CN101319071B - 包含全同立构丙烯共聚物的膜 - Google Patents
包含全同立构丙烯共聚物的膜 Download PDFInfo
- Publication number
- CN101319071B CN101319071B CN200810131872.6A CN200810131872A CN101319071B CN 101319071 B CN101319071 B CN 101319071B CN 200810131872 A CN200810131872 A CN 200810131872A CN 101319071 B CN101319071 B CN 101319071B
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- China
- Prior art keywords
- propylene
- catalyzer
- alkyl
- multipolymer
- polymkeric substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 117
- 229920001577 copolymer Polymers 0.000 title abstract description 41
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 151
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 108
- 229920000642 polymer Polymers 0.000 claims abstract description 82
- 239000000203 mixture Substances 0.000 claims description 98
- 239000000178 monomer Substances 0.000 claims description 43
- 229920000098 polyolefin Polymers 0.000 claims description 16
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims description 12
- 238000001938 differential scanning calorimetry curve Methods 0.000 claims description 6
- 229920001169 thermoplastic Polymers 0.000 claims description 6
- 239000000470 constituent Substances 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 abstract description 77
- 239000004711 α-olefin Substances 0.000 abstract description 25
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 8
- 150000001993 dienes Chemical class 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 193
- -1 polypropylene Polymers 0.000 description 141
- 125000000217 alkyl group Chemical group 0.000 description 99
- 238000000034 method Methods 0.000 description 99
- 125000001072 heteroaryl group Chemical group 0.000 description 90
- 239000003054 catalyst Substances 0.000 description 85
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 71
- 229910052751 metal Inorganic materials 0.000 description 65
- 239000000523 sample Substances 0.000 description 65
- 238000002360 preparation method Methods 0.000 description 59
- 125000003118 aryl group Chemical class 0.000 description 56
- 239000002184 metal Substances 0.000 description 50
- 229920001155 polypropylene Polymers 0.000 description 48
- 239000003446 ligand Substances 0.000 description 47
- 229920001038 ethylene copolymer Polymers 0.000 description 40
- 239000000047 product Substances 0.000 description 40
- 239000000243 solution Substances 0.000 description 40
- 125000003107 substituted aryl group Chemical group 0.000 description 39
- 230000004927 fusion Effects 0.000 description 38
- 238000002844 melting Methods 0.000 description 38
- 230000008018 melting Effects 0.000 description 38
- 125000000547 substituted alkyl group Chemical group 0.000 description 38
- 125000000753 cycloalkyl group Chemical group 0.000 description 37
- 238000005516 engineering process Methods 0.000 description 36
- 230000006399 behavior Effects 0.000 description 35
- 238000006116 polymerization reaction Methods 0.000 description 35
- 230000008569 process Effects 0.000 description 35
- 239000000463 material Substances 0.000 description 34
- 150000001875 compounds Chemical class 0.000 description 33
- 239000001257 hydrogen Substances 0.000 description 33
- 229910052739 hydrogen Inorganic materials 0.000 description 33
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 32
- 125000004415 heterocyclylalkyl group Chemical group 0.000 description 32
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 31
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 31
- 125000003545 alkoxy group Chemical group 0.000 description 30
- 238000006243 chemical reaction Methods 0.000 description 30
- 229910052799 carbon Inorganic materials 0.000 description 29
- 230000014509 gene expression Effects 0.000 description 29
- 125000004104 aryloxy group Chemical group 0.000 description 28
- 239000000460 chlorine Substances 0.000 description 28
- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 28
- 239000002904 solvent Substances 0.000 description 27
- 150000002500 ions Chemical class 0.000 description 26
- 239000010410 layer Substances 0.000 description 26
- 239000004743 Polypropylene Substances 0.000 description 25
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 24
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 23
- 238000012360 testing method Methods 0.000 description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 22
- 238000004519 manufacturing process Methods 0.000 description 22
- 238000009826 distribution Methods 0.000 description 21
- 150000002431 hydrogen Chemical class 0.000 description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 238000005481 NMR spectroscopy Methods 0.000 description 20
- 238000004458 analytical method Methods 0.000 description 20
- 229910052736 halogen Inorganic materials 0.000 description 20
- 150000002367 halogens Chemical class 0.000 description 20
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 19
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 18
- 125000000707 boryl group Chemical group B* 0.000 description 18
- 239000012071 phase Substances 0.000 description 18
- 239000002243 precursor Substances 0.000 description 18
- 238000007789 sealing Methods 0.000 description 18
- 125000004429 atom Chemical group 0.000 description 17
- 230000003197 catalytic effect Effects 0.000 description 17
- 229920001519 homopolymer Polymers 0.000 description 17
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 17
- 239000003153 chemical reaction reagent Substances 0.000 description 16
- 229910052735 hafnium Inorganic materials 0.000 description 16
- 239000012528 membrane Substances 0.000 description 16
- 239000012530 fluid Substances 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 230000006870 function Effects 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 14
- 239000007787 solid Substances 0.000 description 14
- 229910052726 zirconium Inorganic materials 0.000 description 14
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 13
- LIKMAJRDDDTEIG-UHFFFAOYSA-N n-hexene Natural products CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
- 239000002879 Lewis base Substances 0.000 description 12
- 239000004327 boric acid Substances 0.000 description 12
- 230000008859 change Effects 0.000 description 12
- 229910052801 chlorine Inorganic materials 0.000 description 12
- 238000001816 cooling Methods 0.000 description 12
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 12
- 230000010354 integration Effects 0.000 description 12
- 150000007527 lewis bases Chemical class 0.000 description 12
- 229910052760 oxygen Inorganic materials 0.000 description 12
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 12
- 238000001228 spectrum Methods 0.000 description 12
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 12
- 150000001412 amines Chemical class 0.000 description 11
