CN103458859A - 具有增强的聚丙烯酸酯微胶囊的沉积的个人清洁组合物 - Google Patents

具有增强的聚丙烯酸酯微胶囊的沉积的个人清洁组合物 Download PDF

Info

Publication number
CN103458859A
CN103458859A CN2012800160796A CN201280016079A CN103458859A CN 103458859 A CN103458859 A CN 103458859A CN 2012800160796 A CN2012800160796 A CN 2012800160796A CN 201280016079 A CN201280016079 A CN 201280016079A CN 103458859 A CN103458859 A CN 103458859A
Authority
CN
China
Prior art keywords
microcapsule
anion
cleaning compositions
personal cleaning
polyacrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012800160796A
Other languages
English (en)
Inventor
J·O·迪奥拉
M·A·布朗
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Ltd
Procter and Gamble Co
Original Assignee
Procter and Gamble Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Ltd filed Critical Procter and Gamble Ltd
Publication of CN103458859A publication Critical patent/CN103458859A/zh
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Abstract

本发明提供了一种个人清洁组合物，其增强了包含聚丙烯酸酯微胶囊的有益剂到毛发和/或皮肤上的沉积和保留。所述个人清洁组合物是基于阴离子带电聚丙烯酸酯微胶囊、阳离子沉积聚合物、去污表面活性剂和载体的组合的。

