CN1396807A - 除草组合物 - Google Patents
除草组合物 Download PDFInfo
- Publication number
- CN1396807A CN1396807A CN01804089.6A CN01804089A CN1396807A CN 1396807 A CN1396807 A CN 1396807A CN 01804089 A CN01804089 A CN 01804089A CN 1396807 A CN1396807 A CN 1396807A
- Authority
- CN
- China
- Prior art keywords
- base
- wan
- phenyl
- sulfonyl
- shi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 185
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 52
- 150000001875 compounds Chemical class 0.000 claims abstract description 405
- 238000009472 formulation Methods 0.000 claims abstract description 12
- 239000000460 chlorine Substances 0.000 claims description 387
- 125000006414 CCl Chemical group ClC* 0.000 claims description 325
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 203
- -1 amino, benzylthio Chemical group 0.000 claims description 165
- 125000004646 sulfenyl group Chemical group S(*)* 0.000 claims description 148
- 229910052736 halogen Inorganic materials 0.000 claims description 126
- 150000002367 halogens Chemical class 0.000 claims description 125
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 98
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 claims description 95
- 241000196324 Embryophyta Species 0.000 claims description 87
- 125000003545 alkoxy group Chemical group 0.000 claims description 87
- 239000004009 herbicide Substances 0.000 claims description 73
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 70
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 65
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 61
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 60
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 56
- 238000000034 method Methods 0.000 claims description 55
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 claims description 45
- 125000004771 (C1-C4) haloalkylsulfinyl group Chemical group 0.000 claims description 44
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims description 42
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 38
- 229910052760 oxygen Inorganic materials 0.000 claims description 38
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 36
- 244000038559 crop plants Species 0.000 claims description 33
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims description 33
- 125000003342 alkenyl group Chemical group 0.000 claims description 32
- 125000000304 alkynyl group Chemical group 0.000 claims description 32
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 30
- 229910052801 chlorine Inorganic materials 0.000 claims description 30
- 239000001301 oxygen Substances 0.000 claims description 30
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 29
- 229910052757 nitrogen Inorganic materials 0.000 claims description 29
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 claims description 29
- 125000001544 thienyl group Chemical group 0.000 claims description 29
- 229910052799 carbon Inorganic materials 0.000 claims description 28
- 239000011737 fluorine Substances 0.000 claims description 28
- 229910052731 fluorine Inorganic materials 0.000 claims description 28
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 25
- 125000004122 cyclic group Chemical group 0.000 claims description 24
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 21
- 239000005864 Sulphur Substances 0.000 claims description 18
- 125000005108 alkenylthio group Chemical group 0.000 claims description 18
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 17
- 125000004749 (C1-C6) haloalkylsulfinyl group Chemical group 0.000 claims description 16
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims description 16
- 239000012752 auxiliary agent Substances 0.000 claims description 16
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 16
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 13
- 125000004414 alkyl thio group Chemical group 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 12
- 238000009333 weeding Methods 0.000 claims description 11
- 240000008042 Zea mays Species 0.000 claims description 10
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 10
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
- 239000000126 substance Chemical group 0.000 claims description 10
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims description 10
- 230000008485 antagonism Effects 0.000 claims description 9
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 claims description 9
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 8
- 125000005136 alkenylsulfinyl group Chemical group 0.000 claims description 8
- 125000005137 alkenylsulfonyl group Chemical group 0.000 claims description 8
- 125000002947 alkylene group Chemical group 0.000 claims description 8
- 235000005822 corn Nutrition 0.000 claims description 8
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 8
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 8
- 239000011630 iodine Substances 0.000 claims description 7
- 229910052740 iodine Inorganic materials 0.000 claims description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 125000002619 bicyclic group Chemical group 0.000 claims description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 6
- 240000000111 Saccharum officinarum Species 0.000 claims description 5
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 5
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- 125000002088 tosyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])S(*)(=O)=O 0.000 claims description 5
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 239000000080 wetting agent Substances 0.000 claims description 4
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 claims description 2
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims description 2
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 claims description 2
- 125000006415 CF Chemical group FC* 0.000 claims description 2
- 150000001924 cycloalkanes Chemical class 0.000 claims description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000002671 adjuvant Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 description 624
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 264
- 101150065749 Churc1 gene Proteins 0.000 description 264
- 102100038239 Protein Churchill Human genes 0.000 description 264
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 69
- 238000012360 testing method Methods 0.000 description 57
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 56
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 42
- 238000002360 preparation method Methods 0.000 description 40
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 33
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical group CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 24
- 244000292697 Polygonum aviculare Species 0.000 description 23
- 235000006386 Polygonum aviculare Nutrition 0.000 description 23
- 239000003921 oil Substances 0.000 description 23
- 150000003254 radicals Chemical class 0.000 description 23
- 235000019198 oils Nutrition 0.000 description 21
- 239000004094 surface-active agent Substances 0.000 description 21
- 238000009736 wetting Methods 0.000 description 19
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 17
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 17
- 239000007787 solid Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 16
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 16
- 238000001704 evaporation Methods 0.000 description 16
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- 244000017020 Ipomoea batatas Species 0.000 description 15
- 235000002678 Ipomoea batatas Nutrition 0.000 description 15
- ZBZJXHCVGLJWFG-UHFFFAOYSA-N trichloromethyl(.) Chemical compound Cl[C](Cl)Cl ZBZJXHCVGLJWFG-UHFFFAOYSA-N 0.000 description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 14
- 239000000843 powder Substances 0.000 description 14
- JNCMHMUGTWEVOZ-UHFFFAOYSA-N F[CH]F Chemical compound F[CH]F JNCMHMUGTWEVOZ-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000003513 alkali Substances 0.000 description 12
- 239000000376 reactant Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 240000006122 Chenopodium album Species 0.000 description 11
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 11
- 150000004702 methyl esters Chemical class 0.000 description 11
- LJDSTRZHPWMDPG-UHFFFAOYSA-N 2-(butylamino)ethanol Chemical compound CCCCNCCO LJDSTRZHPWMDPG-UHFFFAOYSA-N 0.000 description 10
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 239000004519 grease Substances 0.000 description 10
- 229910052938 sodium sulfate Inorganic materials 0.000 description 10
- 235000011152 sodium sulphate Nutrition 0.000 description 10
- 108010005721 B 581 Proteins 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
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- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
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- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 7
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 7
- 229910052794 bromium Inorganic materials 0.000 description 7
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- ODWJFUQRQUCRJZ-UHFFFAOYSA-N 2-methyl-6-(trifluoromethyl)pyridine-3-carboxylic acid Chemical compound CC1=NC(C(F)(F)F)=CC=C1C(O)=O ODWJFUQRQUCRJZ-UHFFFAOYSA-N 0.000 description 6
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- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 1
- 125000004092 methylthiomethyl group Chemical group [H]C([H])([H])SC([H])([H])* 0.000 description 1
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 description 1
- 239000011785 micronutrient Substances 0.000 description 1
- 235000013369 micronutrients Nutrition 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N monofluoromethane Natural products FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- QHCCDDQKNUYGNC-UHFFFAOYSA-N n-ethylbutan-1-amine Chemical compound CCCCNCC QHCCDDQKNUYGNC-UHFFFAOYSA-N 0.000 description 1
- IUZZLNVABCISOI-UHFFFAOYSA-N n-ethylheptan-1-amine Chemical compound CCCCCCCNCC IUZZLNVABCISOI-UHFFFAOYSA-N 0.000 description 1
- SDQCOADWEMMSGK-UHFFFAOYSA-N n-ethyloctan-1-amine Chemical compound CCCCCCCCNCC SDQCOADWEMMSGK-UHFFFAOYSA-N 0.000 description 1
- NJWMENBYMFZACG-UHFFFAOYSA-N n-heptylheptan-1-amine Chemical compound CCCCCCCNCCCCCCC NJWMENBYMFZACG-UHFFFAOYSA-N 0.000 description 1
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- OZIXTIPURXIEMB-UHFFFAOYSA-N n-methylnonan-1-amine Chemical compound CCCCCCCCCNC OZIXTIPURXIEMB-UHFFFAOYSA-N 0.000 description 1
- SZEGKVHRCLBFKJ-UHFFFAOYSA-N n-methyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNC SZEGKVHRCLBFKJ-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004888 n-propyl amino group Chemical group [H]N(*)C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RTCOGUMHFFWOJV-UHFFFAOYSA-N nicosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(=O)N(C)C)=N1 RTCOGUMHFFWOJV-UHFFFAOYSA-N 0.000 description 1
- FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical compound CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- VMPITZXILSNTON-UHFFFAOYSA-N o-anisidine Chemical compound COC1=CC=CC=C1N VMPITZXILSNTON-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 125000003431 oxalo group Chemical group 0.000 description 1
- FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- CSWIKHNSBZVWNQ-UHFFFAOYSA-N pethoxamide Chemical compound CCOCCN(C(=O)CCl)C(=C(C)C)C1=CC=CC=C1 CSWIKHNSBZVWNQ-UHFFFAOYSA-N 0.000 description 1
- 125000005359 phenoxyalkyl group Chemical group 0.000 description 1
- 125000003884 phenylalkyl group Chemical group 0.000 description 1
- UXCDUFKZSUBXGM-UHFFFAOYSA-N phosphoric tribromide Chemical compound BrP(Br)(Br)=O UXCDUFKZSUBXGM-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 description 1
- 125000006225 propoxyethyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 125000004742 propyloxycarbonyl group Chemical group 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- ATBIAJXSKNPHEI-UHFFFAOYSA-N pyridine-3-carbonyl chloride Chemical compound ClC(=O)C1=CC=CN=C1 ATBIAJXSKNPHEI-UHFFFAOYSA-N 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 150000003235 pyrrolidines Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- SBYHFKPVCBCYGV-UHFFFAOYSA-N quinuclidine Chemical compound C1CC2CCN1CC2 SBYHFKPVCBCYGV-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- MEFOUWRMVYJCQC-UHFFFAOYSA-N rimsulfuron Chemical compound CCS(=O)(=O)C1=CC=CN=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 MEFOUWRMVYJCQC-UHFFFAOYSA-N 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical compound CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 description 1
- 125000005930 sec-butyloxycarbonyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(OC(*)=O)C([H])([H])[H] 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- BCQMBFHBDZVHKU-UHFFFAOYSA-N terbumeton Chemical compound CCNC1=NC(NC(C)(C)C)=NC(OC)=N1 BCQMBFHBDZVHKU-UHFFFAOYSA-N 0.000 description 1
- IROINLKCQGIITA-UHFFFAOYSA-N terbutryn Chemical compound CCNC1=NC(NC(C)(C)C)=NC(SC)=N1 IROINLKCQGIITA-UHFFFAOYSA-N 0.000 description 1
- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- CXPRGLWJJQBWRS-UHFFFAOYSA-N tert-butyl 3-cyclopropyl-3-oxopropanoate Chemical compound CC(C)(C)OC(=O)CC(=O)C1CC1 CXPRGLWJJQBWRS-UHFFFAOYSA-N 0.000 description 1
- 125000005931 tert-butyloxycarbonyl group Chemical group [H]C([H])([H])C(OC(*)=O)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 description 1
- HFRXJVQOXRXOPP-UHFFFAOYSA-N thionyl bromide Chemical compound BrS(Br)=O HFRXJVQOXRXOPP-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 description 1
- RKBCYCFRFCNLTO-UHFFFAOYSA-N triisopropylamine Chemical compound CC(C)N(C(C)C)C(C)C RKBCYCFRFCNLTO-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Pyridine Compounds (AREA)
- Pyrane Compounds (AREA)
Abstract
除草组合物,所述组合物除了包含常用惰性制剂助剂以外,还包含:a)式(I)化合物,其中取代基如权利要求1中所定义;和b)协同有效量的一种或多种式2.1-2.51化合物。本发明组合物还可以包含安全剂。
Description
本发明涉及新的除草组合物,其中包含适于选择性地控制有用植物农作物例如玉米农作物中的杂草的除草活性组分组合。本发明还涉及控制有用植物农作物中的杂草的方法,以及新的组合物在这样的用途中的应用。式I化合物其中取代基的定义在下文中给出,具有除草活性。
令人惊奇的是,现在已经发现,不定量的活性组分、即不定量的式I活性组分与一种或多种下文所列出的已知的、并且某些可商购获得的式2.1-2.51活性组分的组合表现出协同作用,能够控制尤其是在有用植物农作物中生长的大多数杂草(既能控制芽前的杂草,也能控制苗后的杂草)。
因此,本发明提供了用于选择性地控制杂草的新的协同组合物,所述组合物除了含有常规惰性制剂助剂以外,还含有下列组分的混合物作为活性组分:a)除草有效量的式I化合物或其农业可接受盐其中每个R独立地为氢、C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基、C1-C6卤代烷硫基、C1-C6卤代烷基亚磺酰基、C1-C6卤代烷基磺酰基、C1-C6烷氧基羰基、C1-C6烷基羰基、C1-C6烷基氨基、二(C1-C6烷基)氨基、C1-C6烷基氨基磺酰基、二(C1-C6烷基)氨基磺酰基、-N(R1)-S-R2、-N(R3)-SO-R4、-N(R5)-SO2-R6、硝基、氰基、卤素、羟基、氨基、苄硫基、苄基亚磺酰基、苄基磺酰基、苯基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基;其中所述苯基自身可被下列基团单取代、二取代或三取代:C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R45、NR46R47、卤素、氰基、硝基、苯基或苄硫基,其中后面所述的苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;或者每个R独立地为5-10元单环或稠合二环系,所述环系可以是芳环或部分饱和环,并且可以含有1-4个选自氮、氧和硫的杂原子;其中所述环系直接与吡啶环连接,或者经由C1-C4亚烷基与吡啶环连接,并且每个环系不可以含有2个以上的氧原子,不可以含有2个以上的硫原子,所述环系自身可被下列基团单取代、二取代或三取代:C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R7、NR8R9、卤素、氰基、硝基、苯基或苄硫基,其中所述苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代,并且在杂环中的氮上的取代基不是卤素;或者每个R独立地为C1-C4烷氧基-C1-C4烷基或C1-C4烷氧基-C1-C4烷氧基-C1-C4烷基;m是1、2、3或4;R1、R3和R5分别独立地为氢或C1-C6烷基;R2是NR10R11、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基或苯基,其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;R4是NR12R13、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基或苯基,其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;R6是NR14R15、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基或苯基,其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;R7和R45分别独立地为C1-C3烷氧基、C2-C4烷氧基羰基、C1-C3烷硫基、C1-C3烷基亚磺酰基、C1-C3烷基磺酰基或苯基,其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;R8、R10、R12、R14和R46分别独立地为氢或C1-C6烷基;R9、R11、R13、R15和R47分别独立地为C1-C6烷基或C1-C6烷氧基;Q是基团Q1 其中R16、R17、R18和R19分别独立地为氢、羟基、C1-C4烷基、C2-C6链烯基、C2-C6炔基、C1-C4烷氧基羰基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-NHS(O)2、C1-C4卤代烷基、-NH-C1-C4烷基、-N(C1-C4烷基)2、C1-C6烷氧基、氰基、硝基、卤素、或苯基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基、COOH或氰基;或者R16、R17、R18和R19当中的两个相邻取代基形成C2-C6亚烷基桥;R20是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R21R22N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基;且R21和R22分别独立地为氢或C1-C4烷基;或者是基团Q2 其中R23是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4-链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R24R25N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基;R24和R25分别独立地为氢或C1-C4烷基;且Y是氧、硫、化学键或C1-C4亚烷基桥;或者是Q3 其中R44、R37、R38和R39分别独立地为氢、C1-C6烷基、C1-C6卤代烷基、C2-C6链烯基、C2-C6炔基、C1-C6烷氧基羰基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6烷基-NHS(O)2、C1-C6烷基氨基、二(C1-C6烷基)氨基、羟基、C1-C6烷氧基、C3-C6链烯氧基、C3-C6炔氧基、羟基-C1-C6烷基、C1-C4烷基-磺酰基氧基-C1-C6烷基、甲苯磺酰基氧基-C1-C6烷基、卤素、氰基、硝基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-S(O)2O、C1-C6卤代烷硫基、C1-C6卤代烷基亚磺酰基、C1-C6卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C6烷硫基-N(C1-C4烷基)、C1-C6烷基亚磺酰基-N(C1-C4烷基)、C1-C6烷基磺酰基-N(C1-C4烷基)、卤素、硝基、COOH或氰基;或者相邻的R44和R37或R38和R39一起为C3-C6亚烷基;W是氧、硫、亚磺酰基、磺酰基、-CR41R42-、-C(O)-或-NR43-;R41是氢、C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基-C1-C4烷基、C1-C4烷硫基-C1-C4烷基、C1-C4烷基羰基氧基-C1-C4烷基、C1-C4烷基磺酰基氧基-C1-C4烷基、甲苯磺酰基氧基-C1-C4烷基、二(C1-C3烷氧基烷基)甲基、二(C1-C3烷硫基烷基)甲基、(C1-C3烷氧基烷基)-(C1-C3烷硫基烷基)甲基、C3-C5氧杂环烷基、C3-C5硫杂环烷基、C3-C4二氧杂环烷基、C3-C4二硫杂环烷基、C3-C4氧杂硫杂环烷基、甲酰基、C1-C4烷氧基羰基、或苯基,所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C6烷硫基-N(C1-C4烷基)、C1-C6烷基亚磺酰基-N(C1-C4烷基)、C1-C6烷基磺酰基-N(C1-C4烷基)、卤素、硝基、COOH或氰基;或者R42与R39一起为C1-C6亚烷基;R42是氢、C1-C4烷基或C1-C4卤代烷基;R40是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R96R97N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基;R96和R97分别独立地为氢或C1-C4烷基;R43是氢、C1-C4烷基、C1-C4烷氧基羰基、或苯基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基;或者是基团Q4 其中R30是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R31R32N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基;且R31和R32分别独立地为氢或C1-C4烷基;R33和R34分别独立地为氢、羟基、C1-C4烷基、C2-C6链烯基、C2-C6炔基、C1-C4烷氧基羰基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-NHS(O)2、C1-C4卤代烷基、-NH-C1-C4烷基、-N(C1-C4烷基)2、C1-C6烷氧基、氰基、硝基、卤素、或苯基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4-烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基、COOH或氰基;或者R33和R34一起形成C2-C6亚烷基桥;且R35是氢、C1-C4烷基、C1-C4烷氧基羰基、或苯基,所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基、COOH或氰基;或者是基团Q5 其中Z是硫、SO或SO2;R01是氢、C1-C8烷基、被下列基团取代的C1-C8烷基:卤素、C1-C4烷氧基、C1-C4烷硫基、C1-C4烷基磺酰基、C1-C4烷基亚磺酰基、羟基、氰基、硝基、-CHO、-CO2R02、-COR03、-COSR04、-NR05R06、CONR036R037、或苯基,所述苯基自身可被下列基团取代:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7-环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR025R026、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR015CO2R027;或者R01是C2-C8链烯基或被下列基团取代的C2-C8链烯基:卤素、C1-C4烷氧基、C1-C4烷硫基、C1-C4烷基磺酰基、C1-C4烷基亚磺酰基、-CONR032R033、氰基、硝基、-CHO、-CO2R038、-COR039、-COS-C1-C4烷基、-NR034R035、或苯基,所述苯基自身可被下列基团取代:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR040R041、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR043CO2R042;或者R01是C3-C6炔基或被下列基团取代的C3-C6炔基:卤素、C1-C4卤代烷基、氰基、-CO2R044、或苯基,所述苯基自身可被下列基团取代:C1-C4烷基、C1-C6卤代烷基、C1-C4-烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4-烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR028R029、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR031CO2R030;或者R01是C3-C7环烷基或被下列基团取代的C3-C7环烷基:C1-C4烷基、C1-C4烷氧基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、或苯基,所述苯基自身可被下列基团取代:卤素、硝基、氰基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷硫基、C1-C4卤代烷硫基、C1-C4烷基或C1-C4卤代烷基;或者R01是C1-C4亚烷基-C3-C7环烷基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4-烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR045R046、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基或-NR048CO2R047;或者R01是C1-C4亚烷基苯基、COR07或4-6元杂环基;R02、R038、R044和R066分别独立地为氢、C1-C4烷基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)-SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR049R050、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、-C1-C4-烷基苯基或-NR052CO2R053;R03、R039和R067分别独立地为C1-C4烷基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)-SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR068R054、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、-(CH2)t-苯基或-NR056CO2R055;R04是C1-C4烷基;R05是氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基、C3-C7环烷基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2H、N(C3-C6炔基)-SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2H、N(C3-C7环烷基)-SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR057R058、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR060CO2R059;R06是氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基、C3-C7环烷基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4-烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)-SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR061R062、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR064CO2R063;R07是苯基、C1-C4烷基、C1-C4烷氧基或-NR08R09;R08和R09分别独立地为C1-C4烷基、苯基、或被下列基团取代的苯基:卤素、硝基、氰基、C1-C4烷基、C1-C4烷氧基、C1-C4烷硫基、-CO2R066、-COR067、C1-C4烷基磺酰基、C-C4烷基亚磺酰基或C1-C4卤代烷基;或者R08和R09一起形成可被氧、NR065或S间隔的5-元或6-元环;R015、R031、R043、R048、R052、R056、R060和R064分别独立地为氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基或C3-C7环烷基;R025、R026、R027、R028、R029、R030、R032、R033、R034、R035、R036、R037、R040、R041、R042、R045、R046、R047、R049、R050、R053、R054、R055、R057、R058、R059、R061、R062、R053、R065和R068分别独立地为氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基、C3-C7环烷基、苯基、或被下列基团取代的苯基:卤素、硝基、氰基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷硫基、C1-C4卤代烷硫基、C1-C4烷基或C1-C4卤代烷基;且R36是C1-C4烷基、C1-C4卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基、或被下列基团取代的C3-C6环烷基:卤素、C1-C4烷基、C1-C4卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C4烷氧基羰基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4烷基羰基、二(C1-C4烷基)氨基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基-S(O)2O、C1-C4卤代烷基-S(O)2O、或苯基,所述苯基自身可被下列基团取代:卤素、C1-C4烷基、C1-C4卤代烷基、C3-C6链烯基、C3-C6炔基、氰基、硝基或COOH;和b)协同有效量的一种或多种选自下列的化合物:式2.1化合物其中R51是CH2-OMe、乙基或氢;R52是氢,或者R51与R52一起形成基团-CH=CH-CH=CH-;和式2.2化合物其中R53是乙基,R54是甲基或乙基,且R55是-CH(Me)-CH2OMe、<S>-CH(Me)-CH2OMe、CH2OMe或CH2O-CH2CH3;和式2.3化合物其中R56是CH(Me)-CH2OMe或<S>CH(Me)-CH2OMe;和式2.4化合物其中R57是氯、甲氧基或甲硫基,R58是乙基,且R59是乙基、异丙基、-C(CN)(CH3)-CH3或叔丁基;和式2.5化合物其中R60是乙基或正丙基,R61是COO-1/2Ca++、-CH2-CH(Me)S-CH2CH3或基团且X是氧、N-O-CH2CH3或N-O-CH2CH-CH-Cl;和式2.6化合物其中R62是氢、甲氧基或乙氧基,R63是氢、甲基、甲氧基或氟,R64是COOMe、氟或氯,R65是氢或甲基,Y是次甲基、C-F或氮,Z是次甲基或氮,且R66是氟或氯;和式2.7化合物其中R67是氢或-C(O)-S-正辛基;和式2.8化合物其中R68是溴或碘;和式2.9化合物其中R69是氯或硝基;和式2.10化合物其中R70是氟或氯,且R71是-CH2-CH(Cl)-COOCH2CH3或-NH-SO2Me;和式2.11化合物其中R72是三氟甲基或氯;和式2.12化合物其中R73是NH2或<S>NH2;和式2.13化合物其中Y1是氮、次甲基、NH-CHO或N-Me,Y2是氮、次甲基或C-I,Y3是次甲基,Y4是次甲基,或者Y3和Y4一起是硫或C-Cl,Y5是氮或次甲基,Y6是甲基、二氟甲氧基、三氟甲基或甲氧基,Y7是甲氧基或二氟甲氧基,且R74是CONMe2、COOMe、COOC2H5、三氟甲基、CH2-CH2CF3或SO2CH2CH3,或其钠盐(“Me”是甲基);和式2.13.c化合物和式2.14化合物和式2.15化合物和式2.16化合物和式2.17化合物和式2.18化合物和式2.19化合物和式2.20化合物和式2.21化合和式2.22化合物和式2.23化合物和式2.24化合物和式2.25化合物和式2.26化合物和式2.27化合物和式2.28化合物和式2.29化合物和式2.30化合物和式2.31化合物和式2.32化合物和式2.33化合物and the compound of formula 2.34和式2.35化合物和式2.36化合物和式2.37化合物
和式2.38化合物
和式2.39化合物
和式2.40化合物
和式2.41化合物
和式2.42化合物
和式2.43化合物
和式2.44化合物和式2.45化合物和式2.46化合物和式2.47化合物和式2.48化合物和式2.49化合物和式2.50化合物和式2.51化合物
在上式中,“Me”是甲基。在取代基定义中提及的烷基可以是直链或支链,并且是例如甲基、乙基、正丙基、异丙基、正丁基、仲丁基、异丁基、叔丁基、戊基、己基、庚基、辛基、壬基、癸基、十一烷基和十二烷基及其支链异构体。烷氧基、链烯基和炔基衍生自上述烷基。链烯基和炔基可具有一个或一个以上的不饱和键。
亚烷基可以被一个或多个甲基取代;这样的亚烷基优选未取代。这也适用于所有含有C3-C5环烷基-、C3-C5氧杂环烷基-、C3-C5硫杂环烷基-、C3-C4二氧杂环烷基-、C3-C4二硫杂环烷基-、C3-C4氧硫杂环烷基-和N(CH2)-的基团。
卤素一般是氟、氯、溴或碘。这相应地适用于在其它定义例如卤代烷基或卤代苯基中出现的卤素。
具有1-6个碳原子链长的卤代烷基是例如氟甲基、二氟甲基、三氟甲基、氯甲基、二氯甲基、三氯甲基、2,2,2-三氟乙基、2-氟乙基、2-氯乙基、五氟乙基、1,1-二氟-2,2,2-三氯乙基、2,2,3,3-四氟乙基和2,2,2-三氯乙基、五氟乙基、七氟正丙基、五氟正己基;在R2、R3和尤其是R5的定义中的卤代烷基优选为三氯甲基、二氯氟甲基、二氟氯甲基、二氟甲基、三氟甲基、五氟乙基或七氟正丙基。
合适的卤代链烯基包括被卤素取代一次或多次的链烯基,卤素是氟、氯、溴或碘,尤其是氟或氯,例如2,2-二氟-1-甲基乙烯基、3-氟丙烯基、3-氯丙烯基、3-溴丙烯基、2,3,3-三氟丙烯基、2,3,3-三氯丙烯基和4,4,4-三氟丁-2-烯-1-基。优选的被卤素取代1次、2次或3次的C2-C12链烯基是链长为2-5个碳原子的那些。合适的卤代炔基包括例如被卤素取代一次或多次的炔基,卤素是溴或碘,和尤其是氟或氯,例如3-氟丙炔基、3-氯丙炔基、3-溴丙炔基、3,3,3-三氟丙炔基和4,4,4-三氟-丁-2-炔-1-基。优选的被卤素取代1次、2次或3次的炔基是链长为2-5个碳原子的那些。
烷氧基优选具有1-6个碳原子的链长。烷氧基是例如甲氧基、乙氧基、丙氧基、异丙氧基、正丁氧基、异丁氧基、仲丁氧基或叔丁氧基或戊氧基或己氧基异构体,优选甲氧基和乙氧基。烷基羰基优选为乙酰基或丙酰基。烷氧基羰基是例如甲氧基羰基、乙氧基羰基、丙氧基羰基、异丙氧基羰基、正丁氧基羰基、异丁氧基羰基、仲丁氧基羰基或叔丁氧基羰基,优选甲氧基羰基、乙氧基羰基或叔丁氧基羰基。卤代烷氧基优选具有1-8个碳原子的链长。
卤代烷氧基是例如氟甲氧基、二氟甲氧基、三氟甲氧基、2,2,2-三氟乙氧基、1,1,2,2-四氟乙氧基、2-氟乙氧基、2-氯乙氧基、2,2-二氟乙氧基或2,2,2-三氯乙氧基,优选二氟甲氧基、2-氯乙氧基或三氟甲氧基。
烷硫基优选具有1-8个碳原子的链长。
烷硫基是例如甲硫基、乙硫基、丙硫基、异丙硫基、正丁硫基、异丁硫基、仲丁硫基或叔丁硫基,优选为甲硫基或乙硫基。
烷基亚磺酰基是例如甲基亚磺酰基、乙基亚磺酰基、丙基亚磺酰基、异丙基亚磺酰基、正丁基亚磺酰基、异丁基亚磺酰基、仲丁基亚磺酰基或叔丁基亚磺酰基,优选为甲基亚磺酰基或乙基亚磺酰基。
烷基磺酰基是例如甲基磺酰基、乙基磺酰基、丙基磺酰基、异丙基磺酰基、正丁基磺酰基、异丁基磺酰基、仲丁基磺酰基或叔丁基磺酰基,优选为甲基磺酰基或乙基磺酰基。
烷基氨基是例如甲基氨基、乙基氨基、正丙基氨基、异丙基氨基或丁基氨基异构体。二烷基氨基是例如二甲基氨基、甲基乙基氨基、二乙基氨基、正丙基甲基氨基、二丁基氨基或二异丙基氨基。烷基氨基优选具有1-4个碳原子的链长。烷氧基烷基优选具有1-6个碳原子的链长。烷氧基烷基是例如甲氧基甲基、甲氧基乙基、乙氧基甲基、乙氧基乙基、正丙氧基甲基、正丙氧基乙基、异丙氧基甲基或异丙氧基乙基。烷硫基烷基优选具有1-6个碳原子的链长。烷硫基烷基是例如甲硫基甲基、甲硫基乙基、乙硫基甲基、乙硫基乙基、正丙硫基甲基、正丙硫基乙基、异丙硫基甲基、异丙硫基乙基、丁硫基甲基、丁硫基乙基或丁硫基丁基。
环烷基优选具有3-6个环碳原子,并且可以被一个或多个甲基取代;它们优选未取代,例如环丙基、环丁基、环戊基或环己基。苯基,包括作为取代基例如苯氧基、苄基、苄氧基、苯甲酰基、苯硫基、苯基烷基、苯氧基烷基或甲苯磺酰基的一部分的苯基可以是单取代或多取代形式,对于这种情况,取代基可以按照需要在邻位、间位和/或对位。
本发明还包括式I化合物可以与胺、碱金属和碱土金属碱或季铵碱形成的盐。在作为盐形成剂使用的碱金属和碱土金属氢氧化物当中,可特别提及氢氧化锂、氢氧化钠、氢氧化钾、氢氧化镁和氢氧化钙,尤其是氢氧化钠和氢氧化钾。
适用于形成铵盐的胺的实例是氨以及伯、仲和叔C1-C18烷基案、C1-C4羟基烷基胺和C2-C4烷氧基烷基胺,例如甲基胺、乙基胺、正丙基胺、异丙基胺、四种丁基胺异构体、正戊基胺、异戊基胺、己基胺、庚基胺、辛基胺、壬基胺、癸基胺、十五烷基胺、十六烷基胺、十七烷基胺、十八烷基胺、甲基乙基胺、甲异丙基胺、甲基己基胺、甲基壬基胺、甲基十五烷基胺、甲基十八烷基胺、乙基丁基胺、乙基庚基胺、乙基辛基胺、己基庚基胺、己基辛基胺、二甲基胺、二乙基胺、二-正丙基胺、二异丙基胺、二-正丁基胺、二正戊基胺、二异戊基胺、二己基胺、二庚基胺、二辛基胺、乙醇胺、正丙醇胺、异丙醇胺、N,N-二乙醇胺、N-乙基丙醇胺、N-丁基乙醇胺、烯丙基胺、正丁烯基-2-胺、正戊烯基-2-胺、2,3-二甲基丁烯基-2-胺、二丁烯基-2-胺、正己烯基-2-胺、丙二胺、三甲基胺、三乙基胺、三正丙基胺、三异丙基胺、三正丁基胺、三异丁基胺、三仲丁基胺、三正戊基胺、甲氧基乙基胺和乙氧基乙基胺;杂环胺例如吡啶、喹啉、异喹啉、吗啉、哌啶、吡咯烷、二氢吲哚、奎宁环和吖庚因;伯芳基胺例如苯胺、甲氧基苯胺、乙氧基苯胺、邻甲苯胺、间甲苯胺、对甲苯胺、苯二胺、联苯胺、萘基胺、邻氯苯胺、间氯苯胺和对氯苯胺;但是尤其是三乙基胺、异丙基胺和二异丙基胺。
非常令人惊奇的是,式I活性组分与一种或多种选自式2.1-2.51的活性组分的组合对欲控制杂草的作用超过了一般所预计的加和作用,因此扩大了单独活性组分的作用范围,尤其是在下列两个方面:首先,减小了单独的式2.1-2.51化合物的施用量,同时保持了良好的作用水平,其次,对于单独的活性物质以低施用量不可用的情况(从农学角度来看),本发明组合物可获得良好的杂草控制水平。该结果是杂草谱的显著拓宽,并且提高了在有用植物农作物方面的选择性,如果发生了活性组分的非故意剂量过多,这样的结果是必须的并且可取的。在保持良好控制有用植物农作物中的杂草的同时,本发明组合物还使得在继代农作物中有更大的灵活性。
本发明组合物可用于抗大量在农业上很重要的杂草,例如繁缕属、旱金莲属、地老虎属、马唐属、燕麦属、狗尾草属、芥属、毒麦属、茄属、菜豆属、稗属、藨草属、雨久花属、慈菇属、雀麦属、看麦娘属、石茅高梁、筒轴茅属、莎草属、苘麻属、黄花稔属、苍耳属、苋属、藜属、番薯属、苘蒿属、猪殃殃属、堇菜属和婆婆纳属。本发明组合物适用于农业中的所有常用施用方法,例如芽前施用、苗后施用和种子包衣。本发明组合物尤其适用于控制有用植物农作物例如禾谷类、油菜、甜菜、甘蔗、种植园农作物、稻、玉米和大豆中的杂草,以及适用于非选择性杂草控制。
“农作物”还指通过常规育种或基因工程方法使其对除草剂或除草剂类别耐受的农作物。
优选的本发明组合物包含式I化合物,其中每个R独立地为氢、C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基、C1-C6卤代烷硫基、C1-C6卤代烷基亚磺酰基、C1-C6卤代烷基磺酰基、C1-C6烷氧基羰基、C1-C6烷基羰基、C1-C6烷基氨基、二(C1-C6烷基)氨基、C1-C6烷基氨基磺酰基、二(C1-C6烷基)氨基磺酰基、-N(R1)-S-R2、-N(R3)-SO-R4、-N(R5)-SO2-R6、硝基、氰基、卤素、羟基、氨基、苄硫基、苄基亚磺酰基、苄基磺酰基、苯基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基;其中所述苯基自身可被下列基团单取代、二取代或三取代:C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R45、NR46R47、卤素、氰基、硝基、苯基或苄硫基,其中后面提及的苯基和苄硫基自身可在苯环上被C1-C8烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;或者每个R独立地为5-10元单环或稠合二环系,所述环系可以是芳环或部分饱和环,并且可以含有1-4个选自氮、氧和硫的杂原子;其中所述环系直接与吡啶环连接,或者经由C1-C4亚烷基与吡啶环连接,并且每个环系不可以含有2个以上的氧原子,不可以含有2个以上的硫原子,所述环系自身可被下列基团单取代、二取代或三取代:C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R7、NR8R9、卤素、氰基、硝基、苯基或苄硫基,其中所述苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代,并且在杂环中的氮上的取代基不是卤素。
还优选的本发明组合物包含式Ia化合物作为式I化合物其中R48是C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基、C1-C6卤代烷基、或5-10元单环或稠合二环系,所述环系可以是芳环或部分饱和环,并且可以含有1-4个选自氮、氧和硫的杂原子,其中所述环系直接与吡啶环连接,或者经由C1-C4亚烷基与吡啶环连接,并且每个环系不可以含有2个以上的氧原子,不可以含有2个以上的硫原子,所述环系自身可被下列基团单取代、二取代或三取代:C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R7、NR8R9、卤素、氰基、硝基、苯基或苄硫基,其中所述苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代,并且在杂环中的氮上的取代基不是卤素;R49是氢、C1-C6烷基、C1-C6卤代烷基、卤素、或苯基,所述苯基可被下列基团取代:C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基,且R50是C1-C6卤代烷基。
在该组化合物当中,其中R48是C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基或C1-C6卤代烷基的那些是优选的。
对于本发明组合物还优选的是,在式I中,Q是基团Q2或Q3,其中尤其是,在基团Q2中,R23是羟基,在基团Q3中,R40是羟基。在该组化合物当中,其中m是2,且一个取代基R是C1-C4烷氧基-C1-C4烷基或C1-C4烷氧基-C1-C4烷氧基-C1-C4烷基的化合物是特别重要的。
进一步优选的本发明协同混合物包含式I化合物和下列化合物作为活性组分:式2.2.a化合物(2.2.a,aRS,1’S(-)N-(1’-甲基-2’-甲氧基乙基)-N-氯乙酰基-2-乙基-6-甲基苯胺)或式2.2.b化合物或式2.2化合物,其中R3是乙基、R4是甲基、且R5是乙氧基甲基,或式2.2化合物,其中R3是乙基、R4是乙基、且R5是甲氧基甲基,或化合物2.3,或式2.30化合物,或式2.4化合物,或式2.13化合物,或式2.14化合物,或式2.6化合物,其中R12是氢、Z是次甲基、R13是甲基、Y是氮、R14是氟、R15是氢、且R16是氟,或者R12是甲氧基、Z是次甲基、R13是甲氧基、Y是次甲基、R14是氯、R15是甲基、且R16是氯,或式2.7化合物,其中R17是-C(O)-S-正辛基,或式2.12化合物,或式2.18化合物,或式2.19化合物,或式2.21化合物,或式2.25化合物,或式2.33化合物,或式2.45化合物,或式2.1化合物。
尤其优选的本发明协同混合物包含式I化合物和下列化合物作为活性组分:式2.2.a化合物(2.2.a,aRS,1’S(-)N-(1’-甲基-2’-甲氧基乙基)-N-氯乙酰基-2-乙基-6-甲基苯胺)或式2.2.b化合物或式2.2化合物,其中R3是乙基、R4是甲基、且R5是乙氧基甲基,或式2.2化合物,其中R3是乙基、R4是乙基、且R5是甲氧基甲基,或化合物2.3,或式2.30化合物。
已经发现,式I化合物与式2.2a化合物(2.2.a,aRS,1’S(-)N-(1’-甲基-2’-甲氧基乙基)-N-氯乙酰基-2-乙基-6-甲基苯胺)的组合是特别有效的,尤其优选的式I化合物是在下文表1中列出的化合物1.001。
式I化合物可通过类似于在WO 97/46530中描述的方法制得,所述方法包括a)在惰性有机溶剂中,在碱存在下,将式II化合物其中R和m如式I中所定义,且X是离去基团例如卤素,与式III、IV、V或VI化合物反应其中R20、R23、R30和R40是羟基,且其它取代基如式I所定义,以生成式VII、VIII、IX或X化合物, 然后将这些化合物异构化,例如在碱和催化量的二甲基氨基吡啶(DMAP)或氰化物源存在下异构化;或者b)在惰性有机溶剂中,在碱和偶联剂存在下,将式XI化合物其中R和m如式I中所定义,与式III、IV、V或VI化合物反应,以形成式VII、VIII、IX或X化合物,然后将所得化合物异构化,例如按照在路线a)中描述的方法异构化。
其中Q是基团Q5的式I化合物其中Z是硫,且R36和R01如式I中所定义,可按照类似于已知方法(例如在WO 97/43270中描述的方法)的方法制得,所述方法包括a)在碱、二硫化碳、和式XIII烷化剂
R01-X1 (XIII),其中R01如式I中所定义,且X1是离去基团例如卤素或磺酸酯,存在下,将式XII化合物其中R36、R和m如上所定义,转化成式XIV化合物其中Z是硫,R、R01、R36和m如上所定义,然后任选在溶剂中,在碱存在下,用羟基胺盐酸盐将该化合物环化,以形成式Ie化合物其中Z是硫,且R、R36、R01和m如上所定义,然后用氧化剂例如间氯过苯甲酸(m-CPBA)将该化合物氧化。
含有基团Q1、Q2、Q3和Q4,其中R20、R23、R30和R40是羟基的式I化合物尤其可按照上述反应方案制得。反应方案2
为了制备其中Q是基团Q1-Q4,且R20、R23、R30和R40是羟基的式I化合物,可依据反应方案1路线a)使用式II羧酸衍生物作为原料,其中X是离去基团,例如卤素如碘、溴或尤其是氯,N-氧基邻苯二甲酰亚胺或N,O-二甲基羟基氨基或活化酯基团例如(由二环己基碳二亚胺(DCC)和适当羧酸形成的)或(由N-乙基-N’-(3-二甲基氨基丙基)碳二亚胺(EDC)和适当羧酸形成的)。在惰性有机溶剂例如卤代烃如二氯甲烷,腈例如乙腈,或芳烃例如甲苯中,在碱例如烷基胺如三乙胺,芳族胺例如吡啶或4-二甲基氨基吡啶(DMAP)存在下,将这些化合物与式III、IV、V或VI二酮衍生物反应,以形成式VII、VIII、IX和X异构体烯醇醚。酯化在0℃-110℃进行。
式VII、VIII、IX和X酯衍生物异构化成式I二酮衍生物(其中R20、R23、R30和R40是羟基)可例如按照类似于EP 369 803的方法,在碱例如烷基胺如三乙胺,碳酸盐例如碳酸钾,和催化量的DMAP或氰化物源例如丙酮氰醇或氰化钾存在下来进行。
按照反应方案1、路线b),所需的式I二酮(其中R20、R23、R30和R40是羟基)可这样获得,例如按照类似于《化学通信》(Chem.Lett.)1975,1045的方法,在惰性溶剂例如卤代烃如二氯甲烷,腈例如乙腈,或芳烃例如甲苯中,在碱例如烷基胺如三乙胺,和偶联剂例如2-氯-1-甲基-吡啶鎓碘化物存在下,用式III、IV、V或VI二酮衍生物将式XI羧酸酯化。根据所用的溶剂,酯化可在0℃-110℃进行,并且如路线a)所述,首先生成式I异构酯,并且如路线a)所述,例如在碱和催化量的DMAP,或氰化物源存在下,式I异构酯可异构化以形成式I二酮衍生物(其中R20、R23、R30和R40是羟基)。
其中Q是基团Q5的式I化合物的制备可这样进行,即按照反应方案2,例如采用类似于《合成》(Synthesis)1991,301;同前(ibid.)1988,793或《四面体》(Tetrahedron)32,3055(1976)的方法,在碱例如碳酸盐如碳酸钾,金属氢化物如氢化钠,或者以氟化钾/铝,和式III烷基化剂存在下,其中X1是离去基团如卤素例如碘、溴或尤其是氯、R25OSO2O-、CH3SO2O-或将式XII b-二酮衍生物与二硫化碳反应。该反应优选在溶剂例如酰胺如N,N-二甲基甲酰胺(DMF),亚砜例如二甲亚砜(DMSO),或腈例如乙腈中进行。在碱例如乙酸钠存在下,在溶剂例如醇如乙醇或醚例如四氢呋喃中,使用盐酸羟胺将形成的式XIV乙烯酮缩乙硫醇环化,以形成其中Z是S-的式Ie化合物。该环化反应在0℃-100℃进行。可任选按照类似于标准方法的方法,例如使用过酸如间氯过苯甲酸(m-CPBA)或过乙酸将式Ie化合物(Z=S)氧化,以形成相应的式Ie砜和亚砜(Z=SO-或SO2-),其中可通过氧化剂的量来控制硫原子的氧化程度(Z=SO-或SO2-)。
式Ie化合物的氧化(Z=SO-或SO2-)是按照例如在H.O.House,《现代合成反应》″Modern Synthetic Reactions″W.A.Benjamin,Inc.,Menlo Park,California,1972,p.334-335和353-354中描述的方法进行的。
在反应方案1(路线a)中,其中X是离去基团例如卤素如溴、碘或尤其是氯的式II活化羧酸衍生物可按照已知的标准方法,例如在C.Ferri″Reaktionen der organischen Synthese″,Georg Thieme Verlag,Stuttgart,1978,p.461 ff中描述的方法以及如下述反应方案3所示的方法制得。反应方案3
按照反应方案3,式II化合物(X=离去基团)或II(X=卤素)的制备可通过例如使用卤化剂来进行,所述卤化剂是例如亚硫酰卤如亚硫酰氯或亚硫酰溴;卤化磷或磷酰卤例如五氯化磷或三氯氧化磷或五溴化磷或磷酰溴;或草酰卤例如草酰氯,或通过使用用于形成活化酯的试剂例如N,N’-二环己基碳二亚胺(DCC)或N-乙基-N’-(3-二甲基氨基丙基)碳二亚胺(EDC)来进行。在作为卤化剂的式X化合物中,X是离去基团,例如卤素如氟、溴或碘和尤其是氯,且W1是例如PCl2、SOCl、SOBr或ClCOCO。
该方法任选在惰性有机溶剂例如脂族烃、卤代脂族烃、芳烃或卤代芳烃例如正己烷、苯、甲苯、二甲苯、二氯甲烷、1,2-二氯乙烷或氯苯中,在-20℃-该反应混合物的回流温度下、优选40-150℃温度下,在催化量的N,N-二甲基甲酰胺存在下进行。这样的反应一般是已知的,并且以关于离去基团X的多种变化形式描述于文献中。
式III、IV、V和VI化合物是已知的,并且可按照类似于在例如WO92/07837、DE 3 818 958、EP 338 992和DE 3 902 818中描述的方法制得。
在反应方案2中的式XII化合物可通过标准方法,由例如相应的式II化合物制得其中R和m如式I中所定义,且X是离去基团例如卤素,例如经由克莱森缩合而制得,或者通过与式XV酮基羧酸盐反应由式II化合物制得其中R36如式I中所定义,且M+是碱金属离子(参见例如WO 96/26192)。
式II和XI化合物是已知的,并且可按照类似于在例如WO 97/46530,《杂环》(Heterocycles),48,779(1998),《杂环》,46,129(1997)或《四面体通信》(Tetrahedron Letters),1749(1998)中描述的方法制得。
为了制备所有其官能团取决于(R)m定义的其它式I化合物,可使用多种已知的标准方法例如烷基化、卤化、酰化、酰胺化、肟化、氧化和还原,合适的制备方法的选择由各中间体中的取代基的性质(反应性)决定。WO97/46353中描述了这样的反应的实例。
在式I范围内的所有其它化合物可按照考虑吡啶基和Q基团的化学性质的简单方法来制得。
式I终产物可通过浓缩或将溶剂蒸发以常规方式分离,并通过在固体残余物不易溶于其中的溶剂例如醚、芳烃或氯代烃中将固体残余物重结晶或研制,通过蒸馏或使用柱色谱与合适的洗脱剂来纯化。
此外,本领域技术人员熟悉其中一些反应应当有利进行的顺序以防止可能的副反应。
当合成不能直接使得纯的异构体分离出来时,产物可呈两种或更多种异构体的混合物的形式。可按照自身已知的方法分离异构体。制备实施例: 实施例P1:制备4-羟基-3-(2-甲基-6-三氟甲基-吡啶-3-羰基)-二环 [3.2.11]辛-3-烯-2-酮:
将6.68g(0.0305mol)2-甲基-6-三氟甲基-烟酸甲酯(按照在《杂环》,46,129(1997)中描述的方法制得的)溶解在250ml甲醇/水(3∶1混合物)中,并在22℃分批加入1.92g(0.046mol)氢氧化锂水合物。在22℃保持4小时后,将该反应混合物加到乙酸乙酯和2N盐酸中;用水将有机相洗涤3次,用硫酸钠干燥,并通过蒸发浓缩,用少量己烷研制残余物。过滤后,获得了5.69g(产率为90%)预期的2-甲基-6-三氟甲基烟酸,熔点为147-149℃。
将所得2-甲基-6-三氟甲基-烟酸(2.0g,0.0098mol)溶解在20ml草酰氯中。加入3滴二甲基甲酰胺,并将该混合物回流1小时。然后使用旋转蒸发仪将该混合物浓缩,将残余物(2-甲基-6-三氟甲基烟酰氯)置于30ml二氯甲烷中。在0℃,加入2.7ml(0.0196mol)三乙胺和0.12g(0.00098mol)二甲基氨基吡啶,然后滴加溶解在20ml二氯甲烷中的1.49g(0.0108mol)二环[3.2.1]辛-2,4-二酮。在22℃保持3小时后,通过与2N盐酸一起振摇来萃取该反应混合物。将分离的二氯甲烷相用水洗涤,然后通过与10%碳酸氢钠水溶液振摇来萃取,用硫酸钠干燥,并通过蒸发浓缩。获得了3.18g(产率为100%)2-甲基-6-三氟甲基烟酸4-氧代二环[3.2.1]辛-2-烯-2-基酯,为油状物,可不用进一步纯化直接使用。将3.02g(0.0093mol)甲基-6-三氟甲基-烟酸4-氧代二环[3.2.1]辛-2-烯-2-基酯和1.9ml(0.0136mol)三乙胺溶解在45ml乙腈中。在22℃加入0.01ml丙酮氰醇。在22℃保持18小时后,将该反应混合物倒入水与2N盐酸的混合物中,并通过与乙酸乙酯振摇来萃取。将乙酸乙酯相依次用水和盐水洗涤,用硫酸钠干燥,并通过蒸发浓缩,将残余物溶解在少量温热的丙酮中。在静置时产物结晶出来。过滤后,获得了0.99g(产率为33%)预期的4-羟基-3-(2-甲基-6-三氟甲基-吡啶-3-羰基)-二环[3.2.1]辛基-3-烯-2-酮,为白色结晶形式(m.p.75-77℃)。实施例P2:(5-环丙基-3-甲硫基异噁唑-4-基)-(2-甲基-6-三氟甲基-吡 啶-3-基)-甲酮:
将14.8g(0.080mol)3-环丙基-3-氧代丙酸叔丁酯溶解在25mlMeOH中,加入1.93g(0.080mol)镁。滴加7ml四氯化碳,同时在冰浴中冷却,并将该反应混合物在22℃搅拌1小时以使反应完全。通过蒸发将其浓缩后,在22℃将残余物悬浮在100ml乙腈中,并滴加溶解在50ml乙腈中的16.31g(0.073mol)2-甲基-6-三氟甲基-烟酰氯(按照实施例P1中描述的方法制得的)。6小时后,将该反应混合物置于乙酸乙酯中,并用饱和碳酸氢钠溶液洗涤。将分离出的乙酸乙酯相用水洗涤,用硫酸钠干燥,并通过蒸发浓缩。将残余物溶解在160ml二氯甲烷中,并在22℃滴加10ml三氟乙酸。18小时后,将该反应混合物倒入水中,并用二氯甲烷萃取。将二氯甲烷相依次用水和盐水洗涤,用硫酸钠干燥,并通过蒸发浓缩。获得了17.3g(产率为88%)1-环丙基-3-(2-甲基-6-三氟甲基-吡啶-3-基)-丙-1,3-二酮,为油状物,可不用进一步纯化直接使用。
将所得1-环丙基-3-(2-甲基-6-三氟甲基-吡啶-3-基)-丙-1,3-二酮(15.0g,0.055mol)溶解在150ml二甲基甲酰胺中,在0℃分批加入50g以氧化铝为载体的氟化钾(Alox)(0.0055mol/g,0.276mol)。5分钟后,加入6.7g(0.088mol)二硫化碳。2小时后,滴加23.6g(0.166mol)甲基碘,并将该反应混合物在22℃加热。2小时后,过滤出Alox,将滤液倒入水中,并通过与乙酸乙酯振摇来萃取。将乙酸乙酯相依次用水和盐水洗涤,用硫酸钠干燥,并通过蒸发浓缩。通过硅胶色谱纯化残余物(洗脱剂:乙酸乙酯/己烷15/1)。获得了12.0g(产率60%)2-(二-甲硫基-亚甲基)-1-环丙基-3-(2-甲基-6-三氟甲基-吡啶-3-基)-丙-1,3-二酮,为固体。
将12.0g(0.033mol)该产物与5.4g(0.066mol)无水乙酸钠一起悬浮在120ml乙醇中。加入4.6g(0.066mol)盐酸羟胺,并将该混合物在22℃搅拌5小时。然后再加入2.7g无水乙酸钠和2.3g盐酸羟胺。18小时后,用水将该反应混合物稀释,并用乙酸乙酯萃取。将乙酸乙酯相依次用水和盐水洗涤,用硫酸钠干燥,并通过蒸发浓缩。用少量乙酸乙酯研制,获得了9.0g(79.5%)所需产物,为白色结晶(m.p.103-104℃)。实施例P3:(5-环丙基-3-甲基亚磺酰基异噁唑-4-基)-(2-甲基-6-三氟甲 基-吡啶-3-基)-甲酮
将1.50g(0.0043mol)(5-环丙基-3-甲硫基异噁唑-4-基)-(2-甲基-6-三氟甲基-吡啶-3-基)-甲酮溶解在30ml丙酮/水(2∶1混合物)中,并在22℃分批加入1.02g(0.0048mol)偏高碘酸钠。5小时后,使用旋转蒸发仪通过蒸发将该反应混合物浓缩。将残余物置于水和乙酸乙酯中。用硫酸钠将乙酸乙酯相干燥,并通过蒸发浓缩。通过硅胶色谱纯化残余物(洗脱剂:乙酸乙酯/己烷3/1)。获得了0.8g(51%)所需产物,为白色结晶(m.p.96-97℃)。实施例P4:制备3-羟基-4,4-二甲基-2-(2-甲基-6-三氟甲基-吡啶-3-羰 基)-环己-2-烯酮(A2-B24):
将6.68g(0.0305mol)2-甲基-6-三氟甲基-烟酸甲酯(按照在《杂环》,46,129(1997)中描述的方法制得的)溶解在250ml甲醇/水(3∶1混合物)中,并在22℃分批加入1.92g(0.046mol)氢氧化锂水合物。在22℃保持4小时后,将该反应混合物加到乙酸乙酯和2N盐酸中;用水将有机相洗涤3次,用硫酸钠干燥,并通过蒸发浓缩,用少量己烷研制残余物。过滤后,获得了5.69g(产率为90%)预期的2-甲基-6-三氟甲基烟酸,熔点为147-149℃。
将所得2-甲基-6-三氟甲基-烟酸(1.026g,0.005mol)溶解在20ml草酰氯中。加入3滴二甲基甲酰胺,并将该混合物回流1小时。然后用旋转蒸发仪通过蒸发将该混合物浓缩,并将残余物(2-甲基-6-三氟甲基-烟酰氯)置于100ml二氯甲烷中。在0℃加入1.6ml(0.0115mol)三乙胺和0.7g(0.005mol)4,4-二甲基-环己烷-1,3-二酮。在22℃保持2小时后,使用旋转蒸发仪除去溶剂,将剩余的残余物溶解在55ml乙腈中,为了使该中间体重排,加入0.15ml(0.0016mol)丙酮氰醇和0.79ml(0.0057mol)三乙胺。在室温搅拌4小时后,通过蒸发将该反应溶液浓缩。通过硅胶色谱纯化剩余的浆状物。将通过用甲苯、乙醇、二氧杂环己烷、三乙胺和水的混合物(100∶40∶20∶20∶5体积份)(使用所述混合物作为流动相Rf=0.39)洗脱而获得的浅黄色粘稠油状物溶解在二氯甲烷中,并依次用75ml盐酸5%和75ml水洗涤。用硫酸钠将有机溶液干燥后,通过蒸发浓缩,获得了1.05g(63%)纯的标题化合物。1H NMR(d6-DMSO,δppm):1.342,s,6H:2.088,t,J9Hz,2H:2.685,s,3H:2.982,t,J9Hz,2H:8.030,d,J8.1Hz,1H:8.094,d,J8.1Hz,1H。实施例P5:制备5-甲基-5-三氟甲基-环己烷-1,3-二酮(实施例B1066):
将0.64g钠加到40ml乙醇中,加入3.23ml乙酸甲酯和4.9 g 4,4,4-三氟-3-甲基-丁-2-烯酸异丙酯,并将该混合物在沸点温度加热18小时。用稀盐酸和乙酸乙酯萃取后,通过蒸发浓缩。将保留未纯化的2-甲基-4,6-二氧代-2-三氟甲基-环己烷甲酸甲酯在9.1g氢氧化钠存在下在甲醇与水的混合物中于沸点温度酯化。然后用盐酸将该混合物酸化,并用新鲜的乙酸乙酯萃取。重结晶(乙酸乙酯)后,获得了纯的5-甲基-5-三氟甲基环己烷-1,3-二酮,熔点为150-152℃。实施例P6:制备2-羟基-1-甲氧基-5-甲基-4-氧代环己-2-烯甲酸甲酯 (B1069):
用35.8g甲醇钠在65ml二甲亚砜中制成30%溶液,在30-35℃用20分钟加入16.7g 3-甲基-3-丁烯-2-酮与32.4g甲氧基丙二酸二甲酯。将该混合物在35℃搅拌1小时,用盐酸酸化,然后用二氯甲烷萃取数次。将有机相用水洗涤,干燥并浓缩。通过从热的乙酸乙酯和己烷中结晶,获得了纯的2-羟基-1-甲氧基-5-甲基-4-氧代-环己-2-烯羧酸甲酯,熔点为117-117.5℃。实施例P7:制备2-羟基-1-甲氧基-5-甲基-3-(2-甲基-6-三氟甲基-吡啶 -3-羰基)-4-氧代-环己-2-烯羧酸甲酯(A2-B1069):
将2.23g新制的2-甲基-6-三氟甲基-烟酰氯加到2.14g 2-羟基-1-甲氧基-5-甲基-4-氧代-环己-2-烯甲酸甲酯和2.02g三乙胺在30ml乙腈内的混合物中。约30分钟后,加入0.065g氰化钾,并将该混合物搅拌18小时。然后在pH2用水和乙酸乙酯萃取,用硫酸镁干燥,并通过蒸发浓缩。经由硅胶过滤(流动相∶乙酸乙酯/甲醇/三乙胺85∶10∶5),获得了纯的2-羟基-1-甲氧基-5-甲基-3-(2-甲基-6-三氟甲基-吡啶-3-羰基)-4-氧代-环己-2-烯羧酸甲酯,为粘稠的油状物。实施例P8:制备3-羟基-4-甲氧基-6-甲基-2-(2-甲基-6-三氟甲基-吡啶 -3-羰基)-环己-2-烯酮(A2-B1070):
将0.586g氢氧化钾加到在二氧杂环己烷/水(5∶3)内的1.4g 2-羟基-1-甲氧基-5-甲基-3-(2-甲基-6-三氟甲基-吡啶-3-羰基)-4-氧代-环己-2-烯羧酸甲酯中,并将该混合物搅拌3小时。然后将该混合物酸化(pH3),并用新鲜的乙酸乙酯萃取。通过类似于实施例P7的色谱法纯化粗产物,获得了3-羟基-4-甲氧基-6-甲基-2-(2-甲基-6-三氟甲基-吡啶-3-羰基)-环己-2-烯酮,为粘稠的油状物(根据1H-NMR,3种互变异构形式的混合物)。
按照类似方式,并使用在一般反应方案1和2以及其中所提及的参考文献中描述的方法,还可以制得在下表中列出的化合物。在下表中,Ph是苯基,且CC是乙炔基。表1:式Ib化合物: 化合物.
