CN100488362C - 除草组合物 - Google Patents

除草组合物 Download PDF

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CN100488362C
CN100488362C CNB018040896A CN01804089A CN100488362C CN 100488362 C CN100488362 C CN 100488362C CN B018040896 A CNB018040896 A CN B018040896A CN 01804089 A CN01804089 A CN 01804089A CN 100488362 C CN100488362 C CN 100488362C
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CN1396807A (zh
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W·T·鲁格
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Syngenta Participations AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
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Abstract

除草组合物，所述组合物除了包含常用惰性制剂助剂以外，还包含：a)式(I)化合物，其中取代基如权利要求1中所定义；和b)协同有效量的一种或多种式2.1-2.51化合物。本发明组合物还可以包含安全剂。

Description

除草组合物
本发明涉及新的除草组合物，其中包含适于选择性地控制有用植物农作物例如玉米农作物中的杂草的除草活性组分组合。本发明还涉及控制有用植物农作物中的杂草的方法，以及新的组合物在这样的用途中的应用。
式I化合物
Figure C01804089D00041
其中取代基的定义在下文中给出，
具有除草活性。
令人惊奇的是，现在已经发现，不定量的活性组分、即不定量的式I活性组分与一种或多种下文所列出的已知的、并且某些可商购获得的式2.1-2.51活性组分的组合表现出协同作用，能够控制尤其是在有用植物农作物中生长的大多数杂草(既能控制芽前的杂草，也能控制苗后的杂草)。
因此，本发明提供了用于选择性地控制杂草的新的协同组合物，所述组合物除了含有常规惰性制剂助剂以外，还含有下列组分的混合物作为活性组分：
a)除草有效量的式I化合物或其农业可接受盐
Figure C01804089D00051
其中每个R独立地为氢、C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基、C1-C6卤代烷硫基、C1-C6卤代烷基亚磺酰基、C1-C6卤代烷基磺酰基、C1-C6烷氧基羰基、C1-C6烷基羰基、C1-C6烷基氨基、二(C1-C6烷基)氨基、C1-C6烷基氨基磺酰基、二(C1-C6烷基)氨基磺酰基、-N(R1)-S-R2、-N(R3)-SO-R4、-N(R5)-SO2-R6、硝基、氰基、卤素、羟基、氨基、苄硫基、苄基亚磺酰基、苄基磺酰基、苯基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基；其中所述苯基自身可被下列基团单取代、二取代或三取代：C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R45、NR46R47、卤素、氰基、硝基、苯基或苄硫基，其中后面所述的苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代；
或者每个R独立地为5-10元单环或稠合二环系，所述环系可以是芳环或部分饱和环，并且可以含有1-4个选自氮、氧和硫的杂原子；其中所述环系直接与吡啶环连接，或者经由C1-C4亚烷基与吡啶环连接，并且每个环系不可以含有2个以上的氧原子，不可以含有2个以上的硫原子，所述环系自身可被下列基团单取代、二取代或三取代：C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R7、NR8R9、卤素、氰基、硝基、苯基或苄硫基，其中所述苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代，并且在杂环中的氮上的取代基不是卤素；
或者每个R独立地为C1-C4烷氧基-C1-C4烷基或C1-C4烷氧基-C1-C4烷氧基-C1-C4烷基；
m是1、2、3或4；
R1、R3和R5分别独立地为氢或C1-C6烷基；
R2是NR10R11、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基或苯基，其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代；
R4是NR12R13、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基或苯基，其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代；
R6是NR14R15、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基或苯基，其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代；
R7和R45分别独立地为C1-C3烷氧基、C2-C4烷氧基羰基、C1-C3烷硫基、C1-C3烷基亚磺酰基、C1-C3烷基磺酰基或苯基，其中所述苯基自身可被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代；
R8、R10、R12、R14和R46分别独立地为氢或C1-C6烷基；
R9、R11、R13、R15和R47分别独立地为C1-C6烷基或C1-C6烷氧基；
Q是基团Q1
Figure C01804089D00071
其中R16、R17、R18和R19分别独立地为氢、羟基、C1-C4烷基、C2-C6链烯基、C2-C6炔基、C1-C4烷氧基羰基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-NHS(O)2、C1-C4卤代烷基、-NH-C1-C4烷基、-N(C1-C4烷基)2、C1-C6烷氧基、氰基、硝基、卤素、或苯基，其中所述苯基自身可被下列基团取代：C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基、COOH或氰基；或者R16、R17、R18和R19当中的两个相邻取代基形成C2-C6亚烷基桥；
R20是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R21R22N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基，其中所述苯基自身可被下列基团取代：C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基；且R21和R22分别独立地为氢或C1-C4烷基；
或者是基团Q2
Figure C01804089D00081
其中R23是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4-链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R24R25N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基，其中所述苯基自身可被下列基团取代：C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基；
R24和R25分别独立地为氢或C1-C4烷基；且
Y是氧、硫、化学键或C1-C4亚烷基桥；
或者是Q3
Figure C01804089D00091
其中R44、R37、R38和R39分别独立地为氢、C1-C6烷基、C1-C6卤代烷基、C2-C6链烯基、C2-C6炔基、C1-C6烷氧基羰基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6烷基-NHS(O)2、C1-C6烷基氨基、二(C1-C6烷基)氨基、羟基、C1-C6烷氧基、C3-C6链烯氧基、C3-C6炔氧基、羟基-C1-C6烷基、C1-C4烷基-磺酰基氧基-C1-C6烷基、甲苯磺酰基氧基-C1-C6烷基、卤素、氰基、硝基、苯基、或被下列基团取代的苯基：C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-S(O)2O、C1-C6卤代烷硫基、C1-C6卤代烷基亚磺酰基、C1-C6卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C6烷硫基-N(C1-C4烷基)、C1-C6烷基亚磺酰基-N(C1-C4烷基)、C1-C6烷基磺酰基-N(C1-C4烷基)、卤素、硝基、COOH或氰基；或者相邻的R44和R37或R38和R39一起为C3-C6亚烷基；
W是氧、硫、亚磺酰基、磺酰基、-CR41R42-、-C(O)-或-NR43-；
R41是氢、C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基-C1-C4烷基、C1-C4烷硫基-C1-C4烷基、C1-C4烷基羰基氧基-C1-C4烷基、C1-C4烷基磺酰基氧基-C1-C4烷基、甲苯磺酰基氧基-C1-C4烷基、二(C1-C3烷氧基烷基)甲基、二(C1-C3烷硫基烷基)甲基、(C1-C3烷氧基烷基)-(C1-C3烷硫基烷基)甲基、C3-C5氧杂环烷基、C3-C5硫杂环烷基、C3-C4二氧杂环烷基、C3-C4二硫杂环烷基、C3-C4氧杂硫杂环烷基、甲酰基、C1-C4烷氧基羰基、或苯基，所述苯基自身可被下列基团取代：C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C6烷硫基-N(C1-C4烷基)、C1-C6烷基亚磺酰基-N(C1-C4烷基)、C1-C6烷基磺酰基-N(C1-C4烷基)、卤素、硝基、COOH或氰基；或者R42与R39一起为C1-C6亚烷基；
R42是氢、C1-C4烷基或C1-C4卤代烷基；
R40是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R96R97N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基，其中所述苯基自身可被下列基团取代：C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基；R96和R97分别独立地为氢或C1-C4烷基；
R43是氢、C1-C4烷基、C1-C4烷氧基羰基、或苯基，其中所述苯基自身可被下列基团取代：C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基；
或者是基团Q4
Figure C01804089D00111
其中R30是羟基、O-M+、卤素、C1-C12烷氧基、C1-C12烷基羰基氧基、C2-C4链烯基羰基氧基、C3-C6环烷基羰基氧基、C1-C12烷氧基羰基氧基、C1-C12烷基羰基氧基、R31R32N-C(O)O、C1-C12烷硫基、C1-C12烷基亚磺酰基、C1-C12烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C2-C12链烯硫基、C2-C12链烯基亚磺酰基、C2-C12链烯基磺酰基、C2-C12卤代链烯硫基、C2-C12卤代链烯基亚磺酰基、C2-C12卤代链烯基磺酰基、C2-C12炔硫基、C2-C12炔基亚磺酰基、C2-C12炔基磺酰基、C1-C4烷基-S(O)2O、苯基-S(O)2O、(C1-C4烷氧基)2P(O)O、C1-C4烷基(C1-C4烷氧基)P(O)O、H(C1-C4烷氧基)P(O)O、C1-C12-烷基-S(CO)O、苄氧基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基，其中所述苯基自身可被下列基团取代：C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基或氰基；且
R31和R32分别独立地为氢或C1-C4烷基；
R33和R34分别独立地为氢、羟基、C1-C4烷基、C2-C6链烯基、C2-C6炔基、C1-C4烷氧基羰基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-NHS(O)2、C1-C4卤代烷基、-NH-C1-C4烷基、-N(C1-C4烷基)2、C1-C6烷氧基、氰基、硝基、卤素、或苯基，其中所述苯基自身可被下列基团取代：C1-C4烷基、C1-C4卤代烷基、C1-C4-烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基、COOH或氰基；或者
R33和R34一起形成C2-C6亚烷基桥；且
R35是氢、C1-C4烷基、C1-C4烷氧基羰基、或苯基，所述苯基自身可被下列基团取代：C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基羰基、C1-C4烷氧基羰基、氨基、C1-C4烷基氨基、二(C1-C4烷基)氨基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4烷基-S(O)2O、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4卤代烷基-S(O)2O、C1-C4烷基-S(O)2NH、C1-C4烷基-S(O)2N(C1-C4烷基)、卤素、硝基、COOH或氰基；
或者是基团Q5
Figure C01804089D00121
其中Z是硫、SO或SO2；
R01是氢、C1-C8烷基、被下列基团取代的C1-C8烷基：卤素、C1-C4烷氧基、C1-C4烷硫基、C1-C4烷基磺酰基、C1-C4烷基亚磺酰基、羟基、氰基、硝基、-CHO、-CO2R02、-COR03、-COSR04、-NR05R06、CONR036R037、或苯基，所述苯基自身可被下列基团取代：C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7-环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR025R026、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR015CO2R027；
或者R01是C2-C8链烯基或被下列基团取代的C2-C8链烯基：卤素、C1-C4烷氧基、C1-C4烷硫基、C1-C4烷基磺酰基、C1-C4烷基亚磺酰基、-CONR032R033、氰基、硝基、-CHO、-CO2R038、-COR039、-COS-C1-C4烷基、-NR034R035、或苯基，所述苯基自身可被下列基团取代：C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR040R041、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR043CO2R042；
或者R01是C3-C6炔基或被下列基团取代的C3-C6炔基：卤素、C1-C4卤代烷基、氰基、-CO2R044、或苯基，所述苯基自身可被下列基团取代：C1-C4烷基、C1-C6卤代烷基、C1-C4-烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4-烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR028R029、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR031CO2R030；
或者R01是C3-C7环烷基或被下列基团取代的C3-C7环烷基：C1-C4烷基、C1-C4烷氧基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、或苯基，所述苯基自身可被下列基团取代：卤素、硝基、氰基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷硫基、C1-C4卤代烷硫基、C1-C4烷基或C1-C4卤代烷基；或者
R01是C1-C4亚烷基-C3-C7环烷基、苯基、或被下列基团取代的苯基：C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C2-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4-烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR045R046、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基或-NR048CO2R047；或者
R01是C1-C4亚烷基苯基、COR07或4-6元杂环基；
R02、R038、R044和R066分别独立地为氢、C1-C4烷基、苯基、或被下列基团取代的苯基：C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)-SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR049R050、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、-C1-C4-烷基苯基或-NR052CO2R053；
R03、R039和R067分别独立地为C1-C4烷基、苯基、或被下列基团取代的苯基：C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)-SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR068R054、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、-(CH2)t-苯基或-NR056CO2R055；
R04是C1-C4烷基；
R05是氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基、C3-C7环烷基、苯基、或被下列基团取代的苯基：C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4烷基、(C1-C4烷基亚磺酰基-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2H、N(C3-C6炔基)-SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2H、N(C3-C7环烷基)-SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR057R058、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR060CO2R059；
R06是氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基、C3-C7环烷基、苯基、或被下列基团取代的苯基：C1-C4烷基、C1-C6卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C2-C6链烯基、C3-C6炔基、C3-C6链烯氧基、C3-C6炔氧基、卤素、硝基、氰基、-COOH、COOC1-C4烷基、COO苯基、C1-C4烷氧基、苯氧基、(C1-C4烷氧基)-C1-C4烷基、(C1-C4烷硫基)-C1-C4-烷基、(C1-C4烷基亚磺酰基)-C1-C4烷基、(C1-C4烷基磺酰基)-C1-C4烷基、NHSO2-C1-C4烷基、NHSO2-苯基、N(C1-C6烷基)SO2-C1-C4烷基、N(C1-C6烷基)SO2-苯基、N(C2-C6链烯基)-SO2-C1-C4烷基、N(C2-C6链烯基)SO2-苯基、N(C3-C6炔基)SO2-C1-C4烷基、N(C3-C6炔基)SO2-苯基、N(C3-C7环烷基)SO2-C1-C4烷基、N(C3-C7环烷基)SO2-苯基、N(苯基)SO2-C1-C4烷基、N(苯基)SO2-苯基、OSO2-C1-C4烷基、CONR061R062、OSO2-C1-C4卤代烷基、OSO2-苯基、C1-C4烷硫基、C1-C4卤代烷硫基、苯硫基、C1-C4烷基磺酰基、C1-C4卤代烷基磺酰基、苯基磺酰基、C1-C4烷基亚磺酰基、C1-C4卤代烷基亚磺酰基、苯基亚磺酰基、C1-C4亚烷基苯基或-NR064CO2R063；
R07是苯基、C1-C4烷基、C1-C4烷氧基或-NR08R09；
R08和R09分别独立地为C1-C4烷基、苯基、或被下列基团取代的苯基：卤素、硝基、氰基、C1-C4烷基、C1-C4烷氧基、C1-C4烷硫基、-CO2R066、-COR067、C1-C4烷基磺酰基、C-C4烷基亚磺酰基或C1-C4卤代烷基；或者R08和R09一起形成可被氧、NR065或S间隔的5-元或6-元环；
R015、R031、R043、R048、R052、R056、R060和R064分别独立地为氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基或C3-C7环烷基；
R025、R026、R027、R028、R029、R030、R032、R033、R034、R035、R036、R037、R040、R041、R042、R045、R046、R047、R049、R050、R053、R054、R055、R057、R058、R059、R061、R062、R053、R065和R068分别独立地为氢、C1-C4烷基、C2-C6链烯基、C3-C6炔基、C3-C7环烷基、苯基、或被下列基团取代的苯基：卤素、硝基、氰基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷硫基、C1-C4卤代烷硫基、C1-C4烷基或C1-C4卤代烷基；且
R36是C1-C4烷基、C1-C4卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C3-C6环烷基、或被下列基团取代的C3-C6环烷基：卤素、C1-C4烷基、C1-C4卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C4烷氧基羰基、C1-C4烷硫基、C1-C4烷基亚磺酰基、C1-C4烷基磺酰基、C1-C4卤代烷硫基、C1-C4卤代烷基亚磺酰基、C1-C4卤代烷基磺酰基、C1-C4烷基羰基、二(C1-C4烷基)氨基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷基-S(O)2O、C1-C4卤代烷基-S(O)2O、或苯基，所述苯基自身可被下列基团取代：卤素、C1-C4烷基、C1-C4卤代烷基、C3-C6链烯基、C3-C6炔基、氰基、硝基或COOH；
和
b)协同有效量的一种或多种选自下列的化合物：
式2.1化合物
其中R51是CH2-OMe、乙基或氢；
R52是氢，或者R51与R52一起形成基团-CH＝CH-CH＝CH-；
和式2.2化合物
其中R53是乙基，R54是甲基或乙基，且R55是-CH(Me)-CH2OMe、<S>-CH(Me)-CH2OMe、CH2OMe或CH2O-CH2CH3；
和式2.3化合物
Figure C01804089D00182
其中R56是CH(Me)-CH2OMe或<S>CH(Me)-CH2OMe；
和式2.4化合物
Figure C01804089D00183
其中R57是氯、甲氧基或甲硫基，R58是乙基，且R59是乙基、异丙基、-C(CN)(CH3)-CH3或叔丁基；
和式2.5化合物
其中R60是乙基或正丙基，R61是COO-1/2 Ca++、-CH2-CH(Me)S-CH2CH3或基团
Figure C01804089D00191
且X是氧、N-O-CH2CH3或N-O-CH2CH＝CH-Cl；
和式2.6化合物
Figure C01804089D00192
其中R62是氢、甲氧基或乙氧基，R63是氢、甲基、甲氧基或氟，R64是COOMe、氟或氯，R65是氢或甲基，Y是次甲基、C-F或氮，Z是次甲基或氮，且R66是氟或氯；
和式2.7化合物
其中R67是氢或-C(O)-S-正辛基；
和式2.8化合物
Figure C01804089D00194
其中R68是溴或碘；
和式2.9化合物
Figure C01804089D00201
其中R69是氯或硝基；
和式2.10化合物
其中R70是氟或氯，且R71是-CH2-CH(Cl)-COOCH2CH3或-NH-SO2Me；
和式2.11化合物
Figure C01804089D00203
其中R72是三氟甲基或氯；
和式2.12化合物
其中R72是NH3或<S>NH2；
和式2.13化合物
其中Y1是氮、次甲基、NH-CHO或N-Me，Y2是氮、次甲基或C-I，Y3是次甲基，Y4是次甲基，或者Y3和Y4一起是硫或C-Cl，Y5是氮或次甲基，Y6是甲基、二氟甲氧基、三氟甲基或甲氧基，Y7是甲氧基或二氟甲氧基，且R74是CONMe2、COOMe、COOC2H5、三氟甲基、CH2-CH2CF3或SO2CH2CH3，或其钠盐(“Me”是甲基)；
和式2.13.c化合物
和式2.14化合物
Figure C01804089D00213
和式2.15化合物
Figure C01804089D00214
和式2.16化合物
Figure C01804089D00221
和式2.17化合物
Figure C01804089D00222
和式2.18化合物
和式2.19化合物
Figure C01804089D00224
和式2.20化合物
Figure C01804089D00225
和式2.21化合
Figure C01804089D00231
和式2.22化合物
Figure C01804089D00232
和式2.23化合物
Figure C01804089D00233
和式2.24化合物
Figure C01804089D00234
和式2.25化合物
Figure C01804089D00241
和式2.26化合物
Figure C01804089D00242
和式2.27化合物
Figure C01804089D00243
和式2.28化合物
Figure C01804089D00244
和式2.29化合物
Figure C01804089D00251
和式2.30化合物
和式2.31化合物
Figure C01804089D00253
和式2.32化合物
Figure C01804089D00254
和式2.33化合物
Figure C01804089D00255
and the compound of formula 2.34
Figure C01804089D00261
和式2.35化合物
Figure C01804089D00262
和式2.36化合物
Figure C01804089D00263
和式2.37化合物
Figure C01804089D00264
和式2.38化合物
和式2.39化合物
Figure C01804089D00266
和式2.40化合物
Figure C01804089D00267
和式2.41化合物
Figure C01804089D00271
和式2.42化合物
Figure C01804089D00272
和式2.43化合物
Figure C01804089D00273
和式2.44化合物
和式2.45化合物
Figure C01804089D00275
和式2.46化合物
Figure C01804089D00276
和式2.47化合物
Figure C01804089D00281
和式2.48化合物
Figure C01804089D00282
和式2.49化合物
Figure C01804089D00283
和式2.50化合物
Figure C01804089D00284
和式2.51化合物
在上式中，“Me”是甲基。在取代基定义中提及的烷基可以是直链或支链，并且是例如甲基、乙基、正丙基、异丙基、正丁基、仲丁基、异丁基、叔丁基、戊基、己基、庚基、辛基、壬基、癸基、十一烷基和十二烷基及其支链异构体。烷氧基、链烯基和炔基衍生自上述烷基。链烯基和炔基可具有一个或一个以上的不饱和键。
亚烷基可以被一个或多个甲基取代；这样的亚烷基优选未取代。这也适用于所有含有C3-C5环烷基-、C3-C5氧杂环烷基-、C3-C5硫杂环烷基-、C3-C4二氧杂环烷基-、C3-C4二硫杂环烷基-、C3-C4氧硫杂环烷基-和N(CH2)-的基团。
卤素一般是氟、氯、溴或碘。这相应地适用于在其它定义例如卤代烷基或卤代苯基中出现的卤素。
具有1-6个碳原子链长的卤代烷基是例如氟甲基、二氟甲基、三氟甲基、氯甲基、二氯甲基、三氯甲基、2，2，2-三氟乙基、2-氟乙基、2-氯乙基、五氟乙基、1，1-二氟-2，2，2-三氯乙基、2，2，3，3-四氟乙基和2，2，2-三氯乙基、五氟乙基、七氟正丙基、五氟正己基；在R2、R3和尤其是R5的定义中的卤代烷基优选为三氯甲基、二氯氟甲基、二氟氯甲基、二氟甲基、三氟甲基、五氟乙基或七氟正丙基。
合适的卤代链烯基包括被卤素取代一次或多次的链烯基，卤素是氟、氯、溴或碘，尤其是氟或氯，例如2，2-二氟-1-甲基乙烯基、3-氟丙烯基、3-氯丙烯基、3-溴丙烯基、2，3，3-三氟丙烯基、2，3，3-三氯丙烯基和4，4，4-三氟丁-2-烯-1-基。优选的被卤素取代1次、2次或3次的C2-C12链烯基是链长为2-5个碳原子的那些。合适的卤代炔基包括例如被卤素取代一次或多次的炔基，卤素是溴或碘，和尤其是氟或氯，例如3-氟丙炔基、3-氯丙炔基、3-溴丙炔基、3，3，3-三氟丙炔基和4，4，4-三氟-丁-2-炔-1-基。优选的被卤素取代1次、2次或3次的炔基是链长为2-5个碳原子的那些。
烷氧基优选具有1-6个碳原子的链长。烷氧基是例如甲氧基、乙氧基、丙氧基、异丙氧基、正丁氧基、异丁氧基、仲丁氧基或叔丁氧基或戊氧基或己氧基异构体，优选甲氧基和乙氧基。烷基羰基优选为乙酰基或丙酰基。烷氧基羰基是例如甲氧基羰基、乙氧基羰基、丙氧基羰基、异丙氧基羰基、正丁氧基羰基、异丁氧基羰基、仲丁氧基羰基或叔丁氧基羰基，优选甲氧基羰基、乙氧基羰基或叔丁氧基羰基。卤代烷氧基优选具有1-8个碳原子的链长。
