Classifications

• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
  • G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
  • G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
  • G03H1/0252—Laminate comprising a hologram layer
  • G03H1/0256—Laminate comprising a hologram layer having specific functional layer
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
  • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
  • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
  • B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
  • B42D25/29—Securities; Bank notes
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
  • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
  • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
  • B42D25/30—Identification or security features, e.g. for preventing forgery
  • B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
  • B42D25/364—Liquid crystals
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/0147—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on thermo-optic effects
• • B42D2033/26—
• • B42D2033/46—
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
  • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
  • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
  • B42D25/30—Identification or security features, e.g. for preventing forgery
  • B42D25/328—Diffraction gratings; Holograms
• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
  • G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
  • G03H1/0005—Adaptation of holography to specific applications
  • G03H1/0011—Adaptation of holography to specific applications for security or authentication
• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
  • G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
  • G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
  • G03H1/024—Hologram nature or properties
  • G03H1/0244—Surface relief holograms
• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
  • G03H2250/00—Laminate comprising a hologram layer
  • G03H2250/38—Liquid crystal
• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
  • G03H2260/00—Recording materials or recording processes
  • G03H2260/12—Photopolymer

Definitions

• the invention relates to a multilayer body with an optically effective layer system.
• Optically effective layer systems are used, for example, for decorative or informative purposes, or to provide security documents with optical security features, which on the one hand make forgery using modern color copiers and other reproduction systems and on the other hand easily and clearly recognizable to the layman.
• security threads as security elements, wherein the arrangement is such that the thread is partially exposed surface and so the incorporated in the thread optical security features, such as holograms or partial Demetallmaschineen, are verifiable for the viewer.
• EP 1 134 694 A1 it is known from EP 1 134 694 A1 to print on a sheet or a strip of paper an electronic circuit made of organic semiconductor material, which is connected via a conductor track to a metal strip of a banknote.
• the electronic circuit is not based on built-up of conventional semiconductor materials electronic components, but on organic Field effect transistors in polymer semiconductor technology.
• the metal strip serves as an antenna, via which a communication between the semiconductor circuit with a corresponding evaluation circuit is possible.
• the electronic circuit can be used to detect forgeries, further locating the document is possible.
• the invention is based on the object of specifying a multilayer body with an improved visual appearance.
• the object of the invention is achieved with a multilayer body having an optically effective first layer system, wherein the first layer system is an optically variable element (OVD), and the optical effect of the first layer system can be influenced by an electrically controllable second layer system.
• first layer system is an optically variable element (OVD)
• OLED optically variable element
• Such a multi-layer body can be formed with a small thickness and flexible, resulting in respect to his
• the multi-layer body can be produced inexpensively, for example, as a film body in a roll-to-roll process and is therefore suitable for mass products.
• the multilayer body according to the invention can be used both as a novel security element for value documents, security documents and for securing merchandise, as well as for decorative purposes or for product advertising. Furthermore, the multilayer body can be used in displays, in RFID tags and as a status display in electrical appliances.
• the multilayer body may be formed as a large-area foil body, For example, be applied to packaging, windows or building surfaces.
• the second layer system is arranged above the first layer system.
• the second layer system can be controlled in its optical properties, in particular in its optical density and / or in its light scattering and / or in its color.
• the second layer system has an upper and a lower electrode layer, between which one or more layers are arranged.
• the layers are preferably layers whose optical properties can be changed by the application of a voltage between the electrode layers.
• the upper electrode layer and / or the lower electrode layer may be made of polyethylene dioxythiopene (PEDOT) / PSS or PANI.
• the upper electrode layer and / or the lower electrode layer is an ITO (indium-tin oxide) layer.
• ITO indium-tin oxide
• Such layers are transparent conductive layers.
• the upper electrode may also consist of a very thin translucent metal layer.
• the metal layer may have a thickness of 0.5 nm to 30 nm, typically have a thickness of 5 nm and be of gold, silver, chromium, copper or aluminum.
