zh) |
WO (1) | WO2010122873A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105226343A (zh) * | 2015-11-02 | 2016-01-06 | 扬州大学 | 以废铅蓄电池中的含铅化合物为原料制备铅蓄电池正极板的方法 |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AR064292A1 (es) | 2006-12-12 | 2009-03-25 | Commw Scient Ind Res Org | Dispositivo mejorado para almacenamiento de energia |
AR067238A1 (es) | 2007-03-20 | 2009-10-07 | Commw Scient Ind Res Org | Dispositivos optimizados para el almacenamiento de energia |
JP5481922B2 (ja) * | 2009-01-26 | 2014-04-23 | 日本ゼオン株式会社 | 鉛蓄電池用支持体付キャパシタ電極組成物層及び鉛蓄電池用電極の製造方法 |
CA2759689A1 (en) | 2009-04-23 | 2010-10-28 | The Furukawa Battery Co., Ltd. | Method for producing negative plate for use in lead-acid battery and lead-acid battery |
US9401508B2 (en) | 2009-08-27 | 2016-07-26 | Commonwealth Scientific And Industrial Research Organisation | Electrical storage device and electrode thereof |
JP5711483B2 (ja) | 2009-08-27 | 2015-04-30 | 古河電池株式会社 | 鉛蓄電池用複合キャパシタ負極板の製造法及び鉛蓄電池 |
JP5797384B2 (ja) | 2009-08-27 | 2015-10-21 | 古河電池株式会社 | 鉛蓄電池用複合キャパシタ負極板及び鉛蓄電池 |
JP2012133959A (ja) * | 2010-12-21 | 2012-07-12 | Furukawa Battery Co Ltd:The | 鉛蓄電池用複合キャパシタ負極板及び鉛蓄電池 |
JP5598368B2 (ja) * | 2011-02-17 | 2014-10-01 | 株式会社Gsユアサ | 鉛蓄電池及びその負極活物質 |
EP2640040B1 (en) | 2012-03-16 | 2018-10-24 | LG Electronics Inc. | Display module and mobile terminal having the same |
CN103400966B (zh) * | 2013-07-09 | 2015-08-05 | 超威电源有限公司 | 一种铅酸蓄电池极板固化工艺 |
US20190393464A1 (en) * | 2017-12-12 | 2019-12-26 | Hollingsworth & Vose Company | Pasting papers and capacitance layers for batteries comprising multiple fiber types and/or particles |
TWI701861B (zh) * | 2019-08-23 | 2020-08-11 | 百樂電池股份有限公司 | 碳鉛電池 |
JP7008737B2 (ja) * | 2020-03-13 | 2022-01-25 | 本田技研工業株式会社 | リチウムイオン二次電池用電極、およびリチウムイオン二次電池 |
KR102178577B1 (ko) | 2020-06-17 | 2020-11-13 | 주식회사 비티알씨 | 복합카본을 포함하는 전극 및 이를 이용한 에너지 저장장치 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007012596A (ja) * | 2005-05-31 | 2007-01-18 | Shin Kobe Electric Mach Co Ltd | 鉛蓄電池用電極体および鉛蓄電池ならびに鉛蓄電池の製造方法 |
JP2008047452A (ja) * | 2006-08-18 | 2008-02-28 | Shin Kobe Electric Mach Co Ltd | ペースト式電極板及びその製造方法 |
JP2008146898A (ja) * | 2006-12-07 | 2008-06-26 | Shin Kobe Electric Mach Co Ltd | 鉛蓄電池 |
WO2008113133A1 (en) * | 2007-03-20 | 2008-09-25 | Commonwealth Scientific And Industrial Research Organisation | Optimised energy storage device |
Family Cites Families (220)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2856162B2 (ja) | 1996-07-30 | 1999-02-10 | 日本電気株式会社 | 電気二重層コンデンサ及びその製造方法 |
US2938063A (en) | 1957-12-06 | 1960-05-24 | Nat Lead Co | Storage battery active material |
US3881954A (en) | 1974-03-18 | 1975-05-06 | Westinghouse Electric Corp | Method of producing a lead dioxide battery plate |
US4215190A (en) | 1979-06-08 | 1980-07-29 | Ferrando William A | Lightweight battery electrode |
JPS5816839A (ja) | 1981-07-24 | 1983-01-31 | Sumitomo Rubber Ind Ltd | エラストマ−物品の加硫方法 |
JPS59105266U (ja) | 1982-12-27 | 1984-07-16 | 株式会社東芝 | エレベ−タ−の着床予報装置 |
US4507372A (en) | 1983-04-25 | 1985-03-26 | California Institute Of Technology | Positive battery plate |
DE3436290A1 (de) | 1983-10-08 | 1985-04-25 | Honda Giken Kogyo K.K., Tokio/Tokyo | Abgedichtete blei-saeure-batterie |
US4882132A (en) | 1983-12-27 | 1989-11-21 | Monsanto Company | Solvent extraction of cobalt using hydroxamic acids |
US4975253A (en) | 1983-12-27 | 1990-12-04 | Monsanto Company | Solvent extraction of nickel using hydroxamic acids |
US4567284A (en) | 1983-12-27 | 1986-01-28 | Monsanto Company | Cobalt complex of N-alkylalkanohydroxamic acid |
JPS61283173A (ja) | 1985-06-10 | 1986-12-13 | Sharp Corp | 電源素子 |
JPS62103976U (zh) | 1985-12-19 | 1987-07-02 | ||