Description

具有增强的聚丙烯酸酯微胶囊的沉积的个人清洁组合物
技术领域
本发明涉及包含聚丙烯酸酯微胶囊的个人清洁组合物，其中所述聚丙烯酸酯微胶囊到毛发和/或皮肤上具有增强的沉积。
背景技术
当前市场上的许多个人清洁产品通过将有益剂如香料、保湿剂和护肤剂沉积到所期望部位上而用于向毛发和/或皮肤递送有益效果。因此，期望通过增强它们的递送和保留来使此类有益剂的效果最大化。达到此目的的一种方法是将此类有益剂包封于微胶囊中。虽然这些微胶囊能够包封多种有益剂并且将它们递送至所期望部位，但是仍难以改善此类有益剂的保留和递送效率。此类试剂可能由于试剂的物理或化学特性而损失，或者此类试剂可能与其它组合物组分或待处理的部位不相容。当前消费者期望即使在延长的一段时间后仍将包封有益剂沉积并且保留到毛发和/或皮肤上的个人清洁组合物。
一种用于改善处理期间微胶囊到部位上的沉积的已知方法涉及使用某些阳离子沉积聚合物。然而，这本身不一定确保微胶囊的充分沉积。
因此，需要一种提供包封有益剂增强的沉积的个人清洁组合物。此外，需要一种与微胶囊表面缔合，并且当剪切时允许包封待释放的有益剂的聚合物体系。此外，需要一种在延伸的一段时间内提供包封有益剂到部位上增强的保留的个人清洁组合物。
发明内容
一种个人清洁组合物，所述组合物包含：约0.001%至约10%的阴离子带电聚丙烯酸酯微胶囊；约0.01%至约2%的阳离子沉积聚合物；约2%至约50%的去污表面活性剂；和载体。
一种制备个人清洁组合物的方法，其中所述组合物由包括以下步骤的方法形成：用阴离子乳化剂涂覆聚丙烯酸酯微胶囊以形成阴离子聚丙烯酸酯微胶囊；将阴离子聚丙烯酸酯微胶囊与阳离子沉积聚合物混合以形成预混物；将所述预混物加入包含表面活性剂和载体的去污组合物中。
一种制备个人清洁组合物的方法，其中所述组合物由包括以下步骤的方法形成：用阴离子乳化剂涂覆聚丙烯酸酯微胶囊以形成阴离子聚丙烯酸酯微胶囊；将阴离子聚丙烯酸酯微胶囊与阳离子沉积聚合物混合以形成预混物；将所述预混物加入阴离子表面活性剂中；将步骤（c）的所得组合物加入包含表面活性剂和载体的去污组合物中。
具体实施方式
在本发明的所有实施例中，除非另外特别说明，所有百分比均按所述总组合物的重量计。除非另外特别说明，所有比率均为重量比。所有范围是包括端值在内的且可合并的。有效数字的数目既不表示对所指示量的限制，也不表示对测量精确性的限制。除非另外特别说明，所有数值应被理解为可被词“约”修饰。除非另外指明，所有测量均被理解为是在25℃和环境条件下进行的，其中“环境条件”是指在约一大气压和约50%相对湿度下的条件。除非另外指明，所有此类与所列成分相关的重量均以活性物质的含量计，并且不包括可能包含在市售材料中的载体或副产物。
定义
如本文所用，除非另外指明，术语“个人清洁组合物”包括任何可被施用到身体的角蛋白表面的个人清洁组合物，包括皮肤和/或毛发。个人清洁组合物可例如被配制为清洁条、液体、乳液、淋浴凝胶、粉末、棒剂、糊剂、漱口水、泡沫浴、剃刮准备产品、以及用于剃刮的装置。
如本文所用，术语“流体”包括液体和凝胶。
如本文所用，术语“微胶囊”、“包封有益剂”和“固体颗粒”是指聚丙烯酸酯微胶囊。
如本文所用，术语“预混物”是指阴离子聚丙烯酸酯微胶囊与阳离子沉积聚合物的组合。
如本文所用，术语“部位”包括毛发和皮肤。
如本文所用，当用于权利要求中时，包括“一个”和“一种”的冠词被理解为是指一种或多种受权利要求书保护的或所述的物质。
如本文所用，术语“包括”和“包含”是指非限制性的。
在本专利申请测试方法部分中公开的测试方法应被用来确定申请人发明参数的相应值。
除非另外指明，所有组分或组合物含量均是关于该组分或组合物的活性物质部分，并且不包括可能存在于这些组分或组合物的市售来源中的杂质，例如残余溶剂或副产物。
除非另外指明，所有百分比和比率均按重量计来计算。除非另外指明，所有百分比和比率均以总组合物计来计算。
应当理解，在整个说明书中给出的每一最大数值限度包括每一更低的数值限度，如同该更低数值限度在本文中被明确地写出。在本说明书全文中给出的每一最小数值限度将包括每一更高数值限度，如同该更高数值限度在本文中被明确地写出。在本说明书全文中给出的每一数值范围将包括落入此类更宽数值范围内的每一更窄数值范围，如同此类更窄数值范围在本文中被明确地写出。
阴离子聚丙烯酸酯微胶囊的有益效果
消费者期望在清洁过程期间将包封有益剂沉积并且保留到他们毛发和/或皮肤上的个人清洁组合物。传统上，已经使用多种方法来改善微胶囊的沉积，包括（1）使用特定的嵌段共聚物共价结合到微胶囊，以及（2）使用阳离子水溶性聚合物涂覆微胶囊以增加所述微胶囊对所关注基质的亲和力。然而，期望具有优于传统方法的改善的沉积。
已令人惊奇地发现，阴离子乳化剂与聚丙烯酸酯微胶囊之间存在协同作用，从而获得阴离子聚丙烯酸酯微胶囊。当将此类阴离子微胶囊与阳离子沉积聚合物混合时，在阴离子聚丙烯酸酯表面处形成微观结构。此类阴离子微观结构显示出高粘弹性，即使在清洁期间稀释时仍保持完整，并且显示出与角蛋白毛发和/或皮肤表面的强粘附力。与清洁组合物组合，这些性能获得改善的包封有益剂至毛发和/或皮肤的递送效率。
据信，包含阴离子聚丙烯酸酯微胶囊的个人清洁组合物连同特定的阳离子沉积聚合物递送比包含非阴离子聚丙烯酸酯的个人清洁组合物更高的沉积速率。此外，具有特定阳离子沉积聚合物的阴离子聚丙烯酸酯微胶囊还具有在部位上甚至延长的一段时间内的较高保留率。申请人惊奇地发现，可通过如下来实现将阴离子乳化剂加入微胶囊中以形成阴离子微胶囊：或（1）将阴离子乳化剂加入已经形成的微胶囊中，或（2）在微胶囊制备过程期间使阴离子乳化剂与微胶囊表面缔合。一旦形成，就使阴离子聚丙烯酸酯微胶囊与所选的一种或多种特定阳离子聚合物混合以形成预混物，以加入包含阴离子表面活性剂的个人清洁组合物中。
阴离子乳化剂
加入阴离子乳化剂，在微胶囊外表面处与特定阳离子沉积聚合物形成微观结构，即阴离子乳化剂是微胶囊外表面的至少一部分，或物理地或化学地结合到微胶囊的外表面。此类物理结合包括例如氢键、离子相互作用、疏水性相互作用、和电子转移相互作用。此类化学结合包括例如共价键合如共价接枝和交联。
阴离子乳化剂以按所述聚丙烯酸酯微胶囊的重量计约0.1重量%至约40重量%，约0.5重量%至约10重量%，或约0.5重量%至约5重量%的含量存在。
如下所述，可在本发明个人清洁组合物中使用多种阴离子乳化剂。阴离子乳化剂示例并且非限制性地包括以下的水溶性盐：烷基硫酸盐、烷基醚硫酸盐、烷基异硫代硫酸盐、烷基羧酸盐、琥珀酸烷基酯磺酸盐、烷基琥珀酰胺酸盐、烷基硫酸盐（如十二烷基硫酸钠、烷基肌氨酸盐）、蛋白质水解产物的烷基衍生物、酰基天冬氨酸盐、烷基或烷基醚或烷基芳基醚磷酸酯、十二烷基硫酸钠、磷脂或卵磷脂、或皂、硬脂酸钠、硬脂酸钾或硬脂酸铵、油酸盐或棕榈酸盐、烷基芳基磺酸盐（如十二烷基苯磺酸钠）、磺基琥珀酸二烷基酯钠、二辛基磺基琥珀酸盐、磺基琥珀酸二月桂基酯钠、聚(苯乙烯磺酸)钠盐、异丁烯-马来酸酐共聚物、阿拉伯树胶、藻酸钠、羧甲基纤维素、纤维素硫酸盐和果胶、聚(苯乙烯磺酸盐)、异丁烯-马来酸酐共聚物、阿拉伯树胶、角叉菜胶、藻酸钠、果胶酸、黄蓍胶、杏仁胶和琼脂；半合成聚合物如羧甲基纤维素、硫酸化纤维素、硫酸化甲基纤维素、羧甲基淀粉、磷酸盐化淀粉、木质素磺酸；和合成聚合物如马来酸酐共聚物（包括其水解产物）、聚丙烯酸、聚甲基丙烯酸、丙烯酸-丙烯酸丁酯共聚物或巴豆酸均聚物和共聚物、乙烯基苯磺酸或2-丙烯酰胺-2-甲基丙磺酸均聚物和共聚物、以及此类聚合物和共聚物的部分酰胺或部分酯、羧基改性的聚乙烯醇、磺酸改性的聚乙烯醇和磷酸-改性的聚乙烯醇、磷酸化的或硫酸化的三苯乙烯基苯酚乙氧基化物。
此外，还期望使用具有丙烯酸根官能团的阴离子乳化剂，因为这些可在微胶囊制备过程期间共价连接到聚丙烯酸酯微胶囊的外壳部分。用于本文的阴离子乳化剂包括但不限于：聚(甲基)丙烯酸；(甲基)丙烯酸和其具有C1-22烷基、C1-C8烷基、丁基的(甲基)丙烯酸酯的共聚物；(甲基)丙烯酸和(甲基)丙烯酰胺的共聚物；羧基乙烯基聚合物；丙烯酸酯共聚物如丙烯酸酯/丙烯酸C10-30烷基酯交联聚合物、丙烯酸/乙烯基酯共聚物/丙烯酸酯/异癸酸乙烯酯交联聚合物、丙烯酸酯/棕榈基聚氧乙烯醚-25丙烯酸酯共聚物、丙烯酸酯/硬脂基聚氧乙烯醚-20衣康酸酯共聚物、和丙烯酸酯/鲸蜡基聚氧乙烯醚-20衣康酸酯共聚物；聚苯乙烯磺酸酯、甲基丙烯酸和丙烯酰胺甲基丙磺酸的共聚物、以及丙烯酸和丙烯酰胺甲基丙磺酸的共聚物；羧甲基纤维素；羧基瓜尔胶；乙烯和马来酸的共聚物；以及丙烯酸酯硅氧烷聚合物。可包含中和剂以中和本文的阴离子乳化剂。此类中和剂的非限制性例子包括氢氧化钠、氢氧化钾、氢氧化铵、单乙醇胺、二乙醇胺、三乙醇胺、二异丙醇胺、氨基甲基丙醇、氨基丁三醇、四羟基丙基乙二胺、以及它们的混合物。可商购获得的阴离子乳化剂包括例如以商品名Carbopol 981和Carbopol 980由Noveon提供的卡波姆；具有商品名Pemulen TR-1、Pemulen TR-2、Carbopol1342、Carbopol1382和Carbopol ETD2020均购自Noveon的丙烯酸酯/丙烯酸C10-30烷基酯交联聚合物；以CMC系列由Hercules提供的羧甲基纤维素钠；以及具有商品名Capigel由Seppic提供的丙烯酸酯共聚物。在另一个实施例中，阴离子乳化剂为羧甲基纤维素。
聚丙烯酸酯微胶囊
用于微胶囊化的各种方法以及示例性方法和材料示于美国专利6,592,990；美国专利2,730,456；美国专利2,800,457；美国专利2,800,458；和美国专利4,552,811中。整个本专利申请中每个所述的专利以引用方式并入本文至每个提供关于微胶囊化的方法和材料指导的程度。
本发明提出了包含芯材料和壁材料的低渗透性微胶囊，所述壁材料至少部分地包围芯材料，并且在一个实施例中完全包围芯材料。在本发明中，聚丙烯酸酯微胶囊为有益剂微胶囊颗粒，其通过包含聚合物的胶囊壁材料来包封有益剂。
用于本文的胶囊壁材料包括例如由三聚氰胺-甲醛或脲醛缩合物、三聚氰胺-间苯二酚或脲-间苯二酚缩合物形成的那些，以及类似类型的氨基塑料、明胶、聚氨酯、聚酰胺、聚烯烃、多糖、蛋白质、硅氧烷、脂质、改性纤维素、树胶、聚丙烯酸酯、聚磷酸酯、聚苯乙烯和聚酯、或这些材料的组合。在另一个实施例中，提供低渗透性的壁材料为聚丙烯酸酯。
芯中的有益剂可包括选自以下的材料：香料；增白剂；酶；香料；护肤剂、调理剂、保湿剂、增稠剂；抗微生物剂；感觉剂，在一个方面凉爽剂；诱虫剂，在一个方面信息素；抗菌剂；染料；颜料；漂白剂；以及它们的混合物。
本发明可包含一种或多种抗真菌或抗微生物活性物质。当存在时，抗微生物条皂组合物可包含按所述个人清洁组合物的重量计约0.001%至约5%，在另一个实施例中约0.01%至约1.5%，并且在另一个实施例中约0.1%至约1%的抗菌剂。可用于本文的抗微生物剂的例子包括巯基吡啶氧化物或巯基吡啶氧化物的多价金属盐如1-羟基-2-吡啶硫酮锌盐（被称为“1-氧-2-巯基吡啶锌”或“ZPT”）、N-碳酰苯胺例如三氯卡班（还被称为三氯碳酰苯胺）、三氯生、以DP-300得自Ciba-Geigy的卤代的卤代二苯醚、六氯酚、3,4,5-三溴水杨酰苯胺、以及2-吡啶硫醇-1-氧化物、水杨酸和其它有机酸的盐。其它合适的抗微生物剂详细描述于US6,488,943中（被称为抗微生物活性物质）。
用于本文的聚丙烯酸酯微胶囊为初始施用后在一段时间内释放有益剂的那些。释放包封有益剂的可能触发机构可包括但不限于机械力、脱水、光、pH、温度、或甚至离子强度变化。
制备阴离子聚丙烯酸酯微胶囊的方法
阴离子聚丙烯酸酯微胶囊可通过如下形成：（1）用阴离子乳化剂涂覆已经形成的微胶囊；或（2）在微胶囊制备过程期间将阴离子乳化剂加入微胶囊中。产生微胶囊的任何已知方法可用于本文中。制备聚丙烯酸酯微胶囊的示例方法公开于美国专利申请61/328949；美国专利申请61/328954；美国专利申请61/328962；和美国专利申请61/328967中。
在一个实施例中，聚丙烯酸酯微胶囊由油包水或水包油乳化作用形成。在聚丙烯酸酯微胶囊制备过程期间，制备第一组合物作为油相。所述油相可包含油；油溶性或分散性伯胺、仲胺或叔胺；多官能丙烯酸酯或甲基丙烯酸酯单体或低聚物；油溶性酸；引发剂、以及它们的组合。在一个实施例中，使用氮封，同时混合溶液。逐渐升高温度以形成第一组合物反应产物。在形成第一组合物反应产物后，将第二组合物加入该反应产物中。
制备第二组合物作为水相。水相可包含水；可为水溶性或水分散性聚合物或共聚物的乳化剂；至少一种水相引发剂；一种或多种碱或碱盐、以及它们的组合。所谓水相引发剂是指引发剂在水中是可溶解的或可分散的。
然后将第二组合物加入第一组合物反应产物的油溶液中。该加入形成水包油乳液。在第二组合物的存在下，第一组合物的反应导致形成低渗透性微胶囊壁。将所述乳液进一步加热一段时间，并且温度足以分解存在于油相和水相之一或二者中的自由基。
此外，油相中单体和低聚物的聚合致使聚合材料沉淀。在水相和油相的界面处形成微胶囊壁材料的沉淀。
阴离子聚丙烯酸酯微胶囊以约0.01重量%至约50重量%，约0.05重量%至约10重量%，约0.1重量%至约8重量%，或约0.25重量%至3重量%的含量包含在所述组合物中。
用于本文的阴离子聚丙烯酸酯微胶囊是具有约1微米至约80微米，约2微米至约50微米，和约5微米至约30微米粒度的那些。
A.涂覆微胶囊
在本发明的一个实施例中，将阴离子乳化剂加入已经形成的聚丙烯酸酯微胶囊中。阴离子乳化剂通过氢键、范德华力、离子相互作用、疏水性相互作用、或化学反应附接到微胶囊的表面。在一个方面，阴离子乳化剂包围聚丙烯酸酯微胶囊的外表面的至少一部分，或物理地或化学地结合到聚丙烯酸酯微胶囊的外表面。
B.将阴离子乳化剂加入微胶囊中
在另一个实施例中，阴离子乳化剂在微胶囊制备过程期间与微胶囊表面缔合。当制备微胶囊时，在油乳化之前，将阴离子乳化剂溶于可任选包含自由基引发剂的水相中。然后将过量的水相加入油相中以形成水包油乳液。然后在足以分解自由基的温度下将所述乳液加热一段时间，所述自由基定位在油相和水相之一或二者中。因此微胶囊壁材料在水相和油相的界面处形成。在一个实施例中，当所述乳化剂包含丙烯酸酯部分时，所述乳化剂可化学地结合到界面壁材料。
C.形成预混物
一旦由任一形成步骤形成阴离子聚丙烯酸酯微胶囊，将所述阴离子聚丙烯酸酯微胶囊加入特定阳离子沉积聚合物中以形成预混物。已令人惊奇地发现，当与预混物中的阳离子沉积聚合物混合时，聚丙烯酸酯微胶囊上的阴离子电荷导致在微胶囊的外壳上形成微观结构。该预混物表现出，阴离子聚丙烯酸酯微胶囊对毛发和/或皮肤具有比无阴离子电荷和特定阳离子沉积聚合物的微胶囊更高的粘弹性，因此向部位提供有益效果。
浆液/附聚物
在一个实施例中，所述阴离子聚丙烯酸酯微胶囊包含在浆液中。所述浆液可与辅助成分混合以形成组合物，例如调理消费品。
在一个方面，所述浆液可包含一种或多种加工助剂，所述加工助剂选自水、聚集抑制材料如二价盐；颗粒悬浮聚合物如黄原胶、瓜尔胶和羧甲基纤维素。在另一个实施例中，所述加工助剂可选自两性表面活性剂如椰油酰氨基丙基甜菜碱（CAPB）、两性离子表面活性剂、阳离子溶胀性聚合物、胶乳颗粒如基于丙烯酸的酯Rheovis CDE、以及它们的混合物。
在一个方面，所述浆液可包含载体，所述载体选自极性溶剂，包括但不限于水、乙二醇、丙二醇、聚乙二醇、甘油；非极性溶剂，包括但不限于矿物油、香料原料、硅油、烃石蜡油、以及它们的混合物。
在另一个实施例中，所述阴离子聚丙烯酸酯微胶囊包含在具有第二材料的附聚物中。在一个方面，所述第二材料可包括选自以下的材料：二氧化硅、柠檬酸、碳酸钠、硫酸钠、氯化钠、以及基料如硅酸钠、改性纤维素、聚乙二醇、聚丙烯酸酯、聚丙烯酸、沸石以及它们的混合物。
阳离子沉积聚合物
本发明的个人清洁组合物包含当加入阴离子聚丙烯酸酯微胶囊中时形成预混物的阳离子沉积聚合物。本文可使用任何已知的天然或合成阳离子沉积聚合物。例子包括公开于美国专利6,649,155；美国专利申请12/103,902；美国专利公布2008/0206355；和美国专利公布2006/0099167A1中的那些聚合物。
为提供本发明的有益效果，阳离子沉积聚合物以约0.01%至约2%，在一个实施例中约1.5%至约1.9%，在另一个实施例中约1.8%至约2.0%的含量包含在所述组合物中。
阳离子沉积聚合物为水溶性聚合物，其具有约0.5毫当量/克至约12毫当量/克的电荷密度。用于所述组合物中的阳离子沉积聚合物具有约100,000道尔顿至约5,000,000道尔顿的分子量。所述阳离子沉积聚合物为低电荷密度阳离子聚合物。
在一个实施例中，所述阳离子沉积聚合物为合成阳离子沉积聚合物。可使用多种合成阳离子沉积聚合物，包括单烷基链和二烷基链阳离子表面活性剂。在一个实施例中，选择单烷基链阳离子表面活性剂，包括例如单烷基季铵盐和单烷基胺。在另一个实施例中，使用二烷基链阳离子表面活性剂，并且包括例如二烷基（14-18）二甲基氯化铵、二牛脂烷基二甲基氯化铵、二氢化牛脂烷基二甲基氯化铵、二硬脂基二甲基氯化铵、双十六烷基二甲基氯化铵、以及它们的混合物。
在另一个实施例中，所述阳离子沉积聚合物为天然源阳离子聚合物。如本文所用，术语“天然源阳离子聚合物”是指获自天然源的阳离子沉积聚合物。所述天然源可为多糖聚合物。因此，天然源阳离子聚合物可选自包括以下的组：淀粉、瓜尔胶、纤维素、桂皮、刺槐豆胶、魔芋、塔拉胶、半乳甘露聚糖、木薯和合成聚合物。在另一个实施例中，阳离子沉积聚合物选自Mirapol100S（Rhodia）、Jaguar C17、polyDADMAC、Tapiocastarch（Akzo）、polyTriquat、以及它们的混合物。
形成预混物
在加入包含去污表面活性剂和载体的个人清洁组合物中之前，将阳离子沉积聚合物和阴离子聚丙烯酸酯微胶囊混合以形成预混物。
阴离子聚丙烯酸酯微胶囊与阳离子沉积聚合物的重量比（以阴离子微胶囊的干重和阳离子沉积聚合物的干重计）为约0.5:30至约20:1，约5:15至约15:1，和约5:1至约12:1。据信过多的阳离子聚合物因在胶囊壁上形成过多阳离子聚合物涂层而不向有益剂微胶囊提供增强和/或长效的有益效果。该过多的涂层可阻止微胶囊壁破裂并且释放有益剂。
微胶囊和阴离子乳化剂可分散在溶剂如水中，同时与阳离子沉积聚合物混合。在一个实施例中，水的含量为约90%至约50%，在另一个实施例中为约70%至约50%，并且在另一个实施例中为约60%至约50%。在本发明的一个实施例中，在阴离子乳化剂与阳离子沉积聚合物混合之前，它们与微胶囊缔合以形成阴离子聚丙烯酸酯微胶囊。
去污组合物
去污组合物可均为水相，或可包含油相和水相两者。在一个实施例中，去污组合物具有油相和水相两者。在加入去污组合物中后，聚丙烯酸酯微胶囊驻留在此类实施例的水相中。
去污组合物可包含以下组分的任何组合：
A.去污表面活性剂
本发明的个人清洁组合物包含去污表面活性剂。去污表面活性剂向组合物提供清洁性能。去污表面活性剂继而包括阴离子表面活性剂、非离子表面活性剂、阳离子表面活性剂、两性离子表面活性剂、两性表面活性剂、皂、或它们的组合。去污表面活性剂的各种例子和描述示于美国专利6,649,155；美国专利申请12/103,902；和美国专利公布2008/0206355中，并且以引用方式并入本文中。
阴离子表面活性剂组分在清洁组合物中的浓度应足以提供所期望的清洁和起泡性能，并且范围一般为约2%至约50%，约8%至约30%，约10%至约25%，或约12%至约22%。
例如，根据一个实施例，所述表面活性剂可包括一种或多种直链阴离子表面活性剂，如十二烷基硫酸铵、月桂基聚氧乙烯醚硫酸铵、月桂基硫酸钠、月桂基聚氧乙烯醚硫酸钠、月桂基聚氧乙烯醚硫酸钾、月桂基肌氨酸钠、月桂酰肌氨酸钠、肌氨酸月桂酯、椰油基肌氨酸、椰油基硫酸铵、月桂基硫酸钾，以及它们的组合。在一个实施例中，所述表面活性剂包括月桂基聚氧乙烯醚(n)硫酸钠（下文为SLEnS），其中n定义平均乙氧基化摩尔数。在另一个实施例中，n的范围为大于0至8，或约1至约3，或为大约1。应当理解，材料如SLEnS例如可包含显著量的分子，所述分子以一定分布不具有乙氧基化物、具有1摩尔乙氧基化物、2摩尔乙氧基化物、3摩尔乙氧基化物等，所述分布可以是广阔的、狭窄的或截短的。例如，SLE1S可包含显著量的分子，所述分子以一定分布不具有乙氧基化物、具有1摩尔乙氧基化物、3摩尔乙氧基化物等，所述分布可以是广阔的、狭窄的或截短的，并且仍包含其中平均分布为约1的SLE1S。
所述表面活性剂还可包括一种或多种支化阴离子表面活性剂和一甲基支化阴离子表面活性剂，如十三烷基聚氧乙烯醚硫酸钠、十三烷基硫酸钠、C12-13烷基硫酸钠、和C12-13棕榈基聚氧乙烯醚硫酸盐以及C12-13棕榈基聚氧乙烯醚-n硫酸钠。
用于本文个人清洁组合物中的适宜两性或两性离子去污表面活性剂包括已知用于个人护理清洁的那些。此类两性去污表面活性剂的浓度的范围为约0.5%至约20%，和约1%至约10%。合适的两性离子或两性表面活性剂的非限制性例子描述于美国专利5,104,646（Bolich Jr.等人）、5,106,609（Bolich Jr.等人）中。
适用于本文所述个人清洁组合物中的两性表面活性剂包括被广泛描述为脂族仲胺和叔胺的衍生物的那些，其中脂族基团可为直链或支链的，并且其中脂族取代基之一包含约8至约18个碳原子，并且一个包含阴离子水增溶性基团，例如羧基、磺酸根、硫酸根、磷酸根、或膦酸根。属于该定义的化合物的例子包括3-十二烷基氨基丙酸钠、3-十二烷基氨基丙烷磺酸钠、月桂基肌氨酸钠、N-烷基牛磺酸（如根据美国专利2,658,072中的教导由十二烷基胺与羟乙基磺酸钠反应而制得的那些）、N-高级烷基天冬氨酸（如根据美国专利2,438,091中的教导产生的那些），以及在美国专利2,528,378中描述的产物。在一个实施例中，包含在本文所述个人清洁组合物中的表面活性剂可包括两性表面活性剂，其选自月桂酰两性基乙酸钠、椰油酰两性基乙酸钠、月桂酰胺两性基乙酸二钠、椰油酰两性基乙酸二钠、以及它们的混合物。
适用于本文所述个人清洁组合物的表面活性剂中的两性离子表面活性剂包括被广泛描述为脂族季铵、
Figure BDA00003863831500121
和锍化合物的衍生物的那些，其中脂族基团可为直链或支链的，并且其中脂族取代基一直包含约8至约18个碳原子，并且一个脂族取代基包含阴离子基团，例如羧基、磺酸根、硫酸根、磷酸根、或膦酸根。在一个实施例中，包含在本文所述个人清洁组合物中的两性离子表面活性剂可包括一种或多种甜菜碱如椰油酰氨基丙基甜菜碱。
B.含水载体
本发明的制剂可为可倾倒液体的形式（在环境条件下）。因此，此类组合物通常包含含水载体，其以约20%至约95%，或甚至约60%至约85%的含量存在。所述含水载体可包含水，或水和有机溶剂的可混溶的混合物，并且在一个方面可包含水和最少或浓度不大的有机溶剂，除了另外作为其它必要或任选组分的微量组分附带地掺入组合物中的那些。
用于本发明的载体包括水以及低级烷基醇和多元醇的水溶液。用于本文的低级烷基醇为具有1至6个碳原子的一元醇，在一个方面为乙醇和异丙醇。用于本文的多元醇包括丙二醇、已二醇、甘油和丙二醇。
制备方法
本发明的个人清洁组合物可通过如下方法制得，所述方法包括：1）用阴离子乳化剂涂覆聚丙烯酸酯微胶囊以形成阴离子聚丙烯酸酯微胶囊；2）将阴离子聚丙烯酸酯微胶囊与阳离子沉积聚合物混合以形成预混物；以及3）将所述预混物加入包含表面活性剂和载体的去污组合物中。
在另一个实施例中，本发明的个人清洁组合物可通过如下方法制得，所述方法包括：1）用阴离子乳化剂涂覆聚丙烯酸酯微胶囊以形成阴离子聚丙烯酸酯微胶囊；2）将阴离子聚丙烯酸酯微胶囊与阳离子沉积聚合物混合以形成预混物；3）将所述预混物加入阴离子表面活性剂中；以及4）将步骤（3）的所得组合物加入包含表面活性剂和载体的去污组合物中。
已令人惊奇地发现，与不存在混合组分时相比，阴离子聚丙烯酸酯微胶囊与阳离子沉积聚合物组合缔合具有更高的粘弹性，从而提供阴离子微胶囊对毛发的更好粘附性。
例如，当包含丙烯酸和丙烯酸丁酯的共聚物（40,000g/mol的分子量）的阴离子乳化剂与各种阳离子聚合物混合以形成聚合物预混物时，结果为粘弹性显著增加。这种增加表明强效聚电解质相互作用，这以粘弹性组分G’随着阳离子聚合物数量增加而增加来示例（参见表1）。
表1：作为阴离子：阳离子聚合物预混比率的函数的粘弹性。
Figure BDA00003863831500131
此外，当将阴离子表面活性剂加入聚合物预混物中时，还注意到粘弹性显著增加。此类粘弹性的增加受阳离子沉积聚合物和阴离子表面活性剂之间的缔合强度的影响。这以在阴离子表面活性剂加入预混物中时粘弹性组分G’的增加来示例（参见表2）。
表2：作为加入聚合物预混物中的阴离子表面活性剂的函数的粘弹 性。
在本发明的一个实施例中，通过在微胶囊制备过程期间掺入阴离子乳化剂，使阴离子乳化剂共价结合到聚丙烯酸酯微胶囊的外壁。在另一个实施例中，将阴离子乳化剂加入包含完全成形的聚丙烯酸酯微胶囊的浆液中。在经由任一步骤形成阴离子聚丙烯酸酯微胶囊后，然后将阳离子沉积聚合物加入阴离子微胶囊中以形成粘弹性预混物。当该预混物然后与阴离子表面活性剂混合时，聚合物的缔合形成阴离子聚丙烯酸酯微胶囊壁上的微观结构。即使在个人清洁组合物稀释时也形成微观结构。一旦形成，聚合物缔合微观结构的高粘度就致使阴离子聚丙烯酸酯微胶囊即使在个人清洁组合物稀释时也保持其微胶囊结构。此外，微胶囊结构提供多个与基质的接触点，用于增加微胶囊在部位上的时间量。
本发明的聚丙烯酸酯微胶囊可配制成任何合适的形式，并且通过配制人员所选的任何方法来制备，其非限制性例子描述于U.S.5,879,584；U.S.5,691,297；U.S.5,574,005；U.S.5,569,645；U.S.5,565,422；U.S.5,516,448；U.S.5,489,392；U.S.5,486,303中，这些专利均以引用方式并入本文。
产品形式
本发明的个人清洁组合物可为洗去型产品或免洗型产品的形式，并且可配制为多种产品形式，包括但不限于霜膏、凝胶、乳液、摩丝和喷剂。
在一个实施例中，所述个人清洁组合物为包含小于约45%的水的凝胶形式。在此类实施例中，所述凝胶可具有约1,000cps至约10,000cps的净粘度。凝胶的净粘度可定义为1/秒的剪切速率下流体的粘度。科学地讲，粘度为剪切应力与剪切速率的比率。在一些实施例中，凝胶的剪切速率范围为0.01/秒至10/秒。
可根据以下方法，用流变仪测量凝胶产品形式的净粘度：
(1)将样品装载到板上。
(2)在1度锥体与板之间建立1毫米间隙。
(3)在流体上执行0.01/秒至10/秒的剪切扫描。
(4)记录流体的剪切应力响应。
(5)通过计算各剪切速率下剪切应力与剪切速率的比率，测定流体的净粘度。
如本文所示，个人清洁组合物可包含结构化清洁相和有益相。在一个实施例中，结构化清洁相和有益相可物理接触。在一个实施例中，个人清洁组合物可为多相个人清洁组合物，其中结构化清洁相和有益相可显著程度共混或混合，但是仍物理上完全分开，使得肉眼无法检测物理独特性。
在某些实施例中，个人清洁组合物可为多相个人清洁组合物，其中可使结构化清洁相和有益相占据其中储存相的包装内单独但分开的物理空间。在此类实施例中，可储存结构化清洁相和有益相，使得相彼此不直接接触。在另一个实施例中，个人清洁组合物可为多相个人清洁组合物，其中结构化清洁相和有益相物理接触，并且可具有条纹状或大理石花纹状构型。
在另一个实施例中，个人清洁组合物可包含一种或多种上述多相个人清洁组合物的组合。在一个此类实施例中，一种共混的多相个人清洁组合物可以条纹形式与另一种共混的多相个人清洁组合物堆叠。并且在另一个此类实施例中，由颜色分辨的共混的多相个人清洁组合物可以条纹形式堆叠，其中所述共混的多相个人清洁组合物在其它方面可为相似的。
测试方法
应当理解，由于发明描述且受权利要求书保护于本文，在本专利申请测试方法部分中公开的测试方法应被用来测定申请人的发明参数的相应值。
A.ClogP
通过Hansch和Leo（参考文献，A.Leo，在Comprehensive MedicinalChemistry，第4卷，C.Hansch，P.G.Sammens，J.B.Taylor，和C.A.Ramsden编辑的第295页，Pergamon Press，1990，均以引用方式并入本文）的分段方法来测定该“计算的logP”（ClogP）。可通过使用购自Daylight Chemical Information Systems Inc.（Irvine,California U.S.A.）的“CLOGP”程序计算ClogP值。
B.沸点
通过ASTM International的ASTM方法D2887-04a，“Standard TestMethod for Boiling Range Distribution of Petroleum Fractions by GasChromatography,”来测量沸点。
C.中值粒度
使用由Particle Sizing Systems，Santa Barbara CA制造的Accusizer780A来测量粒度。所述仪器使用Duke粒度标准物从0至300μ校准。用于粒度评估的样品通过将约1g胶囊浆液稀释在约5g去离子水中并进一步将约1g该溶液稀释在约25g水中来制备。
将约1g最稀样品加入Accusizer中，并且测试开始，使用自动稀释结构。所述Accusizer应以超过9200计数/秒读数。如果计数小于9200，则应加入附加样品。所述accusizer将稀释测试样本直至9200计数/秒并开始评估。测试之后2分钟，Accusizer将显示结果，包括体积-重量中值尺寸。
宽度指数可通过测定超过95%的累积颗粒体积的粒度（95%尺寸），超过5%的累积颗粒体积的粒度（5%尺寸）以及中值体积-重量粒度（50%尺寸—该尺寸“上方”和“下方”两者的50%的颗粒体积）计算。宽度指数（5）=（（95%尺寸）-（5%尺寸）/50%尺寸）。
D.破裂强度测试方法
分析步骤包括：
a.)将1克颗粒置于1升蒸馏去离子（DI）水中。
b.)允许颗粒在DI水中保留10分钟，然后通过使用60mL注射器过滤器（1.2微米硝化纤维过滤器（微孔，25mm直径））过滤回收颗粒。
c.)测定50个单个颗粒的破裂力。使用Zhang,Z.；Sun,G；“Mechanical Properties of Melamine-Formaldehydemicrocapsules,”（J.Microencapsulation，第18卷，第5期，第593-602页，2001年）中给出的程序来测定颗粒的破裂力。然后通过将破裂力（以牛顿为单位）除以相应球形颗粒的横截面积（πr2，其中r为压缩之前颗粒的半径）来计算各颗粒的破裂强度，所述横截面积如下测定：使用Zhang,Z.；Sun,G；“Mechanical Properties of Melamine-Formaldehyde microcapsules”（J.Microencapsulation，第18卷，第5期，第593-602页，2001年）中的实验设备和方法来测量各单个颗粒的粒度。
d.)使用得自上文c.）的50次独立测量，并且计算具有在受权利要求书保护范围的破裂强度范围内的破裂强度的颗粒百分比。
E.ζ电势
(1)设备规格：Malvern Zeatasizer Nano ZEN3600型样品池，一次性毛细管池（绿色池）
(2)使用Duke标准物来测量PSD，并且使用它来测量ζ电势以确保仪器适当地运行。
(3)用1-2mL乙醇冲洗DTS1060毛细管池，然后用DI水冲洗，以制备毛细管池。
(4)样品制备：首先，将20mL DI水通过0.2微米过滤器过滤到20mL小瓶中。将1滴（50微升）30重量%固体颗粒悬浮液加入小瓶中，并且将样品轻轻来回翻转，直至颗粒悬浮液均匀分散在小瓶中。接着用1-2mL DI水冲洗DTS1060一次性绿色ζ池，然后使用注射器将样品溶液从小瓶中转移到ζ池，确保池中不存在气泡。将池填充至顶部，然后在池出口和入口处放置顶盖（再次确保样品池中不存在气泡）。然后将池置于样品室中，使电极面向体系侧。最后将样品池置于仪器中。
(5)运行条件：
a.折射率=1.35（该数可因悬浮液而变化。可使用折射计测量任何颗粒悬浮液的折射率）
b.温度=25摄氏度
c.平衡时间=1分钟
d.使用Smoluchowski模型来计算ζ电势。
(6)将每个样品平行测定三次。得自仪器的结果以ζ电势报导，以毫伏为单位，无外推。
实例
尽管已用具体实施例来举例说明和描述了本发明，但是对本领域的技术人员显而易见的是，在不脱离本发明的实质和范围的情况下可作出许多其它的改变和变型。因此，随附权利要求书旨在涵盖本发明范围内的所有这些改变和变型。
被称为香味A的香料组合物用来制备本发明的实例。下表列出了成分以及它们的特性。表2提供了香料油组合物的ClogP分类。
表1：
材料名称 ClogP 沸点℃
βγ己烯醇 1.3 155
苯乙醇 1.32 219
新洋茉莉醛 1.77 329
额外的(2,4-二甲基环己烯-3-基)甲醛 1.78 199
乙酸戊酯（异构体共混物） 1.87 135
甜瓜醛 2.09 182
(Z)-碳酸-3-己烯甲酯 2.14 167
乙酸异丁子香酚酯 2.17 303
乙酸顺式-3-己烯酯 2.18 167
茉莉内酯 2.36 219
2,6-亚壬基-1-醇 2.43 213
铃兰吡喃 2.46 238
壬内酯 2.66 193
顺式茉莉酮 2.81 254
乙基里哪醇 2.92 223
Pino Acetaldehyde 2.98 261
二氢茉莉酮酸甲酯 3.01 323
甲基癸烯醇 3.06 242
Azurone 10/tec 0015573 3.06 395
二氢月桂烯醇 3.08 195
Cyclemax 3.23 281
Hivernal 3.29 351
Pomarose 3.51 214
十一烷酸内酯 3.75 228
大马烯酮Total937459 3.89 267
Acalea（01-1963） 3.9 344
水杨酸顺式-3-己烯酯 4 316
β-紫罗兰酮 4.02 267
聚檀香醇 4.21 256
龙涎呋喃 4.58 285
5-环十六烯-1-酮 5.04 331
龙涎酮或木材 5.05 325
左旋麝香酮 5.48 321
海佛麝香947650 5.56 309
实例1：非离子微胶囊（TAS0810101，MVF1837-94B）
将由75g芳香油香味A、75g肉豆蔻酸异丙酯、0.6g DuPont Vazo-52和0.4g DuPont Vazo-67组成的油溶液加入35℃温度控制的钢制带夹套反应器中，所述反应器以1000rpm（4个末端，2”直径的平坦研磨叶片）混合并且以100cc/min施加氮气层。将油溶液在45分钟内加热至75℃，在75℃下保持45分钟，并且在75分钟内冷却至60℃。
当所述第一油溶液达到60℃时，加入由37.5g芳香油、0.5g甲基丙烯酸叔丁胺乙酯、0.4g丙烯酸2-羧乙酯和20g Sartomer CN975（六官能的氨基甲酸酯-丙烯酸酯低聚物）组成的第二油溶液。将混合的油在60℃下再保持10分钟。
停止混合，并且使用漏斗，将由56g5%活性聚乙烯醇Celvol540水溶液、244g水、1.1g20%NaOH和1.2g DuPont Vazo-68WSP组成的水溶液加入油溶液的底部。
再次以2500rpm开始混合60分钟以将油相乳化到水溶液中。研磨结束后，用3”螺旋桨以350rpm继续混合。将批料在60℃下保持45分钟，在30分钟内将温度提高至75℃，在75℃下保持4小时，在30分钟内加热至90℃，然后在90℃下保持8小时。然后使批料冷却至室温。最终的微胶囊具有6.4微米的中值粒度，1.3的宽度指数和负0.5毫伏的ζ电势，以及27.6重量%的总香味A浓度。
实例2：大粒度阴离子微胶囊（TAS1122101）
使用与实例1相同的材料、组合物和工艺条件制备胶囊，具有以下不同：油相上的组成差异为1克Vazo-52、0.8克Vazo-67、0.3克甲基丙烯酸叔丁胺乙酯、0.25克丙烯酸2-羧乙酯和12克Sartomer CN975；并且水相上的组成差异为22克25%活性Colloid 351和308克水。所有其它混合和工艺调理剂保持相同。最终的微胶囊具有10.7微米的中值粒度，1.5的宽度指数和负60毫伏的ζ电势，以及34.9重量%的总香味A浓度。
实例3：小粒度阴离子微胶囊（TAS1123101）
使用与实例1相同的材料、组合物和工艺条件制备胶囊，具有以下不同：油相上的组成差异为1克Vazo-52、0.8克Vazo-67、1.5克甲基丙烯酸叔丁胺乙酯、1.2克丙烯酸2-羧乙酯和60克Sartomer CN975；并且水相上的组成差异为68克25%活性Colloid 351和282克水。所有其它混合和工艺调理剂保持相同。最终的微胶囊具有1.4微米的中值粒度，1.2的宽度指数和负60毫伏的ζ电势，以及20.7重量%的总香味A浓度。
实例4：阴离子微胶囊（TAS1101101）
使用与实例2相同的材料、组合物和工艺条件制备胶囊，具有以下不同：油相上的组成差异为1克甲基丙烯酸叔丁胺乙酯、0.8克丙烯酸2-羧乙酯和40克Sartomer CN975；并且水相上的组成差异为22克25%活性Colloid 351和282克水。所有其它混合和工艺调理剂保持相同。
最终的微胶囊具有4.8微米的中值粒度，1.3的宽度指数和负60毫伏的ζ电势，以及23.5重量%的总香味A浓度。
实例5：身体清洁组合物
将实例1、2和4的微胶囊配制成身体清洁组合物。首先将实例2和4的阴离子微胶囊与15重量%木薯淀粉（Akzo）的溶液混合以形成粘弹性混合物：
微胶囊实例 微胶囊（g） 15%木薯淀粉溶液（g） 水（g） 最终香料含量重量%
2（预混物2） 4.1 2.38 3.52 14.31%
4（预混物4） 6.09 2.38 1.53 14.31%
然后将该预混物加入下文身体清洁组合物中，使用DAFC 400FVZ高速混合器以1900RPM混合1分钟。
Figure BDA00003863831500201
采用以下方案，测定上文每种产品在前臂上的嗅觉表现：
●在流水下将泡夫浸透5秒。（95℉+/-5℉；～1.8L/min）
●在流水下从肘至腕将前臂润湿5秒。
●将1mL一种或多种产品分配到另一个手掌中。
●将产品在施用臂上摩擦5秒。手掌沿着臂缘摩擦以从手掌中移除多余产品。
●不润湿泡夫。以长循环行程将前臂内侧轻轻洗涤10秒。它应当起泡，如果品质不匀，减小压力。
●允许15秒停留时间。
●用流水将前臂冲洗15秒。
●通过将纸巾放置在下臂上，并且将另一只手沿整个内臂行进（肘至腕）而不摩擦，用干净的纸巾干燥。
●在至少30秒内不执行测量，在此期间使臂通到空气中。
●就老化臂（并且暴露于环境空气）的不同时间，评定摩擦前和摩擦后臂的嗅觉表现。
强度标度1至100（无气味至可能最强烈的）
注意到，当将阴离子微胶囊和阳离子聚合物的预混物加入身体清洁组合物中时，检测到每个芳香剂寿命时间点的芳香剂强度显著更高（相对于对照物4A）。
本文所公开的量纲和值不应被理解为严格限于所引用的精确值。相反，除非另外指明，每个这样的量纲旨在表示所述值以及围绕该值功能上等同的范围。例如，所公开的量纲“40mm”旨在表示“约40mm”。
除非明确地不包括在内或换句话讲有所限制，本文所引用的每篇文献，包括任何交叉引用的或相关的专利或专利申请，均特此全文以引用方式并入本文。任何文献的引用不是对其作为本文所公开的或受权利要求书保护的任何发明的现有技术，或者其单独地或者与任何其它参考文献的任何组合，或者参考、提出、建议或公开任何此类发明的认可。此外，当本发明中术语的任何含义或定义与以引用方式并入的文件中相同术语的任何含义或定义矛盾时，应当服从在本发明中赋予该术语的含义或定义。
尽管已用具体实施例来举例说明和描述了本发明，但是对本领域的技术人员显而易见的是，在不脱离本发明的实质和范围的情况下可作出许多其它的改变和变型。因此，随附权利要求书旨在涵盖本发明范围内的所有这些改变和变型。