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 11
- 150000001721 carbon Chemical group 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 239000007789 gas Substances 0.000 description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 11
- 238000003780 insertion Methods 0.000 description 11
- 230000037431 insertion Effects 0.000 description 11
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 230000004087 circulation Effects 0.000 description 10
- 238000002425 crystallisation Methods 0.000 description 10
- 230000008025 crystallization Effects 0.000 description 10
- 230000007935 neutral effect Effects 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 9
- 239000002585 base Substances 0.000 description 9
- 229910052796 boron Inorganic materials 0.000 description 9
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 9
- 125000004122 cyclic group Chemical group 0.000 description 9
- 238000005259 measurement Methods 0.000 description 9
- 230000003287 optical effect Effects 0.000 description 9
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 9
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 8
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- 150000001450 anions Chemical class 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000006260 foam Substances 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 7
- 239000012190 activator Substances 0.000 description 7
- 229910000085 borane Inorganic materials 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 125000005842 heteroatom Chemical group 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 239000012968 metallocene catalyst Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- 229920006395 saturated elastomer Polymers 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 7
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 7
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 6
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- 230000003213 activating effect Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000007334 copolymerization reaction Methods 0.000 description 6
- 238000010828 elution Methods 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 150000002466 imines Chemical class 0.000 description 6
- 238000010606 normalization Methods 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 229920006300 shrink film Polymers 0.000 description 6
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 239000004709 Chlorinated polyethylene Substances 0.000 description 5
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 230000004913 activation Effects 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000002249 anxiolytic agent Substances 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 239000008393 encapsulating agent Substances 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 125000005843 halogen group Chemical group 0.000 description 5
- 125000000623 heterocyclic group Chemical group 0.000 description 5
- 230000000977 initiatory effect Effects 0.000 description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 229920000747 poly(lactic acid) Polymers 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000002516 radical scavenger Substances 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 5
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 4
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- 239000002841 Lewis acid Substances 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 4
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- 150000001639 boron compounds Chemical class 0.000 description 4
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- 229920001971 elastomer Polymers 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 150000007517 lewis acids Chemical class 0.000 description 4
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical group [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 4
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical class C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- YPJKMVATUPSWOH-UHFFFAOYSA-N nitrooxidanyl Chemical compound [O][N+]([O-])=O YPJKMVATUPSWOH-UHFFFAOYSA-N 0.000 description 4
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- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 3
- UQRONKZLYKUEMO-UHFFFAOYSA-N 4-methyl-1-(2,4,6-trimethylphenyl)pent-4-en-2-one Chemical group CC(=C)CC(=O)Cc1c(C)cc(C)cc1C UQRONKZLYKUEMO-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000007848 Bronsted acid Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- COOXAWDWHWRVRD-UHFFFAOYSA-N C[Ti]C Chemical compound C[Ti]C COOXAWDWHWRVRD-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
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- CMEWLCATCRTSGF-UHFFFAOYSA-N N,N-dimethyl-4-nitrosoaniline Chemical compound CN(C)C1=CC=C(N=O)C=C1 CMEWLCATCRTSGF-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 3
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- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical class [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 3
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- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PZWQOGNTADJZGH-SNAWJCMRSA-N (2e)-2-methylpenta-2,4-dienoic acid Chemical compound OC(=O)C(/C)=C/C=C PZWQOGNTADJZGH-SNAWJCMRSA-N 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 2
- QVLAWKAXOMEXPM-DICFDUPASA-N 1,1,1,2-tetrachloro-2,2-dideuterioethane Chemical compound [2H]C([2H])(Cl)C(Cl)(Cl)Cl QVLAWKAXOMEXPM-DICFDUPASA-N 0.000 description 2
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
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US10/139,786 US6960635B2 (en) | 2001-11-06 | 2002-05-05 | Isotactic propylene copolymers, their preparation and use |
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2002
- 2002-05-06 SG SG200602838-5A patent/SG147306A1/en unknown
- 2002-05-06 WO PCT/US2002/014158 patent/WO2003040201A1/en active Application Filing
- 2002-05-06 EP EP02725927A patent/EP1444276A1/en not_active Withdrawn
- 2002-05-06 JP JP2003542246A patent/JP2005508415A/ja active Pending
- 2002-11-05 CN CN200810131873.0A patent/CN101319050A/zh active Pending
- 2002-11-05 CN CN200810131872.6A patent/CN101319071B/zh not_active Expired - Fee Related
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EP1444276A1 (en) | 2004-08-11 |
CN101319050A (zh) | 2008-12-10 |
CN101319071A (zh) | 2008-12-10 |
US20050054800A1 (en) | 2005-03-10 |
JP2005508415A (ja) | 2005-03-31 |
US7041765B2 (en) | 2006-05-09 |
WO2003040201A1 (en) | 2003-05-15 |
US20070249798A1 (en) | 2007-10-25 |
US7897679B2 (en) | 2011-03-01 |
US20040082750A1 (en) | 2004-04-29 |
US20060004167A1 (en) | 2006-01-05 |
SG147306A1 (en) | 2008-11-28 |
US6946535B2 (en) | 2005-09-20 |
US6919407B2 (en) | 2005-07-19 |
US20030194575A1 (en) | 2003-10-16 |
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