JP2003502718A5 - - Google Patents

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Publication number
JP2003502718A5
JP2003502718A5 JP2001505576A JP2001505576A JP2003502718A5 JP 2003502718 A5 JP2003502718 A5 JP 2003502718A5 JP 2001505576 A JP2001505576 A JP 2001505576A JP 2001505576 A JP2001505576 A JP 2001505576A JP 2003502718 A5 JP2003502718 A5 JP 2003502718A5
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Japan
Prior art keywords
composition
photopolymerizable
functionality
perfluorinated
group
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JP2001505576A
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JP2003502718A (ja
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Priority claimed from US09/337,337 external-priority patent/US6306563B1/en
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Publication of JP2003502718A publication Critical patent/JP2003502718A/ja
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【請求項32】 光学素子を製造する方法において、
a) 光重合性組成物を支持体上に施して、光重合性組成物層を形成し、ここで、該光重合性組成物が、少なくとも1つの光重合性開始剤および少なくとも1つの光重合性基を有する少なくとも1つの光重合性モノマー、オリゴマー、またはポリマーを含み、該光重合性モノマー、オリゴマー、またはポリマーが、過フッ素化置換基を含む;
b) 該層を少なくともある程度硬化させ;
c) 反応性イオンエッチング、マイクロ複製、直接レーザ書込み、およびレーザアブレーションからなる群より選択される方法によりコアを形成し;
d) 該コア上に上側クラッド重合性組成物を施し;
e) 該上側クラッド組成物をある程度硬化させて、上側クラッドを形成する;
各工程を含むことを特徴とする方法。
【請求項43】 組成物において、
a) 第1の官能価を有する第1の光硬化性多官能価過フッ素化化合物;
b) 第2の官能価を有する第2の光硬化性多官能価過フッ素化化合物、ここで、該第2の官能価と前記第1の官能価との間の差は少なくとも1つであり、前記第1と第2の光硬化性多官能価過フッ素化化合物が、
【化10】
Figure 2003502718
ここで、xは1−10であり、mおよびnは、それぞれ、無作為に分布したペルフルオロエチレンオキシおよびペルフルオロメチレンオキシ主鎖反復副単位の数を表し、pは−CF(CF3)CF2O−主鎖反復副単位を表す、
からなる群より選択される過フッ素化置換基を含み、;および
c)重合開始剤;
を含むことを特徴とする組成物。
JP2001505576A 1999-06-21 2000-06-21 放射線硬化性フッ素化組成物から作製された光デバイス Pending JP2003502718A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/337,337 US6306563B1 (en) 1999-06-21 1999-06-21 Optical devices made from radiation curable fluorinated compositions
US09/337,337 1999-06-21
PCT/US2000/016997 WO2000078819A1 (en) 1999-06-21 2000-06-21 Optical devices made from radiation curable fluorinated compositions

Publications (2)

Publication Number Publication Date
JP2003502718A JP2003502718A (ja) 2003-01-21
JP2003502718A5 true JP2003502718A5 (ja) 2007-08-02

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JP2001505576A Pending JP2003502718A (ja) 1999-06-21 2000-06-21 放射線硬化性フッ素化組成物から作製された光デバイス

Country Status (11)

Country Link
US (2) US6306563B1 (ja)
EP (2) EP1203031B1 (ja)
JP (1) JP2003502718A (ja)
KR (1) KR100679383B1 (ja)
CN (2) CN1721880A (ja)
AU (1) AU5627900A (ja)
BR (1) BR0011774A (ja)
CA (1) CA2374374A1 (ja)
DE (1) DE60036872T2 (ja)
MX (1) MXPA02000070A (ja)
WO (1) WO2000078819A1 (ja)

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