R75 R76 R77 R78 m.p.(℃)序号1.001 CH3 CF3 H H 75-771.002 CH3CH2 CF3 H H1.003 (CH3)2CH CF3 H H 111-1121.004 CH3(CH2)3 CF3 H H1.005 Ph CF3 H H 油状物1.006 CH2Br CF3 H H1.007 CH2OCH3 CF3 H H 124-1261.008 CH2SMe CF3 H H 油状物1.009 CH2SO2Me CF3 H H 55-551.010 SCH3 CF3 H H化合物
R75 R76 R77 R78 m.p.(℃)序号1.011 SOCH3 CF3 H H1.012 SO2CH3 CF3 H H1.013 SPh CF3 H H1.014 SOPh CF3 H H1.015 SO2Ph CF3 H H1.016 CH3 CF3CF2 H H1.017 CH3CH2 CF3CF2 H H1.018 (CH3)2CH CF3CF2 H H1.019 CH3(CH2)3 CF3CF2 H H1.020 Ph CF3CF2 H H1.021 CH2Br CF3CF2 H H1.022 CH2OCH3 CF3CF2 H H1.023 CH2SMe CF3CF2 H H1.024 CH2SO2Me CF3CF2 H H1.025 SCH3 CF3CF2 H H1.026 SOCH3 CF3CF2 H H1.027 SO2CH3 CF3CF2 H H1.028 SPh CF3CF2 H H1.029 SOPh CF3CF2 H H1.030 SO2Ph CF3CF2 H H1.031 CH3 CHF2 H H1.032 CH3CH2 CHF2 H H1.033 (CH3)2CH CHF2 H H1.034 CH3(CH2)3 CHF2 H H1.035 Ph CHF2 H H1.036 CH2Br CHF2 H H1.037 CH2OCH3 CHF2 H H1.038 CH2SMe CHF2 H H1.039 CH2SO2Me CHF2 H H1.040 SCH3 CHF2 H H1.041 SOCH3 CHF2 H H1.042 SO2CH3 CHF2 H H化合物
R75 R76 R77 R78 m.p.(℃)序号1.043 SPh CHF2 H H1.044 SOPh CHF2 H H1.045 SO2Ph CHF2 H H1.046 CH3 CF3 CH3 H1.047 CH3CH2 CF3 CH3 H1.048 (CH3)2CH CF3 CH3 H1.049 CH3(CH2)3 CF3 CH3 H1.050 Ph CF3 CH3 H1.051 CH2Br CF3 CH3 H1.052 CH2OCH3 CF3 CH3 H1.053 CH2SMe CF3 CH3 H1.054 CH2SO2Me CF3 CH3 H1.055 SCH3 CF3 CH3 H1.056 SOCH3 CF3 CH3 H1.057 SO2CH3 CF3 CH3 H1.058 SPh CF3 CH3 H1.059 SOPh CF3 CH3 H1.060 SO2Ph CF3 CH3 H1.061 CH3 CF3CF2 CH3 H1.062 CH3CH2 CF3CF2 CH3 H1.063 (CH3)2CH CF3CF2 CH3 H1.064 CH3(CH2)3 CF3CF2 CH3 H1.065 Ph CF3CF2 CH3 H1.066 CH2Br CF3CF2 CH3 H1.067 CH2OCH3 CF3CF2 CH3 H1.068 CH2SMe CF3CF2 CH3 H1.069 CH2SO2Me CF3CF2 CH3 H1.070 SCH3 CF3CF2 CH3 H1.071 SOCH3 CF3CF2 CH3 H1.072 SO2CH3 CF3CF2 CH3 H1.073 SPh CF3CF2 CH3 H1.074 SOPh CF3CF2 CH3 H化合物
R75 R76 R77 R78 m.p.(℃)序号1.075 SO2Ph CF3CF2 CH3 H1.076 CH3 CHF2 CH3 H1.077 CH3CH2 CHF2 CH3 H1.078 (CH3)2CH CHF2 CH3 H1.079 CH3(CH2)3 CHF2 CH3 H1.080 Ph CHF2 CH3 H1.081 CH2Br CHF2 CH3 H1.082 CH2OCH3 CHF2 CH3 H1.083 CH2SMe CHF2 CH3 H1.084 CH2SO2Me CHF2 CH3 H1.085 SCH3 CHF2 CH3 H1.086 SOCH3 CHF2 CH3 H1.087 SO2CH3 CHF2 CH3 H1.088 SPh CHF2 CH3 H1.089 SOPh CHF2 CH3 H1.090 SO2Ph CHF2 CH3 H1.091 CH3 CF3 H CH3 92-941.092 CH3CH2 CF3 H CH31.093 (CH3)2CH CF3 H CH31.094 CH3(CH2)3 CF3 H CH31.095 Ph CF3 H CH31.096 CH2Br CF3 H CH31.097 CH2OCH3 CF3 H CH31.098 CH2SMe CF3 H CH31.099 CH2SO2Me CF3 H CH31.100 SCH3 CF3 H CH31.101 SOCH3 CF3 H CH31.102 SO2CH3 CF3 H CH31.103 SPh CF3 H CH31.104 SOPh CF3 H CH31.105 SO2Ph CF3 H CH3
表2:式Ic化合物: 化合物. R75 R76 R77 R78 m.p.(℃)序号2.001 CH3 CF3 H H 107-1092.002 CH3CH2 CF3 H H 油状物2.003 (CH3)2CH CF3 H H 油状物2.004 CH3(CH2)3 CF3 H H2.005 Ph CF3 H H 油状物2.006 CH2Br CF3 H H2.007 CH2OCH3 CF3 H H2.008 CH2SMe CF3 H H2.009 CH2SO2Me CF3 H H2.010 SCH3 CF3 H H2.011 SOCH3 CF3 H H2.012 SO2CH3 CF3 H H2.013 SPh CF3 H H2.014 SOPh CF3 H H2.015 SO2Ph CF3 H H2.016 CH3 CF3CF2 H H2.017 CH3CH2 CF3CF2 H H2.018 (CH3)2CH CF3CF2 H H2.019 CH3(CH2)3 CF3CF2 H H2.020 Ph CF3CF2 H H2.021 CH2Br CF3CF2 H H2.022 CH2OCH3 CF3CF2 H H化合物
R75 R76 R77 R78 m.p.(℃)序号2.023 CH2SMe CF3CF2 H H2.024 CH2SO2Me CF3CF2 H H2.025 SCH3 CF3CF2 H H2.026 SOCH3 CF3CF2 H H2.027 SO2CH3 CF3CF2 H H2.028 SPh CF3CF2 H H2.029 SOPh CF3CF2 H H2.030 SO2Ph CF3CF2 H H2.031 CH3 CHF2 H H2.032 CH3CH2 CHF2 H H2.033 (CH3)2CH CHF2 H H2.034 CH3(CH2)3 CHF2 H H2.035 Ph CHF2 H H2.036 CH2Br CHF2 H H2.037 CH2OCH3 CHF2 H H2.038 CH2SMe CHF2 H H2.039 CH2SO2Me CHF2 H H2.040 SCH3 CHF2 H H2.041 SOCH3 CHF2 H H2.042 SO2CH3 CHF2 H H2.043 SPh CHF2 H H2.044 SOPh CHF2 H H2.045 SO2Ph CHF2 H H2.046 CH3 CF3 CH3 H2.047 CH3CH2 CF3 CH3 H2.048 (CH3)2CH CF3 CH3 H2.049 CH3(CH2)3 CF3 CH3 H2.050 Ph CF3 CH3 H2.051 CH2Br CF3 CH3 H2.052 CH2OCH3 CF3 CH3 H2.053 CH2SMe CF3 CH3 H2.054 CH2SO2Me CF3 CH3 H化合物
R75 R76 R77 R78 m.p.(℃)序号2.055 SCH3 CF3 CH3 H2.056 SOCH3 CF3 CH3 H2.057 SO2CH3 CF3 CH3 H2.058 SPh CF3 CH3 H2.059 SOPh CF3 CH3 H2.060 SO2Ph CF3 CH3 H2.061 CH3 CF3CF2 CH3 H2.062 CH3CH2 CF3CF2 CH3 H2.063 (CH3)2CH CF3CF2 CH3 H2.064 CH3(CH2)3 CF3CF2 CH3 H2.065 Ph CF3CF2 CH3 H2.066 CH2Br CF3CF2 CH3 H2.067 CH2OCH3 CF3CF2 CH3 H2.068 CH2SMe CF3CF2 CH3 H2.069 CH2SO2Me CF3CF2 CH3 H2.070 SCH3 CF3CF2 CH3 H2.071 SOCH3 CF3CF2 CH3 H2.072 SO2CH3 CF3CF2 CH3 H2.073 SPh CF3CF2 CH3 H2.074 SOPh CF3CF2 CH3 H2.075 SO2Ph CF3CF2 CH3 H2.076 CH3 CHF2 CH3 H2.077 CH3CH2 CHF2 CH3 H2.078 (CH3)2CH CHF2 CH3 H2.079 CH3(CH2)3 CHF2 CH3 H2.080 Ph CHF2 CH3 H2.081 CH2Br CHF2 CH3 H2.082 CH2OCH3 CHF2 CH3 H2.083 CH2SMe CHF2 CH3 H2.084 CH2SO2Me CHF2 CH3 H2.085 SCH3 CHF2 CH3 H2.086 SOCH3 CHF2 CH3 H化合物
R75 R76 R77 R78 m.p.(℃)序号2.087 SO2CH3 CHF2 CH3 H2.088 SPh CHF2 CH3 H2.089 SOPh CHF2 CH3 H2.090 SO2Ph CHF2 CH3 H2.091 CH3 CF3 H CH32.092 CH3CH2 CF3 H CH32.093 (CH3)2CH CF3 H CH32.094 CH3(CH2)3 CF3 H CH32.095 Ph CF3 H CH32.096 CH2Br CF3 H CH32.097 CH2OCH3 CF3 H CH32.098 CH2SMe CF3 H CH32.099 CH2SO2Me CF3 H CH32.100 SCH3 CF3 H CH32.101 SOCH3 CF3 H CH32.102 SO2CH3 CF3 H CH32.103 SPh CF3 H CH32.104 SOPh CF3 H CH32.105 SO2Ph CF3 H CH3 表3:式Id化合物: 化合物.
R75 R76 R77 R78 m.p.(℃)序号化合物 R75 R76 R77 R78 m.p.(℃)序号3.001 CH3 CF3 H H3.002 CH3CH2 CF3 H H3.003 (CH3)2CH CF3 H H3.004 CH3(CH2)3 CF3 H H3.005 Ph CF3 H H3.006 CH2Br CF3 H H3.007 CH2OCH3 CF3 H H3.008 CH2SMe CF3 H H3.009 CH2SO2Me CF3 H H3.010 SCH3 CF3 H H3.011 SOCH3 CF3 H H3.012 SO2CH3 CF3 H H3.013 SPh CF3 H H3.014 SOPh CF3 H H3.015 SO2Ph CF3 H H3.016 CH3 CF3CF2 H H3.017 CH3CH2 CF3CF2 H H3.018 (CH3)2CH CF3CF2 H H3.019 CH3(CH2)3 CF3CF2 H H3.020 Ph CF3CF2 H H3.021 CH2Br CF3CF2 H H3.022 CH2OCH3 CF3CF2 H H3.023 CH2SMe CF3CF2 H H3.024 CH2SO2Me CF3CF2 H H3.025 SCH3 CF3CF2 H H3.026 SOCH3 CF3CF2 H H3.027 SO2CH3 CF3CF2 H H3.028 SPh CF3CF2 H H3.029 SOPh CF3CF2 H H3.030 SO2Ph CF3CF2 H H3.031 CH3 CHF2 H H化合物 R75 R76 R77 R78 m.p.(℃)序号3.032 CH3CH2 CHF2 H H3.033 (CH3)2CH CHF2 H H3.034 CH3(CH2)3 CHF2 H H3.035 Ph CHF2 H H3.036 CH2Br CHF2 H H3.037 CH2OCH3 CHF2 H H3.038 CH2SMe CHF2 H H3.039 CH2SO2Me CHF2 H H3.040 SCH3 CHF2 H H3.041 SOCH3 CHF2 H H3.042 SO2CH3 CHF2 H H3.043 SPh CHF2 H H3.044 SOPh CHF2 H H3.045 SO2Ph CHF2 H H3.046 CH3 CF3 CH3 H3.047 CH3CH2 CF3 CH3 H3.048 (CH3)2CH CF3 CH3 H3.049 CH3(CH2)3 CF3 CH3 H3.050 Ph CF3 CH3 H3.051 CH2Br CF3 CH3 H3.052 CH2OCH3 CF3 CH3 H3.053 CH2SMe CF3 CH3 H3.054 CH2SO2Me CF3 CH3 H3.055 SCH3 CF3 CH3 H3.056 SOCH3 CF3 CH3 H3.057 SO2CH3 CF3 CH3 H3.058 SPh CF3 CH3 H3.059 SOPh CF3 CH3 H3.060 SO2Ph CF3 CH3 H3.061 CH3 CF3CF2 CH3 H3.062 CH3CH2 CF3CF2 CH3 H3.063 (CH3)2CH CF3CF2 CH3 H化合物 R75 R76 R77 R78 m.p.(℃)序号3.064 CH3(CH2)3 CF3CF2 CH3 H3.065 Ph CF3CF2 CH3 H3.066 CH2Br CF3CF2 CH3 H3.067 CH2OCH3 CF3CF2 CH3 H3.068 CH2SMe CF3CF2 CH3 H3.069 CH2SO2Me CF3CF2 CH3 H3.070 SCH3 CF3CF2 CH3 H3.071 SOCH3 CF3CF2 CH3 H3.072 SO2CH3 CF3CF2 CH3 H3.073 SPh CF3CF2 CH3 H3.074 SOPh CF3CF2 CH3 H3.075 SO2Ph CF3CF2 CH3 H3.076 CH3 CHF2 CH3 H3.077 CH3CH2 CHF2 CH3 H3.078 (CH3)2CH CHF2 CH3 H3.079 CH3(CH2)3 CHF2 CH3 H3.080 Ph CHF2 CH3 H3.081 CH2Br CHF2 CH3 H3.082 CH2OCH3 CHF2 CH3 H3.083 CH2SMe CHF2 CH3 H3.084 CH2SO2Me CHF2 CH3 H3.085 SCH3 CHF2 CH3 H3.086 SOCH3 CHF2 CH3 H3.087 SO2CH3 CHF2 CH3 H3.088 SPh CHF2 CH3 H3.089 SOPh CHF2 CH3 H3.090 SO2Ph CHF2 CH3 H3.091 CH3 CF3 H CH33.092 CH3CH2 CF3 H CH33.093 (CH3)2CH CF3 H CH33.094 CH3(CH2)3 CF3 H CH33.095 Ph CF3 H CH3化合物 R75 R76 R77 R78 m.p.(℃)序号3.096 CH2Br CF3 H CH33.097 CH2OCH3 CF3 H CH33.098 CH2SMe CF3 H CH33.099 CH2SO2Me CF3 H CH33.100 SCH3 CF3 H CH33.101 SOCH3 CF3 H CH33.102 SO2CH3 CF3 H CH33.103 SPh CF3 H CH33.104 SOPh CF3 H CH33.105 SO2Ph CF3 H CH3 表4:式Ie化合物: 化合物 R75 R76 R77 R78 Z m.p.(℃)序号4.001 CH3 CF3 H H S 103-1044.002 CH3CH2 CF3 H H S4.003 (CH3)2CH CF3 H H S4.004 CH3(CH2)3 CF3 H H S4.005 Ph CF3 H H S4.006 CH2Br CF3 H H S4.007 CH2OCH3 CF3 H H S4.008 CH2SMe CF3 H H S化合物 R75 R76 R77 R78 Z m.p.(℃)序号4.009 CH2SO2Me CF3 H H S4.010 SCH3 CF3 H H S4.011 SOCH3 CF3 H H S4.012 SO2CH3 CF3 H H S4.013 SPh CF3 H H S4.014 SOPh CF3 H H S4.015 SO2Ph CF3 H H S4.016 CH3 CF3CF2 H H S4.017 CH3CH2 CF3CF2 H H S4.018 (CH3)2CH CF3CF2 H H S4.019 CH3(CH2)3 CF3CF2 H H S4.020 Ph CF3CF2 H H S4.021 CH2Br CF3CF2 H H S4.022 CH2OCH3 CF3CF2 H H S4.023 CH2SMe CF3CF2 H H S4.024 CH2SO2Me CF3CF2 H H S4.025 SCH3 CF3CF2 H H S4.026 SOCH3 CF3CF2 H H S4.027 SO2CH3 CF3CF2 H H S4.028 SPh CF3CF2 H H S4.029 SOPh CF3CF2 H H S4.030 SO2Ph CF3CF2 H H S4.031 CH3 CHF2 H H S4.032 CH3CH2 CHF2 H H S4.033 (CH3)2CH CHF2 H H S4.034 CH3(CH2)3 CHF2 H H S4.035 Ph CHF2 H H S4.036 CH2Br CHF2 H H S4.037 CH2OCH3 CHF2 H H S4.038 CH2SMe CHF2 H H S4.039 CH2SO2Me CHF2 H H S4.040 SCH3 CHF2 H H S化合物 R75 R76 R77 R78 Z m.p.(℃)序号4.041 SOCH3 CHF2 H H S4.042 SO2CH3 CHF2 H H S4.043 SPh CHF2 H H S4.044 SOPh CHF2 H H S4.045 SO2Ph CHF2 H H S4.046 CH3 CF3 CH3 H S4.047 CH3CH2 CF3 CH3 H S4.048 (CH3)2CH CF3 CH3 H S4.049 CH3(CH2)3 CF3 CH3 H S4.050 Ph CF3 CH3 H S4.051 CH2Br CF3 CH3 H S4.052 CH2OCH3 CF3 CH3 H S4.053 CH2SMe CF3 CH3 H S4.054 CH2SO2Me CF3 CH3 H S4.055 SCH3 CF3 CH3 H S4.056 SOCH3 CF3 CH3 H S4.057 SO2CH3 CF3 CH3 H S4.058 SPh CF3 CH3 H S4.059 SOPh CF3 CH3 H S4.060 SO2Ph CF3 CH3 H S4.061 CH3 CF3CF2 CH3 H S4.062 CH3CH2 CF3CF2 CH3 H S4.063 (CH3)2CH CF3CF2 CH3 H S4.064 CH3(CH2)3 CF3CF2 CH3 H S4.065 Ph CF3CF2 CH3 H S4.066 CH2Br CF3CF2 CH3 H S4.067 CH2OCH3 CF3CF2 CH3 H S4.068 CH2SMe CF3CF2 CH3 H S4.069 CH2SO2Me CF3CF2 CH3 H S4.070 SCH3 CF3CF2 CH3 H S4.071 SOCH3 CF3CF2 CH3 H S4.072 SO2CH3 CF3CF2 CH3 H S化合物 R75 R76 R77 R78 Z m.p.(℃)序号4.073 SPh CF3CF2 CH3 H S4.074 SOPh CF3CF2 CH3 H S4.075 SO2Ph CF3CF2 CH3 H S4.076 CH3 CHF2 CH3 H S4.077 CH3CH2 CHF2 CH3 H S4.078 (CH3)2CH CHF2 CH3 H S4.079 CH3(CH2)3 CHF2 CH3 H S4.080 Ph CHF2 CH3 H S4.081 CH2Br CHF2 CH3 H S4.082 CH2OCH3 CHF2 CH3 H S4.083 CH2SMe CHF2 CH3 H S4.084 CH2SO2Me CHF2 CH3 H S4.085 SCH3 CHF2 CH3 H S4.086 SOCH3 CHF2 CH3 H S4.087 SO2CH3 CHF2 CH3 H S4.088 SPh CHF2 CH3 H S4.089 SOPh CHF2 CH3 H S4.090 SO2Ph CHF2 CH3 H S4.091 CH3 CF3 H CH3 S4.092 CH3CH2 CF3 H CH3 S4.093 (CH3)2CH CF3 H CH3 S4.094 CH3(CH2)3 CF3 H CH3 S4.095 Ph CF3 H CH3 S4.096 CH2Br CF3 H CH3 S4.097 CH2OCH3 CF3 H CH3 S4.098 CH2SMe CF3 H CH3 S4.099 CH2SO2Me CF3 H CH3 S4.100 SCH3 CF3 H CH3 S4.101 SOCH3 CF3 H CH3 S4.102 SO2CH3 CF3 H CH3 S4.103 SPh CF3 H CH3 S4.104 SOPh CF3 H CH3 S化合物. R75 R76 R77 R78 Z m.p.(℃)序号4.105 SO2Ph CF3 H CH3 S4.106 CH3 CF3 H H SO 96-974.107 CH3CH2 CF3 H H SO4.108 (CH3)2CH CF3 H H SO4.109 CH3(CH2)3 CF3 H H SO4.110 Ph CF3 H H SO4.111 CH2Br CF3 H H SO4.112 CH2OCH3 CF3 H H SO4.113 CH2SMe CF3 H H SO4.114 CH2SO2Me CF3 H H SO4.115 SCH3 CF3 H H SO4.116 SOCH3 CF3 H H SO4.117 SO2CH3 CF3 H H SO4.118 SPh CF3 H H SO4.119 SOPh CF3 H H SO4.120 SO2Ph CF3 H H SO4.121 CH3 CF3CF2 H H SO4.122 CH3CH2 CF3CF2 H H SO4.123 (CH3)2CH CF3CF2 H H SO4.124 CH3(CH2)3 CF3CF2 H H SO4.125 Ph CF3CF2 H H SO4.126 CH2Br CF3CF2 H H SO4.127 CH2OCH3 CF3CF2 H H SO4.128 CH2SMe CF3CF2 H H SO4.129 CH2SO2Me CF3CF2 H H SO4.130 SCH3 CF3CF2 H H SO4.131 SOCH3 CF3CF2 H H SO4.132 SO2CH3 CF3CF2 H H SO4.133 SPh CF3CF2 H H SO4.134 SOPh CF3CF2 H H SO4.135 SO2Ph CF3CF2 H H SO4.136 CH3 CHF2 H H SO化合物 R75 R76 R77 R78 Z m.p.(℃)序号4.137 CH3CH2 CHF2 H H SO4.138 (CH3)2CH CHF2 H H SO4.139 CH3(CH2)3 CHF2 H H SO4.140 Ph CHF2 H H SO4.141 CH2Br CHF2 H H SO4.142 CH2OCH3 CHF2 H H SO4.143 CH2SMe CHF2 H H SO4.144 CH2SO2Me CHF2 H H SO4.145 SCH3 CHF2 H H SO4.146 SOCH3 CHF2 H H SO4.147 SO2CH3 CHF2 H H SO4.148 SPh CHF2 H H SO4.149 SOPh CHF2 H H SO4.150 SO2Ph CHF2 H H SO4.151 CH3 CF3 CH3 H SO4.152 CH3CH2 CF3 CH3 H SO4.153 (CH3)2CH CF3 CH3 H SO4.154 CH3(CH2)3 CF3 CH3 H SO4.155 Ph CF3 CH3 H SO4.156 CH2Br CF3 CH3 H SO4.157 CH2OCH3 CF3 CH3 H SO4.158 CH2SMe CF3 CH3 H SO4.159 CH2SO2Me CF3 CH3 H SO4.160 SCH3 CF3 CH3 H SO4.161 SOCH3 CF3 CH3 H SO4.162 SO2CH3 CF3 CH3 H SO4.163 SPh CF3 CH3 H SO4.164 SOPh CF3 CH3 H SO4.165 SO2Ph CF3 CH3 H SO4.166 CH3 CF3CF2 CH3 H SO4.167 CH3CH2 CF3CF2 CH3 H SO4.168 (CH3)2CH CF3CF2 CH3 H SO化合物 R75 R76 R77 R78 Z m.p.(℃)序号4.169 CH3(CH2)3 CF3CF2 CH3 H SO4.170 Ph CF3CF2 CH3 H SO4.171 CH2Br CF3CF2 CH3 H SO4.172 CH2OCH3 CF3CF2 CH3 H SO4.173 CH2SMe CF3CF2 CH3 H SO4.174 CH2SO2Me CF3CF2 CH3 H SO4.175 SCH3 CF3CF2 CH3 H SO4.176 SOCH3 CF3CF2 CH3 H SO4.177 SO2CH3 CF3CF2 CH3 H SO4.178 SPh CF3CF2 CH3 H SO4.179 SOPh CF3CF2 CH3 H SO4.180 SO2Ph CF3CF2 CH3 H SO4.181 CH3 CHF2 CH3 H SO4.182 CH3CH2 CHF2 CH3 H SO4.183 (CH3)2CH CHF2 CH3 H SO4.184 CH3(CH2)3 CHF2 CH3 H SO4.185 Ph CHF2 CH3 H SO4.186 CH2Br CHF2 CH3 H SO4.187 CH2OCH3 CHF2 CH3 H SO4.188 CH2SMe CHF2 CH3 H SO4.189 CH2SO2Me CHF2 CH3 H SO4.190 SCH3 CHF2 CH3 H SO4.191 SOCH3 CHF2 CH3 H SO4.192 SO2CH3 CHF2 CH3 H SO4.193 SPh CHF2 CH3 H SO4.194 SOPh CHF2 CH3 H SO4.195 SO2Ph CHF2 CH3 H SO4.196 CH3 CF3 H CH3 SO4.197 CH3CH2 CF3 H CH3 SO4.198 (CH3)2CH CF3 H CH3 SO4.199 CH3(CH2)3 CF3 H CH3 SO4.200 Ph CF3 H CH3 SO化合物 R75 R76 R77 R78 Z m.p.(℃)序号4.201 CH2Br CF3 H CH3 SO4.202 CH2OCH3 CF3 H CH3 SO4.203 CH2SMe CF3 H CH3 SO4.204 CH2SO2Me CF3 H CH3 SO4.205 SCH3 CF3 H CH3 SO4.206 SOCH3 CF3 H CH3 SO4.207 SO2CH3 CF3 H CH3 SO4.208 SPh CF3 H CH3 SO4.209 SOPh CF3 H CH3 SO4.210 SO2Ph CF3 H CH3 SO4.211 CH3 CF3 H H SO2 无定形4.212 CH3CH2 CF3 H H SO24.213 (CH3)2CH CF3 H H SO24.214 CH3(CH2)3 CF3 H H SO24.215 Ph CF3 H H SO24.216 CH2Br CF3 H H SO24.217 CH2OCH3 CF3 H H SO24.218 CH2SMe CF3 H H SO24.219 CH2SO2Me CF3 H H SO24.220 SCH3 CF3 H H SO24.221 SOCH3 CF3 H H SO24.222 SO2CH3 CF3 H H SO24.223 SPh CF3 H H SO24.224 SOPh CF3 H H SO24.225 SO2Ph CF3 H H SO24.226 CH3 CF3CF2 H H SO24.227 CH3CH2 CF3CF2 H H SO24.228 (CH3)2CH CF3CF2 H H SO24.229 CH3(CH2)3 CF3CF2 H H SO24.230 Ph CF3CF2 H H SO24.231 CH2Br CF3CF2 H H SO2化合物 R75 R76 R77 R78 Z m.p.(℃)序号4.232 CH2OCH3 CF3CF2 H H SO24.233 CH2SMe CF3CF2 H H SO24.234 CH2SO2Me CF3CF2 H H SO24.235 SCH3 CF3CF2 H H SO24.236 SOCH3 CF3CF2 H H SO24.237 SO2CH3 CF3CF2 H H SO24.238 SPh CF3CF2 H H SO24.239 SOPh CF3CF2 H H SO24.240 SO2Ph CF3CF2 H H SO24.241 CH3 CHF2 H H SO24.242 CH3CH2 CHF2 H H SO24.243 (CH3)2CH CHF2 H H SO24.244 CH3(CH2)3 CHF2 H H SO24.245 Ph CHF2 H H SO24.246 CH2Br CHF2 H H SO24.247 CH2OCH3 CHF2 H H SO24.248 CH2SMe CHF2 H H SO24.249 CH2SO2Me CHF2 H H SO24.250 SCH3 CHF2 H H SO24.251 SOCH3 CHF2 H H SO24.252 SO2CH3 CHF2 H H SO24.253 SPh CHF2 H H SO24.254 SOPh CHF2 H H SO24.255 SO2Ph CHF2 H H SO24.256 CH3 CF3 CH3 H SO24.257 CH3CH2 CF3 CH3 H SO24.258 (CH3)2CH CF3 CH3 H SO24.259 CH3(CH2)3 CF3 CH3 H SO24.260 Ph CF3 CH3 H SO24.261 CH2Br CF3 CH3 H SO24.262 CH2OCH3 CF3 CH3 H SO24.263 CH2SMe CF3 CH3 H SO2化合物 R75 R76 R77 R78 Z m.p.(℃)序号4.264 CH2SO2Me CF3 CH3 H SO24.265 SCH3 CF3 CH3 H SO24.266 SOCH3 CF3 CH3 H SO24.267 SO2CH3 CF3 CH3 H SO24.268 SPh CF3 CH3 H SO24.269 SOPh CF3 CH3 H SO24.270 SO2Ph CF3 CH3 H SO24.271 CH3 CF3CF2 CH3 H SO24.272 CH3CH2 CF3CF2 CH3 H SO24.273 (CH3)2CH CF3CF2 CH3 H SO24.274 CH3(CH2)3 CF3CF2 CH3 H SO24.275 Ph CF3CF2 CH3 H SO24.276 CH2Br CF3CF2 CH3 H SO24.277 CH2OCH3 CF3CF2 CH3 H SO24.278 CH2SMe CF3CF2 CH3 H SO24.279 CH2SO2Me CF3CF2 CH3 H SO24.280 SCH3 CF3CF2 CH3 H SO24.281 SOCH3 CF3CF2 CH3 H SO24.282 SO2CH3 CF3CF2 CH3 H SO24.283 SPh CF3CF2 CH3 H SO24.284 SOPh CF3CF2 CH3 H SO24.285 SO2Ph CF3CF2 CH3 H SO24.286 CH3 CHF2 CH3 H SO24.287 CH3CH2 CHF2 CH3 H SO24.288 (CH3)2CH CHF2 CH3 H SO24.289 CH3(CH2)3 CHF2 CH3 H SO24.290 Ph CHF2 CH3 H SO24.291 CH2Br CHF2 CH3 H SO24.292 CH2OCH3 CHF2 CH3 H SO24.293 CH2SMe CHF2 CH3 H SO24.294 CH2SO2Me CHF2 CH3 H SO24.295 SCH3 CHF2 CH3 H SO2化合物 R75 R76 R77 R78 Z m.p.(℃)序号4.296 SOCH3 CHF2 CH3 H SO24.297 SO2CH3 CHF2 CH3 H SO24.298 SPh CHF2 CH3 H SO24.299 SOPh CHF2 CH3 H SO24.300 SO2Ph CHF2 CH3 H SO24.301 CH3 CF3 H CH3 SO24.302 CH3CH2 CF3 H CH3 SO24.303 (CH3)2CH CF3 H CH3 SO24.304 CH3(CH2)3 CF3 H CH3 SO24.305 Ph CF3 H CH3 SO24.306 CH2Br CF3 H CH3 SO24.307 CH2OCH3 CF3 H CH3 SO24.308 CH2SMe CF3 H CH3 SO24.309 CH2SO2Me CF3 H CH3 SO24.310 SCH3 CF3 H CH3 SO24.311 SOCH3 CF3 H CH3 SO24.312 SO2CH3 CF3 H CH3 SO24.313 SPh CF3 H CH3 SO24.314 SOPh CF3 H CH3 SO24.315 SO2Ph CF3 H CH3 SO2 表5:式XVI化合物: 化合物 R79 R80 R81 R82序号A1 H H H CF3化合物. R79 R80 R81 R82序号A2 CH3 H H CF3A3 CH3CH2 H H CF3A4 (CH3)2CH H H CF3A5 (CH3)3C H H CF3A6 环丙基 H H CF3A7 CH3(CH2)2 H H CF3A8 CH3OCH2 H H CF3A9 CH3O(CH2)2 H H CF3A10 Ph H H CF3A11 PhO H H CF3A12 PhS H H CF3A13 PhSO H H CF3A14 PhSO2 H H CF3A15 CH3S H H CF3A16 CH3SO H H CF3A17 CF3 H H CF3A18 F2CH H H CF3A19 HCC H H CF3A20 CH3CC H H CF3A21 CH2=CH H H CF3A22 CH2=CHCH2 H H CF3A23 CH3SO2N(CH3) H H CF3A24 (CH3)2N H H CF3A25 (CH3)2NSO2 H H CF3A26 ClCH2 H H CF3A27 CH3SCH2 H H CF3A28 CH3SOCH2 H H CF3A29 CH3SO2CH2 H H CF3A30 [1,2,4]-三唑-1-基-甲基 H H CF3A31 CH3 CF3 H CH3A32 CH3 CH3 H CF3A33 H H H CF3CF2化合物 R79 R80 R81 R82序号A34 CH3 H H CF3CF2A35 CH3CH2 H H CF3CF2A36 环丙基 H H CF3CF2A37 (CH3)3C H H CF3CF2A38 (CH3)2CH H H CF3CF2A39 CH3(CH2)2 H H CF3CF2A40 CH3OCH2 H H CF3CF2A41 CH3O(CH2)2 H H CF3CF2A42 Ph H H CF3CF2A43 PhO H H CF3CF2A44 PhS H H CF3CF2A45 PhSO H H CF3CF2A46 PhSO2 H H CF3CF2A47 CH3S H H CF3CF2A48 CH3SO H H CF3CF2A49 CF3 H H CF3CF2A50 F2CH H H CF3CF2A51 HCC H H CF3CF2A52 CH3CC H H CF3CF2A53 CH2=CH H H CF3CF2A54 CH2=CHCH2 H H CF3CF2A55 CH3SO2N(CH3) H H CF3CF2A56 (CH3)2N H H CF3CF2A57 (CH3)2NSO2 H H CF3CF2A58 ClCH2 H H CF3CF2A59 CH3SCH2 H H CF3CF2A60 CH3SOCH2 H H CF3CF2A61 CH3SO2CH2 H H CF3CF2A62 [1,2,4]-三唑-1-基-甲基 H H CF3CF2A63 H H H CF3CF2CF2A64 CH3 H H CF3CF2CF2A65 CH3CH2 H H CF3CF2CF2化合物. R79 R80 R81 R82序号A66 环丙基 H H CF3CF2CF2A67 (CH3)3C H H CF3CF2CF2A68 (CH3)2CH H H CF3CF2CF2A69 CH3(CH2)2 H H CF3CF2CF2A70 CH3OCH2 H H CF3CF2CF2A71 CH3O(CH2)2 H H CF3CF2CF2A72 Ph H H CF3CF2CF2A73 PhO H H CF3CF2CF2A74 PhS H H CF3CF2CF2A75 PhSO H H CF3CF2CF2A76 PhSO2 H H CF3CF2CF2A77 CH3S H H CF3CF2CF2A78 CH3SO H H CF3CF2CF2A79 CF3 H H CF3CF2CF2A80 F2CH H H CF3CF2CF2A81 HCC H H CF3CF2CF2A82 CH3CC H H CF3CF2CF2A83 CH2=CH H H CF3CF2CF2A84 CH2=CHCH2 H H CF3CF2CF2A85 CH3SO2N(CH3) H H CF3CF2CF2A86 (CH3)2N H H CF3CF2CF2A87 (CH3)2NSO2 H H CF3CF2CF2A88 ClCH2 H H CF3CF2CF2A89 CH3SCH2 H H CF3CF2CF2A90 CH3SOCH2 H H CF3CF2CF2A91 CH3SO2CH2 H H CF3CF2CF2A92 [1,2,4]-三唑-1-基-甲基 H H CF3CF2CF2A93 H H H CF2ClA94 CH3 H H CF2ClA95 CH3CH2 H H CF2ClA96 环丙基 H H CF2ClA97 (CH3)3C H H CF2Cl化合物 R79 R80 R81 R82序号A98 (CH3)2CH H H CF2ClA99 CH3(CH2)2 H H CF2ClA100 CH3OCH2 H H CF2ClA101 CH3O(CH2)2 H H CF2ClA102 Ph H H CF2ClA103 PhO H H CF2ClA104 PhS H H CF2ClA105 PhSO H H CF2ClA106 PhSO2 H H CF2ClA107 CH3S H H CF2ClA108 CH3SO H H CF2ClA109 CF3 H H CF2ClA110 F2CH H H CF2ClA111 HCC H H CF2ClA112 CH3CC H H CF2ClA113 CH2=CH H H CF2ClA114 CH2=CHCH2 H H CF2ClA115 CH3SO2N(CH3) H H CF2ClA116 (CH3)2N H H CF2ClA117 (CH3)2NSO2 H H CF2ClA118 ClCH2 H H CF2ClA119 CH3SCH2 H H CF2ClA120 CH3SOCH2 H H CF2ClA121 CH3SO2CH2 H H CF2ClA122 [1,2,4]-三唑-1-基-甲基 H H CF2ClA123 H H H CHF2A124 CH3 H H CHF2A125 CH3CH2 H H CHF2A126 环丙基 H H CHF2A127 (CH3)3C H H CHF2A128 (CH3)2CH H H CHF2A129 CH3(CH2)2 H H CHF2化合物 R79 R80 R81 R82序号A130 CH3OCH2 H H CHF2A131 CH3O(CH2)2 H H CHF2A132 Ph H H CHF2A133 PhO H H CHF2A134 PhS H H CHF2A135 PhSO H H CHF2A136 PhSO2 H H CHF2A137 CH3S H H CHF2A138 CH3SO H H CHF2A139 CF3 H H CHF2A140 F2CH H H CHF2A141 HCC H H CHF2A142 CH3CC H H CHF2A143 CH2=CH H H CHF2A144 CH2=CHCH2 H H CHF2A145 CH3SO2N(CH3) H H CHF2A146 (CH3)2N H H CHF2A147 (CH3)2NSO2 H H CHF2A148 ClCH2 H H CHF2A149 CH3SCH2 H H CHF2A150 CH3SOCH2 H H CHF2A151 CH3SO2CH2 H H CHF2A152 [1,2,4]-三唑-1-基-甲基 H H CHF2A153 H H H CCl3A154 CH3 H H CCl3A155 CH3CH2 H H CCl3A156 环丙基 H H CCl3A157 (CH3)3C H H CCl3A158 (CH3)2CH H H CCl3A159 CH3(CH2)2 H H CCl3A160 CH3OCH2 H H CCl3A161 CH3O(CH2)2 H H CCl3化合物 R79 R80 R81 R82序号A162 Ph H H CCl3A163 PhO H H CCl3A164 PhS H H CCl3A165 PhSO H H CCl3A166 PhSO2 H H CCl3A167 CH3S H H CCl3A168 CH3SO H H CCl3A169 CF3 H H CCl3A170 F2CH H H CCl3A171 HCC H H CCl3A172 CH3CC H H CCl3A173 CH2=CH H H CCl3A174 CH2=CHCH2 H H CCl3A175 CH3SO2N(CH3) H H CCl3A176 (CH3)2N H H CCl3A177 (CH3)2NSO2 H H CCl3A178 ClCH2 H H CCl3A179 CH3SCH2 H H CCl3A180 CH3SOCH2 H H CCl3A181 CH3SO2CH2 H H CCl3A182 [1,2,4]-三唑-1-基-甲基 H H CCl3A183 H H CH3 CF3A184 CH3 H CH3 CF3A185 CH3CH2 H CH3 CF3A186 环丙基 H CH3 CF3A187 (CH3)3C H CH3 CF3A188 (CH3)2CH H CH3 CF3A189 CH3(CH2)2 H CH3 CF3A190 CH3OCH2 H CH3 CF3A191 CH3O(CH2)2 H CH3 CF3A192 Ph H CH3 CF3A193 PhO H CH3 CF3化合物 R79 R80 R81 R82序号A194 PhS H CH3 CF3A195 PhSO H CH3 CF3A196 PhSO2 H CH3 CF3A197 CH3S H CH3 CF3A198 CH3SO H CH3 CF3A199 CF3 H CH3 CF3A200 F2CH H CH3 CF3A201 HCC H CH3 CF3A202 CH3CC H CH3 CF3A203 CH2=CH H CH3 CF3A204 CH2=CHCH2 H CH3 CF3A205 CH3SO2N(CH3) H CH3 CF3A206 (CH3)2N H CH3 CF3A207 (CH3)2NSO2 H CH3 CF3A208 ClCH2 H CH3 CF3A209 CH3SCH2 H CH3 CF3A210 CH3SOCH2 H CH3 CF3A211 CH3SO2CH2 H CH3 CF3A212 H H CH3 CF3CF2A213 CH3 H CH3 CF3CF2A214 CH3CH2 H CH3 CF3CF2A215 环丙基 H CH3 CF3CF2A216 (CH3)3C H CH3 CF3CF2A217 (CH3)2CH H CH3 CF3CF2A218 CH3(CH2)2 H CH3 CF3CF2A219 CH3OCH2 H CH3 CF3CF2A220 CH3O(CH2)2 H CH3 CF3CF2A221 Ph H CH3 CF3CF2A222 PhO H CH3 CF3CF2A223 PhS H CH3 CF3CF2A224 PhSO H CH3 CF3CF2A225 PhSO2 H CH3 CF3CF2化合物 R79 R80 R81 R82序号A226 CH3S H CH3 CF3CF2A227 CH3SO H CH3 CF3CF2A228 CF3 H CH3 CF3CF2A229 F2CH H CH3 CF3CF2A230 HCC H CH3 CF3CF2A231 CH3CC H CH3 CF3CF2A232 CH2=CH H CH3 CF3CF2A233 CH2=CHCH2 H CH3 CF3CF2A234 CH3SO2N(CH3)H CH3 CF3CF2A235 (CH3)2N H CH3 CF3CF2A236 (CH3)2NSO2 H CH3 CF3CF2A237 ClCH2 H CH3 CF3CF2A238 CH3SCH2 H CH3 CF3CF2A239 CH3SOCH2 H CH3 CF3CF2A240 CH3SO2CH2 H CH3 CF3CF2A241 H H CH3 CF3CF2CF2A242 CH3 H CH3 CF3CF2CF2A243 CH3CH2 H CH3 CF3CF2CF2A244 环丙基 H CH3 CF3CF2CF2A245 (CH3)3C H CH3 CF3CF2CF2A246 (CH3)2CH H CH3 CF3CF2CF2A247 CH3(CH2)2 H CH3 CF3CF2CF2A248 CH3OCH2 H CH3 CF3CF2CF2A249 CH3O(CH2)2 H CH3 CF3CF2CF2A250 Ph H CH3 CF3CF2CF2A251 PhO H CH3 CF3CF2CF2A252 PhS H CH3 CF3CF2CF2A253 PhSO H CH3 CF3CF2CF2A254 PhSO2 H CH3 CF3CF2CF2A255 CH3S H CH3 CF3CF2CF2A256 CH3SO H CH3 CF3CF2CF2A257 CF3 H CH3 CF3CF2CF2化合物 R79 R80 R81 R82序号A258 F2CH H CH3 CF3CF2CF2A259 HCC H CH3 CF3CF2CF2A260 CH3CC H CH3 CF3CF2CF2A261 CH2=CH H CH3 CF3CF2CF2A262 CH2=CHCH2 H CH3 CF3CF2CF2A263 CH3SO2N(CH3) H CH3 CF3CF2CF2A264 (CH3)2N H CH3 CF3CF2CF2A265 (CH3)2NSO2 H CH3 CF3CF2CF2A266 ClCH2 H CH3 CF3CF2CF2A267 CH3SCH2 H CH3 CF3CF2CF2A268 CH3SOCH2 H CH3 CF3CF2CF2A269 CH3SO2CH2 H CH3 CF3CF2CF2A270 H H CH3 CF2ClA271 CH3 H CH3 CF2ClA272 CH3CH2 H CH3 CF2ClA273 环丙基 H CH3 CF2ClA274 (CH3)3C H CH3 CF2ClA275 (CH3)2CH H CH3 CF2ClA276 CH3(CH2)2 H CH3 CF2ClA277 CH3OCH2 H CH3 CF2ClA278 CH3O(CH2)2 H CH3 CF2ClA279 Ph H CH3 CF2ClA280 PhO H CH3 CF2ClA281 PhS H CH3 CF2ClA282 PhSO H CH3 CF2ClA283 PhSO2 H CH3 CF2ClA284 CH3S H CH3 CF2ClA285 CH3SO H CH3 CF2ClA286 CF3 H CH3 CF2ClA287 F2CH H CH3 CF2ClA288 HCC H CH3 CF2ClA289 CH3CC H CH3 CF2Cl化合物 R79 R80 R81 R82序号A290 CH2=CH H CH3 CF2ClA291 CH2=CHCH2 H CH3 CF2ClA292 CH3SO2N(CH3) H CH3 CF2ClA293 (CH3)2N H CH3 CF2ClA294 (CH3)2NSO2 H CH3 CF2ClA295 ClCH2 H CH3 CF2ClA296 CH3SCH2 H CH3 CF2ClA297 CH3SOCH2 H CH3 CF2ClA298 CH3SO2CH2 H CH3 CF2ClA299 H H CH3 CHF2A300 CH3 H CH3 CHF2A301 CH3CH2 H CH3 CHF2A302 环丙基 H CH3 CHF2A303 (CH3)3C H CH3 CHF2A304 (CH3)2CH H CH3 CHF2A305 CH3(CH2)2 H CH3 CHF2A306 CH3OCH2 H CH3 CHF2A307 CH3O(CH2)2 H CH3 CHF2A308 Ph H CH3 CHF2A309 PhO H CH3 CHF2A310 PhS H CH3 CHF2A311 PhSO H CH3 CHF2A312 PhSO2 H CH3 CHF2A313 CH3S H CH3 CHF2A314 CH3SO H CH3 CHF2A315 CF3 H CH3 CHF2A316 F2CH H CH3 CHF2A317 HCC H CH3 CHF2A318 CH3CC H CH3 CHF2A319 CH2=CH H CH3 CHF2A320 CH2=CHCH2 H CH3 CHF2A321 CH3SO2N(CH3) H CH3 CHF2化合物 R79 R80 R81 R82序号A322 (CH3)2N H CH3 CHF2A323 (CH3)2NSO2 H CH3 CHF2A324 ClCH2 H CH3 CHF2A325 CH3SCH2 H CH3 CHF2A326 CH3SOCH2 H CH3 CHF2A327 CH3SO2CH2 H CH3 CHF2A328 H H CH3 CCl3A329 CH3 H CH3 CCl3A330 CH3CH2 H CH3 CCl3A331 (CH3)3C H CH3 CCl3A332 (CH3)2CH H CH3 CCl3A333 环丙基 H CH3 CCl3A334 CH3(CH2)2 H CH3 CCl3A335 CH3OCH2 H CH3 CCl3A336 CH3O(CH2)2 H CH3 CCl3A337 Ph H CH3 CCl3A338 PhO H CH3 CCl3A339 PhS H CH3 CCl3A340 PhSO H CH3 CCl3A341 PhSO2 H CH3 CCl3A342 CH3S H CH3 CCl3A343 CH3SO H CH3 CCl3A344 CF3 H CH3 CCl3A345 F2CH H CH3 CCl3A346 HCC H CH3 CCl3A347 CH3CC H CH3 CCl3A348 CH2=CH H CH3 CCl3A349 CH2=CHCH2 H CH3 CCl3A350 CH3SO2N(CH3) H CH3 CCl3A351 (CH3)2N H CH3 CCl3A352 (CH3)2NSO2 H CH3 CCl3A353 ClCH2 H CH3 CCl3化合物 R79 R80 R81 R82序号A354 CH3SCH2 H CH3 CCl3A355 CH3SOCH2 H CH3 CCl3A356 CH3SO2CH2 H CH3 CCl3A357 H H Ph CF3A358 CH3 H Ph CF3A359 CH3CH2 H Ph CF3A360 环丙基 H Ph CF3A361 (CH3)3C H Ph CF3A362 (CH3)2CH H Ph CF3A363 CH3(CH2)2 H Ph CF3A364 CH3OCH2 H Ph CF3A365 CH3O(CH2)2 H Ph CF3A366 Ph H Ph CF3A367 PhO H Ph CF3A368 PhS H Ph CF3A369 PhSO H Ph CF3A370 PhSO2 H Ph CF3A371 CH3S H Ph CF3A372 CH3SO H Ph CF3A373 CF3 H Ph CF3A374 F2CH H Ph CF3A375 HCC H Ph CF3A376 CH3CC H Ph CF3A377 CH2=CH H Ph CF3A378 CH2=CHCH2 H Ph CF3A379 CH3SO2N(CH3) H Ph CF3A380 (CH3)2N H Ph CF3A381 (CH3)2NSO2 H Ph CF3A382 ClCH2 H Ph CF3A383 CH3SCH2 H Ph CF3A384 CH3SOCH2 H Ph CF3A385 CH3SO2CH2 H Ph CF3化合物 R79 R80 R81 R82序号A386 H H Ph CF3CF2A387 CH3 H Ph CF3CF2A388 CH3CH2 H Ph CF3CF2A389 环丙基 H Ph CF3CF2A390 (CH3)3C H Ph CF3CF2A391 (CH3)2CH H Ph CF3CF2A392 CH3(CH2)2 H Ph CF3CF2A393 CH3OCH2 H Ph CF3CF2A394 CH3O(CH2)2 H Ph CF3CF2A395 Ph H Ph CF3CF2A396 PhO H Ph CF3CF2A397 PhS H Ph CF3CF2A398 PhSO H Ph CF3CF2A399 PhSO2 H Ph CF3CF2A400 CH3S H Ph CF3CF2A401 CH3SO H Ph CF3CF2A402 CF3 H Ph CF3CF2A403 F2CH H Ph CF3CF2A404 HCC H Ph CF3CF2A405 CH3CC H Ph CF3CF2A406 CH2=CH H Ph CF3CF2A407 CH2=CHCH2 H Ph CF3CF2A408 CH3SO2N(CH3) H Ph CF3CF2A409 (CH3)2N H Ph CF3CF2A410 (CH3)2NSO2 H Ph CF3CF2A411 ClCH2 H Ph CF3CF2A412 CH3SCH2 H Ph CF3CF2A413 CH3SOCH2 H Ph CF3CF2A414 CH3SO2CH2 H Ph CF3CF2A415 H H Ph CF3CF2CF2A416 CH3 H Ph CF3CF2CF2A417 CH3CH2 H Ph CF3CF2CF2化合物. R79 R80 R81 R82序号A418 环丙基 H Ph CF3CF2CF2A419 (CH3)3C H Ph CF3CF2CF2A420 (CH3)2CH H Ph CF3CF2CF2A421 CH3(CH2)2 H Ph CF3CF2CF2A422 CH3OCH2 H Ph CF3CF2CF2A423 CH3O(CH2)2 H Ph CF3CF2CF2A424 Ph H Ph CF3CF2CF2A425 PhO H Ph CF3CF2CF2A426 PhS H Ph CF3CF2CF2A427 PhSO H Ph CF3CF2CF2A428 PhSO2 H Ph CF3CF2CF2A429 CH3S H Ph CF3CF2CF2A430 CH3SO H Ph CF3CF2CF2A431 CF3 H Ph CF3CF2CF2A432 F2CH H Ph CF3CF2CF2A433 HCC H Ph CF3CF2CF2A434 CH3CC H Ph CF3CF2CF2A435 CH2=CH H Ph CF3CF2CF2A436 CH2=CHCH2 H Ph CF3CF2CF2A437 CH3SO2N(CH3) H Ph CF3CF2CF2A438 (CH3)2N H Ph CF3CF2CF2A439 (CH3)2NSO2 H Ph CF3CF2CF2A440 ClCH2 H Ph CF3CF2CF2A441 CH3SCH2 H Ph CF3CF2CF2A442 CH3SOCH2 H Ph CF3CF2CF2A443 CH3SO2CH2 H Ph CF3CF2CF2A444 H H Ph CF2ClA445 CH3 H Ph CF2ClA446 CH3CH2 H Ph CF2ClA447 cyclopropyl H Ph CF2ClA448 (CH3)3C H Ph CF2ClA449 (CH3)2CH H Ph CF2Cl化合物 R79 R80 R81 R82序号A450 CH3(CH2)2 H Ph CF2ClA451 CH3OCH2 H Ph CF2ClA452 CH3O(CH2)2 