卤代烷氧基是例如氟甲氧基、二氟甲氧基、三氟甲氧基、2，2，2-三氟乙氧基、1，1，2，2-四氟乙氧基、2-氟乙氧基、2-氯乙氧基、2，2-二氟乙氧基或2，2，2-三氯乙氧基，优选二氟甲氧基、2-氯乙氧基或三氟甲氧基。
烷硫基优选具有1-8个碳原子的链长。
烷硫基是例如甲硫基、乙硫基、丙硫基、异丙硫基、正丁硫基、异丁硫基、仲丁硫基或叔丁硫基，优选为甲硫基或乙硫基。
烷基亚磺酰基是例如甲基亚磺酰基、乙基亚磺酰基、丙基亚磺酰基、异丙基亚磺酰基、正丁基亚磺酰基、异丁基亚磺酰基、仲丁基亚磺酰基或叔丁基亚磺酰基，优选为甲基亚磺酰基或乙基亚磺酰基。
烷基磺酰基是例如甲基磺酰基、乙基磺酰基、丙基磺酰基、异丙基磺酰基、正丁基磺酰基、异丁基磺酰基、仲丁基磺酰基或叔丁基磺酰基，优选为甲基磺酰基或乙基磺酰基。
烷基氨基是例如甲基氨基、乙基氨基、正丙基氨基、异丙基氨基或丁基氨基异构体。二烷基氨基是例如二甲基氨基、甲基乙基氨基、二乙基氨基、正丙基甲基氨基、二丁基氨基或二异丙基氨基。烷基氨基优选具有1-4个碳原子的链长。烷氧基烷基优选具有1-6个碳原子的链长。烷氧基烷基是例如甲氧基甲基、甲氧基乙基、乙氧基甲基、乙氧基乙基、正丙氧基甲基、正丙氧基乙基、异丙氧基甲基或异丙氧基乙基。烷硫基烷基优选具有1-6个碳原子的链长。烷硫基烷基是例如甲硫基甲基、甲硫基乙基、乙硫基甲基、乙硫基乙基、正丙硫基甲基、正丙硫基乙基、异丙硫基甲基、异丙硫基乙基、丁硫基甲基、丁硫基乙基或丁硫基丁基。
环烷基优选具有3-6个环碳原子，并且可以被一个或多个甲基取代；它们优选未取代，例如环丙基、环丁基、环戊基或环己基。苯基，包括作为取代基例如苯氧基、苄基、苄氧基、苯甲酰基、苯硫基、苯基烷基、苯氧基烷基或甲苯磺酰基的一部分的苯基可以是单取代或多取代形式，对于这种情况，取代基可以按照需要在邻位、间位和/或对位。
本发明还包括式I化合物可以与胺、碱金属和碱土金属碱或季铵碱形成的盐。在作为盐形成剂使用的碱金属和碱土金属氢氧化物当中，可特别提及氢氧化锂、氢氧化钠、氢氧化钾、氢氧化镁和氢氧化钙，尤其是氢氧化钠和氢氧化钾。
适用于形成铵盐的胺的实例是氨以及伯、仲和叔C1-C18烷基案、C1-C4羟基烷基胺和C2-C4烷氧基烷基胺，例如甲基胺、乙基胺、正丙基胺、异丙基胺、四种丁基胺异构体、正戊基胺、异戊基胺、己基胺、庚基胺、辛基胺、壬基胺、癸基胺、十五烷基胺、十六烷基胺、十七烷基胺、十八烷基胺、甲基乙基胺、甲异丙基胺、甲基己基胺、甲基壬基胺、甲基十五烷基胺、甲基十八烷基胺、乙基丁基胺、乙基庚基胺、乙基辛基胺、己基庚基胺、己基辛基胺、二甲基胺、二乙基胺、二-正丙基胺、二异丙基胺、二-正丁基胺、二正戊基胺、二异戊基胺、二己基胺、二庚基胺、二辛基胺、乙醇胺、正丙醇胺、异丙醇胺、N，N-二乙醇胺、N-乙基丙醇胺、N-丁基乙醇胺、烯丙基胺、正丁烯基-2-胺、正戊烯基-2-胺、2，3-二甲基丁烯基-2-胺、二丁烯基-2-胺、正己烯基-2-胺、丙二胺、三甲基胺、三乙基胺、三正丙基胺、三异丙基胺、三正丁基胺、三异丁基胺、三仲丁基胺、三正戊基胺、甲氧基乙基胺和乙氧基乙基胺；杂环胺例如吡啶、喹啉、异喹啉、吗啉、哌啶、吡咯烷、二氢吲哚、奎宁环和吖庚因；伯芳基胺例如苯胺、甲氧基苯胺、乙氧基苯胺、邻甲苯胺、间甲苯胺、对甲苯胺、苯二胺、联苯胺、萘基胺、邻氯苯胺、间氯苯胺和对氯苯胺；但是尤其是三乙基胺、异丙基胺和二异丙基胺。
非常令人惊奇的是，式I活性组分与一种或多种选自式2.1-2.51的活性组分的组合对欲控制杂草的作用超过了一般所预计的加和作用，因此扩大了单独活性组分的作用范围，尤其是在下列两个方面：首先，减小了单独的式2.1-2.51化合物的施用量，同时保持了良好的作用水平，其次，对于单独的活性物质以低施用量不可用的情况(从农学角度来看)，本发明组合物可获得良好的杂草控制水平。该结果是杂草谱的显著拓宽，并且提高了在有用植物农作物方面的选择性，如果发生了活性组分的非故意剂量过多，这样的结果是必须的并且可取的。在保持良好控制有用植物农作物中的杂草的同时，本发明组合物还使得在继代农作物中有更大的灵活性。
本发明组合物可用于抗大量在农业上很重要的杂草，例如繁缕属、旱金莲属、地老虎属、马唐属、燕麦属、狗尾草属、芥属、毒麦属、茄属、菜豆属、稗属、藨草属、雨久花属、慈菇属、雀麦属、看麦娘属、石茅高梁、筒轴茅属、莎草属、苘麻属、黄花稔属、苍耳属、苋属、藜属、番薯属、苘蒿属、猪殃殃属、堇菜属和婆婆纳属。本发明组合物适用于农业中的所有常用施用方法，例如芽前施用、苗后施用和种子包衣。本发明组合物尤其适用于控制有用植物农作物例如禾谷类、油菜、甜菜、甘蔗、种植园农作物、稻、玉米和大豆中的杂草，以及适用于非选择性杂草控制。
“农作物”还指通过常规育种或基因工程方法使其对除草剂或除草剂类别耐受的农作物。
优选的本发明组合物包含式I化合物，其中每个R独立地为氢、C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基、C1-C6烷氧基、C1-C6卤代烷氧基、C1-C6烷硫基、C1-C6烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基、C1-C6卤代烷硫基、C1-C6卤代烷基亚磺酰基、C1-C6卤代烷基磺酰基、C1-C6烷氧基羰基、C1-C6烷基羰基、C1-C6烷基氨基、二(C1-C6烷基)氨基、C1-C6烷基氨基磺酰基、二(C1-C6烷基)氨基磺酰基、-N(R1)-S-R2、-N(R3)-SO-R4、-N(R5)-SO2-R6、硝基、氰基、卤素、羟基、氨基、苄硫基、苄基亚磺酰基、苄基磺酰基、苯基、苯氧基、苯硫基、苯基亚磺酰基或苯基磺酰基；其中所述苯基自身可被下列基团单取代、二取代或三取代：C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R45、NR46R47、卤素、氰基、硝基、苯基或苄硫基，其中后面提及的苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代；
或者每个R独立地为5-10元单环或稠合二环系，所述环系可以是芳环或部分饱和环，并且可以含有1-4个选自氮、氧和硫的杂原子；其中所述环系直接与吡啶环连接，或者经由C1-C4亚烷基与吡啶环连接，并且每个环系不可以含有2个以上的氧原子，不可以含有2个以上的硫原子，所述环系自身可被下列基团单取代、二取代或三取代：C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R7、NR8R9、卤素、氰基、硝基、苯基或苄硫基，其中所述苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代，R1、R2、R3、R4、R5、R6、R7、R8、R9、R45、R46和R47如上文所定义，并且在杂环中的氮上的取代基不是卤素。
还优选的本发明组合物包含式Ia化合物作为式I化合物
其中R48是C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基、C1-C6卤代烷基、或5-10元单环或稠合二环系，所述环系可以是芳环或部分饱和环，并且可以含有1-4个选自氮、氧和硫的杂原子，其中所述环系直接与吡啶环连接，或者经由C1-C4亚烷基与吡啶环连接，并且每个环系不可以含有2个以上的氧原子，不可以含有2个以上的硫原子，所述环系自身可被下列基团单取代、二取代或三取代：C1-C6烷基、C1-C6卤代烷基、C3-C6链烯基、C3-C6卤代链烯基、C3-C6炔基、C3-C6卤代炔基、C1-C6烷氧基、C1-C6卤代烷氧基、C3-C6链烯氧基、C3-C6炔氧基、巯基、C1-C6烷硫基、C1-C6卤代烷硫基、C3-C6链烯硫基、C3-C6卤代链烯硫基、C3-C6炔硫基、C2-C5烷氧基烷硫基、C3-C5乙酰基烷硫基、C3-C6烷氧基羰基烷硫基、C2-C4氰基烷硫基、C1-C6烷基亚磺酰基、C1-C6卤代烷基亚磺酰基、C1-C6烷基磺酰基、C1-C6卤代烷基磺酰基、氨基磺酰基、C1-C2烷基氨基磺酰基、C2-C4二烷基氨基磺酰基、C1-C3亚烷基-R7、NR8R9、卤素、氰基、硝基、苯基或苄硫基，其中所述苯基和苄硫基自身可在苯环上被C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基取代，并且在杂环中的氮上的取代基不是卤素；
R49是氢、C1-C6烷基、C1-C6卤代烷基、卤素、或苯基，所述苯基可被下列基团取代：C1-C3烷基、C1-C3卤代烷基、C1-C3烷氧基、C1-C3卤代烷氧基、卤素、氰基或硝基，
R50是C1-C6卤代烷基，并且R7、R8、R9和Q如上文所定义。
在该组化合物当中，其中R48是C1-C6烷基、C2-C6链烯基、C2-C6卤代链烯基、C2-C6炔基、C2-C6卤代炔基、C3-C6环烷基或C1-C6卤代烷基的那些是优选的。
对于本发明组合物还优选的是，在式I中，Q是基团Q2或Q3，其中尤其是，在基团Q2中，R23是羟基，在基团Q3中，R40是羟基。在该组化合物当中，其中m是2，且一个取代基R是C1-C4烷氧基-C1-C4烷基或C1-C4烷氧基-C1-C4烷氧基-C1-C4烷基的化合物是特别重要的。
进一步优选的本发明协同混合物包含式I化合物和下列化合物作为活性组分：式2.2.a化合物
Figure C01804089D00351
(2.2.a，aRS，1’S(-)N-(1’-甲基-2’-甲氧基乙基)-N-氯乙酰基-2-乙基-6-甲基苯胺)或式2.2.b化合物
Figure C01804089D00352
或式2.2化合物，其中R3是乙基、R4是甲基、且R5是乙氧基甲基，或式2.2化合物，其中R3是乙基、R4是乙基、且R5是甲氧基甲基，或化合物2.3，或式2.30化合物，或式2.4化合物，或式2.13化合物，或式2.14化合物，或式2.6化合物，其中R12是氢、Z是次甲基、R13是甲基、Y是氮、R14是氟、R15是氢、且R16是氟，或者R12是甲氧基、Z是次甲基、R13是甲氧基、Y是次甲基、R14是氯、R15是甲基、且R16是氯，或式2.7化合物，其中R17是-C(O)-S-正辛基，或式2.12化合物，或式2.18化合物，或式2.19化合物，或式2.21化合物，或式2.25化合物，或式2.33化合物，或式2.45化合物，或式2.1化合物。
尤其优选的本发明协同混合物包含式I化合物和下列化合物作为活性组分：式2.2.a化合物
Figure C01804089D00361
(2.2.a，aRS，1’S(-)N-(1’-甲基-2’-甲氧基乙基)-N-氯乙酰基-2-乙基-6-甲基苯胺)或式2.2.b化合物
Figure C01804089D00362
或式2.2化合物，其中R3是乙基、R4是甲基、且R5是乙氧基甲基，或式2.2化合物，其中R3是乙基、R4是乙基、且R5是甲氧基甲基，或化合物2.3，或式2.30化合物。
已经发现，式I化合物与式2.2a化合物
(2.2.a，aRS，1’S(-)N-(1’-甲基-2’-甲氧基乙基)-N-氯乙酰基-2-乙基-6-甲基苯胺)的组合是特别有效的，尤其优选的式I化合物是在下文表1中列出的化合物1.001。
式I化合物可通过类似于在WO 97/46530中描述的方法制得，所述方法包括
a)在惰性有机溶剂中，在碱存在下，将式II化合物
Figure C01804089D00371
其中R和m如式I中所定义，且X是离去基团例如卤素，
与式III、IV、V或VI化合物反应
Figure C01804089D00372
其中R20、R23、R30和R40是羟基，且其它取代基如式I所定义，
以生成式VII、VIII、IX或X化合物，
Figure C01804089D00381
然后将这些化合物异构化，例如在碱和催化量的二甲基氨基吡啶(DMAP)或氰化物源存在下异构化；或者
b)在惰性有机溶剂中，在碱和偶联剂存在下，将式XI化合物
其中R和m如式I中所定义，
与式III、IV、V或VI化合物反应，
以形成式VII、VIII、IX或X化合物，然后将所得化合物异构化，例如按照在路线a)中描述的方法异构化。
其中Q是基团Q5的式I化合物
Figure C01804089D00383
其中Z是硫，且R36和R01如式I中所定义，
可按照类似于已知方法(例如在WO 97/43270中描述的方法)的方法制得，所述方法包括
a)在碱、二硫化碳、和式XIII烷化剂
R01-X1    (XIII)，
其中R01如式I中所定义，且X1是离去基团例如卤素或磺酸酯，
存在下，将式XII化合物
Figure C01804089D00391
其中R36、R和m如上所定义，
转化成式XIV化合物
Figure C01804089D00392
其中Z是硫，R、R01、R36和m如上所定义，
然后任选在溶剂中，在碱存在下，用羟基胺盐酸盐将该化合物环化，以形成式Ie化合物
其中Z是硫，且R、R36、R01和m如上所定义，
然后用氧化剂例如间氯过苯甲酸(m-CPBA)将该化合物氧化。
下列反应方案1和2中更详细地描述了式I化合物的制备。
反应方案1
路线a)：
Figure C01804089D00401
路线b)：
Figure C01804089D00402
含有基团Q1、Q2、Q3和Q4，其中R20、R23、R30和R40是羟基的式I化合物尤其可按照上述反应方案制得。
反应方案2
Figure C01804089D00411
为了制备其中Q是基团Q1-Q4，且R20、R23、R30和R40是羟基的式I化合物，可依据反应方案1路线a)使用式II羧酸衍生物作为原料，其中X是离去基团，例如卤素如碘、溴或尤其是氯，N-氧基邻苯二甲酰亚胺或N，O-二甲基羟基氨基或活化酯基团例如
Figure C01804089D00412
(由二环己基碳二亚胺(DCC)和适当羧酸形成的)或
Figure C01804089D00413
(由N-乙基-N’-(3-二甲基氨基丙基)碳二亚胺(EDC)和适当羧酸形成的)。在惰性有机溶剂例如卤代烃如二氯甲烷，腈例如乙腈，或芳烃例如甲苯中，在碱例如烷基胺如三乙胺，芳族胺例如吡啶或4-二甲基氨基吡啶(DMAP)存在下，将这些化合物与式III、IV、V或VI二酮衍生物反应，以形成式VII、VIII、IX和X异构体烯醇醚。酯化在0℃-110℃进行。
式VII、VIII、IX和X酯衍生物异构化成式I二酮衍生物(其中R20、R23、R30和R40是羟基)可例如按照类似于EP 369 803的方法，在碱例如烷基胺如三乙胺，碳酸盐例如碳酸钾，和催化量的DMAP或氰化物源例如丙酮氰醇或氰化钾存在下来进行。
按照反应方案1、路线b)，所需的式I二酮(其中R20、R23、R30和R40是羟基)可这样获得，例如按照类似于《化学通信》(Chem.Lett.)1975，1045的方法，在惰性溶剂例如卤代烃如二氯甲烷，腈例如乙腈，或芳烃例如甲苯中，在碱例如烷基胺如三乙胺，和偶联剂例如2-氯-1-甲基-吡啶鎓碘化物存在下，用式III、IV、V或VI二酮衍生物将式XI羧酸酯化。根据所用的溶剂，酯化可在0℃-110℃进行，并且如路线a)所述，首先生成式I异构酯，并且如路线a)所述，例如在碱和催化量的DMAP，或氰化物源存在下，式I异构酯可异构化以形成式I二酮衍生物(其中R20、R23、R30和R40是羟基)。
其中Q是基团Q5的式I化合物的制备可这样进行，即按照反应方案2，例如采用类似于《合成》(Synthesis)1991，301；同前(ibid.)1988，793或《四面体》(Tetrahedron)32，3055(1976)的方法，在碱例如碳酸盐如碳酸钾，金属氢化物如氢化钠，或者以氟化钾/铝，和式III烷基化剂存在下，其中X1是离去基团如卤素例如碘、溴或尤其是氯、R25OSO2O-、CH3SO2O-或
Figure C01804089D00421
将式XII b-二酮衍生物与二硫化碳反应。该反应优选在溶剂例如酰胺如N，N-二甲基甲酰胺(DMF)，亚砜例如二甲亚砜(DMSO)，或腈例如乙腈中进行。在碱例如乙酸钠存在下，在溶剂例如醇如乙醇或醚例如四氢呋喃中，使用盐酸羟胺将形成的式XIV乙烯酮缩乙硫醇环化，以形成其中Z是S-的式Ie化合物。该环化反应在0℃-100℃进行。可任选按照类似于标准方法的方法，例如使用过酸如间氯过苯甲酸(m-CPBA)或过乙酸将式Ie化合物(Z＝S)氧化，以形成相应的式Ie砜和亚砜(Z＝SO-或SO2-)，其中可通过氧化剂的量来控制硫原子的氧化程度(Z＝SO-或SO2-)。
式Ie化合物的氧化(Z＝SO-或SO2-)是按照例如在H.O.House，《现代合成反应》″Modern Synthetic Reactions″W.A.Benjamin，Inc.，Menlo Park，California，1972，p.334-335和353-354中描述的方法进行的。
在反应方案1(路线a)中，其中X是离去基团例如卤素如溴、碘或尤其是氯的式II活化羧酸衍生物可按照已知的标准方法，例如在C.Ferri″Reaktionen der organischen Synthese″，Georg Thieme Verlag，Stuttgart，1978，p.461 ff中描述的方法以及如下述反应方案3所示的方法制得。
反应方案3
Figure C01804089D00431
按照反应方案3，式II化合物(X＝离去基团)或II(X＝卤素)的制备可通过例如使用卤化剂来进行，所述卤化剂是例如亚硫酰卤如亚硫酰氯或亚硫酰溴；卤化磷或磷酰卤例如五氯化磷或三氯氧化磷或五溴化磷或磷酰溴；或草酰卤例如草酰氯，或通过使用用于形成活化酯的试剂例如N，N’-二环己基碳二亚胺(DCC)或N-乙基-N’-(3-二甲基氨基丙基)碳二亚胺(EDC)来进行。在作为卤化剂的式X化合物中，X是离去基团，例如卤素如氟、溴或碘和尤其是氯，且W1是例如PCl2、SOCl、SOBr或ClCOCO。
该方法任选在惰性有机溶剂例如脂族烃、卤代脂族烃、芳烃或卤代芳烃例如正己烷、苯、甲苯、二甲苯、二氯甲烷、1，2-二氯乙烷或氯苯中，在-20℃-该反应混合物的回流温度下、优选40-150℃温度下，在催化量的N，N-二甲基甲酰胺存在下进行。这样的反应一般是已知的，并且以关于离去基团X的多种变化形式描述于文献中。
式III、IV、V和VI化合物是已知的，并且可按照类似于在例如WO92/07837、DE 3 818 958、EP 338 992和DE 3 902 818中描述的方法制得。
在反应方案2中的式XII化合物可通过标准方法，由例如相应的式II化合物制得
Figure C01804089D00441
其中R和m如式I中所定义，且X是离去基团例如卤素，
例如经由克莱森缩合而制得，或者通过与式XV酮基羧酸盐反应由式II化合物制得
Figure C01804089D00442
其中R36如式I中所定义，且M+是碱金属离子(参见例如WO 96/26192)。
式II和XI化合物是已知的，并且可按照类似于在例如WO 97/46530，《杂环》(Heterocycles)，48,779(1998)，《杂环》，46,129(1997)或《四面体通信》(Tetrahedron Letters)，1749(1998)中描述的方法制得。
为了制备所有其官能团取决于(R)m定义的其它式I化合物，可使用多种已知的标准方法例如烷基化、卤化、酰化、酰胺化、肟化、氧化和还原，合适的制备方法的选择由各中间体中的取代基的性质(反应性)决定。WO97/46353中描述了这样的反应的实例。
在式I范围内的所有其它化合物可按照考虑吡啶基和Q基团的化学性质的简单方法来制得。
式I终产物可通过浓缩或将溶剂蒸发以常规方式分离，并通过在固体残余物不易溶于其中的溶剂例如醚、芳烃或氯代烃中将固体残余物重结晶或研制，通过蒸馏或使用柱色谱与合适的洗脱剂来纯化。
此外，本领域技术人员熟悉其中一些反应应当有利进行的顺序以防止可能的副反应。
当合成不能直接使得纯的异构体分离出来时，产物可呈两种或更多种异构体的混合物的形式。可按照自身已知的方法分离异构体。
制备实施例：
实施例P1：制备4-羟基-3-(2-甲基-6-三氟甲基-吡啶-3-羰基)-二环 [3.2.11]辛-3-烯-2-酮：
将6.68g(0.0305mol)2-甲基-6-三氟甲基-烟酸甲酯(按照在《杂环》，46，129(1997)中描述的方法制得的)溶解在250ml甲醇/水(3:1混合物)中，并在22℃分批加入1.92g(0.046mol)氢氧化锂水合物。在22℃保持4小时后，将该反应混合物加到乙酸乙酯和2N盐酸中；用水将有机相洗涤3次，用硫酸钠干燥，并通过蒸发浓缩，用少量己烷研制残余物。过滤后，获得了5.69g(产率为90％)预期的2-甲基-6-三氟甲基烟酸，熔点为147-149℃。
将所得2-甲基-6-三氟甲基-烟酸(2.0g，0.0098mol)溶解在20ml草酰氯中。加入3滴二甲基甲酰胺，并将该混合物回流1小时。然后使用旋转蒸发仪将该混合物浓缩，将残余物(2-甲基-6-三氟甲基烟酰氯)置于30ml二氯甲烷中。在0℃，加入2.7ml(0.0196mol)三乙胺和0.12g(0.00098mol)二甲基氨基吡啶，然后滴加溶解在20ml二氯甲烷中的1.49g(0.0108mol)二环[3.2.1]辛-2，4-二酮。在22℃保持3小时后，通过与2N盐酸一起振摇来萃取该反应混合物。将分离的二氯甲烷相用水洗涤，然后通过与10％碳酸氢钠水溶液振摇来萃取，用硫酸钠干燥，并通过蒸发浓缩。获得了3.18g(产率为100％)2-甲基-6-三氟甲基烟酸4-氧代二环[3.2.1]辛-2-烯-2-基酯，为油状物，可不用进一步纯化直接使用。将3.02g(0.0093mol)甲基-6-三氟甲基-烟酸4-氧代二环[3.2.1]辛-2-烯-2-基酯和1.9ml(0.0136mol)三乙胺溶解在45ml乙腈中。在22℃加入0.01ml丙酮氰醇。在22℃保持18小时后，将该反应混合物倒入水与2N盐酸的混合物中，并通过与乙酸乙酯振摇来萃取。将乙酸乙酯相依次用水和盐水洗涤，用硫酸钠干燥，并通过蒸发浓缩，将残余物溶解在少量温热的丙酮中。在静置时产物结晶出来。过滤后，获得了0.99g(产率为33％)预期的4-羟基-3-(2-甲基-6-三氟甲基-吡啶-3-羰基)-二环[3.2.1]辛基-3-烯-2-酮，为白色结晶形式(m.p.75-77℃)。
实施例P2：(5-环丙基-3-甲硫基异噁唑-4-基)-(2-甲基-6-三氟甲基-吡 啶-3-基)-甲酮：
将14.8g(0.080mol)3-环丙基-3-氧代丙酸叔丁酯溶解在25mlMeOH中，加入1.93g(0.080mol)镁。滴加7ml四氯化碳，同时在冰浴中冷却，并将该反应混合物在22℃搅拌1小时以使反应完全。通过蒸发将其浓缩后，在22℃将残余物悬浮在100ml乙腈中，并滴加溶解在50ml乙腈中的16.31g(0.073mol)2-甲基-6-三氟甲基-烟酰氯(按照实施例P1中描述的方法制得的)。6小时后，将该反应混合物置于乙酸乙酯中，并用饱和碳酸氢钠溶液洗涤。将分离出的乙酸乙酯相用水洗涤，用硫酸钠干燥，并通过蒸发浓缩。将残余物溶解在160ml二氯甲烷中，并在22℃滴加10ml三氟乙酸。18小时后，将该反应混合物倒入水中，并用二氯甲烷萃取。将二氯甲烷相依次用水和盐水洗涤，用硫酸钠干燥，并通过蒸发浓缩。获得了17.3g(产率为88％)1-环丙基-3-(2-甲基-6-三氟甲基-吡啶-3-基)-丙-1，3-二酮，为油状物，可不用进一步纯化直接使用。
将所得1-环丙基-3-(2-甲基-6-三氟甲基-吡啶-3-基)-丙-1，3-二酮(15.0g，0.055mol)溶解在150ml二甲基甲酰胺中，在0℃分批加入50g以氧化铝为载体的氟化钾(Alox)(0.0055mol/g，0.276mol)。5分钟后，加入6.7g(0.088mol)二硫化碳。2小时后，滴加23.6g(0.166mol)甲基碘，并将该反应混合物在22℃加热。2小时后，过滤出Alox，将滤液倒入水中，并通过与乙酸乙酯振摇来萃取。将乙酸乙酯相依次用水和盐水洗涤，用硫酸钠干燥，并通过蒸发浓缩。通过硅胶色谱纯化残余物(洗脱剂：乙酸乙酯/己烷15/1)。获得了12.0g(产率60％)2-(二-甲硫基-亚甲基)-1-环丙基-3-(2-甲基-6-三氟甲基-吡啶-3-基)-丙-1，3-二酮，为固体。
将12.0g(0.033mol)该产物与5.4g(0.066mol)无水乙酸钠一起悬浮在120ml乙醇中。加入4.6g(0.066mol)盐酸羟胺，并将该混合物在22℃搅拌5小时。然后再加入2.7g无水乙酸钠和2.3g盐酸羟胺。18小时后，用水将该反应混合物稀释，并用乙酸乙酯萃取。将乙酸乙酯相依次用水和盐水洗涤，用硫酸钠干燥，并通过蒸发浓缩。用少量乙酸乙酯研制，获得了9.0g(79.5％)所需产物，为白色结晶(m.p.103-104℃)。
实施例P3：(5-环丙基-3-甲基亚磺酰基异噁唑-4-基)-(2-甲基-6-三氟甲 基-吡啶-3-基)-甲酮
将1.50g(0.0043mol)(5-环丙基-3-甲硫基异噁唑-4-基)-(2-甲基-6-三氟甲基-吡啶-3-基)-甲酮溶解在30ml丙酮/水(2:1混合物)中，并在22℃分批加入1.02g(0.0048mol)偏高碘酸钠。5小时后，使用旋转蒸发仪通过蒸发将该反应混合物浓缩。将残余物置于水和乙酸乙酯中。用硫酸钠将乙酸乙酯相干燥，并通过蒸发浓缩。通过硅胶色谱纯化残余物(洗脱剂：乙酸乙酯/己烷3/1)。获得了0.8g(51％)所需产物，为白色结晶(m.p.96-97℃)。
实施例P4：制备3-羟基-4，4-二甲基-2-(2-甲基-6-三氟甲基-吡啶-3-羰 基)-环己-2-烯酮(A2-B24)：
将6.68g(0.0305mol)2-甲基-6-三氟甲基-烟酸甲酯(按照在《杂环》，46,129(1997)中描述的方法制得的)溶解在250ml甲醇/水(3:1混合物)中，并在22℃分批加入1.92g(0.046mol)氢氧化锂水合物。在22℃保持4小时后，将该反应混合物加到乙酸乙酯和2N盐酸中；用水将有机相洗涤3次，用硫酸钠干燥，并通过蒸发浓缩，用少量己烷研制残余物。过滤后，获得了5.69g(产率为90％)预期的2-甲基-6-三氟甲基烟酸，熔点为147-149℃。
将所得2-甲基-6-三氟甲基-烟酸(1.026g，0.005mol)溶解在20ml草酰氯中。加入3滴二甲基甲酰胺，并将该混合物回流1小时。然后用旋转蒸发仪通过蒸发将该混合物浓缩，并将残余物(2-甲基-6-三氟甲基-烟酰氯)置于100ml二氯甲烷中。在0℃加入1.6ml(0.0115mol)三乙胺和0.7g(0.005mol)4，4-二甲基-环己烷-1，3-二酮。在22℃保持2小时后，使用旋转蒸发仪除去溶剂，将剩余的残余物溶解在55ml乙腈中，为了使该中间体重排，加入0.15ml(0.0016mol)丙酮氰醇和0.79ml(0.0057mol)三乙胺。在室温搅拌4小时后，通过蒸发将该反应溶液浓缩。通过硅胶色谱纯化剩余的浆状物。将通过用甲苯、乙醇、二氧杂环己烷、三乙胺和水的混合物(100:40:20:20:5体积份)(使用所述混合物作为流动相Rf＝0.39)洗脱而获得的浅黄色粘稠油状物溶解在二氯甲烷中，并依次用75ml盐酸5％和75ml水洗涤。用硫酸钠将有机溶液干燥后，通过蒸发浓缩，获得了1.05g(63％)纯的标题化合物。
1H NMR(d6-DMSO，δ ppm)：1.342，s，6H：2.088，t，J9Hz，2H：2.685，s，3H：2.982，t，J9Hz，2H：8.030，d，J8.1Hz，1H：8.094，d，J8.1Hz，1H。
实施例P5：制备5-甲基-5-三氟甲基-环己烷-1，3-二酮(实施例B1066)：
将0.64g钠加到40ml乙醇中，加入3.23ml乙酸甲酯和4.9g 4，4，4-三氟-3-甲基-丁-2-烯酸异丙酯，并将该混合物在沸点温度加热18小时。用稀盐酸和乙酸乙酯萃取后，通过蒸发浓缩。将保留未纯化的2-甲基-4，6-二氧代-2-三氟甲基-环己烷甲酸甲酯在9.1g氢氧化钠存在下在甲醇与水的混合物中于沸点温度酯化。然后用盐酸将该混合物酸化，并用新鲜的乙酸乙酯萃取。重结晶(乙酸乙酯)后，获得了纯的5-甲基-5-三氟甲基环己烷-1，3-二酮，熔点为150-152℃。
实施例P6：制备2-羟基-1-甲氧基-5-甲基-4-氧代环己-2-烯甲酸甲酯 (B1069)：
用35.8g甲醇钠在65ml二甲亚砜中制成30％溶液，在30-35℃用20分钟加入16.7g 3-甲基-3-丁烯-2-酮与32.4g甲氧基丙二酸二甲酯。将该混合物在35℃搅拌1小时，用盐酸酸化，然后用二氯甲烷萃取数次。将有机相用水洗涤，干燥并浓缩。通过从热的乙酸乙酯和己烷中结晶，获得了纯的2-羟基-1-甲氧基-5-甲基-4-氧代-环己-2-烯羧酸甲酯，熔点为117-117.5℃。
实施例P7：制备2-羟基-1-甲氧基-5-甲基-3-(2-甲基-6-三氟甲基-吡啶 -3-羰基)-4-氧代-环己-2-烯羧酸甲酯(A2-B1069)：
将2.23g新制的2-甲基-6-三氟甲基-烟酰氯加到2.14g 2-羟基-1-甲氧基-5-甲基-4-氧代-环己-2-烯甲酸甲酯和2.02g三乙胺在30ml乙腈内的混合物中。约30分钟后，加入0.065g氰化钾，并将该混合物搅拌18小时。然后在pH2用水和乙酸乙酯萃取，用硫酸镁干燥，并通过蒸发浓缩。经由硅胶过滤(流动相:乙酸乙酯/甲醇/三乙胺85:10:5)，获得了纯的2-羟基-1-甲氧基-5-甲基-3-(2-甲基-6-三氟甲基-吡啶-3-羰基)-4-氧代-环己-2-烯羧酸甲酯，为粘稠的油状物。
实施例P8：制备3-羟基-4-甲氧基-6-甲基-2-(2-甲基-6-三氟甲基-吡啶 -3-羰基)-环己-2-烯酮(A2-B1070)：
将0.586g氢氧化钾加到在二氧杂环己烷/水(5:3)内的1.4g2-羟基-1-甲氧基-5-甲基-3-(2-甲基-6-三氟甲基-吡啶-3-羰基)-4-氧代-环已-2-烯羧酸甲酯中，并将该混合物搅拌3小时。然后将该混合物酸化(pH3)，并用新鲜的乙酸乙酯萃取。通过类似于实施例P7的色谱法纯化粗产物，获得了3-羟基-4-甲氧基-6-甲基-2-(2-甲基-6-三氟甲基-吡啶-3-羰基)-环己-2-烯酮，为粘稠的油状物(根据1H-NMR，3种互变异构形式的混合物)。
按照类似方式，并使用在一般反应方案1和2以及其中所提及的参考文献中描述的方法，还可以制得在下表中列出的化合物。在下表中，Ph是苯基，且CC是乙炔基。
表1：式Ib化合物：
Figure C01804089D00491
化合物.      R75          R76           R77          R78       m.p.(℃)
序号
1.001        CH3          CF3           H            H         75-77
1.002        CH3CH2       CF3           H            H
1.003        (CH3)2CH     CF3           H            H         111-112
1.004        CH3(CH2)3    CF3           H            H
1.005        Ph           CF3           H            H         油状物
1.006        CH2Br        CF3           H            H
1.007        CH2OCH3      CF3           H            H         124-126