• the second layer system comprises a layer which is arranged between the upper and the lower electrode layer and which has a plurality of liquid crystal bubbles having a diameter of 0.1 .mu.m to 40 .mu.m, bound in a polymer matrix are.
• the polymer matrix may consist, for example, of monomers in a layer thickness of 5 ⁇ m to 40 ⁇ m, e.g. be polymerized by UV irradiation. This may be, for example, the product PN 393 from Nematel.
• the liquid crystal bubbles have liquid crystals in disordered, random orientation. Therefore, they dissipate incident light, so that layers arranged under the layer are imperceptible or can not be sharply imaged.
• the liquid crystals are aligned in an electric field formed between the upper and lower electrode layers when the electrode layers are connected to the poles of an electric power source.
• the voltage source may be both a DC voltage source and an AC voltage source. It can therefore be provided, electrochemical
• Voltage sources electrical resonant circuits, which are in an electromagnetic field and their signal with an electronic circuit to a suitable signal frequency, e.g. 100Hz is processed or to use solar cells as a voltage source for the multilayer body according to the invention.
• the second layer system one between the upper and the Having lower electrode layer arranged liquid crystal layer and at least one polarizer layer.
• two polarizer layers can be provided whose polarization planes are crossed by 90 °.
• the liquid-crystal layer has cholesteric liquid crystals. By the liquid crystals, the polarization direction of the light is rotated by 90 °. As a result, the polarized light can pass through the lower polarization layer.
• the second layer system therefore appears transparent and gives a clear view of the first layer system. If an electric field is formed between the two electrode layers, the second layer system appears dark and obstructs the view of the first layer system arranged thereunder.
• the second layer system has an electrolyte layer arranged between the upper and the lower electrode layer, and that the upper electrode layer is an electrochromic layer, for example made of an electrically conductive organic material
• a redox reaction controllable by the current direction in the electrolyte layer can change the color of an electrochromic layer of PEDOT / PSS from pale blue to dark blue. If the electrochromic layer is made of PANI, the color can be changed from green blue to bluish.
• the electrolyte layer may also contain metal ions, wherein the current direction in the electrolyte layer determines whether metal ions are transported from the electrolyte layer into the electrochromic electrode layer or removed therefrom. For example, if the metal ions are tungsten ions, the electrochromic electrode layer can be controlled from dark blue to colorless.
• electrochromic systems such as those that react to a change in pH. These can also be used.
• the electrically conductive layer forms the lower electrode layer of the second layer system.
• the second layer system has a thermochromic layer and an electrical resistance layer.
• At least one layer of the first layer system forms the electrical resistance layer of the second layer system.
• the second layer system may be configured to include areas that represent pictorial and / or alphanumeric information.
• the areas may, for example, take the form of letters which form a lettering that can emerge through the electrical activation of the second layer system. It may also be a barcode which only emerges when the multilayer body in a reader is exposed to an electric field.
• Such a feature can not be forged with conventional reproduction methods.
• it may be provided in such an application that the second layer system is formed without electrode layers.
• the second layer system is therefore imperceptible. It can further be provided that the optical effect of the second layer system is reversibly controllable.
• the caused by an electrical voltage optical change of the second layer system is obtained after switching off the electrical voltage.
• the liquid crystals may be formed as ferroelectric liquid crystals.
• Ferroelectric liquid crystals can store the effect of the electric field for a long time, for example over weeks, and can be reset by an electrical impulse. It may thus be provided, for example, to use a multilayer body with ferroelectric liquid crystals as data storage for an expiration date.
• the expiration date can be seen after expiration of a period of expiration, because the ferroelectric liquid crystals return to their original position and the second structural layer becomes transparent again.
• it may be provided to form such a multilayer body without electrodes, so that the necessary for the alignment of the ferroelectric liquid crystals electric field can be formed only in dedicated devices.
• An electrically controllable layer system is understood here to be any layer system whose optical effect is changed by applying an electrical voltage in at least one parameter. This is the change of a material property, which is determined by an electrical quantity.
• the first layer system has a replication layer and an optical separation layer or a reflection layer and a replication layer in the replication diffractive relief structure is formed, which forms in particular a diffraction grating and / or a hologram or Kinegram ⁇ or Trustseal or comparable system.
• the first layer system may be a thin-film layer system for generating viewing angle-dependent color shift effects by means of interference.
• the thin film layer system from a sequence of high and low refractive index layers.
• HRI High Refraction Index
• LRI Low Refraction Index
• the first layer system may also be a layer system which is a cholesteric one
