JP2014221509A - 結合研磨物品および形成方法 - Google Patents
結合研磨物品および形成方法 Download PDFInfo
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- JP2014221509A JP2014221509A JP2014146575A JP2014146575A JP2014221509A JP 2014221509 A JP2014221509 A JP 2014221509A JP 2014146575 A JP2014146575 A JP 2014146575A JP 2014146575 A JP2014146575 A JP 2014146575A JP 2014221509 A JP2014221509 A JP 2014221509A
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/04—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
- B24D3/06—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/009—Tools not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/04—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
- B24D3/06—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
- B24D3/10—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements for porous or cellular structure, e.g. for use with diamonds as abrasives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/04—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
- B24D3/14—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic ceramic, i.e. vitrified bondings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1409—Abrasive particles per se
Abstract
【解決手段】金属を含む結合剤中に含まれる砥粒を含む本体を含む研磨物品であって、前記本体は、VP/VBMの比が少なくとも1.5であり、ここでVPは、前記本体の全体積中の砥粒およびフィラーを含む粒子状材料の体積パーセントであり、VBMは、前記本体の全体積中の結合剤の体積パーセントであり、結合剤平均破壊靱性(K1c)が4.0MPa・m0.5以下である。
【選択図】図1
Description
に関する説明を含んでいる。
最初の結合研磨材サンプルでは、当産業において知られている1A1形状を有する直径4インチのホイールを作製する。サンプルの形成は、27 Philo Curtis Road,Sandy Hook,CT 06482,USAに所在するConnecticut Engineering Associate Corporationより入手したU.S.メッシュ325の大きさの45.96グラムの真鍮粉末(すなわち、銅:スズの重量比が60:40)を含む混合物を形成するステップを含む。この真鍮粉末を、Chemetall Chemical Products,New Providence New Jersey,USAより購入した同じ大きさの5.11グラムの水素化チタンと乾式ブレンドする。USメッシュサイズ−120/+140の立方晶窒化ホウ素の砥粒も真鍮粉末および水素化チタンと混合する。この砥粒は、Saint−Gobain Ceramics and Plastics,Worcester,MAのものであり、CBN−Vとして市販されている。
本明細書に記載のサンプル1と同じ方法を使用してサンプル2を作製する。サンプル2は、砥粒材料の25%を置換する量の溶融石英フィラー材料を含んだ。この溶融石英は、U.S.メッシュ−120/+140の大きさであり、Washington Millsより入手した。最終的に形成された結合研磨材は、比(VP/VBM)が2.3であり、気孔(100%相互接続された気孔)の量が本体の全体積の29%体積パーセントである。
サンプル1と同じ形成方法を使用して第3のサンプル(サンプル3)を作製した。最初の混合物は、372グラムの60/40銅/スズの金属結合組成物、41グラムの水素化チタンの活性結合組成物前駆体、359グラムのサイズB181のCBN−Vの砥粒、サイズ100メッシュの38AアルミナとしてSaint−Gobain Grains and Powdersより入手可能な131グラムのフィラー、および58グラムの実施例1で使用したバインダーを使用して形成される。サンプル3は、比(VP/VBM)が2.5であり、気孔率は約29体積%である。
実施例1に記載の方法に従って第4のサンプル(サンプル4)を作製する。最初の混合物は、138グラムの60/40の銅−スズの金属結合組成物、活性結合成分前駆体としての15グラムの水素化チタン、20グラムの実施例1の有機バインダー、およびSaint−Gobain Ceramics and PlasticsよりRB 270/325 U.S.メッシュのダイヤモンドグリットとして入手可能な164グラムのダイヤモンドから形成される。サンプル4は、比(VAG/VBM)が2.3であり、気孔率は約36体積%である。
6%のコバルトを有する直径0.5インチの炭化タングステンの工作物に対するフルート研削に、サンプル4およびサンプルC2を使用する。この種の被削材は、プロット701および702の間の差で示されるように、炭化タングステン含有量が多い(94%対90%)ために実施例4の項作物よりも研削が困難である。プロット701は、10%のコバルトバインダーを有する炭化タングステンの工作物に対する、3000rpmおよび6インチ/分の研削速度で800秒の研削時間でのサンプルC2の研削動力を表している。実際、プロット701は図6のプロット601と同じである。プロット702は、6%のコバルトバインダーを有する炭化タングステンの工作物に対する、3000rpmおよび6インチ/分の研削速度で800秒の研削時間でのサンプルC2の研削動力を表している。図示されるように、サンプルC2の場合、10%のコバルトを有する工作物の研削に必要な動力は、わずか6%のコバルトを有する炭化タングステンでできた工作物の研削に必要な動力よりもはるかに少ない。
Claims (15)
- 金属を含む結合剤中に含まれる砥粒を含む本体を含む研磨物品であって、前記本体は、VP/VBMの比が少なくとも1.5であり、ここでVPは、前記本体の全体積中の砥粒およびフィラーを含む粒子状材料の体積パーセントであり、VBMは、前記本体の全体積中の結合剤の体積パーセントであり、結合剤平均破壊靱性(K1c)が4.0MPa・m0.5以下である、研磨物品。
- 前記結合剤平均破壊靱性(K1c)が、0.6〜4.0MPa・m0.5の間の範囲内である、請求項1に記載の研磨物品。
- 前記結合剤平均破壊靱性(K1c)が、0.6〜3.0MPa・m0.5の間の範囲内である、請求項2に記載の研磨物品。
- 前記VP/VBMの比が、1.5〜9.0の間の範囲内である、請求項1に記載の研磨物品。
- 前記VP/VBMの比が、1.7〜6.0の間の範囲内である、請求項4に記載の研磨物品。
- VAG/VBMの比が少なくとも1.3であり、ここでVAGは、前記本体の全体積中の前記砥粒の体積パーセントであり、VBMは、前記本体の全体積中の前記結合剤の体積パーセントである、請求項1に記載の研磨物品。
- 前記VAG/VBMの比が、1.3〜9.0の間の範囲内である、請求項6に記載の研磨物品。
- 前記結合剤が、前記結合剤の全体積の少なくとも1体積%の活性結合組成物を含む、請求項1に記載の研磨物品。
- 前記活性結合組成物が、前記結合剤の全体積の1体積%〜40体積%の間の範囲内の量で存在する、請求項8に記載の研磨物品。
- 前記活性結合組成物が、金属を含む化合物を含む、請求項8に記載の研磨物品。
- 前記活性結合組成物が、炭化物、窒化物、酸化物、およびそれらの組み合わせからなる群から選択される化合物を含む、請求項8に記載の研磨物品。
- 前記活性結合組成物が、チタン、バナジウム、クロム、ジルコニウム、ハフニウム、タングステン、およびそれらの組み合わせからなる金属元素の群から選択される金属元素を含む、請求項10に記載の研磨物品。
- 前記本体が、少なくとも5体積%の気孔を含み、前記気孔の過半量が、前記本体の前記体積を通過して延在する相互接続された孔隙の網目構造を画定する相互接続された気孔である、請求項1に記載の研磨物品。
- 前記結合剤が少なくとも1種類の遷移金属元素を含む、請求項1に記載の研磨物品。
- 前記結合剤が、銅、スズ、銀、モリブデン、亜鉛、タングステン、鉄、ニッケル、アンチモン、およびそれらの組み合わせからなる金属の群から選択される金属を含む、請求項14に記載の研磨物品。
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