WO2005103127A1 - 微孔性ポリプロピレンフィルムおよびその製造方法 - Google Patents
微孔性ポリプロピレンフィルムおよびその製造方法 Download PDFInfo
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- WO2005103127A1 WO2005103127A1 PCT/JP2005/007585 JP2005007585W WO2005103127A1 WO 2005103127 A1 WO2005103127 A1 WO 2005103127A1 JP 2005007585 W JP2005007585 W JP 2005007585W WO 2005103127 A1 WO2005103127 A1 WO 2005103127A1
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- boppin
- addition
- ratio
- drum
- specific gravity
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/91—Heating, e.g. for cross linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
- B29C48/9135—Cooling of flat articles, e.g. using specially adapted supporting means
- B29C48/914—Cooling of flat articles, e.g. using specially adapted supporting means cooling drums
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
- B29C48/9135—Cooling of flat articles, e.g. using specially adapted supporting means
- B29C48/915—Cooling of flat articles, e.g. using specially adapted supporting means with means for improving the adhesion to the supporting means
- B29C48/9165—Electrostatic pinning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
- B29C48/9135—Cooling of flat articles, e.g. using specially adapted supporting means
- B29C48/915—Cooling of flat articles, e.g. using specially adapted supporting means with means for improving the adhesion to the supporting means
- B29C48/917—Cooling of flat articles, e.g. using specially adapted supporting means with means for improving the adhesion to the supporting means by applying pressurised gas to the surface of the flat article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/919—Thermal treatment of the stream of extruded material, e.g. cooling using a bath, e.g. extruding into an open bath to coagulate or cool the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/005—Shaping by stretching, e.g. drawing through a die; Apparatus therefor characterised by the choice of materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
- B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
- B29C55/14—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively
- B29C55/143—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively firstly parallel to the direction of feed and then transversely thereto
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/36—After-treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249955—Void-containing component partially impregnated with adjacent component
- Y10T428/249958—Void-containing component is synthetic resin or natural rubbers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249986—Void-containing component contains also a solid fiber or solid particle
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Definitions
- the present invention relates to a bobbin suitable for a wide range of uses such as packaging, industrial use, and the like.
- the present invention relates to a bobbin, which is superior in productivity, can be low in weight or high in weight, and can extremely increase the transientness of various bodies, as compared with conventional methods.
- 002i is mainly used for batteries, electrolytic capacitors, etc., various types of separators (itas), articles represented by sanitary products, clothing and medical supplies, and ink container members because of their characteristics of permeability and low weight.
- separators such as separators
- poins such as poppipotin.
- the manufacture of 000 voin can be broadly divided into formula methods and formula methods.
- the formula method is to add the excipient to the poin, finely disperse it, and then extrude the extrudate into a medium or the like to form holes, and if necessary, extend the process before or after the expulsion.
- There are proprietary methods eg, patents, 2).
- the formula method is to produce a glass with a special crystal structure for low melting and high melting conditions, and to open the glass surface mainly for this purpose.
- There are some types of holes that can form pores e.g., Patent 3, etc.
- another dry method is to form pores with different surfaces separated by adding a large amount of inorganic particles or other elements to the poins. It is inorganic (for example, Patents 4 and 5).
- the hole is formed by the difference between the two (for example, patents 6 to 5 and 2). It is important to selectively produce a large quantity of products, so it is important to use, and to produce products in specific cases. Things (for example,
- a pipe that satisfies a specific (lower, S) -metate (lower,) relationship is formed.
- a white poppy with a specific gravity of 55 to 8585, which is made by laminating () consisting of a poin-based fat on the surface has been proposed [2].
- the layers satisfying the above requirements are inorganic and An example is disclosed in which a void is formed by adding a void such as a resin or a non-fat, and then adding a void to form a void, thereby producing a white polypropylene having a specific gravity of 6 to 76.
- the high-molecular-weight portion of potin-po-tetra-o-tin may come out as a target substance, and this significantly deteriorates, so that it was extremely difficult to establish the percentage, transient, and unevenness by the fraction.
- the present invention has been made to solve the above-mentioned problem, and has a low specific gravity, excellent productivity, extremely high transmission performance, and a bobbin with excellent mechanical properties and qualitative properties. To provide. It is also an object of the present invention to provide a bobbin production method which has a low specific gravity, is excellent in productivity, and can extremely enhance permeation performance, and is excellent in mechanical properties and qualities. To solve the problem
- the first description discloses the poppies and the method of producing the poppies that are focused on the specific gravity of the poppies or the tones and the poppies that constitute the poppies.
- the boppiny has sex with a ton ratio of 3 or more, has sex, and has a specific gravity of .about.6.
- the poppins have a ton ratio of 6 or more, have sex, and have a specific gravity of.
- the poppy contains a long puppy in the skeleton, has sex, and has a specific gravity of 6 to 6.
- the process of producing the poppy which includes the poppy having a ton ratio of 3 or more, is melted into a resin form mainly composed of the poppy having the injection.
- the process is characterized in that the process includes a step of taking out a drum and a drum, and a step of biaxially setting the obtained drum to a rate of 5 or more.
- a process of melting a resin containing poppy as a main component into a resin and obtaining a nozzle having a justin and a ton ratio of 6 and having a potion is obtained. It is characterized by including a step of biaxially setting the rate to 5 or more.
- the poppy contains a long-lived poppy in the main skeleton, and is melted into a resin having the characteristic popi as a main component, and the just and the drum are put on the drum. And a step of biaxially setting the obtained number to 5 or more.
- penta, () is 9 to 995.
- the process is characterized in that the resin is melted in the shape of a resin having a pupi as a main component, and is then obtained on a drum, and the obtained toner is biaxially formed with a rate of 5 or more.
- a preferred embodiment common to the boppin of the present invention is characterized in that the boppin is formed of the following.
- the amount is less than that of the conventional boppin, and the method is excellent. Further, for example, it can be manufactured without breaking even if the rate is extended at a very low temperature. As a result, the line degree can be increased as compared with the conventional method, and the productivity is excellent. Further, by extending the ratio in the direction, the specific gravity can be reduced and the degree in the longitudinal direction can be increased as compared with the conventional case. Occasionally the permeability can be significantly improved.
- the boppin with the light of 003 43 has a higher degree of connection in the direction of the arrow than the conventional boppin.
- the physical properties in the longitudinal direction are excellent, so that the donability in the secondary construction process is excellent.
- the physical properties in the longitudinal direction are excellent, so that the permeability can be remarkably improved while maintaining the non-stick property.
- the boppin of these inventions is also excellent in qualitative properties and the like, and is therefore useful for synthesizing, feeling, optical parts, building materials, separation (ita), wound materials, etc.
- FIG. 4 is a diagram schematically showing a line obtained when a fraction is obtained.
- 2 2 is the calorific value (AB), which is the sum of the peaks associated with the melting of the product whose vertex is observed at 4 to 6 C, and the peaks other than those whose vertex is observed on 6 C.
- FIG. 9 is a diagram showing a calorific value (A) obtained by accumulating a peak of a next solution.
- FIG. 33 is a diagram schematically showing a support and a device arrangement when collecting a 200-scan X-ray in the following method (6) using a wide angle X.
- 44 is a diagram schematically showing the position of the sump when sampling the degree distribution pipe in the (0) direction in the following method (6) using wide angle X.
- Embodiment 55 is a diagram showing a degree distribution pipe in the direction of Embodiment 33.
- 66 is a diagram showing a degree distribution pipe in the direction of Comparative 3.
- FIG. 7 is a view showing an S image obtained when the surface of the is observed by a scanning microscope (S).
- 8 7 is a diagram showing an S image obtained when the surface of the 2nd hole sampled in the same manner is observed with S.
- the poppins belonging to the description of 039 are referred to as the poppins that constitute the key (hereinafter, may be simply referred to as the poppins that constitute the key or the poppins of the key. )
- the poppins that constitute the key (hereinafter, may be simply referred to as the poppins that constitute the key or the poppins of the key. )
- the boppin of the present invention includes the ppi with a ton ratio of 3 or higher.
- the puppies of ⁇ include only puppies with a ton ratio of 3 or higher.
- the 4,000 ton ratio can be obtained by using the inflow, and determining the constant according to the Ponce scece 2, 6473 (972) of Cosse.
- ton means the degree strain and degree strain line approximated by exponential numbers. It is the ratio of degrees to degrees at 6 s.
- means for increasing the degree of poppy include, for example, molecular distribution, ultra-high molecular weight entry, long entry, light bridges, low-potency, etc.
- addition outside the poppin which disperses in a pop-like shape in a poppin.
- the ton ratio of the pi is the Pe dse speed.