• Liquid crystal layer and an absorption layer exhibits a viewing angle dependent color shifting effect similar to that of a thin film layer system.
• Electrodes are also conceivable which require only one electrode plane.
• This may be, for example, a heating element for a thermochromic layer or a previously described layer system with cholesteric layers Liquid crystals, which can be controlled in the plane.
• the layer arranged under the liquid crystals may have elevations spaced apart from one another with a width of approx. 20 ⁇ m and a height of 20 ⁇ m to 100 ⁇ m, which are arranged at a distance of less than 100 ⁇ m. Between the elevations, an above-described OVD may be formed, which appears optically as a whole because of the small dimensions of the elevations.
• the electrodes formed on the bumps form strip-shaped areas, which are alternately connected to the poles of a voltage source switchable. The electric field formed between the regions thus extends within the liquid crystal layer and not perpendicular to the liquid crystal layer.
• each electrode area can be controlled in rows and columns.
• liquid crystals located between an upper electrode layer and a checkerboard patterned lower electrode layer point by point. It can therefore be provided that liquid crystals arranged over selected regions of the lower electrode layer are aligned in the electric field and that liquid crystals arranged over non-driven regions of the lower electrode layer retain the disordered alignment.
• the driven or non-driven areas may thus form a pattern, such as an image, logo or one or more alphanumeric characters.
• the electrically isolated areas can be controlled alternately be so that the subregions change their visual appearance successively.
• the multilayer body has a control electronics, which is preferably an organic control electronics.
• the multilayer body has one or more sensors and / or RFID circuits and / or displays and / or switches and / or voltage sources.
• the field of application of the multilayer body according to the invention is roughly outlined, with other applications are not limited thereby.
• the multilayer body is flexible and / or has a flexible, transparent carrier film.
• a flexible multilayer body can advantageously also be applied to curved surfaces. It is particularly resistant to buckling loads that can occur on thin carrier substrates such as packaging, banknotes or documents.
• flexible multilayer bodies can be inexpensively mass-produced on equipment intended for a roll-to-roll process.
• additional assemblies such as RFID tag's, solar cells, batteries, memory, integrated circuits, film switches and sensors can be easily integrated into the multi-layer body.
• FIG. 2a shows a second embodiment of an inventive and 2b multi-layer body in a schematic
• 3a shows a third embodiment of an inventive and 3b multi-layer body in a schematic
• 4a shows a fourth embodiment of an inventive and 4b multilayer body in a schematic
• 5a shows a fifth embodiment of an inventive and 5b multilayer body in a schematic
• 6a shows an application example of a multilayer body according to the invention up to 7b.
• 1 a and 1 b show a schematic sectional view of a multilayer body 1 with an optically variable layer system 10 and a controllable layer system 20.
• the layer system 10 is an optically variable element (OVD) with a structure layer 12 into which a diffraction grating 12b is shaped.
• the structure layer 12 can be formed, for example, from a thermoplastic replication lacquer with a layer thickness of a few ⁇ m into which the diffraction grating 12b has been embossed by means of a heated replication roller.
• the structure layer 12 is covered with a metallic reflection layer 14, which consists for example of aluminum, silver, chromium, copper or gold.
• the controllable layer system 20 has a carrier layer 22, which is arranged on the metallic layer 14.
• the carrier layer 22 is a polymer matrix in which a plurality of liquid crystal bubbles 22f are embedded.
• the liquid crystal bubbles have a diameter of 0.1 .mu.m to 15 .mu.m.
• the polymer matrix consists of PN393, which can be applied with a layer thickness of 5 ⁇ m to 40 ⁇ m. A layer thickness of 10 ⁇ m is preferred.
• a transparent protective layer 26 is arranged, which has an electrode layer 24 on its underside.
• layers 26 and 24 are Agfa's transparent conductive coated Orgakon® film, with electrode layer 24 being a transparent conductive polymer. These are PEDOT / PSS, which can have a layer thickness of 50 nm to 500 nm. A layer thickness of 200 nm is preferred.
• the electrode layer 24 may also be formed as a transparent metallic layer. Between the electrode layer 24 and the metallic reflection layer 14, by applying an electric voltage, an electric field can be formed in which the liquid crystals contained in the liquid crystal bubbles 22f can align. The liquid crystals are symbolized in Figs. Ia and Ib by short dashes.
• the metallic reflection layer 14 in this exemplary embodiment is therefore at the same time an electrode layer for the electrically controllable layer system 20. Thus, it is a layer with a multiple function.
• the electrical voltage for controlling the layer system 20 is provided by an electrical voltage source 30, which is connected by connecting lines 34 and 34 ⁇ and a switch 32 to the layers 14 and 24 in an electrically conductive manner.
• the connecting lines 34, 34 'shown symbolically in FIGS. 1 a and 1 b can be strip conductors which are formed by continuation of the electrically conductive layers 14 and 24. However, it may also be metallic interconnects which are in electrical contact with the layers 14 and 24 and vapor-deposited, for example.
• Fig. Ia shows the multilayer body 1 with the switch 32 open.