JPS63103187A (ja) | 1986-10-20 | 1988-05-07 | 日本軽金属株式会社 | 排気二重窓装置 |
US4770954A (en) | 1987-10-16 | 1988-09-13 | Halliburton Company | Switching power supply and method |
WO1989006865A1 (en) | 1988-01-22 | 1989-07-27 | Japan Storage Battery Co. Ltd. | Alkaline secondary battery and process for its production |
JPH03129667A (ja) | 1989-06-05 | 1991-06-03 | Shin Kobe Electric Mach Co Ltd | 電池用電極及び電池 |
US5069990A (en) | 1989-10-10 | 1991-12-03 | Japan Storage Battery Co., Ltd. | Sealed alkaline secondary battery |
CH678556A5 (zh) | 1990-12-17 | 1991-09-30 | Hugues Edwin Luedi Baertschi | |
JPH04233170A (ja) | 1990-12-27 | 1992-08-21 | Yuasa Corp | コンデンサ一体型電池 |
JPH04294515A (ja) | 1991-03-25 | 1992-10-19 | Matsushita Electric Ind Co Ltd | エネルギー貯蔵素子 |
US5154989A (en) | 1991-09-04 | 1992-10-13 | Medtronic, Inc. | Energy storage device |
US5260855A (en) | 1992-01-17 | 1993-11-09 | Kaschmitter James L | Supercapacitors based on carbon foams |
JPH06128317A (ja) | 1992-06-01 | 1994-05-10 | Tonen Corp | α−オレフィン重合用触媒成分 |
FR2692077A1 (fr) | 1992-06-03 | 1993-12-03 | Sorapec | Accumulateurs à électrodes bipolaires. |
US5384685A (en) | 1992-09-18 | 1995-01-24 | Pinnacle Research Institute, Inc. | Screen printing of microprotrusions for use as a space separator in an electrical storage device |
WO1994007272A1 (en) | 1992-09-18 | 1994-03-31 | Pinnacle Research Institute, Inc. | Energy storage device and methods of manufacture |
US5464453A (en) | 1992-09-18 | 1995-11-07 | Pinnacle Research Institute, Inc. | Method to fabricate a reliable electrical storage device and the device thereof |
US5252105A (en) | 1992-10-06 | 1993-10-12 | General Motors Corporation | Method of forming lead-acid battery electrode |
US5491399A (en) | 1993-05-28 | 1996-02-13 | William E. Gregory | Lead acid battery rejuvenator |
US5604426A (en) | 1993-06-30 | 1997-02-18 | Asahi Glass Company Ltd. | Electric apparatus with a power supply including an electric double layer capacitor |
US5393617A (en) * | 1993-10-08 | 1995-02-28 | Electro Energy, Inc. | Bipolar electrochmeical battery of stacked wafer cells |
JP3185508B2 (ja) | 1993-12-29 | 2001-07-11 | 日本電池株式会社 | 密閉形鉛蓄電池 |
US5429893A (en) | 1994-02-04 | 1995-07-04 | Motorola, Inc. | Electrochemical capacitors having dissimilar electrodes |
US5439756A (en) | 1994-02-28 | 1995-08-08 | Motorola, Inc. | Electrical energy storage device and method of charging and discharging same |
US5419977A (en) | 1994-03-09 | 1995-05-30 | Medtronic, Inc. | Electrochemical device having operatively combined capacitor |
JPH07249405A (ja) | 1994-03-10 | 1995-09-26 | Haibaru:Kk | 電 池 |
US5518833A (en) | 1994-05-24 | 1996-05-21 | Eagle-Picher Industries, Inc. | Nonwoven electrode construction |
US5458043A (en) | 1994-07-28 | 1995-10-17 | The United States Of America As Represented By The Secretary Of The Air Force | Battery charging capacitors electromagnetic launcher |
AU2124495A (en) | 1994-10-12 | 1996-05-06 | Bipolar Technologies Corporation | Bipolar battery cells, batteries, and methods |
US5705259A (en) | 1994-11-17 | 1998-01-06 | Globe-Union Inc. | Method of using a bipolar electrochemical storage device |
US5526223A (en) | 1994-12-01 | 1996-06-11 | Motorola, Inc. | Electrode materials and electrochemical capacitors using same |
US5574353A (en) | 1995-03-31 | 1996-11-12 | Motorola, Inc. | Electrochemical charge storage device having constant voltage discharge |
JP2984908B2 (ja) | 1995-09-19 | 1999-11-29 | 大電株式会社 | 二次電池の電極及びそれを有する二次電池 |
US5587250A (en) | 1995-09-27 | 1996-12-24 | Motorola, Inc. | Hybrid energy storage system |