- the poppy with a ton ratio of 3 or more which is to be blended into the popin as described above, is replaced by It is preferable not to contain it.
- the poppy of this invention contains as shown below, then the poppy containing the pipi is a compound with the pipi whose ton ratio is above 3. It is preferable that there is.
- the pipi having the above-mentioned ton ratio of 3 contains the other than the above, it is preferable to extract and remove it, and it is preferable to set it before adding, but it is preferable to set it before adding. It is not supported by the ton ratio specified in the delivery situation, and in some cases, Therefore, in this case, it is assumed that the condition is satisfied if the ton ratio of the poppy such as the agent is 3 or more.
- the boppin with the lightness of 003 includes the ppi with a ton ratio of 3 higher, so that the flapping is excellent compared to the conventional boppin. Furthermore, it is possible to produce a product that does not break even if it is extended at a low temperature, and it is possible to increase the liability by extending it at a high rate even if the squeezing degree is the same as compared with the conventional bobbin. As much as possible, the unit can be improved. In this way, by including a peak with a ton ratio of 3 or more, the productivity can be improved because the production capacity can be increased and the production capacity can be increased. Furthermore, especially when extended at a high rate, the physical properties of the hand can be enhanced. This is because the inclusion of puppies with a ton ratio of 3 promotes the interlocking of the dies in the system from the cast floor, so that in the subsequent process the rolling force becomes uniform throughout the system. It is presumed to be transmitted.
- the extension (of the rate in the longitudinal direction and the rate in the width direction) can be increased, and the growth can be achieved. Because of the promotion, the specific gravity can be reduced compared to the conventional boppin. In addition, the transmittance can be significantly improved by mainly controlling the layer structure and the condition of the layer.
- the torpedo ratio of the puppies included in the boppin of the light of 0045 is more preferably 35 and more preferably 4 above.
- the ton ratio of the puppies contained in this light boppin will be reduced to the extent described above, and as a result, it will be able to be more stably and more prolonged.
- a method for obtaining a peak having a ton ratio of 3 or more is not particularly limited, but the following methods are exemplified, and these methods are preferred.
- the poppies with a ton ratio of 3 included in the boppin with a lightness of 007 have a high output qualitative effect, an effect on the production described above, and an effect on the improvement of the transparency of these poppies. Skeleton .
- the poppy having a long skeleton is a poppy having a popin chain which is divided into poppy bones.
- the reason for the great effect obtained by the pupil having a long skeleton is that it acts as a simulated tire for the cast floors, and the rolling force is transmitted to the entire system in the subsequent process. Presumed.
- An example of a body of a pipi having a long skeleton is ase.
- Popins such as type P84P633P6S632
- oeas poppins such as type W3S
- o poppins such as type 4226
- a branch value represented by the following is given as a standard value indicating the degree of the 550 peak.
- the tetrane shown here Measure the sample with C according to the above method.
- the weight-averaged molecule used for this determination was the method published in Amecan Laborato (e ca abo ao) a 63 75 (978) by Nehne (... Measure.
- the puppies whose ton ratio is above 3 in the boppin of the light of 005 are: . If the ratio exceeds the above range, the effect of adding a pipe with a ratio of 3 or more will be reduced, and will be worse, or if the weight of the material obtained by extending the ratio will be higher or the permeability will be poor. There is. Ton ratio of 3
- the ton ratio contained in the boppin in the light of 005 has a ton ratio of 3 or higher, and although not particularly limited, it is about 5 for the amount of ppi in the pi,
- the feature is that the effect can be seen even with a small amount of addition. If the above is the case, especially in the case of ⁇ , there is a case where the direction becomes worse especially when the rate is increased at a high rate (the degree of breaking can be broken by about). In addition, the weight obtained when the material is extended at a high rate may be high, or the permeability may be poor. Beyond the surroundings, in the case of vertical and vertical movements, the direction may become worse (especially when the distance increases), especially when extended at a high rate. In addition, the nature of the port may change. In addition, the fraction defined below may decrease more than necessary. More preferably 22, most preferably ⁇ 5-5, for the amount of pipin in pupi with a ton ratio above 3.
- the ton ratio of the Boppin is 6 or more.
- the fact that the ton ratio of ⁇ is above 6 means that the ton ratio obtained by the pupin body of ⁇ ⁇ is above 6.
- the ratio here means that when the liposome of the present invention contains as shown below, This is the value obtained by The value of Pope's ton ratio is lower than that of Pupee's containing To by including, but even in the case of misalignment, the target must be met if certain requirements are met. It can be achieved. If the pipi contains an agent other than the above, extract and remove it, and determine before adding However, it may not be a good idea to represent the ton ratio specified in the delivery situation where the agent was present. In this case, the purpose of the present invention is similarly achieved. In this case, the condition is satisfied if the ton ratio of the agent or the like is 6 or more.
- the ton ratio of the boppi in the boppi is 6 or more, the flow is less and more excellent than the conventional boppi. Furthermore, it can be manufactured without breaking even if the rate is increased at low temperatures, and the line rate can be increased by increasing the rate even with the same cast degree compared to the conventional bobbin. Because it can be high, the unit can be raised. In this way, by having the ton ratio of 6 or more, productivity can be improved because the production capacity can be increased and the production capacity can be increased. Furthermore, especially when extended at a high rate, the physical properties of the hand can be enhanced. This is because the ton ratio of the pipes above 6 promotes the connection between the cast floors and the system, and the subsequent rolling process reduces the rolling force to the whole system. It is presumed to be transmitted to.
- the ton ratio when the ton ratio is composed of pipes having a ratio of more than 6, and the direction is extended at a high rate, the extension (of the rate in the longitudinal direction and the rate in the width direction) can be increased, and the growth is promoted. Therefore, the specific gravity can be reduced as compared with the conventional boppin. In addition, the transparency can be significantly improved by mainly controlling the layer structure and the condition of the layer.
- the ton ratio of the puppy of this light is more preferably 6.5-3, more preferably 7-2, and most preferably 7-2. These can be controlled, for example, by the types of pipes having a long skeleton as shown below.
- puppies having a ratio of 6 are, for example, puppies into which a polymer is introduced, various puppies having a long skeleton in the skeleton, various types of puppies mixed with the skeleton, copolymerization with the skeleton of the BPPI, It can be obtained by entering it in a grade.
- the puppies having a ton ratio of 6 or higher, which constitute the bop pie-im of the present invention, have the above-mentioned effects of the above-mentioned production and the effect of improving the transparency greatly. Use a long pipe for the skeleton. .
- Pupi with a ton ratio of more than 3 can be obtained, for example, by mixing long puppi bopipi in the skeleton or by copolymerizing or grafting the long component into the bopipi skeleton.
- Pupi with a ton ratio of more than 3 can be obtained, for example, by mixing long puppi bopipi in the skeleton or by copolymerizing or grafting the long component into the bopipi skeleton.
- boppi The child structure of boppi has been a linear structure, but it is possible to mix the boppi with this light with the boppi which has the above-mentioned effect and to improve the transparency and transparency. The effect can be increased. This is presumed to be due to the fact that it acts as a tie that simulates the cast floors, and then the rolling force is transmitted to the entire system in the extension process.
- the ton ratio of the pupi to be mixed is more preferably 35, more preferably 4, and even more preferably 4 to.
- boppiny includes ppi.
- the boppin in the light C of 0063 is superior to the conventional boppin since the boppin having the same has less flaking than the conventional boppin. Furthermore, even if the rate is prolonged at low temperatures
- the line degree can be increased by extending it in a high direction, so the unit size can be increased .
- Inclusion of the pipi can increase the production capacity and increase the production capacity, thereby significantly improving the productivity.
- the physical properties of the hand can be enhanced. this is,
- the skeleton includes a long pipi
- the elongation (the ratio in the longitudinal direction and the ratio in the width direction) can be increased, and the formation can be promoted, so that the specific gravity can be reduced as compared with the conventional boppin.
- the transmittance can be significantly improved by mainly controlling the layer structure and conditions of the layer.
- the average amount of the pin-pins contained in the book pin-pin is more than the average, and more preferable that the average is 2 or more.
- the average molecule () of the above-mentioned pipi has the following formula: . Is the above,
- the result of the array may be insufficient. In the future
- the average molecular weight of the pipi can be measured by the method described above.
- Examples of the body of the puppy having a long skeleton include those already described.
- the puppies contained in the boppin of the statement C of 0068 are: . If the ratio exceeds the above range, the additive effect of the pipi possessed may be reduced, and may deteriorate, or the weight of the material obtained by increasing the rate may be increased, or the permeability may be poor.
- the value of the pipi is more preferably below 9.
- the amount of pipi contained in the boppin of C in the description of 0069 is preferably ⁇ 3 with respect to the amount of pipi, and the effect is seen even if a small amount is added.
