JP5564144B1

JP5564144B1 - 硬化性樹脂組成物、そのドライフィルム及び硬化物並びにそれらを用いたプリント配線板

硬化性樹脂組成物、そのドライフィルム及び硬化物並びにそれらを用いたプリント配線板 Download PDF

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Publication number: JP5564144B1
Authority: JP; Japan
Prior art keywords: group; resin composition; curable resin; compound; manufactured
Prior art date: 2013-01-15
Legal status : Active

Application number

JP2013236002A

Other languages

English (en)

Japanese (ja)

Other versions

JP2014156583A (ja

Inventor

一善米田

裕横山

聖夫有馬

Current Assignee

Taiyo Ink Manufacturing Co Ltd

Original Assignee

Taiyo Ink Manufacturing Co Ltd

Priority date

2013-01-15

Filing date

2013-11-14

Publication date

2014-07-30

2013-11-14 Application filed by Taiyo Ink Manufacturing Co Ltd filed Critical Taiyo Ink Manufacturing Co Ltd

2013-11-14 Priority to JP2013236002A priority Critical patent/JP5564144B1/ja

2014-01-13 Priority to KR1020140003815A priority patent/KR20140092252A/ko

2014-01-15 Priority to CN201410017290.0A priority patent/CN103926791B/zh

2014-07-30 Application granted granted Critical

2014-07-30 Publication of JP5564144B1 publication Critical patent/JP5564144B1/ja

2014-08-28 Publication of JP2014156583A publication Critical patent/JP2014156583A/ja

