MX2014005847A - Baterias de litio-azufre con electrolito acuoso. - Google Patents
Baterias de litio-azufre con electrolito acuoso.Info
- Publication number
- MX2014005847A MX2014005847A MX2014005847A MX2014005847A MX2014005847A MX 2014005847 A MX2014005847 A MX 2014005847A MX 2014005847 A MX2014005847 A MX 2014005847A MX 2014005847 A MX2014005847 A MX 2014005847A MX 2014005847 A MX2014005847 A MX 2014005847A
- Authority
- MX
- Mexico
- Prior art keywords
- aqueous electrolyte
- sulfur
- lithium sulfur
- combination
- applications
- Prior art date
Links
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/02—Details
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/26—Selection of materials as electrolytes
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
- H01M4/5815—Sulfides
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
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- H01M8/20—Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
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- H01M10/052—Li-accumulators
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- H01M2300/0002—Aqueous electrolytes
- H01M2300/0014—Alkaline electrolytes
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- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
- H01M2300/0037—Mixture of solvents
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- H01M4/381—Alkaline or alkaline earth metals elements
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- H01M4/386—Silicon or alloys based on silicon
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
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- H01M4/405—Alloys based on lithium
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/665—Composites
- H01M4/667—Composites in the form of layers, e.g. coatings
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/72—Grids
- H01M4/74—Meshes or woven material; Expanded metal
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- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/80—Porous plates, e.g. sintered carriers
- H01M4/806—Nonwoven fibrous fabric containing only fibres
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
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- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/80—Porous plates, e.g. sintered carriers
- H01M4/808—Foamed, spongy materials
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- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/70—Arrangements for stirring or circulating the electrolyte
- H01M50/77—Arrangements for stirring or circulating the electrolyte with external circulating path
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Conductive Materials (AREA)
Abstract
Se proporcionan células de batería de litio-azufre que utilizan agua como un solvente electrolítico. En diversas modalidades, el solvente de agua mejora uno o más de los siguientes atributos de la célula: densidad de energía, densidad de potencia y ciclo de vida. También se puede alcanzar una reducción significativa de costo al utilizar un electrólito acuoso en combinación con un cátodo de azufre. Por ejemplo, en aplicaciones donde es primordial el costo por Watt-hora (Wh), tal como en aplicaciones de almacenamiento de rejilla y tracción, el uso de un electrólito acuoso en combinación con azufre económico como el material activo catódico puede ser un factor cable para la utilidad y las industrias automotrices, proporcionando una solución de costo redituable y compacta para reparto de carga, vehículos eléctricos y almacenamiento de energía renovable.
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161560134P | 2011-11-15 | 2011-11-15 | |
US201261585589P | 2012-01-11 | 2012-01-11 | |
US13/440,847 US8828573B2 (en) | 2011-11-15 | 2012-04-05 | Electrode structures for aqueous electrolyte lithium sulfur batteries |
US201261623031P | 2012-04-11 | 2012-04-11 | |
US13/475,324 US8828574B2 (en) | 2011-11-15 | 2012-05-18 | Electrolyte compositions for aqueous electrolyte lithium sulfur batteries |
US13/676,487 US8828575B2 (en) | 2011-11-15 | 2012-11-14 | Aqueous electrolyte lithium sulfur batteries |
PCT/US2012/065251 WO2013074772A1 (en) | 2011-11-15 | 2012-11-15 | Aqueous electrolyte lithium sulfur batteries |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2014005847A true MX2014005847A (es) | 2014-08-01 |
Family
ID=48430140
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014005847A MX2014005847A (es) | 2011-11-15 | 2012-11-15 | Baterias de litio-azufre con electrolito acuoso. |
Country Status (9)
Country | Link |
---|---|
US (2) | US8828575B2 (es) |
EP (1) | EP2780971A4 (es) |
JP (1) | JP2015503189A (es) |
KR (1) | KR20140096363A (es) |
CN (1) | CN104054209A (es) |
BR (1) | BR112014011715A2 (es) |
CA (1) | CA2854355A1 (es) |
MX (1) | MX2014005847A (es) |
WO (1) | WO2013074772A1 (es) |
Families Citing this family (69)
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US9660265B2 (en) | 2011-11-15 | 2017-05-23 | Polyplus Battery Company | Lithium sulfur batteries and electrolytes and sulfur cathodes thereof |