- the feature is that it is.
- the weight may be high or the permeability may be poor.
- the direction may be deteriorated (partially cut off), especially in the case of extending vertically.
- the nature of the port may change.
- the fraction defined below may decrease more than necessary.
- the fraction in the sample may be reduced, resulting in a higher weight of the resulting image, or transmission or injection may occur.
- More preferred is 2-3 C, even more preferred is 23-2 g. C.
- the boppi in the light of 2 includes a ppi that satisfies the above ().
- the impipi may include only those that satisfy the above ().
- Such puppies are usually puppins (below eSeP, sometimes referred to as SPP) because their S is high.
- S measured at 23 C means that the sump is heated to 23 C using a graph of a metrology tester, and the poppy is extruded at an extrusion speed of 2 minutes to form a strand. This is the force determined when picking up at a speed of 57 minutes (c). However, the force under withdrawal 5 is used as the S Even trap.
- S in poppies has, and the lower the, the higher the S.
- the boppin in the description of the item 2 has less slippage as compared with the conventional boppin by including the ppi that satisfies the above () in the ppins of the camera. Excellent. Furthermore, even if the rate is extended at a low temperature, it can be manufactured without breaking the line, and compared to the conventional bobbin, even if the cast degree is the same, the line rate is extended by extending the rate toward the high. Because it can be high, the unit
- the above-mentioned poppin (SPP) contained in the poppy of boppiny is more preferably the following (4), and further preferably the following (5) What to fill.
- the stability can be increased at a high rate, or the rate can be extended at a high rate.
- the above effects tend to be obtained, even within the above (), depending on, for example, if S is too large for, or if S is too large for S, if vertical, In particular, since may deteriorate, for example, it is preferable to satisfy the following (6), and the following (7) .
- the method for obtaining the SPP is not particularly limited, but the following methods are exemplified, and these methods are preferred.
- the SPP contained in the bop pin image of the description of 00772 has a large effect on the qualitative output of these pipes, the above-mentioned effect on the production, and the effect of improving the transparency. There is a long skeleton .
- the SPP having a long skeleton is a puppy having a pupin chain separated from a poppin skeleton. It is presumed that the large effect as described above is obtained with a pupil having a long skeleton because it acts as a simulated tire on the cast floor, and the rolling force is transmitted to the entire system in the subsequent process. You.
- Examples of SPP having a long skeleton include ase SPP (type P84P633P6S632, etc.) o eas SPP (type W3S, etc.), o SPP (type 4222) 6 etc.).
- the effect of adding the above-mentioned SPP may be reduced, and the quality of the product may be deteriorated, or the image obtained by extending the composition at a high rate may be low, or the permeability may be poor.
- the SPP is more preferably below 9.
- the S of the SPP that satisfies the above () in the boppin image of the description of 0082 is . If S is above, the additional effect of the above-mentioned SPP cannot be obtained, and in particular, in the case of, the direction becomes worse especially when the ratio is increased at a high rate (immediately breaks the image). There is a case. In addition, when the film is stretched at a high rate, the obtained image may have a low value or may have poor permeability. If the distance exceeds the range, the vertical and vertical
- S in SPP that satisfies () is more preferably 4 to 8 c, and still more preferably 5 to 6 c.
- the SPP that satisfies the above () contained in the boppin of the description of 022 2 is not particularly limited, but is preferably up to 5 with respect to the amount of ppin, and is preferably a small amount.
- the feature is that the effect is seen even in addition.
- the direction may be deteriorated especially when the direction is extended at a high rate (i.e., the distance may be broken). It is also obtained when the rate is extended to a higher rate. May be low or the permeability may be poor.
- the distance exceeds the range the direction may become worse when the shaft is vertically and biaxially stretched, particularly when the shaft is extended at a high rate (i.e., the curve may be cut off).
- the nature of the port may change.
- the fraction defined below may be unnecessarily reduced.
- the SPP that satisfies () is more preferably 22, and most preferably 2-2, for the amount of SPP.
- S is 5c and the relationship with S satisfies the above (2), the amount of slack is small and excellent compared to the conventional bobbin. Furthermore, it can be manufactured without breaking even if the rate is increased at low temperatures, and the line rate can be increased by extending the rate at a high rate even if the cast degree is the same as compared with the conventional bobbin. Because it can be done, it can be increased in units. Thus, S is 5c, and the relationship with S satisfies the above (). In addition, productivity can be significantly improved. In addition, especially when extended at a high rate, the physical properties of the hand can be enhanced.
- the ratio (of the ratio in the longitudinal direction and the ratio in the width direction) can be increased, and the formation is promoted, the value can be increased as compared with the conventional Boppin.
- the transmittance can be significantly improved by mainly controlling the layer structure and conditions of the layer.
- the S of the puppies of the boppin in the light of 2 is more preferably 3c, and even more preferably 2c below.
- the following expression (8) is more preferably satisfied
- the following expression (9) is more preferably satisfied with S of the puppy of the light.
- Pupi in which S is 5c and the relationship with S satisfies the above (2) is, for example, a pipe that has a high molecular weight introduced therein, a pipe that has a long skeleton, and the like. High,
- Pupin Enhance its S by mixing with various boppi, or by introducing a part into the skeleton of various boppi by copolymerization, grafting, etc. It can be obtained by:
- the poppies that make up the present poppies have significant effects on the above-mentioned production, and furthermore, the effect of improving the transparency. Use .
- the puppies constituting the boppiim of FIG. 2 have S of 5c and are not particularly limited as long as the above (2) is satisfied. .
- Pupi that satisfies () is, for example, a mixture of SPP, which has a long skeleton in the skeleton of SPP, or copolymerization or grafting of a long component into the skeleton of Boppi to form SPP.
- the child structure of a conventional boppi is a linear structure, but the popi constituting the clear boppiim are mixed with the boppi that has There is a tendency to increase the effect on, the effect on transmission, and the effect on transmission. This is the cast floor
- (surface 3 is a purchase obtained with 200 scans.
- N (,) is used to obtain the point of the rotation peak of the above (3) . If the sump and the counter are fixed at 20, the sump is fixed. This is the degree of the intensity distribution obtained when rotating in the azimuth () direction within the film. If the product of the sump to which the X-rays are emitted with respect to the azimuth in the sump is constant, the degree distribution pipe in the above-mentioned direction (3) corresponds to the one in the film. That is, () corresponds to the component arranged in the direction in the film, and () corresponds to the component arranged in the direction.
- the boppin in the light of [0093] is in a state in which is arranged at a higher altitude than the conventional boppin because the parentheses () and () are as described above.
- the height is higher, so that the physical properties of the hand are better.
- the length of the wire can be increased, a person can be saved, and the drigability is excellent.
- the bhoppin of (3) can achieve both () and the excessiveness and the non-donating property at a high level because () and () are as described above.
- the puppies of ⁇ include puppies whose ton ratio is above 3. ⁇ The ton ratio of the puppy is 6 or more.
- the polymer may be a copolymer obtained by copolymerization, or the polymer may be loaded on a poppy.
- Monomers that constitute such a copolysynthetic component or compound include, for example, tin, ten,
- these boppinies are, for the sake of assistance, at least a kind of at least one selected from other polys other than poyns and poyns. Even if it contains poly.
- the poin system include, but are not limited to, homopolymers or copolymers mainly composed of the above-described monomers such as monomers exemplified above.
- Examples of poynic systems include microdispersion in puffins in the process, and fruit in the subsequent process, e.g., in the presence of pometi pentene and meth pentene.
- ultra-low potency can promote growth, result in lower specific gravity, and even improve permeability, .
- examples of other poin-based polish include poin-based polish, poste-based fat, poad-based fat, ponside-based fat, poly-based fat, and the like. It is not limited to these.
- Examples of other poisons outside the polioline system include microdispersion in puffins in the process, and fruit in the subsequent process, e.g., But not limited to these.
- WP ultra-high molecular weight potin
- P potetraoctin
- Things may come out.
- P may be extruded or spiked due to the generation of hydrofluoric acid due to the decomposition of the poison. Therefore, it may not be preferable to add WP or P substantially as another poin outside the poin system.
- the boppi of these boppinies should be able to use the boppinies of these inventions within a range that does not impair the character of the present invention from the viewpoint of economy and the like. It is permissible to add a key generated during manufacturing or another key generated during manufacturing.
- the poppy of the boppiny includes a poppy with a ton ratio of 3 or higher, if the ton ratio is 6 or higher and has the property defined below. is necessary.
- the poppies of the boppinies include those whose relationship with S satisfies the above (), the relationship of S with 5c S satisfies the above (2), and It is necessary to have the property defined in
- these boppinies are It is preferable to include the 9-pinomer in the total mass of all the ports that compose the rim, even in the case of the product deviation of 2 above as shown below. .
