DK2817148T3 - Metal-harpiks-kompositmateriale og fremgangsmåde til fremstilling heraf - Google Patents
Metal-harpiks-kompositmateriale og fremgangsmåde til fremstilling heraf Download PDFInfo
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- DK2817148T3 DK2817148T3 DK12869137.5T DK12869137T DK2817148T3 DK 2817148 T3 DK2817148 T3 DK 2817148T3 DK 12869137 T DK12869137 T DK 12869137T DK 2817148 T3 DK2817148 T3 DK 2817148T3
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14311—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using means for bonding the coating to the articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
- B29C45/14811—Multilayered articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/286—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysulphones; polysulfides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
- B29C45/14795—Porous or permeable material, e.g. foam
- B29C2045/14803—Porous or permeable material, e.g. foam the injected material entering minute pores
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249955—Void-containing component partially impregnated with adjacent component
- Y10T428/249956—Void-containing component is inorganic
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Claims (15)
- METAL-HARPIKS-KOMPOSITMATERIALE OG FREMGANGSMÅDE TIL FREMSTILLING HERAF1. Fremgangsmåde til fremstilling af et kompositmateriale af et metal og en harpiks, hvilken fremgangsmåde omfatter følgende trin: A) dannelse af nanoporer i mindst en del af overfladen af et formet metal; og B) sprøjtestøbning af en termoplastisk harpiks direkte på overfladen af det formede metal, hvor den termoplastiske harpiks indbefatter en hovedharpiks og en polyolefinharpiks, hovedharpiksen indbefatter en blanding af polyphenylenether og polyphenylensulfid, og polyolefinharpiksen har et smeltepunkt på ca. 65 °C til ca. 105 °C.
- 2. Fremgangsmåde ifølge krav 1, hvor dannelse af nanoporer i trin A) omfatter følgende trin: anodisering af mindst en del af overfladen af det formede metal til dannelse af et oxidlag med nanoporerne derpå.
- 3. Fremgangsmåde ifølge krav 2, hvor oxidlaget har en tykkelse på ca. 1 pm til ca. 10 pm, og nanoporerne har en gennemsnitlig porestørrelse på ca. 10 nm til ca. 100 nm og en gennemsnitlig dybde på ca. 0,5 pm til ca. 9,5 pm.
- 4. Fremgangsmåde ifølge krav 2 eller 3, hvor anodiseringen omfatter: placering af det formede metal som en anode i en H2S04-opløsning med en koncentration på ca. 10 vægtprocent til ca. 30 vægtprocent; og elektrolyse af det formede metal ved en temperatur på ca. 10 °C til ca. 30 °C ved en spænding på ca. 10 V til ca. 100 V i ca. 1 min. til ca. 40 min. til dannelse af oxidlaget med en tykkelse på ca. 1 pm til ca. 10 pm på mindst en del af overfladen af det formede metal.
- 5. Fremgangsmåde ifølge krav 2 til 4, hvor dannelse af nanoporer i trin A) yderligere omfatter følgende trin: nedsænkning af det formede metal med oxidlaget på overfladen deraf i en ætsningsopløsning til dannelse af korrosionsporer i en ydre overflade af oxidlaget.
- 6. Fremgangsmåde ifølge krav 5, hvor korrosionsporerne bringes i forbindelse med nanoporerne, og korrosionsporerne har porestørrelser på ca. 200 nm til ca. 2000 nm og dybder på ca. 0,5 pm til ca. 9,5 pm.
- 7. Fremgangsmåde ifølge krav 5 eller 6, hvor ætsningsopløsningen indbefatter en opløsning, som korroderer oxidlaget.
- 8. Fremgangsmåde ifølge et af de foregående krav, hvor mængden af hovedharpiksen baseret på 100 vægtdele af den termoplastiske harpiks er ca. 70 vægtdele til ca. 95 vægtdele, og mængden af polyolefinharpiksen er ca. 5 vægtdele til ca. 30 vægtdele.
- 9. Fremgangsmåde ifølge et af de foregående krav, hvor den termoplastiske harpiks yderligere indbefatteret strømningsforbedringsmiddel, og mængden af strømningsforbedringsmidlet baseret på 100 vægtdele af den termoplastiske harpiks er ca. 1 vægtdel til ca. 5 vægtdele, og hvor strømningsforbedringsmidlet indbefatter en cyklisk polyester.