1.008        CH2SMe       CF3           H            H         油状物
1.009        CH2SO2Me     CF3           H            H         55-55
1.010        SCH3         CF3           H            H
化合物       R75         R76         R77         R78          m.p.(℃)
序号
1.011        SOCH3       CF3         H           H
1.012        SO2CH3      CF3         H           H
1.013        SPh         CF3         H           H
1.014        SOPh        CF3         H           H
1.015        SO2Ph       CF3         H           H
1.016        CH3         CF3CF2      H           H
1.017        CH3CH2      CF3CF2      H           H
1.018        (CH3)2CH    CF3CF2      H           H
1.019        CH3(CH2)3   CF3CF2      H           H
1.020        Ph          CF3CF2      H           H
1.021        CH2Br       CF3CF2      H           H
1.022        CH2OCH3     CF3CF2      H           H
1.023        CH2SMe      CF3CF2      H           H
1.024        CH2SO2Me    CF3CF2      H           H
1.025        SCH3        CF3CF2      H           H
1.026        SOCH3       CF3CF2      H           H
1.027        SO2CH3      CF3CF2      H           H
1.028        SPh         CF3CF2      H           H
1.029        SOPh        CF3CF2      H           H
1.030        SO2Ph       CF3CF2      H           H
1.031        CH3         CHF2        H           H
1.032        CH3CH2      CHF2        H           H
1.033        (CH3)2CH    CHF2        H           H
1.034        CH3(CH2)3   CHF2        H           H
1.035        Ph          CHF2        H           H
1.036        CH2Br       CHF2        H           H
1.037        CH2OCH3     CHF2        H           H
1.038        CH2SMe      CHF2        H           H
1.039        CH2SO2Me    CHF2        H           H
1.040        SCH3        CHF2        H           H
1.041        SOCH3       CHF2        H           H
1.042        SO2CH3      CHF2        H           H
化合物         R75         R76          R77         R78        m.p.(℃)
序号
1.043          SPh         CHF2         H           H
1.044          SOPh        CHF2         H           H
1.045          SO2Ph       CHF2         H           H
1.046          CH3         CF3          CH3         H
1.047          CH3CH2      CF3          CH3         H
1.048          (CH3)2CH    CF3          CH3         H
1.049          CH3(CH2)3   CF3          CH3         H
1.050          Ph          CF3          CH3         H
1.051          CH2Br       CF3          CH3         H
1.052          CH2OCH3     CF3          CH3         H
1.053          CH2SMe      CF3          CH3         H
1.054          CH2SO2Me    CF3          CH3         H
1.055          SCH3        CF3          CH3         H
1.056          SOCH3       CF3          CH3         H
1.057          SO2CH3      CF3          CH3         H
1.058          SPh         CF3          CH3         H
1.059          SOPh        CF3          CH3         H
1.060          SO2Ph       CF3          CH3         H
1.061          CH3         CF3CF2       CH3         H
1.062          CH3CH2      CF3CF2       CH3         H
1.063          (CH3)2CH    CF3CF2       CH3         H
1.064          CH3(CH2)3   CF3CF2       CH3         H
1.065          Ph          CF3CF2       CH3         H
1.066          CH2Br       CF3CF2       CH3         H
1.067          CH2OCH3     CF3CF2       CH3         H
1.068          CH2SMe      CF3CF2       CH3         H
1.069          CH2SO2Me    CF3CF2       CH3         H
1.070          SCH3        CF3CF2       CH3         H
1.071          SOCH3       CF3CF2       CH3         H
1.072          SO2CH3      CF3CF2       CH3         H
1.073          SPh         CF3CF2       CH3         H
1.074          SOPh        CF3CF2       CH3         H
化合物           R75         R76         R77         R78       m.p.(℃)
序号
1.075            SO2Ph       CF3CF2      CH3         H
1.076            CH3         CHF2        CH3         H
1.077            CH3CH2      CHF2        CH3         H
1.078            (CH3)2CH    CHF2        CH3         H
1.079            CH3(CH2)3   CHF2        CH3         H
1.080            Ph          CHF2        CH3         H
1.081            CH2Br       CHF2        CH3         H
1.082            CH2OCH3     CHF2        CH3         H
1.083            CH2SMe      CHF2        CH3         H
1.084            CH2SO2Me    CHF2        CH3         H
1.085            SCH3        CHF2        CH3         H
1.086            SOCH3       CHF2        CH3         H
1.087            SO2CH3      CHF2        CH3         H
1.088            SPh         CHF2        CH3         H
1.089            SOPh        CHF2        CH3         H
1.090            SO2Ph       CHF2        CH3         H
1.091            CH3         CF3         H           CH3       92-94
1.092            CH3CH2      CF3         H           CH3
1.093            (CH3)2CH    CF3         H           CH3
1.094            CH3(CH2)3   CF3         H           CH3
1.095            Ph          CF3         H           CH3
1.096            CH2Br       CF3         H           CH3
1.097            CH2OCH3     CF3         H           CH3
1.098            CH2SMe      CF3         H           CH3
1.099            CH2SO2Me    CF3         H           CH3
1.100            SCH3        CF3         H           CH3
1.101            SOCH3       CF3         H           CH3
1.102            SO2CH3      CF3         H           CH3
1.103            SPh         CF3         H           CH3
1.104            SOPh        CF3         H           CH3
1.105            SO2Ph       CF3         H           CH3
表2：式Ic化合物：
Figure C01804089D00531
化合物.       R75       R76       R77       R78       m.p.(℃)
序号
2.001         CH3       CF3       H         H         107-109
2.002         CH3CH2    CF3       H         H         油状物
2.003         (CH3)2CH  CF3       H         H         油状物
2.004         CH3(CH2)3 CF3       H         H
2.005         Ph        CF3       H         H         油状物
2.006         CH2Br     CF3       H         H
2.007         CH2OCH3   CF3       H         H
2.008         CH2SMe    CF3       H         H
2.009         CH2SO2Me  CF3       H         H
2.010         SCH3      CF3       H         H
2.011         SOCH3     CF3       H         H
2.012         SO2CH3    CF3       H         H
2.013         SPh       CF3       H         H
2.014         SOPh      CF3       H         H
2.015         SO2Ph     CF3       H         H
2.016         CH3       CF3CF2    H         H
2.017         CH3CH2    CF3CF2    H         H
2.018         (CH3)2CH  CF3CF2    H         H
2.019         CH3(CH2)3 CF3CF2    H         H
2.020         Ph        CF3CF2    H         H
2.021         CH2Br     CF3CF2    H         H
2.022         CH2OCH3   CF3CF2    H         H
化合物      R75        R76      R77        R78       m.p.(℃)
序号
2.023       CH2SMe     CF3CF2   H          H
2.024       CH2SO2Me   CF3CF2   H          H
2.025       SCH3       CF3CF2   H          H
2.026       SOCH3      CF3CF2   H          H
2.027       SO2CH3     CF3CF2   H          H
2.028       SPh        CF3CF2   H          H
2.029       SOPh       CF3CF2   H          H
2.030       SO2Ph      CF3CF2   H          H
2.031       CH3        CHF2     H          H
2.032       CH3CH2     CHF2     H          H
2.033       (CH3)2CH   CHF2     H          H
2.034       CH3(CH2)3  CHF2     H          H
2.035       Ph         CHF2     H          H
2.036       CH2Br      CHF2     H          H
2.037       CH2OCH3    CHF2     H          H
2.038       CH2SMe     CHF2     H          H
2.039       CH2SO2Me   CHF2     H          H
2.040       SCH3       CHF2     H          H
2.041       SOCH3      CHF2     H          H
2.042       SO2CH3     CHF2     H          H
2.043       SPh        CHF2     H          H
2.044       SOPh       CHF2     H          H
2.045       SO2Ph      CHF2     H          H
2.046       CH3        CF3      CH3        H
2.047       CH3CH2     CF3      CH3        H
2.048       (CH3)2CH   CF3      CH3        H
2.049       CH3(CH2)3  CF3      CH3        H
2.050       Ph         CF3      CH3        H
2.051       CH2Br      CF3      CH3        H
2.052       CH2OCH3    CF3      CH3        H
2.053       CH2SMe     CF3      CH3        H
2.054       CH2SO2Me   CF3      CH3        H
化合物       R75       R76       R77        R78        m.p.(℃)
序号
2.055        SCH3      CF3       CH3        H
2.056        SOCH3     CF3       CH3        H
2.057        SO2CH3    CF3       CH3        H
2.058        SPh       CF3       CH3        H
2.059        SOPh      CF3       CH3        H
2.060        SO2Ph     CF3       CH3        H
2.061        CH3       CF3CF2    CH3        H
2.062        CH3CH2    CF3CF2    CH3        H
2.063        (CH3)2CH  CF3CF2    CH3        H
2.064        CH3(CH2)3 CF3CF2    CH3        H
2.065        Ph        CF3CF2    CH3        H
2.066        CH2Br     CF3CF2    CH3        H
2.067        CH2OCH3   CF3CF2    CH3        H
2.068        CH2SMe    CF3CF2    CH3        H
2.069        CH2SO2Me  CF3CF2    CH3        H
2.070        SCH3      CF3CF2    CH3        H
2.071        SOCH3     CF3CF2    CH3        H
2.072        SO2CH3    CF3CF2    CH3        H
2.073        SPh       CF3CF2    CH3        H
2.074        SOPh      CF3CF2    CH3        H
2.075        SO2Ph     CF3CF2    CH3        H
2.076        CH3       CHF2      CH3        H
2.077        CH3CH2    CHF2      CH3        H
2.078        (CH3)2CH  CHF2      CH3        H
2.079        CH3(CH2)3 CHF2      CH3        H
2.080        Ph        CHF2      CH3        H
2.081        CH2Br     CHF2      CH3        H
2.082        CH2OCH3   CHF2      CH3        H
2.083        CH2SMe    CHF2      CH3        H
2.084        CH2SO2Me  CHF2      CH3        H
2.085        SCH3      CHF2      CH3        H
2.086        SOCH3     CHF2      CH3        H
化合物      R75       R76      R77       R78       m.p.(℃)
序号
2.087       SO2CH3    CHF2     CH3       H
2.088       SPh       CHF2     CH3       H
2.089       SOPh      CHF2     CH3       H
2.090       SO2Ph     CHF2     CH3       H
2.091       CH3       CF3      H         CH3
2.092       CH3CH2    CF3      H         CH3
2.093       (CH3)2CH  CF3      H         CH3
2.094       CH3(CH2)3 CF3      H         CH3
2.095       Ph        CF3      H         CH3
2.096       CH2Br     CF3      H         CH3
2.097       CH2OCH3   CF3      H         CH3
2.098       CH2SMe    CF3      H         CH3
2.099       CH2SO2Me  CF3      H         CH3
2.100       SCH3      CF3      H         CH3
2.101       SOCH3     CF3      H         CH3
2.102       SO2CH3    CF3      H         CH3
2.103       SPh       CF3      H         CH3
2.104       SOPh      CF3H               CH3
2.105       SO2Ph     CF3      H         CH3
表3：式Id化合物：
Figure C01804089D00561
化合物.        R75     R76      R77      R78       m.p.(℃)
序号
化合物      R75        R76        R77       R78        m.p.(℃)
序号
3.001       CH3        CF3        H         H
3.002       CH3CH2     CF3        H         H
3.003       (CH3)2CH   CF3        H         H
3.004       CH3(CH2)3  CF3        H         H
3.005       Ph         CF3        H         H
3.006       CH2Br      CF3        H         H
3.007       CH2OCH3    CF3        H         H
3.008       CH2SMe     CF3        H         H
3.009       CH2SO2Me   CF3        H         H
3.010       SCH3       CF3        H         H
3.011       SOCH3      CF3        H         H
3.012       SO2CH3     CF3        H         H
3.013       SPh        CF3        H         H
3.014       SOPh       CF3        H         H
3.015       SO2Ph      CF3        H         H
3.016       CH3        CF3CF2     H         H
3.017       CH3CH2     CF3CF2     H         H
3.018       (CH3)2CH   CF3CF2     H         H
3.019       CH3(CH2)3  CF3CF2     H         H
3.020       Ph         CF3CF2     H         H
3.021       CH2Br      CF3CF2     H         H
3.022       CH2OCH3    CF3CF2     H         H
3.023       CH2SMe     CF3CF2     H         H
3.024       CH2SO2Me   CF3CF2     H         H
3.025       SCH3       CF3CF2     H         H
3.026       SOCH3      CF3CF2     H         H
3.027       SO2CH3     CF3CF2     H         H
3.028       SPh        CF3CF2     H         H
3.029       SOPh       CF3CF2     H         H
3.030       SO2Ph      CF3CF2     H         H
3.031       CH3        CHF2       H         H
化合物      R75        R76         R77       R78        m.p.(℃)
序号
3.032       CH3CH2     CHF2        H         H
3.033       (CH3)2CH   CHF2        H         H
3.034       CH3(CH2)3  CHF2        H         H
3.035       Ph         CHF2        H         H
3.036       CH2Br      CHF2        H         H
3.037       CH2OCH3    CHF2        H         H
3.038       CH2SMe     CHF2        H         H
3.039       CH2SO2Me   CHF2        H         H
3.040       SCH3       CHF2        H         H
3.041       SOCH3      CHF2        H         H
3.042       SO2CH3     CHF2        H         H
3.043       SPh        CHF2        H         H
3.044       SOPh       CHF2        H         H
3.045       SO2Ph      CHF2        H         H
3.046       CH3        CF3         CH3       H
3.047       CH3CH2     CF3         CH3       H
3.048       (CH3)2CH   CF3         CH3       H
3.049       CH3(CH2)3  CF3         CH3       H
3.050       Ph         CF3         CH3       H
3.051       CH2Br      CF3         CH3       H
3.052       CH2OCH3    CF3         CH3       H
3.053       CH2SMe     CF3         CH3       H
3.054       CH2SO2Me   CF3         CH3       H
3.055       SCH3       CF3         CH3       H
3.056       SOCH3      CF3         CH3       H
