AR084818A2 - Catalizador metaloceno, su sintesis y sus usos en la polimerizacion de olefinas - Google Patents

Catalizador metaloceno, su sintesis y sus usos en la polimerizacion de olefinas

Info

Publication number
AR084818A2
AR084818A2 ARP120100076A ARP120100076A AR084818A2 AR 084818 A2 AR084818 A2 AR 084818A2 AR P120100076 A ARP120100076 A AR P120100076A AR P120100076 A ARP120100076 A AR P120100076A AR 084818 A2 AR084818 A2 AR 084818A2
Authority
AR
Argentina
Prior art keywords
catalyst
aluminoxane
synthesis
olefine polymerization
metalocene catalyst
Prior art date
Application number
ARP120100076A
Other languages
English (en)
Inventor
Nicolas S Paczkowski
Andreas Winter
Franz Langhauser
Original Assignee
Novolen Tech Holdings Cv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novolen Tech Holdings Cv filed Critical Novolen Tech Holdings Cv
Publication of AR084818A2 publication Critical patent/AR084818A2/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Un procedimiento para la preparación de una disposición de catalizador que incluye las etapas de combinar un material de soporte con una primera composición que incluye por lo menos un aluminoxano en un primer solvente para proveer un soporte cargado con aluminoxano y, poner en contacto el soporte cargado con aluminoxano con una segunda composición que incluye por lo menos un compuesto metaloceno, un segundo solvente, y un co-catalizador, donde el co-catalizador incluye una segunda porción del por lo menos un aluminoxano solo o en combinación con un compuesto iónico y/o ácido Lewis.
ARP120100076A 2004-12-01 2012-01-10 Catalizador metaloceno, su sintesis y sus usos en la polimerizacion de olefinas AR084818A2 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/001,272 US7169864B2 (en) 2004-12-01 2004-12-01 Metallocene catalysts, their synthesis and their use for the polymerization of olefins

Publications (1)

Publication Number Publication Date
AR084818A2 true AR084818A2 (es) 2013-06-26

Family

ID=36129857

Family Applications (2)

Application Number Title Priority Date Filing Date
ARP050105020A AR052985A1 (es) 2004-12-01 2005-11-30 Catalizador metaloceno su sintesis y sus usos en la polimerizacion de olefinas
ARP120100076A AR084818A2 (es) 2004-12-01 2012-01-10 Catalizador metaloceno, su sintesis y sus usos en la polimerizacion de olefinas

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ARP050105020A AR052985A1 (es) 2004-12-01 2005-11-30 Catalizador metaloceno su sintesis y sus usos en la polimerizacion de olefinas

Country Status (13)

Country Link
US (3) US7169864B2 (es)
EP (1) EP1828266B1 (es)
JP (2) JP5311827B2 (es)
KR (1) KR101354477B1 (es)
CN (2) CN103012623B (es)
AR (2) AR052985A1 (es)
BR (1) BRPI0518701B8 (es)
ES (1) ES2548726T3 (es)
MX (1) MX2007006313A (es)
RU (1) RU2360931C2 (es)
SG (1) SG158099A1 (es)
WO (1) WO2006060544A1 (es)
ZA (1) ZA200704403B (es)