- a port composed of a monomer other than the poppin is added from the viewpoint of assistance, the case that occurs when manufacturing another material outside the boppin of the present invention is added.
- the total amount of the monomers of all the ports constituting the tree is filled with the propylene monomer.
- the proportion of the propylene monomer of boppiny is more preferably 95, and even more preferably 97, based on the total amount of the monomers of all the ports that constitute ii.
- the pupil's mate () of these boppinies is ⁇ 3 minutes from the point of .
- the problems such as unstable discharge at low temperature, long time required for extruding material exchange, difficulty in forming a uniform thickness, and deterioration of May occur.
- the point of the port on the drum greatly fluctuates when the port discharged from the metal is cast into a metal drum in the casting process. Since it is difficult to produce a uniform product in the inside, and there are spots on the surface, the resulting shape may be large, and the unevenness of the hole may be large. Is more preferably ⁇ minute.
- the isotic index of the bopipin of these bopipins is from 92 to 998. If 11 is the above, there may be problems such as the lowering of the waist when the angle is set to 1 and the increase of the distance. As the value of 11 increases, the qualities and the like tend to improve. However, if the value exceeds the above range, the product may deteriorate. 11 is Preferred is 94-99 5, more preferred is 96-99.
- the sump should be pumped at a temperature of 6 C below. 2 After removing impurities and impurities, determine the value of the sump at least 2 minutes at 3 C.
- the polyp It is necessary to have Here, having the property means that the charge of the atmosphere 5 is reduced to 28 C at a rate of C minutes using a meter (SC) according to JS 722 (987), and after maintaining for 5 minutes
- SC meter
- the line obtained when cooling to 3 C with the cooling of C minutes and then at the speed of C minutes again has a peak point at 4 to 6 C accompanying the melting of the product. That the amount of heat released from the peak is higher.
- the first obtained line may be referred to as a first run line
- the second obtained line may be referred to as a second run line.
- the properties of the puppies containing are confirmed.
- the fact that the im possesses the property means that an article is generated when the poppy is touched.
- sex, extrusion, casting, winding, and immediate imposition are performed here. Therefore, if the puppy of the im contains a substance as exemplified below, the sex of the im body containing the is determined.
- the value is an empirical value indicating the product ratio.
- Tanajo e Joes
- Kuoira aooeaeCee 75 34 58 (964).
- the boppin of these inventions has the property of being able to produce an article in the course of its production, and the article is tied to the article in the subsequent process. Holes can be formed by the difference.
- the fraction of the boppin of the present invention is 3 or higher, which is common to the descriptions of 2 and 3.
- the fraction is the melting of the product from Pupin where the peak is observed at 6 C on 4 C on the second run line obtained by using the SC as described above for the second time.
- the fraction is the ratio of the product occupied in the poppies. And determine the fraction of. In addition, 4 to.
- the obtained result may be low or the permeability may be poor.
- the fraction is more preferably above 36, more preferably above 39, and most preferably above 5.
- boppinies are added with soybeans. . If such is not added, a higher fraction as described above may not be obtained.
- bopipin constituting the boppine of the present invention include, for example, boric acid represented by, for example, 2-kisthenium, ganium benzoate, cognium, and tagnium. Aka or Aka
- the present invention is not limited to these. It is also acceptable to use only the type or to mix the two.
- boppinies to be added to bopipipi the above-mentioned ad compounds, particularly represented by the following, and represented by, for example, nku 26 tanjibobo,
- a substance composed of a component that is a basic acid and a component that is a hydroxyl group or a salt of a periodic system can reduce the weight of the resulting im (can increase the weight) and improve the permeability. Preferred.
- Examples of particularly preferred poppies include Nippon Nihon Co., Ltd. (type) and C-poppy P (type 22 SP).
- the amount of impin may decrease. If the above is the above, the resulting image may have insufficient properties, a high specific gravity (low), or poor transmission performance. If the value exceeds the above range, even if added more, the fraction of the obtained im does not improve, the economy is poor, and the dispersibility of the body deteriorates, and conversely, the property may decrease. Of these, the more preferred is -5 to -5, and the more preferred is -5 to -2.
- the distribution in the As described in the detailed description of the specification method below, the dispersal form of Observed with an optical microscope, if the average value of the ratio of the major axis of the observed shape is above, it is defined as being dispersed in. In some cases, it is possible to increase the amount of water and to increase the permeability. Furthermore, as a result of the advancing of only the dies, which is a feature of the above-mentioned inventions, it is possible to form very fine pores very efficiently, so that it is possible to further increase the porosity and enhance the permeability. It may be.
- the puppies constituting the boppiim include, for example, oxidation, heat, chlorine, electrification, lubricant, locking, It is permissible to mix viscosity adjusters and agents.
- the target is the fraction of im obtained by the addition. .
- it is important for oxidation, thermal and thermal properties of the image. Examples of the heat that is preferably added to the bopy pin imum of the present invention include the following.
- 26 e zo () 3 3 3 5 5 5 5 ixa eaaa (tin 24 6 toy) tozo for example, Igi Corporation GX 3 etc. (For example, Igi Corporation GX).
- the present invention is not limited to the above and heat. It is preferable to use these in combination with heat and heat, and it is preferable that the amount of heat is 2 to 3 with respect to the amount of imine.
- the long-term heat resistance may be inferior in the initial process of obtaining the material from the material and in the subsequent two processes. Further, when the heat of each exceeds the above range, even if the heat is further applied, the heat property of the obtained im does not improve, and the economic efficiency may be poor. , Heat, and the like, more preferably from 5 to 9 and more preferably from 1 to 8 with respect to the amount of imine pin.
- anti-electrostatic damage due to im- age may be added to the puppy of the boppiim of the present invention.
- the additives to be added to the bopypinim of the present invention include tincide of betaine conductor, 4th anneal compound, akizitano ance, gusenste, and stainless steel. Gusses, if these, and the like, but are not limited thereto.
- a lubricating agent may be added to the boppine in the present invention. The agent is added to improve the kinetics and release of the thermoplastic as expressed in JS (eg, JS 69 (994)), e.g. It is added to control the friction between technicians.
- Examples of the lubricant to be added to the bopipine of the present invention include ad-added substances such as stearad, ad, oin-ad, and mixtures thereof. However, it is not limited to these. 08 It is preferable that the amount added to the boppine of the present invention is 3 times higher than the amount of impin. , And more preferred are 4-5. In addition, the charge and lubricant . Further, in the case where the addition of any of the above results in a decrease in the fraction, it is preferable not to substantially add them, and it is sufficient to select.
- the puppies of the boppinies of these inventions may be added with inorganic and / or inorganic particles for imparting slipperiness, king, or assisting.
- a child of a metal or metal object for example, a child such as olites, carbonates, gallium carbonates, ana, mosquitoes, umium, kaon, kaonite, tuks, oysters, irons, and titanium
- these compounds include, but are not limited to, these.
- cross-linking a polymer obtained by using the cross-linking to form a polymer compound, for example, a pomethylan-based child, a postine-based child, an ac-based child, a polyurethane-based child
- the children include, but are not limited to, offspring, poster offspring offspring, offspring offspring, and compounds thereof.
- Optical parts building materials, separation (ita), wound materials, etc., clothing, etc., diapers and sanitary goods, batteries and electrolytic capacitors, inks, oils and fats, etc. Demonstrates high productivity characteristics in applications such as blood glucose sensors and tank membranes.
- the solidification of the pond in the casting process (drum degree, metal drums, obtained steel, between metal drums, etc.)
- the high brightness of if the specific gravity is too low or is too high, in the manufacturing process and the subsequent two manufacturing processes, there is a tendency for the length to increase, or to increase the number of people, and if these elephants are seen, The process is overkill or poor in secondary or non-stickiness). Therefore, for the light-weight boppiny, the more preferable is 9 to 56, and the more preferable is 2 to 4.
- the brilliance of the light of 2 is more preferably from 35 to 9, even more preferably from 6 to 85, and most preferably from 65 to 85.
- the product is above 2 . If mimi is 2, it becomes difficult to form a single layer. If mimi 2 is exceeded, the boppin of the present invention may be inferior in characteristics such as transient.
- the surface layer to be formed does not necessarily need to satisfy the scope of the present invention, such as laminating, in-line online, in-line operating, physical wearing, wearing, standing, etc.
- the present invention is not limited to these differences, and the best law may be selected.
- the laminate shall meet the surroundings of this light. .
- the above setting can be applied to improve the surface water, adhesiveness, charge and agent dotting.