3.057       SO2CH3     CF3         CH3       H
3.058       SPh        CF3         CH3       H
3.059       SOPh       CF3         CH3       H
3.060       SO2Ph      CF3         CH3       H
3.061       CH3        CF3CF2      CH3       H
3.062       CH3CH2     CF3CF2      CH3       H
3.063       (CH3)2CH   CF3CF2      CH3       H
化合物      R75          R76          R77          R78              m.p.(℃)
序号
3.064       CH3(CH2)3    CF3CF2       CH3          H
3.065       Ph           CF3CF2       CH3          H
3.066       CH2Br        CF3FC2       CH3          H
3.067       CH2OCH3      CF3CF2       CH3          H
3.068       CH2SMe       CF3CF2       CH3          H
3.069       CH2SO2Me     CF3CF2       CH3          H
3.070       SCH3         CF3CF2       CH3          H
3.071       SOCH3        CF3CF2       CH3          H
3.072       SO2CH3       CF3CF2       CH3          H
3.073       SPh          CF3CF2       CH3          H
3.074       SOPh         CF3CF2       CH3          H
3.075       SO2Ph        CF3CF2       CH3          H
3.076       CH3          CHF2         CH3          H
3.077       CH3CH2       CHF2         CH3          H
3.078       (CH3)2CH     CHF2         CH3          H
3.079       CH3(CH2)3    CHF2         CH3          H
3.080       Ph           CHF2         CH3          H
3.081       CH2Br        CHF2         CH3          H
3.082       CH2OCH3C     HF2          CH3          H
3.083       CH2SMe       CHF2         CH3          H
3.084       CH2SO2Me     CHF2         CH3          H
3.085       SCH3         CHF2         CH3          H
3.086       SOCH3        CHF2         CH3          H
3.087       SO2CH3       CHF2         CH3          H
3.088       SPh          CHF2         CH3          H
3.089       SOPh         CHF2         CH3          H
3.090       SO2Ph        CHF2         CH3          H
3.091       CH3          CF3          H            CH3
3.092       CH3CH2       CF3          H            CH3
3.093       (CH3)2CH     CF3          H            CH3
3.094       CH3(CH2)3    CF3          H            CH3
3.095       Ph           CF3         H            CH3
化合物      R75        R76        R77        R78         m.p.(℃)
序号
3.096       CH2Br      CF3        H          CH3
3.097       CH2OCH3    CF3        H          CH3
3.098       CH2SMe     CF3        H          CH3
3.099       CH2SO2Me   CF3        H          CH3
3.100       SCH3       CF3        H          CH3
3.101       SOCH3      CF3        H          CH3
3.102       SO2CH3     CF3        H          CH3
3.103       SPh        CF3        H          CH3
3.104       SOPh       CF3        H          CH3
3.105       SO2Ph      CF3        H          CH3
表4：式Ie化合物：
Figure C01804089D00601
化合物       R75        R76       R77        R78       Z         m.p.(℃)
序号
4.001        CH3        CF3       H          H         S         103-104
4.002        CH3CH2     CF3       H          H         S
4.003        (CH3)2CH   CF3       H          H         S
4.004        CH3(CH2)3  CF3       H          H         S
4.005        Ph         CF3       H          H         S
4.006        CH2Br      CF3       H          H         S
4.007        CH2OCH3    CF3       H          H         S
4.008        CH2SMe     CF3       H          H         S
化合物        R75       R76       R77        R78         Z        m.p.(℃)
序号
4.009         CH2SO2Me  CF3       H          H           S
4.010         SCH3      CF3       H          H           S
4.011         SOCH3     CF3       H          H           S
4.012         SO2CH3    CF3       H          H           S
4.013         SPh       CF3       H          H           S
4.014         SOPh      CF3       H          H           S
4.015         SO2Ph     CF3       H          H           S
4.016         CH3       CF3CF2    H          H           S
4.017         CH3CH2    CF3CF2    H          H           S
4.018         (CH3)2CH  CF3CF2    H          H           S
4.019         CH3(CH2)3 CF3CF2    H          H           S
4.020         Ph        CF3CF2    H          H           S
4.021         CH2Br     CF3CF2    H          H           S
4.022         CH2OCH3   CF3CF2    H          H           S
4.023         CH2SMe    CF3CF2    H          H           S
4.024         CH2SO2Me  CF3CF2    H          H           S
4.025         SCH3      CF3CF2    H          H           S
4.026         SOCH3     CF3CF2    H          H           S
4.027         SO2CH3    CF3CF2    H          H           S
4.028         SPh       CF3CF2    H          H           S
4.029         SOPh      CF3CF2    H          H           S
4.030         SO2Ph     CF3CF2    H          H           S
4.031         CH3       CHF2      H          H           S
4.032         CH3CH2    CHF2      H          H           S
4.033         (CH3)2CH  CHF2      H          H           S
4.034         CH3(CH2)3 CHF2      H          H           S
4.035         Ph        CHF2      H          H           S
4.036         CH2Br     CHF2      H          H           S
4.037         CH2OCH3   CHF2      H          H           S
4.038         CH2SMe    CHF2      H          H           S
4.039         CH2SO2Me  CHF2      H          H           S
4.040         SCH3      CHF2      H          H           S
化合物        R75       R76        R77        R78        Z        m.p.(℃)
序号
4.041         SOCH3     CHF2       H          H          S
4.042         SO2CH3    CHF2       H          H          S
4.043         SPh       CHF2       H          H          S
4.044         SOPh      CHF2       H          H          S
4.045         SO2Ph     CHF2       H          H          S
4.046         CH3       CF3        CH3        H          S
4.047         CH3CH2    CF3        CH3        H          S
4.048         (CH3)2CH  CF3        CH3        H          S
4.049         CH3(CH2)3 CF3        CH3        H          S
4.050         Ph        CF3        CH3        H          S
4.051         CH2Br     CF3        CH3        H          S
4.052         CH2OCH3   CF3        CH3        H          S
4.053         CH2SMe    CF3        CH3        H          S
4.054         CH2SO2Me  CF3        CH3        H          S
4.055         SCH3      CF3        CH3        H          S
4.056         SOCH3     CF3        CH3        H          S
4.057         SO2CH3    CF3        CH3        H          S
4.058         SPh       CF3        CH3        H          S
4.059         SOPh      CF3        CH3        H          S
4.060         SO2Ph     CF3        CH3        H          S
4.061         CH3       CF3CF2     CH3        H          S
4.062         CH3CH2    CF3CF2     CH3        H          S
4.063         (CH3)2CH  CF3CF2     CH3        H          S
4.064         CH3(CH2)3 CF3CF2     CH3        H          S
4.065         Ph        CF3CF2     CH3        H          S
4.066         CH2Br     CF3CF2     CH3        H          S
4.067         CH2OCH3   CF3CF2     CH3        H          S
4.068         CH2SMe    CF3CF2     CH3        H          S
4.069         CH2SO2Me  CF3CF2     CH3        H          S
4.070         SCH3      CF3CF2     CH3        H          S
4.071         SOCH3     CF3CF2     CH3        H          S
4.072         SO2CH3    CF3CF2     CH3        H          S
化合物        R75        R76       R77        R78      Z        m.p.(℃)
序号
4.073         SPh        CF3CF2    CH3        H        S
4.074         SOPh       CF3CF2    CH3        H        S
4.075         SO2Ph      CF3CF2    CH3        H        S
4.076         CH3        CHF2      CH3        H        S
4.077         CH3CH2     CHF2      CH3        H        S
4.078         (CH3)2CH   CHF2      CH3        H        S
4.079         CH3(CH2)3  CHF2      CH3        H        S
4.080         Ph         CHF2      CH3        H        S
4.081         CH2Br      CHF2      CH3        H        S
4.082         CH2OCH3    CHF2      CH3        H        S
4.083         CH2SMe     CHF2      CH3        H        S
4.084         CH2SO2Me   CHF2      CH3        H        S
4.085         SCH3       CHF2      CH3        H        S
4.086         SOCH3      CHF2      CH3        H        S
4.087         SO2CH3     CHF2      CH3        H        S
4.088         SPh        CHF2      CH3        H        S
4.089         SOPh       CHF2      CH3        H        S
4.090         SO2Ph      CHF2      CH3        H        S
4.091         CH3        CF3       H          CH3      S
4.092         CH3CH2     CF3       H          CH3      S
4.093         (CH3)2CH   CF3       H          CH3      S
4.094         CH3(CH2)3  CF3       H          CH3      S
4.095         Ph         CF3       H          CH3      S
4.096         CH2Br      CF3       H          CH3      S
4.097         CH2OCH3    CF3       H          CH3      S
4.098         CH2SMe     CF3       H          CH3      S
4.099         CH2SO2Me   CF3       H          CH3      S
4.100         SCH3       CF3       H          CH3      S
4.101         SOCH3      CF3       H          CH3      S
4.102         SO2CH3     CF3       H          CH3      S
4.103         SPh        CF3       H          CH3      S
4.104         SOPh       CF3       H          CH3      S
化合物.      R75      R76        R77       R78        Z       m.p.(℃)
序号
4.105        SO2Ph      CF3        H         CH3        S
4.106        CH3        CF3        H         H          SO      96-97
4.107        CH3CH2     CF3        H         H          SO
4.108        (CH3)2CH   CF3        H         H          SO
4.109        CH3(CH2)3  CF3        H         H          SO
4.110        Ph        CF3        H         H          SO
4.111        CH2Br     CF3        H         H          SO
4.112        CH2OCH3   CF3        H         H          SO
4.113        CH2SMe    CF3        H         H          SO
4.114        CH2SO2Me  CF3        H         H          SO
4.115        SCH3      CF3        H         H          SO
4.116        SOCH3     CF3        H         H          SO
4.117        SO2CH3    CF3        H         H          SO
4.118        SPh       CF3        H         H          SO
4.119        SOPh      CF3        H         H          SO
4.120        SO2Ph     CF3        H         H          SO
4.121        CH3       CF3CF2     H         H          SO
4.122        CH3CH2    CF3CF2     H         H          SO
4.123        (CH3)2CH  CF3CF2     H         H          SO
4.124        CH3(CH2)3  CF3CF2     H         H          SO
4.125        Ph        CF3CF2     H         H          SO
4.126        CH2Br     CF3CF2     H         H          SO
4.127        CH2OCH3   CF3CF2     H         H          SO
4.128        CH2SMe    CF3CF2     H         H          SO
4.129        CH2SO2Me  CF3CF2     H         H          SO
4.130        SCH3      CF3CF2     H         H          SO
4.131        SOCH3     CF3CF2     H         H          SO
4.132        SO2CH3    CF3CF2     H         H          SO
4.133        SPh      CF3CF2     H         H          SO
4.134        SOPh     CF3CF2     H         H          SO
4.135        SO2Ph    CF3CF2     H         H          SO
4.136        CH3      CHF2       H         H          SO
化合物       R75       R76        R77       R78        Z      m.p.(℃)
序号
4.137        CH3CH2    CHF2       H         H          SO
4.138        (CH3)2CH  CHF2       H         H          SO
4.139        CH3(CH2)3 CHF2       H         H          SO
4.140        Ph        CHF2       H         H          SO
4.141        CH2Br     CHF2       H         H          SO
4.142        CH2OCH3   CHF2       H         H          SO
4.143        CH2SMe    CHF2       H         H          SO
4.144        CH2SO2Me  CHF2       H         H          SO
4.145        SCH3      CHF2       H         H          SO
4.146        SOCH3     CHF2       H         H          SO
4.147        SO2CH3    CHF2       H         H          SO
4.148        SPh       CHF2       H         H          SO
4.149        SOPh      CHF2       H         H          SO
4.150        SO2Ph     CHF2       H         H          SO
4.151        CH3       CF3        CH3       H          SO
4.152        CH3CH2    CF3        CH3       H          SO
4.153        (CH3)2CH  CF3        CH3       H          SO
4.154        CH3(CH2)3 CF3        CH3       H          SO
4.155        Ph        CF3        CH3       H          SO
4.156        CH2Br     CF3        CH3       H          SO
4.157        CH2OCH3   CF3        CH3       H          SO
4.158        CH2SMe    CF3        CH3       H          SO
4.159        CH2SO2Me  CF3        CH3       H          SO
4.160        SCH3      CF3        CH3       H          SO
4.161        SOCH3     CF3        CH3       H          SO
4.162        SO2CH3    CF3        CH3       H          SO
4.163        SPh       CF3        CH3       H          SO
4.164        SOPh      CF3        CH3       H          SO
4.165        SO2Ph     CF3        CH3       H          SO
4.166        CH3       CF3CF2     CH3       H          SO
4.167        CH3CH2    CF3CF2     CH3       H          SO
4.168        (CH3)2CH  CF3CF2     CH3       H          SO
化合物       R75           R76          R77           R78        Z       m.p.(℃)
序号
4.169        CH3(CH2)3     CF3CF2       CH3           H          SO
4.170        Ph            CF3CF2       CH3           H          SO
4.171        CH2Br         CF3CF2       CH3           H          SO
4.172        CH2OCH3       CF3CF2       CH3           H          SO
4.173        CH2SMe        CF3CF2       CH3           H          SO
4.174        CH2SO2Me      CF3CF2       CH3           H          SO
4.175        SCH3          CF3CF2       CH3           H          SO