US5626729A (en) | 1996-02-01 | 1997-05-06 | Motorola, Inc. | Modified polymer electrodes for energy storage devices and method of making same |
US20040112486A1 (en) | 1996-03-01 | 2004-06-17 | Aust Karl T. | Thermo-mechanical treated lead and lead alloys especially for current collectors and connectors in lead-acid batteries |
JPH1021900A (ja) | 1996-07-01 | 1998-01-23 | Tokuyama Corp | 密閉型鉛蓄電池用正極板および密閉型鉛蓄電池 |
US5821007A (en) | 1996-08-19 | 1998-10-13 | Motorola, Inc. | Power source for an electrical device |
JPH1094182A (ja) | 1996-09-13 | 1998-04-10 | Honda Motor Co Ltd | 電源装置および電気自動車 |
US5849426A (en) | 1996-09-20 | 1998-12-15 | Motorola, Inc. | Hybrid energy storage system |
US5670266A (en) | 1996-10-28 | 1997-09-23 | Motorola, Inc. | Hybrid energy storage system |
IT1285994B1 (it) | 1996-11-25 | 1998-06-26 | Eliodoro S A | Metodo per aumentare l'efficienza di celle foto-elettro-chimiche e celle foto-elettro-chimiche ottenute con tale metodo |
JP3661725B2 (ja) | 1996-12-20 | 2005-06-22 | 旭硝子株式会社 | 電源装置 |
US5744258A (en) | 1996-12-23 | 1998-04-28 | Motorola,Inc. | High power, high energy, hybrid electrode and electrical energy storage device made therefrom |
US6330925B1 (en) | 1997-01-31 | 2001-12-18 | Ovonic Battery Company, Inc. | Hybrid electric vehicle incorporating an integrated propulsion system |
US6011379A (en) | 1997-03-12 | 2000-01-04 | U.S. Nanocorp, Inc. | Method for determining state-of-charge using an intelligent system |
US5993983C1 (en) | 1997-03-14 | 2001-09-18 | Century Mfg Co | Portable power supply using hybrid battery technology |
US5935724A (en) | 1997-04-04 | 1999-08-10 | Wilson Greatbatch Ltd. | Electrochemical cell having multiplate electrodes with differing discharge rate regions |
US5935728A (en) | 1997-04-04 | 1999-08-10 | Wilson Greatbatch Ltd. | Electrochemical cell having multiplate and jellyroll electrodes with differing discharge rate regions |
JP4003845B2 (ja) | 1997-04-17 | 2007-11-07 | 日立マクセル株式会社 | 電気二重層キャパシタと電池とのハイブリッド素子 |
US5916699A (en) | 1997-05-13 | 1999-06-29 | Motorola, Inc. | Hybrid energy storage system |
BR9705871C3 (pt) | 1997-05-26 | 2004-08-10 | Guacemmi Participacoees Societ | Sistema radiante em acumuladores e produto resultante |
US6316563B2 (en) | 1997-05-27 | 2001-11-13 | Showa Denko K.K. | Thermopolymerizable composition and use thereof |
US6087812A (en) | 1997-06-13 | 2000-07-11 | Motorola, Inc. | Independent dual-switch system for extending battery life under transient loads |
US5821006A (en) | 1997-07-07 | 1998-10-13 | Motorola, Inc. | Hybrid cell/capacitor assembly for use in a battery pack |
JPH1141664A (ja) | 1997-07-24 | 1999-02-12 | Toshiba Corp | 無線電話装置 |
US6117585A (en) | 1997-07-25 | 2000-09-12 | Motorola, Inc. | Hybrid energy storage device |
US6190805B1 (en) | 1997-09-10 | 2001-02-20 | Showa Denko Kabushiki Kaisha | Polymerizable compound, solid polymer electrolyte using the same and use thereof |
JPH1197319A (ja) | 1997-09-17 | 1999-04-09 | Ckd Corp | チップ型コンデンサの治具 |
AU719684B2 (en) | 1997-11-11 | 2000-05-18 | Zakrytoe Aktsionernoe Obschestvo "Esma" | Capacitor with dual electric layer |
JPH11224699A (ja) | 1998-02-04 | 1999-08-17 | Fuji Electric Co Ltd | エネルギー貯蔵素子 |
US6610440B1 (en) | 1998-03-10 | 2003-08-26 | Bipolar Technologies, Inc | Microscopic batteries for MEMS systems |
US6765363B2 (en) | 1998-03-10 | 2004-07-20 | U.S. Microbattery, Inc. | Micro power supply with integrated charging capability |
US6514639B2 (en) | 1998-03-20 | 2003-02-04 | Ensci Inc | Negative plate element for a lead acid battery containing efficiency improving additives |
DE19815127A1 (de) | 1998-04-03 | 1999-10-07 | Basf Ag | Mittel mit Copolymerisaten aus N-Vinylcarbonsäureamiden und Monomeren mit hydrophobem Rest, und Verwendung dieser Copolymerisate |