Families Citing this family (109)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
US7598329B2 (en) * 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
US20070299222A1 (en) 2006-04-04 2007-12-27 Fina Technology, Inc. Transition metal catalysts and formation thereof
US7683002B2 (en) * 2006-04-04 2010-03-23 Fina Technology, Inc. Transition metal catalyst and formation thereof
EP1930348A1 (en) 2006-12-05 2008-06-11 Ineos Manufacturing France SAS Supported catalyst system
BRPI0722162A2 (pt) * 2007-10-25 2014-03-18 Lummus Novolen Technology Gmbh Compostos de metaloceno, catalisadores compreendendo os mesmos, processo para produzir um polímero de olefina pelo uso de catalisadores, e homo-e copolímeros de olefina.
US8168556B2 (en) 2007-10-25 2012-05-01 Lummus Novolen Technology Gmbh Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
WO2009054833A2 (en) 2007-10-25 2009-04-30 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
KR101271055B1 (ko) * 2008-03-28 2013-06-04 에스케이종합화학 주식회사 메탈로센 담지촉매 조성물 및 이를 이용한 폴리올레핀의제조방법
US8076429B2 (en) * 2009-03-11 2011-12-13 Lummus Novolen Technology Gmbh Supertransparent high impact strength random block copolymer
KR101050791B1 (ko) * 2009-10-19 2011-07-20 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 혼성 담지 메탈로센 촉매
CN102712701A (zh) 2009-12-07 2012-10-03 尤尼威蒂恩技术有限责任公司 减少催化剂的静电荷的方法和使用该催化剂生产聚烯烃的方法
CN102666603B (zh) * 2009-12-22 2014-10-15 北欧化工公司 在单活性中心催化剂存在的情况下的聚丙烯制备
CN102803308B (zh) 2010-02-18 2015-04-01 尤尼威蒂恩技术有限公司 用于操作聚合反应器的方法
KR102009103B1 (ko) 2010-02-22 2019-08-08 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀 생산물을 생산하기 위한 촉매 시스템 및 이의 사용 방법
US20130046068A1 (en) 2010-03-08 2013-02-21 Hyuck-Ju Kwon Method for preparing supported metallocene catalyst and method for preparing polyolefin using the same
WO2011129956A1 (en) 2010-04-13 2011-10-20 Univation Technologies, Llc Polymer blends and films made therefrom
EP2386581B1 (en) 2010-05-07 2014-03-26 Borealis AG Preparation of a solid catalyst system
EP2402353B1 (en) 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
EP2402354B1 (en) 2010-07-01 2016-03-02 Borealis AG Process for olefin polymerisation using group 4 metallocene as catalysts
CN103097015B (zh) 2010-07-16 2015-11-25 尤尼威蒂恩技术有限责任公司 测量反应器表面上颗粒积聚的系统与方法
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
EP2633104A1 (en) 2010-10-28 2013-09-04 Lummus Novolen Technology Gmbh Nonwoven and yarn polypropylene with additivation
US20120116034A1 (en) 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
RU2587080C2 (ru) 2010-11-30 2016-06-10 Юнивейшн Текнолоджиз, Ллк Способы полимеризации олефинов с использованием экстрагированных карбоксилатов металлов
CN103298843B (zh) 2010-11-30 2015-08-19 尤尼威蒂恩技术有限责任公司 具有改进的流动特征的催化剂组合物及其制造和使用方法
MX337727B (es) 2010-12-17 2016-03-16 Univation Tech Llc Sistemas y metodos para recuperar hidrocarburos a partir de un producto de gas de purga de poliolefinas.
KR20140007360A (ko) 2010-12-22 2014-01-17 보레알리스 아게 가교된 메탈로센 촉매
ES2640318T3 (es) 2010-12-22 2017-11-02 Univation Technologies, Llc Aditivo para procedimientos de polimerización de olefinas
BR112013029135B1 (pt) 2011-05-13 2020-12-15 Univation Technologies, Llc Composição e processo de polimerização
WO2013028283A1 (en) 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
KR101485567B1 (ko) * 2011-09-07 2015-01-23 주식회사 엘지화학 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 담지 메탈로센 촉매
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