4.176        SOCH3         CF3CF2       CH3           H          SO
4.177        SO2CH3        CF3CF2       CH3           H          SO
4.178        SPh           CF3CF2       CH3           H          SO
4.179        SOPh          CF3CF2       CH3           H          SO
4.180        SO2Ph         CF3CF2       CH3           H          SO
4.181        CH3           CHF2         CH3           H          SO
4.182        CH3CH2        CHF2         CH3           H          SO
4.183        (CH3)2CH      CHF2         CH3           H          SO
4.184        CH3(CH2)3     CHF2         CH3           H          SO
4.185        Ph            CHF2         CH3           H          SO
4.186        CH2Br         CHF2         CH3           H          SO
4.187        CH2OCH3       CHF2         CH3           H          SO
4.188        CH2SMe        CHF2         CH3           H          SO
4.189        CH2SO2Me      CHF2         CH3           H          SO
4.190        SCH3          CHF2         CH3           H          SO
4.191        SOCH3         CHF2         CH3           H          SO
4.192        SO2CH3        CHF2         CH3           H          SO
4.193        SPh           CHF2         CH3           H          SO
4.194        SOPh          CHF2         CH3           H          SO
4.195        SO2Ph         CHF2         CH3           H          SO
4.196        CH3           CF3          H             CH3        SO
4.197        CH3CH2        CF3          H             CH3        SO
4.198        (CH3)2CH      CF3          H             CH3        SO
4.199        CH3(CH2)3     CF3          H             CH3        SO
4.200        Ph            CF3          H             CH3        SO
化合物        R75            R76            R77           R78       Z       m.p.(℃)
序号
4.201         CH2Br          CF3            H             CH3       SO
4.202         CH2OCH3        CF3            H             CH3       SO
4.203         CH2SMe         CF3            H             CH3       SO
4.204         CH2SO2Me       CF3            H             CH3       SO
4.205         SCH3           CF3            H             CH3       SO
4.206         SOCH3          CF3            H             CH3       SO
4.207         SO2CH3         CF3            H             CH3       SO
4.208         SPh            CF3            H             CH3       SO
4.209         SOPh           CF3            H             CH3       SO
4.210         SO2Ph          CF3            H             CH3       SO
4.211         CH3            CF3            H             H         SO2     无定形
4.212         CH3CH2         CF3            H             H         SO2
4.213         (CH3)2CH       CF3            H             H         SO2
4.214         CH3(CH2)3      CF3            H             H         SO2
4.215         Ph             CF3            H             H         SO2
4.216         CH2Br          CF3            H             H         SO2
4.217         CH2OCH3        CF3            H             H         SO2
4.218         CH2SMe         CF3            H             H         SO2
4.219         CH2SO2Me       CF3            H             H         SO2
4.220         SCH3           CF3            H             H         SO2
4.221         SOCH3          CF3            H             H         SO2
4.222         SO2CH3         CF3            H             H         SO2
4.223         SPh            CF3            H             H         SO2
4.224         SOPh           CF3            H             H         SO2
4.225         SO2Ph          CF3            H             H         SO2
4.226         CH3            CF3CF2         H             H         SO2
4.227         CH3CH2         CF3CF2         H             H         SO2
4.228         (CH3)2CH       CF3CF2         H             H         SO2
4.229         CH3(CH2)3      CF3CF2         H             H         SO2
4.230         Ph             CF3CF2         H             H         SO2
4.231         CH2Br          CF3CF2         H             H         SO2
化合物       R75       R76        R77         R78       Z          m.p.(℃)
序号
4.232        CH2OCH3   CF3CF2     H           H         SO2
4.233        CH2SMe    CF3CF2     H           H         SO2
4.234        CH2SO2Me  CF3CF2     H           H         SO2
4.235        SCH3      CF3CF2     H           H         SO2
4.236        SOCH3     CF3CF2     H           H         SO2
4.237        SO2CH3    CF3CF2     H           H         SO2
4.238        SPh       CF3CF2     H           H         SO2
4.239        SOPh      CF3CF2     H           H         SO2
4.240        SO2Ph     CF3CF2     H           H         SO2
4.241        CH3       CHF2       H           H         SO2
4.242        CH3CH2    CHF2       H           H         SO2
4.243        (CH3)2CH  CHF2       H           H         SO2
4.244        CH3(CH2)3 CHF2       H           H         SO2
4.245        Ph        CHF2       H           H         SO2
4.246        CH2Br     CHF2       H           H         SO2
4.247        CH2OCH3   CHF2       H           H         SO2
4.248        CH2SMe    CHF2       H           H         SO2
4.249        CH2SO2Me  CHF2       H           H         SO2
4.250        SCH3      CHF2       H           H         SO2
4.251        SOCH3     CHF2       H           H         SO2
4.252        SO2CH3    CHF2       H           H         SO2
4.253        SPh       CHF2       H           H         SO2
4.254        SOPh      CHF2       H           H         SO2
4.255        SO2Ph     CHF2       H           H         SO2
4.256        CH3       CF3        CH3         H         SO2
4.257        CH3CH2    CF3        CH3         H         SO2
4.258        (CH3)2CH  CF3        CH3         H         SO2
4.259        CH3(CH2)3 CF3        CH3         H         SO2
4.260        Ph        CF3        CH3         H         SO2
4.261        CH2Br     CF3        CH3         H         SO2
4.262        CH2OCH3   CF3        CH3         H         SO2
4.263        CH2SMe    CF3        CH3         H         SO2
化合物        R75          R76          R77         R78        Z        m.p.(℃)
序号
4.264         CH2SO2Me     CF3          CH3         H          SO2
4.265         SCH3         CF3          CH3         H          SO2
4.266         SOCH3        CF3          CH3         H          SO2
4.267         SO2CH3       CF3          CH3         H          SO2
4.268         SPh          CF3          CH3         H          SO2
4.269         SOPh         CF3          CH3         H          SO2
4.270         SO2Ph        CF3          CH3         H          SO2
4.271         CH3          CF3CF2       CH3         H          SO2
4.272         CH3CH2       CF3CF2       CH3         H          SO2
4.273         (CH3)2CH     CF3CF2       CH3         H          SO2
4.274         CH3(CH2)3    CF3CF2       CH3         H          SO2
4.275         Ph           CF3CF2       CH3         H          SO2
4.276         CH2Br        CF3CF2       CH3         H          SO2
4.277         CH2OCH3      CF3CF2       CH3         H          SO2
4.278         CH2SMe       CF3CF2       CH3         H          SO2
4.279         CH2SO2Me     CF3CF2       CH3         H          SO2
4.280         SCH3         CF3CF2       CH3         H          SO2
4.281         SOCH3        CF3CF2       CH3         H          SO2
4.282         SO2CH3       CF3CF2       CH3         H          SO2
4.283         SPh          CF3CF2       CH3         H          SO2
4.284         SOPh         CF3CF2       CH3         H          SO2
4.285         SO2Ph        CF3CF2       CH3         H          SO2
4.286         CH3          CHF2         CH3         H          SO2
4.287         CH3CH2       CHF2         CH3         H          SO2
4.288         (CH3)2CH     CHF2         CH3         H          SO2
4.289         CH3(CH2)3    CHF2         CH3         H          SO2
4.290         Ph           CHF2         CH3         H          SO2
4.291         CH2Br        CHF2         CH3         H          SO2
4.292         CH2OCH3      CHF2         CH3         H          SO2
4.293         CH2SMe       CHF2         CH3         H          SO2
4.294         CH2SO2Me     CHF2         CH3         H          SO2
4.295         SCH3         CHF2         CH3         H          SO2
化合物         R75            R76           R77           R78         Z        m.p.(℃)
序号
4.296          SOCH3          CHF2          CH3           H           SO2
4.297          SO2CH3         CHF2          CH3           H           SO2
4.298          SPh            CHF2          CH3           H           SO2
4.299          SOPh           CHF2          CH3           H           SO2
4.300          SO2Ph          CHF2          CH3           H           SO2
4.301          CH3            CF3           H             CH3         SO2
4.302          CH3CH2         CF3           H             CH3         SO2
4.303          (CH3)2CH       CF3           H             CH3         SO2
4.304          CH3(CH2)3      CF3           H             CH3         SO2
4.305          Ph             CF3           H             CH3         SO2
4.306          CH2Br          CF3           H             CH3         SO2
4.307          CH2OCH3        CF3           H             CH3         SO2
4.308          CH2SMe         CF3           H             CH3         SO2
4.309          CH2SO2Me       CF3           H             CH3         SO2
4.310          SCH3           CF3           H             CH3         SO2
4.311          SOCH3          CF3           H             CH3         SO2
4.312          SO2CH3         CF3           H             CH3         SO2
4.313          SPh            CF3           H             CH3         SO2
4.314          SOPh           CF3           H             CH3         SO2
4.315          SO2Ph          CF3           H             CH3         SO2
表5：式XVI化合物：
Figure C01804089D00701
化合物         R79          R80        R81         R82
序号
A1             H            H         H           CF3
化合物.         R79                       R80         R81           R82
序号
A2              CH3                       H           H             CF3
A3              CH3CH2                    H           H             CF3
A4              (CH3)2CH                  H           H             CF3
A5              (CH3)3C                   H           H             CF3
A6              环丙基                    H           H             CF3
A7              CH3(CH2)2                 H           H             CF3
A8              CH3OCH2                   H           H             CF3
A9              CH3O(CH2)2                H           H             CF3
A10             Ph                        H           H             CF3
A11             PhO                       H           H             CF3
A12             PhS                       H           H             CF3
A13             PhSO                      H           H             CF3
A14             PhSO2                     H           H             CF3
A15             CH3S                      H           H             CF3
A16             CH3SO                     H           H             CF3
A17             CF3                       H           H             CF3
A18             F2CH                      H           H             CF3
A19             HCC                       H           H             CF3
A20             CH3CC                     H           H             CF3
A21             CH2＝CH                   H           H             CF3
A22             CH2＝CHCH2                H           H             CF3
A23             CH3SO2N(CH3)              H           H             CF3
A24             (CH3)2N                   H           H             CF3
A25             (CH3)2NSO2                H           H             CF3
A26             ClCH2                     H           H             CF3
A27             CH3SCH2                   H           H             CF3
A28             CH3SOCH2                  H           H             CF3
A29             CH3SO2CH2                 H           H             CF3
A30             [1，2，4]-三唑-1-基-甲基  H           H             CF3
A31             CH3                       CF3          H             CH3
A32             CH3                       CH3         H             CF3
A33             H                         H           H             CF3CF2
化合物       R79                           R80           R81             R82
序号
A34          CH3                           H             H               CF3CF2
A35          CH3CH2                        H             H               CF3CF2
A36          环丙基                        H             H               CF3CF2
A37          (CH3)3C                       H             H               CF3CF2
A38          (CH3)2CH                      H             H               CF3CF2
A39          CH3(CH2)2                     H             H               CF3CF2
A40          CH3OCH2                       H             H               CF3CF2
A41          CH3O(CH2)2                    H             H               CF3CF2
A42          Ph                            H             H               CF3CF2
A43          PhO                           H             H               CF3CF2
A44          PhS                           H             H               CF3CF2
A45          PhSO                          H             H               CF3CF2
A46          PhSO2                         H             H               CF3CF2