• Liquid crystals assume a random random position, so that light incident on the multi-layer body 1 is diffusely reflected, as a result of which the first layer system 10 is not or only indistinctly recognizable or can not form an optical effect.
• FIG. 1b now shows the multilayer body 1 with the switch 32 closed.
• an electric field is now formed whose field lines are perpendicular to the field Surface of the layers 14 and 24 is aligned, so that the arranged in the liquid crystal bubbles 22f liquid crystals now occupy an ordered position with parallel alignment with the electric field lines. Because of their small diameter of a few nm, they impinge light striking the multi-layer body 1 almost completely on the surface of the structure layer 12 occupied by the reflection layer 14, so that the first layer system 10 can develop its optical effect as OVD.
• the electrical voltage source 30 can be both a DC voltage source and an AC voltage source.
• the output from the voltage source 30 voltage is important. In the embodiment shown in Fig. Ia and Ib, a voltage of about 20 V is provided.
• the voltage source 30 is switched on and off by means of the switch 32. But it can also be provided to dispense with the switch 32 and form the voltage source 30 as a resonant circuit in which by an external electromagnetic field a
• Alternating voltage is induced, which is possibly still converted by means of a rectifier into a DC voltage.
• This DC voltage can by a suitable electronics, for example, a ring oscillator, back into an AC voltage in particularly favorable frequency range can be converted by 100 Hz.
• a capacitor which provides when driving with DC voltage even after switching off the electromagnetic field for a limited time.
• the multilayer body forms a so-called RFID tag, ie a circuit arrangement for radio-frequency-based identification of objects, the elements mentioned above can be components of such an RFID tag.
• the RFID tag may be formed as an organic film circuit.
• the structure layer 12 is now formed with a relief structure having elevations with a width of about 20 microns and a height of 20 microns to 100 microns, which are arranged in a decency ⁇ 100 microns. Between the elevations, the diffraction gratings 12b, which are also shown in FIGS. 1a and 1b, are shaped into the structure layer.
• the metallic one is also shown in FIGS. 1a and 1b.
• Reflective layer 14 is now on the projections arranged strip-like regions, which are alternately connected ⁇ to the interconnecting lines 34 and 34 so that the strip-shaped regions of the reflection layer 14 with a closed switch 32 (see Fig. 2b) alternately to the positive or negative pole of the voltage source 30 are connected.
• the electric field formed between the regions thus extends within the carrier layer 22 and not perpendicular to the carrier layer 22, as in the first embodiment shown in FIGS. 1a and 1b.
• the liquid crystals contained in the liquid crystal bubbles 22f become analogous to FIG Field aligned when the switch 32 is closed, as shown in Fig. 2b.
• It can also be provided to arrange the elevations in the structure layer 12 like a checkerboard and to form the connecting lines as a matrix, so that each area of the reflection layer 14 can be driven in rows and columns. Another, not shown
• Embodiment may additionally provide an electrode layer 24, as shown in Fig. Ia and Ib, so that with the aid of the checkerboard patterned reflection layer 14, the liquid crystals arranged over driven areas of the reflection layer 14 are aligned in the electric field and arranged over non-driven areas of the reflection layer 14 Liquid crystals maintain the disordered alignment.
• the driven or uncontrolled areas may thus form a pattern, such as a logo or one or more alphanumeric characters.
• FIGS. 3a and 3b now show a multilayer body 2 which differs from the multilayer body 1 shown in FIGS. 1a and 1b only by the design of the controllable layer system.
• a controllable layer system 40 comprises a liquid crystal layer 42, in which liquid crystals 42f are embedded, which are capable of rotating the polarization plane of polarized light.
• the upper surface of the liquid crystal layer 42 is covered by an upper polarizer layer 46o and the lower surface of the liquid crystal layer is covered by a lower polarizer layer 46u.
• the polarization directions of the polarizer layers 46o and 46u are crossed by 90 °. Incident light is thus polarized before entering the liquid crystal layer.
• the liquid crystals now rotate the polarization plane of the polarized light by 90 °. This has the consequence that the polarized light through the lower polarization layer 46u can pass and is reflected at the reflection layer 14 of the layer system 10.
• the reflected light is now again rotated by the stacked liquid crystals 42f and exits from the upper polarizer layer 46o.
• the layer system 40 therefore appears transparent and gives a view of the OVD layer system 10.
• the transparent protective layer 26 is arranged, which on its underside the
• Electrode layer 24 has. As stated above, layers 26 and 24 are e.g. a transparent conductive coated Orgakon film TM.
• the electrode layer 24 is connected to the voltage source 30 via the connection line 34 * and the switch 32.
• the other pole of the voltage source 30 is connected to the metallic layer 14 through the connection line 34.
• FIG. 2 b shows this state of the multilayer body 2 in which the optical effect formed by the layer system 10 can no longer be observed.
• ferroelectric liquid crystals may be provided. Ferroelectric liquid crystals have the property of storing electric fields, so that the switching state of a liquid crystal layer formed with ferroelectric liquid crystals is maintained for a longer time even after the voltage has been switched off. This liquid crystal layer can be reset by a switching pulse.