ES2729280T3 (es) 2011-11-08 2019-10-31 Univation Tech Llc Métodos para producir poliolefinas con sistemas catalíticos
EP2750797B1 (en) 2011-11-08 2020-04-01 Univation Technologies, LLC Methods of preparing a catalyst system
ES2711081T3 (es) 2012-10-18 2019-04-30 Borealis Ag Catalizador para la polimerización de olefinas
ES2622627T3 (es) 2012-10-18 2017-07-06 Borealis Ag Procedimiento de polimerización
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
US10280283B2 (en) 2012-12-28 2019-05-07 Univation Technologies, Llc Supported catalyst with improved flowability
BR112015018250B1 (pt) 2013-01-30 2021-02-23 Univation Technologies, Llc processo para produzir uma composição catalisadora e processo de polimerização
RU2654061C2 (ru) 2013-02-07 2018-05-16 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Получение полиолефина
WO2014143421A1 (en) 2013-03-15 2014-09-18 Univation Technologies, Llc Tridentate nitrogen based ligands for olefin polymerisation catalysts
EP2970526B1 (en) 2013-03-15 2017-08-09 Univation Technologies, LLC Ligands for catalysts
EP3004032B1 (en) 2013-06-05 2017-12-13 Univation Technologies, LLC Protecting phenol groups
EP3022237B1 (en) 2013-07-17 2018-10-03 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
WO2015009473A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
WO2015009471A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
EP3848401A1 (en) 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
KR101721194B1 (ko) * 2013-11-28 2017-03-29 주식회사 엘지화학 담지 메탈로센 촉매의 제조방법
EP3747913B1 (en) 2014-04-02 2024-04-17 Univation Technologies, LLC Continuity compositions and olefin polymerisation method using the same
EP3183059A1 (en) 2014-08-19 2017-06-28 Univation Technologies, LLC Fluorinated catalyst supports and catalyst systems
CN107148316B (zh) 2014-08-19 2020-10-09 尤尼威蒂恩技术有限责任公司 氟化催化剂载体和催化剂系统
CN106714967B (zh) 2014-08-19 2020-07-17 尤尼威蒂恩技术有限责任公司 氟化催化剂载体和催化剂系统
KR101653356B1 (ko) 2014-10-17 2016-09-01 주식회사 엘지화학 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법
CN105622795B (zh) * 2014-10-28 2019-02-19 中国石油化工股份有限公司 茂金属催化剂组合物及其制备方法
KR101653357B1 (ko) * 2014-11-06 2016-09-01 주식회사 엘지화학 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법
SG11201705607QA (en) 2015-01-21 2017-08-30 Univation Tech Llc Methods for controlling polymer chain scission
CN107107433B (zh) 2015-01-21 2019-09-13 尤尼威蒂恩技术有限责任公司 用于聚烯烃中的凝胶减少的方法
CN107428875B (zh) 2015-03-10 2021-02-26 尤尼威蒂恩技术有限责任公司 喷雾干燥催化剂组合物、制备方法以及在烯烃聚合工艺中的用途
SG11201708069UA (en) 2015-04-08 2017-10-30 Univation Tech Llc Closed reactor transitions between metallocene catalysts
WO2016171810A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
US10519256B2 (en) 2015-04-27 2019-12-31 Univation Technologies, Llc Supported catalyst compositions having improved flow properties and preparation thereof
KR102080640B1 (ko) * 2015-12-23 2020-05-27 주식회사 엘지화학 혼성 담지 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법
KR101969123B1 (ko) 2016-02-17 2019-08-20 주식회사 엘지화학 고강성 및 에너지 절감 발포용 폴리프로필렌
WO2018009016A2 (ko) * 2016-07-07 2018-01-11 주식회사 엘지화학 폴리올레핀 제조용 메탈로센 촉매의 제조방법
KR102064412B1 (ko) 2016-07-07 2020-01-09 주식회사 엘지화학 폴리올레핀 제조용 메탈로센 촉매의 제조방법
KR102206479B1 (ko) * 2016-12-26 2021-01-21 주식회사 엘지화학 담지 메탈로센 촉매의 제조방법
WO2018151903A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
CN111094366B (zh) 2017-08-04 2022-06-24 埃克森美孚化学专利公司 聚乙烯组合物和由其制备的膜
US11021552B2 (en) * 2017-10-31 2021-06-01 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