US6088217A (en) | 1998-05-31 | 2000-07-11 | Motorola, Inc. | Capacitor |
JP2000013915A (ja) | 1998-06-26 | 2000-01-14 | Mitsubishi Materials Corp | 蓄電装置 |
JP2000021408A (ja) | 1998-06-30 | 2000-01-21 | Shin Kobe Electric Mach Co Ltd | 非水電解液二次電池 |
US6208502B1 (en) | 1998-07-06 | 2001-03-27 | Aerovox, Inc. | Non-symmetric capacitor |
KR100547455B1 (ko) | 1998-08-25 | 2006-02-01 | 후지 주코교 카부시키카이샤 | 전극재 |
JP2000077076A (ja) | 1998-09-02 | 2000-03-14 | Toyota Motor Corp | 蓄電池用鉛基合金 |
US6331365B1 (en) | 1998-11-12 | 2001-12-18 | General Electric Company | Traction motor drive system |
US6222723B1 (en) | 1998-12-07 | 2001-04-24 | Joint Stock Company “Elton” | Asymmetric electrochemical capacitor and method of making |
JP3105204B2 (ja) | 1999-02-15 | 2000-10-30 | 株式会社東芝 | 非水電解液二次電池 |
US6252762B1 (en) | 1999-04-21 | 2001-06-26 | Telcordia Technologies, Inc. | Rechargeable hybrid battery/supercapacitor system |
JP3820149B2 (ja) | 1999-06-25 | 2006-09-13 | ザ ボード オブ トラスティーズ オブ ザ ユニバーシティ オブ イリノイ | 動的切換可能な電力変換器 |
US6310789B1 (en) | 1999-06-25 | 2001-10-30 | The Procter & Gamble Company | Dynamically-controlled, intrinsically regulated charge pump power converter |
JP3348405B2 (ja) | 1999-07-22 | 2002-11-20 | エヌイーシートーキン株式会社 | インドール系高分子を用いた二次電池及びキャパシタ |
US20030129458A1 (en) | 1999-09-02 | 2003-07-10 | John C. Bailey | An energy system for delivering intermittent pulses |
JP2001110418A (ja) | 1999-10-13 | 2001-04-20 | Toyota Central Res & Dev Lab Inc | リチウム二次電池用正極およびそれを用いたリチウム二次電池 |
JP4845244B2 (ja) | 1999-10-25 | 2011-12-28 | 京セラ株式会社 | リチウム電池 |
US6576365B1 (en) | 1999-12-06 | 2003-06-10 | E.C.R. - Electro Chemical Research Ltd. | Ultra-thin electrochemical energy storage devices |
EP1126536B1 (en) | 2000-02-16 | 2007-05-16 | Nisshinbo Industries, Inc. | Multi-layer electrode structure, and method of manufacturing same |
JP2001284188A (ja) | 2000-04-03 | 2001-10-12 | Asahi Glass Co Ltd | 電気二重層キャパシタ電極用炭素材料の製造方法及びこの炭素材料を用いた電気二重層キャパシタの製造方法 |
US6555265B1 (en) | 2000-04-06 | 2003-04-29 | Hawker Energy Products, Inc. | Value regulated lead acid battery |
KR100359055B1 (ko) | 2000-04-25 | 2002-11-07 | 한국과학기술연구원 | 박막형 슈퍼 캐패시터 및 그 제조방법 |
JP2001319655A (ja) | 2000-05-10 | 2001-11-16 | Nec Corp | ポリキノキサリンエーテルを用いた2次電池及びキャパシター |
JP2001332264A (ja) | 2000-05-25 | 2001-11-30 | Shin Kobe Electric Mach Co Ltd | 小形制御弁式鉛蓄電池 |
JP4825344B2 (ja) | 2000-06-07 | 2011-11-30 | Fdk株式会社 | 電池・キャパシタ複合素子 |
WO2001095410A1 (en) | 2000-06-07 | 2001-12-13 | Andelman Marc D | Fluid and electrical connected flow-through electrochemical cells, system and method |
AU2002239222A1 (en) | 2000-06-23 | 2002-07-08 | Millenium Energy, Llc | Novel compositions for use in batteries, capacitors, fuel cells and for hydrogen production |
US6333123B1 (en) | 2000-06-28 | 2001-12-25 | The Gillette Company | Hydrogen recombination catalyst |
JP2002047372A (ja) | 2000-07-31 | 2002-02-12 | Nitto Denko Corp | 多孔質フィルムとその製造方法および電池 |
JP5020432B2 (ja) | 2000-08-04 | 2012-09-05 | パナソニック株式会社 | チップ型積層コンデンサ |
JP2002050543A (ja) | 2000-08-04 | 2002-02-15 | Matsushita Electric Ind Co Ltd | チップ型積層コンデンサ |
US6623884B1 (en) | 2000-08-07 | 2003-09-23 | Wilson Greatbatch Ltd. | Electrochemical lithium ion secondary cell having multiplate and jellyroll electrodes with differing discharge rate regions |
US6541140B1 (en) | 2000-08-07 | 2003-04-01 | Wilson Greatbatch Technologies, Inc. | Electrochemical lithium ion secondary cell having multiplate electrodes with differing discharge rate regions |
JP2002075788A (ja) | 2000-09-05 | 2002-03-15 | Nec Corp | 電気二重層コンデンサおよび電池セルの積層体 |
JP3471304B2 (ja) | 2000-09-18 | 2003-12-02 | Necトーキン株式会社 | インドール系化合物を用いた二次電池及びキャパシタ |