H Ph CF2ClA453 Ph H Ph CF2ClA454 PhO H Ph CF2ClA455 PhS H Ph CF2ClA456 PhSO H Ph CF2ClA457 PhSO2 H Ph CF2ClA458 CH3S H Ph CF2ClA459 CH3SO H Ph CF2ClA460 CF3 H Ph CF2ClA461 F2CH H Ph CF2ClA462 HCC H Ph CF2ClA463 CH3CC H Ph CF2ClA464 CH2=CH H Ph CF2ClA465 CH2=CHCH2 H Ph CF2ClA466 CH3SO2N(CH3) H Ph CF2ClA467 (CH3)2N H Ph CF2ClA468 (CH3)2NSO2 H Ph CF2ClA469 ClCH2 H Ph CF2ClA470 CH3SCH2 H Ph CF2ClA471 CH3SOCH2 H Ph CF2ClA472 CH3SO2CH2 H Ph CF2ClA473 H H Ph CHF2A474 CH3 H Ph CHF2A475 CH3CH2 H Ph CHF2A476 环丙基 H Ph CHF2A477 (CH3)3C H Ph CHF2A478 (CH3)2CH H Ph CHF2A479 CH3(CH2)2 H Ph CHF2A480 CH3OCH2 H Ph CHF2A481 CH3O(CH2)2 H Ph CHF2化合物 R79 R80 R81 R82序号A482 Ph H Ph CHF2A483 PhO H Ph CHF2A484 PhS H Ph CHF2A485 PhSO H Ph CHF2A486 PhSO2 H Ph CHF2A487 CH3S H Ph CHF2A488 CH3SO H Ph CHF2A489 CF3 H Ph CHF2A490 F2CH H Ph CHF2A491 HCC H Ph CHF2A492 CH3CC H Ph CHF2A493 CH2=CH H Ph CHF2A494 CH2=CHCH2 H Ph CHF2A495 CH3SO2N(CH3) H Ph CHF2A496 (CH3)2N H Ph CHF2A497 (CH3)2NSO2 H Ph CHF2A498 ClCH2 H Ph CHF2A499 CH3SCH2 H Ph CHF2A500 CH3SOCH2 H Ph CHF2A501 CH3SO2CH2 H Ph CHF2A502 H H Ph CCl3A503 CH3 H Ph CCl3A504 CH3CH2 H Ph CCl3A505 环丙基 H Ph CCl3A506 (CH3)3C H Ph CCl3A507 (CH3)2CH H Ph CCl3A508 CH3(CH2)2 H Ph CCl3A509 CH3OCH2 H Ph CCl3A510 CH3O(CH2)2 H Ph CCl3A511 Ph H Ph CCl3A512 PhO H Ph CCl3A513 PhS H Ph CCl3化合物 R79 R80 R81 R82序号A514 PhSO H Ph CCl3A515 PhSO2 H Ph CCl3A516 CH3S H Ph CCl3A517 CH3SO H Ph CCl3A518 CF3 H Ph CCl3A519 F2CH H Ph CCl3A520 HCC H Ph CCl3A521 CH3CC H Ph CCl3A522 CH2=CH H Ph CCl3A523 CH2=CHCH2 H Ph CCl3A524 CH3SO2N(CH3) H Ph CCl3A525 (CH3)2N H Ph CCl3A526 (CH3)2NSO2 H Ph CCl3A527 ClCH2 H Ph CCl3A528 CH3SCH2 H Ph CCl3A529 CH3SOCH2 H Ph CCl3A530 CH3SO2CH2 H Ph CCl3A531 H CH3 H CF3A532 H CH3CH2 H CF3A533 H 环丙基 H CF3A534 H (CH3)3CH H CF3A535 H (CH3)2CH H CF3A536 H CH3(CH2)2 H CF3A537 H CH3OCH2 H CF3A538 H CH3O(CH2)2 H CF3A539 H Ph H CF3A540 H PhO H CF3A541 H PhS H CF3A542 H PhSO H CF3A543 H PhSO2 H CF3A544 H CH3S H CF3A545 H CH3SO H CF3化合物 R79 R80 R81 R82序号A546 H CF3 H CF3A547 H F2CH H CF3A548 H HCC H CF3A549 H CH3CC H CF3A550 H CH2=CH H CF3A551 H CH2=CHCH2 H CF3A552 H CH3SO2N(CH3) H CF3A553 H (CH3)2N H CF3A554 H (CH3)2NSO2 H CF3A555 H CH3SCH2 H CF3A556 H CH3SOCH2 H CF3A557 H CH3SO2CH2 H CF3A558 H CH3 H CF3CF2A559 H CH3CH2 H CF3CF2A560 H 环丙基 H CF3CF2A561 H (CH3)3C H CF3CF2A562 H (CH3)2CH H CF3CF2A563 H CH3(CH2)2 H CF3CF2A564 H CH3OCH2 H CF3CF2A565 H CH3O(CH2)2 H CF3CF2A566 H Ph H CF3CF2A567 H PhO H CF3CF2A568 H PhS H CF3CF2A569 H PhSO H CF3CF2A570 H PhSO2 H CF3CF2A571 H CH3S H CF3CF2A572 H CH3SO H CF3CF2A573 H CF3 H CF3CF2A574 H F2CH H CF3CF2A575 H HCC H CF3CF2A576 H CH3CC H CF3CF2A577 H CH2=CH H CF3CF2化合物 R79 R80 R81 R82序号A578 H CH2=CHCH2 H CF3CF2A579 H CH3SO2N(CH3) H CF3CF2A580 H (CH3)2N H CF3CF2A581 H (CH3)2NSO2 H CF3CF2A582 H CH3SCH2 H CF3CF2A583 H CH3SOCH2 H CF3CF2A584 H CH3SO2CH2 H CF3CF2A585 H CH3 H CF3CF2CF2A586 H CH3CH2 H CF3CF2CF2A587 H 环丙基 H CF3CF2CF2A588 H (CH3)3C H CF3CF2CF2A589 H (CH3)2CH H CF3CF2CF2A590 H CH3(CH2)2 H CF3CF2CF2A591 H CH3OCH2 H CF3CF2CF2A592 H CH3O(CH2)2 H CF3CF2CF2A593 H Ph H CF3CF2CF2A594 H PhO H CF3CF2CF2A595 H PhS H CF3CF2CF2A596 H PhSO H CF3CF2CF2A597 H PhSO2 H CF3CF2CF2A598 H CH3S H CF3CF2CF2A599 H CH3SO H CF3CF2CF2A600 H CF3 H CF3CF2CF2A601 H F2CH H CF3CF2CF2A602 H HCC H CF3CF2CF2A603 H CH3CC H CF3CF2CF2A604 H CH2=CH H CF3CF2CF2A605 H CH2=CHCH2 H CF3CF2CF2A606 H CH3SO2N(CH3) H CF3CF2CF2A607 H (CH3)2N H CF3CF2CF2A608 H (CH3)2NSO2 H CF3CF2CF2A609 H CH3SCH2 H CF3CF2CF2化合物 R79 R80 R81 R82序号A610 H CH3SOCH2 H CF3CF2CF2A611 H CH3SO2CH2 H CF3CF2CF2A612 H CH3 H CF2ClA613 H CH3CH2 H CF2ClA614 H 环丙基 H CF2ClA615 H (CH3)3C H CF2ClA616 H (CH3)2CH H CF2ClA617 H CH3(CH2)2 H CF2ClA618 H CH3OCH2 H CF2ClA619 H CH3O(CH2)2 H CF2ClA620 H Ph H CF2ClA621 H PhO H CF2ClA622 H PhS H CF2ClA623 H PhSO H CF2ClA624 H PhSO2 H CF2ClA625 H CH3S H CF2ClA626 H CH3SO H CF2ClA627 H CF3 H CF2ClA628 H F2CH H CF2ClA629 H HCC H CF2ClA630 H CH3CC H CF2ClA631 H CH2=CH H CF2ClA632 H CH2=CHCH2 H CF2ClA633 H CH3SO2N(CH3) H CF2ClA634 H (CH3)2N H CF2ClA635 H (CH3)2NSO2 H CF2ClA636 H CH3SCH2 H CF2ClA637 H CH3SOCH2 H CF2ClA638 H CH3SO2CH2 H CF2ClA639 H CH3 H CHF2A640 H CH3CH2 H CHF2A641 H 环丙基 H CHF2化合物 R79 R80 R81 R82序号A642 H (CH3)3C H CHF2A643 H (CH3)2CH H CHF2A644 H CH3(CH2)2 H CHF2A645 H CH3OCH2 H CHF2A646 H CH3O(CH2)2 H CHF2A647 H Ph H CHF2A648 H PhO H CHF2A649 H PhS H CHF2A650 H PhSO H CHF2A651 H PhSO2 H CHF2A652 H CH3S H CHF2A653 H CH3SO H CHF2A654 H CF3 H CHF2A655 H F2CH H CHF2A656 H HCC H CHF2A657 H CH3CC H CHF2A658 H CH2=CH H CHF2A659 H CH2=CHCH2 H CHF2A660 H CH3SO2N(CH3) H CHF2A661 H (CH3)2N H CHF2A662 H (CH3)2NSO2 H CHF2A663 H CH3SCH2 H CHF2A664 H CH3SOCH2 H CHF2A665 H CH3SO2CH2 H CHF2A666 H CH3 H CCl3A667 H CH3CH2 H CCl3A668 H 环丙基 H CCl3A669 H (CH3)3C H CCl3A670 H (CH3)2CH H CCl3A671 H CH3(CH2)2 H CCl3A672 H CH3OCH2 H CCl3A673 H CH3O(CH2)2 H CCl3化合物 R79 R80 R81 R82序号A674 H Ph H CCl3A675 H PhO H CCl3A676 H PhS H CCl3A677 H PhSO H CCl3A678 H PhSO2 H CCl3A679 H CH3S H CCl3A680 H CH3SO H CCl3A681 H CF3 H CCl3A682 H F2CH H CCl3A683 H HCC H CCl3A684 H CH3CC H CCl3A685 H CH2=CH H CCl3A686 H CH2=CHCH2 H CCl3A687 H CH3SO2N(CH3)H CCl3A688 H (CH3)2N H CCl3A689 H (CH3)2NSO2 H CCl3A690 H CH3SCH2 H CCl3A691 H CH3SOCH2 H CCl3A692 H CH3SO2CH2 H CCl3A693 H CH3 CH3 CF3A694 H CH3CH2 CH3 CF3A695 H 环丙基 CH3 CF3A696 H (CH3)3C CH3 CF3A697 H (CH3)2CH CH3 CF3A698 H CH3(CH2)2 CH3 CF3A699 H CH3OCH2 CH3 CF3A700 H CH3O(CH2)2 CH3 CF3A701 H Ph CH3 CF3A702 H PhO CH3 CF3A703 H PhS CH3 CF3A704 H PhSO CH3 CF3A705 H PhSO2 CH3 CF3化合物. R79 R80 R81 R82序号A706 H CH3S CH3 CF3A707 H CH3SO CH3 CF3A708 H CF3 CH3 CF3A709 H F2CH CH3 CF3A710 H HCC CH3 CF3A711 H CH3CC CH3 CF3A712 H CH2=CH CH3 CF3A713 H CH2=CHCH2 CH3 CF3A714 H CH3SO2N(CH3) CH3 CF3A715 H (CH3)2N CH3 CF3A716 H (CH3)2NSO2 CH3 CF3A717 H CH3SCH2 CH3 CF3A718 H CH3SOCH2 CH3 CF3A719 H CH3SO2CH2 CH3 CF3A720 H CH3 CH3 CF3CF2A721 H CH3CH2 CH3 CF3CF2A722 H 环丙基 CH3 CF3CF2A723 H (CH3)3C CH3 CF3CF2A724 H (CH3)2CH CH3 CF3CF2A725 H CH3(CH2)2 CH3 CF3CF2A726 H CH3OCH2 CH3 CF3CF2A727 H CH3O(CH2)2 CH3 CF3CF2A728 H Ph CH3 CF3CF2A729 H PhO CH3 CF3CF2A730 H PhS CH3 CF3CF2A731 H PhSO CH3 CF3CF2A732 H PhSO2 CH3 CF3CF2A733 H CH3S CH3 CF3CF2A734 H CH3SO CH3 CF3CF2A735 H CF3 CH3 CF3CF2A736 H F2CH CH3 CF3CF2A737 H HCC CH3 CF3CF2化合物 R79 R80 R81 R82序号A738 H CH3CC CH3 CF3CF2A739 H CH2=CH CH3 CF3CF2A740 H CH2=CHCH2 CH3 CF3CF2A741 H CH3SO2N(CH3) CH3 CF3CF2A742 H (CH3)2N CH3 CF3CF2A743 H (CH3)2NSO2 CH3 CF3CF2A744 H CH3SCH2 CH3 CF3CF2A745 H CH3SOCH2 CH3 CF3CF2A746 H CH3SO2CH2 CH3 CF3CF2A747 H CH3 CH3 CF3CF2CF2A748 H CH3CH2 CH3 CF3CF2CF2A749 H 环丙基 CH3 CF3CF2CF2A750 H (CH3)3C CH3 CF3CF2CF2A751 H (CH3)2CH CH3 CF3CF2CF2A752 H CH3(CH2)2 CH3 CF3CF2CF2A753 H CH3OCH2 CH3 CF3CF2CF2A754 H CH3O(CH2)2 CH3 CF3CF2CF2A755 H Ph CH3 CF3CF2CF2A756 H PhO CH3 CF3CF2CF2A757 H PhS CH3 CF3CF2CF2A758 H PhSO CH3 CF3CF2CF2A759 H PhSO2 CH3 CF3CF2CF2A760 H CH3S CH3 CF3CF2CF2A761 H CH3SO CH3 CF3CF2CF2A762 H CF3 CH3 CF3CF2CF2A763 H F2CH CH3 CF3CF2CF2A764 H HCC CH3 CF3CF2CF2A765 H CH3CC CH3 CF3CF2CF2A766 H CH2=CH CH3 CF3CF2CF2A767 H CH2=CHCH2 CH3 CF3CF2CF2A768 H CH3SO2N(CH3) CH3 CF3CF2CF2A769 H (CH3)2N CH3 CF3CF2CF2化合物 R79 R80 R81 R82序号A770 H (CH3)2NSO2 CH3 CF3CF2CF2A771 H CH3SCH2 CH3 CF3CF2CF2A772 H CH3SOCH2 CH3 CF3CF2CF2A773 H CH3SO2CH2 CH3 CF3CF2CF2A774 H CH3 CH3 CF2ClA775 H CH3CH2 CH3 CF2ClA776 H 环丙基 CH3 CF2ClA777 H (CH3)3C CH3 CF2ClA778 H (CH3)2CH CH3 CF2ClA779 H CH3(CH2)2 CH3 CF2ClA780 H CH3OCH2 CH3 CF2ClA781 H CH3O(CH2)2 CH3 CF2ClA782 H Ph CH3 CF2ClA783 H PhO CH3 CF2ClA784 H PhS CH3 CF2ClA785 H PhSO CH3 CF2ClA786 H PhSO2 CH3 CF2ClA787 H CH3S CH3 CF2ClA788 H CH3SO CH3 CF2ClA789 H CF3 CH3 CF2ClA790 H F2CH CH3 CF2ClA791 H HCC CH3 CF2ClA792 H CH3CC CH3 CF2ClA793 H CH2=CH CH3 CF2ClA794 H CH2=CHCH2 CH3 CF2ClA795 H CH3SO2N(CH3)CH3 CF2ClA796 H (CH3)2N CH3 CF2ClA797 H (CH3)2NSO2 CH3 CF2ClA798 H CH3SCH2 CH3 CF2ClA799 H CH3SOCH2 CH3 CF2ClA800 H CH3SO2CH2 CH3 CF2ClA801 H CH3 CH3 CHF2化合物 R79 R80 R81 R82序号A802 H CH3CH2 CH3 CHF2A803 H 环丙基 CH3 CHF2A804 H (CH3)3C CH3 CHF2A805 H (CH3)2CH CH3 CHF2A806 H CH3(CH2)2 CH3 CHF2A807 H CH3OCH2 CH3 CHF2A808 H CH3O(CH2)2 CH3 CHF2A809 H Ph CH3 CHF2A810 H PhO CH3 CHF2A811 H PhS CH3 CHF2A812 H PhSO CH3 CHF2A813 H PhSO2 CH3 CHF2A814 H CH3S CH3 CHF2A815 H CH3SO CH3 CHF2A816 H CF3 CH3 CHF2A817 H F2CH CH3 CHF2A818 H HCC CH3 CHF2A819 H CH3CC CH3 CHF2A820 H CH2=CH CH3 CHF2A821 H CH2=CHCH2 CH3 CHF2A822 H CH3SO2N(CH3) CH3 CHF2A823 H (CH3)2N CH3 CHF2A824 H (CH3)2NSO2 CH3 CHF2A825 H CH3SCH2 CH3 CHF2A826 H CH3SOCH2 CH3 CHF2A827 H CH3SO2CH2 CH3 CHF2A828 H CH3 CH3 CCl3A829 H CH3CH2 CH3 CCl3A830 H 环丙基 CH3 CCl3A831 H (CH3)3C CH3 CCl3A832 H (CH3)2CH CH3 CCl3A833 H CH3(CH2)2 CH3 CCl3化合物 R79 R80 R81 R82序号A834 H CH3OCH2 CH3 CCl3A835 H CH3O(CH2)2 CH3 CCl3A836 H Ph CH3 CCl3A837 H PhO CH3 CCl3A838 H PhS CH3 CCl3A839 H PhSO CH3 CCl3A840 H PhSO2 CH3 CCl3A841 H CH3S CH3 CCl3A842 H CH3SO CH3 CCl3A843 H CF3 CH3 CCl3A844 H F2CH CH3 CCl3A845 H HCC CH3 CCl3A846 H CH3CC CH3 CCl3A847 H CH2=CH CH3 CCl3A848 H CH2=CHCH2 CH3 CCl3A849 H CH3SO2N(CH3) CH3 CCl3A850 H (CH3)2N CH3 CCl3A851 H (CH3)2NSO2 CH3 CCl3A852 H CH3SCH2 CH3 CCl3A853 H CH3SOCH2 CH3 CCl3A854 H CH3SO2CH2 CH3 CCl3A855 H CH3 Ph CF3A856 H CH3CH2 Ph CF3A857 H (CH3)2CH Ph CF3A858 H (CH3)2CH Ph CF3A859 H 环丙基 Ph CF3A860 H CH3(CH2)2 Ph CF3A861 H CH3OCH2 Ph CF3A862 H CH3O(CH2)2 Ph CF3A863 H Ph Ph CF3A864 H PhO Ph CF3A865 H PhS Ph CF3化合物 R79 R80 R81 R82序号A866 H PhSO Ph CF3A867 H PhSO2 Ph CF3A868 H CH3S Ph CF3A869 H CH3SO Ph CF3A870 H CF3 Ph CF3A871 H F2CH Ph CF3A872 H HCC Ph CF3A873 H CH3CC Ph CF3A874 H CH2=CH Ph CF3A875 H CH2=CHCH2 Ph CF3A876 H CH3SO2N(CH3)Ph CF3A877 H (CH3)2N Ph CF3A878 H (CH3)2NSO2 Ph CF3A879 H CH3SCH2 Ph CF3A880 H CH3SOCH2 Ph CF3A881 H CH3SO2CH2 Ph CF3A882 H CH3 Ph CF3CF2A883 H CH3CH2 Ph CF3CF2A884 H 环丙基 Ph CF3CF2A885 H (CH3)3C Ph CF3CF2A886 H (CH3)2CH Ph CF3CF2A887 H CH3(CH2)2 Ph CF3CF2A888 H CH3OCH2 Ph CF3CF2A889 H CH3O(CH2)2 Ph CF3CF2A890 H Ph Ph CF3CF2A891 H PhO Ph CF3CF2A892 H PhS Ph CF3CF2A893 H PhSO Ph CF3CF2A894 H PhSO2 Ph CF3CF2A895 H CH3S Ph CF3CF2A896 H CH3SO Ph CF3CF2A897 H CF3 Ph CF3CF2化合物 R79 R80 R81 R82序号A898 H F2CH Ph CF3CF2A899 H HCC Ph CF3CF2A900 H CH3CC Ph CF3CF2A901 H CH2=CH Ph CF3CF2A902 H CH2=CHCH2 Ph CF3CF2A903 H CH3SO2N(CH3) Ph CF3CF2A904 H (CH3)2N Ph CF3CF2A905 H (CH3)2NSO2 Ph CF3CF2A906 H CH3SCH2 Ph CF3CF2A907 H CH3SOCH2 Ph CF3CF2A908 H CH3SO2CH2 Ph CF3CF2A909 H CH3 Ph CF3CF2CF2A910 H CH3CH2 Ph CF3CF2CF2A911 H 环丙基 Ph CF3CF2CF2A912 H (CH3)3C Ph CF3CF2CF2A913 H (CH3)2C Ph CF3CF2CF2A914 H CH3(CH2)2 Ph CF3CF2CF2A915 H CH3OCH2 Ph CF3CF2CF2A916 H CH3O(CH2)2 Ph CF3CF2CF2A917 H Ph Ph CF3CF2CF2A918 H PhO Ph CF3CF2CF2A919 H PhS Ph CF3CF2CF2A920 H PhSO Ph CF3CF2CF2A921 H PhSO2 Ph CF3CF2CF2A922 H CH3S Ph CF3CF2CF2A923 H CH3SO Ph CF3CF2CF2A924 H CF3 Ph CF3CF2CF2A925 H F2CH Ph CF3CF2CF2A926 H HCC Ph CF3CF2CF2A927 H CH3CC Ph CF3CF2CF2A928 H CH2=CH Ph CF3CF2CF2A929 H CH2=CHCH2 Ph CF3CF2CF2化合物 R79 R80 R81 R82序号A930 H CH3SO2N(CH3) Ph CF3CF2CF2A931 H (CH3)2N Ph CF3CF2CF2A932 H (CH3)2NSO2 Ph CF3CF2CF2A933 H CH3SCH2 Ph CF3CF2CF2A934 H CH3SOCH2 Ph CF3CF2CF2A935 H CH3SO2CH2 Ph CF3CF2CF2A936 H CH3 Ph CF2ClA937 H CH3CH2 Ph CF2ClA938 H 环丙基 Ph CF2ClA939 H (CH3)3C Ph CF2ClA940 H (CH3)2CH Ph CF2ClA941 H CH3(CH2)2 Ph CF2ClA942 H CH3OCH2 Ph CF2ClA943 H CH3O(CH2)2 Ph CF2ClA944 H Ph Ph CF2ClA945 H PhO Ph CF2ClA946 H PhS Ph CF2ClA947 H PhSO Ph CF2ClA948 H PhSO2 Ph CF2ClA949 H CH3S Ph CF2ClA950 H CH3SO Ph CF2ClA951 H CF3 Ph CF2ClA952 H F2CH Ph CF2ClA953 H HCC Ph CF2ClA954 H CH3CC Ph CF2ClA955 H CH2=CH Ph CF2ClA956 H CH2=CHCH2 Ph CF2ClA957 H CH3SO2N(CH3) Ph CF2ClA958 H (CH3)2N Ph CF2ClA959 H (CH3)2NSO2 Ph CF2ClA960 H CH3SCH2 Ph CF2ClA961 H CH3SOCH2 Ph CF2Cl化合物 R79 R80 R81 R82序号A962 H CH3SO2CH2 Ph CF2ClA963 H CH3 Ph CHF2A964 H CH3CH2 Ph CHF2A965 H (CH3)3C Ph CHF2A966 H (CH3)2CH Ph CHF2A967 H 环丙基 Ph CHF2A968 H CH3(CH2)2 Ph CHF2A969 H CH3OCH2 Ph CHF2A970 H CH3O(CH2)2 Ph CHF2A971 H Ph Ph CHF2A972 H PhO Ph CHF2A973 H PhS Ph CHF2A974 H PhSO Ph CHF2A975 H PhSO2 Ph CHF2A976 H CH3S Ph CHF2A977 H CH3SO Ph CHF2A978 H CF3 Ph CHF2A979 H F2CH Ph CHF2A980 H HCC Ph CHF2A981 H CH3CC Ph CHF2A982 H CH2=CH Ph CHF2A983 H CH2=CHCH2 Ph CHF2A984 H CH3SO2N(CH3) Ph CHF2A985 H (CH3)2N Ph CHF2A986 H (CH3)2NSO2 Ph CHF2A987 H CH3SCH2 Ph CHF2A988 H CH3SOCH2 Ph CHF2A989 H CH3SO2CH2 Ph CHF2A990 H CH3 Ph CCl3A991 H CH3CH2 Ph CCl3A992 H (CH3)3C Ph CCl3A993 H (CH3)2CH Ph CCl3化合物 R79 R80 R81 R82序号A994 H 环丙基 Ph CCl3A995 H CH3(CH2)2 Ph CCl3A996 H CH3OCH2 Ph CCl3A997 H CH3O(CH2)2 Ph CCl3A998 H Ph Ph CCl3A999 H PhO Ph CCl3A1000 H PhS Ph CCl3A1001 H PhSO Ph CCl3A1002 H PhSO2 Ph CCl3A1003 H CH3S Ph CCl3A1004 H CH3SO Ph CCl3A1005 H CF3 Ph CCl3A1006 H F2CH Ph CCl3A1007 H HCC Ph CCl3A1008 H CH3CC Ph CCl3A1009 H CH2=CH Ph CCl3A1010 H CH2=CHCH2 Ph CCl3A1011 H CH3SO2N(CH3) Ph CCl3A1012 H (CH3)2N Ph CCl3A1013 H (CH3)2NSO2 Ph CCl3A1014 H CH3SCH2 Ph CCl3A1015 H CH3SOCH2 Ph CCl3A1016 H CH3SO2CH2 Ph CCl3A1017 F H H CF3A1018 Cl H H CF3A1019 Br H H CF3A1020 CN H H CF3A1021 CH3SO2O H H CF3A1022 CH3O H H CF3A1023 CH2CH3O H H CF3A1024 CH2CH=CH2O H H CF3A1025 HCCCH2O H H CF3化合物 R79 R80 R81 R82序号A1026 S-苄基 H H CF3A1027 SO2-苄基 H H CF3A1028 ClCH2 H H CF3A1029 BrCH2 H H CF3A1030 FCH2 H H CF3A1031 CHF2CH2 H H CF3A1032 CF3CH2 H H CF3A1033 三唑基甲基 H H CF3A1034 CHCl2CH2 H H CF3A1035 ClCH=CH H H CF3A1036 Cl2C=CH H H CF3A1037 CF3CH=CH H H CF3A1038 ClCC H H CF3A1039 Ph H H CF3A1040 CH3 CH3 H CF3A1041 CH3 OH H CF3A1042 CH3 F H CF3A1043 CH3 Cl H CF3A1044 F CH3 H CF3A1045 Cl CH3 H CF3A1046 H F H CF3A1047 H Cl H CF3A1048 H Br H CF3A1049 H OH H CF3A1050 H OCH3 H CF3A1051 H OCHF2 H CF3A1052 H OSO2CH3 H CF3A1053 H OSO2CF3 H CF3A1054 H ClCH2 H CF3A1055 H BrCH2 H CF3A1056 H FCH2 H CF3A1057 H CHF2CH2 H CF3化合物 R79 R80 R81 R82序号A1058 H CF3CH2 H CF3A1059 H 三唑基甲基 H CF3A1060 H CHCl2CH2 H CF3A1061 H ClCH=CH H CF3A1062 H Cl2C=CH H CF3A1063 H CF3CH=CH H CF3A1064 H ClCC H CF3A1065 H CH3C(O) H CF3A1066 H 苯基 H CF3A1067 H SO2CH3 H CF3A1068 H SO2CF3 H CF3A1069 H CN H CF3A1070 H NO2 H CF3A1071 CH3 H F CF3A1072 CH3 H Cl CF3A1073 CH3 H Br CF3A1074 CH3 H CN CF3A1075 CH3 H CH3O CF3A1076 CH3 H CH3S CF3A1077 CH3 H CH3SO CF3A1078 CH3 H CH3SO2 CF3在下表6中,Q是Q3 且Q3代表下列基团B:表6:基团B:基团 R44 R37 R38 R39 R40 WB1 H H H H OH CH2B2 CH3 H H H OH CH2B3 CH3CH2 H H H OH CH2B4 CH3CH2CH2 H H H OH CH2B5 (CH3)2CH H H H OH CH2B6 (CH3)3C H H H OH CH2B7 CH3S H H H OH CH2B8 CH3SO H H H OH CH2B9 CH3SO2 H H H OH CH2B10 Ph H H H OH CH2B11 CH3O H H H OH CH2B12 CH3CO2 H H H OH CH2B13 CH3CH2CO2 H H H OH CH2B14 CH2=CHCH2 H H H OH CH2B15 HCCCH2 H H H OH CH2B16 CF3 H H H OH CH2B17 (CH3)2NSO2 H H H OH CH2B18 (CH3)2N H H H OH CH2B19 PhO H H H OH CH2B20 PhS H H H OH CH2B21 PhSO H H H OH CH2B22 PhSO2 H H H OH CH2B23 CN H H H OH CH2B24 CH3 CH3 H H OH CH2B25 CH3CH2 CH3 H H OH CH2B26 CH3CH2CH2 CH3 H H OH CH2B27 (CH3)2CH CH3 H H OH CH2B28 (CH3)3C CH3 H H OH CH2B29 CH3S CH3 H H OH CH2B30 CH3SO CH3 H H OH CH2B31 CH3SO2 CH3 H H OH CH2B32 Ph CH3 H H OH CH2基团 R44 R37 R38 R39 R40 WB33 CH3O CH3 H H OH CH2B34 CH3CO2 CH3 H H OH CH2B35 CH3CH2CO2 CH3 H H OH CH2B36 CH2=CHCH2 CH3 H H OH CH2B37 HCCCH2 CH3 H H OH CH2B38 CF3 CH3 H H OH CH2B39 (CH3)2NSO2 CH3 H H OH CH2B40 (CH3)2N CH3 H H OH CH2B41 PhO CH3 H H OH CH2B42 PhS CH3 H H OH CH2B43 PhSO CH3 H H OH CH2B44 PhSO2 CH3 H H OH CH2B45 CN CH3 H H OH CH2B46 CH3 H CH3 H OH CH2B47 CH3CH2 H CH3 H OH CH2B48 CH3CH2CH2 H CH3 H OH CH2B49 (CH3)2CH H CH3 H OH CH2B50 (CH3)3C H CH3 H OH CH2B51 CH3S H CH3 H OH CH2B52 CH3SO H CH3 H OH CH2B53 CH3SO2 H CH3 H OH CH2B54 Ph H CH3 H OH CH2B55 CH3O H CH3 H OH CH2B56 CH3CO2 H CH3 H OH CH2B57 CH3CH2CO2 H CH3 H OH CH2B58 CH2=CHCH2 H CH3 H OH CH2B59 HCCCH2 H CH3 H OH CH2B60 CF3 H CH3 H OH CH2B61 (CH3)2NSO2 H CH3 H OH CH2B62 (CH3)2N H CH3 H OH CH2B63 PhO H CH3 H OH CH2B64 PhS H CH3 H OH CH2B65 PhSO H CH3 H OH CH2基团 R44 R37 R38 R39 R40 WB66 PhSO2 H CH3 H OH CH2B67 CN H CH3 H OH CH2B68 CH3 CH3 CH3 H OH CH2B69 CH3CH2 CH3 CH3 H OH CH2B70 CH3CH2CH2 CH3 CH3 H OH CH2B71 (CH3)2CH CH3 CH3 H OH CH2B72 (CH3)3C CH3 CH3 H OH CH2B73 CH3S CH3 CH3 H OH CH2B74 CH3SO CH3 CH3 H OH CH2B75 CH3SO2 CH3 CH3 H OH CH2B76 Ph CH3 CH3 H OH CH2B77 CH3O CH3 CH3 H OH CH2B78 CH3CO2 CH3 CH3 H OH CH2B79 CH3CH2CO2 CH3 CH3 H OH CH2B80 CH2=CHCH2 CH3 CH3 H OH CH2B81 HCCCH2 CH3 CH3 H OH CH2B82 CF3 CH3 CH3 H OH CH2B83 (CH3)2NSO2 CH3 CH3 H OH CH2B84 (CH3)2N CH3 CH3 H OH CH2B85 PhO CH3 CH3 H OH CH2B86 PhS CH3 CH3 H OH CH2B87 PhSO CH3 CH3 H OH CH2B88 PhSO2 CH3 CH3 H OH CH2B89 CN CH3 CH3 H OH CH2B90 CH3 CH3 CH3 CH3 OH CH2B91 CH3CH2 CH3 CH3 CH3 OH CH2B92 CH3CH2CH2 CH3 CH3 CH3 OH CH2B93 (CH3)2CH CH3 CH3 CH3 OH CH2B94 (CH3)3C CH3 CH3 CH3 OH CH2B95 CH3S CH3 CH3 CH3 OH CH2B96 CH3SO CH3 CH3 CH3 OH CH2B97 CH3SO2 CH3 CH3 CH3 OH CH2B98 Ph CH3 CH3 CH3 OH CH2基团 R44 R37 R38 R39 R40 WB99 CH3O CH3 CH3 CH3 OH CH2B100 CH3CO2 CH3 CH3 CH3 OH CH2B101 CH3CH2CO2 CH3 CH3 CH3 OH CH2B102 CH2=CHCH2 CH3 CH3 CH3 OH CH2B103 HCCCH2 CH3 CH3 CH3 OH CH2B104 CF3 CH3 CH3 CH3 OH CH2B105 (CH3)2NSO2 CH3 CH3 CH3 OH CH2B106 (CH3)2N CH3 CH3 CH3 OH CH2B107 PhO CH3 CH3 CH3 OH CH2B108 PhS CH3 CH3 CH3 OH CH2B109 PhSO CH3 CH3 CH3 OH CH2B110 PhSO2 CH3 CH3 CH3 OH CH2B111 CN CH3 CH3 CH3 OH CH2B112 CH3CH2 CH3CH2 H H OH CH2B113 CH3CH2CH2 CH3CH2 H H OH CH2B114 (CH3)2CH CH3CH2 H H OH CH2B115 (CH3)3C CH3CH2 H H OH CH2B116 CH3S CH3CH2 H H OH CH2B117 CH3SO CH3CH2 H H OH CH2B118 CH3SO2 CH3CH2 H H OH CH2B119 Ph CH3CH2 H H OH CH2B120 CH3O CH3CH2 H H OH CH2B121 CH3CO2 CH3CH2 H H OH CH2B122 CH3CH2CO2 CH3CH2 H H OH CH2B123 CH2=CHCH2 CH3CH2 H H OH CH2B124 HCCCH2 CH3CH2 H H OH CH2B125 CF3 CH3CH2 H H OH CH2B126 (CH3)2NSO2 CH3CH2 H H OH CH2B127 (CH3)2N CH3CH2 H H OH CH2B128 PhO CH3CH2 H H OH CH2B129 PhS CH3CH2 H H OH CH2B130 PhSO CH3CH2 H H OH CH2B131 PhSO2 CH3CH2 H H OH CH2基团 R44 R37 R38 R39 R40 WB132 CN CH3CH2 H H OH CH2B133 H H H H OH CHCH3B134 CH3 H H H OH CHCH3B135 CH3CH2 H H H OH CHCH3B136 CH3CH2CH2 H H H OH CHCH3B137 (CH3)2CH H H H OH CHCH3B138 (CH3)3C H H H OH CHCH3B139 CH3S H H H OH CHCH3B140 CH3SO H H H OH CHCH3B141 CH3SO2 H H H OH CHCH3B142 Ph H H H OH CHCH3B143 CH3O H H H OH CHCH3B144 CH3CO2 H H H OH CHCH3B145 CH3CH2CO2 H H H OH CHCH3B146 CH2=CHCH2 H H H OH CHCH3B147 HCCCH2 H H H OH CHCH3B148 CF3 H H H OH CHCH3B149 (CH3)2NSO2 H H H OH CHCH3B150 (CH3)2N H H H OH CHCH3B151 PhO H H H OH CHCH3B152 PhS H H H OH CHCH3B153 PhSO H H H OH CHCH3B154 PhSO2 H H H OH CHCH3B155 CN H H H OH CHCH3B156 CH3 CH3 H H OH CHCH3B157 CH3CH2 CH3 H H OH CHCH3B158 CH3CH2CH2 CH3 H H OH CHCH3B159 (CH3)2CH CH3 H H OH CHCH3B160 (CH3)3C CH3 H H OH CHCH3B161 CH3S CH3 H H OH CHCH3B162 CH3SO CH3 H H OH CHCH3B163 CH3SO2 CH3 H H OH CHCH3B164 Ph CH3 H H OH CHCH3基团 R44 R37 R38 R39 R40 WB165 CH3O CH3 H H OH CHCH3B166 CH3CO2 CH3 H H OH CHCH3B167 CH3CH2CO2 CH3 H H OH CHCH3B168 CH2=CHCH2 CH3 H H OH CHCH3B169 HCCCH2 CH3 H H OH CHCH3B170 CF3 CH3 H H OH CHCH3B171 (CH3)2NSO2 CH3 H H OH CHCH3B172 (CH3)2N CH3 H H OH CHCH3B173 PhO CH3 H H OH CHCH3B174 PhS CH3 H H OH CHCH3B175 PhSO CH3 H H OH CHCH3B176 PhSO2 CH3 H H OH CHCH3B177 CN CH3 H H OH CHCH3B178 CH3 H CH3 H OH CHCH3B179 CH3CH2 H CH3 H OH CHCH3B180 CH3CH2CH2 H CH3 H OH CHCH3B181 (CH3)2CH H CH3 H OH CHCH3B182 (CH3)3C H CH3 H OH CHCH3B183 CH3S H CH3 H OH CHCH3B184 CH3SO H CH3 H OH CHCH3B185 CH3SO2 H CH3 H OH CHCH3B186 Ph H CH3 H OH CHCH3B187 CH3O H CH3 H OH CHCH3B188 CH3CO2 H CH3 H OH CHCH3B189 CH3CH2CO2 H CH3 H OH CHCH3B190 CH2=CHCH2 H CH3 H OH CHCH3B191 HCCCH2 H CH3 H OH CHCH3B192 CF3 H CH3 H OH CHCH3B193 (CH3)2NSO2 H CH3 H OH CHCH3B194 (CH3)2N H CH3 H OH CHCH3B195 PhO H CH3 H OH CHCH3B196 PhS H CH3 H OH CHCH3B197 PhSO H CH3 H OH CHCH3基团 R44 R37 R38 R39 R40 WB198 PhSO2 H CH3 H OH CHCH3B199 CN H CH3 H OH CHCH3B200 CH3 CH3 CH3 H OH CHCH3B201 CH3CH2 CH3 CH3 H OH CHCH3B202 CH3CH2CH2 CH3 CH3 H OH CHCH3B203 (CH3)2CH CH3 CH3 H OH CHCH3B204 (CH3)3C CH3 CH3 H OH CHCH3B205 CH3S CH3 CH3 H OH CHCH3B206 CH3SO CH3 CH3 H OH CHCH3B207 CH3SO2 CH3 CH3 H OH CHCH3B208 Ph CH3 CH3 H OH CHCH3B209 CH3O CH3 CH3 H OH CHCH3B210 CH3CO2 CH3 CH3 H OH CHCH3B211 CH3CH2CO2 CH3 CH3 H OH CHCH3B212 CH2=CHCH2 CH3 CH3 H OH CHCH3B213 HCCCH2 CH3 CH3 H OH CHCH3B214 CF3 CH3 CH3 H OH CHCH3B215 (CH3)2NSO2 CH3 CH3 H OH CHCH3B216 (CH3)2N CH3 CH3 H OH CHCH3B217 PhO CH3 CH3 H OH CHCH3B218 PhS CH3 CH3 H OH CHCH3B219 PhSO CH3 CH3 H OH CHCH3B220 PhSO2 CH3 CH3 H OH CHCH3B221 CN CH3 CH3 H OH CHCH3B222 CH3 CH3 CH3 CH3 OH CHCH3B223 CH3CH2 CH3 CH3 CH3 OH CHCH3B224 CH3CH2CH2 CH3 CH3 CH3 OH CHCH3B225 (CH3)2CH CH3 CH3 CH3 OH CHCH3B226 (CH3)3C CH3 CH3 CH3 OH CHCH3B227 CH3S CH3 CH3 CH3 OH CHCH3B228 CH3SO CH3 CH3 CH3 OH CHCH3B229 CH3SO2 CH3 CH3 CH3 OH CHCH3B230 Ph CH3 CH3 CH3 OH CHCH3基团 R44 R37 R38 R39 R40 WB231 CH3O CH3 CH3 CH3 OH CHCH3B232 CH3CO2 CH3 CH3 CH3 OH CHCH3B233 CH3CH2CO2 CH3 CH3 CH3 OH CHCH3B234 CH2=CHCH2 CH3 CH3 CH3 OH CHCH3B235 HCCCH2 CH3 CH3 CH3 OH CHCH3B236 CF3 CH3 CH3 CH3 OH CHCH3B237 (CH3)2NSO2 CH3 CH3 CH3 OH CHCH3B238 (CH3)2N CH3 CH3 CH3 OH CHCH3B239 PhO CH3 CH3 CH3 OH CHCH3B240 PhS CH3 CH3 CH3 OH CHCH3B241 PhSO CH3 CH3 CH3 OH CHCH3B242 PhSO2 CH3 CH3 CH3 OH CHCH3B243 CN CH3 CH3 CH3 OH CHCH3B244 CH3CH2 CH3CH2 H H OH CHCH3B245 CH3CH2CH2 CH3CH2 H H OH CHCH3B246 (CH3)2CH CH3CH2 H H OH CHCH3B247 (CH3)3C CH3CH2 H H OH CHCH3B248 CH3S CH3CH2 H H OH CHCH3B249 CH3SO CH3CH2 H H OH CHCH3B250 CH3SO2 CH3CH2 H H OH CHCH3B251 Ph CH3CH2 H H OH CHCH3B252 CH3O CH3CH2 H H OH CHCH3B253 CH3CO2 CH3CH2 H H OH CHCH3B254 CH3CH2CO2 CH3CH2 H H OH CHCH3B255 CH2=CHCH2 CH3CH2 H H OH CHCH3B256 HCCCH2 CH3CH2 H H OH CHCH3B257 CF3 CH3CH2 H H OH CHCH3B258 (CH3)2NSO2 CH3CH2 H H OH CHCH3B259 (CH3)2N CH3CH2 H H OH CHCH3B260 PhO CH3CH2 H H OH CHCH3B261 PhS CH3CH2 H H OH CHCH3B262 PhSO CH3CH2 H H OH CHCH3B263 PhSO2 CH3CH2 H H OH CHCH3基团 R44 R37 R38 R39 R40 WB264 CN CH3CH2 H H OH CHCH3B265 H H H H OH C=OB266 CH3 H H H OH C=OB267 CH3CH2 H H H OH C=OB268 CH3CH2CH2 H H H OH C=OB269 (CH3)2CH H H H OH C=OB270 (CH3)3C H H H OH C=OB271 CH3S H H H OH C=OB272 CH3SO H H H OH C=OB273 CH3SO2 H H H OH C=OB274 Ph H H H OH C=OB275 CH3O H H H OH C=OB276 CH3CO2 H H H OH C=OB277 CH3CH2CO2 H H H OH C=OB278 CH2=CHCH2 H H H OH C=OB279 HCCCH2 H H H OH C=OB280 CF3 H H H OH C=OB281 (CH3)2NSO2 H H H OH C=OB282 (CH3)2N H H H OH C=OB283 PhO H H H OH C=OB284 PhS H H H OH C=OB285 PhSO H H H OH C=OB286 PhSO2 H H H OH C=OB287 CN H H H OH C=OB288 CH3 CH3 H H OH C=OB289 CH3CH2 CH3 H H OH C=OB290 CH3CH2CH2 CH3 H H OH C=OB291 (CH3)2CH CH3 H H OH C=OB292 (CH3)3C CH3 H H OH C=OB293 CH3S CH3 H H OH C=OB294 CH3SO CH3 H H OH C=OB295 CH3SO2 CH3 H H OH C=OB296 Ph CH3 H H OH C=O基团 R44 R37 R38 R39 R40 WB297 CH3O CH3 H H OH C=OB298 CH3CO2 CH3 H H OH C=OB299 CH3CH2CO2 CH3 H H OH C=OB300 CH2=CHCH2 CH3 H H OH C=OB301 HCCCH2 CH3 H H OH C=OB302 CF3 CH3 H H OH C=OB303 (CH3)2NSO2 CH3 H H OH C=OB304 (CH3)2N CH3 H H OH C=OB305 PhO CH3 H H OH C=OB306 PhS CH3 H H OH C=OB307 PhSO CH3 H H OH C=OB308 PhSO2 CH3 H H OH C=OB309 CN CH3 H H OH C=OB310 CH3 H CH3 H OH C=OB311 CH3CH2 H CH3 H OH C=OB312 CH3CH2CH2 H CH3 H OH C=OB313 (CH3)2CH H CH3 H OH C=OB314 (CH3)3C H CH3 H OH C=OB315 CH3S H CH3 H OH C=OB316 CH3SO H CH3 H OH C=OB317 CH3SO2 H CH3 H OH C=OB318 Ph H CH3 H OH C=OB319 CH3O H CH3 H OH C=OB320 CH3CO2 H CH3 H OH C=OB321 CH3CH2CO2 H CH3 H OH C=OB322 CH2=CHCH2 H CH3 H OH C=OB323 HCCCH2 H CH3 H OH C=OB324 CF3 H CH3 H OH C=OB325 (CH3)2NSO2 H CH3 H OH C=OB326 (CH3)2N H CH3 H OH C=OB327 PhO H CH3 H OH C=OB328 PhS H CH3 H OH C=OB329 PhSO H CH3 H OH C=O基团 R44 R37 R38 R39 R40 WB330 PhSO2 H CH3 H OH C=OB331 CN H CH3 H OH C=OB332 CH3 CH3 CH3 H OH C=OB333 CH3CH2 CH3 CH3 H OH C=OB334 CH3CH2CH2 CH3 CH3 H OH C=OB335 (CH3)2CH CH3 CH3 H OH C=OB336 (CH3)3C CH3 CH3 H OH C=OB337 CH3S CH3 CH3 H OH C=OB338 CH3SO CH3 CH3 H OH C=OB339 CH3SO2 CH3 CH3 H OH C=OB340 Ph CH3 CH3 H OH C=OB341 CH3O CH3 CH3 H OH C=OB342 CH3CO2 CH3 CH3 H OH C=OB343 CH3CH2CO2 CH3 CH3 H OH C=OB344 CH2=CHCH2 CH3 CH3 H OH C=OB345 HCCCH2 CH3 CH3 H OH C=OB346 CF3 CH3 CH3 H OH C=OB347 (CH3)2NSO2 CH3 CH3 H OH C=OB348 (CH3)2N CH3 CH3 H OH C=OB349 PhO CH3 CH3 H OH C=OB350 PhS CH3 CH3 H OH C=OB351 PhSO CH3 CH3 H OH C=OB352 PhSO2 CH3 CH3 H OH C=OB353 CN CH3 CH3 H OH C=OB354 CH3 CH3 CH3 CH3 OH C=OB355 CH3CH2 CH3 CH3 CH3 OH C=OB356 CH3CH2CH2 CH3 CH3 CH3 OH C=OB357 (CH3)2CH CH3 CH3 CH3 OH C=OB358 (CH3)3C CH3 CH3 CH3 OH C=OB359 CH3S CH3 CH3 CH3 OH C=OB360 CH3SO CH3 CH3 CH3 OH C=OB361 CH3SO2 CH3 CH3 CH3 OH C=OB362 Ph CH3 CH3 CH3 OH C=O基团 R44 R37 R38 R39 R40 WB363 CH3O CH3 CH3 CH3 OH C=OB364 CH3CO2 CH3 CH3 CH3 OH C=OB365 CH3CH2CO2 CH3 CH3 CH3 OH C=OB366 CH2=CHCH2 CH3 CH3 CH3 OH C=OB367 HCCCH2 CH3 CH3 CH3 OH C=OB368 CF3 CH3 CH3 CH3 OH C=OB369 (CH3)2NSO2 CH3 CH3 CH3 OH C=OB370 (CH3)2N CH3 CH3 CH3 OH C=OB371 PhO CH3 CH3 CH3 OH C=OB372 PhS CH3 CH3 CH3 OH C=OB373 PhSO CH3 CH3 CH3 OH C=OB374 PhSO2 CH3 CH3 CH3 OH C=OB375 CN CH3 CH3 CH3 OH C=OB376 CH3CH2 CH3CH2 H H OH C=OB377 CH3CH2CH2 CH3CH2 H H OH C=OB378 (CH3)2CH CH3CH2 H H OH C=OB379 (CH3)3C CH3CH2 H H OH C=OB380 CH3S CH3CH2 H H OH C=OB381 CH3SO CH3CH2 H H OH C=OB382 CH3SO2 CH3CH2 H H OH C=OB383 Ph CH3CH2 H H OH C=OB384 CH3O CH3CH2 H H OH C=OB385 CH3CO2 CH3CH2 H H OH C=OB386 CH3CH2CO2 CH3CH2 H H OH C=OB387 CH2=CHCH2 CH3CH2 H H OH C=OB388 HCCCH2 CH3CH2 H H OH C=OB389 CF3 CH3CH2 H H OH C=OB390 (CH3)2NSO2 CH3CH2 H H OH C=OB391 (CH3)2N CH3CH2 H H OH C=OB392 PhO CH3CH2 H H OH C=OB393 PhS CH3CH2 H H OH C=OB394 PhSO CH3CH2 H H OH C=OB395 PhSO2 CH3CH2 H H OH C=O基团 R44 R37 R38 R39 R40 WB396 CN CH3CH2 H H OH C=OB397 H H H H OH N-CH3B398 CH3 H H H OH N-CH3B399 CH3CH2 H H H OH N-CH3B400 CH3CH2CH2 H H H OH N-CH3B401 (CH3)2CH H H H OH N-CH3B402 (CH3)3C H H H OH N-CH3B403 CH3S H H H OH N-CH3B404 CH3SO H H H OH N-CH3B405 CH3SO2 H H H OH N-CH3B406 Ph H H H OH N-CH3B407 CH3O H H H OH N-CH3B408 CH3CO2 H H H OH N-CH3B409 CH3CH2CO2 H H H OH N-CH3B410 CH2=CHCH2 H H H OH N-CH3B411 HCCCH2 H H H OH N-CH3B412 CF3 H H H OH N-CH3B413 (CH3)2NSO2 H H H OH N-CH3B414 (CH3)2N H H H OH N-CH3B415 PhO H H H OH N-CH3B416 PhS H H H OH N-CH3B417 PhSO H H H OH N-CH3B418 PhSO2 H H H OH N-CH3B419 CN H H H OH N-CH3B420 CH3 CH3 H H OH N-CH3B421 CH3CH2 CH3 H H OH N-CH3B422 CH3CH2CH2 CH3 H H OH N-CH3B423 (CH3)2CH