A47          CH3S                          H             H               CF3CF2
A48          CH3SO                         H             H               CF3CF2
A49          CF3                           H             H               CF3CF2
A50          F2CH                          H             H               CF3CF2
A51          HCC                           H             H               CF3CF2
A52          CH3CC                         H             H               CF3CF2
A53          CH2＝CH                       H             H               CF3CF2
A54          CH2＝CHCH2                    H             H               CF3CF2
A55          CH3SO2N(CH3)                  H             H               CF3CF2
A56          (CH3)2N                       H             H               CF3CF2
A57          (CH3)2NSO2                    H             H               CF3CF2
A58          ClCH2                         H             H               CF3CF2
A59          CH3SCH2                       H             H               CF3CF2
A60          CH3SOCH2                       H             H               CF3CF2
A61          CH3SO2CH2                     H             H               CF3CF2
A62          [1，2，4]-三唑-1-基-甲基      H             H               CF3CF2
A63          H                             H             H               CF3CF2CF2
A64          CH3                           H             H               CF3CF2CF2
A65          CH3CH2                        H             H               CF3CF2CF2
化合物.     R79                         R80          R81         R82
序号
A66         环丙基                      H            H           CF3CF2CF2
A67         (CH3)3C                     H            H           CF3CF2CF2
A68         (CH3)2CH                    H            H           CF3CF2CF2
A69         CH3(CH2)2                   H            H           CF3CF2CF2
A70         CH3OCH2                     H            H           CF3CF2CF2
A71         CH3O(CH2)2                  H            H           CF3CF2CF2
A72         Ph                          H            H           CF3CF2CF2
A73         PhO                         H            H           CF3CF2CF2
A74         PhS                         H            H           CF3CF2CF2
A75         PhSO                        H            H           CF3CF2CF2
A76         PhSO2                       H            H           CF3CF2CF2
A77         CH3S                        H            H           CF3CF2CF2
A78         CH3SO                       H            H           CF3CF2CF2
A79         CF3                         H            H           CF3CF2CF2
A80         F2CH                        H            H           CF3CF2CF2
A81         HCC                         H            H           CF3CF2CF2
A82         CH3CC                       H            H           CF3CF2CF2
A83         CH2＝CH                     H            H           CF3CF2CF2
A84         CH2＝CHCH2                  H            H           CF3CF2CF2
A85         CH3SO2N(CH3)                H            H           CF3CF2CF2
A86         (CH3)2N                     H            H           CF3CF2CF2
A87         (CH3)2NSO2                  H            H           CF3CF2CF2
A88         ClCH2                       H            H           CF3CF2CF2
A89         CH3SCH2                     H            H           CF3CF2CF2
A90         CH3SOCH2                    H            H           CF3CF2CF2
A91         CH3SO2CH2                   H            H           CF3CF2CF2
A92         [1，2，4]-三唑-1-基-甲基    H            H           CF3CF2CF2
A93         H                           H            H           CF2Cl
A94         CH3                         H            H           CF2Cl
A95         CH3CH2                      H            H           CF2Cl
A96         环丙基                      H            H           CF2Cl
A97         (CH3)3C                     H            H           CF2Cl
化合物     R79                       R80       R81        R82
序号
A98        (CH3)2CH                  H         H          CF2Cl
A99        CH3(CH2)2                 H         H          CF2Cl
A100       CH3OCH2                   H         H          CF2Cl
A101       CH3O(CH2)2                H         H          CF2Cl
A102       Ph                        H         H          CF2Cl
A103       PhO                       H         H          CF2Cl
A104       PhS                       H         H          CF2Cl
A105       PhSO                      H         H          CF2Cl
A106       PhSO2                     H         H          CF2Cl
A107       CH3S                      H         H          CF2Cl
A108       CH3SO                     H         H          CF2Cl
A109       CF3                       H         H          CF2Cl
A110       F2CH                      H         H          CF2Cl
A111       HCC                       H         H          CF2Cl
A112       CH3CC                     H         H          CF2Cl
A113       CH2＝CH                   H         H          CF2Cl
A114       CH2＝CHCH2                H         H          CF2Cl
A115       CH3SO2N(CH3)              H         H          CF2Cl
A116       (CH3)2N                   H         H          CF2Cl
A117       (CH3)2NSO2                H         H          CF2Cl
A118       ClCH2                     H         H          CF2Cl
A119       CH3SCH2                   H         H          CF2Cl
A120       CH3SOCH2                  H         H          CF2Cl
A121       CH3SO2CH2                 H         H          CF2Cl
A122       [1，2，4]-三唑-1-基-甲基  H         H          CF2Cl
A123       H                         H         H          CHF2
A124       CH3                       H         H          CHF2
A125       CH3CH2                    H         H          CHF2
A126       环丙基                    H         H          CHF2
A127       (CH3)3C                   H         H          CHF2
A128       (CH3)2CH                  H         H          CHF2
A129       CH3(CH2)2                 H         H          CHF2
化合物     R79                              R80          R81            R82
序号
A130       CH3OCH2                          H            H              CHF2
A131       CH3O(CH2)2                       H            H              CHF2
A132       Ph                               H            H              CHF2
A133       PhO                              H            H              CHF2
A134       PhS                              H            H              CHF2
A135       PhSO                             H            H              CHF2
A136       PhSO2                            H            H              CHF2
A137       CH3S                             H            H              CHF2
A138       CH3SO                            H            H              CHF2
A139       CF3                              H            H              CHF2
A140       F2CH                             H            H              CHF2
A141       HCC                              H            H              CHF2
A142       CH3CC                            H            H              CHF2
A143       CH2＝CH                          H            H              CHF2
A144       CH2＝CHCH2                       H            H              CHF2
A145       CH3SO2N(CH3)                     H            H              CHF2
A146       (CH3)2N                          H            H              CHF2
A147       (CH3)2NSO2                       H            H              CHF2
A148       ClCH2                            H            H              CHF2
A149       CH3SCH2                          H            H              CHF2
A150       CH3SOCH2                         H            H              CHF2
A151       CH3SO2CH2                        H            H              CHF2
A152       [1，2，4]-三唑-1-基-甲基         H            H              CHF2
A153       H                                H            H              CCl3
A154       CH3                              H            H              CCl3
A155       CH3CH2                           H            H              CCl3
A156       环丙基                           H            H              CCl3
A157       (CH3)3C                          H            H              CCl3
A158       (CH3)2CH                         H            H              CCl3
A159       CH3(CH2)2                        H            H              CCl3
A160       CH3OCH2                          H            H              CCl3
A161       CH3O(CH2)2                       H            H              CCl3
化合物       R79                       R80       R81         R82
序号
A162         Ph                        H         H           CCl3
A163         PhO                       H         H           CCl3
A164         PhS                       H         H           CCl3
A165         PhSO                      H         H           CCl3
A166         PhSO2                     H         H           CCl3
A167         CH3S                      H         H           CCl3
A168         CH3SO                     H         H           CCl3
A169         CF3                       H         H           CCl3
A170         F2CH                      H         H           CCl3
A171         HCC                       H         H           CCl3
A172         CH3CC                     H         H           CCl3
A173         CH2＝CH                   H         H           CCl3
A174         CH2＝CHCH2                H         H           CCl3
A175         CH3SO2N(CH3)              H         H           CCl3
A176         (CH3)2N                   H         H           CCl3
A177         (CH3)2NSO2                H         H           CCl3
A178         ClCH2                     H         H           CCl3
A179         CH3SCH2                   H         H           CCl3
A180         CH3SOCH2                  H         H           CCl3
A181         CH3SO2CH2                 H         H           CCl3
A182         [1，2，4]-三唑-1-基-甲基  H         H           CCl3
A183         H                         H         CH3         CF3
A184         CH3                       H         CH3         CF3
A185         CH3CH2                    H         CH3         CF3
A186         环丙基                    H         CH3         CF3
A187         (CH3)3C                   H         CH3         CF3
A188         (CH3)2CH                  H         CH3         CF3
A189         CH3(CH2)2                 H         CH3         CF3
A190         CH3OCH2                   H         CH3         CF3
A191         CH3O(CH2)2                H         CH3         CF3
A192         Ph                        H         CH3         CF3
A193         PhO                       H         CH3         CF3
化合物     R79                      R80       R81       R82
序号
A194       PhS                      H         CH3       CF3
A195       PhSO                     H         CH3       CF3
A196       PhSO2                    H         CH3       CF3
A197       CH3S                     H         CH3       CF3
A198       CH3SO                    H         CH3       CF3
A199       CF3                      H         CH3       CF3
A200       F2CH                     H         CH3       CF3
A201       HCC                      H         CH3       CF3
A202       CH3CC                    H         CH3       CF3
A203       CH2＝CH                  H         CH3       CF3
A204       CH2＝CHCH2               H         CH3       CF3
A205       CH3SO2N(CH3)             H         CH3       CF3
A206       (CH3)2N                  H         CH3       CF3
A207       (CH3)2NSO2               H         CH3       CF3
A208       ClCH2                    H         CH3       CF3
A209       CH3SCH2                  H         CH3       CF3
A210       CH3SOCH2                 H         CH3       CF3
A211       CH3SO2CH2                H         CH3       CF3
A212       H                        H         CH3       CF3CF2
A213       CH3                      H         CH3       CF3CF2
A214       CH3CH2                   H         CH3       CF3CF2
A215       环丙基                   H         CH3       CF3CF2
A216       (CH3)3C                  H         CH3       CF3CF2
A217       (CH3)2CH                 H         CH3       CF3CF2
A218       CH3(CH2)2                H         CH3       CF3CF2
A219       CH3OCH2                  H         CH3       CF3CF2
A220       CH3O(CH2)2               H         CH3       CF3CF2
A221       Ph                       H         CH3       CF3CF2
A222       PhO                      H         CH3       CF3CF2
A223       PhS                      H         CH3       CF3CF2
A224       PhSO                     H         CH3       CF3CF2
A225       PhSO2                    H         CH3       CF3CF2
化合物      R79         R80       R81        R82
序号
A226        CH3S        H         CH3        CF3CF2
A227        CH3SO       H         CH3        CF3CF2
A228        CF3         H         CH3        CF3CF2
A229        F2CH        H         CH3        CF3CF2
A230        HCC         H         CH3        CF3CF2
A231        CH3CC       H         CH3        CF3CF2
A232        CH2＝CH     H         CH3        CF3CF2
A233        CH2＝CHCH2  H         CH3        CF3CF2
A234        CH3SO2N(CH3)H         CH3        CF3CF2
A235        (CH3)2N     H         CH3        CF3CF2
A236        (CH3)2NSO2  H         CH3        CF3CF2
A237        ClCH2       H         CH3        CF3CF2
A238        CH3SCH2     H         CH3        CF3CF2