- the ambient gas air, oxygen, nitrogen, carbon dioxide, or a gas system is preferable. From the viewpoint of economic efficiency, it is particularly preferable to operate in air. Further, flame treatment, plasm treatment and the like are also preferred from the viewpoint of improving the surface strength. There is no special limit of force, but it may cause excessive surface .
- the degree of transientness of the obtained energy is
- the process of casting during the casting process (drum degree, metal drum, obtained metal, between metal drums, etc.) ((Vertical if)), (Vertical or horizontal, vertical or horizontal, simultaneous biaxial, biaxial stretching, etc., can be controlled by degree, elongation, etc. In case of transient If And the subsequent two steps may have poor ductility. If the gas exceeds the above range, the transmission performance may be insufficient and high. Moth, more preferred is ⁇ 9, most preferred is 5 ⁇ 3.
- the space between the flow lines is defined as the time when the flow line lands on the surface when the flow line penetrates in the thickness direction and fills the holes. Then, measure the time until the light is completely transparent,
- the solidification of the po in the casting process drum degree, metal drum, (E.g., between metal drums), (vertical if), (vertical if horizontal, vertical or horizontal, simultaneous biaxial, biaxial stretching, etc.), degrees, elongation, etc. It can be controlled by such means.
- the dongeability may be inferior.
- the transmission performance may be insufficient due to insufficient transmission performance.
- Line more preferably ⁇ 325, most preferred -5 ⁇ 925.
- the Young's modulus in the hand direction of the bobbin is above In such cases, there is a case where the dongeability is inferior in and after the second process.
- the Young's modulus in the hand direction can be controlled by the im puppy (corresponding to 11 etc.), the resulting im (), and the im () ().
- the Young's modulus in the hand direction is more preferably over 3GPa, and even more preferably over 3gGPa.
- the upper limit is not set. In some cases, for example, ⁇ .
- the degree of hand direction at 25C is as described above, the ductility may be inferior in or after the two construction steps. It can be controlled by () (), () (), etc. of the im (obtained). , More preferably above 5 Pa, even more preferably above 55 Pa.
- the above-mentioned don'tability tends to be excellent, and although there is no upper limit, if it is excessively low, the transmission performance may be poor. So, for example, 5 Pa .
- the qualitative quality is preferably kept low, even at relatively low temperatures.
- the hand direction at 5C of these invention boppi .
- the ratio exceeds the above range, the shrinkage of the image will increase in the secondary construction process, which may cause defects such as cracks and mosquitoes.
- It can be controlled by the hand direction, 5mm (corresponding to 11 etc.), (, degree, etc.), and (regular time, temperature, etc.) in 5C.
- the hand direction is more preferably 4.5 times lower.
- the hand direction at 5C of these inventions The lower the temperature, the better the above process tends to be.
- the lower limit is not set, but in order to control the temperature lower, it is necessary to raise the constant temperature to a certain level, and the pores are closed and the specific gravity decreases. Or the transmission performance may be poor. .
- the friction coefficient () of the boppin is: .
- the friction coefficient of ⁇ is measured by the method described in the detailed description of the following fixing method, with the sim surfaces superimposed. If s is as described above, the wire may slip too much during the winding of the wire to cause a winding gap, and the wire may not be wound. If s exceeds the above range, slipping may be poor at the time of winding, and the wound after winding may occur. s is more preferably 3 to 5.
- the boppin is preferably biaxial.
- the two axes biaxially, it is possible to promote the formation of pores.
- a method for producing a boppin with a lightness of 0142 for example, a poppin having a sex, including a ppi with a ton ratio of 3 or more, or
- the ton ratio of the tongue is 6 or more, and the tongue having the sex is prepared.
- the boppin of the light of 32 for example, the following () o (S)> 61 o () 82 ()
- a method of producing a light-emitting polypium film for example, a p-pin having a sex, including a p-pi with a ratio of 3 or more,
- the prepared pipes are supplied to the extruder, and at a rate of 2 to C, the data is extruded from a stack and cooled in a cast form on a cooling metal drum. It is also possible to add other ports outside the poppin to the prepared poppi.
- a cooling metal drum (6 to 3 C of a cas drum) is used to form a large amount of articles under moderate conditions, and the product is extremely low. High to make it transient . If the degree of the drum is above, the fraction of the obtained drum may decrease, and if it exceeds the above range, the transformation of the drum on the drum becomes insufficient, and it becomes difficult to separate the bird from the drum. There are cases. In addition, it is estimated that the transient property of the obtained material increases near the upper limit and decreases toward the lower limit in the above-mentioned temperature range, and depends on the in the obtained values.
- ⁇ is the sum of ⁇ and ⁇ is a sump, and corresponds to the fraction of the astrun line obtained using SC. If it is transient, cast drums are preferred to 25 ° C.
- the time when the end contacts the drum (hereinafter, sometimes simply referred to as "drum time") is .
- the interval between the drums means a time when the first landing on the drum in the above-mentioned casting process is a start time () and a time required until the point is released from the drum.
- the casting process is composed of a plurality of drums, the sum of the times when the casts contact the drums is the distance between the metal drums. If the distance between the drums is as described above, the weight of the two-axis shaft will be higher than necessary due to the sticking of the points at the above points and the small number of products generated at the points (low fraction of the points) (Is lower than necessary). If the distance between the drums exceeds the above range, depending on the size of the metal drum, the metal drum may be unnecessarily low and productivity may be remarkable.
- the drum is more preferably 7-45 and even more preferably 8-4 seconds.
- the method of the cooling drum may be a method using electrostatic force (hing), a method using surface force of water, an ani, a press, an underwater casting method, or the like.
- the thickness is good and the cooling rate can be controlled by the amount of attachment.
- a is attached to the drum surface, and it can be set to ⁇ 2C.
- the degree of the surface it may be possible to control the surface, and hence the surface, that is, to control the transientness of the obtained laser.
- the second and third layers are shared on one side of the bobbin.
- the obtained () is biaxially processed by using the above method.
- the wire is preheated through the wire kept at a predetermined temperature, and then the wire is passed through the wire kept at a predetermined temperature, and then extended in the longitudinal direction and cooled immediately.
- the (longitudinal) ratio is important. Normally, it is 3 to 4.5 times in the vertical direction when boppiny is manufactured, and if it exceeds 5 times, it becomes difficult to stabilize it, and it is broken. In the case of the invention's boppiny, if it is to be heavier and more transient, . If the orientation ratio is above, the weight of the obtained material may be high and the permeability may be inferior.Because of the low magnification, the production (line) may be delayed even at the same casting degree, and the productivity may be inferior. . If the rate of
- Dividing at least vertically into the above two points is in terms of transmission performance, surface control, etc. There are cases. It is possible to select an appropriate condition from the viewpoints of stability, unevenness of thickness, target and transparency. . In addition, at the time of
- the heat is led to a tenter formula, and is preheated at a certain degree and is prolonged.
- the direction is less than or equal to 2. If the propensity ratio exceeds two times, may worsen. It is necessary to select an appropriate condition from the viewpoints of stability, thickness, target or transparency. .
- After elongating in the direction of 0155 further increase the qualitative properties of the obtained material, and further increase the slack in the above direction.
- the boppine of the present invention is preferred as a feeling suitable for sublimation by coating the surface with a receptor and netting such as paper.
- the boppins of the present invention are preferred as articles such as wound materials, articles for clothing, articles for diapers and sanitary articles, and the like.
- the boppin of the above description is mainly composed of pipi, it is excellent in electrical insulation when used as a battery or electrolytic capacitor.
- the boppin of the invention can be biaxial, for example, it is superior in terms of extraction method, lamella, and conventional inorganic or non-organic materials. Roughness can also be given.
- conventional Compared with the conventional method, the permeability can be increased while maintaining the fineness, and the overperformance is equal to or higher than the above-mentioned method or the method using a lens. In this case, the electric resistance () can be reduced as compared with the conventional method.
- it since it has an excellent degree and protrusion, it is possible to make the center body thin while maintaining the value.
- the specific gravity of the boppin according to the invention is extremely low (is large), for example, when used as a battery, the electrolysis can be increased, and the battery capacity can be increased. Also, due to the over performance, the time required for electrolysis in the battery erecting process can be shortened as compared with the conventional method, and it has excellent strength and ruggedness. It has excellent battery life because of its excellent durability. In addition, by performing various treatments using various agents and the like, this can be further increased, and the battery stand-up can be further improved.
- the boppin of the present invention is preferred as a center.
- the boppin of the invention can be biaxial, for example, the tensile strength is the same even when the weight is the same as compared with the conventional method obtained by the extraction method, lamella, or inorganic or non-distributed. High reliability and excellent long-term reliability (operability). Further, by adding various agents and the like, the aqueous property of the obtained water can be controlled according to the quality of the water, and the transient property in the case of separation (iter) can be enhanced.