CH3 H H OH N-CH3B424 (CH3)3C CH3 H H OH N-CH3B425 CH3S CH3 H H OH N-CH3B426 CH3SO CH3 H H OH N-CH3B427 CH3SO2 CH3 H H OH N-CH3B428 Ph CH3 H H OH N-CH3基团 R44 R37 R38 R39 R40 WB429 CH3O CH3 H H OH N-CH3B430 CH3CO2 CH3 H H OH N-CH3B431 CH3CH2CO2 CH3 H H OH N-CH3B432 CH2=CHCH2 CH3 H H OH N-CH3B433 HCCCH2 CH3 H H OH N-CH3B434 CF3 CH3 H H OH N-CH3B435 (CH3)2NSO2 CH3 H H OH N-CH3B436 (CH3)2N CH3 H H OH N-CH3B437 PhO CH3 H H OH N-CH3B438 PhS CH3 H H OH N-CH3B439 PhSO CH3 H H OH N-CH3B440 PhSO2 CH3 H H OH N-CH3B441 CN CH3 H H OH N-CH3B442 CH3 H CH3 H OH N-CH3B443 CH3CH2 H CH3 H OH N-CH3B444 CH3CH2CH2 H CH3 H OH N-CH3B445 (CH3)2CH H CH3 H OH N-CH3B446 (CH3)3C H CH3 H OH N-CH3B447 CH3S H CH3 H OH N-CH3B448 CH3SO H CH3 H OH N-CH3B449 CH3SO2 H CH3 H OH N-CH3B450 Ph H CH3 H OH N-CH3B451 CH3O H CH3 H OH N-CH3B452 CH3CO2 H CH3 H OH N-CH3B453 CH3CH2CO2 H CH3 H OH N-CH3B454 CH2=CHCH2 H CH3 H OH N-CH3B455 HCCCH2 H CH3 H OH N-CH3B456 CF3 H CH3 H OH N-CH3B457 (CH3)2NSO2 H CH3 H OH N-CH3B458 (CH3)2N H CH3 H OH N-CH3B459 PhO H CH3 H OH N-CH3B460 PhS H CH3 H OH N-CH3B461 PhSO H CH3 H OH N-CH3基团 R44 R37 R38 R39 R40 WB462 PhSO2 H CH3 H OH N-CH3B463 CN H CH3 H OH N-CH3B464 CH3 CH3 CH3 H OH N-CH3B465 CH3CH2 CH3 CH3 H OH N-CH3B466 CH3CH2CH2 CH3 CH3 H OH N-CH3B467 (CH3)2CH CH3 CH3 H OH N-CH3B468 (CH3)3C CH3 CH3 H OH N-CH3B469 CH3S CH3 CH3 H OH N-CH3B470 CH3SO CH3 CH3 H OH N-CH3B471 CH3SO2 CH3 CH3 H OH N-CH3B472 Ph CH3 CH3 H OH N-CH3B473 CH3O CH3 CH3 H OH N-CH3B474 CH3CO2 CH3 CH3 H OH N-CH3B475 CH3CH2CO2 CH3 CH3 H OH N-CH3B476 CH2=CHCH2 CH3 CH3 H OH N-CH3B477 HCCCH2 CH3 CH3 H OH N-CH3B478 CF3 CH3 CH3 H OH N-CH3B479 (CH3)2NSO2 CH3 CH3 H OH N-CH3B480 (CH3)2N CH3 CH3 H OH N-CH3B481 PhO CH3 CH3 H OH N-CH3B482 PhS CH3 CH3 H OH N-CH3B483 PhSO CH3 CH3 H OH N-CH3B484 PhSO2 CH3 CH3 H OH N-CH3B485 CN CH3 CH3 H OH N-CH3B486 CH3 CH3 CH3 CH3 OH N-CH3B487 CH3CH2 CH3 CH3 CH3 OH N-CH3B488 CH3CH2CH2 CH3 CH3 CH3 OH N-CH3B489 (CH3)2CH CH3 CH3 CH3 OH N-CH3B490 (CH3)3C CH3 CH3 CH3 OH N-CH3B491 CH3S CH3 CH3 CH3 OH N-CH3B492 CH3SO CH3 CH3 CH3 OH N-CH3B493 CH3SO2 CH3 CH3 CH3 OH N-CH3B494 Ph CH3 CH3 CH3 OH N-CH3基团 R44 R37 R38 R39 R40 WB495 CH3O CH3 CH3 CH3 OH N-CH3B496 CH3CO2 CH3 CH3 CH3 OH N-CH3B497 CH3CH2CO2 CH3 CH3 CH3 OH N-CH3B498 CH2=CHCH2 CH3 CH3 CH3 OH N-CH3B499 HCCCH2 CH3 CH3 CH3 OH N-CH3B500 CF3 CH3 CH3 CH3 OH N-CH3B501 (CH3)2NSO2 CH3 CH3 CH3 OH N-CH3B502 (CH3)2N CH3 CH3 CH3 OH N-CH3B503 PhO CH3 CH3 CH3 OH N-CH3B504 PhS CH3 CH3 CH3 OH N-CH3B505 PhSO CH3 CH3 CH3 OH N-CH3B506 PhSO2 CH3 CH3 CH3 OH N-CH3B507 CN CH3 CH3 CH3 OH N-CH3B508 CH3CH2 CH3CH2 H H OH N-CH3B509 CH3CH2CH2 CH3CH2 H H OH N-CH3B510 (CH3)2CH CH3CH2 H H OH N-CH3B511 (CH3)3C CH3CH2 H H OH N-CH3B512 CH3S CH3CH2 H H OH N-CH3B513 CH3SO CH3CH2 H H OH N-CH3B514 CH3SO2 CH3CH2 H H OH N-CH3B515 Ph CH3CH2 H H OH N-CH3B516 CH3O CH3CH2 H H OH N-CH3B517 CH3CO2 CH3CH2 H H OH N-CH3B518 CH3CH2CO2 CH3CH2 H H OH N-CH3B519 CH2=CHCH2 CH3CH2 H H OH N-CH3B520 HCCCH2 CH3CH2 H H OH N-CH3B521 CF3 CH3CH2 H H OH N-CH3B522 (CH3)2NSO2 CH3CH2 H H OH N-CH3B523 (CH3)2N CH3CH2 H H OH N-CH3B524 PhO CH3CH2 H H OH N-CH3B525 PhS CH3CH2 H H OH N-CH3B526 PhSO CH3CH2 H H OH N-CH3B527 PhSO2 CH3CH2 H H OH N-CH3基团 R44 R37 R38 R39 R40 WB528 CN CH3CH2 H H OH N-CH3B529 H H H H OH OB530 CH3 H H H OH OB531 CH3CH2 H H H OH OB532 CH3CH2CH2 H H H OH OB533 (CH3)2CH H H H OH OB534 (CH3)3C H H H OH OB535 CH3S H H H OH OB536 CH3SO H H H OH OB537 CH3SO2 H H H OH OB538 Ph H H H OH OB539 CH3O H H H OH OB540 CH3CO2 H H H OH OB541 CH3CH2CO2 H H H OH OB542 CH2=CHCH2 H H H OH OB543 HCCCH2 H H H OH OB544 CF3 H H H OH OB545 (CH3)2NSO2 H H H OH OB546 (CH3)2N H H H OH OB547 PhO H H H OH OB548 PhS H H H OH OB549 PhSO H H H OH OB550 PhSO2 H H H OH OB551 CN H H H OH OB552 CH3 CH3 H H OH OB553 CH3CH2 CH3 H H OH OB554 CH3CH2CH2 CH3 H H OH OB555 (CH3)2CH CH3 H H OH OB556 (CH3)3C CH3 H H OH OB557 CH3S CH3 H H OH OB558 CH3SO CH3 H H OH OB559 CH3SO2 CH3 H H OH OB560 Ph CH3 H H OH O基团 R44 R37 R38 R39 R40 WB561 CH3O CH3 H H OH OB562 CH3CO2 CH3 H H OH OB563 CH3CH2CO2 CH3 H H OH OB564 CH2=CHCH2 CH3 H H OH OB565 HCCCH2 CH3 H H OH OB566 CF3 CH3 H H OH OB567 (CH3)2NSO2 CH3 H H OH OB568 (CH3)2N CH3 H H OH OB569 PhO CH3 H H OH OB570 PhS CH3 H H OH OB571 PhSO CH3 H H OH OB572 PhSO2 CH3 H H OH OB573 CN CH3 H H OH OB574 CH3 H CH3 H OH OB575 CH3CH2 H CH3 H OH OB576 CH3CH2CH2 H CH3 H OH OB577 (CH3)2CH H CH3 H OH OB578 (CH3)3C H CH3 H OH OB579 CH3S H CH3 H OH OB580 CH3SO H CH3 H OH OB581 CH3SO2 H CH3 H OH OB582 Ph H CH3 H OH OB583 CH3O H CH3 H OH OB584 CH3CO2 H CH3 H OH OB585 CH3CH2CO2 H CH3 H OH OB586 CH2=CHCH2 H CH3 H OH OB587 HCCCH2 H CH3 H OH OB588 CF3 H CH3 H OH OB589 (CH3)2NSO2 H CH3 H OH OB590 (CH3)2N H CH3 H OH OB591 PhO H CH3 H OH OB592 PhS H CH3 H OH OB593 PhSO H CH3 H OH O基团 R44 R37 R38 R39 R40 WB594 PhSO2 H CH3 H OH OB595 CN H CH3 H OH OB596 CH3 CH3 CH3 H OH OB597 CH3CH2 CH3 CH3 H OH OB598 CH3CH2CH2 CH3 CH3 H OH OB599 (CH3)2CH CH3 CH3 H OH OB600 (CH3)3C CH3 CH3 H OH OB601 CH3S CH3 CH3 H OH OB602 CH3SO CH3 CH3 H OH OB603 CH3SO2 CH3 CH3 H OH OB604 Ph CH3 CH3 H OH OB605 CH3O CH3 CH3 H OH OB606 CH3CO2 CH3 CH3 H OH OB607 CH3CH2CO2 CH3 CH3 H OH OB608 CH2=CHCH2 CH3 CH3 H OH OB609 HCCCH2 CH3 CH3 H OH OB610 CF3 CH3 CH3 H OH OB611 (CH3)2NSO2 CH3 CH3 H OH OB612 (CH3)2N CH3 CH3 H OH OB613 PhO CH3 CH3 H OH OB614 PhS CH3 CH3 H OH OB615 PhSO CH3 CH3 H OH OB616 PhSO2 CH3 CH3 H OH OB617 CN CH3 CH3 H OH OB618 CH3 CH3 CH3 CH3 OH OB619 CH3CH2 CH3 CH3 CH3 OH OB620 CH3CH2CH2 CH3 CH3 CH3 OH OB621 (CH3)2CH CH3 CH3 CH3 OH OB622 (CH3)3C CH3 CH3 CH3 OH OB623 CH3S CH3 CH3 CH3 OH OB624 CH3SO CH3 CH3 CH3 OH OB625 CH3SO2 CH3 CH3 CH3 OH OB626 Ph CH3 CH3 CH3 OH O基团 R44 R37 R38 R39 R40 WB627 CH3O CH3 CH3 CH3 OH OB628 CH3CO2 CH3 CH3 CH3 OH OB629 CH3CH2CO2 CH3 CH3 CH3 OH OB630 CH2=CHCH2 CH3 CH3 CH3 OH OB631 HCCCH2 CH3 CH3 CH3 OH OB632 CF3 CH3 CH3 CH3 OH OB633 (CH3)2NSO2 CH3 CH3 CH3 OH OB634 (CH3)2N CH3 CH3 CH3 OH OB635 PhO CH3 CH3 CH3 OH OB636 PhS CH3 CH3 CH3 OH OB637 PhSO CH3 CH3 CH3 OH OB638 PhSO2 CH3 CH3 CH3 OH OB639 CN CH3 CH3 CH3 OH OB640 CH3CH2 CH3CH2 H H OH OB641 CH3CH2CH2 CH3CH2 H H OH OB642 (CH3)2CH CH3CH2 H H OH OB643 (CH3)3C CH3CH2 H H OH OB644 CH3S CH3CH2 H H OH OB645 CH3SO CH3CH2 H H OH OB646 CH3SO2 CH3CH2 H H OH OB647 Ph CH3CH2 H H OH OB648 CH3O CH3CH2 H H OH OB649 CH3CO2 CH3CH2 H H OH OB650 CH3CH2CO2 CH3CH2 H H OH OB651 CH2=CHCH2 CH3CH2 H H OH OB652 HCCCH2 CH3CH2 H H OH OB653 CF3 CH3CH2 H H OH OB654 (CH3)2NSO2 CH3CH2 H H OH OB655 (CH3)2N CH3CH2 H H OH OB656 PhO CH3CH2 H H OH OB657 PhS CH3CH2 H H OH OB658 PhSO CH3CH2 H H OH OB659 PhSO2 CH3CH2 H H OH O基团 R44 R37 R38 R39 R40 WB660 CN CH3CH2 H H OH OB661 H H H H OH SB662 CH3 H H H OH SB663 CH3CH2 H H H OH SB664 CH3CH2CH2 H H H OH SB665 (CH3)2CH H H H OH SB666 (CH3)3C H H H OH SB667 CH3S H H H OH SB668 CH3SO H H H OH SB669 CH3SO2 H H H OH SB670 Ph H H H OH SB671 CH3O H H H OH SB672 CH3CO2 H H H OH SB673 CH3CH2CO2 H H H OH SB674 CH2=CHCH2 H H H OH SB675 HCCCH2 H H H OH SB676 CF3 H H H OH SB677 (CH3)2NSO2 H H H OH SB678 (CH3)2N H H H OH SB679 PhO H H H OH SB680 PhS H H H OH SB681 PhSO H H H OH SB682 PhSO2 H H H OH SB683 CN H H H OH SB684 CH3 CH3 H H OH SB685 CH3CH2 CH3 H H OH SB686 CH3CH2CH2 CH3 H H OH SB687 (CH3)2CH CH3 H H OH SB688 (CH3)3C CH3 H H OH SB689 CH3S CH3 H H OH SB690 CH3SO CH3 H H OH SB691 CH3SO2 CH3 H H OH SB692 Ph CH3 H H OH S基团 R44 R37 R38 R39 R40 WB693 CH3O CH3 H H OH SB694 CH3CO2 CH3 H H OH SB695 CH3CH2CO2 CH3 H H OH SB696 CH2=CHCH2 CH3 H H OH SB697 HCCCH2 CH3 H H OH SB698 CF3 CH3 H H OH SB699 (CH3)2NSO2 CH3 H H OH SB700 (CH3)2N CH3 H H OH SB701 PhO CH3 H H OH SB702 PhS CH3 H H OH SB703 PhSO CH3 H H OH SB704 PhSO2 CH3 H H OH SB705 CN CH3 H H OH SB706 CH3 H CH3 H OH SB707 CH3CH2 H CH3 H OH SB708 CH3CH2CH2 H CH3 H OH SB709 (CH3)2CH H CH3 H OH SB710 (CH3)3C H CH3 H OH SB711 CH3S H CH3 H OH SB712 CH3SO H CH3 H OH SB713 CH3SO2 H CH3 H OH SB714 Ph H CH3 H OH SB715 CH3O H CH3 H OH SB716 CH3CO2 H CH3 H OH SB717 CH3CH2CO2 H CH3 H OH SB718 CH2=CHCH2 H CH3 H OH SB719 HCCCH2 H CH3 H OH SB720 CF3 H CH3 H OH SB721 (CH3)2NSO2 H CH3 H OH SB722 (CH3)2N H CH3 H OH SB723 PhO H CH3 H OH SB724 PhS H CH3 H OH SB725 PhSO H CH3 H OH S基团 R44 R37 R38 R39 R40 WB726 PhSO2 H CH3 H OH SB727 CN H CH3 H OH SB728 CH3 CH3 CH3 H OH SB729 CH3CH2 CH3 CH3 H OH SB730 CH3CH2CH2 CH3 CH3 H OH SB731 (CH3)2CH CH3 CH3 H OH SB732 (CH3)3C CH3 CH3 H OH SB733 CH3S CH3 CH3 H OH SB734 CH3SO CH3 CH3 H OH SB735 CH3SO2 CH3 CH3 H OH SB736 Ph CH3 CH3 H OH SB737 CH3O CH3 CH3 H OH SB738 CH3CO2 CH3 CH3 H OH SB739 CH3CH2CO2 CH3 CH3 H OH SB740 CH2=CHCH2 CH3 CH3 H OH SB741 HCCCH2 CH3 CH3 H OH SB742 CF3 CH3 CH3 H OH SB743 (CH3)2NSO2 CH3 CH3 H OH SB744 (CH3)2N CH3 CH3 H OH SB745 PhO CH3 CH3 H OH SB746 PhS CH3 CH3 H OH SB747 PhSO CH3 CH3 H OH SB748 PhSO2 CH3 CH3 H OH SB749 CN CH3 CH3 H OH SB750 CH3 CH3 CH3 CH3 OH SB751 CH3CH2 CH3 CH3 CH3 OH SB752 CH3CH2CH2 CH3 CH3 CH3 OH SB753 (CH3)2CH CH3 CH3 CH3 OH SB754 (CH3)3C CH3 CH3 CH3 OH SB755 CH3S CH3 CH3 CH3 OH SB756 CH3SO CH3 CH3 CH3 OH SB757 CH3SO2 CH3 CH3 CH3 OH SB758 Ph CH3 CH3 CH3 OH S基团 R44 R37 R38 R39 R40 WB759 CH3O CH3 CH3 CH3 OH SB760 CH3CO2 CH3 CH3 CH3 OH SB761 CH3CH2CO2 CH3 CH3 CH3 OH SB762 CH2=CHCH2 CH3 CH3 CH3 OH SB763 HCCCH2 CH3 CH3 CH3 OH SB764 CF3 CH3 CH3 CH3 OH SB765 (CH3)2NSO2 CH3 CH3 CH3 OH SB766 (CH3)2N CH3 CH3 CH3 OH SB767 PhO CH3 CH3 CH3 OH SB768 PhS CH3 CH3 CH3 OH SB769 PhSO CH3 CH3 CH3 OH SB770 PhSO2 CH3 CH3 CH3 OH SB771 CN CH3 CH3 CH3 OH SB772 CH3CH2 CH3CH2 H H OH SB773 CH3CH2CH2 CH3CH2 H H OH SB774 (CH3)2CH CH3CH2 H H OH SB775 (CH3)3C CH3CH2 H H OH SB776 CH3S CH3CH2 H H OH SB777 CH3SO CH3CH2 H H OH SB778 CH3SO2 CH3CH2 H H OH SB779 Ph CH3CH2 H H OH SB780 CH3O CH3CH2 H H OH SB781 CH3CO2 CH3CH2 H H OH SB782 CH3CH2CO2 CH3CH2 H H OH SB783 CH2=CHCH2 CH3CH2 H H OH SB784 HCCCH2 CH3CH2 H H OH SB785 CF3 CH3CH2 H H OH SB786 (CH3)2NSO2 CH3CH2 H H OH SB787 (CH3)2N CH3CH2 H H OH SB788 PhO CH3CH2 H H OH SB789 PhS CH3CH2 H H OH SB790 PhSO CH3CH2 H H OH SB791 PhSO2 CH3CH2 H H OH S基团 R44 R37 R38 R39 R40 WB792 CN CH3CH2 H H OH SB793 H H H H OH SO2B794 CH3 H H H OH SO2B795 CH3CH2 H H H OH SO2B796 CH3CH2CH2 H H H OH SO2B797 (CH3)2CH H H H OH SO2B798 (CH3)3C H H H OH SO2B799 CH3S H H H OH SO2B800 CH3SO H H H OH SO2B801 CH3SO2 H H H OH SO2B802 Ph H H H OH SO2B803 CH3O H H H OH SO2B804 CH3CO2 H H H OH SO2B805 CH3CH2CO2 H H H OH SO2B806 CH2=CHCH2 H H H OH SO2B807 HCCCH2 H H H OH SO2B808 CF3 H H H OH SO2B809 (CH3)2NSO2 H H H OH SO2B810 (CH3)2N H H H OH SO2B811 PhO H H H OH SO2B812 PhS H H H OH SO2B813 PhSO H H H OH SO2B814 PhSO2 H H H OH SO2B815 CN H H H OH SO2B816 CH3 CH3 H H OH SO2B817 CH3CH2 CH3 H H OH SO2B818 CH3CH2CH2 CH3 H H OH SO2B819 (CH3)2CH CH3 H H OH SO2B820 (CH3)3C CH3 H H OH SO2B821 CH3S CH3 H H OH SO2B822 CH3SO CH3 H H OH SO2B823 CH3SO2 CH3 H H OH SO2B824 Ph CH3 H H OH SO2基团 R44 R37 R38 R39 R40 WB825 CH3O CH3 H H OH SO2B826 CH3CO2 CH3 H H OH SO2B827 CH3CH2CO2 CH3 H H OH SO2B828 CH2=CHCH2 CH3 H H OH SO2B829 HCCCH2 CH3 H H OH SO2B830 CF3 CH3 H H OH SO2B831 (CH3)2NSO2 CH3 H H OH SO2B832 (CH3)2N CH3 H H OH SO2B833 PhO CH3 H H OH SO2B834 PhS CH3 H H OH SO2B835 PhSO CH3 H H OH SO2B836 PhSO2 CH3 H H OH SO2B837 CN CH3 H H OH SO2B838 CH3 H CH3 H OH SO2B839 CH3CH2 H CH3 H OH SO2B840 CH3CH2CH2 H CH3 H OH SO2B841 (CH3)2CH H CH3 H OH SO2B842 (CH3)3C H CH3 H OH SO2B843 CH3S H CH3 H OH SO2B844 CH3SO H CH3 H OH SO2B845 CH3SO2 H CH3 H OH SO2B846 Ph H CH3 H OH SO2B847 CH3O H CH3 H OH SO2B848 CH3CO2 H CH3 H OH SO2B849 CH3CH2CO2 H CH3 H OH SO2B850 CH2=CHCH2 H CH3 H OH SO2B851 HCCCH2 H CH3 H OH SO2B852 CF3 H CH3 H OH SO2B853 (CH3)2NSO2 H CH3 H OH SO2B854 (CH3)2N H CH3 H OH SO2B855 PhO H CH3 H OH SO2B856 PhS H CH3 H OH SO2B857 PhSO H CH3 H OH SO2基团 R44 R37 R38 R39 R40 WB858 PhSO2 H CH3 H OH SO2B859 CN H CH3 H OH SO2B860 CH3 CH3 CH3 H OH SO2B861 CH3CH2 CH3 CH3 H OH SO2B862 CH3CH2CH2 CH3 CH3 H OH SO2B863 (CH3)2CH CH3 CH3 H OH SO2B864 (CH3)3C CH3 CH3 H OH SO2B865 CH3S CH3 CH3 H OH SO2B866 CH3SO CH3 CH3 H OH SO2B867 CH3SO2 CH3 CH3 H OH SO2B868 Ph CH3 CH3 H OH SO2B869 CH3O CH3 CH3 H OH SO2B870 CH3CO2 CH3 CH3 H OH SO2B871 CH3CH2CO2 CH3 CH3 H OH SO2B872 CH2=CHCH2 CH3 CH3 H OH SO2B873 HCCCH2 CH3 CH3 H OH SO2B874 CF3 CH3 CH3 H OH SO2B875 (CH3)2NSO2 CH3 CH3 H OH SO2B876 (CH3)2N CH3 CH3 H OH SO2B877 PhO CH3 CH3 H OH SO2B878 PhS CH3 CH3 H OH SO2B879 PhSO CH3 CH3 H OH SO2B880 PhSO2 CH3 CH3 H OH SO2B881 CN CH3 CH3 H OH SO2B882 CH3 CH3 CH3 CH3 OH SO2B883 CH3CH2 CH3 CH3 CH3 OH SO2B884 CH3CH2CH2 CH3 CH3 CH3 OH SO2B885 (CH3)2CH CH3 CH3 CH3 OH SO2B886 (CH3)3C CH3 CH3 CH3 OH SO2B887 CH3S CH3 CH3 CH3 OH SO2B888 CH3SO CH3 CH3 CH3 OH SO2B889 CH3SO2 CH3 CH3 CH3 OH SO2B890 Ph CH3 CH3 CH3 OH SO2基团 R44 R37 R38 R39 R40 WB891 CH3O CH3 CH3 CH3 OH SO2B892 CH3CO2 CH3 CH3 CH3 OH SO2B893 CH3CH2CO2 CH3 CH3 CH3 OH SO2B894 CH2=CHCH2 CH3 CH3 CH3 OH SO2B895 HCCCH2 CH3 CH3 CH3 OH SO2B896 CF3 CH3 CH3 CH3 OH SO2B897 (CH3)2NSO2 CH3 CH3 CH3 OH SO2B898 (CH3)2N CH3 CH3 CH3 OH SO2B899 PhO CH3 CH3 CH3 OH SO2B900 PhS CH3 CH3 CH3 OH SO2B901 PhSO CH3 CH3 CH3 OH SO2B902 PhSO2 CH3 CH3 CH3 OH SO2B903 CN CH3 CH3 CH3 OH SO2B904 CH3CH2 CH3CH2 H H OH SO2B905 CH3CH2CH2 CH3CH2 H H OH SO2B906 (CH3)2CH CH3CH2 H H OH SO2B907 (CH3)3C CH3CH2 H H OH SO2B908 CH3S CH3CH2 H H OH SO2B909 CH3SO CH3CH2 H H OH SO2B910 CH3SO2 CH3CH2 H H OH SO2B911 Ph CH3CH2 H H OH SO2B912 CH3O CH3CH2 H H OH SO2B913 CH3CO2 CH3CH2 H H OH SO2B914 CH3CH2CO2 CH3CH2 H H OH SO2B915 CH2=CHCH2 CH3CH2 H H OH SO2B916 HCCCH2 CH3CH2 H H OH SO2B917 CF3 CH3CH2 H H OH SO2B918 (CH3)2NSO2 CH3CH2 H H OH SO2B919 (CH3)2N CH3CH2 H H OH SO2B920 PhO CH3CH2 H H OH SO2B921 PhS CH3CH2 H H OH SO2B922 PhSO CH3CH2 H H OH SO2B923 PhSO2 CH3CH2 H H OH SO2基团 R44 R37 R38 R39 R40 WB924 CN CH3CH2 H H OH SO2B925 H H H H OH CH(CO2CH2CH3)B926 CH3 H H H OH CH(CO2CH2CH3)B927 CH3CH2 H H H OH CH(CO2CH2CH3)B928 CH3CH2CH2 H H H OH CH(CO2CH2CH3)B929 (CH3)2CH H H H OH CH(CO2CH2CH3)B930 (CH3)3C H H H OH CH(CO2CH2CH3)B931 CH3S H H H OH CH(CO2CH2CH3)B932 CH3SO H H H OH CH(CO2CH2CH3)B933 CH3SO2 H H H OH CH(CO2CH2CH3)B934 Ph H H H OH CH(CO2CH2CH3)B935 CH3O H H H OH CH(CO2CH2CH3)B936 CH3CO2 H H H OH CH(CO2CH2CH3)B937 CH3CH2CO2 H H H OH CH(CO2CH2CH3)B938 CH2=CHCH2 H H H OH CH(CO2CH2CH3)B939 HCCCH2 H H H OH CH(CO2CH2CH3)B940 CF3 H H H OH CH(CO2CH2CH3)B941 (CH3)2NSO2 H H H OH CH(CO2CH2CH3)B942 (CH3)2N H H H OH CH(CO2CH2CH3)B943 PhO H H H OH CH(CO2CH2CH3)B944 PhS H H H OH CH(CO2CH2CH3)B945 PhSO H H H OH CH(CO2CH2CH3)B946 PhSO2 H H H OH CH(CO2CH2CH3)B947 CN H H H OH CH(CO2CH2CH3)B948 CH3 CH3 H H OH CH(CO2CH2CH3)B949 CH3CH2 CH3 H H OH CH(CO2CH2CH3)B950 CH3CH2CH2 CH3 H H OH CH(CO2CH2CH3)B951 (CH3)2CH CH3 H H OH CH(CO2CH2CH3)B952 (CH3)3C CH3 H H OH CH(CO2CH2CH3)B953 CH3S CH3 H H OH CH(CO2CH2CH3)B954 CH3SO CH3 H H OH CH(CO2CH2CH3)B955 CH3SO2 CH3 H H OH CH(CO2CH2CH3)B956 Ph CH3 H H OH CH(CO2CH2CH3)基团 R44 R37 R38 R39 R40 WB957 CH3O CH3 H H OH CH(CO2CH2CH3)B958 CH3CO2 CH3 H H OH CH(CO2CH2CH3)B959 CH3CH2CO2 CH3 H H OH CH(CO2CH2CH3)B960 CH2=CHCH2 CH3 H H OH CH(CO2CH2CH3)B961 HCCCH2 CH3 H H OH CH(CO2CH2CH3)B962 CF3 CH3 H H OH CH(CO2CH2CH3)B963 (CH3)2NSO2 CH3 H H OH CH(CO2CH2CH3)B964 (CH3)2N CH3 H H OH CH(CO2CH2CH3)B965 PhO CH3 H H OH CH(CO2CH2CH3)B966 PhS CH3 H H OH CH(CO2CH2CH3)B967 PhSO CH3 H H OH CH(CO2CH2CH3)B968 PhSO2 CH3 H H OH CH(CO2CH2CH3)B969 CN CH3 H H OH CH(CO2CH2CH3)B970 CH3 H CH3 H OH CH(CO2CH2CH3)B971 CH3CH2 H CH3 H OH CH(CO2CH2CH3)B972 CH3CH2CH2 H CH3 H OH CH(CO2CH2CH3)B973 (CH3)2CH H CH3 H OH CH(CO2CH2CH3)B974 (CH3)3C H CH3 H OH CH(CO2CH2CH3)B975 CH3S H CH3 H OH CH(CO2CH2CH3)B976 CH3SO H CH3 H OH CH(CO2CH2CH3)B977 CH3SO2 H CH3 H OH CH(CO2CH2CH3)B978 Ph H CH3 H OH CH(CO2CH2CH3)B979 CH3O H CH3 H OH CH(CO2CH2CH3)B980 CH3CO2 H CH3 H OH CH(CO2CH2CH3)B981 CH3CH2CO2 H CH3 H OH CH(CO2CH2CH3)B982 CH2=CHCH2 H CH3 H OH CH(CO2CH2CH3)B983 HCCCH2 H CH3 H OH CH(CO2CH2CH3)B984 CF3 H CH3 H OH CH(CO2CH2CH3)B985 (CH3)2NSO2 H CH3 H OH CH(CO2CH2CH3)B986 (CH3)2N H CH3 H OH CH(CO2CH2CH3)B987 PhO H CH3 H OH CH(CO2CH2CH3)B988 PhS H CH3 H OH CH(CO2CH2CH3)B989 PhSO H CH3 H OH CH(CO2CH2CH3)基团 R44 R37 R38 R39 R40 WB990 PhSO2 H CH3 H OH CH(CO2CH2CH3)B991 CN H CH3 H OH CH(CO2CH2CH3)B992 CH3 CH3 CH3 H OH CH(CO2CH2CH3)B993 CH3CH2 CH3 CH3 H OH CH(CO2CH2CH3)B994 CH3CH2CH2 CH3 CH3 H OH CH(CO2CH2CH3)B995 (CH3)2CH CH3 CH3 H OH CH(CO2CH2CH3)B996 (CH3)3C CH3 CH3 H OH CH(CO2CH2CH3)B997 CH3S CH3 CH3 H OH CH(CO2CH2CH3)B998 CH3SO CH3 CH3 H OH CH(CO2CH2CH3)B999 CH3SO2 CH3 CH3 H OH CH(CO2CH2CH3)B1000 Ph CH3 CH3 H OH CH(CO2CH2CH3)B1001 CH3O CH3 CH3 H OH CH(CO2CH2CH3)B1002 CH3CO2 CH3 CH3 H OH CH(CO2CH2CH3)B1003 CH3CH2CO2 CH3 CH3 H OH CH(CO2CH2CH3)B1004 CH2=CHCH2 CH3 CH3 H OH CH(CO2CH2CH3)B1005 HCCCH2 CH3 CH3 H OH CH(CO2CH2CH3)B1006 CF3 CH3 CH3 H OH CH(CO2CH2CH3)B1007 (CH3)2NSO2 CH3 CH3 H OH CH(CO2CH2CH3)B1008 (CH3)2N CH3 CH3 H OH CH(CO2CH2CH3)B1009 PhO CH3 CH3 H OH CH(CO2CH2CH3)B1010 PhS CH3 CH3 H OH CH(CO2CH2CH3)B1011 PhSO CH3 CH3 H OH CH(CO2CH2CH3)B1012 PhSO2 CH3 CH3 H OH CH(CO2CH2CH3)B1013 CN CH3 CH3 H OH CH(CO2CH2CH3)B1014 CH3 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1015 CH3CH2 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1016 CH3CH2CH2 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1017 (CH3)2CH CH3 CH3 CH3 OH CH(CO2CH2CH3)B1018 (CH3)3C CH3 CH3 CH3 OH CH(CO2CH2CH3)B1019 CH3S CH3 CH3 CH3 OH CH(CO2CH2CH3)B1020 CH3SO CH3 CH3 CH3 OH CH(CO2CH2CH3)B1021 CH3SO2 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1022 Ph CH3 CH3 CH3 OH CH(CO2CH2CH3)基团 R44 R37 R38 R39 R40 WB1023 CH3O CH3 CH3 CH3 OH CH(CO2CH2CH3)B1024 CH3CO2 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1025 CH3CH2CO2 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1026 CH2=CHCH2 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1027 HCCCH2 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1028 CF3 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1029 (CH3)2NSO2 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1030 (CH3)2N CH3 CH3 CH3 OH CH(CO2CH2CH3)B1031 PhO CH3 CH3 CH3 OH CH(CO2CH2CH3)B1032 PhS CH3 CH3 CH3 OH CH(CO2CH2CH3)B1033 PhSO CH3 CH3 CH3 OH CH(CO2CH2CH3)B1034 PhSO2 CH3 CH3 CH3 OH CH(CO2CH2CH3)B1035 CN CH3 CH3 CH3 OH CH(CO2CH2CH3)B1036 CH3CH2 CH3CH2 H H OH CH(CO2CH2CH3)B1037 CH3CH2CH2 CH3CH2 H H OH CH(CO2CH2CH3)B1038 (CH3)2CH CH3CH2 H H OH CH(CO2CH2CH3)B1039 (CH3)3C CH3CH2 H H OH CH(CO2CH2CH3)B1040 CH3S CH3CH2 H H OH CH(CO2CH2CH3)B1041 CH3SO CH3CH2 H H OH CH(CO2CH2CH3)B1042 CH3SO2 CH3CH2 H H OH CH(CO2CH2CH3)B1043 Ph CH3CH2 H H OH CH(CO2CH2CH3)B1044 CH3O CH3CH2 H H OH CH(CO2CH2CH3)B1045 CH3CO2 CH3CH2 H H OH CH(CO2CH2CH3)B1046 CH3CH2CO2 CH3CH2 H H OH CH(CO2CH2CH3)B1047 CH2=CHCH2 CH3CH2 H H OH CH(CO2CH2CH3)B1048 HCCCH2 CH3CH2 H H OH CH(CO2CH2CH3)B1049 CF3 CH3CH2 H H OH CH(CO2CH2CH3)B1050 (CH3)2NSO2 CH3CH2 H H OH CH(CO2CH2CH3)B1051 (CH3)2N CH3CH2 H H OH CH(CO2CH2CH3)B1052 PhO CH3CH2 H H OH CH(CO2CH2CH3)B1053 PhS CH3CH2 H H OH CH(CO2CH2CH3)B1054 PhSO CH3CH2 H H OH CH(CO2CH2CH3)B1055 PhSO2 CH3CH2 H H OH CH(CO2CH2CH3)基团 R44 R37 R38 R39 R40 WB1056 CN CH3CH2 H H OH CH(CO2CH2CH3)B1057 CH3OCO H H H OH CHPhB1058 H H H H OH CHPhB1059 H H H H OH CH(CH2CH3)B1060 H H H H OH CH(CH2CH2CH3)B1061 H H H H OH CH(CH(CH3)2)B1062 H H H H OH CH(C(CH3)3)B1063 H H H H OH C(CH3)2B1064 H H H H OH CH(CF3)B1065 CH3OCO H H H OH C(CH3)(CF3)B1066 H H H H OH C(CH3)(CF3)B1067 CH3OCO CH3O H H OH CH2B1068 H CH3O H H OH CH2B1069 CH3O CH3OCO H CH3 OH CH2B1070 CH3O H CH3 H OH CH2B1071 Cl H H H OH CH2B1072 F H H H OH CH2B1073 H H H H OH CH(OCH3)2B1074 H H H H OH CH2OSO2CH3B1075 CH3 CH3 CH3 CH3 OH S(O)B1076 ClCH2CH2 H H H OH CH2B1077 HO(CH2)2 H H H OH CH2B1078 MsO(CH2)2 H H H OH CH2B1079 HOCH(CH3)CH2 H H H OH CH2B1080 MsOCH(CH3)CH2 H H H OH CH2B1081 (CH3)2CH H CH3 CH3 OH CH2B1082 HCCCH2 H CH3 CH3 OH CH2B1083 H2C=CCH2 H CH3 CH3 OH CH2在下表7中,Q是Q6 且Q6代表下列基团C:表7:基团C:基团 R84 R85 R86 R83 p WC1 H H H OH 1 CH2C2 CH3 H H OH 1 CH2C3 CH3CH2 H H OH 1 CH2C4 CH3CH2CH2 H H OH 1 CH2C5 (CH3)2CH H H OH 1 CH2C6 (CH3)3C H H OH 1 CH2C7 CH3S H H OH 1 CH2C8 CH3SO H H OH 1 CH2C9 CH3SO2 H H OH 1 CH2C10 Ph H H OH 1 CH2C11 CH3O H H OH 1 CH2C12 CH3OCO2 H H OH 1 CH2C13 CH3CH2OCO2 H H OH 1 CH2C14 CH2=CHCH2 H H OH 1 CH2C15 HCCCH2 H H OH 1 CH2C16 CF3 H H OH 1 CH2C17 (CH3)2NSO2 H H OH 1 CH2C18 (CH3)2N H H OH 1 CH2C19 PhO H H OH 1 CH2C20 PhS H H OH 1 CH2C21 PhSO H H OH 1 CH2C22 PhSO2 H H OH 1 CH2基团 R84 R85 R86 R83 p WC23 CN H H OH 1 CH2C24 CH3 CH3 H OH 1 CH2C25 CH3CH2 CH3 H OH 1 CH2C26 CH3CH2CH2 CH3 H OH 1 CH2C27 (CH3)2CH CH3 H OH 1 CH2C28 (CH3)3C CH3 H OH 1 CH2C29 CH3S CH3 H OH 1 CH2C30 CH3SO CH3 H OH 1 CH2C31 CH3SO2 CH3 H OH 1 CH2C32 Ph CH3 H OH 1 CH2C33 CH3O CH3 H OH 1 CH2C34 CH3OCO2 CH3 H OH 1 CH2C35 CH3CH2OCO2 CH3 H OH 1 CH2C36 CH2=CHCH2 CH3 H OH 1 CH2C37 HCCCH2 CH3 H OH 1 CH2C38 CF3 CH3 H OH 1 CH2C39 (CH3)2NSO2 CH3 H OH 1 CH2C40 (CH3)2N CH3 H OH 1 CH2C41 PhO CH3 H OH 1 CH2C42 PhS CH3 H OH 1 CH2C43 PhSO CH3 H OH 1 CH2C44 PhSO2 CH3 H OH 1 CH2C45 CN CH3 H OH 1 CH2C46 H H H OH 4 CH2C47 CH3 H H OH 4 CH2C48 CH3CH2 H H OH 4 CH2C49 CH3CH2CH2 H H OH 4 CH2C50 (CH3)2CH H H OH 4 CH2C51 (CH3)3C H H OH 4 CH2C52 CH3S H H OH 4 CH2C53 CH3SO H H OH 4 CH2C54 CH3SO2 H H OH 4 CH2C55 Ph H H OH 4 CH2基团 R84 R85 R86 R83 p WC56 CH3O H H OH 4 CH2C57 CH3OCO2 H H OH 4 CH2C58 CH3CH2OCO2 H H OH 4 CH2C59 CH2=CHCH2 H H OH 4 CH2C60 HCCCH2 H H OH 4 CH2C61 CF3 H H OH 4 CH2C62 (CH3)2NSO2 H H OH 4 CH2C63 (CH3)2N H H OH 4 CH2C64 PhO H H OH 4 CH2C65 PhS H H OH 4 CH2C66 PhSO H H OH 4 CH2C67 PhSO2 H H OH 4 CH2C68 CN H H OH 4 CH2C69 CH3 CH3 H OH 4 CH2C70 CH3CH2 CH3 H OH 4 CH2C71 CH3CH2CH2 CH3 H OH 4 CH2C72 (CH3)2CH CH3 H OH 4 CH2C73 (CH3)3C CH3 H OH 4 CH2C74 CH3S CH3 H OH 4 CH2C75 CH3SO CH3 H OH 4 CH2C76 CH3SO2 CH3 H OH 4 CH2C77 Ph CH3 H OH 4 CH2C78 CH3O CH3 H OH 4 CH2C79 CH3OCO2 CH3 H OH 4 CH2C80 CH3CH2OCO2 CH3 H OH 4 CH2C81 CH2=CHCH2 CH3 H OH 4 CH2C82 HCCCH2 CH3 H OH 4 CH2C83 CF3 CH3 H OH 4 CH2C84 (CH3)2NSO2 CH3 H OH 4 CH2C85 (CH3)2N CH3 H OH 4 CH2C86 PhO CH3 H OH 4 CH2C87 PhS CH3 H OH 4 CH2C88 PhSO CH3 H OH 4 CH2基团 R84 R85 R86 R83 p WC89 PhSO2 CH3 H OH 4 CH2C90 CN CH3 H OH 4 CH2C91 H H H OH 3 CH2C92 CH3 H H OH 3 CH2C93 CH3CH2 H H OH 3 CH2C94 CH3CH2CH2 H H OH 3 CH2C95 (CH3)2CH H H OH 3 CH2C96 (CH3)3C H H OH 3 CH2C97 CH3S H H OH 3 CH2C98 CH3SO H H OH 3 CH2C99 CH3SO2 H H OH 3 CH2C100 Ph H H OH 3 CH2C101 CH3O H H OH 3 CH2C102 CH3OCO2 H H OH 3 CH2C103 CH3CH2OCO2 H H OH 3 CH2C104 CH2=CHCH2 H H OH 3 CH2C105 HCCCH2 H H OH 3 CH2C106 CF3 H H OH 3 CH2C107 (CH3)2NSO2 H H OH 3 CH2C108 (CH3)2N H H OH 3 CH2C109 PhO H H OH 3 CH2C110 PhS H H OH 3 CH2C111 PhSO H H OH 3 CH2C112 PhSO2 H H OH 3 CH2C113 CN H H OH 3 CH2C114 CH3 CH3 H OH 3 CH2C115 CH3CH2 CH3 H OH 3 CH2C116 CH3CH2CH2 CH3 H OH 3 CH2C117 (CH3)2CH CH3 H OH 3 CH2C118 (CH3)3C CH3 H OH 3 CH2C119 CH3S CH3 H OH 3 CH2C120 CH3SO CH3 H OH 3 CH2C121 CH3SO2 CH3 H OH 3 CH2基团 R84 R85 R86 R83 p WC122 Ph CH3 H OH 3 CH2C123 CH3O CH3 H OH 3 CH2C124 CH3OCO2 CH3 H OH 3 CH2C125 CH3CH2OCO2 CH3 H OH 3 CH2C126 CH2=CHCH2 CH3 H OH 3 CH2C127 HCCCH2 CH3 H OH 3 CH2C128 CF3 CH3 H OH 3 CH2C129 (CH3)2NSO2 CH3 H OH 3 CH2C130 (CH3)2N CH3 H OH 3 CH2C131 PhO CH3 H OH 3 CH2C132 PhS CH3 H OH 3 CH2C133 PhSO CH3 H OH 3 CH2C134 PhSO2 CH3 H OH 3 CH2C135 CN CH3 H OH 3 CH2C136 CH3CH2 CH3CH2 H OH 1 CH2C137 H H H OH 1 CH(CH3)C138 CH3 H H OH 1 CH(CH3)C139 CH3 CH3 H OH 1 CH(CH3)C140 CH2CH3 H H OH 1 CH(CH3)C141 CH2CH3 CH3 H OH 1 CH(CH3)C142 CH3CH2 CH3CH2 H OH 1 CH(CH3)C143 H H CH3 OH 1 CH2C144 CH3 CH3 CH3 OH 1 CH2C145 CH3CH2 CH3CH2 CH3 OH 1 CH2C146 H H H OH 2 CH2C147 CH3 CH3 H OH 2 CH2C148 CH3CH2 CH3CH2 H OH 2 CH2C149 H H H OH 5 CH2C150 CH3 CH3 H OH 5 CH2C151 CH3CH2 CH3CH2 H OH 5 CH2在下表8中,Q是Q8 且Q8代表下列基团D:表8:基团D:基团 R88 R89 R90 R91 R87 oD1 H H H H OH 2D2 CH3 H H H OH 2D3 CH3CH2 H H H OH 2D4 CH3CH2CH2 H H H OH 2D5 (CH3)2CH H H H OH 2D6 (CH3)3C H H H OH 2D7 CH3S H H H OH 2D8 CH3SO H H H OH 2D9 CH3SO2 H H H OH 2D10 Ph H H H OH 2D11 CH3O H H H OH 2D12 CH2=CHCH2 H H H OH 2D13 HCCCH2 H H H OH 2D14 CF3 H H H OH 2D15 PhO H H H OH 2D16 PhS H H H OH 2D17 PhSO H H H OH 2D18 PhSO2 H H H OH 2D19 CH3 CH3 H H OH 2D20 CH3CH2 CH3 H H OH 2D21 CH3CH2CH2 CH3 H H OH 2D22 (CH3)2CH CH3 H H OH 2D23 (CH3)3C CH3 H H OH 2基团 R88 R89 R90 R91 R87 oD24 CH3S CH3 H H OH 2D25 CH3SO CH3 H H OH 2D26 CH3SO2 CH3 H H OH 2D27 Ph CH3 H H OH 2D28 CH3O CH3 H H OH 2D29 CH2=CHCH2 CH3 H H OH 2D30 HCCCH2 CH3 H H OH 2D31 CF3 CH3 H H OH 2D32 PhO CH3 H H OH 2D33 PhS CH3 H H OH 2D34 PhSO CH3 H H OH 2D35 PhSO2 CH3 H H OH 2D36 H H H H OH 3D37 CH3 H H H OH 3D38 CH3CH2 H H H OH 3D39 CH3CH2CH2 H H H OH 3D40 (CH3)2CH H H H OH 3D41 (CH3)3C H H H OH 3D42 CH3S H H H OH 3D43 CH3SO H H H OH 3D44 CH3SO2 H H H OH 3D45 Ph H H H OH 3D46 CH3O H H H OH 3D47 CH2=CHCH2 H H H OH 3D48 HCCCH2 H H H OH 3D49 CF3 H H H OH 3D50 PhO H H H OH 3D51 PhS H H H OH 3D52 PhSO H H H OH 3D53 PhSO2 H H H OH 3D54 CH3 CH3 H H OH 3D55 CH3CH2 CH3 H H OH 3D56 CH3CH2CH2 CH3 H H OH 3基团 R88 R89 R90 R91 R87 oD57 (CH3)2CH CH3 H H OH 3D58 (CH3)3C CH3 H H OH 3D59 CH3S CH3 H H OH 3D60 CH3SO CH3 H H OH 3D61 CH3SO2 CH3 H H OH 3D62 Ph CH3 H H OH 3D63 CH3O CH3 H H OH 3D64 CH2=CHCH2 CH3 H H OH 3D65 HCCCH2 CH3 H H OH 3D66 CF3 CH3 H H OH 3D67 PhO CH3 H H OH 3D68 PhS CH3 H H OH 3D69 PhSO CH3 H H OH 3D70 PhSO2 CH3 H H OH 3D71 H H H H OH 4D72 CH3 H H H OH 4D73 CH3CH2 H H H OH 4D74 CH3CH2CH2 H H H OH 4D75 (CH3)2CH H H H OH 4D76 (CH3)3C H H H OH 4D77 CH3S H H H OH 4D78 CH3SO H H H OH 4D79 CH3SO2 H H H OH 4D80 Ph H H H OH 4D81 CH3O H H H OH 4D82 CH2=CHCH2 H H H OH 4D83 HCCCH2 H H H OH 4D84 CF3 H H H OH 4D85 PhO H H H OH 4D86 PhS H H H OH 4D87 PhSO H H H OH 4D88 PhSO2 H H H OH 4D89 CH3 CH3 H H OH 4基团 R88 R89 R90 R91 R87 oD90 CH3CH2 CH3 H H OH 4D91 CH3CH2CH2 CH3 H H OH 4D92 (CH3)2CH CH3 H H OH 4D93 (CH3)3C CH3 H H OH 4D94 CH3S CH3 H H OH 4D95 CH3SO CH3 H H OH 4D96 CH3SO2 CH3 H H OH 4D97 Ph CH3 H H OH 4D98 CH3O CH3 H H OH 4D99 CH2=CHCH2 CH3 H H OH 4D100 HCCCH2 CH3 H H OH 4D101 CF3 CH3 H H OH 4D102 PhO CH3 H H OH 4D103 PhS CH3 H H OH 4D104 PhSO CH3 H H OH 4D105 PhSO2 CH3 H H OH 4D106 H H H CH3 OH 4D107 H H H CH3 OH 3D108 H H H H OH 1D109 CH3 H H H OH 1D110 CH3OCO CH3 H H OH 1D111 CH3CH2OCO CH3 H H OH 1D112 CH3O CH3 H H OH 1D113 CH3S CH3 H H OH 1D114 CH3SO CH3 H H OH 1D115 CH3SO2 CH3 