A239        CH3SOCH2    H         CH3        CF3CF2
A240        CH3SO2CH2   H         CH3        CF3CF2
A241        H           H         CH3        CF3CF2CF2
A242        CH3         H         CH3        CF3CF2CF2
A243        CH3CH2      H         CH3        CF3CF2CF2
A244        环丙基      H         CH3        CF3CF2CF2
A245        (CH3)3C     H         CH3        CF3CF2CF2
A246        (CH3)2CH    H         CH3        CF3CF2CF2
A247        CH3(CH2)2   H         CH3        CF3CF2CF2
A248        CH3OCH2     H         CH3        CF3CF2CF2
A249        CH3O(CH2)2  H         CH3        CF3CF2CF2
A250        Ph          H         CH3        CF3CF2CF2
A251        PhO         H         CH3        CF3CF2CF2
A252        PhS         H         CH3        CF3CF2CF2
A253        PhSO        H         CH3        CF3CF2CF2
A254        PhSO2       H         CH3        CF3CF2CF2
A255        CH3S        H         CH3        CF3CF2CF2
A256        CH3SO       H         CH3        CF3CF2CF2
A257        CF3         H         CH3        CF3CF2CF2
化合物      R79         R80         R81        R82
序号
A258        F2CH        H           CH3        CF3CF2CF2
A259        HCC         H           CH3        CF3CF2CF2
A260        CH3CC       H           CH3        CF3CF2CF2
A261        CH2＝CH     H           CH3        CF3CF2CF2
A262        CH2＝CHCH2  H           CH3        CF3CF2CF2
A263        CH3SO2N(CH3)H           CH3        CF3CF2CF2
A264        (CH3)2N     H           CH3        CF3CF2CF2
A265        (CH3)2NSO2  H           CH3        CF3CF2CF2
A266        ClCH2       H           CH3        CF3CF2CF2
A267        CH3SCH2     H           CH3        CF3CF2CF2
A268        CH3SOCH2    H           CH3        CF3CF2CF2
A269        CH3SO2CH2   H           CH3        CF3CF2CF2
A270        H           H           CH3        CF2Cl
A271        CH3         H           CH3        CF2Cl
A272        CH3CH2      H           CH3        CF2Cl
A273        环丙基      H           CH3        CF2Cl
A274        (CH3)3C     H           CH3        CF2Cl
A275        (CH3)2CH    H           CH3        CF2Cl
A276        CH3(CH2)2   H           CH3        CF2Cl
A277        CH3OCH2     H           CH3        CF2Cl
A278        CH3O(CH2)2  H           CH3        CF2Cl
A279        Ph          H           CH3        CF2Cl
A280        PhO         H           CH3        CF2Cl
A281        PhS         H           CH3        CF2Cl
A282        PhSO        H           CH3        CF2Cl
A283        PhSO2       H           CH3        CF2Cl
A284        CH3S        H           CH3        CF2Cl
A285        CH3SO       H           CH3        CF2Cl
A286        CF3         H           CH3        CF2Cl
A287        F2CH        H           CH3        CF2Cl
A288        HCC         H           CH3        CF2Cl
A289        CH3CC       H           CH3        CF2Cl
化合物      R79            R80       R81       R82
序号
A290        CH2＝CH        H         CH3       CF2Cl
A291        CH2＝CHCH2     H         CH3       CF2Cl
A292        CH3SO2N(CH3)   H         CH3       CF2Cl
A293        (CH3)2N        H         CH3       CF2Cl
A294        (CH3)2NSO2     H         CH3       CF2Cl
A295        ClCH2          H         CH3       CF2Cl
A296        CH3SCH2        H         CH3       CF2Cl
A297        CH3SOCH2       H         CH3       CF2Cl
A298        CH3SO2CH2      H         CH3       CF2Cl
A299        H              H         CH3       CHF2
A300        CH3            H         CH3       CHF2
A301        CH3CH2         H         CH3       CHF2
A302        环丙基         H         CH3       CHF2
A303        (CH3)3C        H         CH3       CHF2
A304        (CH3)2CH       H         CH3       CHF2
A305        CH3(CH2)2      H         CH3       CHF2
A306        CH3OCH2        H         CH3       CHF2
A307        CH3O(CH2)2     H         CH3       CHF2
A308        Ph             H         CH3       CHF2
A309        PhO            H         CH3       CHF2
A310        PhS            H         CH3       CHF2
A311        PhSO           H         CH3       CHF2
A312        PhSO2          H         CH3       CHF2
A313        CH3S           H         CH3       CHF2
A314        CH3SO          H         CH3       CHF2
A315        CF3            H         CH3       CHF2
A316        F2CH           H         CH3       CHF2
A317        HCC            H         CH3       CHF2
A318        CH3CC          H         CH3       CHF2
A319        CH2＝CH        H         CH3       CHF2
A320        CH2＝CHCH2     H         CH3       CHF2
A321        CH3SO2N(CH3)   H         CH3       CHF2
化合物      R79                R80          R81            R82
序号
A322        (CH3)2N            H            CH3            CHF2
A323        (CH3)2NSO2         H            CH3            CHF2
A324        ClCH2              H            CH3            CHF2
A325        CH3SCH2            H            CH3            CHF2
A326        CH3SOCH2           H            CH3            CHF2
A327        CH3SO2CH2          H            CH3            CHF2
A328        H                  H            CH3            CCl3
A329        CH3                H            CH3            CCl3
A330        CH3CH2             H            CH3            CCl3
A331        (CH3)3C            H            CH3            CCl3
A332        (CH3)2CH           H            CH3            CCl3
A333        环丙基             H            CH3            CCl3
A334        CH3(CH2)2          H            CH3            CCl3
A335        CH3OCH2            H            CH3            CCl3
A336        CH3O(CH2)2         H            CH3            CCl3
A337        Ph                 H            CH3            CCl3
A338        PhO                H            CH3            CCl3
A339        PhS                H            CH3            CCl3
A340        PhSO               H            CH3            CCl3
A341        PhSO2              H            CH3            CCl3
A342        CH3S               H            CH3            CCl3
A343        CH3SO              H            CH3            CCl3
A344        CF3                H            CH3            CCl3
A345        F2CH               H            CH3            CCl3
A346        HCC                H            CH3            CCl3
A347        CH3CC              H            CH3            CCl3
A348        CH2＝CH            H            CH3            CCl3
A349        CH2＝CHCH2         H            CH3            CCl3
A350        CH3SO2N(CH3)       H            CH3            CCl3
A351        (CH3)2N            H            CH3            CCl3
A352        (CH3)2NSO2         H            CH3            CCl3
A353        ClCH2              H            CH3            CCl3
化合物     R79               R80             R81             R82
序号
A354       CH3SCH2           H               CH3             CCl3
A355       CH3SOCH2          H               CH3             CCl3
A356       CH3SO2CH2         H               CH3             CCl3
A357       H                 H               Ph              CF3
A358       CH3               H               Ph              CF3
A359       CH3CH2            H               Ph              CF3
A360       环丙基            H               Ph              CF3
A361       (CH3)3C           H               Ph              CF3
A362       (CH3)2CH          H               Ph              CF3
A363       CH3(CH2)2         H               Ph              CF3
A364       CH3OCH2           H               Ph              CF3
A365       CH3O(CH2)2        H               Ph              CF3
A366       Ph                H               Ph              CF3
A367       PhO               H               Ph              CF3
A368       PhS               H               Ph              CF3
A369       PhSO              H               Ph              CF3
A370       PhSO2             H               Ph              CF3
A371       CH3S              H               Ph              CF3
A372       CH3SO             H               Ph              CF3
A373       CF3               H               Ph              CF3
A374       F2CH              H               Ph              CF3
A375       HCC               H               Ph              CF3
A376       CH3CC             H               Ph              CF3
A377       CH2＝CH           H               Ph              CF3
A378       CH2＝CHCH2        H               Ph              CF3
A379       CH3SO2N(CH3)      H               Ph              CF3
A380       (CH3)2N           H               Ph              CF3
A381       (CH3)2NSO2        H               Ph              CF3
A382       ClCH2             H               Ph              CF3
A383       CH3SCH2           H               Ph              CF3
A384       CH3SOCH2          H               Ph              CF3
A385       CH3SO2CH2         H               Ph              CF3
化合物      R79           R80          R81          R82
序号
A386        H             H            Ph           CF3CF2
A387        CH3           H            Ph           CF3CF2
A388        CH3CH2        H            Ph           CF3CF2
A389        环丙基        H            Ph           CF3CF2
A390        (CH3)3C       H            Ph           CF3CF2
A391        (CH3)2CH      H            Ph           CF3CF2
A392        CH3(CH2)2     H            Ph           CF3CF2
A393        CH3OCH2       H            Ph           CF3CF2
A394        CH3O(CH2)2    H            Ph           CF3CF2
A395        Ph            H            Ph           CF3CF2
A396        PhO           H            Ph           CF3CF2
A397        PhS           H            Ph           CF3CF2
A398        PhSO          H            Ph           CF3CF2
A399        PhSO2         H            Ph           CF3CF2
A400        CH3S          H            Ph           CF3CF2
A401        CH3SO         H            Ph           CF3CF2
A402        CF3           H            Ph           CF3CF2
A403        F2CH          H            Ph           CF3CF2
A404        HCC           H            Ph           CF3CF2
A405        CH3CC         H            Ph           CF3CF2
A406        CH2＝CH       H            Ph           CF3CF2
A407        CH2＝CHCH2    H            Ph           CF3CF2
A408        CH3SO2N(CH3)  H            Ph           CF3CF2
A409        (CH3)2N       H            Ph           CF3CF2
A410        (CH3)2NSO2    H            Ph           CF3CF2
A411        ClCH2         H            Ph           CF3CF2
A412        CH3SCH2       H            Ph           CF3CF2
A413        CH3SOCH2      H            Ph           CF3CF2
A414        CH3SO2CH2     H            Ph           CF3CF2
A415        H             H            Ph           CF3CF2CF2
A416        CH3           H            Ph           CF3CF2CF2
A417        CH3CH2        H            Ph           CF3CF2CF2
化合物.        R79            R80        R81         R82
序号
A418           环丙基         H          Ph          CF3CF2CF2
A419           (CH3)3C        H          Ph          CF3CF2CF2
A420           (CH3)2CH       H          Ph          CF3CF2CF2
A421           CH3(CH2)2      H          Ph          CF3CF2CF2
A422           CH3OCH2        H          Ph          CF3CF2CF2
A423           CH3O(CH2)2     H          Ph          CF3CF2CF2
A424           Ph             H          Ph          CF3CF2CF2
A425           PhO            H          Ph          CF3CF2CF2
A426           PhS            H          Ph          CF3CF2CF2
A427           PhSO           H          Ph          CF3CF2CF2
A428           PhSO2          H          Ph          CF3CF2CF2
A429           CH3S           H          Ph          CF3CF2CF2
A430           CH3SO          H          Ph          CF3CF2CF2
A431           CF3            H          Ph          CF3CF2CF2
A432           F2CH           H          Ph          CF3CF2CF2
A433           HCC            H          Ph          CF3CF2CF2
A434           CH3CC          H          Ph          CF3CF2CF2
A435           CH2＝CH        H          Ph          CF3CF2CF2
A436           CH2＝CHCH2     H          Ph          CF3CF2CF2
A437           CH3SO2N(CH3)   H          Ph          CF3CF2CF2
A438           (CH3)2N        H          Ph          CF3CF2CF2
A439           (CH3)2NSO2     H          Ph          CF3CF2CF2
A440           ClCH2          H          Ph          CF3CF2CF2
A441           CH3SCH2        H          Ph          CF3CF2CF2
A442           CH3SOCH2       H          Ph          CF3CF2CF2
A443           CH3SO2CH2      H          Ph          CF3CF2CF2
A444           H              H          Ph          CF2Cl
A445           CH3            H          Ph          CF2Cl
A446           CH3CH2         H          Ph          CF2Cl
A447           cyclopropyl    H          Ph          CF2Cl
A448           (CH3)3C        H          Ph          CF2Cl
A449           (CH3)2CH       H          Ph          CF2Cl
化合物        R79          R80            R81          R82
序号
A450          CH3(CH2)2    H              Ph           CF2Cl
A451          CH3OCH2      H              Ph           CF2Cl
A452          CH3O(CH2)2   H              Ph           CF2Cl
A453          Ph           H              Ph           CF2Cl
A454          PhO          H              Ph           CF2Cl
A455          PhS          H              Ph           CF2Cl
A456          PhSO         H              Ph           CF2Cl
A457          PhSO2        H              Ph           CF2Cl
A458          CH3S         H              Ph           CF2Cl
A459          CH3SO        H              Ph           CF2Cl
A460          CF3          H              Ph           CF2Cl