- the boppinies of these inventions can be used for various separations ) Is preferred.
- the fine holes are formed at the same time, the light-emitting bopypins 2 and 3 are excellent in concealment and optical properties.
- the second order as described below can further improve the reflectivity. Furthermore, by adding or spreading various kinds of agents or the like, reliability (usability) for long-term use can be imparted.
- a new function can be provided to the boppin of the light of 2, 3 and 3 by assembling various qualities to the boppin by the work of tin or the like. For example, by covering the wall with the refractive index material, the film and the substance due to the reflection, which has further improved properties, are coated on the wall, and by continuing these in the thickness direction, the electric conductivity in the thickness direction is obtained. However, it can be deployed outside of these areas, such as a conductive film in the inward direction of the camera or a drug that carries a drug.
- the boppin of the invention uses the conventional method, is capable of continuous operation, and can increase the productivity as compared with the conventional method, the above-mentioned method, melody or higher method can be used.
- the material having characteristics can be manufactured at a lower cost than the extraction method and the mellas.
- Ming Bhoppin can be preferred for packaging, industrial use, etc.
- Ton The measurement was performed on the following conditions using Poeee Scece 643 (972) of Cose. The measurements were performed at Sachicenter Co., Ltd.Twinki Ometa 22 type (ad)
- the inflow occurs at the capillary orifice (AP,... Is expressed in degrees and degrees).
- the degree strain and the degree morning line are approximated as numbers, respectively, and these numbers are used to calculate ⁇ at a strain of 6 s.
- the heat of fusion is the area surrounded by the sly calorie line until the calorie curve deviates from Sly with the rise and then returns to the position of the sly. And tried to process it.
- reference numeral 2 indicates the amount of heat released by the melting of the product
- reference numeral 3 indicates the amount of heat released by the other solutions. The same procedure can be used to confirm the nature of the pin tip. In the table, es for those with gender and o for those with gender.
- the sample was cut out to a size of 3 ⁇ 4 using Radio Co., Ltd. (S 2) and determined at 23 C 65 according to JS 72 (999) (alternative method). The same rule was applied to the sump for 5 lines, and the average of the obtained weights was defined as (d) of the sump.
- the film-shaped one is subjected to ejection processing as necessary, the required amount is taken out to the size below 5. Fill into the place at 23 C, and then It was pre-filled in 5 minutes to) at 25c in the display above, and was preheated in place. After 6 minutes from the sampling, the pouring was started according to the above conditions, and the strand was started to be stripped. After the sample was filled, data collection was started, and the average value of the specified force was collected between 2 and 6 minutes after filling (c). In addition, the same data was used for the sample obtained by using the attached software (key system program) for the sump, and the average value of the obtained S was defined as S of the sump.
- FIG. 3 is a diagram schematically showing the arrangement of the sump and the device at the time of collecting the 200 scan X-puis.
- the normal 5 to the image plane of the sump 4 is 0 () with respect to the human X 6, the cut is placed in front of the diffraction X 7, and the X counter is set. ) Is present, and the location of the counter is only 20 (.).
- the X source passes through the data, hysteresis, and the slit, and the X6 is obtained.
- Ometer 8 which is a rotatable axis for adjusting the degree with the counter counter sump. In squid, the sump is parallel to its shim plane,
- Fig. 4 schematically shows the position of the sump when the sump 3 was observed from the direction (3-5) in the line direction (3-5). Is every time two of the Ometa 8 sumps make.
- the sump is drawn in the upward direction for convenience, but the reference direction is clear, and if the X-rays shown below are constant, the vertical and horizontal sump Questionable. Sump has also been asked to evaluate the fabric in the gym.
- the film is set so that the surface of the film is parallel to the direction of 9 meters.
- the rotation peak of the (3) plane near 20 43 includes the component in the molecular direction. Therefore, 8.
- the ligature corresponds to lying mainly.
- Fig. 5 shows an example of the direction distribution pipe obtained in the following section.
- 6 is an example of the one obtained in the below.
- the direction ((), direction (()) is obtained by the following method.
- 0193 shows the sump and wide-angle X cases.
- X-Py was obtained by 200 scans.
- the sump dissolved in the C tetrane was measured using an Ostwald meter manufactured by Mitsui Co., Ltd. (dd). Five similar determinations were made for the sump, and the average of the obtained degrees was regarded as the degree of the sump.
- the amount of heat released (A As an example, the following was used from the calorific value (A as 2 of 3) generated from the absorption pipe accompanying the solution from the pupin except for the peak at 2C and 2C. . A small amount of heat or a peak may be observed between the peaks of A and the peak of A. However, this peak may be deleted.
- the sample was determined at 25C65 using an On-Tech Co., Ltd. Then, the sample was stretched for 3 minutes, and the Young (GPa) and (Pa) were measured.The same measurement was performed for 5 lines with a sump, and the average of the obtained Young and degree was regarded as the Young and degree of the sump.
- the state of ⁇ is discriminated from the X obtained by shooting the following three lines on 3. o Insert perpendicular to the plane formed by the parentheses () and (). Insert perpendicular to the plane formed by the parent's direction and perpendicular to the plane formed by the parent's direction.
- ⁇ Diffraction is obtained in the true direction of X, which reflects the deviation and whose diffraction degree is not equal.
- the description of 202, 2 and 3 will be explained based on the implementation. Note that only the desired Unless otherwise noted, the amount of pouring was adjusted to a predetermined value in order to obtain a positive result.
- the ton, the (S), the meteate (), the penta, (), the isotic index, and the index (11) of the puppies constituting the suffixes are designated as sumps.
- the values of the tones, (S), mates (), (), isotropic indices, and indexes (11) are the values specified for the pipes that make up the A layer to which the light is applied. It is the value specified for the pipe before the addition of the other po of the poly added with other poly outside the polyp.
- the properties, fractions, specific gravities, vacancies, and (c) of the properties of the layer are the values determined for the obtained body of the layer, both in the layered layer and in the layer to which other ports are added. .
- a prepin having the following composition was prepared.
- IGI Corporation GX-5 was added, and as heat, IGI Corporation G68 was added.
- the mixture was supplied to a biaxial shaft, cooled at 3 C, extruded into a shape, cooled through a 2 C bath, cooled to a chip length of 3, and then cooled at 2 C.
- the raw material and the raw material are supplied to the reactor at 22 C, and the filter of 2 is later heated to 2 C.
- the slabs were preheated by passing them through a group placed on C, then passed through a C-hold, cooled down to 8 C by 4 in the longitudinal direction with C. Subsequently, the end of this lip was held by a clip, introduced into a tester, preheated at 35C, and extended eight times in C. Then, 5 was given in the width direction in the tenter, fixed with C, made uniform, cooled to room temperature and rolled up to obtain a bobbin pin having a thickness of 25.
- Fig. 3 shows the result of the simulation and the simulation result.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability.
- Young in the longitudinal direction, high strength, and excellent qualitative properties were also obtained.
- Table 2 shows the results.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability.
- Young in the longitudinal direction, strength was high, and qualitative properties were excellent.
- the ratio in the longitudinal direction has been increased by 6 times.
- Table 2 shows the results.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability.
- Young in the longitudinal direction, strength was high, and qualitative properties were excellent.
- Example 2 The same condition was used as in Example 2, with 5 being the number of pipes, 5 in the longitudinal direction, and 7 in the width direction.
- the Boppin of this was implemented 4.
- Table 2 shows the results.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability.
- Young in the longitudinal direction, strength was high, and qualitative properties were excellent.
- Table 2 shows the results.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability.
- Young in the longitudinal direction, strength was high, and qualitative properties were excellent.
- a prepin having the following composition was prepared.
- Igi Co., Ltd. X As a heat source, Igi Co., Ltd. X was added, and as heat, Igi Co., Ltd., GO 68 was added. This was supplied to a biaxial shaft, extruded at 3 C into a shape, cooled through a 2 C bath to make the tip 3 length, and then cooled at 2 C.
- the raw material chips are supplied to, and at 22 C, a 2-meter filter is extruded from a metal heated to 2 C later, and the surface of the cast drum heated to 2 C and the drum surface Then, hot air heated to 4 C was sprayed using an annealer to form a ⁇ shape while closely adhering. At this time, it took 4 seconds with the gold drum.
- Table 2 shows the results.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability. Also, the Young's degree in the longitudinal direction was high and the qualitative properties were excellent.
- Table 2 shows the results.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability.
- Young in the longitudinal direction, strength was high, and qualitative properties were excellent.
- Table 2 shows the results.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability.
- Young in the longitudinal direction, strength was high, and qualitative properties were excellent.
- the results are shown in Table 3.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability.
- Young in the longitudinal direction, strength was high, and qualitative properties were excellent.
