DE69619854T2 - Radikalishe Massepolymerisation unter Verwendung eines diskontinuierlichen Reaktors - Google Patents
Radikalishe Massepolymerisation unter Verwendung eines diskontinuierlichen ReaktorsInfo
- Publication number
- DE69619854T2 DE69619854T2 DE69619854T DE69619854T DE69619854T2 DE 69619854 T2 DE69619854 T2 DE 69619854T2 DE 69619854 T DE69619854 T DE 69619854T DE 69619854 T DE69619854 T DE 69619854T DE 69619854 T2 DE69619854 T2 DE 69619854T2
- Authority
- DE
- Germany
- Prior art keywords
- mixture
- initiator
- reaction
- temperature
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- 238000010526 radical polymerization reaction Methods 0.000 claims description 20
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- MHPUGCYGQWGLJL-UHFFFAOYSA-N dimethyl pentanoic acid Natural products CC(C)CCCC(O)=O MHPUGCYGQWGLJL-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
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- 125000000524 functional group Chemical group 0.000 description 1
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- 238000007757 hot melt coating Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
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- 238000004811 liquid chromatography Methods 0.000 description 1
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
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- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
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- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
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- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/572,310 US5637646A (en) | 1995-12-14 | 1995-12-14 | Bulk radical polymerization using a batch reactor |
| PCT/US1996/018503 WO1997021736A1 (en) | 1995-12-14 | 1996-11-12 | Bulk radical polymerization using a batch reactor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69619854D1 DE69619854D1 (de) | 2002-04-18 |
| DE69619854T2 true DE69619854T2 (de) | 2002-10-02 |
Family
ID=24287257
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69619854T Expired - Lifetime DE69619854T2 (de) | 1995-12-14 | 1996-11-12 | Radikalishe Massepolymerisation unter Verwendung eines diskontinuierlichen Reaktors |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US5637646A (enExample) |
| EP (1) | EP0866810B1 (enExample) |
| JP (1) | JP3837458B2 (enExample) |
| KR (1) | KR19990072192A (enExample) |
| CN (1) | CN1209140A (enExample) |
| AU (1) | AU7681996A (enExample) |
| BR (1) | BR9611919A (enExample) |
| CA (1) | CA2238366A1 (enExample) |
| DE (1) | DE69619854T2 (enExample) |
| WO (1) | WO1997021736A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10153966B4 (de) * | 2001-05-09 | 2005-05-12 | List Ag | Verfahren zur Durchführung von Polymerisationsreaktionen |
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| CA2238366A1 (en) | 1997-06-19 |
| US5753768A (en) | 1998-05-19 |
| BR9611919A (pt) | 1999-03-30 |
| US5637646A (en) | 1997-06-10 |
| MX9804624A (es) | 1998-10-31 |
| AU7681996A (en) | 1997-07-03 |
| JP2000501764A (ja) | 2000-02-15 |
| JP3837458B2 (ja) | 2006-10-25 |
| KR19990072192A (ko) | 1999-09-27 |
| US5986011A (en) | 1999-11-16 |
| CN1209140A (zh) | 1999-02-24 |
| EP0866810B1 (en) | 2002-03-13 |
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| WO1997021736A1 (en) | 1997-06-19 |
| DE69619854D1 (de) | 2002-04-18 |
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