2016-04-21 Priority to KR1020160048785A priority patent/KR20160051705A/ko

Status Active legal-status Critical Current

2033-11-14 Anticipated expiration legal-status Critical

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239000011342 resin composition Substances 0.000 title claims abstract description 90
229920005989 resin Polymers 0.000 claims abstract description 95
239000011347 resin Substances 0.000 claims abstract description 95
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 80
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 52
239000000377 silicon dioxide Substances 0.000 claims abstract description 26
239000012766 organic filler Substances 0.000 claims abstract description 24
239000003999 initiator Substances 0.000 claims abstract description 16
229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 11
150000001875 compounds Chemical class 0.000 claims description 67
239000003822 epoxy resin Substances 0.000 claims description 58
229920000647 polyepoxide Polymers 0.000 claims description 58
238000000576 coating method Methods 0.000 claims description 42
239000011248 coating agent Substances 0.000 claims description 39
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 34
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 31
229910052698 phosphorus Inorganic materials 0.000 claims description 31
239000011574 phosphorus Substances 0.000 claims description 31
229920003986 novolac Polymers 0.000 claims description 24
229920001187 thermosetting polymer Polymers 0.000 claims description 23
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 22
238000000034 method Methods 0.000 claims description 20
239000004305 biphenyl Substances 0.000 claims description 17
235000010290 biphenyl Nutrition 0.000 claims description 17
239000003063 flame retardant Substances 0.000 claims description 17
229910052751 metal Inorganic materials 0.000 claims description 15
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 14
238000001035 drying Methods 0.000 claims description 14
239000002184 metal Substances 0.000 claims description 14
230000015572 biosynthetic process Effects 0.000 claims description 9
PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical group C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 9
JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 9
ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 8
150000003839 salts Chemical class 0.000 claims description 8
229910000679 solder Inorganic materials 0.000 claims description 6
230000036961 partial effect Effects 0.000 claims description 4
238000000016 photochemical curing Methods 0.000 claims description 4
230000007547 defect Effects 0.000 abstract description 7
-1 diol compound Chemical class 0.000 description 131
239000000049 pigment Substances 0.000 description 86
239000010408 film Substances 0.000 description 75
239000003086 colorant Substances 0.000 description 36
239000000203 mixture Substances 0.000 description 34
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 31
125000002887 hydroxy group Chemical group [H]O* 0.000 description 31
125000004432 carbon atom Chemical group C* 0.000 description 30
239000000047 product Substances 0.000 description 30
239000000758 substrate Substances 0.000 description 25
229920000642 polymer Polymers 0.000 description 24
125000000217 alkyl group Chemical group 0.000 description 23
239000000126 substance Substances 0.000 description 23
239000004593 Epoxy Substances 0.000 description 20
238000011156 evaluation Methods 0.000 description 19
239000012948 isocyanate Substances 0.000 description 17
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238000006243 chemical reaction Methods 0.000 description 16
230000000052 comparative effect Effects 0.000 description 16
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229910052757 nitrogen Inorganic materials 0.000 description 16
239000005056 polyisocyanate Substances 0.000 description 16
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238000011161 development Methods 0.000 description 14
230000018109 developmental process Effects 0.000 description 14
239000000806 elastomer Substances 0.000 description 14
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 14
239000007787 solid Substances 0.000 description 14
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 13
239000007864 aqueous solution Substances 0.000 description 13
238000013329 compounding Methods 0.000 description 13
125000003700 epoxy group Chemical group 0.000 description 13
238000002156 mixing Methods 0.000 description 13
239000000178 monomer Substances 0.000 description 13
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 13
239000002253 acid Substances 0.000 description 12
239000000463 material Substances 0.000 description 12
GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 12
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 12
229920005862 polyol Polymers 0.000 description 12
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 11
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
229910052802 copper Inorganic materials 0.000 description 11
239000010949 copper Substances 0.000 description 11
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
239000003054 catalyst Substances 0.000 description 10
239000007795 chemical reaction product Substances 0.000 description 10
150000003077 polyols Chemical class 0.000 description 10
235000013824 polyphenols Nutrition 0.000 description 10
239000002904 solvent Substances 0.000 description 10
125000003545 alkoxy group Chemical group 0.000 description 9
229910052782 aluminium Inorganic materials 0.000 description 9
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 9
125000004122 cyclic group Chemical group 0.000 description 9
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 9
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 9
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 9
229920000728 polyester Polymers 0.000 description 9
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical group S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 9
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 8
230000001588 bifunctional effect Effects 0.000 description 8
239000010410 layer Substances 0.000 description 8
239000002245 particle Substances 0.000 description 8
238000007650 screen-printing Methods 0.000 description 8
229910052708 sodium Inorganic materials 0.000 description 8
239000011734 sodium Substances 0.000 description 8
238000012360 testing method Methods 0.000 description 8
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 7
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
150000008065 acid anhydrides Chemical class 0.000 description 7
150000001252 acrylic acid derivatives Chemical class 0.000 description 7
125000003277 amino group Chemical group 0.000 description 7
150000008064 anhydrides Chemical class 0.000 description 7
150000004056 anthraquinones Chemical class 0.000 description 7
239000003963 antioxidant agent Substances 0.000 description 7
238000005452 bending Methods 0.000 description 7
XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 7
239000007822 coupling agent Substances 0.000 description 7
239000000945 filler Substances 0.000 description 7
239000003960 organic solvent Substances 0.000 description 7
229920001721 polyimide Polymers 0.000 description 7
238000003825 pressing Methods 0.000 description 7