KR102326791B1 (ko) * 2017-11-27 2021-11-16 주식회사 엘지화학 폴리프로필렌 및 그 제조방법
WO2019103306A1 (ko) * 2017-11-27 2019-05-31 주식회사 엘지화학 폴리프로필렌 및 그 제조방법
KR102405286B1 (ko) * 2017-12-06 2022-06-02 주식회사 엘지화학 메탈로센 담지 촉매의 제조방법, 상기 제조방법으로 제조된 메탈로센 담지 촉매, 및 이를 제조하여 제조한 폴리프로필렌
KR102464410B1 (ko) * 2017-12-14 2022-11-04 주식회사 엘지화학 필라멘트용 폴리프로필렌 및 그 제조방법
KR102343937B1 (ko) 2017-12-26 2021-12-27 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용한 폴리프로필렌의 제조 방법
WO2019156482A1 (ko) * 2018-02-08 2019-08-15 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조방법
KR102342780B1 (ko) * 2018-02-08 2021-12-23 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조방법
WO2019210030A1 (en) 2018-04-26 2019-10-31 Exxonmobil Chemical Patents Inc. Non-coordinating anion type activators containing cation having branched alkyl groups
US20210002397A1 (en) * 2018-05-09 2021-01-07 Borealis Ag Process for preparing propylene copolymers comprising c4-c12-apha olefin comonomer units
CN112313254B (zh) 2018-06-19 2023-04-18 埃克森美孚化学专利公司 聚乙烯组合物和由其制备的膜
KR102431269B1 (ko) 2018-11-02 2022-08-10 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법
KR102372221B1 (ko) 2018-11-06 2022-03-10 주식회사 엘지화학 프로필렌 공중합체 수지 조성물 및 그 제조방법
KR102388031B1 (ko) 2018-11-06 2022-04-19 주식회사 엘지화학 펠렛형 폴리프로필렌 수지 및 그 제조방법
KR102576669B1 (ko) * 2018-12-26 2023-09-11 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용한 올레핀계 중합체의 제조방법
EP3976668A1 (en) 2019-05-29 2022-04-06 Borealis AG Catalyst system
WO2021001176A1 (en) 2019-07-04 2021-01-07 Borealis Ag Long chain branched propylene polymer composition
KR102482938B1 (ko) * 2019-09-30 2022-12-29 주식회사 엘지화학 펠렛형 폴리프로필렌 수지 조성물 및 그 제조방법
WO2021119089A1 (en) 2019-12-11 2021-06-17 Exxonmobil Chemical Patents Inc. Processes for introduction of liquid activators in olefin polymerization reactions
WO2021126523A1 (en) 2019-12-19 2021-06-24 Exxonmobil Chemical Patents Inc. Production of impact copolymer polypropylene using metallocene and ziegler-natta catalysts in parallel reactors
CN115485311A (zh) 2020-02-24 2022-12-16 埃克森美孚化学专利公司 用于生产乙烯叉基封端的聚α-烯烃的柄型-双(茚-2-基)催化剂
US20230141606A1 (en) 2020-03-25 2023-05-11 Exxonmobil Chemical Patents Inc. Alkylation of Transition Metal Coordination Catalyst Complexes
WO2021262842A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM
WO2021262838A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom
US20240002560A1 (en) 2020-07-23 2024-01-04 Borealis Ag Process for the preparation of a multimodal polyethylene
US20230357454A1 (en) 2020-08-10 2023-11-09 Exxonmobil Chemical Patents Inc. Methods for Delivery of Non-Aromatic Solutions to Polymerization Reactors
WO2022268960A1 (en) 2021-06-24 2022-12-29 Borealis Ag Utilization of 1-hexene in multi-stage polyolefin production
US20240294682A1 (en) 2021-06-24 2024-09-05 Borealis Ag Process for producing polyethylene polymers
US20240301104A1 (en) 2021-06-24 2024-09-12 Borealis Ag Use of a swelling agent in multi-stage polyolefin production
US20240287217A1 (en) 2021-06-24 2024-08-29 Borealis Ag Process for polymerising olefins having narrow particle size distribution
CN117561286A (zh) 2021-06-24 2024-02-13 博里利斯股份公司 在多阶段聚烯烃生产中改善催化剂性能
CN118076874A (zh) 2021-06-24 2024-05-24 博里利斯股份公司 确定烯烃聚合催化剂的压缩特性的方法
CN115894757B (zh) * 2021-09-30 2024-06-04 中国石油化工股份有限公司 乙烯-烯醇共聚物及其制备方法
CN118324971A (zh) * 2023-02-03 2024-07-12 中化学科学技术研究有限公司 一种烯烃共聚催化剂体系及其应用
EP4424723A1 (en) 2023-02-28 2024-09-04 Lummus Novolen Technology Gmbh Polypropylene production using a propylene stream comprising propane