US6517972B1 (en) | 2000-09-29 | 2003-02-11 | Telcordia Technologies, Inc. | High energy density hybrid battery/supercapacitor system |
JP2002118036A (ja) | 2000-10-10 | 2002-04-19 | Sanshin:Kk | 蓄電用電子部品および複合電極体 |
CN1357899A (zh) | 2000-12-13 | 2002-07-10 | 中国科学院成都有机化学研究所 | 碳纳米管用于超级电容器电极材料 |
US7110242B2 (en) | 2001-02-26 | 2006-09-19 | C And T Company, Inc. | Electrode for electric double layer capacitor and method of fabrication thereof |
US7119047B1 (en) | 2001-02-26 | 2006-10-10 | C And T Company, Inc. | Modified activated carbon for capacitor electrodes and method of fabrication thereof |
JP2002298853A (ja) | 2001-03-28 | 2002-10-11 | Tagawa Kazuo | リチウム二次電池および電気二重層キャパシタ |
JP2002367613A (ja) * | 2001-04-03 | 2002-12-20 | Hitachi Ltd | 鉛蓄電池 |
EP1248307A1 (en) | 2001-04-03 | 2002-10-09 | Hitachi, Ltd. | Lead-acid battery |
JP3573102B2 (ja) | 2001-04-20 | 2004-10-06 | ソニー株式会社 | 負極活物質及び非水電解質二次電池 |
EP1382081A1 (en) | 2001-04-24 | 2004-01-21 | Reveo, Inc. | Hybrid electrochemical cell system |
US6466429B1 (en) | 2001-05-03 | 2002-10-15 | C And T Co., Inc. | Electric double layer capacitor |
US6628504B2 (en) | 2001-05-03 | 2003-09-30 | C And T Company, Inc. | Electric double layer capacitor |
US6653014B2 (en) | 2001-05-30 | 2003-11-25 | Birch Point Medical, Inc. | Power sources for iontophoretic drug delivery systems |
TW571494B (en) | 2001-06-05 | 2004-01-11 | Us Microbattery Inc | Micro power supply with integrated charging capability |
US20040121204A1 (en) | 2001-06-07 | 2004-06-24 | Adelman Marc D. | Fluid electrical connected flow-through electrochemical cells, system and method |
JP4364460B2 (ja) | 2001-08-07 | 2009-11-18 | 古河電池株式会社 | 鉛蓄電池用負極 |
KR20030014988A (ko) | 2001-08-14 | 2003-02-20 | 한국전자통신연구원 | 하이브리드 전원소자 및 그 제조방법 |
JP3794553B2 (ja) | 2001-09-06 | 2006-07-05 | 株式会社デンソー | リチウム二次電池電極及びリチウム二次電池 |
JP2003087988A (ja) | 2001-09-06 | 2003-03-20 | Furukawa Electric Co Ltd:The | 蓄電装置 |
JP3815774B2 (ja) | 2001-10-12 | 2006-08-30 | 松下電器産業株式会社 | 電解質を含む電気化学素子 |
JP4004769B2 (ja) | 2001-10-17 | 2007-11-07 | Necトーキン株式会社 | 電解液、並びにこれを用いた電気化学セル |
WO2003055791A2 (en) | 2001-10-17 | 2003-07-10 | Applied Materials, Inc. | Improved etch process for etching microstructures |
FR2831318B1 (fr) | 2001-10-22 | 2006-06-09 | Commissariat Energie Atomique | Dispositif de stockage d'energie a recharge rapide, sous forme de films minces |
JP2003132941A (ja) | 2001-10-29 | 2003-05-09 | Matsushita Electric Ind Co Ltd | コンデンサ一体型の固体電解質二次電池 |
JP3809549B2 (ja) | 2001-11-22 | 2006-08-16 | 株式会社日立製作所 | 電源装置と分散型電源システムおよびこれを搭載した電気自動車 |
JP2003200739A (ja) | 2002-01-08 | 2003-07-15 | Nissan Motor Co Ltd | 蓄電装置およびその使用 |
JP2005293850A (ja) | 2002-03-08 | 2005-10-20 | Akira Fujishima | 電力貯蔵体用電極、電力貯蔵体、および電力貯蔵方法 |
KR100416617B1 (ko) | 2002-03-25 | 2004-02-05 | 삼성전자주식회사 | tDQSS 윈도우를 개선할 수 있는 데이터 입력방법 및데이터 입력버퍼 |
DE60324407D1 (de) | 2002-04-18 | 2008-12-11 | Furukawa Battery Co Ltd | Legierung auf bleibasis für eine bleispeicherbatterie, platte für eine bleispeicherbatterie und bleispeicherbatterie |
US6706079B1 (en) | 2002-05-03 | 2004-03-16 | C And T Company, Inc. | Method of formation and charge of the negative polarizable carbon electrode in an electric double layer capacitor |
US7105252B2 (en) | 2002-05-22 | 2006-09-12 | Firefly Energy, Inc. | Carbon coated battery electrodes |
JP2004055541A (ja) | 2002-05-31 | 2004-02-19 | Hitachi Maxell Ltd | 複合エネルギー素子 |
JP3969223B2 (ja) | 2002-07-10 | 2007-09-05 | クラレケミカル株式会社 | 活性炭及び活性炭を用いた電気二重層キャパシタ用電極 |
EP1418428A1 (en) | 2002-11-07 | 2004-05-12 | GenOdyssee | Method to provide natural therapeutic agents with high therapeutic index |