Claims (15)

1.一种个人清洁组合物，包含：
(a)0.001%至10%的阴离子带电聚丙烯酸酯微胶囊；
(b)0.01%至2%的阳离子沉积聚合物；和
(c)2%至50%的去污表面活性剂；和
(d)载体。
2.根据权利要求1所述的个人清洁组合物，其中所述阴离子带电聚丙烯酸酯微胶囊包含阴离子乳化剂和聚丙烯酸酯微胶囊。
3.根据权利要求2所述的个人清洁组合物，其中所述阴离子乳化剂包围所述聚丙烯酸酯微胶囊的外表面的至少一部分，或物理地或化学地结合到所述聚丙烯酸酯微胶囊的外表面。
4.根据权利要求2或3中任一项所述的个人清洁组合物，其中将所述阴离子乳化剂和所述聚丙烯酸酯微胶囊混合，使得所述阴离子乳化剂与所述聚丙烯酸酯微胶囊的重量比为1.0:40至0.5:5。
5.根据前述权利要求中任一项所述的个人清洁组合物，其中将所述阴离子带电聚丙烯酸酯微胶囊和所述阳离子沉积聚合物混合，使得所述阴离子带电聚丙烯酸酯微胶囊与所述阳离子沉积聚合物的重量比为1.0:0.01至1.0:10。
6.根据前述权利要求中任一项所述的个人清洁组合物，其中所述阴离子乳化剂选自：聚(甲基)丙烯酸；(甲基)丙烯酸和其具有C1-C22烷基的(甲基)丙烯酸酯的共聚物；(甲基)丙烯酸和(甲基)丙烯酰胺的共聚物；以及它们的混合物。
7.根据前述权利要求中任一项所述的个人清洁组合物，其中所述阴离子聚丙烯酸酯微胶囊具有2微米至80微米的粒度。
8.根据前述权利要求中任一项所述的个人清洁组合物，其中所述聚丙烯酸酯微胶囊具有芯和包封所述芯的外壳。
9.根据前述权利要求中任一项所述的个人清洁组合物，其中所述芯包含6%至99.9%的有益剂。
10.根据前述权利要求中任一项所述的个人清洁组合物，其中所述阳离子沉积聚合物为水溶性聚合物，其具有0.5毫当量/克至12毫当量/克的电荷密度，并且其中所述阳离子沉积聚合物具有100,000道尔顿至5,000,000道尔顿的分子量。
11.根据前述权利要求中任一项所述的个人清洁组合物，其中所述去污表面活性剂为阴离子型的、非离子型的、阳离子型的、两性离子型的、两性型的、皂、或它们的组合。
12.根据前述权利要求中任一项所述的个人清洁组合物，其中所述阴离子带电聚丙烯酸酯微胶囊包含在附聚物中，并且其中所述附聚物包含选自以下的材料：二氧化硅、柠檬酸、碳酸钠、硫酸钠、氯化钠、以及基料如硅酸钠、改性纤维素、聚乙二醇、聚丙烯酸酯、聚丙烯酸、沸石以及它们的混合物。
13.根据前述权利要求中任一项所述的个人清洁组合物，其中所述个人清洁组合物为凝胶的形式，并且其中所述凝胶包含小于45%的水。
14.根据权利要求13所述的个人清洁组合物，其中所述凝胶具有1,000cps至10,000cps的净粘度。
15.一种制备个人清洁组合物的方法，所述方法包括以下步骤：
a)用阴离子乳化剂涂覆聚丙烯酸酯微胶囊以形成阴离子聚丙烯酸酯微胶囊；
b)将所述阴离子聚丙烯酸酯微胶囊与阳离子沉积聚合物混合以形成预混物；
c)将所述预混物加入包含表面活性剂和载体的去污组合物中。
CN2012800160796A 2011-04-07 2012-04-04 具有增强的聚丙烯酸酯微胶囊的沉积的个人清洁组合物 Pending CN103458859A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161472882P 2011-04-07 2011-04-07
US61/472,882 2011-04-07
PCT/US2012/032101 WO2012138710A2 (en) 2011-04-07 2012-04-04 Personal cleansing compositions with increased deposition of polyacrylate microcapsules