H H OH 1D116 CH3CH2 H H H OH 1D117 CH3OCO CH3CH2 H H OH 1D118 CH3CH2OCO CH3CH2 H H OH 1D119 CH3O CH3CH2 H H OH 1D120 CH3S CH3CH2 H H OH 1D121 CH3SO CH3CH2 H H OH 1D122 CH3SO2 CH3CH2 H H OH 1基团 R88 R89 R90 R91 R87 oD123 CH3CH2S CH3 H H OH 1D124 CH3CH2SO CH3 H H OH 1D125 CH3CH2SO2 CH3 H H OH 1D126 CH3CH2S CH3CH2 H H OH 1D127 CH3CH2SO CH3CH2 H H OH 1D128 CH3CH2SO2 CH3CH2 H H OH 1D129 H H CH3 H OH 1D130 CH3 H CH3 H OH 1D131 CH3OCO CH3 CH3 H OH 1D132 CH3CH2OCO CH3 CH3 H OH 1D133 CH3O CH3 CH3 H OH 1D134 CH3S CH3 CH3 H OH 1D135 CH3SO CH3 CH3 H OH 1D136 CH3SO2 CH3 CH3 H OH 1D137 H H H CH3 OH 1D138 CH3 H H CH3 OH 1D139 H H CH3 CH3 OH 1D140 CH3CH2OCO CH3 H H OH 4表9:式If化合物: 化合物. R92 R93 R94 R95 Q3序号A1 H H H CF3 B24A2 CH3 H H CF3 B24A3 CH3CH2 H H CF3 B24化合物 R92 R93 R94 R95 Q3序号A4 (CH3)2CH H H CF3 B24A5 (CH3)3C H H CF3 B24A6 环丙基 H H CF3 B24A7 CH3(CH2)2 H H CF3 B24A8 CH3OCH2 H H CF3 B24A9 CH3O(CH2)2 H H CF3 B24A10 Ph H H CF3 B24A11 PhO H H CF3 B24A12 PhS H H CF3 B24A13 PhSO H H CF3 B24A14 PhSO2 H H CF3 B24A15 CH3S H H CF3 B24A16 CH3SO H H CF3 B24A17 CF3 H H CF3 B24A18 F2CH H H CF3 B24A19 HCC H H CF3 B24A20 CH3CC H H CF3 B24A21 CH2=CH H H CF3 B24A22 CH2=CHCH2 H H CF3 B24A23 CH3SO2N(CH3) H H CF3 B24A24 (CH3)2N H H CF3 B24A25 (CH3)2NSO2 H H CF3 B24A26 ClCH2 H H CF3 B24A27 CH3SCH2 H H CF3 B24A28 CH3SOCH2 H H CF3 B24A29 CH3SO2CH2 H H CF3 B24A30 [1,2,4]-三唑-1-基-甲基 H H CF3 B24A31 CH3 CF3 H CH3 B24A32 CH3 CH3 H CF3 B24A33 H H H CF3CF2 B24A34 CH3 H H CF3CF2 B24A35 CH3CH2 H H CF3CF2 B24化合物 R92 R93 R94 R95 Q3序号A36 环丙基 H H CF3CF2 B24A37 (CH3)3C H H CF3CF2 B24A38 (CH3)2CH H H CF3CF2 B24A39 CH3(CH2)2 H H CF3CF2 B24A40 CH3OCH2 H H CF3CF2 B24A41 CH3O(CH2)2 H H CF3CF2 B24A42 Ph H H CF3CF2 B24A43 PhO H H CF3CF2 B24A44 PhS H H CF3CF2 B24A45 PhSO H H CF3CF2 B24A46 PhSO2 H H CF3CF2 B24A47 CH3S H H CF3CF2 B24A48 CH3SO H H CF3CF2 B24A49 CF3 H H CF3CF2 B24A50 F2CH H H CF3CF2 B24A51 HCC H H CF3CF2 B24A52 CH3CC H H CF3CF2 B24A53 CH2=CH H H CF3CF2 B24A54 CH2=CHCH2 H H CF3CF2 B24A55 CH3SO2N(CH3) H H CF3CF2 B24A56 (CH3)2N H H CF3CF2 B24A57 (CH3)2NSO2 H H CF3CF2 B24A58 ClCH2 H H CF3CF2 B24A59 CH3SCH2 H H CF3CF2 B24A60 CH3SOCH2 H H CF3CF2 B24A61 CH3SO2CH2 H H CF3CF2 B24A62 [1,2,4]-三唑-1-基-甲基 H H CF3CF2 B24A63 H H H CF3CF2CF2 B24A64 CH3 H H CF3CF2CF2 B24A65 CH3CH2 H H CF3CF2CF2 B24A66 环丙基 H H CF3CF2CF2 B24A67 (CH3)3C H H CF3CF2CF2 B24化合物 R92 R93 R94 R95 Q3序号A68 (CH3)2CH H H CF3CF2CF2 B24A69 CH3(CH2)2 H H CF3CF2CF2 B24A70 CH3OCH2 H H CF3CF2CF2 B24A71 CH3O(CH2)2 H H CF3CF2CF2 B24A72 Ph H H CF3CF2CF2 B24A73 PhO H H CF3CF2CF2 B24A74 PhS H H CF3CF2CF2 B24A75 PhSO H H CF3CF2CF2 B24A76 PhSO2 H H CF3CF2CF2 B24A77 CH3S H H CF3CF2CF2 B24A78 CH3SO H H CF3CF2CF2 B24A79 CF3 H H CF3CF2CF2 B24A80 F2CH H H CF3CF2CF2 B24A81 HCC H H CF3CF2CF2 B24A82 CH3CC H H CF3CF2CF2 B24A83 CH2=CH H H CF3CF2CF2 B24A84 CH2=CHCH2 H H CF3CF2CF2 B24A85 CH3SO2N(CH3) H H CF3CF2CF2 B24A86 (CH3)2N H H CF3CF2CF2 B24A87 (CH3)2NSO2 H H CF3CF2CF2 B24A88 ClCH2 H H CF3CF2CF2 B24A89 CH3SCH2 H H CF3CF2CF2 B24A90 CH3SOCH2 H H CF3CF2CF2 B24A91 CH3SO2CH2 H H CF3CF2CF2 B24A92 [1,2,4]-三唑-1-基-甲基 H H CF3CF2CF2 B24A93 H H H CF2Cl B24A94 CH3 H H CF2Cl B24A95 CH3CH2 H H CF2Cl B24A96 环丙基 H H CF2Cl B24A97 (CH3)3C H H CF2Cl B24A98 (CH3)2CH H H CF2Cl B24A99 CH3(CH2)2 H H CF2Cl B24化合物 R92 R93 R94 R95 Q3序号A100 CH3OCH2 H H CF2Cl B24A101 CH3O(CH2)2 H H CF2Cl B24A102 Ph H H CF2Cl B24A103 PhO H H CF2Cl B24A104 PhS H H CF2Cl B24A105 PhSO H H CF2Cl B24A106 PhSO2 H H CF2Cl B24A107 CH3S H H CF2Cl B24A108 CH3SO H H CF2Cl B24A109 CF3 H H CF2Cl B24A110 F2CH H H CF2Cl B24A111 HCC H H CF2Cl B24A112 CH3CC H H CF2Cl B24A113 CH2=CH H H CF2Cl B24A114 CH2=CHCH2 H H CF2Cl B24A115 CH3SO2N(CH3) H H CF2Cl B24A116 (CH3)2N H H CF2Cl B24A117 (CH3)2NSO2 H H CF2Cl B24A118 ClCH2 H H CF2Cl B24A119 CH3SCH2 H H CF2Cl B24A120 CH3SOCH2 H H CF2Cl B24A121 CH3SO2CH2 H H CF2Cl B24A122 [1,2,4]-三唑-1-基-甲基 H H CF2Cl B24A123 H H H CHF2 B24A124 CH3 H H CHF2 B24A125 CH3CH2 H H CHF2 B24A126 环丙基 H H CHF2 B24A127 (CH3)3C H H CHF2 B24A128 (CH3)2CH H H CHF2 B24A129 CH3(CH2)2 H H CHF2 B24A130 CH3OCH2 H H CHF2 B24A131 CH3O(CH2)2 H H CHF2 B24化合物 R92 R93 R94 R95 Q3序号A132 Ph H H CHF2 B24A133 PhO H H CHF2 B24A134 PhS H H CHF2 B24A135 PhSO H H CHF2 B24A136 PhSO2 H H CHF2 B24A137 CH3S H H CHF2 B24A138 CH3SO H H CHF2 B24A139 CF3 H H CHF2 B24A140 F2CH H H CHF2 B24A141 HCC H H CHF2 B24A142 CH3CC H H CHF2 B24A143 CH2=CH H H CHF2 B24A144 CH2=CHCH2 H H CHF2 B24A145 CH3SO2N(CH3) H H CHF2 B24A146 (CH3)2N H H CHF2 B24A147 (CH3)2NSO2 H H CHF2 B24A148 ClCH2 H H CHF2 B24A149 CH3SCH2 H H CHF2 B24A150 CH3SOCH2 H H CHF2 B24A151 CH3SO2CH2 H H CHF2 B24A152 [1,2,4]-三唑-1-基-甲基 H H CHF2 B24A153 H H H CCl3 B24A154 CH3 H H CCl3 B24A155 CH3CH2 H H CCl3 B24A156 环丙基 H H CCl3 B24A157 (CH3)3C H H CCl3 B24A158 (CH3)2CH H H CCl3 B24A159 CH3(CH2)2 H H CCl3 B24A160 CH3OCH2 H H CCl3 B24A161 CH3O(CH2)2 H H CCl3 B24A162 Ph H H CCl3 B24A163 PhO H H CCl3 B24化合物 R92 R93 R94 R95 Q3序号A164 PhS H H CCl3 B24A165 PhSO H H CCl3 B24A166 PhSO2 H H CCl3 B24A167 CH3S H H CCl3 B24A168 CH3SO H H CCl3 B24A169 CF3 H H CCl3 B24A170 F2CH H H CCl3 B24A171 HCC H H CCl3 B24A172 CH3CC H H CCl3 B24A173 CH2=CH H H CCl3 B24A174 CH2=CHCH2 H H CCl3 B24A175 CH3SO2N(CH3) H H CCl3 B24A176 (CH3)2N H H CCl3 B24A177 (CH3)2NSO2 H H CCl3 B24A178 ClCH2 H H CCl3 B24A179 CH3SCH2 H H CCl3 B24A180 CH3SOCH2 H H CCl3 B24A181 CH3SO2CH2 H H CCl3 B24A182 [1,2,4]-三唑-1-基-甲基 H H CCl3 B24A183 H H CH3 CF3 B24A184 CH3 H CH3 CF3 B24A185 CH3CH2 H CH3 CF3 B24A186 环丙基 H CH3 CF3 B24A187 (CH3)3C H CH3 CF3 B24A188 (CH3)2CH H CH3 CF3 B24A189 CH3(CH2)2 H CH3 CF3 B24A190 CH3OCH2 H CH3 CF3 B24A191 CH3O(CH2)2 H CH3 CF3 B24A192 Ph H CH3 CF3 B24A193 PhO H CH3 CF3 B24A194 PhS H CH3 CF3 B24A195 PhSO H CH3 CF3 B24化合物 R92 R93 R94 R95 Q3序号A196 PhSO2 H CH3 CF3 B24A197 CH3S H CH3 CF3 B24A198 CH3SO H CH3 CF3 B24A199 CF3 H CH3 CF3 B24A200 F2CH H CH3 CF3 B24A201 HCC H CH3 CF3 B24A202 CH3CC H CH3 CF3 B24A203 CH2=CH H CH3 CF3 B24A204 CH2=CHCH2 H CH3 CF3 B24A205 CH3SO2N(CH3) H CH3 CF3 B24A206 (CH3)2N H CH3 CF3 B24A207 (CH3)2NSO2 H CH3 CF3 B24A208 ClCH2 H CH3 CF3 B24A209 CH3SCH2 H CH3 CF3 B24A210 CH3SOCH2 H CH3 CF3 B24A211 CH3SO2CH2 H CH3 CF3 B24A212 H H CH3 CF3CF2 B24A213 CH3 H CH3 CF3CF2 B24A214 CH3CH2 H CH3 CF3CF2 B24A215 环丙基 H CH3 CF3CF2 B24A216 (CH3)3C H CH3 CF3CF2 B24A217 (CH3)2CH H CH3 CF3CF2 B24A218 CH3(CH2)2 H CH3 CF3CF2 B24A219 CH3OCH2 H CH3 CF3CF2 B24A220 CH3O(CH2)2 H CH3 CF3CF2 B24A221 Ph H CH3 CF3CF2 B24A222 PhO H CH3 CF3CF2 B24A223 PhS H CH3 CF3CF2 B24A224 PhSO H CH3 CF3CF2 B24A225 PhSO2 H CH3 CF3CF2 B24A226 CH3S H CH3 CF3CF2 B24A227 CH3SO H CH3 CF3CF2 B24化合物 R92 R93 R94 R95 Q3序号A228 CF3 H CH3 CF3CF2 B24A229 F2CH H CH3 CF3CF2 B24A230 HCC H CH3 CF3CF2 B24A231 CH3CC H CH3 CF3CF2 B24A232 CH2=CH H CH3 CF3CF2 B24A233 CH2=CHCH2 H CH3 CF3CF2 B24A234 CH3SO2N(CH3) H CH3 CF3CF2 B24A235 (CH3)2N H CH3 CF3CF2 B24A236 (CH3)2NSO2 H CH3 CF3CF2 B24A237 ClCH2 H CH3 CF3CF2 B24A238 CH3SCH2 H CH3 CF3CF2 B24A239 CH3SOCH2 H CH3 CF3CF2 B24A240 CH3SO2CH2 H CH3 CF3CF2 B24A241 H H CH3 CF3CF2CF2 B24A242 CH3 H CH3 CF3CF2CF2 B24A243 CH3CH2 H CH3 CF3CF2CF2 B24A244 环丙基 H CH3 CF3CF2CF2 B24A245 (CH3)3C H CH3 CF3CF2CF2 B24A246 (CH3)2CH H CH3 CF3CF2CF2 B24A247 CH3(CH2)2 H CH3 CF3CF2CF2 B24A248 CH3OCH2 H CH3 CF3CF2CF2 B24A249 CH3O(CH2)2 H CH3 CF3CF2CF2 B24A250 Ph H CH3 CF3CF2CF2 B24A251 PhO H CH3 CF3CF2CF2 B24A252 PhS H CH3 CF3CF2CF2 B24A253 PhSO H CH3 CF3CF2CF2 B24A254 PhSO2 H CH3 CF3CF2CF2 B24A255 CH3S H CH3 CF3CF2CF2 B24A256 CH3SO H CH3 CF3CF2CF2 B24A257 CF3 H CH3 CF3CF2CF2 B24A258 F2CH H CH3 CF3CF2CF2 B24A259 HCC H CH3 CF3CF2CF2 B24化合物 R92 R93 R94 R95 Q3序号A260 CH3CC H CH3 CF3CF2CF2 B24A261 CH2=CH H CH3 CF3CF2CF2 B24A262 CH2=CHCH2 H CH3 CF3CF2CF2 B24A263 CH3SO2N(CH3) H CH3 CF3CF2CF2 B24A264 (CH3)2N H CH3 CF3CF2CF2 B24A265 (CH3)2NSO2 H CH3 CF3CF2CF2 B24A266 ClCH2 H CH3 CF3CF2CF2 B24A267 CH3SCH2 H CH3 CF3CF2CF2 B24A268 CH3SOCH2 H CH3 CF3CF2CF2 B24A269 CH3SO2CH2 H CH3 CF3CF2CF2 B24A270 H H CH3 CF2Cl B24A271 CH3 H CH3 CF2Cl B24A272 CH3CH2 H CH3 CF2Cl B24A273 环丙基 H CH3 CF2Cl B24A274 (CH3)3C H CH3 CF2Cl B24A275 (CH3)2CH H CH3 CF2Cl B24A276 CH3(CH2)2 H CH3 CF2Cl B24A277 CH3OCH2 H CH3 CF2Cl B24A278 CH3O(CH2)2 H CH3 CF2Cl B24A279 Ph H CH3 CF2Cl B24A280 PhO H CH3 CF2Cl B24A281 PhS H CH3 CF2Cl B24A282 PhSO H CH3 CF2Cl B24A283 PhSO2 H CH3 CF2Cl B24A284 CH3S H CH3 CF2Cl B24A285 CH3SO H CH3 CF2Cl B24A286 CF3 H CH3 CF2Cl B24A287 F2CH H CH3 CF2Cl B24A288 HCC H CH3 CF2Cl B24A289 CH3CC H CH3 CF2Cl B24A290 CH2=CH H CH3 CF2Cl B24A291 CH2=CHCH2 H CH3 CF2Cl B24化合物 R92 R93 R94 R95 Q3序号A292 CH3SO2N(CH3) H CH3 CF2Cl B24A293 (CH3)2N H CH3 CF2Cl B24A294 (CH3)2NSO2 H CH3 CF2Cl B24A295 ClCH2 H CH3 CF2Cl B24A296 CH3SCH2 H CH3 CF2Cl B24A297 CH3SOCH2 H CH3 CF2Cl B24A298 CH3SO2CH2 H CH3 CF2Cl B24A299 H H CH3 CHF2 B24A300 CH3 H CH3 CHF2 B24A301 CH3CH2 H CH3 CHF2 B24A302 环丙基 H CH3 CHF2 B24A303 (CH3)3C H CH3 CHF2 B24A304 (CH3)2CH H CH3 CHF2 B24A305 CH3(CH2)2 H CH3 CHF2 B24A306 CH3OCH2 H CH3 CHF2 B24A307 CH3O(CH2)2 H CH3 CHF2 B24A308 Ph H CH3 CHF2 B24A309 PhO H CH3 CHF2 B24A310 PhS H CH3 CHF2 B24A311 PhSO H CH3 CHF2 B24A312 PhSO2 H CH3 CHF2 B24A313 CH3S H CH3 CHF2 B24A314 CH3SO H CH3 CHF2 B24A315 CF3 H CH3 CHF2 B24A316 F2CH H CH3 CHF2 B24A317 HCC H CH3 CHF2 B24A318 CH3CC H CH3 CHF2 B24A319 CH2=CH H CH3 CHF2 B24A320 CH2=CHCH2 H CH3 CHF2 B24A321 CH3SO2N(CH3) H CH3 CHF2 B24A322 (CH3)2N H CH3 CHF2 B24A323 (CH3)2NSO2 H CH3 CHF2 B24化合物 R92 R93 R94 R95 Q3序号A324 ClCH2 H CH3 CHF2 B24A325 CH3SCH2 H CH3 CHF2 B24A326 CH3SOCH2 H CH3 CHF2 B24A327 CH3SO2CH2 H CH3 CHF2 B24A328 H H CH3 CCl3 B24A329 CH3 H CH3 CCl3 B24A330 CH3CH2 H CH3 CCl3 B24A331 (CH3)3C H CH3 CCl3 B24A332 (CH3)2CH H CH3 CCl3 B24A333 环丙基 H CH3 CCl3 B24A334 CH3(CH2)2 H CH3 CCl3 B24A335 CH3OCH2 H CH3 CCl3 B24A336 CH3O(CH2)2 H CH3 CCl3 B24A337 Ph H CH3 CCl3 B24A338 PhO H CH3 CCl3 B24A339 PhS H CH3 CCl3 B24A340 PhSO H CH3 CCl3 B24A341 PhSO2 H CH3 CCl3 B24A342 CH3S H CH3 CCl3 B24A343 CH3SO H CH3 CCl3 B24A344 CF3 H CH3 CCl3 B24A345 F2CH H CH3 CCl3 B24A346 HCC H CH3 CCl3 B24A347 CH3CC H CH3 CCl3 B24A348 CH2=CH H CH3 CCl3 B24A349 CH2=CHCH2 H CH3 CCl3 B24A350 CH3SO2N(CH3) H CH3 CCl3 B24A351 (CH3)2N H CH3 CCl3 B24A352 (CH3)2NSO2 H CH3 CCl3 B24A353 ClCH2 H CH3 CCl3 B24A354 CH3SCH2 H CH3 CCl3 B24A355 CH3SOCH2 H CH3 CCl3 B24化合物 R92 R93 R94 R95 Q3序号A356 CH3SO2CH2 H CH3 CCl3 B24A357 H H Ph CF3 B24A358 CH3 H Ph CF3 B24A359 CH3CH2 H Ph CF3 B24A360 环丙基 H Ph CF3 B24A361 (CH3)3C H Ph CF3 B24A362 (CH3)2CH H Ph CF3 B24A363 CH3(CH2)2 H Ph CF3 B24A364 CH3OCH2 H Ph CF3 B24A365 CH3O(CH2)2 H Ph CF3 B24A366 Ph H Ph CF3 B24A367 PhO H Ph CF3 B24A368 PhS H Ph CF3 B24A369 PhSO H Ph CF3 B24A370 PhSO2 H Ph CF3 B24A371 CH3S H Ph CF3 B24A372 CH3SO H Ph CF3 B24A373 CF3 H Ph CF3 B24A374 F2CH H Ph CF3 B24A375 HCC H Ph CF3 B24A376 CH3CC H Ph CF3 B24A377 CH2=CH H Ph CF3 B24A378 CH2=CHCH2 H Ph CF3 B24A379 CH3SO2N(CH3) H Ph CF3 B24A380 (CH3)2N H Ph CF3 B24A381 (CH3)2NSO2 H Ph CF3 B24A382 ClCH2 H Ph CF3 B24A383 CH3SCH2 H Ph CF3 B24A384 CH3SOCH2 H Ph CF3 B24A385 CH3SO2CH2 H Ph CF3 B24A386 H H Ph CF3CF2 B24A387 CH3 H Ph CF3CF2 B24化合物 R92 R93 R94 R95 Q3序号A388 CH3CH2 H Ph CF3CF2 B24A389 环丙基 H Ph CF3CF2 B24A390 (CH3)3C H Ph CF3CF2 B24A391 (CH3)2CH H Ph CF3CF2 B24A392 CH3(CH2)2 H Ph CF3CF2 B24A393 CH3OCH2 H Ph CF3CF2 B24A394 CH3O(CH2)2 H Ph CF3CF2 B24A395 Ph H Ph CF3CF2 B24A396 PhO H Ph CF3CF2 B24A397 PhS H Ph CF3CF2 B24A398 PhSO H Ph CF3CF2 B24A399 PhSO2 H Ph CF3CF2 B24A400 CH3S H Ph CF3CF2 B24A401 CH3SO H Ph CF3CF2 B24A402 CF3 H Ph CF3CF2 B24A403 F2CH H Ph CF3CF2 B24A404 HCC H Ph CF3CF2 B24A405 CH3CC H Ph CF3CF2 B24A406 CH2=CH H Ph CF3CF2 B24A407 CH2=CHCH2 H Ph CF3CF2 B24A408 CH3SO2N(CH3) H Ph CF3CF2 B24A409 (CH3)2N H Ph CF3CF2 B24A41O (CH3)2NSO2 H Ph CF3CF2 B24A411 ClCH2 H Ph CF3CF2 B24A412 CH3SCH2 H Ph CF3CF2 B24A413 CH3SOCH2 H Ph CF3CF2 B24A414 CH3SO2CH2 H Ph CF3CF2 B24A415 H H Ph CF3CF2CF2 B24A416 CH3 H Ph CF3CF2CF2 B24A417 CH3CH2 H Ph CF3CF2CF2 B24A418 环丙基 H Ph CF3CF2CF2 B24A419 (CH3)3C H Ph CF3CF2CF2 B24化合物 R92 R93 R94 R95 Q3序号A420 (CH3)2CH H Ph CF3CF2CF2 B24A421 CH3(CH2)2 H Ph CF3CF2CF2 B24A422 CH3OCH2 H Ph CF3CF2CF2 B24A423 CH3O(CH2)2 H Ph CF3CF2CF2 B24A424 Ph H Ph CF3CF2CF2 B24A425 PhO H Ph CF3CF2CF2 B24A426 PhS H Ph CF3CF2CF2 B24A427 PhSO H Ph CF3CF2CF2 B24A428 PhSO2 H Ph CF3CF2CF2 B24A429 CH3S H Ph CF3CF2CF2 B24A430 CH3SO H Ph CF3CF2CF2 B24A431 CF3 H Ph CF3CF2CF2 B24A432 F2CH H Ph CF3CF2CF2 B24A433 HCC H Ph CF3CF2CF2 B24A434 CH3CC H Ph CF3CF2CF2 B24A435 CH2=CH H Ph CF3CF2CF2 B24A436 CH2=CHCH2 H Ph CF3CF2CF2 B24A437 CH3SO2N(CH3) H Ph CF3CF2CF2 B24A438 (CH3)2N H Ph CF3CF2CF2 B24A439 (CH3)2NSO2 H Ph CF3CF2CF2 B24A440 ClCH2 H Ph CF3CF2CF2 B24A441 CH3SCH2 H Ph CF3CF2CF2 B24A442 CH3SOCH2 H Ph CF3CF2CF2 B24A443 CH3SO2CH2 H Ph CF3CF2CF2 B24A444 H H Ph CF2Cl B24A445 CH3 H Ph CF2Cl B24A446 CH3CH2 H Ph CF2Cl B24A447 环丙基 H Ph CF2Cl B24A448 (CH3)3C H Ph CF2Cl B24A449 (CH3)2CH H Ph CF2Cl B24A450 CH3(CH2)2 H Ph CF2Cl B24A451 CH3OCH2 H Ph CF2Cl B24化合物 R92 R93 R94 R95 Q3序号A452 CH3O(CH2)2 H Ph CF2Cl B24A453 Ph H Ph CF2Cl B24A454 PhO H Ph CF2Cl B24A455 PhS H Ph CF2Cl B24A456 PhSO H Ph CF2Cl B24A457 PhSO2 H Ph CF2Cl B24A458 CH3S H Ph CF2Cl B24A459 CH3SO H Ph CF2Cl B24A460 CF3 H Ph CF2Cl B24A461 F2CH H Ph CF2Cl B24A462 HCC H Ph CF2Cl B24A463 CH3CC H Ph CF2Cl B24A464 CH2=CH H Ph CF2Cl B24A465 CH2=CHCH2 H Ph CF2Cl B24A466 CH3SO2N(CH3) H Ph CF2Cl B24A467 (CH3)2N H Ph CF2Cl B24A468 (CH3)2NSO2 H Ph CF2Cl B24A469 ClCH2 H Ph CF2Cl B24A470 CH3SCH2 H Ph CF2Cl B24A471 CH3SOCH2 H Ph CF2Cl B24A472 CH3SO2CH2 H Ph CF2Cl B24A473 H H Ph CHF2 B24A474 CH3 H Ph CHF2 B24A475 CH3CH2 H Ph CHF2 B24A476 环丙基 H Ph CHF2 B24A477 (CH3)3C H Ph CHF2 B24A478 (CH3)2CH H Ph CHF2 B24A479 CH3(CH2)2 H Ph CHF2 B24A480 CH3OCH2 H Ph CHF2 B24A481 CH3O(CH2)2 H Ph CHF2 B24A482 Ph H Ph CHF2 B24A483 PhO H Ph CHF2 B24化合物 R92 R93 R94 R95 Q3序号A484 PhS H Ph CHF2 B24A485 PhSO H Ph CHF2 B24A486 PhSO2 H Ph CHF2 B24A487 CH3S H Ph CHF2 B24A488 CH3SO H Ph CHF2 B24A489 CF3 H Ph CHF2 B24A490 F2CH H Ph CHF2 B24A491 HCC H Ph CHF2 B24A492 CH3CC H Ph CHF2 B24A493 CH2=CH H Ph CHF2 B24A494 CH2=CHCH2 H Ph CHF2 B24A495 CH3SO2N(CH3) H Ph CHF2 B24A496 (CH3)2N H Ph CHF2 B24A497 (CH3)2NSO2 H Ph CHF2 B24A498 ClCH2 H Ph CHF2 B24A499 CH3SCH2 H Ph CHF2 B24A500 CH3SOCH2 H Ph CHF2 B24A501 CH3SO2CH2 H Ph CHF2 B24A502 H H Ph CCl3 B24A503 CH3 H Ph CCl3 B24A504 CH3CH2 H Ph CCl3 B24A505 环丙基 H Ph CCl3 B24A506 (CH3)3C H Ph CCl3 B24A507 (CH3)2CH H Ph CCl3 B24A508 CH3(CH2)2 H Ph CCl3 B24A509 CH3OCH2 H Ph CCl3 B24A510 CH3O(CH2)2 H Ph CCl3 B24A511 Ph H Ph CCl3 B24A512 PhO H Ph CCl3 B24A513 PhS H Ph CCl3 B24A514 PhSO H Ph CCl3 B24A515 PhSO2 H Ph CCl3 B24化合物 R92 R93 R94 R95 Q3序号A516 CH3S H Ph CCl3 B24A517 CH3SO H Ph CCl3 B24A518 CF3 H Ph CCl3 B24A519 F2CH H Ph CCl3 B24A520 HCC H Ph CCl3 B24A521 CH3CC H Ph CCl3 B24A522 CH2=CH H Ph CCl3 B24A523 CH2=CHCH2 H Ph CCl3 B24A524 CH3SO2N(CH3) H Ph CCl3 B24A525 (CH3)2N H Ph CCl3 B24A526 (CH3)2NSO2 H Ph CCl3 B24A527 ClCH2 H Ph CCl3 B24A528 CH3SCH2 H Ph CCl3 B24A529 CH3SOCH2 H Ph CCl3 B24A530 CH3SO2CH2 H Ph CCl3 B24A531 H CH3 H CF3 B24A532 H CH3CH2 H CF3 B24A533 H 环丙基 H CF3 B24A534 H (CH3)3CH H CF3 B24A535 H (CH3)2CH H CF3 B24A536 H CH3(CH2)2 H CF3 B24A537 H CH3OCH2 H CF3 B24A538 H CH3O(CH2)2 H CF3 B24A539 H Ph H CF3 B24A540 H PhO H CF3 B24A541 H PhS H CF3 B24A542 H PhSO H CF3 B24A543 H PhSO2 H CF3 B24A544 H CH3S H CF3 B24A545 H CH3SO H CF3 B24A546 H CF3 H CF3 B24A547 H F2CH H CF3 B24化合物 R92 R93 R94 R95 Q3序号A548 H HCC H CF3 B24A549 H CH3CC H CF3 B24A550 H CH2=CH H CF3 B24A551 H CH2=CHCH2 H CF3 B24A552 H CH3SO2N(CH3) H CF3 B24A553 H (CH3)2N H CF3 B24A554 H (CH3)2NSO2 H CF3 B24A555 H CH3SCH2 H CF3 B24A556 H CH3SOCH2 H CF3 B24A557 H CH3SO2CH2 H CF3 B24A558 H CH3 H CF3CF2 B24A559 H CH3CH2 H CF3CF2 B24A560 H 环丙基 H CF3CF2 B24A561 H (CH3)3C H CF3CF2 B24A562 H (CH3)2CH H CF3CF2 B24A563 H CH3(CH2)2 H CF3CF2 B24A564 H CH3OCH2 H CF3CF2 B24A565 H CH3O(CH2)2 H CF3CF2 B24A566 H Ph H CF3CF2 B24A567 H PhO H CF3CF2 B24A568 H PhS H CF3CF2 B24A569 H PhSO H CF3CF2 B24A570 H PhSO2 H CF3CF2 B24A571 H CH3S H CF3CF2 B24A572 H CH3SO H CF3CF2 B24A573 H CF3 H CF3CF2 B24A574 H F2CH H CF3CF2 B24A575 H HCC H CF3CF2 B24A576 H CH3CC H CF3CF2 B24A577 H CH2=CH H CF3CF2 B24A578 H CH2=CHCH2 H CF3CF2 B24A579 H CH3SO2N(CH3) H CF3CF2 B24化合物 R92 R93 R94 R95 Q3序号A580 H (CH3)2N H CF3CF2 B24A581 H (CH3)2NSO2 H CF3CF2 B24A582 H CH3SCH2 H CF3CF2 B24A583 H CH3SOCH2 H CF3CF2 B24A584 H CH3SO2CH2 H CF3CF2 B24A585 H CH3 H CF3CF2CF2 B24A586 H CH3CH2 H CF3CF2CF2 B24A587 H 环丙基 H CF3CF2CF2 B24A588 H (CH3)3C H CF3CF2CF2 B24A589 H (CH3)2CH H CF3CF2CF2 B24A590 H CH3(CH2)2 H CF3CF2CF2 B24A591 H CH3OCH2 H CF3CF2CF2 B24A592 H CH3O(CH2)2 H CF3CF2CF2 B24A593 H Ph H CF3CF2CF2 B24A594 H PhO H CF3CF2CF2 B24A595 H PhS H CF3CF2CF2 B24A596 H PhSO H CF3CF2CF2 B24A597 H PhSO2 H CF3CF2CF2 B24A598 H CH3S H CF3CF2CF2 B24A599 H CH3SO H CF3CF2CF2 B24A600 H CF3 H CF3CF2CF2 B24A601 H F2CH H CF3CF2CF2 B24A602 H HCC H CF3CF2CF2 B24A603 H CH3CC H CF3CF2CF2 B24A604 H CH2=CH H CF3CF2CF2 B24A605 H CH2=CHCH2 H CF3CF2CF2 B24A606 H CH3SO2N(CH3) H CF3CF2CF2 B24A607 H (CH3)2N H CF3CF2CF2 B24A608 H (CH3)2NSO2 H CF3CF2CF2 B24A609 H CH3SCH2 H CF3CF2CF2 B24A610 H CH3SOCH2 H CF3CF2CF2 B24A611 H CH3SO2CH2 H CF3CF2CF2 B24化合物 R92 R93 R94 R95 Q3序号A612 H CH3 H CF2Cl B24A613 H CH3CH2 H CF2Cl B24A614 H 环丙基 H CF2Cl B24A615 H (CH3)3C H CF2Cl B24A616 H (CH3)2CH H CF2Cl B24A617 H CH3(CH2)2 H CF2Cl B24A618 H CH3OCH2 H CF2Cl B24A619 H CH3O(CH2)2 H CF2Cl B24A620 H Ph H CF2Cl B24A621 H PhO H CF2Cl B24A622 H PhS H CF2Cl B24A623 H PhSO H CF2Cl B24A624 H PhSO2 H CF2Cl B24A625 H CH3S H CF2Cl B24A626 H CH3SO H CF2Cl B24A627 H CF3 H CF2Cl B24A628 H F2CH H CF2Cl B24A629 H HCC H CF2Cl B24A630 H CH3CC H CF2Cl B24A631 H CH2=CH H CF2Cl B24A632 H CH2=CHCH2 H CF2Cl B24A633 H CH3SO2N(CH3) H CF2Cl B24A634 H (CH3)2N H CF2Cl B24A635 H (CH3)2NSO2 H CF2Cl B24A636 H CH3SCH2 H CF2Cl B24A637 H CH3SOCH2 H CF2Cl B24A638 H CH3SO2CH2 H CF2Cl B24A639 H CH3 H CHF2 B24A640 H CH3CH2 H CHF2 B24A641 H 环丙基 H CHF2 B24A642 H (CH3)3C H CHF2 B24A643 H (CH3)2CH H CHF2 B24化合物 R92 R93 R94 R95 Q3序号A644 H CH3(CH2)2 H CHF2 B24A645 H CH3OCH2 H CHF2 B24A646 H CH3O(CH2)2 H CHF2 B24A647 H Ph H CHF2 B24A648 H PhO H CHF2 B24A649 H PhS H CHF2 B24A650 H PhSO H CHF2 B24A651 H PhSO2 H CHF2 B24A652 H CH3S H CHF2 B24A653 H CH3SO H CHF2 B24A654 H CF3 H CHF2 B24A655 H F2CH H CHF2 B24A656 H HCC H CHF2 B24A657 H CH3CC H CHF2 B24A658 H CH2=CH H CHF2 B24A659 H CH2=CHCH2 H CHF2 B24A660 H CH3SO2N(CH3) H CHF2 B24A661 H (CH3)2N H CHF2 B24A662 H (CH3)2NSO2 H CHF2 B24A663 H CH3SCH2 H CHF2 B24A664 H CH3SOCH2 H CHF2 B24A665 H CH3SO2CH2 H CHF2 B24A666 H CH3 H CCl3 B24A667 H CH3CH2 H CCl3 B24A668 H 环丙基 H CCl3 B24A669 H (CH3)3C H CCl3 B24A670 H (CH3)2CH H CCl3 B24A671 H CH3(CH2)2 H CCl3 B24A672 H CH3OCH2 H CCl3 B24A673 H CH3O(CH2)2 H CCl3 B24A674 H Ph H CCl3 B24A675 H PhO H CCl3 B24化合物 R92 R93 R94 R95 Q3序号A676 H PhS H CCl3 B24A677 H PhSO H CCl3 B24A678 H PhSO2 H CCl3 B24A679 H CH3S H CCl3 B24A680 H CH3SO H CCl3 B24A681 H CF3 H CCl3 B24A682 H F2CH H CCl3 B24A683 H HCC H CCl3 B24A684 H CH3CC H CCl3 B24A685 H CH2=CH H CCl3 B24A686 H CH2=CHCH2 H CCl3 B24A687 H CH3SO2N(CH3) H CCl3 B24A688 H (CH3)2N H CCl3 B24A689 H (CH3)2NSO2 H CCl3 B24A690 H CH3SCH2 H CCl3 B24A691 H CH3SOCH2 H CCl3 B24A692 H CH3SO2CH2 H CCl3 B24A693 H CH3 CH3 CF3 B24A694 H CH3CH2 CH3 CF3 B24A695 H 环丙基 CH3 CF3 B24A696 H (CH3)3C CH3 CF3 B24A697 H (CH3)2CH CH3 CF3 B24A698 H CH3(CH2)2 CH3 CF3 B24A699 H CH3OCH2 CH3 CF3 B24A700 H CH3O(CH2)2 CH3 CF3 B24A701 H Ph CH3 CF3 B24A702 H PhO CH3 CF3 B24A703 H PhS CH3 CF3 B24A704 H PhSO CH3 CF3 B24A705 H PhSO2 CH3 CF3 B24A706 H CH3S CH3 CF3 B24A707 H CH3SO CH3 CF3 B24化合物 R92 R93 R94 R95 Q3序号A708 H CF3 CH3 CF3 B24A709 H F2CH CH3 CF3 B24A710 H HCC CH3 CF3 B24A711 H CH3CC CH3 CF3 B24A712 H CH2=CH CH3 CF3 B24A713 H CH2=CHCH2 CH3 CF3 B24A714 H CH3SO2N(CH3) CH3 CF3 B24A715 H (CH3)2N CH3 CF3 B24A716 H (CH3)2NSO2 CH3 CF3 B24A717 H CH3SCH2 CH3 CF3 B24A718 H CH3SOCH2 CH3 CF3 B24A719 H CH3SO2CH2 CH3 CF3 B24A720 H CH3 CH3 CF3CF2 B24A721 H CH3CH2 CH3 CF3CF2 B24A722 H 环丙基 CH3 CF3CF2 B24A723 H (CH3)3C CH3 CF3CF2 B24A724 H (CH3)2CH CH3 CF3CF2 B24A725 H CH3(CH2)2 CH3 CF3CF2 B24A726 H CH3OCH2 CH3 CF3CF2 B24A727 H CH3O(CH2)2 CH3 CF3CF2 B24A728 H Ph CH3 CF3CF2 B24A729 H PhO CH3 CF3CF2 B24A730 H PhS CH3 CF3CF2 B24A731 H PhSO CH3 CF3CF2 B24A732 H PhSO2 CH3 CF3CF2 B24A733 H CH3S CH3 CF3CF2 B24A734 H CH3SO CH3 CF3CF2 B24A735 H CF3 CH3 CF3CF2 B24A736 H F2CH CH3 CF3CF2 B24A737 H HCC CH3 CF3CF2 B24A738 H CH3CC CH3 CF3CF2 B24A739 H CH2=CH CH3 CF3CF2 B24化合物 R92 R93 R94 R95 Q3序号A740 H CH2=CHCH2 CH3 CF3CF2 B24A741 H CH3SO2N(CH3) CH3 CF3CF2 B24A742 H (CH3)2N CH3 CF3CF2 B24A743 H (CH3)2NSO2 CH3 CF3CF2 B24A744 H CH3SCH2 CH3 CF3CF2 B24A745 H CH3SOCH2 CH3 CF3CF2 B24A746 H CH3SO2CH2 CH3 CF3CF2 B24A747 H CH3 CH3 CF3CF2CF2 B24A748 H CH3CH2 CH3 CF3CF2CF2 B24A749 H 环丙基 CH3 CF3CF2CF2 B24A750 H (CH3)3C CH3 CF3CF2CF2 B24A751 H (CH3)2CH CH3 CF3CF2CF2 B24A752 H CH3(CH2)2 CH3 CF3CF2CF2 B24A753 H CH3OCH2 CH3 CF3CF2CF2 B24A754 H CH3O(CH2)2 CH3 CF3CF2CF2 B24A755 H Ph CH3 CF3CF2CF2 B24A756 H PhO CH3 CF3CF2CF2 B24A757 H PhS CH3 CF3CF2CF2 B24A758 H PhSO CH3 CF3CF2CF2 B24A759 H PhSO2 CH3 CF3CF2CF2 B24A760 H CH3S CH3 CF3CF2CF2 B24A761 H CH3SO CH3 CF3CF2CF2 B24A762 H CF3 CH3 CF3CF2CF2 B24A763 H F2CH CH3 CF3CF2CF2 B24A764 H HCC CH3 CF3CF2CF2 B24A765 H CH3CC CH3 CF3CF2CF2 B24A766 H CH2=CH CH3 CF3CF2CF2 B24A767 H CH2=CHCH2 CH3 CF3CF2CF2 B24A768 H CH3SO2N(CH3) CH3 CF3CF2CF2 B24A769 H (CH3)2N CH3 CF3CF2CF2 B24A770 H (CH3)2NSO2 CH3 CF3CF2CF2 B24A771 H CH3SCH2 CH3 CF3CF2CF2 B24化合物 R92 R93 R94 R95 Q3序号A772 H CH3SOCH2 CH3 CF3CF2CF2 B24A773 H CH3SO2CH2 CH3 CF3CF2CF2 B24A774 H CH3 CH3 CF2Cl B24A775 H CH3CH2 CH3 CF2Cl B24A776 H 环丙基 CH3 CF2Cl B24A777 H (CH3)3C CH3 CF2Cl B24A778 H (CH3)2CH CH3 CF2Cl B24A779 H CH3(CH2)2 CH3 CF2Cl B24A780 H CH3OCH2 CH3 CF2Cl B24A781 H CH3O(CH2)2 CH3 CF2Cl B24A782 H Ph CH3 CF2Cl B24A783 H PhO CH3 CF2Cl B24A784 H PhS CH3 CF2Cl B24A785 H PhSO CH3 CF2Cl B24A786 H PhSO2 CH3 CF2Cl B24A787 H CH3S CH3 CF2Cl B24A788 H CH3SO CH3 CF2Cl B24A789 H CF3 CH3 CF2Cl B24A790 H F2CH CH3 CF2Cl B24A791 H HCC CH3 CF2Cl B24A792 H CH3CC CH3 CF2Cl B24A793 H CH2=CH CH3 CF2Cl B24A794 H CH2=CHCH2 CH3 CF2Cl B24A795 H CH3SO2N(CH3) CH3 CF2Cl B24A796 H (CH3)2N CH3 CF2Cl B24A797 H (CH3)2NSO2 CH3 CF2Cl B24A798 H CH3SCH2 CH3 CF2Cl B24A799 H CH3SOCH2 CH3 CF2Cl B24A800 H CH3SO2CH2 CH3 CF2Cl B24A801 H CH3 CH3 CHF2 B24A802 H CH3CH2 CH3 CHF2 B24A803 H 环丙基 CH3 CHF2 B24化合物 R92 R93 R94 R95 Q3序号A804 H (CH3)3C CH3 CHF2 B24A805 H (CH3)2CH CH3 CHF2 B24A806 H CH3(CH2)2 CH3 CHF2 B24A807 H CH3OCH2 CH3 CHF2 B24A808 H CH3O(CH2)2 CH3 CHF2 B24A809 H Ph CH3 CHF2 B24A810 H PhO CH3 CHF2 B24A811 H PhS CH3 CHF2 B24A812 H PhSO CH3 CHF2 B24A813 H PhSO2 CH3 CHF2 B24A814 H CH3S CH3 CHF2 B24A815 H CH3SO CH3 CHF2 B24A816 H CF3 CH3 CHF2 B24A817 H F2CH CH3 CHF2 B24A818 H HCC CH3 CHF2 B24A819 H CH3CC CH3 CHF2 B24A820 H CH2=CH CH3 CHF2 B24A821 H CH2=CHCH2 CH3 CHF2 B24A822 H CH3SO2N(CH3) CH3 CHF2 B24A823 H (CH3)2N CH3 CHF2 B24A824 H (CH3)2NSO2 CH3 CHF2 B24A825 H CH3SCH2 CH3 CHF2 B24A826 H CH3SOCH2 CH3 CHF2 B24A827 H CH3SO2CH2 CH3 CHF2 B24A828 H CH3 CH3 CCl3 B24A829 H CH3CH2 CH3 CCl3 B24A830 H 环丙基 CH3 CCl3 B24A831 H (CH3)3C CH3 CCl3 B24A832 H (CH3)2CH CH3 CCl3 B24A833 H CH3(CH2)2 CH3 CCl3 B24A834 H CH3OCH2 CH3 CCl3 B24A835 H CH3O(CH2)2 CH3 CCl3 B24化合物 R92 R93 R94 R95 Q3序号A836 H Ph CH3 CCl3 B24A837 H PhO CH3 CCl3 B24A838 H PhS CH3 CCl3 B24A839 H PhSO CH3 CCl3 B24A840 H PhSO2 CH3 CCl3 B24A841 H CH3S CH3 CCl3 B24A842 H CH3SO CH3 CCl3 B24A843 H CF3 CH3 CCl3 B24A844 H F2CH CH3 CCl3 B24A845 H HCC CH3 CCl3 B24A846 H CH3CC CH3 CCl3 B24A847 H CH2=CH CH3 CCl3 B24A848 H CH2=CHCH2 CH3 CCl3 B24A849 H CH3SO2N(CH3) CH3 CCl3 B24A850 H (CH3)2N CH3 CCl3 B24A851 H (CH3)2NSO2 CH3 CCl3 B24A852 H CH3SCH2 CH3 CCl3 B24A853 H CH3SOCH2 CH3 CCl3 B24A854 H CH3SO2CH2 CH3 CCl3 B24A855 H CH3 Ph CF3 B24A856 H CH3CH2 Ph CF3 B24A857 H (CH3)2CH Ph CF3 B24A858 H (CH3)2CH Ph CF3 B24A859 H 环丙基 Ph CF3 B24A860 H CH3(CH2)2 Ph CF3 B24A861 H CH3OCH2 Ph CF3 B24A862 H CH3O(CH2)2 Ph CF3 B24A863 H Ph Ph CF3 B24A864 H PhO Ph CF3 B24A865 H PhS Ph CF3 B24A866 H PhSO Ph CF3 B24A867 H PhSO2 Ph CF3 B24化合物 R92 R93 R94 R95 Q3序号A868 H CH3S Ph CF3 B24A869 H CH3SO Ph CF3 B24A870 H CF3 Ph CF3 B24A871 H F2CH Ph CF3 B24A872 H HCC Ph CF3 B24A873 H CH3CC Ph CF3 B24A874 H CH2=CH Ph CF3 B24A875 H CH2=CHCH2 Ph CF3 B24A876 H CH3SO2N(CH3) Ph CF3 B24A877 H (CH3)2N Ph CF3 B24A878 H (CH3)2NSO2 Ph CF3 B24A879 H CH3SCH2 Ph CF3 B24A880 H CH3SOCH2 Ph CF3 B24A881 H CH3SO2CH2 Ph CF3 B24A882 H CH3 Ph CF3CF2 B24A883 H CH3CH2 Ph CF3CF2 B24A884 H 环丙基 Ph CF3CF2 B24A885 H (CH3)3C Ph CF3CF2 B24A886 H (CH3)2CH Ph CF3CF2 B24A887 H CH3(CH2)2 Ph CF3CF2 B24A888 H CH3OCH2 Ph CF3CF2 B24A889 H CH3O(CH2)2 Ph CF3CF2 B24A890 H Ph Ph CF3CF2 B24A891 H PhO Ph CF3CF2 B24A892 H PhS Ph CF3CF2 B24A893 H PhSO Ph CF3CF2 B24A894 H PhSO2 Ph CF3CF2 B24A895 H CH3S Ph CF3CF2 B24A896 H CH3SO Ph CF3CF2 B24A897 H CF3 Ph CF3CF2 B24A898 H F2CH Ph CF3CF2 B24A899 H HCC Ph CF3CF2 B24化合物 R92 R93 R94 R95 Q3序号A900 H CH3CC Ph CF3CF2 B24A901 H CH2=CH Ph CF3CF2 B24A902 H CH2=CHCH2 Ph CF3CF2 B24A903 H CH3SO2N(CH3) Ph CF3CF2 B24A904 H (CH3)2N Ph CF3CF2 B24A905 H (CH3)2NSO2 Ph CF3CF2 B24A906 H CH3SCH2 Ph CF3CF2 B24A907 H CH3SOCH2 Ph CF3CF2 B24A908 H CH3SO2CH2 Ph CF3CF2 B24A909 H CH3 Ph CF3CF2CF2 B24A910 H CH3CH2 Ph CF3CF2CF2 B24A911 H 环丙基 Ph CF3CF2CF2 B24A912 H (CH3)3C Ph CF3CF2CF2 B24A913 H (CH3)2CH Ph CF3CF2CF2 B24A914 H CH3(CH2)2 Ph CF3CF2CF2 B24A915 H CH3OCH2 Ph CF3CF2CF2 B24A916 H CH3O(CH2)2 Ph CF3CF2CF2 B24A917 H Ph Ph CF3CF2CF2 B24A918 H PhO Ph CF3CF2CF2 B24A919 H PhS Ph CF3CF2CF2 B24A920 H PhSO Ph CF3CF2CF2 B24A921 H PhSO2 Ph CF3CF2CF2 B24A922 H CH3S Ph CF3CF2CF2 B24A923 H CH3SO Ph CF3CF2CF2 B24A924 H CF3 Ph CF3CF2CF2 B24A925 H F2CH Ph CF3CF2CF2 B24A926 H HCC Ph CF3CF2CF2 B24A927 H CH3CC Ph CF3CF2CF2 B24A928 H CH2=CH Ph CF3CF2CF2 B24A929 H CH2=CHCH2 Ph CF3CF2CF2 B24A930 H CH3SO2N(CH3) Ph CF3CF2CF2 B24A931 H (CH3)2N Ph CF3CF2CF2 B24化合物 R92 R93 R94 R95 Q3序号A932 H (CH3)2NSO2 Ph CF3CF2CF2 B24A933 H CH3SCH2 Ph CF3CF2CF2 B24A934 H