CA2394056A1 (fr) | 2002-07-12 | 2004-01-12 | Hydro-Quebec | Particules comportant un noyau non conducteur ou semi conducteur recouvert d'un couche conductrice, leurs procedes d'obtention et leur utilisation dans des dispositifs electrochimiques |
JP3657245B2 (ja) | 2002-07-18 | 2005-06-08 | Necトーキン株式会社 | インドール系化合物を用いた二次電池およびキャパシタ |
WO2004012964A1 (ja) | 2002-08-01 | 2004-02-12 | Japan Storage Battery Co., Ltd. | 乗物用電源装置およびこの電源装置を備えた乗物 |
JP2004134369A (ja) | 2002-08-13 | 2004-04-30 | Shin Kobe Electric Mach Co Ltd | リチウム二次電池及び電気自動車 |
EP1391961B1 (en) | 2002-08-19 | 2006-03-29 | Luxon Energy Devices Corporation | Battery with built-in load leveling |
AU2002952234A0 (en) | 2002-10-24 | 2002-11-07 | Commonwealth Scientific And Industrial Research Organisation | Lead compositions for lead-acid batteries |
JP4833504B2 (ja) | 2002-11-22 | 2011-12-07 | 日立マクセルエナジー株式会社 | 電気化学キャパシタおよびそれを構成要素とするハイブリッド電源 |
JP4375042B2 (ja) | 2003-02-18 | 2009-12-02 | 三菱化学株式会社 | 非水系リチウムイオン二次電池用の負極材料及び負極、並びに非水系リチウムイオン二次電池 |
US7006346B2 (en) | 2003-04-09 | 2006-02-28 | C And T Company, Inc. | Positive electrode of an electric double layer capacitor |
JP2004355823A (ja) | 2003-05-27 | 2004-12-16 | Nec Tokin Corp | ハイブリッド型蓄電部品 |
JP2005026349A (ja) | 2003-06-30 | 2005-01-27 | Tdk Corp | 電気化学キャパシタ用電極の製造方法及び電気化学キャパシタの製造方法 |
JP2005032938A (ja) | 2003-07-11 | 2005-02-03 | Sanyo Electric Co Ltd | 電気二重層コンデンサ及び電池 |
JP4329434B2 (ja) | 2003-07-30 | 2009-09-09 | 三菱化学株式会社 | リチウム二次電池用正極及びそれを用いたリチウム二次電池 |
JP2005080470A (ja) | 2003-09-02 | 2005-03-24 | Japan Radio Co Ltd | 蓄電装置 |
ES2537655T3 (es) | 2003-09-18 | 2015-06-10 | Commonwealth Scientific And Industrial Research Organisation | Dispositivos de almacenamiento de energía de alto rendimiento |
JP2005129446A (ja) | 2003-10-27 | 2005-05-19 | Hitachi Ltd | 電気化学エネルギー貯蔵デバイス |
TWI276240B (en) | 2003-11-26 | 2007-03-11 | Ind Tech Res Inst | Fuel cell power supply device |
JP2005160271A (ja) | 2003-11-28 | 2005-06-16 | Honda Motor Co Ltd | ハイブリッド電源装置およびモータ駆動装置および車両 |
TWI268005B (en) | 2003-12-01 | 2006-12-01 | Yi-Hsuan Huang | Active additive for lead-acid battery and its application |
JP2005183632A (ja) | 2003-12-18 | 2005-07-07 | Mitsubishi Chemicals Corp | 電気化学デバイス及びこれを用いた電気二重層コンデンサ又は電池 |
JP4294515B2 (ja) | 2004-03-08 | 2009-07-15 | 積水ハウス株式会社 | 侵入手口体験装置 |
JP2005294497A (ja) | 2004-03-31 | 2005-10-20 | Kyocera Chemical Corp | 電気二重層コンデンサ及び電池 |
JP4148175B2 (ja) | 2004-03-31 | 2008-09-10 | 新神戸電機株式会社 | 鉛合金及びそれを用いた鉛蓄電池 |
JP2005327489A (ja) | 2004-05-12 | 2005-11-24 | Matsushita Electric Ind Co Ltd | 蓄電素子用正極 |
JP2005332655A (ja) | 2004-05-19 | 2005-12-02 | Hitachi Ltd | エネルギー貯蔵デバイス、それを用いたモジュール、及び電気自動車 |
JP4617727B2 (ja) | 2004-06-08 | 2011-01-26 | パナソニック株式会社 | 二次電源 |
WO2006006218A1 (ja) | 2004-07-09 | 2006-01-19 | Osaka Gas Co., Ltd. | 電気二重層キャパシタ用活性炭、電気二重層キャパシタ用活性炭電極およびそれを用いた電気二重層キャパシタ |
JP2006156002A (ja) | 2004-11-26 | 2006-06-15 | Nissan Motor Co Ltd | 固体電解質電池 |
KR100758482B1 (ko) | 2004-12-07 | 2007-09-12 | 주식회사 엘지화학 | 표면 처리된 다공성 필름 및 이를 이용한 전기 화학 소자 |
KR100570359B1 (ko) | 2004-12-23 | 2006-04-12 | 비나텍주식회사 | 하이브리드 전지 |
WO2007058421A1 (en) | 2005-11-16 | 2007-05-24 | Vina Technology Co., Ltd. | Hybrid battery |
US20060172196A1 (en) | 2005-01-11 | 2006-08-03 | Matsushita Electric Industrial Co., Ltd. | Non-aqueous electrolyte rechargeable battery and manufacturing method of negative electrode employed therein |
JP2006252902A (ja) | 2005-03-10 | 2006-09-21 | Kawasaki Heavy Ind Ltd | ハイブリッド電池 |
KR100700711B1 (ko) | 2005-04-15 | 2007-03-27 | 주식회사 에너랜드 | 하이브리드 전기에너지 저장장치 |
JP4839669B2 (ja) | 2005-04-28 | 2011-12-21 | 日本ゼオン株式会社 | 電気化学素子電極用複合粒子 |
JP4894165B2 (ja) | 2005-05-19 | 2012-03-14 | パナソニック株式会社 | 二次電池用放電回路並びにそれを具備した二次電池パック及び電子機器 |