Publications (1)

Publication Number Publication Date
CN103458859A true CN103458859A (zh) 2013-12-18

Family

ID=46028145

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2012800160796A Pending CN103458859A (zh) 2011-04-07 2012-04-04 具有增强的聚丙烯酸酯微胶囊的沉积的个人清洁组合物

Country Status (6)

Country Link
US (1) US9162085B2 (zh)
EP (1) EP2694017B1 (zh)
JP (2) JP6283607B2 (zh)
CN (1) CN103458859A (zh)
MX (1) MX2013010980A (zh)
WO (1) WO2012138710A2 (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107148263A (zh) * 2014-11-10 2017-09-08 宝洁公司 个人护理组合物
CN110418669A (zh) * 2017-03-16 2019-11-05 宝洁公司 包含微胶囊的消费产品组合物
CN111163840A (zh) * 2017-11-15 2020-05-15 弗门尼舍有限公司 改善沉积的微胶囊

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9186642B2 (en) 2010-04-28 2015-11-17 The Procter & Gamble Company Delivery particle
US9993793B2 (en) 2010-04-28 2018-06-12 The Procter & Gamble Company Delivery particles
CN103458858B (zh) 2011-04-07 2016-04-27 宝洁公司 具有增强的聚丙烯酸酯微胶囊的沉积的洗发剂组合物
US8980292B2 (en) 2011-04-07 2015-03-17 The Procter & Gamble Company Conditioner compositions with increased deposition of polyacrylate microcapsules
JP6283607B2 (ja) * 2011-04-07 2018-02-21 ザ プロクター アンド ギャンブル カンパニー ポリアクリレートマイクロカプセルの堆積が増大されたパーソナルクレンジング組成物
CN103561713B (zh) 2011-05-26 2016-11-02 宝洁公司 具有有效香料浓郁度的组合物
WO2014118095A2 (en) * 2013-01-30 2014-08-07 Unilever Plc Compositions with improved aesthetic and sensorial properties
US9611362B2 (en) 2013-07-29 2017-04-04 The Procter & Gamble Company Cationic organopolysiloxanes
US9540489B2 (en) 2013-07-29 2017-01-10 The Procter & Gamble Company Blocky cationic organopolysiloxane
US9963470B2 (en) 2013-07-29 2018-05-08 The Procter & Gamble Company Branched blocky cationic organopolysiloxane
US9580670B2 (en) 2013-07-29 2017-02-28 The Procter & Gamble Company Consumer product compositions comprising organopolysiloxane conditioning polymers
US9993418B2 (en) 2013-07-29 2018-06-12 The Procter & Gamble Company Benefit agent emulsions and consumer products containing such emulsions
US10414873B2 (en) 2013-07-29 2019-09-17 The Procter & Gamble Company Organopolysiloxane polymers
US10081910B2 (en) 2013-07-29 2018-09-25 The Procter & Gamble Company Absorbent articles comprising organopolysiloxane conditioning polymers
US9701929B2 (en) 2013-07-29 2017-07-11 The Procter & Gamble Company Consumer product compositions comprising organopolysiloxane emulsions
EP3151871A1 (en) * 2014-06-09 2017-04-12 The Procter & Gamble Company Dispenser with two reservoirs
EP2980171B1 (de) * 2014-07-31 2017-05-03 Fachhochschule Münster Härtbare zusammensetzung und gehärtetes erzeugnis mit antimikrobiellen eigenschaften
JP6487662B2 (ja) * 2014-10-21 2019-03-20 花王株式会社 ボディリンス剤
US10966916B2 (en) 2014-11-10 2021-04-06 The Procter And Gamble Company Personal care compositions
WO2016077327A1 (en) 2014-11-10 2016-05-19 The Procter & Gamble Company Personal care compositions with two benefit phases
MX2017006148A (es) 2014-11-10 2017-07-27 Procter & Gamble Composiciones para el cuidado personal con dos fases beneficas.
ES2667487T3 (es) * 2014-12-08 2018-05-11 Takasago International Corporation Composiciones cosméticas con aclarado
EP3316973B1 (en) * 2015-06-30 2019-08-07 Firmenich SA Delivery system with improved deposition
BR112018004702B1 (pt) * 2015-10-29 2021-07-06 Unilever Ip Holdings B.V. Composição de higiene pessoal
WO2017085033A1 (en) 2015-11-18 2017-05-26 Basf Se Improvements in or relating to organic compounds
US10159638B2 (en) 2016-06-21 2018-12-25 Johnson & Johnson Consumer Inc. Personal care compositions containing complexing polyelectrolytes
EP3282003B1 (en) 2016-08-09 2020-09-02 Takasago International Corporation Solid composition comprising free and encapsulated fragrances
US10676701B2 (en) * 2017-03-16 2020-06-09 The Procter & Gamble Company Consumer product compositions comprising microcapsules
US10385297B2 (en) 2017-03-16 2019-08-20 The Procter & Gamble Company Methods for making encapsulate-containing product compositions
US10611988B2 (en) 2017-03-16 2020-04-07 The Procter & Gamble Company Methods for making encapsulate-containing product compositions
US10385296B2 (en) 2017-03-16 2019-08-20 The Procter & Gamble Company Methods for making encapsulate-containing product compositions
EP3461470A1 (en) * 2017-09-28 2019-04-03 The Procter & Gamble Company Conditioner compositions with polyacrylate microcapsules having improved long-lasting odor benefit
WO2019079405A1 (en) 2017-10-20 2019-04-25 The Procter & Gamble Company AEROSOL FOAMING CLEANSER FOR THE SKIN
WO2019079409A1 (en) 2017-10-20 2019-04-25 The Procter & Gamble Company CLEANER FOR AEROSOL MOUSSE FOAM
WO2019177717A1 (en) 2018-03-13 2019-09-19 The Procter & Gamble Company Consumer product compositions comprising microcapsules
WO2019177718A1 (en) 2018-03-13 2019-09-19 The Procter & Gamble Company Consumer product compositions comprising microcapsules
WO2019177716A1 (en) 2018-03-13 2019-09-19 The Procter & Gamble Company Consumer product compositions comprising microcapsules
EP3643292A1 (en) 2018-10-24 2020-04-29 The Procter & Gamble Company Conditioner compositions with increased deposition of polyacrylate microcapsules
EP3643290A1 (en) 2018-10-24 2020-04-29 The Procter & Gamble Company Conditioner compositions with increased deposition of polyacrylate microcapsules
EP3643289A1 (en) 2018-10-24 2020-04-29 The Procter & Gamble Company Conditioner compositions with increased deposition of polyacrylate microcapsules
CN113015904A (zh) 2018-11-29 2021-06-22 宝洁公司 用于筛选个人护理产品的方法
EP3970690A3 (en) 2020-06-05 2022-07-06 International Flavors & Fragrances Inc. Consumer products with improved aesthetics

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6849584B2 (en) * 2001-11-02 2005-02-01 The Procter & Gamble Company Composition containing a cationic polymer and water insoluble solid material
CN1655753A (zh) * 2001-10-03 2005-08-17 宝洁公司 包含颗粒和沉积助剂的洗发剂
WO2010079466A2 (en) * 2010-04-28 2010-07-15 The Procter & Gamble Company Delivery particles