Family Cites Families (103)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US614032A (en) * 1898-11-08 bpicer
US628795A (en) * 1899-05-13 1899-07-11 Charles Bradley Harkness Door-check.
DE3127133A1 (de) 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4530914A (en) 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
DE3508887A1 (de) 1985-03-13 1986-09-25 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von optisch aktiven polyolefinen
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US4931417A (en) 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
DE3808268A1 (de) 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US5120867A (en) 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US4871705A (en) 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
DE3907964A1 (de) 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
DE59107926D1 (de) 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5239022A (en) 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
US5243001A (en) 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
DE59104869D1 (de) 1990-11-12 1995-04-13 Hoechst Ag 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
US5436305A (en) 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
DE4120009A1 (de) 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
TW300901B (es) 1991-08-26 1997-03-21 Hoechst Ag
EP0537686B1 (de) 1991-10-15 2005-01-12 Basell Polyolefine GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
US5359015A (en) 1991-11-07 1994-10-25 Exxon Chemical Patents Inc. Metallocene catalysts and their production and use
US5932669A (en) 1991-11-30 1999-08-03 Targor Gmbh Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
TW318184B (es) 1991-11-30 1997-10-21 Hoechst Ag
DE59206948D1 (de) 1991-11-30 1996-09-26 Hoechst Ag Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
TW309523B (es) 1991-11-30 1997-07-01 Hoechst Ag
US5830821A (en) 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
DK0574597T3 (da) 1992-06-13 1998-09-14 Targor Gmbh Fremgangsmåde til fremstilling af brosluttede chirale metallocenkatalysatorer af bisindenyltypen
TW294669B (es) 1992-06-27 1997-01-01 Hoechst Ag
ES2128371T3 (es) 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
JP3307704B2 (ja) 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
CA2125247C (en) 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
DE69434709T2 (de) 1993-06-07 2006-10-19 Mitsui Chemicals, Inc. Propylenelastomere
JPH06345816A (ja) * 1993-06-14 1994-12-20 Mitsui Toatsu Chem Inc 固体触媒成分およびこれを用いたオレフィンの重合方法
DE69426938T2 (de) * 1993-11-08 2001-11-08 Mobil Oil Corp., Fairfax Verfahren zur polymerisierung oder copolymerisierung von ethylen
JP3423378B2 (ja) 1993-11-12 2003-07-07 三井化学株式会社 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
DE4344689A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344688A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
ATE188972T1 (de) 1994-06-24 2000-02-15 Exxon Chemical Patents Inc Polymerisationskatalysatorsystem, ihre herstellung und gebrauch
US6140432A (en) 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US6124230A (en) 1995-07-13 2000-09-26 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US6166153A (en) * 1995-07-18 2000-12-26 Fina Technology, Inc. Process for the syndiotactic propagation of olefins
US5635437A (en) 1995-07-28 1997-06-03 Exxon Chemicals Patents, Inc. Method for preparing metallocene catalyst systems
EP0763546B1 (de) 1995-09-13 1997-05-28 Witco GmbH Verfahren zur Herstellung von Metallocen-Katalysatorsystemen auf inerten Trägermaterialien unter Verwendung von Gasphasenreaktoren