JP4506571B2 (ja) | 2005-06-07 | 2010-07-21 | トヨタ自動車株式会社 | 車両用電源システムおよび車両 |
US7649335B2 (en) | 2005-06-07 | 2010-01-19 | Toyota Jidosha Kabushiki Kaisha | Vehicular power supply system and vehicle |
DE102005038351A1 (de) | 2005-08-11 | 2007-02-15 | Siemens Ag | Elektrochemischer Energiespeicher |
US8194394B2 (en) | 2005-09-22 | 2012-06-05 | Honda Motor Co., Ltd. | Polarized electrode and electric double-layer capacitor |
US20080264291A1 (en) | 2005-10-19 | 2008-10-30 | Rail Power Technologies Corp | Design of a Large Low Maintenance Battery Pack for a Hybrid Locomotive |
US20070128472A1 (en) | 2005-10-27 | 2007-06-07 | Tierney T K | Cell Assembly and Casing Assembly for a Power Storage Device |
JP4957011B2 (ja) | 2006-02-21 | 2012-06-20 | トヨタ自動車株式会社 | 電池パック構造 |
KR100614118B1 (ko) | 2006-02-24 | 2006-08-22 | 주식회사 비츠로셀 | 하이브리드 전지 |
JP2007280803A (ja) | 2006-04-07 | 2007-10-25 | Teijin Ltd | ハイブリッド型積層電極、それを用いたハイブリッド二次電源 |
JP2008022605A (ja) | 2006-07-11 | 2008-01-31 | Fdk Energy Co Ltd | キャパシタ一体型電池 |
KR100921345B1 (ko) | 2006-07-31 | 2009-10-13 | 주식회사 엘지화학 | 캐패시터-이차전지 구조의 하이브리드형 전극조립체 |
US8023251B2 (en) | 2006-10-23 | 2011-09-20 | Axion Power International, Inc. | Hybrid energy storage device and method of making same |
AR064292A1 (es) | 2006-12-12 | 2009-03-25 | Commw Scient Ind Res Org | Dispositivo mejorado para almacenamiento de energia |
JP5041351B2 (ja) | 2006-12-15 | 2012-10-03 | 日本カーボン株式会社 | リチウムイオン二次電池用負極活物質の製造方法及びリチウムイオン二次電池用負極活物質 |
JP5029809B2 (ja) | 2007-01-15 | 2012-09-19 | 信越化学工業株式会社 | 非水電解液並びにこれを用いた二次電池 |
CA2677940C (en) | 2007-02-16 | 2013-10-22 | Universal Supercapacitors Llc | Electrochemical supercapacitor/lead-acid battery hybrid electrical energy storage device |
JP4983304B2 (ja) | 2007-02-26 | 2012-07-25 | 新神戸電機株式会社 | エネルギ変換デバイス |
CN100481609C (zh) | 2007-06-25 | 2009-04-22 | 中南大学 | 一种超级电容电池 |
EP2172422B1 (en) | 2007-07-04 | 2018-10-03 | Power Carbon Technology Co., Ltd. | Process for producing activated carbon for electric double layer capacitor electrode |
JP5171824B2 (ja) | 2007-07-20 | 2013-03-27 | エナックス株式会社 | 蓄電デバイス |
US7948739B2 (en) | 2007-08-27 | 2011-05-24 | Nanotek Instruments, Inc. | Graphite-carbon composite electrode for supercapacitors |
JP2009081949A (ja) | 2007-09-26 | 2009-04-16 | Toshiba Corp | 組電池の保護装置及びこれを含む組電池システム |
CN100555715C (zh) | 2007-09-28 | 2009-10-28 | 深圳市今星光实业有限公司 | 一种铅酸蓄电池正极铅膏 |
JP2009104827A (ja) | 2007-10-22 | 2009-05-14 | Hitachi Ltd | 画像表示装置 |
JP2009135056A (ja) | 2007-12-03 | 2009-06-18 | Shin Kobe Electric Mach Co Ltd | 電源装置 |
DE102007058837A1 (de) | 2007-12-05 | 2009-06-10 | Technische Universität Clausthal | Elektrochemisches Energieumwandlungssystem |
WO2009094931A1 (en) | 2008-01-28 | 2009-08-06 | Ang Yang | Charge-and-work type charging battery |
FR2927472B1 (fr) | 2008-02-11 | 2010-07-30 | Commissariat Energie Atomique | Systeme hybride de stockage d'energie electrique a electrodes bipolaires |
JP4834021B2 (ja) | 2008-03-14 | 2011-12-07 | メタウォーター株式会社 | メタン発酵処理方法 |
US8030901B2 (en) | 2008-04-16 | 2011-10-04 | Nisshinbo Holdings Inc. | Electric energy storage device |
US8017273B2 (en) | 2008-04-28 | 2011-09-13 | Ut-Battelle Llc | Lightweight, durable lead-acid batteries |
WO2009137508A1 (en) | 2008-05-05 | 2009-11-12 | Ada Technologies, Inc. | High performance carbon nanocomposites for ultracapacitors |
WO2010008392A1 (en) | 2008-07-18 | 2010-01-21 | Meadwestvaco Corporation | Enhanced negative plates for lead acid batteries |
WO2010032785A1 (ja) | 2008-09-22 | 2010-03-25 | 日本ゼオン株式会社 | 鉛蓄電池用電極および鉛蓄電池 |
CN101414691A (zh) | 2008-11-27 | 2009-04-22 | 苏州大学 | 碳板负极板密封铅酸电池 |