Family Cites Families (534)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE406221A (zh) 1933-11-15
US2438091A (en) 1943-09-06 1948-03-16 American Cyanamid Co Aspartic acid esters and their preparation
BE498391A (zh) 1944-10-16
BE498392A (zh) 1945-11-09
US2528378A (en) 1947-09-20 1950-10-31 John J Mccabe Jr Metal salts of substituted quaternary hydroxy cycloimidinic acid metal alcoholates and process for preparation of same
US2658072A (en) 1951-05-17 1953-11-03 Monsanto Chemicals Process of preparing amine sulfonates and products obtained thereof
US2730456A (en) 1953-06-30 1956-01-10 Ncr Co Manifold record material
USRE24899E (en) 1953-06-30 1960-11-29 Oil-containrab
US2730457A (en) 1953-06-30 1956-01-10 Ncr Co Pressure responsive record materials
US2800457A (en) 1953-06-30 1957-07-23 Ncr Co Oil-containing microscopic capsules and method of making them
US2826551A (en) 1954-01-04 1958-03-11 Simoniz Co Nontangling shampoo
US2809971A (en) 1955-11-22 1957-10-15 Olin Mathieson Heavy-metal derivatives of 1-hydroxy-2-pyridinethiones and method of preparing same
US3429827A (en) 1962-11-23 1969-02-25 Moore Business Forms Inc Method of encapsulation
US3236733A (en) 1963-09-05 1966-02-22 Vanderbilt Co R T Method of combatting dandruff with pyridinethiones metal salts detergent compositions
US3332880A (en) 1965-01-04 1967-07-25 Procter & Gamble Detergent composition
US3516941A (en) 1966-07-25 1970-06-23 Minnesota Mining & Mfg Microcapsules and process of making
US3761418A (en) 1967-09-27 1973-09-25 Procter & Gamble Detergent compositions containing particle deposition enhancing agents
US3580853A (en) 1967-09-27 1971-05-25 Procter & Gamble Detergent compositions containing particle deposition enhancing agents
JPS5212150B1 (zh) 1968-06-04 1977-04-05
US3772215A (en) 1969-06-13 1973-11-13 Nat Patent Dev Corp Water soluble entrapping of a fragrance
US3681248A (en) 1969-06-13 1972-08-01 Nat Patent Dev Corp Water soluble entrapping of a fragrance
US3691140A (en) 1970-03-09 1972-09-12 Spencer Ferguson Silver Acrylate copolymer microspheres
US4075134A (en) 1970-06-08 1978-02-21 The Dow Chemical Company Emulsion polymerization method for preparing microspheres having liquid center and seamless rigid walls
US3965033A (en) 1970-07-27 1976-06-22 Fuji Photo Film Co., Ltd. Process for the production of oil-containing microcapsules
US3886085A (en) 1971-08-31 1975-05-27 Fuji Photo Film Co Ltd Process for producing fine oil-containing microcapsules having strong protective shells and microcapsules produced thereby
US3753196A (en) 1971-10-05 1973-08-14 Kulite Semiconductor Products Transducers employing integral protective coatings and supports
US3826756A (en) 1972-02-22 1974-07-30 Loctite Corp Process for preparing discrete particles of microencapsulated liquid anaerobic compositions
US4285720A (en) 1972-03-15 1981-08-25 Stauffer Chemical Company Encapsulation process and capsules produced thereby
US3958581A (en) 1972-05-17 1976-05-25 L'oreal Cosmetic composition containing a cationic polymer and divalent metal salt for strengthening the hair
US3898039A (en) 1972-06-15 1975-08-05 Tong Joe Lin Article having fumigant containing substrate for diffusion promoting candle
CA1018893A (en) 1972-12-11 1977-10-11 Roger C. Birkofer Mild thickened shampoo compositions with conditioning properties
FR2215864A5 (zh) 1973-01-25 1974-08-23 Pepro
US4062799A (en) 1973-01-30 1977-12-13 Fuji Photo Film Co., Ltd. Method of forming microcapsule films having low porosity
JPS545051Y2 (zh) 1973-09-05 1979-03-05
GB1403139A (en) 1973-09-18 1975-08-13 Colgate Palmolive Co Antiperspirant compositions
US3964500A (en) 1973-12-26 1976-06-22 Lever Brothers Company Lusterizing shampoo containing a polysiloxane and a hair-bodying agent
JPS5843137B2 (ja) 1974-04-09 1983-09-24 富士写真フイルム株式会社 カプセルカホウホウ
US4422853A (en) 1974-05-16 1983-12-27 L'oreal Hair dyeing compositions containing quaternized polymer
US4217914A (en) 1974-05-16 1980-08-19 L'oreal Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin
US4001140A (en) 1974-07-10 1977-01-04 Ncr Corporation Capsule manufacture
US3929678A (en) 1974-08-01 1975-12-30 Procter & Gamble Detergent composition having enhanced particulate soil removal performance
US4046750A (en) 1974-09-30 1977-09-06 California Institute Of Technology Ionene modified small polymeric beads
US4093556A (en) 1975-07-02 1978-06-06 Loctite Corporation Process for microencapsulation of metallocenes
AT365448B (de) 1975-07-04 1982-01-11 Oreal Kosmetische zubereitung
US4197865A (en) 1975-07-04 1980-04-15 L'oreal Treating hair with quaternized polymers
CH589464A5 (zh) 1975-07-11 1977-07-15 Filtrox Maschinenbau Ag
GB1507739A (en) 1975-11-26 1978-04-19 Wiggins Teape Ltd Capsules
US4145184A (en) 1975-11-28 1979-03-20 The Procter & Gamble Company Detergent composition containing encapsulated perfume
GB1546480A (en) 1976-04-26 1979-05-23 Fellows A N Disinfectant and sterilizing preparations
US4100103A (en) 1976-12-30 1978-07-11 Ncr Corporation Capsule manufacture
US4234627A (en) 1977-02-04 1980-11-18 The Procter & Gamble Company Fabric conditioning compositions
LU76955A1 (zh) 1977-03-15 1978-10-18
JPS5819261Y2 (ja) 1977-04-20 1983-04-20 株式会社岡村製作所 扉装置
JPS5425277A (en) 1977-07-27 1979-02-26 Fuji Photo Film Co Ltd Method of producing microcapsule
US4166152B1 (en) 1977-08-17 1999-05-18 Minnesota Mining & Mfg Tacky polymeric microspheres
FR2416008A1 (fr) 1978-02-02 1979-08-31 Oreal Lyophilisats de liposomes
JPS54107881A (en) 1978-02-14 1979-08-24 Fuji Photo Film Co Ltd Preparation of minute capsule
US4197346A (en) 1978-10-10 1980-04-08 Appleton Papers Inc. Self-contained pressure-sensitive record material and process of preparation
US4275055A (en) 1979-06-22 1981-06-23 Conair Corporation Hair conditioner having a stabilized, pearlescent effect
US4507280A (en) 1979-07-02 1985-03-26 Clairol Incorporated Hair conditioning composition and method for use
US4663158A (en) 1979-07-02 1987-05-05 Clairol Incorporated Hair conditioning composition containing cationic polymer and amphoteric surfactant and method for use
JPS5651238A (en) 1979-10-02 1981-05-08 Fuji Photo Film Co Ltd Production of microminiature capsule
US4379753A (en) 1980-02-07 1983-04-12 The Procter & Gamble Company Hair care compositions
US4345080A (en) 1980-02-07 1982-08-17 The Procter & Gamble Company Pyridinethione salts and hair care compositions
US4323683A (en) 1980-02-07 1982-04-06 The Procter & Gamble Company Process for making pyridinethione salts
US4529586A (en) 1980-07-11 1985-07-16 Clairol Incorporated Hair conditioning composition and process
US4423099A (en) 1980-07-28 1983-12-27 Ciba-Geigy Corporation Membrane modified hydrogels
US4470982A (en) 1980-12-22 1984-09-11 The Procter & Gamble Company Shampoo compositions
JPS5814942A (ja) 1981-07-17 1983-01-28 Jujo Paper Co Ltd 微小カプセルの製造方法
GR76237B (zh) 1981-08-08 1984-08-04 Procter & Gamble
US4446032A (en) 1981-08-20 1984-05-01 International Flavors & Fragrances Inc. Liquid or solid fabric softener composition comprising microencapsulated fragrance suspension and process for preparing same
US4428869A (en) 1981-08-20 1984-01-31 International Flavors & Fragrances Inc. Cologne consisting of microcapsule suspension
US4364837A (en) 1981-09-08 1982-12-21 Lever Brothers Company Shampoo compositions comprising saccharides
JPS5889661A (ja) 1981-11-20 1983-05-28 Kanegafuchi Chem Ind Co Ltd 分散方法
JPS58132006U (ja) 1982-03-01 1983-09-06 ナショナル住宅産業株式会社 水切板取付構造
US4444699A (en) 1982-04-20 1984-04-24 Appleton Papers Inc. Capsule manufacture
US4561998A (en) 1982-05-24 1985-12-31 The Procter & Gamble Company Near-neutral pH detergents containing anionic surfactant, cosurfactant and fatty acid
NL8203275A (nl) 1982-08-20 1984-03-16 Naarden International Nv Werkwijze ter bereiding van luchtverfrissingsgelen, alsmede de aldus verkregen gelen.
US4550862A (en) 1982-11-17 1985-11-05 The Procter & Gamble Company Liquid product pouring and measuring package with self draining feature
US4597898A (en) 1982-12-23 1986-07-01 The Proctor & Gamble Company Detergent compositions containing ethoxylated amines having clay soil removal/anti-redeposition properties
JPS59159175A (ja) 1983-03-02 1984-09-08 Konishiroku Photo Ind Co Ltd 圧力定着性マイクロカプセル型トナ−
JPS59139268U (ja) 1983-03-10 1984-09-18 上平　光治 水抜の出来る洗容器
CH652035A5 (fr) 1983-03-23 1985-10-31 Firmenich & Cie Element de support gelifie pour dispositifs de diffusion de vapeurs d'agents assainissants.
US4552811A (en) 1983-07-26 1985-11-12 Appleton Papers Inc. Capsule manufacture
US4574110A (en) 1983-07-28 1986-03-04 Mitsui Toatsu Chemicals, Incorporated Process for producing microcapsules and microcapsule slurry
US4610927A (en) 1983-09-14 1986-09-09 Kureha Kagaku Kogyo Kabushiki Kaisha Microcapsules containing a hydrophobic, volatile core substance and their production
AU561281B2 (en) 1983-09-14 1987-05-07 Three Bond Co. Ltd. Acrylic photopolymerised micro-capsules
DE3333654A1 (de) 1983-09-17 1985-03-28 Cassella Ag, 6000 Frankfurt Verkapselte, in wasser schwerloesliche salze, ihre herstellung und ihre verwendung
US4515705A (en) 1983-11-14 1985-05-07 The Procter & Gamble Company Compositions containing odor purified proteolytic enzymes and perfumes
DE3346601C2 (de) 1983-12-23 1986-06-12 Feldmühle AG, 4000 Düsseldorf Mikrokapseln, Verfahren zu ihrer Herstellung und ihre Verwendung in druckempfindlichen kohlefreien Durchschreibepapieren
US4601863A (en) 1984-02-09 1986-07-22 Kanzaki Paper Manufacturing Co., Ltd. Process for producing powder of microcapsules
NL8401362A (nl) 1984-04-27 1985-11-18 Tno Werkwijze voor het met een polymeer omhullen van deeltjesvormige materialen teneinde de gereguleerde afgifte van deze materialen aan de omgeving mogelijk te maken alsmede aldus verkregen omhuld deeltjesvormig materiaal.
US4537707A (en) 1984-05-14 1985-08-27 The Procter & Gamble Company Liquid detergents containing boric acid and formate to stabilize enzymes
US4537706A (en) 1984-05-14 1985-08-27 The Procter & Gamble Company Liquid detergents containing boric acid to stabilize enzymes
JPS6187734A (ja) 1984-10-03 1986-05-06 Japan Synthetic Rubber Co Ltd 中空ポリマ−粒子の製造方法
USRE34584E (en) 1984-11-09 1994-04-12 The Procter & Gamble Company Shampoo compositions
CA1261276A (en) 1984-11-09 1989-09-26 Mark B. Grote Shampoo compositions
JPS61244366A (ja) 1985-04-23 1986-10-30 小林　健郎 薬効成分徐放性粉粒体
JPH0611396B2 (ja) 1985-07-17 1994-02-16 日本製紙株式会社 微小カプセルの製造方法
US4863626A (en) 1985-08-21 1989-09-05 The Clorox Company Encapsulated enzyme in dry bleach composition
ES2001074A6 (es) 1985-08-21 1988-04-16 Clorox Co Perfeccionamientos en la fabricacion de productos blanqueantes secos basados en diperacidos.
US5145675A (en) 1986-03-31 1992-09-08 Advanced Polymer Systems, Inc. Two step method for preparation of controlled release formulations
JPS62116506U (zh) 1986-01-14 1987-07-24
US4803947A (en) 1986-01-15 1989-02-14 Canon Kabushiki Kaisha Apparatus for forming deposited film
FR2599975B1 (fr) 1986-06-16 1994-06-17 Pointier Alain Produit diffuseur de parfum, absorbant d'odeurs, et extincteur pour cendriers
JPS63112190A (ja) 1986-10-30 1988-05-17 Fuji Photo Film Co Ltd 記録材料
US5370881A (en) 1987-04-20 1994-12-06 Fuisz Technologies Ltd. Water-soluble delivery systems for hydrophobic liquids
JPH0775666B2 (ja) 1987-05-08 1995-08-16 日本合成ゴム株式会社 カプセル化粒子の製造方法
JPH0421513Y2 (zh) 1987-06-23 1992-05-15
JPH0517338Y2 (zh) 1987-07-31 1993-05-10
GB8719091D0 (en) 1987-08-12 1987-09-16 Unilever Plc Skin treatment composition
US5225278A (en) 1987-08-26 1993-07-06 Rohm And Haas Company Process for microencapsulation
ATE176396T1 (de) 1987-10-22 1999-02-15 Procter & Gamble Chelatbildner enthaltende lichtschutzmittel
US4911851A (en) 1987-11-06 1990-03-27 The Procter & Gamble Company Detergent compatible, dryer released fabric softening/antistatic agents
GB9110408D0 (en) 1989-08-24 1991-07-03 Allied Colloids Ltd Polymeric compositions
JP2634836B2 (ja) 1988-01-29 1997-07-30 大王製紙株式会社 マイクロカプセルの製造方法
US4882220A (en) 1988-02-02 1989-11-21 Kanebo, Ltd. Fibrous structures having a durable fragrance
CA1303437C (en) 1988-02-29 1992-06-16 Nobuo Kawahashi Hollow polymer particles, process for production thereof, and use thereof as pigment
JPH01256965A (ja) 1988-04-07 1989-10-13 Toray Ind Inc 消臭剤およびそれからなる消臭性成形品
GB8808359D0 (en) 1988-04-09 1988-05-11 Kitty Little Ltd Deodorizing composition
JPH06361Y2 (ja) 1988-05-23 1994-01-05 株式会社吉野工業所 キャップ
US4919841A (en) 1988-06-06 1990-04-24 Lever Brothers Company Wax encapsulated actives and emulsion process for their production
US4824707A (en) 1988-06-27 1989-04-25 Donald Spector Decorative air freshener unit
US4968451A (en) 1988-08-26 1990-11-06 The Procter & Gamble Company Soil release agents having allyl-derived sulfonated end caps
US5856409A (en) 1989-04-07 1999-01-05 Dow Corning Corporation Method of making hydrophobic copolymers hydrophilic
JP2502146B2 (ja) 1989-04-12 1996-05-29 日本製紙株式会社 微小カプセルの製造方法
EP0471036B2 (en) 1989-05-04 2004-06-23 Southern Research Institute Encapsulation process
US5137646A (en) 1989-05-11 1992-08-11 The Procter & Gamble Company Coated perfume particles in fabric softener or antistatic agents
US5188753A (en) 1989-05-11 1993-02-23 The Procter & Gamble Company Detergent composition containing coated perfume particles
WO1991001801A1 (en) 1989-08-01 1991-02-21 Kanebo, Ltd. Microcapsule, treatment liquid containing microcapsules, and textile structure having microcapsules stuck thereto
US5104646A (en) 1989-08-07 1992-04-14 The Procter & Gamble Company Vehicle systems for use in cosmetic compositions
US5106609A (en) 1990-05-01 1992-04-21 The Procter & Gamble Company Vehicle systems for use in cosmetic compositions
US5071706A (en) 1989-08-31 1991-12-10 Eurand America, Incorporated Oily, free-flowing, microcapsules
US5066419A (en) 1990-02-20 1991-11-19 The Procter & Gamble Company Coated perfume particles
US5105823A (en) 1990-04-05 1992-04-21 Blum Alvin S Shielded replaceable lancet blade assembly
US5292835A (en) 1990-05-16 1994-03-08 Basf Aktiengesellschaft Microcapsules
US5234682A (en) 1990-06-21 1993-08-10 Revlon Consumer Products Corporation Cosmetic compositions
ATE132736T1 (de) 1990-06-21 1996-01-15 Revlon Consumer Prod Corp Kosmetische zubereitungen
GB9021061D0 (en) 1990-09-27 1990-11-07 Unilever Plc Encapsulating method and products containing encapsulated material
US5113585A (en) 1990-09-28 1992-05-19 The Gillette Company Shaving system
JP2555475B2 (ja) 1990-10-16 1996-11-20 工業技術院長 無機質微小球体の製造方法
JPH04156851A (ja) 1990-10-19 1992-05-29 Toyo Ink Mfg Co Ltd 消臭組成物
JP2526431Y2 (ja) 1990-11-14 1997-02-19 カルソニック株式会社 自動変速機用オイルクーラ
US5120349A (en) 1990-12-07 1992-06-09 Landec Labs, Inc. Microcapsule having temperature-dependent permeability profile
US5176903A (en) 1990-12-13 1993-01-05 Revlon Consumer Products Corporation Antiperspirant/deodorant containing microcapsules
EP0510761B1 (en) 1991-04-24 1995-03-08 Unilever N.V. Wax-encapsulated particles and method for making same
US5219887A (en) * 1991-06-07 1993-06-15 Minnesota Mining And Manufacturing Company Disinfecting shampoo composition for animals
EP0523287A1 (en) 1991-07-18 1993-01-20 The Procter & Gamble Company Perfume additives for fabric-softening compositions
US5232613A (en) 1991-08-28 1993-08-03 The Procter & Gamble Company Process for preparing protected particles of water sensitive material
US5234611A (en) 1991-08-28 1993-08-10 The Procter & Gamble Company Fabric softener, preferably liquid, with protected, dryer-activated, cyclodextrin/perfume complex
DE4130743A1 (de) 1991-09-16 1993-03-18 Bayer Ag Mikrokapseln aus isocyanaten mit polyethylenoxidhaltigen gruppen
GB9120952D0 (en) 1991-10-02 1991-11-13 Unilever Plc Perfume particles
WO1993008600A1 (en) 1991-10-15 1993-04-29 Velox Computer Technology, Inc. Intrinsically controlled cooling container
ES2091591T3 (es) 1991-12-20 1996-11-01 Procter & Gamble Un procedimiento para preparar una composicion de capsulas de perfume.
US5580578A (en) 1992-01-27 1996-12-03 Euro-Celtique, S.A. Controlled release formulations coated with aqueous dispersions of acrylic polymers
JP3104394B2 (ja) 1992-05-13 2000-10-30 日本製紙株式会社 微小カプセルの製造方法
US6325995B1 (en) 1992-09-21 2001-12-04 The Procter & Gamble Company Lipsticks compositions containing association structures
JPH0641576U (ja) 1992-11-16 1994-06-03 株式会社ナカツカ 敷 物
US6375872B1 (en) 1992-11-17 2002-04-23 Moore Business Forms Microencapsulated adhesive
JPH08506991A (ja) 1993-02-22 1996-07-30 クエスト・インターナショナル・ビー・ブイ 耐湿性組成物
FR2702961A1 (fr) 1993-03-26 1994-09-30 Couvreur Continental Dispositif de diffusion lente, régulière et prolongée d'une substance volatile telle qu'une substance aromatique.
WO1994023697A1 (en) 1993-04-22 1994-10-27 Depotech Corporation Cyclodextrin liposomes encapsulating pharmacologic compounds and methods for their use
DE4321205B4 (de) 1993-06-25 2006-06-29 Basf Ag Mikrokapseln, Verfahren zu ihrer Herstellung und ihre Verwendung
ES2149874T3 (es) 1993-07-22 2000-11-16 Pfizer Dispositivos osmoticos con revestimientos permeables al vapor.
US5366652A (en) 1993-08-27 1994-11-22 The Procter & Gamble Company Process for making high density detergent agglomerates using an anhydrous powder additive
US5486303A (en) 1993-08-27 1996-01-23 The Procter & Gamble Company Process for making high density detergent agglomerates using an anhydrous powder additive
US5681852A (en) 1993-11-12 1997-10-28 The Procter & Gamble Company Desquamation compositions
ATE212827T1 (de) 1993-11-12 2002-02-15 Procter & Gamble Abschuppende zusammensetzung von salicylsäure und zwitterionischen verbindungen
US5782409A (en) 1993-12-06 1998-07-21 Paul; Leonard Air freshening and deodorizing system
US5468473A (en) 1994-02-09 1995-11-21 Innova Products, Inc. Antiperspirant for hands and feet
IT1276525B1 (it) 1994-04-13 1997-10-31 Webcraft Technologies Inc Dispositivo e procedimento per la esposizione selettiva di liquidi microincapsulati.
US6531156B1 (en) 1994-04-15 2003-03-11 Temple University Aqueous solven encapsulation method, apparatus and microcapsules
JPH07305049A (ja) 1994-05-12 1995-11-21 Sekisui Chem Co Ltd 無機硬化性組成物および無機硬化体の製造方法
PE6995A1 (es) 1994-05-25 1995-03-20 Procter & Gamble Composicion que comprende un polimero de polialquilenoamina etoxilado propoxilado como agente de separacion de sucio
US5637401A (en) 1994-06-08 1997-06-10 Fragrance Technology Trust Odorant composition, delivery system and method
US5725869A (en) 1994-06-20 1998-03-10 Zeneca Limited Microsphere reservoirs for controlled release application
US6944952B1 (en) 1994-07-01 2005-09-20 The Gillette Company Shaving system
UA54371C2 (uk) 1994-07-01 2003-03-17 Дзе Джіллєт Компані Пристрій для вологого гоління, взаємодіючий зі шкірою елемент цього пристрою та спосіб виготовлення цього елемента
US6594904B1 (en) 1994-07-01 2003-07-22 The Gillette Company Shaving system
US5879584A (en) 1994-09-10 1999-03-09 The Procter & Gamble Company Process for manufacturing aqueous compositions comprising peracids
US5516448A (en) 1994-09-20 1996-05-14 The Procter & Gamble Company Process for making a high density detergent composition which includes selected recycle streams for improved agglomerate
US5691297A (en) 1994-09-20 1997-11-25 The Procter & Gamble Company Process for making a high density detergent composition by controlling agglomeration within a dispersion index
US5489392A (en) 1994-09-20 1996-02-06 The Procter & Gamble Company Process for making a high density detergent composition in a single mixer/densifier with selected recycle streams for improved agglomerate properties
US6298558B1 (en) 1994-10-31 2001-10-09 The Gillette Company Skin engaging member
US5534179A (en) 1995-02-03 1996-07-09 Procter & Gamble Detergent compositions comprising multiperacid-forming bleach activators
US5716938A (en) 1995-02-07 1998-02-10 Provitt; Robert Darnell Mattress freshener and room deodorizer composition
US5574005A (en) 1995-03-07 1996-11-12 The Procter & Gamble Company Process for producing detergent agglomerates from high active surfactant pastes having non-linear viscoelastic properties
US5569645A (en) 1995-04-24 1996-10-29 The Procter & Gamble Company Low dosage detergent composition containing optimum proportions of agglomerates and spray dried granules for improved flow properties
US6358577B1 (en) 1995-06-07 2002-03-19 Pechiney Emballage Flexible Europe Membrane permeable to aromatic products
US5702714A (en) 1995-06-07 1997-12-30 Goss; Louis Skin conditioner
US5597936A (en) 1995-06-16 1997-01-28 The Procter & Gamble Company Method for manufacturing cobalt catalysts