• FIG. 4a and 4b now show a multilayer body 3, in which on the optically variable layer system 10, an electrically controllable layer system 50 is arranged, which is formed of an electrolyte layer 52 which is contacted with two electrode layers.
• the lower electrode layer is as in the previously described
• An upper electrode layer 54 is formed of an electrochromic material, such as PEDOT / PSS.
• the upper electrode layer 54 is covered by the protective layer 26.
• Both electrode layers 14 and 54 are connected to the voltage source 30 with the connection lines 34 and 34 ⁇ , which are led to a switch 32u.
• the voltage source 30 is a DC voltage source whose polarity determines the optical state of the electrochromic electrode layer 54.
• the current direction is determined by the position of the switch 32u and transported in the illustrated embodiment, metal ions from the electrolyte layer 52 in the electrochromic electrode layer 54 or removed therefrom.
• the electrochromic electrode layer 54 may be controlled from dark blue to colorless.
• further embodiments are possible, which are based on determined by the current direction redox reactions or on the change in the pH of the electrolyte layer.
• the switch 32u is a two-pole change-over switch with the aid of which the current direction of the electric current flowing through the electrolyte layer 52 can be reversed. In this way, the electrochromic electrode layer 54 can be brought from a first colored opaque state to a colorless transparent state.
• FIGS. 5a and 5b show a multilayer body 4 in which an electrically controllable layer system 60 which has a thermochromic layer 62 is arranged on the optically variable layer system 10.
• the thermochromic layer 62 consists in the illustrated embodiment of TCX B-31 Fa. Coates Screen in a layer thickness of about 20 microns. The layer thickness can be between 0.5 and 100 microns.
• the thermochromic layer 62 is covered by the protective layer 26.
• the metallic reflection layer 14 of the layer system 10 is connected by the electrical connection lines 34, 34 'and the switch 32 to the voltage source 30 and at the same time forms an electrical resistance layer for heating the thermochromic layer 62.
• the reflection layer 14 to a layer that is functionally assigned to two layer systems of the multilayer body.
• the resistance layer is transparent, for example made of ITO (indium-tin oxide) or another conductive material.
• ITO indium-tin oxide
• PANI for transparent resistance layers come For example, PEDOT / PSS or PANI in question.
• the resistance layer can also be arranged below the structure layer 12 and in this case does not have to be transparent.
• thermochromic layer 62 is opaque when the switch 32 is opened. Now, if the switch 32 is closed, as shown in Fig. 5b, the reflective layer 14 is heated by the onset of current flow and consequently also on the
• thermochromic layer 62 heated and transparent in this way. Now, the optical effect formed by the optically variable layer system 10 is perceptible.
• FIGS. 6a to 7b now show an example of application of the multilayer body according to the invention.
• FIG. 6a shows a schematic sectional view of a multilayer body 5, which is designed like the multilayer body 1 shown in FIGS. 1a and 1b.
• Fig. Ia and Ib are summarized.
• a layer 52 of liquid crystal bubbles bonded in a polymer matrix is provided with an upper electrode layer 54 and disposed on an OVD layer system 56 formed of a replicating layer and a metallic reflecting layer as shown in Figs. Ia and Ib.
• the reflection layer facing the OVD layer system also forms the lower electrode layer for the layer 52.
• the OVD layer system 56 has a lettering 56s, which is only indistinct or imperceptible because of the opaque in the dead state layer 52.
• FIGS. 7a and 7b show the multi-layer body 5, whose electrode layers are now connected to the voltage source 58 because the switch 58 s is closed.
• the layer 52 is therefore designed as a clear layer, so that now arranged on the OVD layer system 56 lettering 56s is clearly legible.
• the optical effect to perceive which may be, for example, a color change when tilting the multi-layer body 5. It may also be provided that the lettering 56s shows a viewing angle-dependent optical effect, e.g. his position seems to change.
• the multilayer body according to the invention may have further layers, for example an adhesive layer which is applied to the rear side of the optically variable layer system or layers which form functional elements such as voltage sources, sensors or electronic circuits. It can preferably be provided that the layers are formed from polymers, in particular also for the formation of electronic circuits.
• the term "organic" circuits should also be understood to mean circuits or circuit arrangements which, in addition to organic layers, also have or only inorganic layers.
• the multilayer bodies of the invention are further characterized by the fact that they can be formed with a small thickness and flexible, resulting in particular advantages in terms of their application and their production.
• the multilayer bodies can, for example, as a film body are produced inexpensively in a roll-to-roll process and are therefore suitable for mass production.
• the multilayer body according to the invention can also have an inflexible carrier material, for example of glass or ceramic, without departing from the scope of the invention.
• the multilayer body according to the invention can also be designed for an irreversible change in the optical properties. It may be provided, for example, that the change is caused by a short-term overvoltage and the multi-layer body permanently signals the overstress that has occurred. Such an effect can be triggered, for example, in electrochromic layers by an irreversible chemical process in the electrolyte layer.