CA2759689A1 (en) | 2009-04-23 | 2010-10-28 | The Furukawa Battery Co., Ltd. | Method for producing negative plate for use in lead-acid battery and lead-acid battery |
JP5797384B2 (ja) | 2009-08-27 | 2015-10-21 | 古河電池株式会社 | 鉛蓄電池用複合キャパシタ負極板及び鉛蓄電池 |
JP5711483B2 (ja) | 2009-08-27 | 2015-04-30 | 古河電池株式会社 | 鉛蓄電池用複合キャパシタ負極板の製造法及び鉛蓄電池 |
US9401508B2 (en) | 2009-08-27 | 2016-07-26 | Commonwealth Scientific And Industrial Research Organisation | Electrical storage device and electrode thereof |
JP2012133959A (ja) | 2010-12-21 | 2012-07-12 | Furukawa Battery Co Ltd:The | 鉛蓄電池用複合キャパシタ負極板及び鉛蓄電池 |
-
2010
- 2010-03-19 CA CA2759689A patent/CA2759689A1/en not_active Abandoned
- 2010-03-19 JP JP2011510269A patent/JP5680528B2/ja active Active
- 2010-03-19 US US13/265,944 patent/US9450232B2/en active Active
- 2010-03-19 KR KR1020117027792A patent/KR20120027260A/ko active IP Right Grant
- 2010-03-19 MX MX2011011106A patent/MX340874B/es active IP Right Grant
- 2010-03-19 CN CN201080029032.4A patent/CN102484245B/zh not_active Expired - Fee Related
- 2010-03-19 EP EP10766932.7A patent/EP2424011A4/en not_active Withdrawn
- 2010-03-19 WO PCT/JP2010/055479 patent/WO2010122873A1/ja active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007012596A (ja) * | 2005-05-31 | 2007-01-18 | Shin Kobe Electric Mach Co Ltd | 鉛蓄電池用電極体および鉛蓄電池ならびに鉛蓄電池の製造方法 |
JP2008047452A (ja) * | 2006-08-18 | 2008-02-28 | Shin Kobe Electric Mach Co Ltd | ペースト式電極板及びその製造方法 |
JP2008146898A (ja) * | 2006-12-07 | 2008-06-26 | Shin Kobe Electric Mach Co Ltd | 鉛蓄電池 |
WO2008113133A1 (en) * | 2007-03-20 | 2008-09-25 | Commonwealth Scientific And Industrial Research Organisation | Optimised energy storage device |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105226343A (zh) * | 2015-11-02 | 2016-01-06 | 扬州大学 | 以废铅蓄电池中的含铅化合物为原料制备铅蓄电池正极板的方法 |
Also Published As
Publication number | Publication date |
---|---|
MX340874B (es) | 2016-07-28 |
KR20120027260A (ko) | 2012-03-21 |
CN102484245B (zh) | 2015-11-25 |
CA2759689A1 (en) | 2010-10-28 |
MX2011011106A (es) | 2012-02-29 |
US9450232B2 (en) | 2016-09-20 |
EP2424011A1 (en) | 2012-02-29 |
US20120094174A1 (en) | 2012-04-19 |
JPWO2010122873A1 (ja) | 2012-10-25 |
WO2010122873A1 (ja) | 2010-10-28 |
EP2424011A4 (en) | 2014-01-15 |
JP5680528B2 (ja) | 2015-03-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102484245A (zh) | 铅蓄电池用负极板的制造方法以及铅蓄电池 | |
JP5715630B2 (ja) | 蓄電装置及びその電極 | |
CN103855431B (zh) | 一种提高锂离子电池循环性能的化成方法 | |
CN103904291B (zh) | 水系锂离子电池电极及其制备方法、水系锂离子电池 | |
US5952123A (en) | Electrode plates for lead-acid battery and their manufacturing method | |
CN107735889B (zh) | 掺杂的导电氧化物以及基于此材料的改进电化学储能装置极板 | |
CN101764264B (zh) | 一种超级铅酸电池 | |
US10763500B2 (en) | Zinc electrodes for batteries | |
JP2014096238A (ja) | 蓄電デバイス用正極の製造方法、及び正極 | |
CN105047877A (zh) | 负极活性材料及其制备方法和应用 | |
CN111732867A (zh) | 一种涂层浆料和涂层和锂离子电池及其用途 | |
CN1331257C (zh) | 汽车起动用阀控密封铅酸蓄电池正极铅膏及制备方法 | |
CN116914119A (zh) | 一种补锂正极及其制备方法和应用 | |
KR101142533B1 (ko) | 금속계 아연 음극 활물질 및 이를 이용한 리튬이차전지 | |
JP5557385B2 (ja) | プロトンを挿入種とする蓄電デバイス | |
JP5396216B2 (ja) | 鉛蓄電池 | |
CN108539151B (zh) | 二次电池用电极材料及二次电池 | |
US9705135B2 (en) | Negative electrode for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery | |
JP2000251896A (ja) | 鉛蓄電池及びその製造方法 | |
CN112366363A (zh) | 一种耐高温锂离子电池的制备方法 | |
CN113451658A (zh) | 一种三维电极结构的全固态锂离子电池及其制造方法 | |
KR102424563B1 (ko) | 다공성 그래핀이 코팅된 Pb@C 나노입자 촉매 극판 제조 방법 | |
Matthews et al. | The behaviour of lead dioxide electrodes in acidic sulfate electrolytes | |
KR20230044876A (ko) | 탄소 종이를 사용한 납축전지의 극판 제조방법 | |
JP2771584B2 (ja) | 非焼結式密閉アルカリ蓄電池の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151125 Termination date: 20210319 |
|
CF01 | Termination of patent right due to non-payment of annual fee |