WO1997011775A2 (de) * 1995-09-28 1997-04-03 Targor Gmbh Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
KR100473546B1 (ko) * 1996-06-11 2005-05-16 바스프 악티엔게젤샤프트 담체로서무기산화물을이용한메탈로센촉매시스템
EP0906343B1 (en) 1996-06-17 2001-04-18 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
ATE200785T1 (de) * 1996-07-04 2001-05-15 Basf Ag Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren
EP1312619B1 (en) 1996-12-09 2007-11-14 Mitsubishi Chemical Corporation Catalyst for the polymerisation of alpha olefins
KR19980051220A (ko) * 1996-12-23 1998-09-15 김종진 유동성 실리카를 이용한 담지형 알루미녹산의 제조방법
DE69813800T2 (de) 1997-01-21 2004-02-12 Mitsubishi Chemical Corp. Organische verbindungen enthaltend silizium oder germanium, übergangsmetallkomplexe, katalysatoren für alpha-olefin polymerisation und verfahren zur herstellung von alpha-olefinpolymeren
DE19757563A1 (de) 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6228795B1 (en) 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
US6100214A (en) 1997-06-05 2000-08-08 Exxon Chemical Patents Inc. Polymeric supported catalysts for olefin polymerization
JP4116148B2 (ja) 1998-06-08 2008-07-09 三菱化学株式会社 新規な遷移金属化合物、オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法
AU4932899A (en) * 1998-08-03 2000-02-28 Chisso Corporation Processes for the preparation of metallocene complexes
DE19903306A1 (de) 1999-01-28 2000-08-03 Targor Gmbh Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung
KR100430438B1 (ko) * 1998-10-22 2004-07-19 대림산업 주식회사 담지메탈로센촉매,그제조방법및이를이용한폴리올레핀의중합방법
JP4195138B2 (ja) * 1998-12-10 2008-12-10 出光興産株式会社 アルミニウムオキシ化合物、オレフィン重合用触媒成分及びポリオレフィンの製造方法
JP2001064322A (ja) * 1999-06-24 2001-03-13 Idemitsu Petrochem Co Ltd プロピレン系重合体及びその成形体並びにプロピレン系重合体の製造方法
DE19962129A1 (de) * 1999-12-21 2001-06-28 Targor Gmbh Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
BRPI0016723B1 (pt) 1999-12-23 2018-02-27 Basell Polyolefine Gmbh. Metaloceno, sistema catalisador, e, processo para a copolimerização de propileno com etileno
DE10028432A1 (de) 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
US6380124B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380123B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380334B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376408B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6399723B1 (en) 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376411B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376407B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376627B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380330B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6608149B2 (en) 2000-12-04 2003-08-19 Univation Technologies, Llc Polymerization process
US6555495B2 (en) 2000-12-06 2003-04-29 Univation Technologies, Llc Catalyst support method and polymerization with supported catalysts
US6777366B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
US6583242B2 (en) * 2001-08-02 2003-06-24 Equistar Chemicals, Lp Supported olefin polymerization catalysts
US7307071B2 (en) * 2001-12-04 2007-12-11 Onyx Pharmaceuticals, Inc RAF-MEK-ERK pathway inhibitors to treat cancer
US6908972B2 (en) * 2002-04-16 2005-06-21 Equistar Chemicals, Lp Method for making polyolefins
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
US6765074B2 (en) * 2002-09-27 2004-07-20 Equistar Chemicals, Lp Olefin polymerization process
US6710005B1 (en) 2003-04-10 2004-03-23 Equistar Chemicals, Lp Aluminoxane modification
DE10326273B4 (de) * 2003-06-11 2008-06-12 Advanced Micro Devices, Inc., Sunnyvale Verfahren zur Reduzierung der Scheibenkontaminierung durch Entfernen von Metallisierungsunterlagenschichten am Scheibenrand
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins

