KR101354477B1 - 메탈로센 촉매, 그 합성 및 올레핀들의 중합을 위한 그 용도 - Google Patents

메탈로센 촉매, 그 합성 및 올레핀들의 중합을 위한 그 용도 Download PDF

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Publication number
KR101354477B1
KR101354477B1 KR1020077012546A KR20077012546A KR101354477B1 KR 101354477 B1 KR101354477 B1 KR 101354477B1 KR 1020077012546 A KR1020077012546 A KR 1020077012546A KR 20077012546 A KR20077012546 A KR 20077012546A KR 101354477 B1 KR101354477 B1 KR 101354477B1
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South Korea
Prior art keywords
methyl
indenyl
phenyl
zirconium dichloride
carbon atoms
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Korean (ko)
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KR20070092217A (ko
Inventor
니콜라 파츠코우스키
안드레아스 윈터
프란즈 랑그하우저
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노볼렌 테크놀로지 홀딩스 씨.브이.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1020077012546A 2004-12-01 2005-12-01 메탈로센 촉매, 그 합성 및 올레핀들의 중합을 위한 그 용도 Expired - Fee Related KR101354477B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/001,272 2004-12-01
US11/001,272 US7169864B2 (en) 2004-12-01 2004-12-01 Metallocene catalysts, their synthesis and their use for the polymerization of olefins
PCT/US2005/043421 WO2006060544A1 (en) 2004-12-01 2005-12-01 Metallocene catalysts, their synthesis and their use for the polymerization of olefins

Publications (2)

Publication Number Publication Date
KR20070092217A KR20070092217A (ko) 2007-09-12
KR101354477B1 true KR101354477B1 (ko) 2014-01-24

Family

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KR1020077012546A Expired - Fee Related KR101354477B1 (ko) 2004-12-01 2005-12-01 메탈로센 촉매, 그 합성 및 올레핀들의 중합을 위한 그 용도

Country Status (13)

Country Link
US (3) US7169864B2 (https=)
EP (1) EP1828266B1 (https=)
JP (2) JP5311827B2 (https=)
KR (1) KR101354477B1 (https=)
CN (2) CN103012623B (https=)
AR (2) AR052985A1 (https=)
BR (1) BRPI0518701B8 (https=)
ES (1) ES2548726T3 (https=)
MX (1) MX2007006313A (https=)
RU (1) RU2360931C2 (https=)
SG (1) SG158099A1 (https=)
WO (1) WO2006060544A1 (https=)
ZA (1) ZA200704403B (https=)

Cited By (4)

* Cited by examiner, † Cited by third party
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KR20170075533A (ko) * 2015-12-23 2017-07-03 주식회사 엘지화학 혼성 담지 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법
US9783557B2 (en) 2014-10-17 2017-10-10 Lg Chem, Ltd. Metallocene catalyst for preparing a high molecular weight polyolefin and a preparation method thereof
US9884926B2 (en) 2014-11-06 2018-02-06 Lg Chem, Ltd. Metallocene catalyst for preparing a high molecular weight polyolefin and a preparation method thereof
US10889667B2 (en) 2016-02-17 2021-01-12 Lg Chem, Ltd. High-stiffness and energy-reducing polypropylene for foaming

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US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
US7598329B2 (en) * 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
US7683002B2 (en) * 2006-04-04 2010-03-23 Fina Technology, Inc. Transition metal catalyst and formation thereof
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KR19980051220A (ko) * 1996-12-23 1998-09-15 김종진 유동성 실리카를 이용한 담지형 알루미녹산의 제조방법
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US9783557B2 (en) 2014-10-17 2017-10-10 Lg Chem, Ltd. Metallocene catalyst for preparing a high molecular weight polyolefin and a preparation method thereof
US9884926B2 (en) 2014-11-06 2018-02-06 Lg Chem, Ltd. Metallocene catalyst for preparing a high molecular weight polyolefin and a preparation method thereof
KR20170075533A (ko) * 2015-12-23 2017-07-03 주식회사 엘지화학 혼성 담지 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법
KR102080640B1 (ko) 2015-12-23 2020-05-27 주식회사 엘지화학 혼성 담지 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법
US10889667B2 (en) 2016-02-17 2021-01-12 Lg Chem, Ltd. High-stiffness and energy-reducing polypropylene for foaming

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BRPI0518701B1 (pt) 2018-09-25
MX2007006313A (es) 2007-11-23
CN103012623A (zh) 2013-04-03
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ES2548726T3 (es) 2015-10-20
US20080287286A1 (en) 2008-11-20
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AR052985A1 (es) 2007-04-18
US20060116490A1 (en) 2006-06-01
US20070082806A1 (en) 2007-04-12
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RU2360931C2 (ru) 2009-07-10
CN101124252B (zh) 2011-10-05
WO2006060544A1 (en) 2006-06-08
ZA200704403B (en) 2008-09-25
BRPI0518701A2 (pt) 2008-12-02
JP2008522013A (ja) 2008-06-26
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SG158099A1 (en) 2010-01-29
BRPI0518701B8 (pt) 2023-01-24
US7169864B2 (en) 2007-01-30
EP1828266A1 (en) 2007-09-05
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