US5565422A (en) 1995-06-23 1996-10-15 The Procter & Gamble Company Process for preparing a free-flowing particulate detergent composition having improved solubility
US5607980A (en) 1995-07-24 1997-03-04 The Procter & Gamble Company Topical compositions having improved skin feel
US5576282A (en) 1995-09-11 1996-11-19 The Procter & Gamble Company Color-safe bleach boosters, compositions and laundry methods employing same
US5674478A (en) 1996-01-12 1997-10-07 The Procter & Gamble Company Hair conditioning compositions
US5750122A (en) 1996-01-16 1998-05-12 The Procter & Gamble Company Compositions for treating hair or skin
US5648328A (en) 1996-02-06 1997-07-15 The Procter & Gamble Company Process for producing a particulate laundry additive composition for perfume delivery
US5656584A (en) 1996-02-06 1997-08-12 The Procter & Gamble Company Process for producing a particulate laundry additive composition for perfume delivery
EP0824563B1 (en) 1996-03-04 2005-06-15 General Electric Company Silicone aminopolyalkyleneoxide block copolymers
US5723420A (en) 1996-03-04 1998-03-03 The Procter & Gamble Company Personal cleansing bar compositions which contain a fragrance-releasing complex for improved fragrance delivery
US5756436A (en) 1996-03-27 1998-05-26 The Procter & Gamble Company Conditioning shampoo compositions containing select cationic conditioning polymers
MA24137A1 (fr) 1996-04-16 1997-12-31 Procter & Gamble Fabrication d'agents de surface ramifies .
FR2747669B1 (fr) 1996-04-22 1998-05-22 Rhone Poulenc Chimie Procede de preparation de particules creuses de silice
AU3480597A (en) 1996-06-11 1998-01-07 Procter & Gamble Company, The Process for producing a particulate laundry additive for perfume delivery having improved physical properties
EP0904065A4 (en) 1996-06-14 2000-06-14 Emisphere Tech Inc MICRO-ENCLOSED FRAGRANCES AND PRODUCTION METHOD
US5783536A (en) 1996-06-26 1998-07-21 Lever Brothers Company, Division Of Conopco, Inc. Bar composition comprising additive for delivering benefit agent
EP0820762A1 (en) 1996-07-15 1998-01-28 Unilever Plc Perfume compositions
US5929022A (en) 1996-08-01 1999-07-27 The Procter & Gamble Company Detergent compositions containing amine and specially selected perfumes
EP0829259A1 (en) 1996-09-04 1998-03-18 Warner-Lambert Company Foam/gel with microbeads and/or fine particles
CA2265804A1 (en) 1996-09-18 1998-03-26 Athanasios Surutzidis Process for making particulate laundry additive composition
AU4985497A (en) 1996-10-25 1998-05-22 Mccormick & Company, Inc. Fat-coated encapsulation compositions and method for preparing the same
US6503495B1 (en) 1996-10-31 2003-01-07 The Procter & Gamble Company Cosmetic compositions having improved wear and beauty
DE19645024A1 (de) 1996-10-31 1998-05-07 Basf Ag Bleichhilfsmittel enthaltende Mikrokapseln
CA2275302A1 (en) 1996-12-17 1998-06-25 The Procter & Gamble Company Absorbent articles with odor control system
CA2277143C (en) 1996-12-23 2008-02-19 Ciba Specialty Chemicals Water Treatments Limited Particles having surface properties and methods of making them
JPH10195478A (ja) 1996-12-27 1998-07-28 Lion Corp 洗浄剤組成物
JP4021513B2 (ja) 1997-02-21 2007-12-12 水澤化学工業株式会社 超低嵩密度、高比表面積、高多孔性を有するアルミナ又はアルミナ水和物、その製造方法並びに用途
US5956848A (en) 1997-02-27 1999-09-28 The Gillette Company Shaving system
EP0973855B1 (en) 1997-03-07 2003-08-06 The Procter & Gamble Company Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acids
ES2245020T3 (es) 1997-03-07 2005-12-16 THE PROCTER & GAMBLE COMPANY Metodos mejorados de producir macropoliciclos con puente cruzado.
BR9701287A (pt) 1997-03-14 1998-11-10 Unilever Nv Composição de tratamento de tecidos na lavagem e processo para tratar tecidos para proporcionar aos mesmos propriedades de repelência à sujeira
EP0970179A1 (en) 1997-03-20 2000-01-12 The Procter & Gamble Company Laundry additive particle having multiple surface coatings
US6248364B1 (en) 1997-04-07 2001-06-19 3M Innovative Properties Company Encapsulation process and encapsulated products
US5833971A (en) 1997-06-16 1998-11-10 Baldwin; Stanley Perfumed rocks
IT1292371B1 (it) 1997-06-18 1999-02-08 Biofarm Srl Cerotto con microcapsule racchiudenti essenze e metodo per la sua preparazione
US5800805A (en) 1997-06-19 1998-09-01 Church & Dwight Co., Inc Aerosol deodorant product
US5945085A (en) 1997-06-19 1999-08-31 Church & Dwight Co., Inc. Aerosol deodorant-antiperspirant product
US6451754B1 (en) 1997-08-02 2002-09-17 The Procter & Gamble Company Process for preparing detergent tablet
IT1295289B1 (it) 1997-10-07 1999-05-04 Telos S R L Co-macinati per uso cosmetico e dermatologico
EP1024785B1 (en) 1997-10-24 2003-01-15 The Procter & Gamble Company Cleansing and conditioning article for skin or hair having improved fragrance delivery
EP1030734B1 (en) 1997-11-10 2003-08-06 Quest International B.V. Encapsulate of active material in alginate matrix
GB9803831D0 (en) 1998-02-25 1998-04-22 Cussons Int Ltd Washing composition
US6093411A (en) 1998-03-16 2000-07-25 The Procter & Gamble Company Compositions for regulating skin appearance
US6682749B1 (en) 1998-04-03 2004-01-27 Colgate-Palmolive Company Low Residue cosmetic composition
US6498135B1 (en) 1998-04-06 2002-12-24 Procter & Gamble Company Process for producing electrostatically coated non-particulate detergent product
US5962018A (en) 1998-04-28 1999-10-05 Avon Products, Inc. Method of treating the skin with organic acids in anhydrous microsphere delivery systems
US6207782B1 (en) 1998-05-28 2001-03-27 Cromption Corporation Hydrophilic siloxane latex emulsions
ATE367845T1 (de) 1998-06-15 2007-08-15 Procter & Gamble Riechstoffzusammensetzungen
US6800598B1 (en) 1998-07-29 2004-10-05 Reckitt Benckiser N.V. Composition for use in a dishwashing machine
GB9818782D0 (en) 1998-08-28 1998-10-21 Crosfield Joseph & Sons Granular compositions
DE19842766A1 (de) 1998-09-18 2000-03-23 Beiersdorf Ag Emulgatorfreie feindisperse Systeme vom Typ Öl-in-Wasser und Wasser-in-Öl
US20080113025A1 (en) 1998-11-02 2008-05-15 Elan Pharma International Limited Compositions comprising nanoparticulate naproxen and controlled release hydrocodone
US20090149479A1 (en) 1998-11-02 2009-06-11 Elan Pharma International Limited Dosing regimen
DK1126826T6 (en) 1998-11-02 2019-06-24 Alkermes Pharma Ireland Ltd Multiparticulate modified release of methylphenidate
US20070160675A1 (en) 1998-11-02 2007-07-12 Elan Corporation, Plc Nanoparticulate and controlled release compositions comprising a cephalosporin
US20080118556A1 (en) 1998-11-02 2008-05-22 Elan Corporation, Plc Modified Release of Compositions Containing a Combination of Carbidopa, Levodopa and Entacapone
US20070122481A1 (en) 1998-11-02 2007-05-31 Elan Corporation Plc Modified Release Compositions Comprising a Fluorocytidine Derivative for the Treatment of Cancer
US20060240105A1 (en) 1998-11-02 2006-10-26 Elan Corporation, Plc Multiparticulate modified release composition
US20080102121A1 (en) 1998-11-02 2008-05-01 Elan Pharma International Limited Compositions comprising nanoparticulate meloxicam and controlled release hydrocodone
FR2785530B1 (fr) 1998-11-09 2000-12-15 Oreal Composition cosmetique sans transfert comprenant une dispersion de particules de polymere et un agent rheologique particulier
US6294514B1 (en) 1998-11-24 2001-09-25 The Procter & Gamble Company Process for preparing mono-long chain amine oxide surfactants with low nitrite, nitrosamine and low residual peroxide
JP2002531457A (ja) 1998-11-30 2002-09-24 ザ、プロクター、エンド、ギャンブル、カンパニー 架橋テトラアザマクロサイクル類の製造方法
US6159485A (en) 1999-01-08 2000-12-12 Yugenic Limited Partnership N-acetyl aldosamines, n-acetylamino acids and related n-acetyl compounds and their topical use
WO2000041528A2 (en) 1999-01-14 2000-07-20 Amcol International Corporation Improved controlled release compositions and method
US6258857B1 (en) 1999-02-04 2001-07-10 Kyowa Industrial Co., Ltd. Internal liquid composition contained as internal liquid in a releasing container and releasing container product
EP1034705A3 (de) 1999-03-10 2001-02-28 Haarmann & Reimer Gmbh Einbettungsmittel und Verfahren zur Einbettung von Riech- und/oder Aromastoffen
FR2791992B1 (fr) 1999-04-12 2003-06-13 Rhodia Chimie Sa Systeme multi-particulaire vecteur de matiere(s) active(s), sa preparation et ses utilisations
US6488943B1 (en) 1999-04-13 2002-12-03 The Procter & Gamble Company Antimicrobial wipes which provide improved immediate germ reduction
US6767880B1 (en) 1999-04-19 2004-07-27 The Procter & Gamble Company Liquid dishwashing detergent composition having polymeric particles
DE19918265A1 (de) 1999-04-22 2000-10-26 Henkel Kgaa Abrasivstoffhaltiges Reinigungsmittel mit Mikrokapseln
DE19918267A1 (de) 1999-04-22 2000-10-26 Henkel Kgaa Handgeschirrspülmittel mit Mikrokapseln
JP2000309625A (ja) * 1999-04-26 2000-11-07 Toyo Ink Mfg Co Ltd 硬化性樹脂組成物
US6245733B1 (en) 1999-04-30 2001-06-12 James Mosbaugh Porous agglomerations of fused microspheres
US6649155B1 (en) 1999-05-03 2003-11-18 The Procter & Gamble Company Anti-dandruff and conditioning shampoos containing certain cationic polymers
AU3885199A (en) 1999-05-07 2000-11-21 Procter & Gamble Company, The Cosmetic compositions comprising cyclic oligosaccharide and fragrance
DE59912559D1 (de) 1999-07-02 2005-10-20 Cognis Ip Man Gmbh Mikrokapseln - III
DE19932144A1 (de) 1999-07-09 2001-01-11 Basf Ag Mikrokapselzubereitungen und Mikrokapseln enthaltende Wasch- und Reinigungsmittel
CN100360652C (zh) 1999-07-20 2008-01-09 宝洁公司 改进的包封的油颗粒
USD424745S (en) 1999-08-05 2000-05-09 The Gillette Company Shaving aid strip for razor cartridge
JP2001049287A (ja) 1999-08-06 2001-02-20 Yoshihiro Kusaka 香料組成物
US6348218B1 (en) 1999-10-04 2002-02-19 Invent Resources, Inc. Self dosing skin preparation
TR200200887T2 (tr) 1999-10-04 2002-08-21 Unilever N.V. Güzel koku parçacıkları içeren deterjan bileşimi.
TWI260315B (en) 1999-10-29 2006-08-21 Ciba Sc Holding Ag Polymorphic forms of sertraline hydrochloride
US20050119351A1 (en) 1999-10-29 2005-06-02 Van Der Schaaf Paul A. Polymorphic forms of sertraline hydrochloride
US7442838B2 (en) 1999-10-29 2008-10-28 Ciba Specialty Chemicals Corp. Polymorphic forms of sertraline hydrochloride
US6790814B1 (en) 1999-12-03 2004-09-14 Procter & Gamble Company Delivery system having encapsulated porous carrier loaded with additives, particularly detergent additives such as perfumes
FR2801811B1 (fr) 1999-12-06 2002-05-03 Gerard Habar Procede de fabrication de microcapsules portant des charges cationiques
US6235274B1 (en) 1999-12-21 2001-05-22 International Flavors & Fragrances Inc. Microparticles which controllably release olfactorily active substances, methods of using same and processes for preparing same
DE10000223A1 (de) 2000-01-05 2001-07-12 Basf Ag Mikrokapselzubereitungen und Mikrokapseln enthaltende Wasch- und Reinigungsmittel
US6780507B2 (en) 2000-02-09 2004-08-24 Analytical Research Systems, Inc. Hydrocapsules and method of preparation thereof
WO2001062376A1 (de) 2000-02-23 2001-08-30 Henkel Kommanditgesellschaft Auf Aktien Mikro- und/oder nanokapseln
EP1259268A1 (en) 2000-02-25 2002-11-27 James Mosbaugh Method of shaping porous agglomerations of fused microspheres
DE10012063A1 (de) 2000-03-14 2001-09-20 Basf Ag Weichkapseln enthaltend Polymerisate von Vinylestern und Polyethern, deren Verwendung und Herstellung
DE10015468A1 (de) 2000-03-29 2001-10-11 Basf Ag Hartkapseln, enthaltend Polymerisate und Vinylestern und Polyethern, deren Verwendung und Herstellung
CN1422144A (zh) * 2000-03-31 2003-06-04 宝洁公司 用于增加体积的包含微球的免洗型美发组合物
DE60129427T3 (de) 2000-05-11 2014-07-24 The Procter & Gamble Company Hochkonzentrierte wäscheweichspülerzusammensetzungen und diese enthaltende mittel
US20030104969A1 (en) 2000-05-11 2003-06-05 Caswell Debra Sue Laundry system having unitized dosing
US7208463B2 (en) 2000-06-02 2007-04-24 The Procter & Gamble Company Fragrance compositions
ES2248340T3 (es) 2000-06-05 2006-03-16 Syngenta Limited Nuevas microcapsulas.
DE10027634A1 (de) 2000-06-06 2001-12-13 Basf Ag Verwendung von kationisch modifizierten, teilchenförmigen, hydrophoben Polymeren als Zusatz zu Spül- oder Pflegemitteln für Textilien und als Zusatz zu Waschmitteln
DE10031132A1 (de) 2000-06-30 2002-01-17 Henkel Kgaa Verfahren zur Herstellung aktivstoffhaltiger Kapseln mit ultradünner Wandschicht
US20020016269A1 (en) 2000-07-06 2002-02-07 The Procter & Gamble Co. Particle perfume delivery system
US6696049B2 (en) 2000-07-10 2004-02-24 The Procter & Gamble Company Cosmetic compositions
US7041767B2 (en) 2000-07-27 2006-05-09 Ge Bayer Silicones Gmbh & Co. Kg Polysiloxane polymers, method for their production and the use thereof
ES2227271T3 (es) 2000-07-27 2005-04-01 GE BAYER SILICONES GMBH & CO. KG Compuestos de poliamonio-polisiloxano, procedimiento para su produccion y su uso.
CA2385221C (en) 2000-09-06 2011-01-11 Appleton Papers Inc. In situ microencapsulated adhesive
US7407650B2 (en) 2000-10-27 2008-08-05 The Procter & Gamble Company Fragrance compositions
US7413731B2 (en) 2000-10-27 2008-08-19 The Procter And Gamble Company Fragrance compositions
EP1201743A1 (en) 2000-10-31 2002-05-02 The Procter & Gamble Company Detergent compositions
US7208465B2 (en) 2000-11-03 2007-04-24 The Procter & Gamble Company Methods and compositions for improved fragrancing of a surface
DE10062585A1 (de) 2000-12-15 2002-06-27 Henkel Kgaa Teilchenförmiges Additiv für Wasch- und Reinigungsmittel
US6864223B2 (en) 2000-12-27 2005-03-08 Colgate-Palmolive Company Thickened fabric conditioners
DE10064878A1 (de) 2000-12-27 2002-07-04 Cognis Deutschland Gmbh Verkapselung von Emulsionen
GB0104698D0 (en) 2001-02-26 2001-04-11 Syngenta Ltd Process for producing microcapsules
DE10112441A1 (de) 2001-03-15 2002-09-19 Degussa Kieselsäure durch Fällung mit konstanter Alkalizahl und deren Verwendung
ES2238353T3 (es) 2001-03-22 2005-09-01 Cognis Ip Management Gmbh Microcapsulas.
DE50105243D1 (de) 2001-03-22 2005-03-10 Cognis Iberia Sl Mikrokapseln (VIII)
WO2002076479A1 (en) 2001-03-27 2002-10-03 Bime Laboratories Composition for treating acne vulgaris and fabrication method
US7230750B2 (en) 2001-05-15 2007-06-12 E Ink Corporation Electrophoretic media and processes for the production thereof
EP1247568A1 (de) 2001-04-03 2002-10-09 Primacare S.L., c/o Cognis Iberica S.L. Mikrokapseln (XIII)
GB2374082A (en) 2001-04-04 2002-10-09 Procter & Gamble Particles for a detergent product
MXPA03010130A (es) 2001-05-04 2004-03-10 Procter & Gamble Composiciones modificadoras del ambiente, articulos que las contienen y metodos.
JP2002326904A (ja) 2001-05-08 2002-11-15 Shiseido Co Ltd 粉末状化粧料
US7241835B2 (en) 2001-05-16 2007-07-10 General Electric Company Cosmetic compositions comprising silicone gels
US20030203978A1 (en) 2001-05-16 2003-10-30 O'brien Michael Joseph Cosmetic compositions comprising silicone gels comprising entrapped, occluded or encapsulated pigments
US20030031722A1 (en) 2001-06-04 2003-02-13 Hongjie Cao Starch-oil composites for use in personal care applications
US7270828B2 (en) 2001-06-20 2007-09-18 The Procter & Gamble Company Personal care composition comprising hydrophobic gel
GB0115681D0 (en) 2001-06-27 2001-08-22 Ciba Spec Chem Water Treat Ltd Process for making polymeric particles
WO2003005986A1 (en) 2001-07-11 2003-01-23 Unilever Plc Hair treatment compositions
US6881482B2 (en) 2001-08-16 2005-04-19 Southwest Research Institute Microencapsulation using electromagnetic energy and core and shell materials with different dielectric constants and dissipation factors
DE60209804T2 (de) 2001-08-20 2006-08-17 Unilever N.V. Photobleichsprenkel und sie enthaltende waschmittel
US7211273B2 (en) 2001-08-28 2007-05-01 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Detergent or personal care composition with oil capsules
GB0121176D0 (en) 2001-08-31 2001-10-24 Unilever Plc Perfumed coloured speckle composition and particulate laundry detergent compositions containing it
US6982256B2 (en) 2001-09-07 2006-01-03 Boehringer Ingelheim Pharma Kg Tolerance of 4-(4-(2-pyrrolylcarbonyl)-1-piperazinyl)-3-trifluoromethyl-benzoylguanidine in intravenous administration
JP4082558B2 (ja) 2001-09-21 2008-04-30 株式会社リコー 摩擦駆動装置
CN1558747A (zh) 2001-10-03 2004-12-29 包含阳离子聚合物和颗粒的洗发剂
US7186679B2 (en) 2001-10-11 2007-03-06 Hair Systems, Inc. Stabilization of fragrances in salt mixtures by dual encapsulation and entrapment
US20030077378A1 (en) 2001-10-22 2003-04-24 Lou Wen Chin Hydroxypropyl cellulose encapsulation material
US6607717B1 (en) 2001-10-24 2003-08-19 Dow Corning Corporation Silicon based quaternary ammonium functional compositions and their applications
US6482969B1 (en) 2001-10-24 2002-11-19 Dow Corning Corporation Silicon based quaternary ammonium functional compositions and methods for making them
FR2831802B1 (fr) 2001-11-08 2004-10-15 Oreal Compositions cosmetiques contenant une silicone aminee et un agent epaississant et leurs utilisations
AU2002347442A1 (en) 2001-11-22 2003-06-10 Firmenich Sa Perfuming or flavouring microcapsules comprising a fireproofing agent
DE10163142A1 (de) 2001-12-20 2003-07-10 Henkel Kgaa Polymere Duftkapseln und ihre Herstellung
US20040138088A1 (en) 2002-01-09 2004-07-15 Croda, Inc. Immidazoline quats
US20030186834A1 (en) 2002-01-09 2003-10-02 Croda, Inc. Immidazoline quats
US7799421B2 (en) 2002-02-14 2010-09-21 Akzo Nobel N.V. Controlled release materials
US6806249B2 (en) 2002-02-28 2004-10-19 Unilever Home & Personal Care Usa, A Division Of Conopco Perfume containing surfactant compositions having perfume burst when diluted
US6797683B2 (en) 2002-03-04 2004-09-28 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Ordered liquid crystalline cleansing composition with benefit agent particles
JP4156851B2 (ja) 2002-03-22 2008-09-24 オリンパス株式会社 マイクロダイセクション装置
US7419947B2 (en) 2002-03-27 2008-09-02 Novozymes A/S Process for preparing granules with filamentous coatings
US7053034B2 (en) 2002-04-10 2006-05-30 Salvona, Llc Targeted controlled delivery compositions activated by changes in pH or salt concentration
US20030194416A1 (en) 2002-04-15 2003-10-16 Adl Shefer Moisture triggered release systems comprising aroma ingredients providing fragrance burst in response to moisture
US20040175404A1 (en) 2002-04-15 2004-09-09 Adi Shefer Moisture triggered sealed release system
US20030199412A1 (en) 2002-04-17 2003-10-23 Gargi Gupta Fragrance containing cleaning product
US20030216488A1 (en) 2002-04-18 2003-11-20 The Procter & Gamble Company Compositions comprising a dispersant and microcapsules containing an active material
US20030215417A1 (en) 2002-04-18 2003-11-20 The Procter & Gamble Company Malodor-controlling compositions comprising odor control agents and microcapsules containing an active material
US7192599B2 (en) 2002-06-03 2007-03-20 Mmp, Inc. Mattifying oil-in-water emulsion
US20080206355A1 (en) 2002-06-04 2008-08-28 The Procter & Gamble Company Composition comprising a particulate zinc material, a pyrithione or a polyvalent metal salt of a pyrithione and a synthetic cationic polymer
ATE477042T1 (de) 2002-06-12 2010-08-15 Traptek Llc Verkapselte aktive teilchen und verfahren für ihre herstellung und verwendung
US7235261B2 (en) 2002-06-27 2007-06-26 Haarmann & Reimer Corporation Controlled release encapsulation
ES2280763T3 (es) 2002-06-27 2007-09-16 Unilever N.V. Composicion de perfume.
WO2004006967A1 (en) 2002-07-11 2004-01-22 Firmenich Sa Composition of controlled release of perfumes and flavours
US6846785B2 (en) 2002-07-31 2005-01-25 The Dial Corporation Liquid soap with vitamin beads and method for making same
MXPA05001299A (es) 2002-08-02 2005-04-28 Gillette Co Composiciones claras para cuidado personal que contienen capsulas visibles.
MX276989B (es) 2002-08-14 2010-06-30 Quest Int Serv Bv Composiciones que comprenden material encapsulado.
GB0220580D0 (en) 2002-09-04 2002-10-09 Unilever Plc Hair treatment composition
WO2004022220A1 (en) 2002-09-04 2004-03-18 Southwest Research Institute Microencapsulation of oxygen or water sensitive materials
JP2004099743A (ja) 2002-09-10 2004-04-02 T Hasegawa Co Ltd カプセル化香料およびその用途
US20040071742A1 (en) 2002-10-10 2004-04-15 Popplewell Lewis Michael Encapsulated fragrance chemicals
BR0303954A (pt) 2002-10-10 2004-09-08 Int Flavors & Fragrances Inc Composição, fragrância, método para divisão de uma quantidade efetiva olfativa de fragrância em um produto sem enxague e produto sem enxague
US7125835B2 (en) 2002-10-10 2006-10-24 International Flavors & Fragrances Inc Encapsulated fragrance chemicals