CH3SOCH2 Ph CF3CF2CF2 B24A935 H CH3SO2CH2 Ph CF3CF2CF2 B24A936 H CH3 Ph CF2Cl B24A937 H CH3CH2 Ph CF2Cl B24A938 H 环丙基 Ph CF2Cl B24A939 H (CH3)3C Ph CF2Cl B24A940 H (CH3)2CH Ph CF2Cl B24A941 H CH3(CH2)2 Ph CF2Cl B24A942 H CH3OCH2 Ph CF2Cl B24A943 H CH3O(CH2)2 Ph CF2Cl B24A944 H Ph Ph CF2Cl B24A945 H PhO Ph CF2Cl B24A946 H PhS Ph CF2Cl B24A947 H PhSO Ph CF2Cl B24A948 H PhSO2 Ph CF2Cl B24A949 H CH3S Ph CF2Cl B24A950 H CH3SO Ph CF2Cl B24A951 H CF3 Ph CF2Cl B24A952 H F2CH Ph CF2Cl B24A953 H HCC Ph CF2Cl B24A954 H CH3CC Ph CF2Cl B24A955 H CH2=CH Ph CF2Cl B24A956 H CH2=CHCH2 Ph CF2Cl B24A957 H CH3SO2N(CH3) Ph CF2Cl B24A958 H (CH3)2N Ph CF2Cl B24A959 H (CH3)2NSO2 Ph CF2Cl B24A960 H CH3SCH2 Ph CF2Cl B24A961 H CH3SOCH2 Ph CF2Cl B24A962 H CH3SO2CH2 Ph CF2Cl B24A963 H CH3 Ph CHF2 B24化合物 R92 R93 R94 R95 Q3序号A964 H CH3CH2 Ph CHF2 B24A965 H (CH3)3C Ph CHF2 B24A966 H (CH3)2CH Ph CHF2 B24A967 H 环丙基 Ph CHF2 B24A968 H CH3(CH2)2 Ph CHF2 B24A969 H CH3OCH2 Ph CHF2 B24A970 H CH3O(CH2)2 Ph CHF2 B24A971 H Ph Ph CHF2 B24A972 H PhO Ph CHF2 B24A973 H PhS Ph CHF2 B24A974 H PhSO Ph CHF2 B24A975 H PhSO2 Ph CHF2 B24A976 H CH3S Ph CHF2 B24A977 H CH3SO Ph CHF2 B24A978 H CF3 Ph CHF2 B24A979 H F2CH Ph CHF2 B24A980 H HCC Ph CHF2 B24A981 H CH3CC Ph CHF2 B24A982 H CH2=CH Ph CHF2 B24A983 H CH2=CHCH2 Ph CHF2 B24A984 H CH3SO2N(CH3) Ph CHF2 B24A985 H (CH3)2N Ph CHF2 B24A986 H (CH3)2NSO2 Ph CHF2 B24A987 H CH3SCH2 Ph CHF2 B24A988 H CH3SOCH2 Ph CHF2 B24A989 H CH3SO2CH2 Ph CHF2 B24A990 H CH3 Ph CCl3 B24A991 H CH3CH2 Ph CCl3 B24A992 H (CH3)3C Ph CCl3 B24A993 H (CH3)2CH Ph CCl3 B24A994 H 环丙基 Ph CCl3 B24A995 H CH3(CH2)2 Ph CCl3 B24化合物 R92 R93 R94 R95 Q3序号A996 H CH3OCH2 Ph CCl3 B24A997 H CH3O(CH2)2 Ph CCl3 B24A998 H Ph Ph CCl3 B24A999 H PhO Ph CCl3 B24A1000 H PhS Ph CCl3 B24A1001 H PhSO Ph CCl3 B24A1002 H PhSO2 Ph CCl3 B24A1003 H CH3S Ph CCl3 B24A1004 H CH3SO Ph CCl3 B24A1005 H CF3 Ph CCl3 B24A1006 H F2CH Ph CCl3 B24A1007 H HCC Ph CCl3 B24A1008 H CH3CC Ph CCl3 B24A1009 H CH2=CH Ph CCl3 B24A1010 H CH2=CHCH2 Ph CCl3 B24A1011 H CH3SO2N(CH3) Ph CCl3 B24A1012 H (CH3)2N Ph CCl3 B24A1013 H (CH3)2NSO2 Ph CCl3 B24A1014 H CH3SCH2 Ph CCl3 B24A1015 H CH3SOCH2 Ph CCl3 B24A1016 H CH3SO2CH2 Ph CCl3 B24A1017 F H H CF3 B24A1018 Cl H H CF3 B24A1019 Br H H CF3 B24A1020 CN H H CF3 B24A1021 CH3SO2O H H CF3 B24A1022 CH3O H H CF3 B24A1023 CH2CH3O H H CF3 B24A1024 CH2CH=CH2O H H CF3 B24A1025 HCCCH2O H H CF3 B24A1026 S-苄基 H H CF3 B24A1027 SO2-苄基 H H CF3 B24化合物 R92 R93 R94 R95 Q3序号A1028 ClCH2 H H CF3 B24A1029 BrCH2 H H CF3 B24A1030 FCH2 H H CF3 B24A1031 CHF2CH2 H H CF3 B24A1032 CF3CH2 H H CF3 B24A1033 三唑基甲基 H H CF3 B24A1034 CHCl2CH2 H H CF3 B24A1035 ClCH=CH H H CF3 B24A1036 Cl2C=CH H H CF3 B24A1037 CF3CH=CH H H CF3 B24A1038 ClCC H H CF3 B24A1039 Ph H H CF3 B24A1040 CH3 CH3 H CF3 B24A1041 CH3 OH H CF3 B24A1042 CH3 F H CF3 B24A1043 CH3 Cl H CF3 B24A1044 F CH3 H CF3 B24A1045 Cl CH3 H CF3 B24A1046 H F H CF3 B24A1047 H Cl H CF3 B24A1048 H Br H CF3 B24A1049 H OH H CF3 B24A1050 H OCH3 H CF3 B24A1051 H OCHF2 H CF3 B24A1052 H OSO2CH3 H CF3 B24A1053 H OSO2CF3 H CF3 B24A1054 H ClCH2 H CF3 B24A1055 H BrCH2 H CF3 B24A1056 H FCH2 H CF3 B24A1057 H CHF2CH2 H CF3 B24A1058 H CF3CH2 H CF3 B24A1059 H 三唑基甲基 H CF3 B24化合物 R92 R93 R94 R95 Q3序号A1060 H CHCl2CH2 H CF3 B24A1061 H ClCH=CH H CF3 B24A1062 H Cl2C=CH H CF3 B24A1063 H CF3CH=CH H CF3 B24A1064 H ClCC H CF3 B24A1065 H CH3C(O) H CF3 B24A1066 H 苯基 H CF3 B24A1067 H SO2CH3 H CF3 B24A1068 H SO2CF3 H CF3 B24A1069 H CN H CF3 B24A1070 H NO2 H CF3 B24A1071 CH3 H F CF3 B24A1072 CH3 H Cl CF3 B24A1073 CH3 H Br CF3 B24A1074 CH3 H CN CF3 B24A1075 CH3 H CH3O CF3 B24A1076 CH3 H CH3S CF3 B24A1077 CH3 H CH3SO CF3 B24A1078 CH3 H CH3SO2 CF3 B24表9a:式Ig化合物: Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36B37 B38 B39 B40 B41 B42 B43 B44 B45 B46 B47 B48Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B49 B50 B51 B52 B53 B54 B55 B56 B57 B58 B59 B60B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B95 B96B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108B109 B110 B111 B112 B113 B114 B115 B116 B117 B118 B119 B120B121 B122 B123 B124 B125 B126 B127 B128 B129 B130 B131 B132B133 B134 B135 B136 B137 B138 B139 B140 B141 B142 B143 B144B145 B146 B147 B148 B149 B150 B151 B152 B153 B154 B155 B156B157 B158 B159 B160 B161 B162 B163 B164 B165 B166 B167 B168B169 B170 B171 B172 B173 B174 B175 B176 B177 B178 B179 B180B181 B182 B183 B184 B185 B186 B187 B188 B189 B190 B191 B192B193 B194 B195 B196 B197 B198 B199 B200 B201 B202 B203 B204B205 B206 B207 B208 B209 B210 B211 B212 B213 B214 B215 B216B217 B218 B219 B220 B221 B222 B223 B224 B225 B226 B227 B228B229 B230 B231 B232 B233 B234 B235 B236 B237 B238 B239 B240B241 B242 B243 B244 B245 B246 B247 B248 B249 B250 B251 B252B253 B254 B255 B256 B257 B258 B259 B260 B261 B262 B263 B264B265 B266 B267 B268 B269 B270 B271 B272 B273 B274 B275 B276B277 B278 B279 B280 B281 B282 B283 B284 B285 B286 B287 B288B289 B290 B291 B292 B293 B294 B295 B296 B297 B298 B299 B300B301 B302 B303 B304 B305 B306 B307 B308 B309 B310 B311 B312B313 B314 B315 B316 B317 B318 B319 B320 B321 B322 B323 B324B325 B326 B327 B328 B329 B330 B331 B332 B333 B334 B335 B336B337 B338 B339 B340 B341 B342 B343 B344 B345 B346 B347 B348B349 B350 B351 B352 B353 B354 B355 B356 B357 B358 B359 B360B361 B362 B363 B364 B365 B366 B367 B368 B369 B370 B371 B372B373 B374 B375 B376 B377 B378 B379 B380 B381 B382 B383 B384B385 B386 B387 B388 B389 B390 B391 B392 B393 B394 B395 B396B397 B398 B399 B400 B401 B402 B403 B404 B405 B406 B407 B408B409 B410 B411 B412 B413 B414 B415 B416 B417 B418 B419 B420B421 B422 B423 B424 B425 B426 B427 B428 B429 B430 B431 B432B433 B434 B435 B436 B437 B438 B439 B440 B441 B442 B443 B444Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B445 B446 B447 B448 B449 B450 B451 B452 B453 B454 B455 B456B457 B458 B459 B460 B461 B462 B463 B464 B465 B466 B467 B468B469 B470 B471 B472 B473 B474 B475 B476 B477 B478 B479 B480B481 B482 B483 B484 B485 B486 B487 B488 B489 B490 B491 B492B493 B494 B495 B496 B497 B498 B499 B500 B501 B502 B503 B504B505 B506 B507 B508 B509 B510 B511 B512 B513 B514 B515 E516B517 B518 B519 B520 B521 B522 B523 B524 B525 B526 B527 B528B529 B530 B531 B532 B533 B534 B535 B536 B537 B538 B539 B540B541 B542 B543 B544 B545 B546 B547 B548 B549 B550 B551 B552B553 B554 B555 B556 B557 B558 B559 B560 B561 B562 B563 B564B565 B566 B567 B568 B569 B570 B571 B572 B573 B574 B575 B576B577 B578 B579 B580 B581 B582 B583 B584 B585 B586 B587 B588B589 B590 B591 B592 B593 B594 B595 B596 B597 B598 B599 B600B601 B602 B603 B604 B605 B606 B607 B608 B609 B610 B611 B612B613 B614 B615 B616 B617 B618 B619 B620 B621 B622 B623 B624B625 B626 B627 B628 B629 B630 B631 B632 B633 B634 B635 B636B637 B638 B639 B640 B641 B642 B643 B644 B645 B646 B647 B648B649 B650 B651 B652 B653 B654 B655 B656 B657 B658 B659 B660B661 B662 B663 B664 B665 B666 B667 B668 B669 B670 B671 B672B773 B774 B775 B776 B777 B778 B779 B780 B781 B782 B783 B784B785 B786 B787 B788 B789 B790 B791 B792 B793 B794 B795 B796B797 B798 B799 B800 B801 B802 B803 B804 B805 B806 B807 B808B809 B810 B811 B812 B813 B814 B815 B816 B817 B818 B819 B820B821 B822 B823 B824 B825 B826 B827 B828 B829 B830 B831 B832B833 B834 B835 B836 B837 B838 B839 B840 B841 B842 B843 B844B845 B846 B847 B848 B849 B850 B851 B852 B853 B854 B855 B856B857 B858 B859 B860 B861 B862 B863 B864 B865 B866 B867 B868B869 B870 B871 B872 B873 B874 B875 B876 B877 B878 B879 B880B881 B882 B883 B884 B885 B886 B887 B888 B889 B890 B891 B892B893 B894 B895 B896 B897 B898 B899 B900 B901 B902 B903 B904B905 B906 B907 B908 B909 B910 B911 B912 B913 B914 B915 B916B917 B918 B919 B920 B921 B922 B923 B924 B925 B926 B927 B928B929 B930 B931 B932 B933 B934 B935 B936 B937 B938 B939 B940Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B941 B942 B943 B944 B945 B946 B947 B948 B949 B950 B951 B952B953 B954 B955 B956 B957 B958 B959 B960 B961 B962 B963 B964B965 B966 B967 B968 B969 B970 B971 B972 B973 B974 B975 B976B977 B978 B979 B980 B981 B982 B983 B984 B985 B986 B987 B988B989 B990 B991 B992 B993 B994 B995 B996 B997 B998 B999 B1000B1001 B1002 B1003 B1004 B1005 B1006 B1007 B1008 B1009 B1010 B1011 B1012B1013 B1014 B1015 B1016 B1017 B1018 B1019 B1020 B1021 B1022 B1023 B1024B1025 B1026 B1027 B1028 B1029 B1030 B1031 B1032 B1033 B1034 B1035 B1036B1037 B1038 B1039 B1040 B1041 B1042 B1043 B1044 B1045 B1046 B1047 B1048B1049 B1050 B1051 B1052 B1053 B1054 B1055 B1056 B1057 B1058 B1059 B1060B1061 B1062 B1063 B1064 B1065 B1066 B1067 B1068 B1069 B1070 B1071 B1072B1073 B1074 B1075 B1076 B1077 B1078 B1079 B1080 B1081 B1082 B1083表10:式Ih化合物: Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36B37 B38 B39 B40 B41 B42 B43 B44 B45 B46 B47 B48B49 B50 B51 B52 B53 B54 B55 B56 B57 B58 B59 B60B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B95 B96B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108B109 B110 B111 B112 B113 B114 B115 B116 B117 B118 B119 B120B121 B122 B123 B124 B125 B126 B127 B128 B129 B130 B131 B132B133 B134 B135 B136 B137 B138 B139 B140 B141 B142 B143 B144Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B145 B146 B147 B148 B149 B150 B151 B152 B153 B154 B155 B156B157 B158 B159 B160 B161 B162 B163 B164 B165 B166 B167 B168B169 B170 B171 B172 B173 B174 B175 B176 B177 B178 B179 B180B181 B182 B183 B184 B185 B186 B187 B188 B189 B190 B191 B192B193 B194 B195 B196 B197 B198 B199 B200 B201 B202 B203 B204B205 B206 B207 B208 B209 B210 B211 B212 B213 B214 B215 B216B217 B218 B219 B220 B221 B222 B223 B224 B225 B226 B227 B228B229 B230 B231 B232 B233 B234 B235 B236 B237 B238 B239 B240B241 B242 B243 B244 B245 B246 B247 B248 B249 B250 B251 B252B253 B254 B255 B256 B257 B258 B259 B260 B261 B262 B263 B264B265 B266 B267 B268 B269 B270 B271 B272 B273 B274 B275 B276B277 B278 B279 B280 B281 B282 B283 B284 B285 B286 B287 B288B289 B290 B291 B292 B293 B294 B295 B296 B297 B298 B299 B300B301 B302 B303 B304 B305 B306 B307 B308 B309 B310 B311 B312B313 B314 B315 B316 B317 B318 B319 B320 B321 B322 B323 B324B325 B326 B327 B328 B329 B330 B331 B332 B333 B334 B335 B336B337 B338 B339 B340 B341 B342 B343 B344 B345 B346 B347 B348B349 B350 B351 B352 B353 B354 B355 B356 B357 B358 B359 B360B361 B362 B363 B364 B365 B366 B367 B368 B369 B370 B371 B372B373 B374 B375 B376 B377 B378 B379 B380 B381 B382 B383 B384B385 B386 B387 B388 B389 B390 B391 B392 B393 B394 B395 B396B397 B398 B399 B400 B401 B402 B403 B404 B405 B406 B407 B408B409 B410 B411 B412 B413 B414 B415 B416 B417 B418 B419 B420B421 B422 B423 B424 B425 B426 B427 B428 B429 B430 B431 B432B433 B434 B435 B436 B437 B438 B439 B440 B441 B442 B443 B444B445 B446 B447 B448 B449 B450 B451 B452 B453 B454 B455 B456B457 B458 B459 B460 B461 B462 B463 B464 B465 B466 B467 B468B469 B470 B471 B472 B473 B474 B475 B476 B477 B478 B479 B480B481 B482 B483 B484 B485 B486 B487 B488 B489 B490 B491 B492B493 B494 B495 B496 B497 B498 B499 B500 B501 B502 B503 B504B505 B506 B507 B508 B509 B510 B511 B512 B513 B514 B515 B516B517 B518 B519 B520 B521 B522 B523 B524 B525 B526 B527 B528B529 B530 B531 B532 B533 B534 B535 B536 B537 B538 B539 B540Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B541 B542 B543 B544 B545 B546 B547 B548 B549 B550 B551 B552B553 B554 B555 B556 B557 B558 B559 B560 B561 B562 B563 B564B565 B566 B567 B568 B569 B570 B571 B572 B573 B574 B575 B576B577 B578 B579 B580 B581 B582 B583 B584 B585 B586 B587 B588B589 B590 B591 B592 B593 B594 B595 B596 B597 B598 B599 B600B601 B602 B603 B604 B605 B606 B607 B608 B609 B610 B611 B612B613 B614 B615 B616 B617 B618 B619 B620 B621 B622 B623 B624B625 B626 B627 B628 B629 B630 B631 B632 B633 B634 B635 B636B637 B638 B639 B640 B641 B642 B643 B644 B645 B646 B647 B648B649 B650 B651 B652 B653 B654 B655 B656 B657 B658 B659 B660B661 B662 B663 B664 B665 B666 B667 B668 B669 B670 B671 B672B773 B774 B775 B776 B777 B778 B779 B780 B781 B782 B783 B784B785 B786 B787 B788 B789 B790 B791 B792 B793 B794 B795 B796B797 B798 B799 B800 B801 B802 B803 B804 B805 B806 B807 B808B809 B810 B811 B812 B813 B814 B815 B816 B817 B818 B819 B820B821 B822 B823 B824 B825 B826 B827 B828 B829 B830 B831 B832B833 B834 B835 B836 B837 B838 B839 B840 B841 B842 B843 B844B845 B846 B847 B848 B849 B850 B851 B852 B853 B854 B855 B856B857 B858 B859 B860 B861 B862 B863 B864 B865 B866 B867 B868B869 B870 B871 B872 B873 B874 B875 B876 B877 B878 B879 B880B881 B882 B883 B884 B885 B886 B887 B888 B889 B890 B891 B892B893 B894 B895 B896 B897 B898 B899 B900 B901 B902 B903 B904B905 B906 B907 B908 B909 B910 B911 B912 B913 B914 B915 B916B917 B918 B919 B920 B921 B922 B923 B924 B925 B926 B927 B928B929 B930 B931 B932 B933 B934 B935 B936 B937 B938 B939 B940B941 B942 B943 B944 B945 B946 B947 B948 B949 B950 B951 B952B953 B954 B955 B956 B957 B958 B959 B960 B961 B962 B963 B964B965 B966 B967 B968 B969 B970 B971 B972 B973 B974 B975 B976B977 B978 B979 B980 B981 B982 B983 B984 B985 B986 B987 B988B989 B990 B991 B992 B993 B994 B995 B996 B997 B998 B999 B1000B1001 B1002 B1003 B1004 B1005 B1006 B1007 B1008 B1009 B1010 B1011 B1012B1013 B1014 B1015 B1016 B1017 B1018 B1019 B1020 B1021 B1022 B1023 B1024B1025 B1026 B1027 B1028 B1029 B1030 B1031 B1032 B1033 B1034 B1035 B1036Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B1037 B1038 B1039 B1040 B1041 B1042 B1043 B1044 B1045 B1046 B1047 B1048B1049 B1050 B1051 B1052 B1053 B1054 B1055 B1056 B1057 B1058 B1059 B1060B1061 B1062 B1063 B1064 B1065 B1066 B1067 B1068 B1069 B1070 B1071 B1072B1073 B1074 B1075 B1076 B1077 B1078 B1079 B1080 B1081 B1082 B1083表11:式Ik化合物: Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36B37 B38 B39 B40 B41 B42 B43 B44 B45 B46 B47 B48B49 B50 B51 B52 B53 B54 B55 B56 B57 B58 B59 B60B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B95 B96B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108B109 B110 B111 B112 B113 B114 B115 B116 B117 B118 B119 B120B121 B122 B123 B124 B125 B126 B127 B128 B129 B130 B131 B132B133 B134 B135 B136 B137 B138 B139 B140 B141 B142 B143 B144B145 B146 B147 B148 B149 B150 B151 B152 B153 B154 B155 B156B157 B158 B159 B160 B161 B162 B163 B164 B165 B166 B167 B168B169 B170 B171 B172 B173 B174 B175 B176 B177 B178 B179 B180B181 B182 B183 B184 B185 B186 B187 B188 B189 B190 B191 B192B193 B194 B195 B196 B197 B198 B199 B200 B201 B202 B203 B204B205 B206 B207 B208 B209 B210 B211 B212 B213 B214 B215 B216B217 B218 B219 B220 B221 B222 B223 B224 B225 B226 B227 B228B229 B230 B231 B232 B233 B234 B235 B236 B237 B238 B239 B240Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B241 B242 B243 B244 B245 B246 B247 B248 B249 B250 B251 B252B253 B254 B255 B256 B257 B258 B259 B260 B261 B262 B263 B264B265 B266 B267 B268 B269 B270 B271 B272 B273 B274 B275 B276B277 B278 B279 B280 B281 B282 B283 B284 B285 B286 B287 B288B289 B290 B291 B292 B293 B294 B295 B296 B297 B298 B299 B300B301 B302 B303 B304 B305 B306 B307 B308 B309 B310 B311 B312B313 B314 B315 B316 B317 B318 B319 B320 B321 B322 B323 B324B325 B326 B327 B328 B329 B330 B331 B332 B333 B334 B335 B336B337 B338 B339 B340 B341 B342 B343 B344 B345 B346 B347 B348B349 B350 B351 B352 B353 B354 B355 B356 B357 B358 B359 B360B361 B362 B363 B364 B365 B366 B367 B368 B369 B370 B371 B372B373 B374 B375 B376 B377 B378 B379 B380 B381 B382 B383 B384B385 B386 B387 B388 B389 B390 B391 B392 B393 B394 B395 B396B397 B398 B399 B400 B401 B402 B403 B404 B405 B406 B407 B408B409 B410 B411 B412 B413 B414 B415 B416 B417 B418 B419 B420B421 B422 B423 B424 B425 B426 B427 B428 B429 B430 B431 B432B433 B434 B435 B436 B437 B438 B439 B440 B441 B442 B443 B444B445 B446 B447 B448 B449 B450 B451 B452 B453 B454 B455 B456B457 B458 B459 B460 B461 B462 B463 B464 B465 B466 B467 B468B469 B470 B471 B472 B473 B474 B475 B476 B477 B478 B479 B480B481 B482 B483 B484 B485 B486 B487 B488 B489 B490 B491 B492B493 B494 B495 B496 B497 B498 B499 B500 B501 B502 B503 B504B505 B506 B507 B508 B509 B510 B511 B512 B513 B514 B515 B516B517 B518 B519 B520 B521 B522 B523 B524 B525 B526 B527 B528B529 B530 B531 B532 B533 B534 B535 B536 B537 B538 B539 B540B541 B542 B543 B544 B545 B546 B547 B548 B549 B550 B551 B552B553 B554 B555 B556 B557 B558 B559 B560 B561 B562 B563 B564B565 B566 B567 B568 B569 B570 B571 B572 B573 B574 B575 B576B577 B578 B579 B580 B581 B582 B583 B584 B585 B586 B587 B588B589 B590 B591 B592 B593 B594 B595 B596 B597 B598 B599 B600B601 B602 B603 B604 B605 B606 B607 B608 B609 B610 B611 B612B613 B614 B615 B616 B617 B618 B619 B620 B621 B622 B623 B624B625 B626 B627 B628 B629 B630 B631 B632 B633 B634 B635 B636Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B637 B638 B639 B640 B641 B642 B643 B644 B645 B646 B647 B648B649 B650 B651 B652 B653 B654 B655 B656 B657 B658 B659 B660B661 B662 B663 B664 B665 B666 B667 B668 B669 B670 B671 B672B773 B774 B775 B776 B777 B778 B779 B780 B781 B782 B783 B784B785 B786 B787 B788 B789 B790 B791 B792 B793 B794 B795 B796B797 B798 B799 B800 B801 B802 B803 B804 B805 B806 B807 B808B809 B810 B811 B812 B813 B814 B815 B816 B817 B818 B819 B820B821 B822 B823 B824 B825 B826 B827 B828 B829 B830 B831 B832B833 B834 B835 B836 B837 B838 B839 B840 B841 B842 B843 B844B845 B846 B847 B848 B849 B850 B851 B852 B853 B854 B855 B856B857 B858 B859 B860 B861 B862 B863 B864 B865 B866 B867 B868B869 B870 B871 B872 B873 B874 B875 B876 B877 B878 B879 B880B881 B882 B883 B884 B885 B886 B887 B888 B889 B890 B891 B892B893 B894 B895 B896 B897 B898 B899 B900 B901 B902 B903 B904B905 B906 B907 B908 B909 B910 B911 B912 B913 B914 B915 B916B917 B918 B919 B920 B921 B922 B923 B924 B925 B926 B927 B928B929 B930 B931 B932 B933 B934 B935 B936 B937 B938 B939 B940B941 B942 B943 B944 B945 B946 B947 B948 B949 B950 B951 B952B953 B954 B955 B956 B957 B958 B959 B960 B961 B962 B963 B964B965 B966 B967 B968 B969 B970 B971 B972 B973 B974 B975 B976B977 B978 B979 B980 B981 B982 B983 B984 B985 B986 B987 B988B989 B990 B991 B992 B993 B994 B995 B996 B997 B998 B999 B1000B1001 B1002 B1003 B1004 B1005 B1006 B1007 B1008 B1009 B1010 B1011 B1012B1013 B1014 B1015 B1016 B1017 B1018 B1019 B1020 B1021 B1022 B1023 B1024B1025 B1026 B1027 B1028 B1029 B1030 B1031 B1032 B1033 B1034 B1035 B1036B1037 B1038 B1039 B1040 B1041 B1042 B1043 B1044 B1045 B1046 B1047 B1048B1049 B1050 B1051 B1052 B1053 B1054 B1055 B1056 B1057 B1058 B1059 B1060B1061 B1062 B1063 B1064 B1065 B1066 B1067 B1068 B1069 B1070 B1071 B1072B1073 B1074 B1075 B1076 B1077 B1078 B1079 B1080 B1081 B1082 B1083表12:式Im化合物: Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36B37 B38 B39 B40 B41 B42 B43 B44 B45 B46 B47 B48B49 B50 B51 B52 B53 B54 B55 B56 B57 B58 B59 B60B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B95 B96B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108B109 B110 B111 B112 B113 B114 B115 B116 B117 B118 B119 B120B121 B122 B123 B124 B125 B126 B127 B128 B129 B130 B131 B132B133 B134 B135 B136 B137 B138 B139 B140 B141 B142 B143 B144B145 B146 B147 B148 B149 B150 B151 B152 B153 B154 B155 B156B157 B158 B159 B160 B161 B162 B163 B164 B165 B166 B167 B168B169 B170 B171 B172 B173 B174 B175 B176 B177 B178 B179 B180B181 B182 B183 B184 B185 B186 B187 B188 B189 B190 B191 B192B193 B194 B195 B196 B197 B198 B199 B200 B201 B202 B203 B204B205 B206 B207 B208 B209 B210 B211 B212 B213 B214 B215 B216B217 B218 B219 B220 B221 B222 B223 B224 B225 B226 B227 B228B229 B230 B231 B232 B233 B234 B235 B236 B237 B238 B239 B240B241 B242 B243 B244 B245 B246 B247 B248 B249 B250 B251 B252B253 B254 B255 B256 B257 B258 B259 B260 B261 B262 B263 B264B265 B266 B267 B268 B269 B270 B271 B272 B273 B274 B275 B276B277 B278 B279 B280 B281 B282 B283 B284 B285 B286 B287 B288B289 B290 B291 B292 B293 B294 B295 B296 B297 B298 B299 B300B301 B302 B303 B304 B305 B306 B307 B308 B309 B310 B311 B312B313 B314 B315 B316 B317 B318 B319 B320 B321 B322 B323 B324Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B325 B326 B327 B328 B329 B330 B331 B332 B333 B334 B335 B336B337 B338 B339 B340 B341 B342 B343 B344 B345 B346 B347 B348B349 B350 B351 B352 B353 B354 B355 B356 B357 B358 B359 B360B361 B362 B363 B364 B365 B366 B367 B368 B369 B370 B371 B372B373 B374 B375 B376 B377 B378 B379 B380 B381 B382 B383 B384B385 B386 B387 B388 B389 B390 B391 B392 B393 B394 B395 B396B397 B398 B399 B400 B401 B402 B403 B404 B405 B406 B407 B408B409 B410 B411 B412 B413 B414 B415 B416 B417 B418 B419 B420B421 B422 B423 B424 B425 B426 B427 B428 B429 B430 B431 B432B433 B434 B435 B436 B437 B438 B439 B440 B441 B442 B443 B444B445 B446 B447 B448 B449 B450 B451 B452 B453 B454 B455 B456B457 B458 B459 B460 B461 B462 B463 B464 B465 B466 B467 B468B469 B470 B471 B472 B473 B474 B475 B476 B477 B478 B479 B480B481 B482 B483 B484 B485 B486 B487 B488 B489 B490 B491 B492B493 B494 B495 B496 B497 B498 B499 B500 B501 B502 B503 B504B505 B506 B507 B508 B509 B510 B511 B512 B513 B514 B515 B516B517 B518 B519 B520 B521 B522 B523 B524 B525 B526 B527 B528B529 B530 B531 B532 B533 B534 B535 B536 B537 B538 B539 B540B541 B542 B543 B544 B545 B546 B547 B548 B549 B550 B551 B552B553 B554 B555 B556 B557 B558 B559 B560 B561 B562 B563 B564B565 B566 B567 B568 B569 B570 B571 B572 B573 B574 B575 B576B577 B578 B579 B580 B581 B582 B583 B584 B585 B586 B587 B588B589 B590 B591 B592 B593 B594 B595 B596 B597 B598 B599 B600B601 B602 B603 B604 B605 B606 B607 B608 B609 B610 B611 B612B613 B614 B615 B616 B617 B618 B619 B620 B621 B622 B623 B624B625 B626 B627 B628 B629 B630 B631 B632 B633 B634 B635 B636B637 B638 B639 B640 B641 B642 B643 B644 B645 B646 B647 B648B649 B650 B651 B652 B653 B654 B655 B656 B657 B658 B659 B660B661 B662 B663 B664 B665 B666 B667 B668 B669 B670 B671 B672B773 B774 B775 B776 B777 B778 B779 B780 B781 B782 B783 B784B785 B786 B787 B788 B789 B790 B791 B792 B793 B794 B795 B796B797 B798 B799 B800 B801 B802 B803 B804 B805 B806 B807 B808B809 B810 B811 B812 B813 B814 B815 B816 B817 B818 B819 B820Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B821 B822 B823 B824 B825 B826 B827 B828 B829 B830 B831 B832B833 B834 B835 B836 B837 B838 B839 B840 B841 B842 B843 B844B845 B846 B847 B848 B849 B850 B851 B852 B853 B854 B855 B856B857 B858 B859 B860 B861 B862 B863 B864 B865 B866 B867 B868B869 B870 B871 B872 B873 B874 B875 B876 B877 B878 B879 B880B881 B882 B883 B884 B885 B886 B887 B888 B889 B890 B891 B892B893 B894 B895 B896 B897 B898 B899 B900 B901 B902 B903 B904B905 B906 B907 B908 B909 B910 B911 B912 B913 B914 B915 B916B917 B918 B919 B920 B921 B922 B923 B924 B925 B926 B927 B928B929 B930 B931 B932 B933 B934 B935 B936 B937 B938 B939 B940B941 B942 B943 B944 B945 B946 B947 B948 B949 B950 B951 B952B953 B954 B955 B956 B957 B958 B959 B960 B961 B962 B963 B964B965 B966 B967 B968 B969 B970 B971 B972 B973 B974 B975 B976B977 B978 B979 B980 B981 B982 B983 B984 B985 B986 B987 B988B989 B990 B991 B992 B993 B994 B995 B996 B997 B998 B999 B1000B1001 B1002 B1003 B1004 B1005 B1006 B1007 B1008 B1009 B1010 B1011 B1012B1013 B1014 B1015 B1016 B1017 B1018 B1019 B1020 B1021 B1022 B1023 B1024B1025 B1026 B1027 B1028 B1029 B1030 B1031 B1032 B1033 B1034 B1035 B1036B1037 B1038 B1039 B1040 B1041 B1042 B1043 B1044 B1045 B1046 B1047 B1048B1049 B1050 B1051 B1052 B1053 B1054 B1055 B1056 B1057 B1058 B1059 B1060B1061 B1062 B1063 B1064 B1065 B1066 B1067 B1068 B1069 B1070 B1071 B1072B1073 B1074 B1075 B1076 B1077 B1078 B1079 B1080 B1081 B1082 B1083表13:式In化合物: Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36B37 B38 B39 B40 B41 B42 B43 B44 B45 B46 B47 B48B49 B50 B51 B52 B53 B54 B55 B56 B57 B58 B59 B60B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B95 B96B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108B109 B110 B111 B112 B113 B114 B115 B116 B117 B118 B119 B120B121 B122 B123 B124 B125 B126 B127 B128 B129 B130 B131 B132B133 B134 B135 B136 B137 B138 B139 B140 B141 B142 B143 B144B145 B146 B147 B148 B149 B150 B151 B152 B153 B154 B155 B156B157 B158 B159 B160 B161 B162 B163 B164 B165 B166 B167 B168B169 B170 B171 B172 B173 B174 B175 B176 B177 B178 B179 B180B181 B182 B183 B184 B185 B186 B187 B188 B189 B190 B191 B192B193 B194 B195 B196 B197 B198 B199 B200 B201 B202 B203 B204B205 B206 B207 B208 B209 B210 B211 B212 B213 B214 B215 B216B217 B218 B219 B220 B221 B222 B223 B224 B225 B226 B227 B228B229 B230 B231 B232 B233 B234 B235 B236 B237 B238 B239 B240B241 B242 B243 B244 B245 B246 B247 B248 B249 B250 B251 B252B253 B254 B255 B256 B257 B258 B259 B260 B261 B262 B263 B264B265 B266 B267 B268 B269 B270 B271 B272 B273 B274 B275 B276B277 B278 B279 B280 B281 B282 B283 B284 B285 B286 B287 B288B289 B290 B291 B292 B293 B294 B295 B296 B297 B298 B299 B300B301 B302 B303 B304 B305 B306 B307 B308 B309 B310 B311 B312B313 B314 B315 B316 B317 B318 B319 B320 B321 B322 B323 B324B325 B326 B327 B328 B329 B330 B331 B332 B333 B334 B335 B336B337 B338 B339 B340 B341 B342 B343 B344 B345 B346 B347 B348B349 B350 B351 B352 B353 B354 B355 B356 B357 B358 B359 B360B361 B362 B363 B364 B365 B366 B367 B368 B369 B370 B371 B372B373 B374 B375 B376 B377 B378 B379 B380 B381 B382 B383 B384B385 B386 B387 B388 B389 B390 B391 B392 B393 B394 B395 B396B397 B398 B399 B400 B401 B402 B403 B404 B405 B406 B407 B408B409 B410 B411 B412 B413 B414 B415 B416 B417 B418 B419 B420Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B421 B422 B423 B424 B425 B426 B427 B428 B429 B430 B431 B432B433 B434 B435 B436 B437 B438 B439 B440 B441 B442 B443 B444B445 B446 B447 B448 B449 B450 B451 B452 B453 B454 B455 B456B457 B458 B459 B460 B461 B462 B463 B464 B465 B466 B467 B468B469 B470 B471 B472 B473 B474 B475 B476 B477 B478 B479 B480B481 B482 B483 B484 B485 B486 B487 B488 B489 B490 B491 B492B493 B494 B495 B496 B497 B498 B499 B500 B501 B502 B503 B504B505 B506 B507 B508 B509 B510 B511 B512 B513 B514 B515 B516B517 B518 B519 B520 B521 B522 B523 B524 B525 B526 B527 B528B529 B530 B531 B532 B533 B534 B535 B536 B537 B538 B539 B540B541 B542 B543 B544 B545 B546 B547 B548 B549 B550 B551 B552B553 B554 B555 B556 B557 B558 B559 B560 B561 B562 B563 B564B565 B566 B567 B568 B569 B570 B571 B572 B573 B574 B575 B576B577 B578 B579 B580 B581 B582 B583 B584 B585 B586 B587 B588B589 B590 B591 B592 B593 B594 B595 B596 B597 B598 B599 B600B601 B602 B603 B604 B605 B606 B607 B608 B609 B610 B611 B612B613 B614 B615 B616 B617 B618 B619 B620 B621 B622 B623 B624B625 B626 B627 B628 B629 B630 B631 