239000012321 sodium triacetoxyborohydride Substances 0.000 description 7
238000003786 synthesis reaction Methods 0.000 description 7
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
238000002835 absorbance Methods 0.000 description 6
239000003513 alkali Substances 0.000 description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
239000013039 cover film Substances 0.000 description 6
125000004663 dialkyl amino group Chemical group 0.000 description 6
125000005442 diisocyanate group Chemical group 0.000 description 6
229910001507 metal halide Inorganic materials 0.000 description 6
150000005309 metal halides Chemical class 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
239000002966 varnish Substances 0.000 description 6
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 5
239000006087 Silane Coupling Agent Substances 0.000 description 5
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
125000002723 alicyclic group Chemical group 0.000 description 5
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 5
125000003118 aryl group Chemical group 0.000 description 5
125000000751 azo group Chemical group [*]N=N[*] 0.000 description 5
239000011230 binding agent Substances 0.000 description 5
239000006229 carbon black Substances 0.000 description 5
150000002009 diols Chemical class 0.000 description 5
239000011521 glass Substances 0.000 description 5
238000010438 heat treatment Methods 0.000 description 5
125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
239000011256 inorganic filler Substances 0.000 description 5
229910003475 inorganic filler Inorganic materials 0.000 description 5
NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 5
239000000347 magnesium hydroxide Substances 0.000 description 5
229910001862 magnesium hydroxide Inorganic materials 0.000 description 5
NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 5
125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 5
CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 5
239000003208 petroleum Substances 0.000 description 5
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238000002360 preparation method Methods 0.000 description 5
239000001062 red colorant Substances 0.000 description 5
239000007921 spray Substances 0.000 description 5
150000003553 thiiranes Chemical class 0.000 description 5
239000010936 titanium Substances 0.000 description 5
229910052719 titanium Inorganic materials 0.000 description 5
WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
239000005058 Isophorone diisocyanate Substances 0.000 description 4
239000004721 Polyphenylene oxide Substances 0.000 description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 4
238000010521 absorption reaction Methods 0.000 description 4
125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 4
230000001476 alcoholic effect Effects 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
125000002947 alkylene group Chemical group 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
229920003180 amino resin Polymers 0.000 description 4
230000003078 antioxidant effect Effects 0.000 description 4
ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical class C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
239000000038 blue colorant Substances 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
238000001723 curing Methods 0.000 description 4
125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 4
UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical class OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 4
239000004744 fabric Substances 0.000 description 4
230000002349 favourable effect Effects 0.000 description 4
125000000524 functional group Chemical group 0.000 description 4
238000009413 insulation Methods 0.000 description 4
229910052742 iron Inorganic materials 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
150000002513 isocyanates Chemical class 0.000 description 4
230000031700 light absorption Effects 0.000 description 4
238000005259 measurement Methods 0.000 description 4
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine powder Natural products NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 4
150000002978 peroxides Chemical class 0.000 description 4
229950000688 phenothiazine Drugs 0.000 description 4
150000003014 phosphoric acid esters Chemical class 0.000 description 4
239000004417 polycarbonate Substances 0.000 description 4
229920000515 polycarbonate Polymers 0.000 description 4
229920000570 polyether Polymers 0.000 description 4
229920002635 polyurethane Polymers 0.000 description 4
239000004814 polyurethane Substances 0.000 description 4
WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 4
239000000243 solution Substances 0.000 description 4
150000005846 sugar alcohols Polymers 0.000 description 4
238000012719 thermal polymerization Methods 0.000 description 4
239000006097 ultraviolet radiation absorber Substances 0.000 description 4
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical class C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 3
GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 3
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Natural products CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 3
239000004925 Acrylic resin Substances 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
239000004952 Polyamide Substances 0.000 description 3
239000004698 Polyethylene Substances 0.000 description 3
239000004642 Polyimide Substances 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
UMHKOAYRTRADAT-UHFFFAOYSA-N [hydroxy(octoxy)phosphoryl] octyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OP(O)(=O)OCCCCCCCC UMHKOAYRTRADAT-UHFFFAOYSA-N 0.000 description 3
BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 3
239000002318 adhesion promoter Substances 0.000 description 3
125000003282 alkyl amino group Chemical group 0.000 description 3
150000008641 benzimidazolones Chemical class 0.000 description 3
150000008366 benzophenones Chemical class 0.000 description 3
IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 3
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
230000008859 change Effects 0.000 description 3
229910052804 chromium Inorganic materials 0.000 description 3
239000011889 copper foil Substances 0.000 description 3
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
125000005843 halogen group Chemical group 0.000 description 3
239000003112 inhibitor Substances 0.000 description 3
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
229910052748 manganese Inorganic materials 0.000 description 3
239000011572 manganese Substances 0.000 description 3
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
229910052753 mercury Inorganic materials 0.000 description 3
229910001510 metal chloride Inorganic materials 0.000 description 3
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 3
229910052759 nickel Inorganic materials 0.000 description 3
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
125000003566 oxetanyl group Chemical group 0.000 description 3
DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 3
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
150000002989 phenols Chemical class 0.000 description 3
229920006287 phenoxy resin Polymers 0.000 description 3
239000013034 phenoxy resin Substances 0.000 description 3
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