US7585824B2 (en) 2002-10-10 2009-09-08 International Flavors & Fragrances Inc. Encapsulated fragrance chemicals
US20040091445A1 (en) 2002-11-01 2004-05-13 The Procter & Gamble Company Rinse-off personal care compositions comprising cationic perfume polymeric particles
US7524807B2 (en) 2002-11-01 2009-04-28 The Procter & Gamble Company Rinse-off personal care compositions comprising anionic and/or nonionic perfume polymeric particles
US20040109920A1 (en) 2002-12-04 2004-06-10 Bioactives Llc Coated carotenoid cyclodextrin complexes
BR0205449A (pt) 2002-12-09 2006-03-07 Biolab Sanus Farmaceutica Ltda composições farmacêuticas de peptìdeos, secretados pelas glándulas do veneno de serpentes, particurlamente da bothrops jararaca, inibidores de vasopeptidases, evasins, seus análogos, derivaados e produtos associados para o desenvolvimento de aplicações e uso em doenças crÈnico-degenerativas
AU2003211300A1 (en) 2003-01-07 2004-07-29 Hanjin Printing And Chemical Co., Ltd. Deodorizing film of sanitary absorbent
GB0300808D0 (en) 2003-01-14 2003-02-12 Unilever Plc Home and personal care compositions with lubricants
EP1604011A4 (en) 2003-01-21 2009-12-09 Ptc Therapeutics Inc METHODS FOR IDENTIFYING COMPOUNDS THAT MODULATE THE EXPRESSION OF DEPENDENT GENES FROM A NON-TRANSLATED REGION, AND METHODS OF USING SAME
US8426194B2 (en) 2003-01-21 2013-04-23 Ptc Therapeutics, Inc. Methods and agents for screening for compounds capable of modulating VEGF expression
US9068234B2 (en) 2003-01-21 2015-06-30 Ptc Therapeutics, Inc. Methods and agents for screening for compounds capable of modulating gene expression
EP1443058A1 (en) 2003-01-29 2004-08-04 Firmenich Sa Polymeric particles and fragrance delivery systems
WO2004075933A2 (en) 2003-02-26 2004-09-10 Lavipharm S.A. Devices for releasing volatile substances and methods of producing the devices
US7293719B2 (en) 2003-02-28 2007-11-13 American Covers, Inc. Air freshener and method
US7137570B2 (en) 2003-02-28 2006-11-21 American Covers, Inc. Air freshener and method
US20050169793A1 (en) 2003-02-28 2005-08-04 American Covers, Inc. Air freshener and method
US20040175347A1 (en) 2003-03-04 2004-09-09 The Procter & Gamble Company Regulation of mammalian keratinous tissue using hexamidine compositions
US20040208902A1 (en) 2003-04-18 2004-10-21 Gupta Shyam K. Controlled-release nano-diffusion delivery systems for cosmetic and pharmaceutical compositions
US20060127430A1 (en) 2003-04-18 2006-06-15 Bioderm Research Controlled-Release of Cosmetic and Pharmaceutical Agents via Osmotic Nano-Diffusion from Zeolite Cage Complexes
ES2431836T3 (es) 2003-04-23 2013-11-28 The Procter & Gamble Company Una composición que comprende un polímero catiónico potenciador de la deposición superficial
DE10319738A1 (de) 2003-04-30 2004-11-18 Basf Ag Verfahren zur Herstellung von wässrigen Dispersionen von Polyelektrolytkomplexen und ihre Verwendung zur Erhöhung der Naßfestigkeit von Papier, Pappe und Karton
PL1622576T3 (pl) 2003-05-07 2007-06-29 Firmenich & Cie Perfumy do rozpylania o ulepszonej adhezyjności
US20050014674A1 (en) 2003-05-28 2005-01-20 L'oreal Cosmetic compositions for making up and/or caring for skin
EP2263788B1 (en) 2003-07-31 2018-07-25 Sol-Gel Technologies Ltd. A process for the preparation of microcapsules filled with active ingredients
EP1502646B1 (en) 2003-08-01 2016-07-13 The Procter & Gamble Company Microcapsules
US20050038188A1 (en) 2003-08-14 2005-02-17 Dongchan Ahn Silicones having improved chemical resistance and curable silicone compositions having improved migration resistance
US7226607B2 (en) 2003-09-11 2007-06-05 The Procter & Gamble Company Compositions comprising a dispersant and microcapsules containing an active material and a stabilizer
US20060263898A1 (en) 2003-10-29 2006-11-23 Walter Paget Perfume delivery systems based on inorganic nano particles
JP2007511625A (ja) 2003-10-29 2007-05-10 フイルメニツヒ　ソシエテ　アノニム 無機物ナノ粒子に基づく香料送達系
EP1711231A1 (en) 2003-10-31 2006-10-18 Firmenich Sa Fragrance delivery system for surface cleaners and conditioners
EP1687261A4 (en) 2003-11-12 2007-09-05 Flexitral Inc NEW OXYNITRILE
US20050112152A1 (en) 2003-11-20 2005-05-26 Popplewell Lewis M. Encapsulated materials
US20050113282A1 (en) 2003-11-20 2005-05-26 Parekh Prabodh P. Melamine-formaldehyde microcapsule slurries for fabric article freshening
US7105064B2 (en) 2003-11-20 2006-09-12 International Flavors & Fragrances Inc. Particulate fragrance deposition on surfaces and malodour elimination from surfaces
EP1541121B1 (en) 2003-12-11 2007-03-21 Rohm And Haas Company System and process for releasing encapsulated active ingredients
DE10358799A1 (de) 2003-12-12 2005-07-14 Basf Ag Verwendung von wasserdispergierbaren Copolymerisaten von Hydroxyalkyl(meth)acrylaten zur Herstellung von Hartkapseln
US20050129759A1 (en) 2003-12-16 2005-06-16 Milan Sojka Sustained release compositions and controlled delivery method
JP2005194308A (ja) 2003-12-26 2005-07-21 Mitsubishi Chemicals Corp 徐放性香料担体及びそれを用いた徐放性香料
US7399324B2 (en) 2004-01-29 2008-07-15 Camovision Of Georgia, Llc Active agent delivery device
US7311900B2 (en) 2004-02-11 2007-12-25 Belle-Aire Fregrances, Inc. Gel/air freshener system
US7452547B2 (en) 2004-03-31 2008-11-18 Johnson&Johnson Consumer Co., Inc. Product for treating the skin comprising a polyamine microcapsule wall and a skin lightening agent
WO2005097197A1 (de) 2004-04-05 2005-10-20 Basf Aktiengesellschaft Wirkstoffhaltige polymerteilchen
US20050227907A1 (en) 2004-04-13 2005-10-13 Kaiping Lee Stable fragrance microcapsule suspension and process for using same
US20050226900A1 (en) 2004-04-13 2005-10-13 Winton Brooks Clint D Skin and hair treatment composition and process for using same resulting in controllably-releasable fragrance and/or malodour counteractant evolution
US7211556B2 (en) 2004-04-15 2007-05-01 Colgate-Palmolive Company Fabric care composition comprising polymer encapsulated fabric or skin beneficiating ingredient
DE102004020400A1 (de) 2004-04-23 2005-11-17 Henkel Kgaa Parfümierte Feststoffe
EP1600151B1 (en) 2004-04-29 2008-08-13 Kao Corporation Perfume particles and a process for preparing the same
US20050276831A1 (en) 2004-06-10 2005-12-15 Dihora Jiten O Benefit agent containing delivery particle
DK1781752T3 (da) 2004-08-10 2013-01-14 Basf Se Grovkornet mikrokapselmiddel
EP1637188A1 (en) 2004-08-20 2006-03-22 Firmenich Sa Improved liquid/sprayable compositions comprising fragranced aminoplast capsules
GB0419268D0 (en) 2004-08-31 2004-09-29 Givaudan Sa Organic compounds
WO2006027664A2 (en) 2004-09-08 2006-03-16 Firmenich Sa Process for producing nano-capsules containing a fragrance
EP1814924A2 (en) 2004-10-08 2007-08-08 Firmenich Sa Amphiphilic star block copolymers
EP1655344A1 (en) 2004-11-05 2006-05-10 The Procter & Gamble Company Polymeric compositions for sustained release of volatile materials
US20060099167A1 (en) 2004-11-05 2006-05-11 Staudigel James A Personal care composition containing a non-guar galactomannan polymer derivative
EP1661977A1 (en) 2004-11-29 2006-05-31 The Procter & Gamble Company Detergent compositions
WO2006069061A1 (en) 2004-12-21 2006-06-29 Degussa Gmbh Perfume delivery system
WO2006070578A1 (ja) 2004-12-28 2006-07-06 Qualicaps Co., Ltd. 硬カプセルのバンドシール
DE102005002411A1 (de) 2005-01-18 2006-07-27 Basf Ag Grobteilige Mikrokapselzubereitung
US20060165740A1 (en) 2005-01-24 2006-07-27 Goldschmidt Chemical Corporation Perfume delivery system
US20060166855A1 (en) 2005-01-25 2006-07-27 Howard Murad Fragrance delivery system
FR2881048B1 (fr) 2005-01-27 2009-07-17 Laggridore Soc Par Actions Sim Composition parfumante sous forme compactee
FR2881959B1 (fr) 2005-02-14 2007-04-06 Monique Cervilla Composition parfumee a diffusion controlee
US20070298061A1 (en) 2005-02-25 2007-12-27 Cadbury Adams Usa Llc Process for manufacturing a delivery system for active components as part of an edible compostion
EP1702674A1 (en) 2005-03-16 2006-09-20 Cognis IP Management GmbH Visible beads
US20070207174A1 (en) 2005-05-06 2007-09-06 Pluyter Johan G L Encapsulated fragrance materials and methods for making same
US20060248665A1 (en) 2005-05-06 2006-11-09 Pluyter Johan G L Encapsulated fragrance materials and methods for making same
US20060275237A1 (en) 2005-05-09 2006-12-07 Bissett Donald L Skin care compositions containing idebenone
US20060258557A1 (en) 2005-05-11 2006-11-16 Popplewell Lewis M Hard surface cleaning compositions and methods for making same
US7575633B2 (en) 2005-05-17 2009-08-18 Nordson Corporation Fluid dispenser with positive displacement pump
US20060263311A1 (en) 2005-05-19 2006-11-23 Scavone Timothy A Consumer noticeable improvement in wetness protection using solid antiperspirant compositions
US20060292098A1 (en) 2005-05-19 2006-12-28 Scavone Timothy A Consumer noticeable improvement in wetness protection
US8632755B2 (en) 2005-05-19 2014-01-21 The Procter & Gamble Company Consumer noticeable improvement in wetness protection
US8147808B2 (en) 2005-05-19 2012-04-03 The Procter & Gamble Company Consumer noticeable improvement in wetness protection using solid antiperspirant compositions
WO2006127454A2 (en) 2005-05-23 2006-11-30 Appleton Papers Inc. Oil-in-water capsule manufacture process and microcapsules produced by such process
WO2006132863A1 (en) 2005-06-03 2006-12-14 Isp Investments Inc. Fragrance delivery system
US20070041929A1 (en) 2005-06-16 2007-02-22 Torgerson Peter M Hair conditioning composition comprising silicone polymers containing quaternary groups
DE102005029777A1 (de) 2005-06-24 2007-01-04 Henkel Kgaa Rückstandsarmer Deodorant- oder Antitranspirant-Stift auf Basis einer ethanolhaltigen Öl-in-Wasser-Dispersion
FR2887886B1 (fr) 2005-07-01 2010-01-08 Oreal Polymere cationique neutralise, composition le comprenant et procede de traitement cosmetique
WO2007031872A2 (en) 2005-07-13 2007-03-22 L'oréal Keratin fibre coating composition comprising a liquid fatty phase and a tackifying resin
EP1745770A1 (fr) 2005-07-13 2007-01-24 L'Oréal Produit cosmétique bicouche, ses utilisations et kit de maquillage contenant ce produit
US20070048339A1 (en) 2005-08-31 2007-03-01 Popplewell Lewis M Structured materials
US20070286904A1 (en) 2005-08-31 2007-12-13 Popplewell Lewis M Structured materials
GB0518059D0 (en) 2005-09-06 2005-10-12 Dow Corning Delivery system for releasing active ingredients
US20080213451A1 (en) 2005-09-12 2008-09-04 Miharu Ogura Flavor Composition or Fragrance Composition, and Flavor-Improving Agents
US20070071781A1 (en) 2005-09-19 2007-03-29 Nelson Technologies, Inc. Compositions for rupturable capsules and methods of making the same
US20070071978A1 (en) * 2005-09-23 2007-03-29 Sojka Milan F Cosmetic Composition Containing Thermoplastic Microspheres and Skin Beneficial Agents
US20080226575A1 (en) 2005-09-30 2008-09-18 Avon Products, Inc. Long-Lasting Cosmetic Composition, Method For Using, and Process For Making
US20070078071A1 (en) 2005-09-30 2007-04-05 Kaiping Lee Spray dry capsule products and methods for preparing and using same
JP2009514660A (ja) 2005-10-28 2009-04-09 ソーラーブレ， インコーポレイテッド 光−応答性マイクロカプセル化物質、組成物およびそれらの使用方法
EP1951068A1 (en) 2005-11-11 2008-08-06 Firmenich S.A. Flavour and/or fragrance capsules
GB0524659D0 (en) 2005-12-02 2006-01-11 Unilever Plc Improvements relating to fabric treatment compositions
US20070134411A1 (en) 2005-12-14 2007-06-14 General Electric Company Method for making compositions containing microcapsules and compositions made thereof
US20070138672A1 (en) 2005-12-15 2007-06-21 Kaiping Lee Process for preparing a high stability microcapsule product and method for using same
US20070138671A1 (en) 2005-12-15 2007-06-21 Anastasiou Theodore J Encapsulated active material with reduced formaldehyde potential
US20070138673A1 (en) 2005-12-15 2007-06-21 Kaiping Lee Process for Preparing a High Stability Microcapsule Product and Method for Using Same
US20070138674A1 (en) 2005-12-15 2007-06-21 Theodore James Anastasiou Encapsulated active material with reduced formaldehyde potential
US9427391B2 (en) 2006-01-09 2016-08-30 The Procter & Gamble Company Personal care compositions containing cationic synthetic copolymer and a detersive surfactant
EP1989283A2 (en) 2006-02-28 2008-11-12 The Procter and Gamble Company Compositions comprising benefit agent containing delivery particles
US20080027575A1 (en) 2006-04-21 2008-01-31 Jones Stevan D Modeling systems for health and beauty consumer goods
WO2007128326A1 (en) 2006-05-03 2007-11-15 Evonik Goldschmidt Gmbh Perfume delivery system for cleaners
US20070286837A1 (en) 2006-05-17 2007-12-13 Torgerson Peter M Hair care composition comprising an aminosilicone and a high viscosity silicone copolymer emulsion
US7985445B2 (en) 2006-05-18 2011-07-26 Appleton Papers Inc. Water-in-oil capsule manufacture process and microcapsules produced by such process
BRPI0711486B8 (pt) 2006-05-19 2021-05-25 Firmenich & Cie processo de secagem por atomização de uma etapa
GB0610562D0 (en) 2006-05-30 2006-07-05 Givaudan Sa Microcapsules
BRPI0713595A2 (pt) 2006-06-13 2012-10-30 Givaudan Sa composições de encapsulamento
AU2007269428A1 (en) 2006-06-30 2008-01-10 Colgate-Palmolive Company Cationic polymer stabilized microcapsule composition
WO2008006762A2 (de) 2006-07-13 2008-01-17 Basf Se Polyelektrolyt-modifizierte mikrokapseln
US20080091573A1 (en) 2006-10-11 2008-04-17 Jonathan Shelon Controlled Depletion of a Stochastically Varying Resource Pool
WO2008046839A1 (de) * 2006-10-17 2008-04-24 Basf Se Mikrokapseln
US20080107615A1 (en) 2006-11-08 2008-05-08 L'oreal Detackified compositions
ES2429168T3 (es) 2006-11-14 2013-11-13 Sociedad Anónima Minera Catalano-Aragonesa Proceso para la aditivación de fibras sintéticas, fibras artificiales y polímeros con propiedades especiales
MX2009005006A (es) 2006-11-17 2009-05-20 Ciba Holding Inc Microcapsulas, su uso y procesos para su fabricacion.
GB0623110D0 (en) 2006-11-21 2006-12-27 Ciba Sc Holding Ag Microcapules, their use and processes for their manufacture
US20100061954A1 (en) 2006-11-28 2010-03-11 Gerald Adams Hair treatment compositions
US8129327B2 (en) 2006-12-01 2012-03-06 The Procter & Gamble Company Packaging for high moisture bar soap
DE102006058253A1 (de) 2006-12-08 2008-06-19 Cavis Microcaps Gmbh Mikrokapsel zur Freisetzung von Stoffen durch Extraktion
US7833960B2 (en) 2006-12-15 2010-11-16 International Flavors & Fragrances Inc. Encapsulated active material containing nanoscaled material
JP2008156565A (ja) 2006-12-26 2008-07-10 Lion Corp 洗濯用添加剤粒子とその製造方法および、これを含む衣料用洗剤
BRPI0807098A2 (pt) 2007-02-15 2014-04-29 Procter & Gamble Composições para liberação de agente de benefício
DE102007010109A1 (de) 2007-02-28 2008-09-04 Henkel Ag & Co. Kgaa Wirkstoffträgersysteme
US8741316B2 (en) 2007-03-12 2014-06-03 Board Of Regents, The University Of Texas System Highly porous, recognitive polymer systems
US8771713B2 (en) 2007-03-12 2014-07-08 Board Of Regents, The University Of Texas System Method and process for the production of multi-coated recognitive and releasing systems
WO2008112826A1 (en) 2007-03-12 2008-09-18 Board Of Regents, The University Of Texas System Method and process for the production of multi-coated recognitive and releasing systems
US8821899B2 (en) 2007-03-12 2014-09-02 Board Of Regents, The University Of Texas System Method and process for the production of multi-coated recognitive and releasing systems
US8349300B2 (en) 2007-04-19 2013-01-08 The Procter & Gamble Company Personal care compositions containing at least two cationic polymers and an anionic surfactant
WO2008129028A1 (en) 2007-04-24 2008-10-30 Unilever Plc Perfumed dispensing device
US8470762B2 (en) 2007-05-31 2013-06-25 Colgate-Palmolive Company Fabric softening compositions comprising polymeric materials
GB0710369D0 (en) 2007-06-01 2007-07-11 Unilever Plc Improvements relating to perfume particles
US20080311064A1 (en) 2007-06-12 2008-12-18 Yabin Lei Higher Performance Capsule Particles
US20080317788A1 (en) 2007-06-22 2008-12-25 Rafael Louzan Garcia Additive for Domestic Washing Processes
US7538077B2 (en) 2007-06-26 2009-05-26 Conopco, Inc. Extruded personal washing bars with plate-like polymeric inclusions
US20090029900A1 (en) 2007-07-27 2009-01-29 The Procter & Gamble Company Personal care article for sequentially dispensing compositions with distinct fragrance characters
US20090324660A1 (en) 2007-07-27 2009-12-31 Jonathan Robert Cetti Personal-care article for sequentially dispensing compositions with different fragrances
US20090035365A1 (en) 2007-07-30 2009-02-05 Lewis Michael Popplewell Density Controlled Capsule Particles and Methods of Making the Same
JP5101202B2 (ja) 2007-08-02 2012-12-19 太陽化学株式会社 球状メソ多孔体
CN101088567A (zh) 2007-08-03 2007-12-19 梁小江 防潮除臭剂及其制备方法
US20090053165A1 (en) 2007-08-20 2009-02-26 Mark Anthony Brown Method for Treating Damaged Hair
GB0718300D0 (en) 2007-09-20 2007-10-31 Univ Leeds Microcapsules and methods
GB0718532D0 (en) 2007-09-22 2007-10-31 Unilever Plc Improvements relating to fabric treatment compositions
CN101821373A (zh) 2007-10-12 2010-09-01 荷兰联合利华有限公司 含对比薄片状视觉提示的粒状去污剂组合物
WO2009080695A1 (en) 2007-12-21 2009-07-02 Akzo Nobel N.V. Compositions for protection and release of active materials
KR101415994B1 (ko) 2007-12-27 2014-07-08 (주)아모레퍼시픽 카로티노이드를 안정화한 이중층 구조의 고분자 캡슐, 그 제조 방법 및 이를 함유하는 화장료 조성물
KR101658938B1 (ko) 2008-01-15 2016-09-22 바스프 에스이 방출 거동이 향상된 향기 포함 마이크로캡슐
WO2009090617A2 (en) 2008-01-18 2009-07-23 The Procter & Gamble Company Concentrated personal cleansing compositions
KR100982275B1 (ko) 2008-01-28 2010-09-15 이대희 지방산 은 및 유기산 은 화합물이 함유된 방향제 조성물
FR2926978B1 (fr) 2008-02-06 2010-05-07 Oreal Composition deodorante et/ou anti-transpirante a base de micrioparticules interferentielles ; procede de maquillage et traitement de la transpiration et/ou des odeurs corporelles en particulier axillaires
EP2247275B1 (en) 2008-02-15 2017-11-29 The Procter and Gamble Company Delivery particle
GB0803538D0 (en) 2008-02-27 2008-04-02 Dow Corning Deposition of lipophilic active material in surfactant containing compositions
BRPI0909220A2 (pt) 2008-03-26 2015-08-25 Procter & Gamble Partícula de liberação
US20090258042A1 (en) * 2008-04-14 2009-10-15 Theodore James Anastasiou Encapsulated Active Materials Containing Adjunct Crosslinkers
US20090274906A1 (en) 2008-05-01 2009-11-05 Appleton Papers Inc. Particle with low permeance wall
US8067089B2 (en) 2008-05-01 2011-11-29 Appleton Papers Inc. Cationic microcapsule particles
US8071214B2 (en) 2008-05-01 2011-12-06 Appleton Papers Inc. Particle with selected permeance wall
DE102008044700A1 (de) 2008-08-15 2010-02-18 Dr. Scheller Cosmetics Ag Zusammensetzungen für die topische Anwendung in der Hautpflege mit verbessertem Wirkprofil
EP2181692B1 (en) 2008-10-27 2016-09-28 Unilever PLC Antiperspirant compositions
EP2181691B1 (en) 2008-10-27 2016-12-21 Unilever PLC Antiperspirant compositions
ES2610627T3 (es) 2008-10-27 2017-04-28 Unilever N.V. Composiciones antitranspirantes o desodorantes
MX2011004847A (es) 2008-11-07 2011-05-30 Procter & Gamble Agente benefico que contiene particulas de suministro.
US20100190673A1 (en) 2009-01-29 2010-07-29 Johan Smets Encapsulates
US20100190674A1 (en) 2009-01-29 2010-07-29 Johan Smets Encapsulates
EP2221039B1 (en) 2009-02-18 2017-11-22 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Antiperspirant compositions
US8986717B2 (en) 2009-08-06 2015-03-24 Conopco, Inc. Fragrance-containing compositions
JP5017338B2 (ja) 2009-09-07 2012-09-05 キヤノン株式会社 有機トランジスタの製造方法
US9186642B2 (en) 2010-04-28 2015-11-17 The Procter & Gamble Company Delivery particle
US20110269657A1 (en) 2010-04-28 2011-11-03 Jiten Odhavji Dihora Delivery particles
US9993793B2 (en) * 2010-04-28 2018-06-12 The Procter & Gamble Company Delivery particles
CN103458858B (zh) 2011-04-07 2016-04-27 宝洁公司 具有增强的聚丙烯酸酯微胶囊的沉积的洗发剂组合物
JP6283607B2 (ja) * 2011-04-07 2018-02-21 ザ プロクター アンド ギャンブル カンパニー ポリアクリレートマイクロカプセルの堆積が増大されたパーソナルクレンジング組成物
US8980292B2 (en) 2011-04-07 2015-03-17 The Procter & Gamble Company Conditioner compositions with increased deposition of polyacrylate microcapsules
CN103561713B (zh) 2011-05-26 2016-11-02 宝洁公司 具有有效香料浓郁度的组合物
AR094138A1 (es) 2012-09-20 2015-07-15 Procter & Gamble Composicion y metodo para elaborar microcapsulas secadas por aspersion
WO2014047502A2 (en) 2012-09-20 2014-03-27 The Procter & Gamble Company Anhydrous compositions having microcapsules and non-volatile oils
CA2884857C (en) 2012-09-20 2018-03-13 The Procter & Gamble Company Compositions and articles having a parent fragrance and microcapsules encapsulating a non-parent fragrance