- the value was set to 5 and the degree in the longitudinal direction was set to C. Twenty-five boppinies made under the same conditions were implemented.
- Table 2 shows the results. The weight was excellent and the specific gravity was low. In addition, Young in the longitudinal direction, strength was high, and qualitative was excellent. 0227 ()
- step 2 the same as in step 2 was implemented.
- Table 2 shows the results.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability.
- Young in the longitudinal direction, strength was high, and qualitative properties were excellent.
- Example 2 25 boppinies prepared in the same manner as in the case of “5” of the puppies possessed were evaluated as “Example 2”.
- Table 2 shows the results.
- the obtained material was excellent in water resistance, low in specific gravity, and excellent in permeability.
- Young in the longitudinal direction, strength was high, and qualitative properties were excellent.
- a 4C wind was blown from the drum side of the drum using an ani, and the pieces were pressed into close contact with each other. At this time, it took 4 seconds with the gold drum. In addition, the layer C was extruded from the base so that it came into contact with the metal drum.
- Table 3 shows the results. The obtained image was excellent in low weight and low specific gravity. In addition, Young in the longitudinal direction, strength was high, and qualitative was excellent. 0234 (
- the degree in the longitudinal direction was set to 2 C.
- Tables 2 and 4 show the results.
- the obtained im had higher specific gravity and insufficient permeation performance as compared with the im obtained by using the stand.
- a prepin having the following composition was prepared.
- IGI Corporation GX-5 was added, and as heat, IGI Corporation G68 was added.
- the mixture was supplied to a biaxial shaft, cooled at 3 C, extruded into a shape, cooled through a 2 C bath, cooled to a chip length of 3, and then cooled at 2 C.
- Raw material chips, Idemitsu as hollow 5) The added resin composition was supplied at a time, and the mixture was extruded at 28 ° C from a hot metal heated to 26 ° C.
- the heated just drum was molded into a shape by blowing a 4C air from the drum side of the just and ii using an annihilator and closely contacting each other. In this case, it took 4 seconds with the gold drum.
- the preheated heat is passed through a group placed on C, and while it is kept at C, it is cooled down to warm immediately in the longitudinal direction. Subsequently, the end of this tube was held in a cup, introduced into a tenter, preheated at 65, and expanded 9-fold at 5 C. Then, 8 was given in the width direction in the tenter, and the temperature was fixed at 6 C. Then, the film was cooled and wound up to obtain a poppy with a thickness of 25.
- Tables 2 and 4 show the results. In the just-casting process, the sticks could not be released while remaining sticky to the just drum, and could not be continuously fed, so it could not be manufactured industrially.
- Tables 2 and 4 show the results. ⁇ Since many tears occurred during stretching, satisfactory results could not be obtained at all, and it could not be manufactured industrially.
- Tables 2 and 4 show the results. Although the image obtained was excellent in, the specific gravity was extremely high, and its weight and clear appearance were presumed to be such that the hole was not substantially formed. You.
- the ratio in the longitudinal direction was reduced to four times, and the degree in the longitudinal direction was set to 2 C. Twenty-five bopins produced in the same manner were used.
- the results are shown in Tables 2 and 4.
- the obtained material had a higher specific gravity and was substantially permeable as compared with the material obtained by using the platform.
- the ratio in the longitudinal direction was reduced to four times, and the degree in the longitudinal direction was set to 2 C.
- a 25 x bobbin made in the same manner was designated as 2.
- the results are shown in Tables 2 and 4.
- the obtained material had a higher specific gravity and was substantially permeable as compared with the material obtained by using the platform.
- the ratio in the longitudinal direction was reduced to 4 times, and the degree in the longitudinal direction was set to 25C.
- the results are shown in Tables 2 and 4.
- the obtained material had a higher specific gravity and was substantially permeable as compared with the material obtained by using the platform.
- the results are shown in Tables 2 and 4.
- the obtained material had a higher specific gravity and was substantially permeable as compared with the material obtained by using the platform.
- Tables 2 and 4 show the results. Since many tears occurred during stretching, satisfactory results could not be obtained at all, and it could not be manufactured industrially.
- Example 8 the ratio in the longitudinal direction was reduced to 4 times, and the degree in the longitudinal direction was set to 25 ° C. It was set to 9.
- Tables 2 and 4 show the results.
- the resulting im- ages were obtained with the platform and had a higher specific gravity than the ims.
- the bright bones include poppies with a ton ratio of 3 and / or include poppies with and / or having a ton ratio of 6; By having the property, was able to improve significantly. Also, at a low temperature Even so, it is a function that does not break the image, and the burden has been further reduced. Furthermore, the transitivity could be controlled by the composition, raw material composition and conditions of the im, and the permeability could be significantly improved.
- Example 3 An S image obtained when observed with an electron microscope (S) was shown. (7, 8 of 6) was also observed on the misaligned surface, and a fine quiver (7, 8, 7) was observed in the hole.
- Example 3 no substantial enlargement and non-uniformity of pores were observed, although the temperature was much lower than in Comparative Example 2. Even more surprisingly, it was confirmed that the number of quids having the size of nome order was larger in Example 3 than in Comparative Example 2, and the structure was fine.
- the structure is controlled by including a sex having a ton ratio of 3 or more, and / or having a ton ratio of 6 or more. It has been found possible. This is the force
- a prepin having the following composition was prepared.
- S in the above SPP is a value measured under the conditions of 5 minutes for taking over.
- IGI Corporation GX-5 was added, and as heat, IGI Corporation G68 was added. This was supplied to a biaxial shaft, cooled at 3 C, extruded into a shape, cooled through a 2 C bath, cooled to a chip length, and then cooled at 2 C.
- the raw material chips are supplied to, and the 2nd pit is extruded from the metal heated to 2 C later, and then formed on a metal drum (casting drum, cast drum) heated to 2 C on the surface Casing and the drums were molded into a shape by using an anai from the drum side of the cassette and using hot air blown by heating in step 4 to make close contact with each other. At this time, it took 4 seconds with the gold drum.
- a metal drum casting drum, cast drum
- the mixture was fixed with C, cooled, cooled to room temperature and rolled up to obtain a 25-inch thick bobbin.
- the results and the results of the experiments are shown in 5, 7 and 8, respectively.
- the obtained material was excellent in, high in, and excellent in permeability.
- Young in the longitudinal direction, high strength, and excellent qualitative properties were also obtained.
- Example 2 25 boppinies produced in the same manner with the ratio in the longitudinal direction increased to 5 times were designated as 22.
- Example 24 the number of bopipins was 2, the length was set to 5 and the width was set to 7, and 25 bopinpiins manufactured in the same manner were designated as Example 24.
- a prepin having the following composition was prepared.
- Igi Co., Ltd. X was added, and as heat, Igi Co., Ltd. 68 was added.
- the raw material chips are supplied to, and at 22 C, a 2-meter filter is extruded from a metal heated to 2 C later, and the surface of the cast drum heated to 2 C and the drum surface Then, hot air heated to 4 C was sprayed using an annealer to form and adhere to each other while the pieces were closely adhered to each other. In this case, 4 with the gold drum It was.
- the preheated pieces are passed through a group placed on C and preheated, passed through a holding section at C, cooled down to C in the longitudinal direction. 5
- the end of the mushroom was held by a cup, introduced into a tenter, preheated by C, and extended by 8 times in C. 5 in the width direction in the tenter
- the mixture was fixed with C, cooled, cooled to room temperature, and rolled up to obtain a bolus film having a thickness of 2.
- ⁇ was set to 5
- ⁇ was set to C in the longitudinal direction.
- the cast drum heated to C was blown out from the drum side of the cass and the drum with an anani to blow the air at 4 C, and the cast drum was pressed into a tight shape to obtain a cast. At this time, it took 4 seconds with the gold drum. In addition, the C layer was extruded out of the mouthpiece so as to contact the metal drum.
- the (C) heat was passed through a group placed on C, preheated, passed through a holding place at C, cooled down to 9 C by 5 in the longitudinal direction with C. Subsequently, the end of the image was held in a cup, introduced into a tenter, preheated at 4 C, and heated to 8 at 4 C. Then, 5 was given in the width direction in the tenter, fixed at C, made uniform, cooled to room temperature and rolled up to obtain a 25-mm thick bobbin pin.
- Tables 6, 7 and 8 show the results and results of . Since many tears occurred during stretching, satisfactory results could not be obtained at all, and it could not be manufactured industrially.
- the degree in the longitudinal direction was set to 2 C.
- the ratio in the longitudinal direction was increased by a factor of 5 in 22 (23).
- a prepared lipoprotein was prepared.
- IGI Corporation G X 5 was added, and as heat, IGI Corporation G 68 was added.