US8828574B2 (en) | 2011-11-15 | 2014-09-09 | Polyplus Battery Company | Electrolyte compositions for aqueous electrolyte lithium sulfur batteries |
US8828573B2 (en) | 2011-11-15 | 2014-09-09 | Polyplus Battery Company | Electrode structures for aqueous electrolyte lithium sulfur batteries |
DE102011088910A1 (de) * | 2011-12-16 | 2013-06-20 | Robert Bosch Gmbh | Lithium-Schwefel-Zellen-Separator mit Polysulfidsperrschicht |
CN103427125B (zh) * | 2012-05-15 | 2016-04-13 | 清华大学 | 硫基聚合物锂离子电池的循环方法 |
KR101488296B1 (ko) * | 2012-12-27 | 2015-01-30 | 현대자동차주식회사 | 리튬 이차전지 셀 구조 |
JP6055365B2 (ja) * | 2013-04-19 | 2016-12-27 | 本田技研工業株式会社 | 電解液供給型電池及びその操作方法 |
KR101508128B1 (ko) * | 2013-04-22 | 2015-04-08 | 한국에너지기술연구원 | 리튬-공기 전지용 양극, 그의 제조방법 및 그를 포함하는 리튬-공기 전지 |
JP2016526757A (ja) * | 2013-06-19 | 2016-09-05 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 再充電可能な電気化学セル用のアルカリイオン伝導性セパレーターアセンブリ |
CA2820635A1 (en) * | 2013-06-21 | 2014-12-21 | Hydro-Quebec | All-solid state polymer li-s electrochemical cells and their manufacturing processes |
JP6629200B2 (ja) | 2013-08-08 | 2020-01-15 | シオン・パワー・コーポレーション | 電気化学電池における自己回復電極保護 |
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US9882243B2 (en) | 2013-09-26 | 2018-01-30 | Eaglepicher Technologies, Llc | Lithium-sulfur battery and methods of reducing insoluble solid lithium-polysulfide depositions |
US9991493B2 (en) | 2013-10-15 | 2018-06-05 | Eaglepicher Technologies, Llc | High energy density non-aqueous electrochemical cell with extended operating temperature window |
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CA2957918A1 (en) | 2014-08-11 | 2016-02-18 | The Arizona Board Of Regents On Behalf Of The University Of Arizona | Aligned graphene-carbon nanotube porous carbon composite |
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EP3204971A4 (en) * | 2014-10-08 | 2018-10-24 | Wayne State University | Electrocatalysis of lithium polysulfides: current collectors as electrodes in li/s battery configuration |
KR101868196B1 (ko) * | 2014-10-31 | 2018-06-15 | 주식회사 엘지화학 | 다층구조의 황전극을 포함하는 리튬-황 전지 |
US10147968B2 (en) | 2014-12-02 | 2018-12-04 | Polyplus Battery Company | Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods |
US11749834B2 (en) | 2014-12-02 | 2023-09-05 | Polyplus Battery Company | Methods of making lithium ion conducting sulfide glass |
US11984553B2 (en) | 2014-12-02 | 2024-05-14 | Polyplus Battery Company | Lithium ion conducting sulfide glass fabrication |
US10164289B2 (en) | 2014-12-02 | 2018-12-25 | Polyplus Battery Company | Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods |
US10601071B2 (en) | 2014-12-02 | 2020-03-24 | Polyplus Battery Company | Methods of making and inspecting a web of vitreous lithium sulfide separator sheet and lithium electrode assemblies |
US10461321B2 (en) * | 2015-02-18 | 2019-10-29 | Nanotek Instruments, Inc. | Alkali metal-sulfur secondary battery containing a pre-sulfurized cathode and production process |
WO2016160703A1 (en) | 2015-03-27 | 2016-10-06 | Harrup Mason K | All-inorganic solvents for electrolytes |
KR101704186B1 (ko) * | 2015-04-16 | 2017-02-07 | 현대자동차주식회사 | 리튬황 전고체 전지 양극 |
US10439219B2 (en) | 2015-04-17 | 2019-10-08 | Uchicago Argonne, Llc | Ultrastable cathodes for lithium sulfur batteries |
CN106549188B (zh) * | 2015-09-18 | 2019-01-22 | 中国科学院大连化学物理研究所 | 一种锌硫单液流电池系统 |
WO2017075577A1 (en) | 2015-10-30 | 2017-05-04 | Massachusetts Institute Of Technology | Air-breathing aqueous sulfur rechargeable batteries |
EP3420610A4 (en) * | 2016-02-26 | 2019-10-09 | Case Western Reserve University | COMPOSITE MEMBRANES FOR CIRCULATING BATTERIES |
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-
2012
- 2012-11-14 US US13/676,487 patent/US8828575B2/en not_active Expired - Fee Related
- 2012-11-15 CA CA2854355A patent/CA2854355A1/en not_active Abandoned
- 2012-11-15 EP EP12850015.4A patent/EP2780971A4/en not_active Withdrawn
- 2012-11-15 BR BR112014011715A patent/BR112014011715A2/pt not_active Application Discontinuation
- 2012-11-15 CN CN201280066987.6A patent/CN104054209A/zh active Pending
- 2012-11-15 JP JP2014542457A patent/JP2015503189A/ja active Pending
- 2012-11-15 WO PCT/US2012/065251 patent/WO2013074772A1/en active Application Filing
- 2012-11-15 MX MX2014005847A patent/MX2014005847A/es active IP Right Grant
- 2012-11-15 KR KR1020147016013A patent/KR20140096363A/ko not_active Application Discontinuation
-
2014
- 2014-07-17 US US14/334,573 patent/US20140322584A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
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US20140322584A1 (en) | 2014-10-30 |
BR112014011715A2 (pt) | 2017-05-09 |
CN104054209A (zh) | 2014-09-17 |
KR20140096363A (ko) | 2014-08-05 |
WO2013074772A1 (en) | 2013-05-23 |
EP2780971A1 (en) | 2014-09-24 |
CA2854355A1 (en) | 2013-05-23 |
JP2015503189A (ja) | 2015-01-29 |
EP2780971A4 (en) | 2015-07-08 |
US8828575B2 (en) | 2014-09-09 |
US20130141050A1 (en) | 2013-06-06 |
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