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1655753A (zh) * 2001-10-03 2005-08-17 宝洁公司 包含颗粒和沉积助剂的洗发剂
US6849584B2 (en) * 2001-11-02 2005-02-01 The Procter & Gamble Company Composition containing a cationic polymer and water insoluble solid material
WO2010079466A2 (en) * 2010-04-28 2010-07-15 The Procter & Gamble Company Delivery particles

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107148263A (zh) * 2014-11-10 2017-09-08 宝洁公司 个人护理组合物
CN107148263B (zh) * 2014-11-10 2021-07-06 宝洁公司 个人护理组合物
CN110418669A (zh) * 2017-03-16 2019-11-05 宝洁公司 包含微胶囊的消费产品组合物
CN111163840A (zh) * 2017-11-15 2020-05-15 弗门尼舍有限公司 改善沉积的微胶囊
CN111163840B (zh) * 2017-11-15 2022-06-24 弗门尼舍有限公司 改善沉积的微胶囊

Also Published As

Publication number Publication date
JP6283607B2 (ja) 2018-02-21
EP2694017B1 (en) 2019-05-22
MX2013010980A (es) 2013-10-30
WO2012138710A3 (en) 2013-01-10
EP2694017A2 (en) 2014-02-12
JP2016128499A (ja) 2016-07-14
WO2012138710A2 (en) 2012-10-11
JP2014510142A (ja) 2014-04-24
US20120276175A1 (en) 2012-11-01
US9162085B2 (en) 2015-10-20

Similar Documents

Publication Publication Date Title
CN103458859A (zh) 具有增强的聚丙烯酸酯微胶囊的沉积的个人清洁组合物
CN103458858B (zh) 具有增强的聚丙烯酸酯微胶囊的沉积的洗发剂组合物
EP3217950B1 (en) Personal care compositions
CN103458871B (zh) 具有增强的聚丙烯酸酯微胶囊的沉积的调理剂组合物
ES2621203T3 (es) Composiciones que comprenden un material encapsulado
CN107249545A (zh) 提供活性物质的延迟释放的组合物
CN102858944A (zh) 递送颗粒
CN102858940A (zh) 递送颗粒
CN108348885A (zh) 提供活性物的受控释放的微胶囊和组合物
US10966916B2 (en) Personal care compositions
CN111447913A (zh) 具有带改善持久气味有益效果的聚氨酯微胶囊的组合物

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20131218