Landscapes

• Physics & Mathematics (AREA)
• General Physics & Mathematics (AREA)
• Nonlinear Science (AREA)
• Business, Economics & Management (AREA)
• Accounting & Taxation (AREA)
• Finance (AREA)
• Optics & Photonics (AREA)
• Engineering & Computer Science (AREA)
• Computer Security & Cryptography (AREA)
• Chemical & Material Sciences (AREA)
• Crystallography & Structural Chemistry (AREA)
• Liquid Crystal (AREA)
• Diffracting Gratings Or Hologram Optical Elements (AREA)
• Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
• Semiconductor Lasers (AREA)

Priority Applications (8)

Applications Claiming Priority (2)

Publications (1)

Family

ID=36932719

Family Applications (1)

Country Status (11)

Cited By (3)

Families Citing this family (26)

Citations (13)

Family Cites Families (258)

• 2005
  • 2005-07-04 DE DE102005031448A patent/DE102005031448A1/de not_active Ceased
• 2006
  • 2006-07-04 JP JP2008519845A patent/JP5425466B2/ja not_active Expired - Fee Related
  • 2006-07-04 CN CN2006800284242A patent/CN101258516B/zh not_active Expired - Fee Related
  • 2006-07-04 EP EP06762366.0A patent/EP1899901B8/de active Active
  • 2006-07-04 CA CA2614064A patent/CA2614064C/en active Active
  • 2006-07-04 US US11/994,571 patent/US7940340B2/en not_active Expired - Fee Related
  • 2006-07-04 AU AU2006265350A patent/AU2006265350B2/en not_active Ceased
  • 2006-07-04 ES ES06762366.0T patent/ES2560861T3/es active Active
  • 2006-07-04 KR KR1020087002408A patent/KR101424820B1/ko not_active Expired - Fee Related
  • 2006-07-04 WO PCT/EP2006/006472 patent/WO2007003405A1/de not_active Ceased
  • 2006-07-04 TW TW095124285A patent/TWI457634B/zh not_active IP Right Cessation

Patent Citations (13)

Also Published As

Similar Documents

Legal Events