- the mixture was supplied to a twin shaft, cooled at 28 C, extruded into a shape, cooled through a 2 C bath, cooled to a chip length of 5, and then cooled at 2 C.
- the raw material chips obtained as a cavity, and a resin composition containing 5 parts of Idemitsu Co., Ltd.
- a 4 C wind was blown from the drum side of the mist to the just-heated drum using an ani, and the pieces were molded into a to-like shape while being in close contact with each other.
- the time with the gold drum was 4 seconds.
- the temperature and elongation in the longitudinal direction were set to 32C and 37C, respectively, and the direction, preheating degree, elongation, and thermal constant temperature were set to 65 and 6C6C, respectively.
- the Poppin of 25 was set to 29.
- the ratio in the longitudinal direction was reduced to 4 times, and the degree in the longitudinal direction was set to 25C.
- the ratio in the longitudinal direction was reduced to 4 times, and the degree in the longitudinal direction was set to 25 ° C.
- ⁇ was excellent in water content, low in specific gravity, and excellent in permeability.
- a prepin having the following composition was prepared.
- IGI GX Co., Ltd. 8 was added.
- the mixture was supplied to a biaxial shaft, cooled at 3 C, extruded in a gut shape, passed through a 2 C bath, cooled to a chip length of 3, and then cooled at 2 C.
- the raw material chips are supplied to, and the metal drums (casting drums and cast drums) heated on the surface 2C are extruded from a metal heated to 2C and then extruded from a 2-meter filter.
- hot air heated to 4 C was blown from the drum side of the cas and ii using an ani to adhere to each other to form a tee, thereby obtaining a tee. At this time, it took 4 seconds with the gold drum.
- the preheated pieces were passed through a group placed on C and preheated, passed through a holding section at C, cooled down to 75C by C in the longitudinal direction. Subsequently, the end of this box was held by a cup, introduced into a tenter, preheated by C, and extended by 8 times in C. Then, 5 was given in the width direction in the tenter, and the temperature was fixed with C. After being equalized, it was cooled down to room temperature and rolled up to obtain a boppin having a thickness of 2.
- Table 9 shows the results.
- the obtained material was excellent in, low in specific gravity and excellent in permeability (A).
- Young in the longitudinal direction, high strength, and excellent qualitative properties were also obtained.
- the thickness was set to 35 in 3.
- Bhoppin was implemented as 36. In addition, it was C232u of the obtained bone.
- Table 9 shows the results. It is said that In particular, the specific gravity was low and the permeability was excellent. In addition, Young in the longitudinal direction, high strength, and excellent qualitative properties were also obtained.
- Table 9 shows the results.
- the resulting image was excellent () and low in specific gravity.
- Young in the longitudinal direction, strength was high, and qualitative was excellent.
- This fat was supplied to the unit (b) at 26 C, and introduced into the above. Then, the extrusion (b) is laminated on the surface of the extrusion (a) with a mouthpiece, and is extruded into a cast shape. Then, a 4C wind was blown onto the plate to form a close-up while being closely adhered. In this case, it took 2 seconds with the gold drum.
- Table 9 shows the results.
- the obtained material was excellent () and low in specific gravity.
- Young in the longitudinal direction, strength was high, and qualitative was excellent.
- step 2 The boppin of step 2 has been reset.
- Table 9 shows the results of the simulations performed.
- the car As compared with the three cars, the car was low, the specific gravity was high, and the transmission performance was insufficient.
- the boppiny is 32. In addition, it was C2324 of the obtained bone.
- Table 9 shows the results. The weight of the car was lower and the specific gravity was higher than those of the three cars. (3 3)
- Table 9 shows the results. Since tears spattered during elongation (6), satisfactory results could not be obtained, and industrial production was not possible.
- Table 9 shows the results. The result was lower than that of three cars. In particular, the degree of gravity was higher than that of Nge, and the specific gravity was high because Nge did not work effectively. ()
- a puffin having the following composition and no pipi was added was prepared.
- IGI Corporation G X 5 was added, and as heat, IGI Corporation G 68 was added.
- the mixture was supplied to a biaxial shaft, cooled at 30 C, extruded into a shape, cooled through a 2 C bath, cooled to a chip length, and then cooled at C. 3 8
- Table 9 shows the results of (36) 0367 that were attempted in the same manner as that supplied in (a). Since many tears occurred during stretching (3), they were not entirely satisfactory and could not be industrially manufactured.
- Table 9 shows the results. The weight of the car was lower and the specific gravity was higher than those of the three cars. ()
- Segado 25 of sales was changed to 38.
- Segado 25 is a boppin using lamella.
- Table 9 shows the results.
- the key that was given was the key, and the specific gravity was higher than that of the three keys.
- the direction of the vehicle was too high, it had the property of being easily driven.
- the selected boppi is the next boppi shown in the comparison. () And () are extremely high compared to
- the physical properties in the longitudinal direction are high even when the specific gravity is low. In this way, compared to conventional bobbin, even though the specific gravity is the same or lower, the physical properties in the longitudinal direction are higher, and the stock, winding, ting, garment, and stamping after and after Excellent in long-lasting, in-person, long-lasting, and dangling in the printing and netting processes. Therefore, the high () (of the obtained key was able to achieve both the weight and the transient and non-tongue properties at a high level, and the key obtained was low in specific gravity, It is excellent in transparency, and this transitivity can be improved by adding different types of cells from the viewpoint of advancement. () () Should be controlled by the condition represented by the rate. Thus, if the rate is increased further in this direction, the production tends to deteriorate in the first place, but by controlling the raw materials, the quality is maintained, and the above-mentioned superior performance is obtained.
- the above-mentioned useable, 0372, 2 light boppin is superior in that it has less lazyness than the conventional boppin. Furthermore, for example, it can be manufactured without breaking even if the rate is increased at a very low temperature, the line degree can be increased as compared with the conventional, and the productivity is excellent. In addition, by extending the ratio in a higher direction, the specific gravity can be reduced and the degree in the longitudinal direction can be increased as compared with the conventional case. Occasionally the permeability can be significantly improved.
- the 03733 light boppin has a higher degree of connection in the direction of the arrow than the conventional boppin. As a result, the physical properties in the longitudinal direction are excellent, so that the donability in the secondary construction process is excellent.
- the boppin of the invention is also excellent in qualitative properties and the like, it can be used for synthesizing, feeling, optical parts, building materials, separation (ita), wound materials, etc. Demonstrates excellent properties in fields such as garments, diapers and sanitary goods, batteries and electrolytic capacitors, inks, oils and fats, blood glucose sensors, and tank membranes. You.
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Description
Claims
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/578,884 US8491991B2 (en) | 2004-04-22 | 2005-04-21 | Microporous polypropylene film and process for producing the same |
EP05734391A EP1757653B1 (en) | 2004-04-22 | 2005-04-21 | Microporous polypropylene film and process for producing the same |
CN2005800206499A CN1972986B (zh) | 2004-04-22 | 2005-04-21 | 微孔性聚丙烯薄膜及其制造方法 |
KR1020067021685A KR101243091B1 (ko) | 2004-04-22 | 2005-04-21 | 미공성 폴리프로필렌 필름 및 그 제조방법 |
KR1020127034161A KR101342934B1 (ko) | 2004-04-22 | 2005-04-21 | 미공성 폴리프로필렌 필름 |
KR1020127034159A KR101316671B1 (ko) | 2004-04-22 | 2005-04-21 | 미공성 폴리프로필렌 필름 및 그 제조방법 |
DE602005026121T DE602005026121D1 (de) | 2004-04-22 | 2005-04-21 | Mikroporöse polypropylenfolie und herstellungsverfahren dafür |
AT05734391T ATE496963T1 (de) | 2004-04-22 | 2005-04-21 | Mikroporöse polypropylenfolie und herstellungsverfahren dafür |
AU2005235863A AU2005235863A1 (en) | 2004-04-22 | 2005-04-21 | Microporous polypropylene film and process for producing the same |
CA2563787A CA2563787C (en) | 2004-04-22 | 2005-04-21 | Microporous polypropylene film having a .beta.-crystal activity and a low specific gravity |
JP2006512577A JP4984890B2 (ja) | 2004-04-22 | 2005-04-21 | 微孔性ポリプロピレンフィルムおよびその製造方法 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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JP2004126572 | 2004-04-22 | ||
JP2004126571 | 2004-04-22 | ||
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EP (2) | EP1757653B1 (ja) |
JP (3) | JP4984890B2 (ja) |
KR (3) | KR101316671B1 (ja) |
CN (2) | CN101880419B (ja) |
AT (1) | ATE496963T1 (ja) |
AU (1) | AU2005235863A1 (ja) |
CA (3) | CA2563787C (ja) |
DE (1) | DE602005026121D1 (ja) |
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