B632 B633 B634 B635 B636B637 B638 B639 B640 B641 B642 B643 B644 B645 B646 B647 B648B649 B650 B651 B652 B653 B654 B655 B656 B657 B658 B659 B660B661 B662 B663 B664 B665 B666 B667 B668 B669 B670 B671 B672B773 B774 B775 B776 B777 B778 B779 B780 B781 B782 B783 B784B785 B786 B787 B788 B789 B790 B791 B792 B793 B794 B795 B796B797 B798 B799 B800 B801 B802 B803 B804 B805 B806 B807 B808B809 B810 B811 B812 B813 B814 B815 B816 B817 B818 B819 B820B821 B822 B823 B824 B825 B826 B827 B828 B829 B830 B831 B832B833 B834 B835 B836 B837 B838 B839 B840 B841 B842 B843 B844B845 B846 B847 B848 B849 B850 B851 B852 B853 B854 B855 B856B857 B858 B859 B860 B861 B862 B863 B864 B865 B866 B867 B868B869 B870 B871 B872 B873 B874 B875 B876 B877 B878 B879 B880B881 B882 B883 B884 B885 B886 B887 B888 B889 B890 B891 B892B893 B894 B895 B896 B897 B898 B899 B900 B901 B902 B903 B904B905 B906 B907 B908 B909 B910 B911 B912 B913 B914 B915 B916Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B917 B918 B919 B920 B921 B922 B923 B924 B925 B926 B927 B928B929 B930 B931 B932 B933 B934 B935 B936 B937 B938 B939 B940B941 B942 B943 B944 B945 B946 B947 B948 B949 B950 B951 B952B953 B954 B955 B956 B957 B958 B959 B960 B961 B962 B963 B964B965 B966 B967 B968 B969 B970 B971 B972 B973 B974 B975 B976B977 B978 B979 B980 B981 B982 B983 B984 B985 B986 B987 B988B989 B990 B991 B992 B993 B994 B995 B996 B997 B998 B999 B1000B1001 B1002 B1003 B1004 B1005 B1006 B1007 B1008 B1009 B1010 B1011 B1012B1013 B1014 B1015 B1016 B1017 B1018 B1019 B1020 B1021 B1022 B1023 B1024B1025 B1026 B1027 B1028 B1029 B1030 B1031 B1032 B1033 B1034 B1035 B1036B1037 B1038 B1039 B1040 B1041 B1042 B1043 B1044 B1045 B1046 B1047 B1048B1049 B1050 B1051 B1052 B1053 B1054 B1055 B1056 B1057 B1058 B1059 B1060B1061 B1062 B1063 B1064 B1065 B1066 B1067 B1068 B1069 B1070 B1071 B1072B1073 B1074 B1075 B1076 B1077 B1078 B1079 B1080 B1081 B1082 B1083表14:式Io化合物: Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36B37 B38 B39 B40 B41 B42 B43 B44 B45 B46 B47 B48B49 B50 B51 B52 B53 B54 B55 B56 B57 B58 B59 B60B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B95 B96B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108B109 B110 B111 B112 B113 B114 B115 B116 B117 B118 B119 B120Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B121 B122 B123 B124 B125 B126 B127 B128 B129 B130 B131 B132B133 B134 B135 B136 B137 B138 B139 B140 B141 B142 B143 B144B145 B146 B147 B148 B149 B150 B151 B152 B153 B154 B155 B156B157 B158 B159 B160 B161 B162 B163 B164 B165 B166 B167 B168B169 B170 B171 B172 B173 B174 B175 B176 B177 B178 B179 B180B181 B182 B183 B184 B185 B186 B187 B188 B189 B190 B191 B192B193 B194 B195 B196 B197 B198 B199 B200 B201 B202 B203 B204B205 B206 B207 B208 B209 B210 B211 B212 B213 B214 B215 B216B217 B218 B219 B220 B221 B222 B223 B224 B225 B226 B227 B228B229 B230 B231 B232 B233 B234 B235 B236 B237 B238 B239 B240B241 B242 B243 B244 B245 B246 B247 B248 B249 B250 B251 B252B253 B254 B255 B256 B257 B258 B259 B260 B261 B262 B263 B264B265 B266 B267 B268 B269 B270 B271 B272 B273 B274 B275 B276B277 B278 B279 B280 B281 B282 B283 B284 B285 B286 B287 B288B289 B290 B291 B292 B293 B294 B295 B296 B297 B298 B299 B300B301 B302 B303 B304 B305 B306 B307 B308 B309 B310 B311 B312B313 B314 B315 B316 B317 B318 B319 B320 B321 B322 B323 B324B325 B326 B327 B328 B329 B330 B331 B332 B333 B334 B335 B336B337 B338 B339 B340 B341 B342 B343 B344 B345 B346 B347 B348B349 B350 B351 B352 B353 B354 B355 B356 B357 B358 B359 B360B361 B362 B363 B364 B365 B366 B367 B368 B369 B370 B371 B372B373 B374 B375 B376 B377 B378 B379 B380 B381 B382 B383 B384B385 B386 B387 B388 B389 B390 B391 B392 B393 B394 B395 B396B397 B398 B399 B400 B401 B402 B403 B404 B405 B406 B407 B408B409 B410 B411 B412 B413 B414 B415 B416 B417 B418 B419 B420B421 B422 B423 B424 B425 B426 B427 B428 B429 B430 B431 B432B433 B434 B435 B436 B437 B438 B439 B440 B441 B442 B443 B444B445 B446 B447 B448 B449 B450 B451 B452 B453 B454 B455 B456B457 B458 B459 B460 B461 B462 B463 B464 B465 B466 B467 B468B469 B470 B471 B472 B473 B474 B475 B476 B477 B478 B479 B480B481 B482 B483 B484 B485 B486 B487 B488 B489 B490 B491 B492B493 B494 B495 B496 B497 B498 B499 B500 B501 B502 B503 B504B505 B506 B507 B508 B509 B510 B511 B512 B513 B514 B515 B516Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B517 B518 B519 B520 B521 B522 B523 B524 B525 B526 B527 B528B529 B530 B531 B532 B533 B534 B535 B536 B537 B538 B539 B540B541 B542 B543 B544 B545 B546 B547 B548 B549 B550 B551 B552B553 B554 B555 B556 B557 B558 B559 B560 B561 B562 B563 B564B565 B566 B567 B568 B569 B570 B571 B572 B573 B574 B575 B576B577 B578 B579 B580 B581 B582 B583 B584 B585 B586 B587 B588B589 B590 B591 B592 B593 B594 B595 B596 B597 B598 B599 B600B601 B602 B603 B604 B605 B606 B607 B608 B609 B610 B611 B612B613 B614 B615 B616 B617 B618 B619 B620 B621 B622 B623 B624B625 B626 B627 B628 B629 B630 B631 B632 B633 B634 B635 B636B637 B638 B639 B640 B641 B642 B643 B644 B645 B646 B647 B648B649 B650 B651 B652 B653 B654 B655 B656 B657 B658 B659 B660B661 B662 B663 B664 B665 B666 B667 B668 B669 B670 B671 B672B773 B774 B775 B776 B777 B778 B779 B780 B781 B782 B783 B784B785 B786 B787 B788 B789 B790 B791 B792 B793 B794 B795 B796B797 B798 B799 B800 B801 B802 B803 B804 B805 B806 B807 B808B809 B810 B811 B812 B813 B814 B815 B816 B817 B818 B819 B820B821 B822 B823 B824 B825 B826 B827 B828 B829 B830 B831 B832B833 B834 B835 B836 B837 B838 B839 B840 B841 B842 B843 B844B845 B846 B847 B848 B849 B850 B851 B852 B853 B854 B855 B856B857 B858 B859 B860 B861 B862 B863 B864 B865 B866 B867 B868B869 B870 B871 B872 B873 B874 B875 B876 B877 B878 B879 B880B881 B882 B883 B884 B885 B886 B887 B888 B889 B890 B891 B892B893 B894 B895 B896 B897 B898 B899 B900 B901 B902 B903 B904B905 B906 B907 B908 B909 B910 B911 B912 B913 B914 B915 B916B917 B918 B919 B920 B921 B922 B923 B924 B925 B926 B927 B928B929 B930 B931 B932 B933 B934 B935 B936 B937 B938 B939 B940B941 B942 B943 B944 B945 B946 B947 B948 B949 B950 B951 B952B953 B954 B955 B956 B957 B958 B959 B960 B961 B962 B963 B964B965 B966 B967 B968 B969 B970 B971 B972 B973 B974 B975 B976B977 B978 B979 B980 B981 B982 B983 B984 B985 B986 B987 B988B989 B990 B991 B992 B993 B994 B995 B996 B997 B998 B999 B1000B1001 B1002 B1003 B1004 B1005 B1006 B1007 B1008 B1009 B1010 B1011 B1012Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B1013 B1014 B1015 B1016 B1017 B1018 B1019 B1020 B1021 B1022 B1023 B1024B1025 B1026 B1027 B1028 B1029 B1030 B1031 B1032 B1033 B1034 B1035 B1036B1037 B1038 B1039 B1040 B1041 B1042 B1043 B1044 B1045 B1046 B1047 B1048B1049 B1050 B1051 B1052 B1053 B1054 B1055 B1056 B1057 B1058 B1059 B1060B1061 B1062 B1063 B1064 B1065 B1066 B1067 B1068 B1069 B1070 B1071 B1072B1073 B1074 B1075 B1076 B1077 B1078 B1079 B1080 B1081 B1082 B1083表15:式Ip化合物: Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36B37 B38 B39 B40 B41 B42 B43 B44 B45 B46 B47 B48B49 B50 B51 B52 B53 B54 B55 B56 B57 B58 B59 B60B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B95 B96B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108B109 B110 B111 B112 B113 B114 B115 B116 B117 B118 B119 B120B121 B122 B123 B124 B125 B126 B127 B128 B129 B130 B131 B132B133 B134 B135 B136 B137 B138 B139 B140 B141 B142 B143 B144B145 B146 B147 B148 B149 B150 B151 B152 B153 B154 B155 B156B157 B158 B159 B160 B161 B162 B163 B164 B165 B166 B167 B168B169 B170 B171 B172 B173 B174 B175 B176 B177 B178 B179 B180B181 B182 B183 B184 B185 B186 B187 B188 B189 B190 B191 B192B193 B194 B195 B196 B197 B198 B199 B200 B201 B202 B203 B204Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B205 B206 B207 B208 B209 B210 B211 B212 B213 B214 B215 B216B217 B218 B219 B220 B221 B222 B223 B224 B225 B226 B227 B228B229 B230 B231 B232 B233 B234 B235 B236 B237 B238 B239 B240B241 B242 B243 B244 B245 B246 B247 B248 B249 B250 B251 B252B253 B254 B255 B256 B257 B258 B259 B260 B261 B262 B263 B264B265 B266 B267 B268 B269 B270 B271 B272 B273 B274 B275 B276B277 B278 B279 B280 B281 B282 B283 B284 B285 B286 B287 B288B289 B290 B291 B292 B293 B294 B295 B296 B297 B298 B299 B300B301 B302 B303 B304 B305 B306 B307 B308 B309 B310 B311 B312B313 B314 B315 B316 B317 B318 B319 B320 B321 B322 B323 B324B325 B326 B327 B328 B329 B330 B331 B332 B333 B334 B335 B336B337 B338 B339 B340 B341 B342 B343 B344 B345 B346 B347 B348B349 B350 B351 B352 B353 B354 B355 B356 B357 B358 B359 B360B361 B362 B363 B364 B365 B366 B367 B368 B369 B370 B371 B372B373 B374 B375 B376 B377 B378 B379 B380 B381 B382 B383 B384B385 B386 B387 B388 B389 B390 B391 B392 B393 B394 B395 B396B397 B398 B399 B400 B401 B402 B403 B404 B405 B406 B407 B408B409 B410 B411 B412 B413 B414 B415 B416 B417 B418 B419 B420B421 B422 B423 B424 B425 B426 B427 B428 B429 B430 B431 B432B433 B434 B435 B436 B437 B438 B439 B440 B441 B442 B443 B444B445 B446 B447 B448 B449 B450 B451 B452 B453 B454 B455 B456B457 B458 B459 B460 B461 B462 B463 B464 B465 B466 B467 B468B469 B470 B471 B472 B473 B474 B475 B476 B477 B478 B479 B480B481 B482 B483 B484 B485 B486 B487 B488 B489 B490 B491 B492B493 B494 B495 B496 B497 B498 B499 B500 B501 B502 B503 B504B505 B506 B507 B508 B509 B510 B511 B512 B513 B514 B515 B516B517 B518 B519 B520 B521 B522 B523 B524 B525 B526 B527 B528B529 B530 B531 B532 B533 B534 B535 B536 B537 B538 B539 B540B541 B542 B543 B544 B545 B546 B547 B548 B549 B550 B551 B552B553 B554 B555 B556 B557 B558 B559 B560 B561 B562 B563 B564B565 B566 B567 B568 B569 B570 B571 B572 B573 B574 B575 B576B577 B578 B579 B580 B581 B582 B583 B584 B585 B586 B587 B588B589 B590 B591 B592 B593 B594 B595 B596 B597 B598 B599 B600Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B601 B602 B603 B604 B605 B606 B607 B608 B609 B610 B611 B612B613 B614 B615 B616 B617 B618 B619 B620 B621 B622 B623 B624B625 B626 B627 B628 B629 B630 B631 B632 B633 B634 B635 B636B637 B638 B639 B640 B641 B642 B643 B644 B645 B646 B647 B648B649 B650 B651 B652 B653 B654 B655 B656 B657 B658 B659 B660B661 B662 B663 B664 B665 B666 B667 B668 B669 B670 B671 B672B773 B774 B775 B776 B777 B778 B779 B780 B781 B782 B783 B784B785 B786 B787 B788 B789 B790 B791 B792 B793 B794 B795 B796B797 B798 B799 B800 B801 B802 B803 B804 B805 B806 B807 B808B809 B810 B811 B812 B813 B814 B815 B816 B817 B818 B819 B820B821 B822 B823 B824 B825 B826 B827 B828 B829 B830 B831 B832B833 B834 B835 B836 B837 B838 B839 B840 B841 B842 B843 B844B845 B846 B847 B848 B849 B850 B851 B852 B853 B854 B855 B856B857 B858 B859 B860 B861 B862 B863 B864 B865 B866 B867 B868B869 B870 B871 B872 B873 B874 B875 B876 B877 B878 B879 B880B881 B882 B883 B884 B885 B886 B887 B888 B889 B890 B891 B892B893 B894 B895 B896 B897 B898 B899 B900 B901 B902 B903 B904B905 B906 B907 B908 B909 B910 B911 B912 B913 B914 B915 B916B917 B918 B919 B920 B921 B922 B923 B924 B925 B926 B927 B928B929 B930 B931 B932 B933 B934 B935 B936 B937 B938 B939 B940B941 B942 B943 B944 B945 B946 B947 B948 B949 B950 B951 B952B953 B954 B955 B956 B957 B958 B959 B960 B961 B962 B963 B964B965 B966 B967 B968 B969 B970 B971 B972 B973 B974 B975 B976B977 B978 B979 B980 B981 B982 B983 B984 B985 B986 B987 B988B989 B990 B991 B992 B993 B994 B995 B996 B997 B998 B999 B1000B1001 B1002 B1003 B1004 B1005 B1006 B1007 B1008 B1009 B1010 B1011 B1012B1013 B1014 B1015 B1016 B1017 B1018 B1019 B1020 B1021 B1022 B1023 B1024B1025 B1026 B1027 B1028 B1029 B1030 B1031 B1032 B1033 B1034 B1035 B1036B1037 B1038 B1039 B1040 B1041 B1042 B1043 B1044 B1045 B1046 B1047 B1048B1049 B1050 B1051 B1052 B1053 B1054 B1055 B1056 B1057 B1058 B1059 B1060B1061 B1062 B1063 B1064 B1065 B1066 B1067 B1068 B1069 B1070 B1071 B1072B1073 B1074 B1075 B1076 B1077 B1078 B1079 B1080 B1081 B1082 B1083表16:式Iq化合物: Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12B13 B14 B15 B16 B17 B18 B19 B20 B21 B22 B23 B24B25 B26 B27 B28 B29 B30 B31 B32 B33 B34 B35 B36B37 B38 B39 B40 B41 B42 B43 B44 B45 B46 B47 B48B49 B50 B51 B52 B53 B54 B55 B56 B57 B58 B59 B60B61 B62 B63 B64 B65 B66 B67 B68 B69 B70 B71 B72B73 B74 B75 B76 B77 B78 B79 B80 B81 B82 B83 B84B85 B86 B87 B88 B89 B90 B91 B92 B93 B94 B95 B96B97 B98 B99 B100 B101 B102 B103 B104 B105 B106 B107 B108B109 B110 B111 B112 B113 B114 B115 B116 B117 B118 B119 B120B121 B122 B123 B124 B125 B126 B127 B128 B129 B130 B131 B132B133 B134 B135 B136 B137 B138 B139 B140 B141 B142 B143 B144B145 B146 B147 B148 B149 B150 B151 B152 B153 B154 B155 B156B157 B158 B159 B160 B161 B162 B163 B164 B165 B166 B167 B168B169 B170 B171 B172 B173 B174 B175 B176 B177 B178 B179 B180B181 B182 B183 B184 B185 B186 B187 B188 B189 B190 B191 B192B193 B194 B195 B196 B197 B198 B199 B200 B201 B202 B203 B204B205 B206 B207 B208 B209 B210 B211 B212 B213 B214 B215 B216B217 B218 B219 B220 B221 B222 B223 B224 B225 B226 B227 B228B229 B230 B231 B232 B233 B234 B235 B236 B237 B238 B239 B240B241 B242 B243 B244 B245 B246 B247 B248 B249 B250 B251 B252B253 B254 B255 B256 B257 B258 B259 B260 B261 B262 B263 B264B265 B266 B267 B268 B269 B270 B271 B272 B273 B274 B275 B276B277 B278 B279 B280 B281 B282 B283 B284 B285 B286 B287 B288B289 B290 B291 B292 B293 B294 B295 B296 B297 B298 B299 B300Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B301 B302 B303 B304 B305 B306 B307 B308 B309 B310 B311 B312B313 B314 B315 B316 B317 B318 B319 B320 B321 B322 B323 B324B325 B326 B327 B328 B329 B330 B331 B332 B333 B334 B335 B336B337 B338 B339 B340 B341 B342 B343 B344 B345 B346 B347 B348B349 B350 B351 B352 B353 B354 B355 B356 B357 B358 B359 B360B361 B362 B363 B364 B365 B366 B367 B368 B369 B370 B371 B372B373 B374 B375 B376 B377 B378 B379 B380 B381 B382 B383 B384B385 B386 B387 B388 B389 B390 B391 B392 B393 B394 B395 B396B397 B398 B399 B400 B401 B402 B403 B404 B405 B406 B407 B408B409 B410 B411 B412 B413 B414 B415 B416 B417 B418 B419 B420B421 B422 B423 B424 B425 B426 B427 B428 B429 B430 B431 B432B433 B434 B435 B436 B437 B438 B439 B440 B441 B442 B443 B444B445 B446 B447 B448 B449 B450 B451 B452 B453 B454 B455 B456B457 B458 B459 B460 B461 B462 B463 B464 B465 B466 B467 B468B469 B470 B471 B472 B473 B474 B475 B476 B477 B478 B479 B480B481 B482 B483 B484 B485 B486 B487 B488 B489 B490 B491 B492B493 B494 B495 B496 B497 B498 B499 B500 B501 B502 B503 B504B505 B506 B507 B508 B509 B510 B511 B512 B513 B514 B515 B516B517 B518 B519 B520 B521 B522 B523 B524 B525 B526 B527 B528B529 B530 B531 B532 B533 B534 B535 B536 B537 B538 B539 B540B541 B542 B543 B544 B545 B546 B547 B548 B549 B550 B551 B552B553 B554 B555 B556 B557 B558 B559 B560 B561 B562 B563 B564B565 B566 B567 B568 B569 B570 B571 B572 B573 B574 B575 B576B577 B578 B579 B580 B581 B582 B583 B584 B585 B586 B587 B588B589 B590 B591 B592 B593 B594 B595 B596 B597 B598 B599 B600B601 B602 B603 B604 B605 B606 B607 B608 B609 B610 B611 B612B613 B614 B615 B616 B617 B618 B619 B620 B621 B622 B623 B624B625 B626 B627 B628 B629 B630 B631 B632 B633 B634 B635 B636B637 B638 B639 B640 B641 B642 B643 B644 B645 B646 B647 B648B649 B650 B651 B652 B653 B654 B655 B656 B657 B658 B659 B660B661 B662 B663 B664 B665 B666 B667 B668 B669 B670 B671 B672B773 B774 B775 B776 B777 B778 B779 B780 B781 B782 B783 B784B785 B786 B787 B788 B789 B790 B791 B792 B793 B794 B795 B796Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3
Q 3B797 B798 B799 B800 B801 B802 B803 B804 B805 B806 B807 B808B809 B810 B811 B812 B813 B814 B815 B816 B817 B818 B819 B820B821 B822 B823 B824 B825 B826 B827 B828 B829 B830 B831 B832B833 B834 B835 B836 B837 B838 B839 B840 B841 B842 B843 B844B845 B846 B847 B848 B849 B850 B851 B852 B853 B854 B855 B856B857 B858 B859 B860 B861 B862 B863 B864 B865 B866 B867 B868B869 B870 B871 B872 B873 B874 B875 B876 B877 B878 B879 B880B881 B882 B883 B884 B885 B886 B887 B888 B889 B890 B891 B892B893 B894 B895 B896 B897 B898 B899 B900 B901 B902 B903 B904B905 B906 B907 B908 B909 B910 B911 B912 B913 B914 B915 B916B917 B918 B919 B920 B921 B922 B923 B924 B925 B926 B927 B928B929 B930 B931 B932 B933 B934 B935 B936 B937 B938 B939 B940B941 B942 B943 B944 B945 B946 B947 B948 B949 B950 B951 B952B953 B954 B955 B956 B957 B958 B959 B960 B961 B962 B963 B964B965 B966 B967 B968 B969 B970 B971 B972 B973 B974 B975 B976B977 B978 B979 B980 B981 B982 B983 B984 B985 B986 B987 B988B989 B990 B991 B992 B993 B994 B995 B996 B997 B998 B999 B1000B1001 B1002 B1003 B1004 B1005 B1006 B1007 B1008 B1009 B1010 B1011 B1012B1013 B1014 B1015 B1016 B1017 B1018 B1019 B1020 B1021 B1022 B1023 B1024B1025 B1026 B1027 B1028 B1029 B1030 B1031 B1032 B1033 B1034 B1035 B1036B1037 B1038 B1039 B1040 B1041 B1042 B1043 B1044 B1045 B1046 B1047 B1048B1049 B1050 B1051 B1052 B1053 B1054 B1055 B1056 B1057 B1058 B1059 B1060B1061 B1062 B1063 B1064 B1065 B1066 B1067 B1068 B1069 B1070 B1071 B1072B1073 B1074 B1075 B1076 B1077 B1078 B1079 B1080 B1081 B1082 B1083表17:式Ir化合物: Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6 Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6
Q 6C1 C2 C3 C4 C5 C6 C7 C8 C9 C10 C11 C12C13 C14 C15 C16 C17 C18 C19 C20 C21 C22 C23 C24C25 C26 C27 C28 C29 C30 C31 C32 C33 C34 C35 C36C37 C38 C39 C40 C41 C42 C43 C44 C45 C46 C47 C48C49 C50 C51 C52 C53 C54 C55 C56 C57 C58 C59 C60C61 C62 C63 C64 C65 C66 C67 C68 C69 C70 C71 C72C73 C74 C75 C76 C77 C78 C79 C80 C81 C82 C83 C84C85 C86 C87 C88 C89 C90 C91 C92 C93 C94 C95 C96C97 C98 C99 C100 C101 C102 C103 C104 C105 C106 C107 C108C109 C110 C111 C112 C113 C114 C115 C116 C117 C118 C119 C120C121 C122 C123 C124 C125 C126 C127 C128 C129 C130 C131 C132C133 C134 C135 C136 C137 C138 C139 C140 C141 C142 C143 C144C145 C146 C147 C148 C149 C150 C151表18:式Is化合物: Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7D1 D2 D3 D4 D5 D6 D7 D8 D9 D10 D11 D12D13 D14 D15 D16 D17 D18 D19 D20 D21 D22 D23 D24D25 D26 D27 D28 D29 D30 D31 D32 D33 D34 D35 D36D37 D38 D39 D40 D41 D42 D43 D44 D45 D46 D47 D48D49 D50 D51 D52 D53 D54 D55 D56 D57 D58 D59 D60D61 D62 D63 D64 D65 D66 D67 D68 D69 D70 D71 D72D73 D74 D75 D76 D77 D78 D79 D80 D81 D82 D83 D84D85 D86 D87 D88 D89 D90 D91 D92 D93 D94 D95 D96D97 D98 D99 D100 D101 D102 D103 D104 D105 D106 D107 D108D109 D110 D111 D112 D113 D114 D115 D116 D117 D118 D119 D120Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7
Q 7D121 D122 D123 D124 D125 D126 D127 D128 D129 D130 D131 D132D133 D134 D135 D136 D137 D138 D139 D140表19:式Iv化合物: 化合物序号 R75E1 CH2OCH3E2 CH2OC2H5E3 CH2O-正丙基E4 CH2O-异丙基E5 CH2O-正丁基E6 CH2O-异丁基E7 CH2O-叔丁基E8 (CH2)2OCH3E9 (CH2)2O-乙基E10 (CH2)2O-正丙基E11 (CH2)2O-异丙基E12 (CH2)2O-正丁基E13 (CH2)2O-异丁基E14 (CH2)2O-叔丁基E15 (CH2)2O(CH2)2OCH3E16 (CH2)2O(CH2)2OCH3E17 C2H5表20:表5-19的物理数据(数据=m.p.,单位为℃):化合物 物理数据 化合物 物理数据 化合物 物理数据A2 150-151 C46 159-161 A2-B1058 88-89A3 148-149 C91 141-143 A2-B1066 粘稠物A4 143-144 C146 99-101 A2-B1067 树脂油状物A5 81-82 C149 148-150 A2-B1069 油状物A6 148-150 A2-B1 90-92 A2-B1069 粘稠油状物A7 105-106 A2-B68 120-121 A8-B1 97-98A8 123-124 A2-B2 树脂状物 A7-B1 油状物A9 73-74 A2-B90 树脂状物 A3-B1 42-44A10 165-167 A2-B93 95-96 A94-B1 57-58A15 164-166 A2-B46 61-62顺式-rac A66-B24 80-82A17 99-100 A2-B46 83-84反式-rac A64-B1 49-51A26 143-144 A2-B91 树脂状物 A154-B1 94-95A27 107-108 A2-B1081 油状物 A6-B1 123-124A29 173-174 A2-B1082 树脂状物 A6-B24 油状物A30 178-181 A2-B1083 树脂状物 A34-B1 53-54A31 209-210 A2-B29 87-88 A2-B25 油状物A32 145-146 A2-B73 树脂状物 A2-B925 油状物A34 170-171 A2-B95 106-107 E8 55-56A64 134-135 A2-B31 151-153 E17 99-101A94 134-135 A2-B75 无定形物A154 108-110 A2-B24 油状物B1057 166-167 A2-B5 树脂状物B1058 结晶 A2-C91 树脂状物B1061 结晶 A2-C146 油状物B1063 结晶 A2-B112 树脂状物B1065 油状物 A2-D140 油状物B1066 150-152 A2-B1057 无定形物B1067 122-123 A2-B1063 油状物B1069 117-118 A2-B1061 油状物B1070 结晶 A2-B133 油状物
式2.1和2.3-2.13.c化合物的名称是甲氧咪草烟、咪唑乙烟酸、咪唑喹啉酸、咪唑烟酸、二甲吩草胺、莠去津、特丁津、西玛津、特丁净、氰乙酰肼、莠灭净、甲氧去草净、调环酸钙、稀禾定、烯草酮、吡喃草酮(tepraloxydim)、唑嘧磺草胺、磺草唑胺、哒草特、溴苯腈、碘苯腈、磺草酮、唑酮草酯(carfentrazone)、甲磺草胺、异噁唑草酮、草铵膦、氟嘧磺隆、氟磺隆、砜嘧磺隆、氯吡嘧磺隆、烟嘧磺隆、乙氧嘧磺隆、啶嘧磺隆和噻吩磺隆,并且以下列条目号描述在《农药手册》(PesticideManual),第11版,英国作物保护委员会(British Crop ProtectionCouncil),1997中:412、415、414、413、240、34、692、651、693、168、20、691、595、648、146、49、339、495、626、88、425、664、112、665、436、382、589、613、644、389、519、287、325和704。其中Y1、Y3和Y4是次甲基,Y2是C-I,R74是COOMe,Y5是氮,Y6是甲基,且Y7是甲氧基的式2.13化合物以名称碘甲磺隆(尤其是钠盐)描述在AGROWNo.296,16th 1月1998,p.22中。其中Y1、Y2、Y3和Y4是次甲基,R74是三氟甲基,Y5是氮,Y6是三氟甲基,且Y7是甲氧基的式2.13化合物的名称是甲酰氨磺隆,并描述在DE-A-40 38 430中。其中Y1是NH-CHO,Y2、Y3和Y4是次甲基,R74是CONMe2,Y5是次甲基,且Y6和Y7是甲氧基的式2.13化合物描述在例如WO 95/29899中。
式2.12化合物的S对映体以CAS-Reg.No.[35597-44-5]登记。通式2.2化合物,aRS,1’S(-)N-(1’-甲基-2’-甲氧基-乙基)-N-氯乙酰基-2-乙基-6-甲基苯胺,和通式2.3化合物,(1S,aRS)-2-氯-N-(2,4-二甲基-3-噻吩基)-N-(2-甲氧基-1-甲基乙基)-乙酰胺描述在例如WO97/34485中。其中R69是NO2的式2.9化合物的名称是甲基磺草酮,并且描述在例如US-A-5 006 158中。其中R62是乙氧基,R63是氟,Y是次甲基,R64是甲氧基羰基,R65是氢,且R66是氯的式2.6化合物的名称是氯酯磺草胺(cloransulam),并描述在例如AGROW No.261,2nd 8月1996,p.21中。其中R62是甲氧基,R63是氢,Y是C-F,R64是氟,R65是氢,且R66是氟的式2.6化合物的名称是双氟磺草胺,并描述在US-A-5 163 995中。
此外,本发明组合物的下列化合物描述在《农药手册》(PesticideManual),第11版,英国作物保护委员会(British Crop ProtectionCouncil),1997中:式化合物(名称) 《农药手册》第11版,条目号2.14(嗪草酮) 4972.15(苯草醚) 82.16(草甘膦) 3832.17(灭草松) 652.18(二甲戊灵) 5572.19(麦草畏) 2102.20(丁草敌) 1002.22(异恶草松) 1502.23(2,4-D) 1922.24(氟烯草酸) 3402.25(氟噻甲草酯) 3592.26(呋草酮) 3562.27(丙炔氟草胺) 3412.28(百草枯) 5502.29(唑啶草酮) 372.30(fluthiamid) 512.33(sulfosate) 3832.34(磺草灵) 332.35(氟草敏) 5262.36(特草定) 6892.37(噻唑烟酸) 7022.38(氟硫草定) 2592.39(环嗪酮) 4002.40(敌草隆) 2602.41(MCPA) 4552.42(甲氯丙酸) 4592.43(丁噻隆) 683
其中R67是氢的式2.7化合物及其制备描述在US-A-3 790 571中;其中R62是乙氧基,Z是氮,R63是氟,R64是氯,R65是氢,且R66是氯的式2.6化合物描述在US-A-5 498 773中。式2.21化合物及其制备描述在US-A-5 183 492中;式2.22化合物以名称双环磺草酮描述在AGROW No.296,16th 1月1998,p.22中。式2.31化合物以名称四唑酰草胺描述在1997年英国作物保护会议-杂草,会议论文集(The 1997 British CropProtect ion Conference-Weeds,Conference Proceedings)Vol.1,2-8,p.67-72中;式2.32化合物以名称JV 485(isoxapropazol)描述在1997年英国作物保护会议-杂草,会议论文集Vol.1,3A-2,p.93-98中。式2.44化合物的名称是pethoxamid,并描述在EP-A-0 206 251中。式2.45化合物的名称是丙苯磺隆,并描述在EP-A-0 507 171中;式2.46化合物的名称是异丙吡草酯,并描述在例如US-A-5 530 126中。式2.47化合物的名称是吲哚酮草酯,并描述在例如DE-A-4 037 840中。式2.48化合物的名称是双苯嘧草酮,并描述在例如WO 97/08953中。式2.49化合物的名称是氟吡草腙,并描述在例如EP-A-0 646 315中。式2.50化合物(氨唑草酮)及其制备公开在DD 298 393和US-A-5 194 085中。式2.51化合物(flufenpyr-ethyl)描述在美国化学会论文文摘(Abstractsof Papers American Chemical Society),(2000)Vol.220,No.部分1,pp.AGRO 174中。
非常令人惊奇的是,式I活性组分与一种或多种选自式2.1-2.51的活性组分的组合对欲控制杂草的作用超过了一般所预计的加和作用,因此扩大了单独活性组分的作用范围,尤其是在下列两个方面:首先,减小了单独的式2.1-2.51化合物的施用量,同时保持了良好的作用水平,其次,对于单独的活性物质以低施用量不可用的情况(从农学角度来看),本发明组合物亦可获得良好的杂草控制水平。该结果是杂草谱的显著拓宽,并且提高了在有用植物农作物方面的选择性,如果发生了活性组分的非故意剂量过多,这样的结果是必须的并且希望的。在保持良好控制有用植物农作物中的杂草的同时,本发明组合物还使得在继代农作物中有更大的灵活性。
本发明组合物可用于抗大量在农业上很重要的杂草,例如繁缕属、豆瓣菜属、剪股颖属、马唐属、燕麦属、狗尾草属、芥属、毒麦属、茄属、菜豆属、稗属、藨草属、雨久花属、慈菇属、雀麦属、看麦娘属、石茅高梁、筒轴茅属、莎草属、苘麻属植物、黄花稔属、苍耳属、苋属、藜属、番薯属、苘蒿属、猪殃殃属、堇菜属和婆婆纳属。本发明组合物适用于农业中的所有常用施用方法,例如芽前施用、苗后施用和种子包衣。本发明组合物尤其适用于控制有用植物农作物例如禾谷类植物、油菜、甜菜、甘蔗、种植园农作物、稻、玉米和大豆中的杂草,以及适用于非选择性杂草控制。
“农作物”还指通过常规育种或基因工程方法使其对除草剂或除草剂类别耐受的农作物。
本发明组合物包含任意混合比例的式I活性组分和式2.1-2.51活性组分,但是其中一种组分的量通常超过另一种组分的量。式I活性组分与式2.1-2.51混合配伍的混合比例(重量比)一般为1∶2000-2000∶1、尤其是200∶1-1∶200。
施用量可在宽的限度内变化,并取决于土壤性质、施用方法(芽前或苗后;种子包衣;播沟施用;非耕种施用等)、农作物植物、欲控制的杂草、主要的气候条件、和由施用方法控制的其它因素、施用时间和目标农作物。本发明活性组分混合物一般可以以1-5000g活性组分混合物/公顷的比例施用。
式I化合物与式式2.1-2.51化合物的混合物可以以未改性的形式使用,也就是说,以合成所获得的形式使用。然而,优选以常规方式将它们与制剂技术常用的助剂例如溶剂、固体载体或表面活性剂一起加工配制,例如配制成乳油、可直接喷雾或稀释的溶液、稀的乳剂、可湿性粉剂、可溶性粉剂、粉尘剂、粒剂或微胶囊。根据使用目的和主要环境来选择作为组合物性质的施用方法例如喷雾、雾化、撒布、润湿、撒施或浇泼。
制剂,即包含式I和式2.1-2.51化合物(活性组分)、以及适当时一种或多种固体或液体制剂助剂的组合物、制剂或混合物是以自身已知的方式制得的,例如通过将活性组分与制剂助剂例如溶剂或固体载体充分混合和/或研磨而制得。此外,在制剂的制备中可使用表面活性化合物(表面活性剂)。
溶剂和固体载体的实例描述在例如WO 97/34485第6页中。
根据欲配制的式I化合物的性质,合适的表面活性化合物是具有良好乳化、分散和润湿性质的非离子、阳离子和/或阴离子表面活性剂以及表面活性剂混合物。
合适的阴离子、非离子和阳离子表面活性剂描述在例如WO 97/34485第7和8页中。
制剂技术常用的表面活性剂也适用于本发明除草组合物的制备,这些表面活性剂特别描述在《McCutcheon洗涤剂和乳化剂年鉴》(″McCutcheon’s Detergents and Emulsifiers Annual″)MC PublishingCorp.,Ridgewood New Jersey,1981,Stache,H.,″Tensid-Taschenbuch″,Carl Hanser Verlag,Munich/Nienna,1981以及M.和J.Ash,《表面活性剂大全》(″Encyclopedia of Surfactants″),Vol 1-111,Chemical Publishing Co.,New York,1980-81中。
除草制剂通常含有0.1-99%重量、尤其是0.1-95%重量的包含式I化合物和式2.1-2.51化合物的活性组分混合物,1-99.9%重量的固体或液体制剂助剂,和0-25%重量、尤其是0.1-25%重量的表面活性剂。
然而,市售产品一般是配制成浓缩物,最终的使用者通常使用稀释的制剂。组合物还可以含有其它组分,例如稳定剂如植物油或环氧化植物油(环氧化椰子油、菜籽油或豆油),消泡剂例如硅油,防腐剂,粘度调节剂,粘合剂,增粘剂,以及肥料和其它活性组分。优选的制剂具有尤其是下列组成:(%=重量百分比)乳油:活性组分混合物:1-90%、优选5-20%表面活性剂: 1-30%、优选10-20%液体载体: 5-94%、优选70-85%粉剂:活性组分混合物:0.1-10%、优选0.1-5%固体载体: 99.9-90%、优选99.9-99%胶悬剂:活性组分混合物:5-75%、优选10-50%水: 94-24%、优选88-30%表面活性剂: 1-40%、优选2-30%可湿性粉剂:活性组分混合物:0.5-90%、优选1-80%表面活性剂: 0.5-20%、优选1-15%固体载体: 5-95%、优选15-90%粒剂:活性组分混合物:0.1-30%、优选0.1-15%固体载体: 99.5-70%、优选97-85%
下列实施例进一步举例说明了本发明,但不是限制本发明。F1.乳油 a) b) c) d)活性组分混合物 5% 10% 25% 50%十二烷基苯磺酸钙 6% 8% 6% 8%蓖麻油聚乙二醇醚 4% - 4% 4%(36mol氧化乙烯)辛基苯酚聚乙二醇醚 - 4% - 2%(7-8mol氧化乙烯)环己酮 - - 10% 20%芳烃混合物 85% 78% 55% 16%C9-C12
通过用水稀释,可由这样的乳油获得任意所需浓度的乳剂。F2.溶液 a) b) c) d)活性组分混合物 5% 10% 50% 90%1-甲氧基-3-(3-甲氧基丙氧基)-丙烷 - 20% 20% -聚乙二醇MW 400 20% 10% - -N-甲基-2-吡咯烷酮 - - 30% 10%芳烃混合物 75% 60% - -C9-C12
该溶液适于以微滴的形式使用。F3.可湿性粉剂 a) b) c) d)活性组分混合物 5% 25% 50% 80%木质素磺酸钠 4% - 3% -十二烷基硫酸钠 2% 3% - 4%二异丁基萘磺酸钠 - 6% 5% 6%辛基苯酚聚乙二醇醚 - 1% 2% -(7-8mol氧化乙烯)高度分散的硅酸 1% 3% 5% 10%高岭土 88% 62% 35% -
将活性组分与助剂充分混合,并将该混合物在合适的研磨机中磨碎,获得了可湿性粉剂,可以用水稀释以获得任意所需浓度的悬浮剂。F4.包衣粒剂 a) b) c)活性组分混合物 0.1% 5% 15%高度分散的硅酸 0.9% 2% 2%无机载体 99.0% 93% 83%(φ0.1-1mm)例如CaCO3或SiO2
将活性组分溶解在二氯甲烷中,通过喷雾施加到载体上,然后将溶剂真空蒸发。F5.包衣粒剂 a) b) c)活性组分混合物 0.1% 5% 15%聚乙二醇MW 200 1.0% 2% 3%高度分散的硅酸 0.9% 1% 2%无机载体 98.0% 92% 80%(φ0.1-1mm)例如CaCO3或SiO2
在混合器中将细研磨的活性组分均匀地施加到用聚乙二醇润湿的载体上。以该方式获得了无粉尘的包衣粒剂。F6.挤出粒剂 a) b) c) d)活性组分混合物 0.1% 3% 5% 15%木质素磺酸钠 1.5% 2% 3% 4%羧甲基纤维素 1.4% 2% 2% 2%高岭土 97.0% 93% 90% 79%
将活性组分混合,与助剂研磨,用水将该混合物润湿。将该混合物挤出,然后在气流中干燥。F7.粉剂 a) b) c)活性组分混合物 0.1% 1% 5%滑石粉 39.9% 49% 35%高岭土 60.0% 50% 60%
即用型粉尘剂是通过将活性组分与载体混合、并将混合物在合适的研磨机中研磨而获得的。F8.胶悬剂 a) b) c) d)活性组分混合物 3% 10% 25% 50%乙二醇 5% 5% 5% 5%壬基苯酚聚乙二醇醚 - 1% 2% -(15mol氧化乙烯)木质素磺酸钠 3% 3% 4% 5%羧甲基纤维素 1% 1% 1% 1%37%甲醛水溶液 0.2% 0.2% 0.2% 0.2%硅油乳液 0.8% 0.8% 0.8% 0.8%水 87% 79% 62% 38%
将细研磨的活性组分与助剂充分混合,获得了胶悬剂,通过用水稀释可由其获得任意所需浓度的悬浮液。
实际上更经常将式I化合物与式2.1-2.51混合伴侣单独配制,临用前在施用器中将其以所需混合比例以“桶混”的形式混合在一起。生物实施例:
当式I与2.1-2.51化合物的活性组分组合的作用大于单独施用的活性组分的作用之和时,即存在协同作用。
对于给定的两种除草剂组合,预计的除草作用We可如下计算(参见COLBY,S.R.,″计算除草剂组合的协同和拮抗反应″,《杂草》(Weeds)15,p.20-22,1967):
We=X+[Y·(100-X)/100]其中:X=与未处理的对照(=0%)相比,在用式I化合物以pkg/公顷的施用量处理时的除草作用百分比。Y=与未处理的对照相比,在用式2.1-2.51化合物以qkg/公顷的施用量处理时的除草作用百分比。We=在用式I和2.1-2.51化合物以p+qkg/公顷的施用量处理后,预计的除草作用(与未处理的对照相比,除草作用百分比)。
当实际上观测到的作用大于预计的We的值时,即存在协同作用。
在下列实施例中证实了式I化合物与式2.1-2.51化合物的组合的协同作用。实验描述-芽前测试:
将塑料盆内的标准土壤中播种单子叶和双子叶测试植物。播种后,立即通过喷雾施用水悬浮液形式的测试物(500升水/ha)。施用量取决于在大田条件和温室条件下确定的最适剂量。然后让测试植物在温室中于最适条件下生长。36天后评价测试(%作用,100%=植物已经死亡,0%=没有植物毒害作用)。本发明组合物的协同作用的实例如下表B1-B6所示:
混合物A含有915g/升式2.2a化合物和45g/升式3.1化合物作为活性组分。表B1:
表B2:
表B3:
表B4:
表B5:
表B6:
实验描述-苗后测试:
测试植物: | 化合物1.00l[25g/ha] | 混合物A[900g/ha] | 化合物1.001[25g/ha]+混合物A[900g/ha] | 依据Colby的We |
高粱 | 30 | 20 | 90 | 44 |
藜 | 0 | 0 | 100 | 0 |
黄花稔 | 0 | 70 | 100 | 70 |
测试植物: | 化合物1.001[12.5g/ha] | 混合物A[900g/ha] | 化合物1.001[12.5g/ha]+混合物A[900g/ha] | 依据Colby的We |
高粱 | 0 | 20 | 80 | 20 |
藜 | 0 | 0 | 95 | 0 |
黄花稔 | 0 | 70 | 95 | 70 |
测试植物: | 化合物1.001[6.25g/ha] | 混合物A[900g/ha] | 化合物1.001[6.25g/ha]+混合物A[900g/ha] | 依据Colby的We |
高粱 | 0 | 20 | 70 | 20 |
藜 | 0 | 0 | 95 | 0 |
黄花稔 | 0 | 70 | 95 | 70 |
测试植物: | 化合物1.001[25g/ha] | 混合物A[300g/ha] | 化合物1.001[25g/ha]+混合物A[300g/ha] | 依据Colby的We |
藜 | 0 | 0 | 90 | 0 |
番薯 | 30 | 0 | 100 | 30 |
黄花稔 | 0 | 0 | 40 | 0 |
测试植物: | 化合物1.001[12.5g/ha] | 混合物A[300g/ha] | 化合物1.001[12.5g/ha]+混合物A[300g/ha] | 依据Colby的We |
藜 | 0 | 0 | 80 | 0 |
番薯 | 0 | 0 | 60 | 0 |
黄花稔 | 0 | 0 | 40 | 0 |
测试植物: | 化合物1.001[6.25g/ha] | 混合物A[300g/ha] | 化合物1.001[6.25g/ha]+混合物A[300g/ha] | 依据Colby的We |
藜 | 0 | 0 | 80 | 0 |
番薯 | 0 | 0 | 60 | 0 |
黄花稔 | 0 | 0 | 40 | 0 |
将测试植物在塑料盆中于温室条件下生长至2-叶-3-叶期。使用标准土壤作为栽培基质。在2-叶-3-叶期,将除草剂以自身的形式并作为混合物施加到测试植物上。施加是用测试物在500升水/ha中的水悬浮液进行的。施用量取决于在大田条件和温室条件下确定的最适剂量。33天后评价测试(%作用,100%=植物已经死亡,0%=没有植物毒害作用)。本发明组合物的协同作用的实例如下表B7-B10所示:
混合物A含有915g/升式2.2a化合物和45g/升式3.1化合物作为活性组分。表B7:苗后测试:
表B8:苗后测试:
表B9:苗后测试:
表B10:苗后测试:
测试植物: | 化合物1.001[12.5g/ha] | 混合物A[900g/ha] | 化合物1.001[12.5g/ha]+混合物A[900g/ha] | 依据Colby的We |
番薯 | 0 | 0 | 80 | 0 |
蓼 | 0 | 20 | 100 | 20 |
苍耳 | 80 | 0 | 100 | 80 |
测试植物: | 化合物1.001[12.5g/ha] | 混合物A[300g/ha] | 化合物1.001[12.5g/ha]+混合物A[300g/ha] | 依据Colby的We |
番薯 | 0 | 0 | 80 | 0 |
蓼 | 0 | 0 | 70 | 0 |
苍耳 | 80 | 0 | 98 | 80 |
测试植物: | 化合物1.001[6.25g/ha] | 混合物A[900g/ha] | 化合物1.001[6.25g/ha]+混合物A[900g/ha] | 依据Colby的We |
番薯 | 0 | 0 | 70 | 0 |
蓼 | 0 | 20 | 70 | 20 |
苍耳 | 70 | 0 | 80 | 70 |
测试植物: | 化合物1.001[6.25g/ha] | 混合物A[300g/ha] | 化合物1.001[6.25g/ha]+混合物A[300g/ha] | 依据Colby的We |
番薯 | 0 | 0 | 80 | 0 |
蓼 | 0 | 0 | 70 | 0 |
苍耳 | 70 | 0 | 70 | 70 |
在下表中,是在14天后进行评价:表B11:芽前作用:
表B12:芽前作用:
表B13:芽前作用:
表B14:芽前作用:化合物2.13a相当于这样的式2.13化合物,其中R74是-CH2CH2CF3,Y1、Y2、Y3和Y4各是次甲基,Y5是氮,且Y6是甲基。
表B15:芽前作用:
表B16:芽前作用:
表B17:芽前作用:化合物2.4.a相当于其中R57是氯、R58是乙基、且R59是叔丁基的式2.4化合物。
表B18:芽前作用:
表B19:芽前作用:化合物2.3.a相当于其中R56是CH(Me)-CH2OMe的式2.3化合物。
表B20:芽前作用:化合物2.2.c相当于其中R53和R54是乙基,且R55是CH2OMe的式2.2化合物。
表B21:芽前作用:
测试植物: | 化合物E8[50g/ha] | 化合物2.18[500g/ha] | 化合物E8[50g/ha]+化合物2.18[500g/ha] | 依据Colby的We |
蓼 | 50 | 80 | 95 | 90 |
测试植物: | 化合物E8[100g/ha] | 化合物2.14[250g/ha] | 化合物E8[100g/ha]+化合物2.14[250g/ha] | 依据Colby的We |
蓼 | 50 | 50 | 90 | 75 |
测试植物: | 化合物E8[100g/ha] | 化合物2.14[125g/ha] | 化合物E8[100g/ha]+化合物2.14[125g/ha] | 依据Colby的We |
蓼 | 50 | 30 | 90 | 65 |
测试植物: | 化合物E8[100g/ha] | 化合物2.13a[60g/ha] | 化合物E8[100g/ha]+化合物2.13a[60g/ha] | 依据Colby的We |
蓼 | 50 | 80 | 95 | 90 |
测试植物: | 化合物E8[50g/ha] | 化合物2.30[60g/ha] | 化合物E8[50g/ha]+化合物2.30[60g/ha] | 依据Colby的We |
蓼 | 50 | 30 | 90 | 65 |
测试植物: | 化合物E8[50g/ha] | 化合物2.21[30g/ha] | 化合物E8[50g/ha]+化合物2.21[30g/ha] | 依据Colby的We |
蓼 | 50 | 50 | 100 | 75 |
测试植物: | 化合物E8[50g/ha] | 化合物2.4.a[125g/ha] | 化合物E8[50g/ha]+化合物2.4.a[125g/ha] | 依据Colby的We |
蓼 | 50 | 30 | 85 | 65 |
测试植物: | 化合物1.001[25g/ha] | 化合物2.2.b[300g/ha] | 化合物1.001[25g/ha]+化合物2.2.b[300g/ha] | 依据Colby的We |
藜 | 80 | 0 | 95 | 80 |
茄 | 80 | 40 | 98 | 88 |
莎草 | 0 | 0 | 50 | 0 |
测试植物: | 化合物1.001[12.5g/ha] | 化合物2.3.a[100g/ha] | 化合物1.001[12.5g/ha]+化合物2.3.a[100g/ha] | 依据Colby的We |
藜 | 80 | 20 | 90 | 84 |
茄 | 75 | 60 | 90 | 90 |
莎草 | 0 | 20 | 60 | 20 |
测试植物: | 化合物1.001[12.5g/ha] | 化合物2.2.c[100g/ha] | 化合物1.001[12.5g/ha]+化合物2.2.c[100g/ha] | 依据Colby的We |
藜 | 80 | 20 | 90 | 84 |
茄 | 75 | 50 | 95 | 88 |
莎草 | 0 | 0 | 30 | 0 |
化合物2.2.d相当于其中R53是乙基、R54是甲基、且R55是CH2O-CH2CH3的式2.2化合物。
表B22:芽前作用:
测试植物: | 化合物1.001[12.5g/ha] | 化合物2.2.d[100g/ha] | 化合物1.001[12.5g/ha]+化合物2.2.d[100g/ha] | 依据Colby的We |
茄 | 75 | 60 | 95 | 90 |
测试植物: | 化合物1.001[25g/ha] | 化合物2.30[100g/ha] | 化合物1.001[25g/ha]+化合物2.30[100g/ha] | 依据Colby的We |
莎草 | 10 | 0 | 60 | 10 |
在下表中,是在31天后进行评价:表B23:芽前作用:化合物2.4.a相当于其中R57是氯、R58是乙基、且R59是异丙基的式2.4化合物。
表B24:芽前作用:化合物2.4.b相当于其中R57是氯、R58是乙基、且R59是乙基的式2.4化合物。
表B25:芽前作用:化合物2.4.c相当于其中R57是氯、R58是乙基、且R59是叔丁基的式2.4化合物。
表B26:芽前作用:化合物2.4.d相当于其中R57是甲硫基、R58是乙基、且R59是叔丁基的式2.4化合物。
表B27:芽前作用:
表B28:芽前作用:化合物2.6.a相当于这样的式2.6化合物,其中R62是氢、R63是甲基、R64是氟、R65是氢、Y是氮、Z是次甲基、且R66是氟。
测试植物: | 化合物1.001[25g/ha] | 化合物2.4.a[250g/ha] | 化合物1.001[25g/ha]+化合物2.4.a[250g/ha] | 依据Colby的We |
蓼 | 0 | 20 | 80 | 20 |
测试植物: | 化合物1.001[25g/ha] | 化合物2.4.b[125g/ha] | 化合物1.001[25g/ha]+化合物2.4.b[125g/ha] | 依据Colby的We |
蓼 | 0 | 0 | 40 | 0 |
测试植物: | 化合物1.001[25g/ha] | 化合物2.4.c[250g/ha] | 化合物1.001[25g/ha]+化合物2.4.c[250g/ha] | 依据Colby的We |
番薯 | 70 | 0 | 90 | 70 |
苍耳 | 80 | 0 | 100 | 80 |
测试植物: | 化合物1.001[25g/ha] | 化合物2.4.d[250g/ha] | 化合物1.001[25g/ha]+化合物2.4.d[250g/ha] | 依据Colby的We |
番薯 | 70 | 0 | 80 | 70 |
苍耳 | 80 | 10 | 95 | 82 |
测试植物: | 化合物1.001[25g/ha] | 化合物2.14[125g/ha] | 化合物1.001[25g/ha]+化合物2.14[125g/ha] | 依据Colby的We |
番薯 | 70 | 0 | 85 | 70 |
苍耳 | 80 | 20 | 100 | 84 |
测试植物: | 化合物1.001[50g/ha] | 化合物2.6.a[30g/ha] | 化合物1.001[50g/ha]+化合物2.6.a[30g/ha] | 依据Colby的We |
蓼 | 0 | 30 | 90 | 30 |
在下表中,是在21天后进行评价。表B29:苗后作用:化合物2.7.a相当于其中R67是-C(O)-S-正辛基的式2.7化合物。
表B30:苗后作用:
表B31:苗后作用:
表B32:苗后作用:
表B33:苗后作用:化合物2.12.a相当于其中R73是NH2的式2.12化合物。
表B34:苗后作用:
表B35:苗后作用:化合物2.1.a相当于其中R52是氢、且R51是乙基的式2.1化合物。
表B36:苗后作用:化合物2.1.b相当于其中R51是CH2OMe、且R52是氢的式2.1化合物。
测试植物: | 化合物1.001[25g/ha] | 化合物2.7.a[250g/ha] | 化合物1.001[25g/ha]+化合物2.7.a[250g/ha] | 依据Colby的We |
番薯 | 30 | 10 | 80 | 30 |
蓼 | 75 | 0 | 95 | 75 |
苍耳 | 90 | 10 | 100 | 91 |
测试植物: | 化合物1.001[25g/ha] | 化合物2.19[250g/ha] | 化合物1.001[25g/ha]+化合物2.19[250g/ha] | 依据Colby的We |
番薯 | 30 | 60 | 95 | 72 |
测试植物: | 化合物1.001[25g/ha] | 化合物2.16[360g/ha] | 化合物1.001[25g/ha]+化合物2.16[360g/ha] | 依据Colby的We |
番薯 | 30 | 20 | 70 | 46 |
蓼 | 75 | 10 | 90 | 84 |
测试植物: | 化合物1.001[12.5g/ha] | 化合物2.33[360g/ha] | 化合物1.001[12.5g/ha]+化合物2.33[360g/ha] | 依据Colby的We |
蓼 | 30 | 0 | 90 | 30 |
测试植物: | 化合物1.001[25g/ha] | 化合物2.12.a[400g/ha] | 化合物1.001[25g/ha]+化合物2.33.a[400g/ha] | 依据Colby的We |
番薯 | 30 | 20 | 90 | 44 |
测试植物: | 化合物1.001[12.5g/ha] | 化合物2.25[2g/ha] | 化合物1.001[12.5g/ha]+化合物2.25[2g/ha] | 依据Colby的We |
番薯 | 30 | 0 | 50 | 30 |
蓼 | 30 | 0 | 40 | 30 |
测试植物: | 化合物1.001[12.5g/ha] | 化合物2.1.a[30g/ha] | 化合物1.001[12.5g/ha]+化合物2.1.a[30g/ha] | 依据Colby的We |
蓼 | 30 | 30 | 70 | 51 |
测试植物: | 化合物1.001[25g/ha] | 化合物2.1.b[30g/ha] | 化合物1.001[25g/ha]+化合物2.1.b[30g/ha] | 依据Colby的We |
蓼 | 75 | 30 | 90 | 83 |
在下表中,是在23天后进行评价:表B37:芽前作用:化合物2.13.b相当于这样的式2.13化合物,其中R74是-COOMe,Y1、Y2、Y3和Y4各是次甲基,Y5是次甲基,且Y6和Y7是二氟甲氧基。
表B38:芽前作用:
表B39:芽前作用:化合物2.13.d相当于这样的式2.13化合物,其中Y1、Y2、Y3和Y4是次甲基,R74是三氟甲基,Y5是氮,Y6是三氟甲基,且Y7是甲氧基。
测试植物: | 化合物1.001[6g/ha] | 化合物2.13.b[15g/ha] | 化合物1.001[6g/ha]+化合物2.13.b[15g/ha] | 依据Colby的We |
藜 | 50 | 70 | 95 | 85 |
测试植物: | 化合物1.001[6g/ha] | 化合物2.13.c[60g/ha] | 化合物1.001[6g/ha]+化合物2.13.c[60g/ha] | 依据Colby的We |
藜 | 50 | 10 | 85 | 55 |
测试植物: | 化合物1.001[6g/ha] | 化合物2.13.d[7.5g/ha] | 化合物1.001[6g/ha]+化合物2.13.d[7.5g/ha] | 依据Colby的We |
苋 | 10 | 80 | 95 | 82 |
已经令人惊奇地表明,特定的安全剂适于和本发明协同组合物混合。因此,本发明还涉及用于控制有用植物农作物、尤其是玉米农作物中的禾草和杂草的选择性除草组合物,所述组合物包含式I化合物、一种或多种选自式2.1-2.51化合物的化合物、和安全剂(对抗剂、解毒剂),所述组合物保护有用植物、但是不保护杂草,并对抗除草剂的植物毒害作用,以及这样的组合物在控制有用植物中的杂草中的应用。
本发明还提供了选择性除草组合物,所述组合物除了包含常用惰性制剂助剂例如载体、溶剂和润湿剂以外,还包含下列组分的混合物作为活性组分:a)除草协同有效量的式I化合物和一种或多种选自式2.1-2.51化合物的化合物,和b)除草拮抗有效量的选自下列的化合物:式3.1化合物和式3.2化合物和式3.3化合物和式3.4化合物和式3.5化合物和式3.6化合物和式3.7化合物和式3.8化合物和式3.9化合物Cl2CHCON(CH2CH=CH2)2 (3.9),和式3.10化合物和式3.11化合物和式3.12化合物及其乙酯和式3.13化合物和式3.14化合物和式3.15化合物和式3.16化合物
本发明还提供了选择性除草组合物,所述组合物除了包含常用惰性制剂助剂例如载体、溶剂和润湿剂以外,还包含下列组分的混合物作为活性组分:a)除草有效量的式I化合物,和b)除草拮抗有效量的选自式3.1、3.2、3.3、3.4、3.5、3.6、3.7、3.8、3.9、3.10、3.11、3.12、3.13、3.14、3.15和3.16化合物的化合物。
优选的本发明组合物包含选自式3.1、3.3和3.8化合物的化合物作为安全剂。这样安全剂尤其适用于包含上述优选的式I化合物和任选的式2.1-2.51化合物的本发明组合物。
已经表明,式I化合物与式3.1化合物的组合是特别有效的组合物,化合物1.001是特别优选的式I化合物。该组合物优选与式2.2a化合物一起使用(2.2a,aRS,1’S(-)N-(1’-甲基-2’-甲氧基乙基)-N-氯乙酰基-2-乙基-6-甲基苯胺)。
本发明还涉及选择性地控制有用植物农作物中的杂草的方法,所述方法包括用除草有效量的式I除草剂、视情况而定的一种或多种选自式2.1-2.51化合物的除草剂、和除草拮抗有效量的式3.1-3.16安全剂来处理有用植物、种子或其切条、或其耕作区域。
式3.1-3.16化合物是已知的,并描述在例如《农药手册》,第11版,英国作物保护委员会,1997中,条目号为61(式3.1,解草嗪)、304(式3.2,解草啶)、154(式3.3,解草酯)、462(式3.4,吡咯解草酯)、377(式3.5,解草恶唑)、363(式3.8,氟草肟)、213(式3.9,烯丙酰草胺)和350(式3.10,解草胺)。式3.11化合物的名称是MON 4660(Monsanto),并描述在例如EP-A-0 436 483中。
式3.6化合物(AC 304 415)描述在例如EP-A-0 613 618中,式3.7化合物描述在DE-A-2 948 535中。式3.12化合物描述在DE-A-4 331 448中,式3.13化合物描述在DE-A-3 525 205中。式3.14化合物是已知的,描述在例如US-A-5 215 570中,式3.15化合物描述在例如EP-A-0 929543中。式3.16化合物描述在WO 99/00020中。除了式3.16化合物以外,描述在WO 99/00020中的其它3-(5-四唑基-羰基)-2-喹诺酮,尤其是在第21-29页的表1和2中具体公开的化合物也适于保护农作物植物抗式I化合物的植物毒害作用。
作为可通过式3.1-3.16安全剂拮抗上述除草剂损害作用而得以保护的农作物植物,可尤其提及的有禾谷类植物、棉花、大豆、甜菜、甘蔗、种植园农作物、油菜、玉米和稻,更尤其是玉米。“农作物”还指通过常规育种或基因工程方法使其对除草剂或除草剂类别耐受的农作物。
欲控制的杂草既可以是单子叶杂草,也可以是双子叶杂草,例如繁缕属、剪股颖属、马唐属、燕麦属、阿披拉草属、臂形草属、虉草属、狗尾草属、芥属、毒麦属、茄属、稗属、藨草属、雨久花属、慈菇属、黍属、雀麦属、看麦娘属、石茅高梁、双色高梁、筒轴茅属、莎草属、苘麻属、黄花稔属、苍耳属、苋属、藜属、番薯属、苘蒿属、猪殃殃属、堇菜属和婆婆纳属。
耕作区域包括农作物植物已经生长或者已经将这些农作物植物的种子播种的土地区域,以及准备用这样的农作物植物耕作的土地。
根据预期应用,式3.1-3.16安全剂可以在农作物植物种子的预处理中使用(种子或切条的包衣),或者可以在播种前或播种后引入到土壤中。然而,其可以在植物出芽后单独施用或者与除草剂一起施用。因此,用安全剂处理植物或种子一般可以在独立于施用除草剂的时间进行。然而,也可以通过同时施用除草剂和安全剂(例如以桶混的形式)来处理植物。安全剂的施用量与除草剂的施用量的比例主要取决于施用方法。对于通过使用包含安全剂和除草剂的组合的桶混物或者通过单独施用安全剂和除草剂来进行的大田处理,除草剂与安全剂的比例一般为100∶1-1∶10、优选20∶1-1∶1。对于大田处理,通常施用0.001-1.0千克安全剂/公顷、优选0.001-0.25千克安全剂/公顷。
除草剂的施用量一般为0.001-5kg/ha,但是优选为0.005-0.5kg/ha。
本发明组合物适用于农业中的所有常用方法,例如芽前施用、苗后施用和种子包衣。
对于种子包衣,一般施用0.001-10g安全剂/kg种子、优选0.05-2g安全剂/kg种子。当在播种前不久安全剂以液体形式通过浸泡施用时,有利起见,所用的安全剂溶液含有浓度为1-10000ppm、优选为100-1000ppm的安全剂。
为了施用,有利起见,将式3.1-3.16安全剂或者这些安全剂与式I除草剂以及视情况而定的一种或多种选自式2.1-2.51的除草剂的组合与制剂技术中的常用制剂一起加工配制,例如配制成乳油、可包衣糊剂、可直接喷雾或稀释的溶液、可湿性粉剂、可溶性粉剂、粉剂、粒剂或微胶囊。
这样的制剂描述在例如WO 97/34485第9-13页中。制剂是以自身已知的方式制得的,例如通过将活性组分与制剂助剂例如溶剂或固体载体充分混合和/或研磨而制得。此外,在制剂的制备中可使用表面活性化合物(表面活性剂)。溶剂和固体载体的实例描述在例如WO 97/34485第6页中。
根据欲配制的式I、2.1-2.51和3.1-3.16化合物的性质,可使用的表面活性化合物是具有良好乳化、分散和润湿性质的非离子、阳离子和/或阴离子表面活性剂以及表面活性剂混合物。合适的阴离子、非离子和阳离子表面活性剂描述在例如WO 97/34485第7和8页中。制剂技术常用的表面活性剂也适用于本发明除草组合物的制备,这些表面活性剂特别描述在《McCutcheon洗涤剂和乳化剂年鉴》″McCutcheon’s Detergentsand Emulsifiers Annual″MC Publishing Corp.,Ridgewood New Jersey,1981,Stache,H.,″Tensid-Taschenbuch″,Carl Hanser Verlag,Munich/Nienna,1981和M.and J.Ash,《表面活性剂大全》(″Encyclopedia of Surfactants″),Vol 1-111,Chemical PublishingCo.,New York,1980-81中。
除草制剂通常含有0.1-99%重量、尤其是0.1-95%重量的包含式I化合物、选自式2.1-2.51化合物的化合物、和式3.1-3.16化合物的活性组分混合物,1-99.9%重量的固体或液体制剂助剂,和0-25%重量、尤其是0.1-25%重量的表面活性剂。然而,市售产品一般是配制成浓缩物,最终的使用者通常使用稀释的制剂。
组合物还可以含有其它组分,例如稳定剂如植物油或环氧化植物油(环氧化椰子油、菜籽油或豆油),消泡剂例如硅油,防腐剂,粘度调节剂,粘合剂,增粘剂,以及肥料和其它活性组分。在保护植物以对抗式I和2.1-2.51除草剂的损害作用的过程中,为了使用式3.1-3.16安全剂或包含它们的组合物,可使用多种不同的方法和技术,例如下列:i)种子包衣a)通过在容器中振摇用式3.1-3.16化合物的可湿性粉剂将种子包衣,直至粉剂在种子表面上分布均匀(干法包衣)。在该方法中,每100kg种子使用大约1-500g式3.1-3.16化合物(4g-2kg可湿性粉剂)。b)按照a)的方法,用式3.1-3.16化合物的乳油将种子包衣(湿法包衣)。c)通过将种子在含有100-1000ppm式3.1-3.16化合物的液体中浸泡1-72小时,然后任选将种子干燥来进行包衣(浸泡包衣)。
给种子包衣或处理发芽的幼苗是优选的施用方法,因为用活性组分处理完全是针对目标农作物。通常每100kg种子使用1-1000g解毒剂、优选5-250g解毒剂,但是根据使得能够还加入其它组分或微量营养素的方法,该浓度限度可向上或向下改变(重复包衣)。ii)作为桶混物施用
使用解毒剂与除草剂的混合物(二者的重量比为10∶1-1∶100)的液体制剂,除草剂的施用量为0.005-5.0kg/公顷。这样的桶混物在播种之前或之后施用。iii)施用到播沟中
将式3.1-3.16混合物以乳油、可湿性粉剂或粒剂的形式施加到开放的播种种子的犁沟内。一旦种子犁沟已覆盖,即以常规方式采用芽前法施用除草剂。iv)控制活性组分的释放
将在溶液中的式3.1-3.16化合物施加到无机物载体或聚合颗粒(尿素/甲醛)上,并干燥。如果需要的话,还可以施加上使得活性组分在特定时间内以计量的量释放的包衣(包衣粒剂)。
优选的制剂尤其具有下列组成:(%=重量百分比)乳油:活性组分混合物:1-90%、优选5-20%表面活性剂: 1-30%、优选10-20%液体载体: 5-94%、优选70-85%粉剂:活性组分混合物:0.1-10%、优选0.1-5%固体载体: 99.9-90%、优选99.9-99%胶悬剂:活性组分混合物:5-75%、优选10-50%水: 94-24%、优选88-30%表面活性剂: 1-40%、优选2-30%可湿性粉剂:活性组分混合物:0.5-90%、优选1-80%表面活性剂: 0.5-20%、优选1-15%固体载体: 5-95%、优选15-90%粒剂:活性组分混合物:0.1-30%、优选0.1-15%固体载体: 99.5-70%、优选97-85%
下列实施例进一步举例说明了本发明,但不是限制本发明。式I除草剂、任选的式2.1-2.51除草剂、和式3.1-3.16安全剂的混合物的制剂实施例(%=重量百分比)F1.乳油 a) b) c) d)活性组分混合物 5% 10% 25% 50%十二烷基苯磺酸钙 6% 8% 6% 8%蓖麻油聚乙二醇醚 4% - 4% 4%(36mol氧化乙烯)辛基苯酚聚乙二醇醚 - 4% - 2%(7-8mol氧化乙烯)环己酮 - - 10% 20%芳烃混合物 85% 78% 55% 16%C9-C12
通过用水稀释,可由这样的乳油获得任意所需浓度的乳剂。F2.溶液 a) b) c) d)活性组分混合物 5% 10% 50% 90%1-甲氧基-3-(3-甲氧基- - 20% 20% -丙氧基)-丙烷聚乙二醇MW 400 20% 10% - -N-甲基-2-吡咯烷酮 - - 30% 10%芳烃混合物 75% 60% - -C9-C12
该溶液适于以微滴的形式使用。F3.可湿性粉剂 a) b) c) d)活性组分混合物 5% 25% 50% 80%木质素磺酸钠 4% - 3% -十二烷基硫酸钠 2% 3% - 4%二异丁基萘磺酸钠 - 6% 5% 6%辛基苯酚聚乙二醇醚 - 1% 2% -(7-8mol氧化乙烯)高度分散的硅酸 1% 3% 5% 10%高岭土 88% 62% 35% -
将活性组分与助剂充分混合,并将该混合物在合适的研磨机中磨碎,获得了可湿性粉剂,可以用水稀释以获得任意所需浓度的悬浮剂。F4.包衣粒剂 a) b) c)活性组分混合物 0.1% 5% 15%高度分散的硅酸 0.9% 2% 2%无机载体 99.0% 93% 83%(φ0.1-1mm)例如CaCO3或SiO2
将活性组分溶解在二氯甲烷中,通过喷雾施加到载体上,然后将溶剂真空蒸发。F5.包衣粒剂 a) b) c)活性组分混合物 0.1% 5% 15%聚乙二醇MW 200 1.0% 2% 3%高度分散的硅酸 0.9% 1% 2%无机载体 98.0% 92% 80%(φ0.1-1mm)例如CaCO3或SiO2
在混合器中将细研磨的活性组分均匀地施加到用聚乙二醇润湿的载体上。以该方式获得了无粉尘的包衣粒剂。F6.挤出粒剂 a) b) c) d)活性组分混合物 0.1% 3% 5% 15%木质素磺酸钠 1.5% 2% 3% 4%羧甲基纤维素 1.4% 2% 2% 2%高岭土 97.0% 93% 90% 79%
将活性组分混合,与助剂研磨,用水将该混合物润湿。将该混合物挤出,然后在气流中干燥。F7.粉尘剂 a) b) c)活性组分混合物 0.1% 1% 5%滑石粉 39.9% 49% 35%高岭土 60.0% 50% 60%
即用型粉尘剂是通过将活性组分与载体混合、并将混合物在合适的研磨机中研磨而获得的。F8.胶悬剂 a) b) c) d)活性组分混合物 3% 10% 25% 50%乙二醇 5% 5% 5% 5%壬基苯酚聚乙二醇醚 - 1% 2% -(15mol氧化乙烯)木质素磺酸钠 3% 3% 4% 5%羧甲基纤维素 1% 1% 1% 1%37%甲醛水溶液 0.2% 0.2% 0.2% 0.2%硅油乳液 0.8% 0.8% 0.8% 0.8%水 87% 79% 62% 38%
将细研磨的活性组分与助剂充分混合,获得了胶悬剂,通过用水稀释可由其获得任意所需浓度的悬浮液。
实际上更经常将式I化合物、式2.1-2.51化合物和式3.1-3.16化合物单独配制,临用前在施用器中将其以所需混合比例以“桶混”的形式混合在一起。
下列实施例举例说明了式3.1-3.16安全剂保护农作物植物对抗式I除草剂的植物毒害作用的能力。生物实施例:安全作用
将测试植物在塑料盆中于温室条件下生长至4-叶期。在该阶段将单独的除草剂、除草剂与作为安全剂测试的化合物的混合物施加到测试植物上。以用500升水/公顷由25%可湿性粉剂(实施例F3,b)制得的测试化合物的水悬浮液的形式施用。施用4周后,使用百分比标度评价除草剂对农作物植物例如玉米和禾谷类植物的毒害作用,100%是指测试植物已经死亡,0%是指没有任何植物毒害作用。
在该测试中获得的结果证实了式3.1-3.16化合物可显著减轻由式I除草剂与一种或多种式2.1-2.51除草剂的组合所引起的农作物植物损害。安全作用的实例如下表B40所示:表B40:
测试植物 | 化合物1.001[50g/ha] | 化合物1.001[50g/ha]+化合物3.3[50g/ha] | 化合物1.001[50g/ha]+化合物3.1[50g/ha] | 化合物1.001[50g/ha]+化合物3.8[50g/ha] |
玉米 | 50 | 5 | 5 | 0 |
苘麻 | 100 | 100 | 100 | 100 |
狗尾草 | 100 | 100 | 100 | 100 |
当依据实施例F1、F2和F4-F8配制混合物时,获得了相同结果。
Claims (16)
1.选择性除草组合物,所述组合物除了含有常规惰性制剂助剂以外,还含有下列组分的混合物作为活性组分:a)除草有效量的式I化合物或其农业可接受盐其中每个R独立地为氢、C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基、C1-C6卤代烷硫基、C1-C6卤代烷基亚磺酰基、C1-C6卤代烷基磺酰基、C1-C6烷氧基羰基、C1-C6烷基羰基、C1-C6烷基氨基、二(C1-C6烷基)氨基、C1-C6烷基氨基磺酰基、二(C1-C6烷基)氨基磺酰基、-N(R1)-S-R2、-N(R3)-SO-R4、-N(R5)-SO2-R6、硝基、氰基、卤素、羟基、氨基、苄硫基、苄基亚磺酰基、苄基磺酰基、苯基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基;其中所述苯基自身可被下列基团单取代、二取代或三取代:C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R45、NR46R47、卤素、氰基、硝基、苯基或苄硫基,其中后面所述的苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;或者每个R独立地为5-10元单环或稠合二环系,所述环系可以是芳环或部分饱和环,并且可以含有1-4个选自氮、氧和硫的杂原子;其中所述环系直接与吡啶环连接,或者经由C1-C4亚烷基与吡啶环连接,并且每个环系不可以含有2个以上的氧原子,不可以含有2个以上的硫原子,所述环系自身可被下列基团单取代、二取代或三取代:C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R7、NR8R9、卤素、氰基、硝基、苯基或苄硫基,其中所述苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代,并且在杂环中的氮上的取代基不是卤素;或者每个R独立地为C1-C4烷氧基-C1-C4烷基或C1-C4烷氧基-C1-C4烷氧基-C1-C4烷基;m是1、2、3或4;R1、R3和R5分别独立地为氢或C1-C6烷基;R2是NR10R11、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基或苯基,其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;R4是NR12R13、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基或苯基,其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;R6是NR14R15、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基或苯基,其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;R7和R45分别独立地为C1-C3烷氧基、C2-C4烷氧基羰基、C1-C3烷硫基、C1-C3烷基亚磺酰基、C1-C3烷基磺酰基或苯基,其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;R8、R10、R12、R14和R46分别独立地为氢或C1-C6烷基;R9、R11、R13、R15和R47分别独立地为C1-C6烷基或C1-C6烷氧基;Q是基团Q1 其中R16、R17、R18和R19分别独立地为氢、羟基、C1-C4烷基、C2-C6链烯基、C2-C6炔基、C1-C4烷氧基羰基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-NHS(O)2、C1-C4卤代烷基、-NH-C1-C4烷基、-N(C1-C4烷基)2、C1-C6烷氧基、氰基、硝基、卤素、或苯基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基、COOH或氰基;或者R16、R17、R18和R19当中的两个相邻取代基形成C2-C6亚烷基桥;R20是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R21R22N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基;且R21和R22分别独立地为氢或C1-C4烷基;或者是基团Q2 其中R23是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4-链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R24R25N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基;R24和R25分别独立地为氢或C1-C4烷基;且Y是氧、硫、化学键或C1-C4亚烷基桥;或者是Q3 其中R44、R37、R38和R39分别独立地为氢、C1-C6烷基、C1-C6卤代烷基、C2-C6链烯基、C2-C6炔基、C1-C6烷氧基羰基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6烷基-NHS(O)2、C1-C6烷基氨基、二(C1-C6烷基)氨基、羟基、C1-C6烷氧基、C3-C6链烯氧基、C3-C6炔氧基、羟基-C1-C6烷基、C1-C4烷基-磺酰基氧基-C1-C6烷基、甲苯磺酰基氧基-C1-C6烷基、卤素、氰基、硝基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-S(O)2O、C1-C6卤代烷硫基、C1-C6卤代烷基亚磺酰基、C1-C6卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C6烷硫基-N(C1-C4烷基)、C1-C6烷基亚磺酰基-N(C1-C4烷基)、C1-C6烷基磺酰基-N(C1-C4烷基)、卤素、硝基、COOH或氰基;或者相邻的R44和R37或R38和R39一起为C3-C6亚烷基;W是氧、硫、亚磺酰基、磺酰基、-CR41R42-、-C(O)-或-NR43-;R41是氢、C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基-C1-C4烷基、C1-C4烷硫基-C1-C4烷基、C1-C4烷基羰基氧基-C1-C4烷基、C1-C4烷基磺酰基氧基-C1-C4烷基、甲苯磺酰基氧基-C1-C4烷基、二(C1-C3烷氧基烷基)甲基、二(C1-C3烷硫基烷基)甲基、(C1-C3烷氧基烷基)-(C1-C3烷硫基烷基)甲基、C3-C5氧杂环烷基、C3-C5硫杂环烷基、C3-C4二氧杂环烷基、C3-C4二硫杂环烷基、C3-C4氧硫杂环烷基、甲酰基、C1-C4烷氧基羰基、或苯基,所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C6烷硫基-N(C1-C4烷基)、C1-C6烷基亚磺酰基-N(C1-C4烷基)、C1-C6烷基磺酰基-N(C1-C4烷基)、卤素、硝基、COOH或氰基;或者R42与R39一起为C1-C6亚烷基;R42是氢、C1-C4烷基或C1-C4卤代烷基;R40是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R96R97N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基;R96和R97分别独立地为氢或C1-C4烷基;R43是氢、C1-C4烷基、C1-C4烷氧基羰基、或苯基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基;或者是基团Q4 其中R30是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R31R32N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基;且R31和R32分别独立地为氢或C1-C4烷基;R33和R34分别独立地为氢、羟基、C1-C4烷基、C2-C6链烯基、C2-C6炔基、C1-C4烷氧基羰基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-NHS(O)2、C1-C4卤代烷基、-NH-C1-C4烷基、-N(C1-C4烷基)2、C1-C6烷氧基、氰基、硝基、卤素、或苯基,其中所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4-烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基、COOH或氰基;或者R33和R34一起形成C2-C6亚烷基桥;且R35是氢、C1-C4烷基、C1-C4烷氧基羰基、或苯基,所述苯基自身可被下列基团取代:C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基、COOH或氰基;或者是基团Q5 其中Z是硫、SO或SO2;R01是氢、C1-C8烷基、被下列基团取代的C1-C8烷基:卤素、C1-C4烷氧基、C1-C4烷硫基、C1-C4烷基磺酰基、C1-C4烷基亚磺酰基、羟基、氰基、硝基、-CHO、-CO2R02、-COR03、-COSR04、-NR05R06、CONR036R037、或苯基,所述苯基自身可被下列基团取代:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7-环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR025R026、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR015CO2R027;或者R01是C2-C8链烯基或被下列基团取代的C2-C8链烯基:卤素、C1-C4烷氧基、C1-C4烷硫基、C1-C4烷基磺酰基、C1-C4烷基亚磺酰基、-CONR032R033、氰基、硝基、-CHO、-CO2R038、-COR039、-COS-C1-C4烷基、-NR034R035、或苯基,所述苯基自身可被下列基团取代:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR040R041、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR043CO2R042;或者R01是C3-C6炔基或被下列基团取代的C3-C6炔基:卤素、C1-C4卤代烷基、氰基、-CO2R044、或苯基,所述苯基自身可被下列基团取代:C1-C4烷基、C1-C6卤代烷基、C1-C4-烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4-烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR028R029、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR031CO2R030;或者R01是C3-C7环烷基或被下列基团取代的C3-C7环烷基:C1-C4烷基、C1-C4烷氧基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、或苯基,所述苯基自身可被下列基团取代:卤素、硝基、氰基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷硫基、C1-C4卤代烷硫基、C1-C4烷基或C1-C4卤代烷基;或者R01是C1-C4亚烷基-C3-C7环烷基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C2-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4-烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR045R046、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基或-NR048CO2R047;或者R01是C1-C4亚烷基苯基、COR07或4-6元杂环基;R02、R038、R044和R066分别独立地为氢、C1-C4烷基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)-SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR049R050、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、-C1-C4-烷基苯基或-NR052CO2R053;R03、R039和R067分别独立地为C1-C4烷基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)-SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR068R054、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、-(CH2)t-苯基或-NR056CO2R055;R04是C1-C4烷基;R05是氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基、C3-C7环烷基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2H、N(C3-C6炔基)-SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2H、N(C3-C7环烷基)-SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR057R058、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR060CO2R059;R06是氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基、C3-C7环烷基、苯基、或被下列基团取代的苯基:C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4-烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)-SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR061R062、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR064CO2R063;R07是苯基、C1-C4烷基、C1-C4烷氧基或-NR08R09;R08和R09分别独立地为C1-C4烷基、苯基、或被下列基团取代的苯基:卤素、硝基、氰基、C1-C4烷基、C1-C4烷氧基、C1-C4烷硫基、-CO2R066、-COR067、C1-C4烷基磺酰基、C1-C4烷基亚磺酰基或C1-C4卤代烷基;或者R08和R09一起形成可被氧、NR065或S间隔的5-元或6-元环;R015、R031、R043、R048、R052、R056、R060和R064分别独立地为氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基或C3-C7环烷基;R025、R026、R027、R028、R029、R030、R032、R033、R034、R035、R036、R037、R040、R041、R042、R045、R046、R047、R049、R050、R053、R054、R055、R057、R058、R059、R061、R062、R053、R065和R068分别独立地为氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基、C3-C7环烷基、苯基、或被下列基团取代的苯基:卤素、硝基、氰基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷硫基、C1-C4卤代烷硫基、C1-C4烷基或C1-C4卤代烷基;且R36是C1-C4烷基、C1-C4卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基、或被下列基团取代的C3-C6环烷基:卤素、C1-C4烷基、C1-C4卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C4烷氧基羰基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4烷基羰基、二(C1-C4烷基)氨基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基-S(O)2O、C1-C4卤代烷基-S(O)2O、或苯基,所述苯基自身可被下列基团取代:卤素、C1-C4烷基、C1-C4卤代烷基、C3-C6链烯基、C3-C6炔基、氰基、硝基或COOH;和b)协同有效量的一种或多种选自下列的化合物:式2.1化合物其中R51是CH2-OMe、乙基或氢;R52是氢,或者R51与R52一起形成基团-CH=CH-CH=CH-;和式2.2化合物其中R53是乙基,R54是甲基或乙基,且R55是-CH(Me)-CH2OMe、<S>-CH(Me)-CH2OMe、CH2OMe或CH2O-CH2CH3;和式2.3化合物其中R56是CH(Me)-CH2OMe或<S>CH(Me)-CH2OMe;和式2.4化合物其中R57是氯、甲氧基或甲硫基,R58是乙基,且R59是乙基、异丙基、-C(CN)(CH3)-CH3或叔丁基;和式2.5化合物其中R60是乙基或正丙基,R61是COO-1/2Ca++、-CH2-CH(Me)S-CH2CH3或基团且X是氧、N-O-CH2CH3或N-O-CH2CH=CH-Cl;和式2.6化合物其中R62是氢、甲氧基或乙氧基,R63是氢、甲基、甲氧基或氟,R64是COOMe、氟或氯,R65是氢或甲基,Y是次甲基、C-F或氮,Z是次甲基或氮,且R66是氟或氯;和式2.7化合物
其中R67是氢或-C(O)-S-正辛基;和式2.8化合物其中R68是溴或碘;和式2.9化合物其中R69是氯或硝基;和式2.10化合物其中R70是氟或氯,且R71是-CH2-CH(Cl)-COOCH2CH3或-NH-SO2Me;和式2.11化合物其中R72是三氟甲基或氯;和式2.12化合物其中R73是NH2或<S>NH2;和式2.13化合物其中Y1是氮、次甲基、NH-CHO或N-Me,Y2是氮、次甲基或C-I,Y3是次甲基,Y4是次甲基,或者Y3和Y4一起是硫或C-Cl,Y5是氮或次甲基,Y6是甲基、二氟甲氧基、三氟甲基或甲氧基,Y7是甲氧基或二氟甲氧基,且R74是CONMe2、COOMe、COOC2H5、三氟甲基、CH2-CH2CF3或SO2CH2CH3,或其钠盐;和式2.13.c化合物和式2.14化合物和式2.15化合物和式2.16化合物和式2.17化合物和式2.18化合物和式2.19化合物和式2.20化合物和式2.21化合物和式2.22化合物和式2.23化合物和式2.24化合物和式2.25化合物和式2.26化合物和式2.27化合物和式2.28化合物和式2.29化合物和式2.30化合物和式2.31化合物和式2.32化合物和式2.33化合物和式2.34化合物和式2.35化合物和式2.36化合物和式2.37化合物和式2.38化合物和式2.39化合物和式2.40化合物和式2.41化合物和式2.42化合物和式2.43化合物和式2.44化合物和式2.45化合物和式2.46化合物和式2.47化合物和式2.48化合物和式2.49化合物和式2.50化合物和式2.51化合物
2.权利要求1的组合物,其中在式I中其中每个R独立地为氢、C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基、C1-C6卤代烷硫基、C1-C6卤代烷基亚磺酰基、C1-C6卤代烷基磺酰基、C1-C6烷氧基羰基、C1-C6烷基羰基、C1-C6烷基氨基、二(C1-C6烷基)氨基、C1-C6烷基氨基磺酰基、二(C1-C6烷基)氨基磺酰基、-N(R1)-S-R2、-N(R3)-SO-R4、-N(R5)-SO2-R6、硝基、氰基、卤素、羟基、氨基、苄硫基、苄基亚磺酰基、苄基磺酰基、苯基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基;其中所述苯基自身可被下列基团单取代、二取代或三取代:C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R45、NR46R47、卤素、氰基、硝基、苯基或苄硫基,其中后面提及的苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代;或者每个R独立地为5-10元单环或稠合二环系,所述环系可以是芳环或部分饱和环,并且可以含有1-4个选自氮、氧和硫的杂原子;其中所述环系直接与吡啶环连接,或者经由C1-C4亚烷基与吡啶环连接,并且每个环系不可以含有2个以上的氧原子,不可以含有2个以上的硫原子,所述环系自身可被下列基团单取代、二取代或三取代:C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R7、NR8R9、卤素、氰基、硝基、苯基或苄硫基,其中所述苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代,并且在杂环中的氮上的取代基不是卤素。
3.权利要求1的组合物,其中所述组合物包含式Ia化合物作为式I化合物其中R48是C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基、C1-C6卤代烷基、或5-10元单环或稠合二环系,所述环系可以是芳环或部分饱和环,并且可以含有1-4个选自氮、氧和硫的杂原子,其中所述环系直接与吡啶环连接,或者经由C1-C4亚烷基与吡啶环连接,并且每个环系不可以含有2个以上的氧原子,不可以含有2个以上的硫原子,所述环系自身可被下列基团单取代、二取代或三取代:C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R7、NR8R9、卤素、氰基、硝基、苯基或苄硫基,其中所述苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代,并且在杂环中的氮上的取代基不是卤素;R49是氢、C1-C6烷基、C1-C6卤代烷基、卤素、或苯基,所述苯基可被下列基团取代:C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基,且R50是C1-C6卤代烷基。
4.权利要求3的组合物,其中R48是C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基或C1-C6卤代烷基。
5.权利要求1的组合物,其中在式I中,Q是基团Q2或Q3。
6.权利要求5的组合物,其中在基团Q2中,R23是羟基。
7.权利要求5的组合物,其中在基团Q3中,R40是羟基。
8.控制有用植物农作物中不希望的植物生长的方法,所述方法包括将除草有效量的权利要求1的组合物作用于农作物植物或其场所。
9.权利要求8的方法,其中所述农作物植物是玉米或甘蔗。
10.权利要求8的方法,其中用所述组合物以相当于1-5000g活性组分/公顷总量的施用量处理有用植物农作物。
12.选择性控制有用植物农作物中的杂草和禾草的方法,所述方法包括用除草协同有效量的权利要求10的组合物处理有用植物、种子或其切条、或其耕作区域。
13.权利要求12的方法,其中除草剂的施用量为1-5000g/ha,安全剂的施用量为0.001-0.5kg/ha。
14.权利要求12的方法,其中所述有用植物是玉米或甘蔗。
16.选择性控制有用植物农作物中的杂草和禾草的方法,所述方法包括用除草协同有效量的权利要求14的组合物处理有用植物、种子或其切条、或其耕作区域。
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2001
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- 2001-01-23 PL PL356434A patent/PL202070B1/pl unknown
- 2001-01-23 BR BRPI0107811-9A patent/BR0107811B1/pt not_active IP Right Cessation
- 2001-01-23 DK DK01909680T patent/DK1250047T3/da active
- 2001-01-23 EP EP04029625A patent/EP1520472A3/en not_active Withdrawn
- 2001-01-23 HU HU0301083A patent/HU230041B1/hu not_active IP Right Cessation
- 2001-01-23 AT AT01909680T patent/ATE290785T1/de active
- 2001-01-23 SK SK1082-2002A patent/SK10822002A3/sk not_active Application Discontinuation
- 2001-01-23 WO PCT/EP2001/000720 patent/WO2001054501A2/en active IP Right Grant
- 2001-01-23 RU RU2002121642/04A patent/RU2260949C2/ru not_active IP Right Cessation
- 2001-01-23 JP JP2001555490A patent/JP4880161B2/ja not_active Expired - Fee Related
- 2001-01-23 AR ARP010100287A patent/AR027928A1/es active IP Right Grant
- 2001-01-23 ES ES01909680T patent/ES2238425T3/es not_active Expired - Lifetime
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- 2001-01-23 MX MXPA02006931A patent/MXPA02006931A/es active IP Right Grant
- 2001-01-23 CZ CZ2002-2547A patent/CZ304537B6/cs not_active IP Right Cessation
- 2001-01-23 DE DE60109411T patent/DE60109411T2/de not_active Expired - Lifetime
- 2001-01-23 CN CNB018040896A patent/CN100488362C/zh not_active Expired - Lifetime
- 2001-01-23 EP EP01909680A patent/EP1250047B9/en not_active Expired - Lifetime
- 2001-01-23 PT PT01909680T patent/PT1250047E/pt unknown
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2002
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- 2002-08-13 HR HR20020669A patent/HRP20020669B1/xx not_active IP Right Cessation
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