- 10. Fremgangsmåde ifølge et af de foregående krav, hvor den termoplastiske harpiks yderligere indbefatter en glasfiber, og mængden af glasfiberen baseret på 100 vægtdele af den termoplastiske harpiks er ca. 1 vægtdel til ca. 30 vægtdele.
- 11. Fremgangsmåde ifølge et af de foregående krav, hvor vægtforholdet mellem polyphenylenetherog polyphenylensulfid i hovedharpiksen erca. 3:1 til ca. 1:3.
- 12. Fremgangsmåde ifølge et af de foregående krav, hvor polyolefinharpiksen indbefatter en podet polyethylen.
- 13. Fremgangsmåde ifølge et af de foregående krav, hvor det formede metal fremstilles ud fra mindst én, der er valgt fra gruppen bestående af aluminium, rustfrit stål og magnesium.
- 14. Metal-harpiks-kompositmateriale, der omfatter: en formet metaldel med nanoporer i mindst en del af overfladen deraf; en plastdel fremstillet af en termoplastisk harpiks, som er sprøjtestøbt på overfladen af den formede metaldel; hvor den termoplastiske harpiks indbefatter en hovedharpiks og en polyolefinharpiks, hovedharpiksen indbefatter en blanding af polyphenylenether og polyphenylensulfid, og polyolefinharpiksen har et smeltepunkt på ca. 65 °C til ca. 105 °C.
- 15. Metal-harpiks-kompositmateriale ifølge krav 14, hvor der dannes et oxidlag mellem metaldelen og plastdelen; oxidlaget indeholder korrosionsporer i overfladen, som er i kontakt med plastdelen, og nanoporer i overfladen er i kontakt med den formede metaldel; nanoporerne har en gennemsnitlig porestørrelse på ca. 10 nm til ca. 100 nm og en gennemsnitlig dybde på ca. 0,5 pm til ca. 9,5 pm, og korrosionsporerne har en gennemsnitlig porestørrelse på ca. 200 nm til ca. 2000 nm og en gennemsnitlig dybde på ca. 0,5 pm til ca. 9,5 pm; en del af korrosionsporerne bringes i forbindelse med en del af nanoporerne; og en del af harpiksen fyldes i nanoporerne og korrosionsporerne.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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CN201210043637.XA CN103286908B (zh) | 2012-02-24 | 2012-02-24 | 一种金属树脂一体化成型方法和一种金属树脂复合体 |
PCT/CN2012/082025 WO2013123769A1 (en) | 2012-02-24 | 2012-09-26 | Metal-resin composite and method for producing the same |
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DK2817148T3 true DK2817148T3 (da) | 2017-10-23 |
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DK12869137.5T DK2817148T3 (da) | 2012-02-24 | 2012-09-26 | Metal-harpiks-kompositmateriale og fremgangsmåde til fremstilling heraf |
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US (1) | US9770884B2 (da) |
EP (1) | EP2817148B1 (da) |
JP (1) | JP6293062B2 (da) |
KR (2) | KR20160084497A (da) |
CN (1) | CN103286908B (da) |
DK (1) | DK2817148T3 (da) |
WO (1) | WO2013123769A1 (da) |
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CN103286910B (zh) | 2012-02-24 | 2015-09-30 | 比亚迪股份有限公司 | 一种金属树脂一体化成型方法和一种金属树脂复合体 |
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US9770884B2 (en) | 2017-09-26 |
CN103286908B (zh) | 2015-09-30 |
JP2015511190A (ja) | 2015-04-16 |
CN103286908A (zh) | 2013-09-11 |
KR20140125845A (ko) | 2014-10-29 |
KR101853164B1 (ko) | 2018-06-04 |
EP2817148A4 (en) | 2015-11-04 |
JP6293062B2 (ja) | 2018-03-14 |
US20140363657A1 (en) | 2014-12-11 |
EP2817148A1 (en) | 2014-12-31 |
EP2817148B1 (en) | 2017-07-12 |
KR20160084497A (ko) | 2016-07-13 |
WO2013123769A1 (en) | 2013-08-29 |
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