Also Published As

Publication number Publication date
BRPI0518701B1 (pt) 2018-09-25
EP1828266B1 (en) 2015-07-22
US20070082806A1 (en) 2007-04-12
CN101124252A (zh) 2008-02-13
AR052985A1 (es) 2007-04-18
CN103012623A (zh) 2013-04-03
RU2007124637A (ru) 2009-01-10
JP2011231328A (ja) 2011-11-17
CN101124252B (zh) 2011-10-05
US20060116490A1 (en) 2006-06-01
US7169864B2 (en) 2007-01-30
US20080287286A1 (en) 2008-11-20
ZA200704403B (en) 2008-09-25
SG158099A1 (en) 2010-01-29
RU2360931C2 (ru) 2009-07-10
JP2008522013A (ja) 2008-06-26
KR101354477B1 (ko) 2014-01-24
JP5311827B2 (ja) 2013-10-09
ES2548726T3 (es) 2015-10-20
MX2007006313A (es) 2007-11-23
WO2006060544A1 (en) 2006-06-08
BRPI0518701A2 (pt) 2008-12-02
EP1828266A1 (en) 2007-09-05
CN103012623B (zh) 2015-09-16
BRPI0518701B8 (pt) 2023-01-24
KR20070092217A (ko) 2007-09-12

Similar Documents

Publication Publication Date Title
AR084818A2 (es) Catalizador metaloceno, su sintesis y sus usos en la polimerizacion de olefinas
ATE462731T1 (de) Katalysatorzusammensetzung zur olefinpolymerisierung
ATE544788T1 (de) Verbesserte saure aktivator-träger und katalysatoren für die olefinpolymerisation
AR080409A2 (es) Metodo para producir un catalizador o precatalizador util en la elaboracion de alquenil alcanoatos y metodo para producir alquenil alcanoatos
ECSP088221A (es) Agonistas adrenoreceptores alfa2c
AR068546A1 (es) Catalizadores de polimerizacion para producir polimeros con baja elasticidad de la masa fundida
ATE508190T1 (de) Mehrfachpromotor-expressionskassetten zurgleichzeitigen zuführung von rnai-agentien
AR072685A1 (es) Composicion topica para el tratamiento de queratosis actinica
AR056539A1 (es) Dentifrico blanqueador de fase unica
CL2012000374A1 (es) Metodo para la preparacion de una composicion saborizante activa que comprende una primera reaccion entre un compuesto amino y un carbonilo, resultando una primera mezcla de intermediarios, una segunda reaccion con un segundo compuesto amino solo o en combinacion con un compuesto carbinilo, resultando una segunda mezcla de intermediarios, reacciones serparadas adicionales con compuestos de otras clases quimicas, ultima reaccion que comprende una mezcla de todas las mezclas de intermediarios anteriores.
AR059060A1 (es) Catalizadores selectivos para la hidrodesulfuracion de nafta
AR026138A1 (es) Una composicion apropiada para secuestrante oxigeno y metodo para utilizar la misma, metodo para secuestrante oxigeno mediante dicha composicion y unarticulo de empaque que comprende dicha composicion.
AR084330A1 (es) Polimeros a base de etileno y procesos para formarlos
AR046681A1 (es) Proceso de preparacion de hidrocarburos de cadena ramificada
CL2008002430A1 (es) Compuestos derivados de bencenosulfonamida, inhibidores de catepsina c; composicion farmaceutica que los comprende; y su uso para el tratamiento de la epoc.
CL2008001620A1 (es) Induccion de fenotipo tolerogenico en celulas dendriticas maduras
ATE524482T1 (de) Ionische flüssigkeiten mit niedriger viskosität
CY1108321T1 (el) Καινοφανη παραγωγα δικαρβοξυλικου οξεος
AR074637A1 (es) Formas de sal de adicion acida de r-(+)-n-propargil-1-aminoindano (es decir , base de rasagilina), un compuesto de formula (1), procesos para prepararlos y aislarlos y usos de los mismos
ES2674177T3 (es) Preparación de suero
AR056395A1 (es) Composicion que comprende asfalto, copolimero de etileno y azufre
UY28731A1 (es) Compuestos quimicos
BR112014031934A8 (pt) Método com base em euglobulina para determinar a atividade biológica de defibrotide
AR060264A1 (es) Composicion farmaceutica que contiene lactato y calcio, usos de dicha composicion y metodo de preparacion
ATE500210T1 (de) Verfahren zur telomerisation von nicht cyclischen olefinen

Legal Events

Date Code Title Description
FB Suspension of granting procedure