A461          F2CH         H              Ph           CF2Cl
A462          HCC          H              Ph           CF2Cl
A463          CH3CC        H              Ph           CF2Cl
A464          CH2＝CH      H              Ph           CF2Cl
A465          CH2＝CHCH2   H              Ph           CF2Cl
A466          CH3SO2N(CH3) H              Ph           CF2Cl
A467          (CH3)2N      H              Ph           CF2Cl
A468          (CH3)2NSO2   H              Ph           CF2Cl
A469          ClCH2        H              Ph           CF2Cl
A470          CH3SCH2      H              Ph           CF2Cl
A471          CH3SOCH2     H              Ph           CF2Cl
A472          CH3SO2CH2    H              Ph           CF2Cl
A473          H            H              Ph           CHF2
A474          CH3          H              Ph           CHF2
A475          CH3CH2       H              Ph           CHF2
A476          环丙基       H              Ph           CHF2
A477          (CH3)3C      H              Ph           CHF2
A478          (CH3)2CH     H              Ph           CHF2
A479          CH3(CH2)2    H              Ph           CHF2
A480          CH3OCH2      H              Ph           CHF2
A481          CH3O(CH2)2   H              Ph           CHF2
化合物        R79          R80        R81        R82
序号
A482          Ph           H          Ph         CHF2
A483          PhO          H          Ph         CHF2
A484          PhS          H          Ph         CHF2
A485          PhSO         H          Ph         CHF2
A486          PhSO2        H          Ph         CHF2
A487          CH3S         H          Ph         CHF2
A488          CH3SO        H          Ph         CHF2
A489          CF3          H          Ph         CHF2
A490          F2CH         H          Ph         CHF2
A491          HCC          H          Ph         CHF2
A492          CH3CC        H          Ph         CHF2
A493          CH2＝CH      H          Ph         CHF2
A494          CH2＝CHCH2   H          Ph         CHF2
A495          CH3SO2N(CH3) H          Ph         CHF2
A496          (CH3)2N      H          Ph         CHF2
A497          (CH3)2NSO2   H          Ph         CHF2
A498          ClCH2        H          Ph         CHF2
A499          CH3SCH2      H          Ph         CHF2
A500          CH3SOCH2     H          Ph         CHF2
A501          CH3SO2CH2    H          Ph         CHF2
A502          H            H          Ph         CCl3
A503          CH3          H          Ph         CCl3
A504          CH3CH2       H          Ph         CCl3
A505          环丙基       H          Ph         CCl3
A506          (CH3)3C      H          Ph         CCl3
A507          (CH3)2CH     H          Ph         CCl3
A508          CH3(CH2)2    H          Ph         CCl3
A509          CH3OCH2      H          Ph         CCl3
A510          CH3O(CH2)2   H          Ph         CCl3
A511          Ph           H          Ph         CCl3
A512          PhO          H          Ph         CCl3
A513          PhS          H          Ph         CCl3
化合物        R79         R80        R81        R82
序号
A514          PhSO        H          Ph         CCl3
A515          PhSO2       H          Ph         CCl3
A516          CH3S        H          Ph         CCl3
A517          CH3SO       H          Ph         CCl3
A518          CF3         H          Ph         CCl3
A519          F2CH        H          Ph         CCl3
A520          HCC         H          Ph         CCl3
A521          CH3CC       H          Ph         CCl3
A522          CH2＝CH     H          Ph         CCl3
A523          CH2＝CHCH2  H          Ph         CCl3
A524          CH3SO2N(CH3)H          Ph         CCl3
A525          (CH3)2N     H          Ph         CCl3
A526          (CH3)2NSO2  H          Ph         CCl3
A527          ClCH2       H          -Ph        CCl3
A528          CH3SCH2     H          Ph         CCl3
A529          CH3SOCH2    H          Ph         CCl3
A530          CH3SO2CH2   H          Ph         CCl3
A531          H           CH3        H          CF3
A532          H           CH3CH2     H          CF3
A533          H           环丙基     H          CF3
A534          H           (CH3)3CH   H          CF3
A535          H           (CH3)2CH   H          CF3
A536          H           CH3(CH2)2  H          CF3
A537          H           CH3OCH2    H          CF3
A538          H           CH3O(CH2)2 H          CF3
A539          H           Ph         H          CF3
A540          H           PhO        H          CF3
A541          H           PhS        H          CF3
A542          H           PhSO       H          CF3
A543          H           PhSO2      H          CF3
A544          H           CH3S       H          CF3
A545          H           CH3SO      H          CF3
化合物       R79        R80             R81        R82
序号
A546         H          CF3             H          CF3
A547         H          F2CH            H          CF3
A548         H          HCC             H          CF3
A549         H          CH3CC           H          CF3
A550         H          CH2＝CH         H          CF3
A551         H          CH2＝CHCH2      H          CF3
A552         H          CH3SO2N(CH3)    H          CF3
A553         H          (CH3)2N         H          CF3
A554         H          (CH3)2NSO2      H          CF3
A555         H          CH3SCH2         H          CF3
A556         H          CH3SOCH2        H          CF3
A557         H          CH3SO2CH2       H          CF3
A558         H          CH3             H          CF3CF2
A559         H          CH3CH2          H          CF3CF2
A560         H          环丙基          H          CF3CF2
A561         H          (CH3)3C         H          CF3CF2
A562         H          (CH3)2CH        H          CF3CF2
A563         H          CH3(CH2)2       H          CF3CF2
A564         H          CH3OCH2         H          CF3CF2
A565         H          CH3O(CH2)2      H          CF3CF2
A566         H          Ph              H          CF3CF2
A567         H          PhO             H          CF3CF2
A568         H          PhS             H          CF3CF2
A569         H          PhSO            H          CF3CF2
A570         H          PhSO2           H          CF3CF2
A571         H          CH3S            H          CF3CF2
A572         H          CH3SO           H          CF3CF2
A573         H          CF3             H          CF3CF2
A574         H          F2CH            H          CF3CF2
A575         H          HCC             H          CF3CF2
A576         H          CH3CC           H          CF3CF2
A577         H          CH2＝CH         H          CF3CF2
化合物        R79           R80           R81            R82
序号
A578          H             CH2＝CHCH2    H              CF3CF2
A579          H             CH3SO2N(CH3)  H              CF3CF2
A580          H             (CH3)2N       H              CF3CF2
A581          H             (CH3)2NSO2    H              CF3CF2
A582          H             CH3SCH2       H              CF3CF2
A583          H             CH3SOCH2      H              CF3CF2
A584          H             CH3SO2CH2     H              CF3CF2
A585          H             CH3           H              CF3CF2CF2
A586          H             CH3CH2        H              CF3CF2CF2
A587          H             环丙基        H              CF3CF2CF2
A588          H             (CH3)3C       H              CF3CF2CF2
A589          H             (CH3)2CH      H              CF3CF2CF2
A590          H             CH3(CH2)2     H              CF3CF2CF2
A591          H             CH3OCH2       H              CF3CF2CF2
A592          H             CH3O(CH2)2    H              CF3CF2CF2
A593          H             Ph            H              CF3CF2CF2
A594          H             PhO           H              CF3CF2CF2
A595          H             PhS           H              CF3CF2CF2
A596          H             PhSO          H              CF3CF2CF2
A597          H             PhSO2         H              CF3CF2CF2
A598          H             CH3S          H              CF3CF2CF2
A599          H             CH3SO         H              CF3CF2CF2
A600          H             CF3           H              CF3CF2CF2
A601          H             F2CH          H              CF3CF2CF2
A602          H             HCC           H              CF3CF2CF2
A603          H             CH3CC         H              CF3CF2CF2
A604          H             CH2＝CH       H              CF3CF2CF2
A605          H             CH2＝CHCH2    H              CF3CF2CF2
A606          H             CH3SO2N(CH3)  H              CF3CF2CF2
A607          H             (CH3)2N       H              CF3CF2CF2
A608          H             (CH3)2NSO2    H              CF3CF2CF2
A609          H             CH3SCH2       H              CF3CF2CF2
化合物          R79         R80           R81           R82
序号
A610            H           CH3SOCH2      H             CF3CF2CF2
A611            H           CH3SO2CH2     H             CF3CF2CF2
A612            H           CH3           H             CF2Cl
A613            H           CH3CH2        H             CF2Cl
A614            H           环丙基        H             CF2Cl
A615            H           (CH3)3C       H             CF2Cl
A616            H           (CH3)2CH      H             CF2Cl
A617            H           CH3(CH2)2     H             CF2Cl
A618            H           CH3OCH2       H             CF2Cl
A619            H           CH3O(CH2)2    H             CF2Cl
A620            H           Ph            H             CF2Cl
A621            H           PhO           H             CF2Cl
A622            H           PhS           H             CF2Cl
A623            H           PhSO          H             CF2Cl
A624            H           PhSO2         H             CF2Cl
A625            H           CH3S          H             CF2Cl
A626            H           CH3SO         H             CF2Cl
A627            H           CF3           H             CF2Cl
A628            H           F2CH          H             CF2Cl
A629            H           HCC           H             CF2Cl
A630            H           CH3CC         H             CF2Cl
A631            H           CH2＝CH       H             CF2Cl
A632            H           CH2＝CHCH2    H             CF2Cl
A633            H           CH3SO2N(CH3)  H             CF2Cl
A634            H           (CH3)2N       H             CF2Cl
A635            H           (CH3)2NSO2    H             CF2Cl
A636            H           CH3SCH2       H             CF2Cl
A637            H           CH3SOCH2      H             CF2Cl
A638            H           CH3SO2CH2     H             CF2Cl
A639            H           CH3           H             CHF2
A640            H           CH3CH2        H             CHF2
A641            H           环丙基        H             CHF2
化合物       R79         R80            R81         R82
序号
A642         H           (CH3)3C        H           CHF2
A643         H           (CH3)2CH       H           CHF2
A644         H           CH3(CH2)2      H           CHF2
A645         H           CH3OCH2        H           CHF2
A646         H           CH3O(CH2)2     H           CHF2
A647         H           Ph             H           CHF2
A648         H           PhO            H           CHF2
A649         H           PhS            H           CHF2
A650         H           PhSO           H           CHF2
A651         H           PhSO2          H           CHF2
A652         H           CH3S           H           CHF2
A653         H           CH3SO          H           CHF2
A654         H           CF3            H           CHF2
A655         H           F2CH           H           CHF2
A656         H           HCC            H           CHF2
A657         H           CH3CC          H           CHF2
A658         H           CH2＝CH        H           CHF2
A659         H           CH2＝CHCH2     H           CHF2
A660         H           CH3SO2N(CH3)   H           CHF2
A661         H           (CH3)2N        H           CHF2
A662         H           (CH3)2NSO2     H           CHF2
A663         H           CH3SCH2        H           CHF2
A664         H           CH3SOCH2       H           CHF2
A665         H           CH3SO2CH2      H           CHF2
A666         H           CH3            H           CCl3
A667         H           CH3CH2         H           CCl3
A668         H           环丙基         H           CCl3
A669         H           (CH3)3C        H           CCl3
A670         H           (CH3)2CH       H           CCl3
A671         H           CH3(CH2)2      H           CCl3
A672         H           CH3OCH2        H           CCl3
A673         H           CH3O(CH2)2     H           CCl3
化合物        R79        R80              R81           R82
序号
A674          H          Ph               H             CCl3
A675          H          PhO              H             CCl3
A676          H          PhS              H             CCl3
A677          H          PhSO             H             CCl3
A678          H          PhSO2            H             CCl3
A679          H          CH3S             H             CCl3
A680          H          CH3SO            H             CCl3
A681          H          CF3              H             CCl3
A682          H          F2CH             H             CCl3
A683          H          HCC              H             CCl3
A684          H          CH3CC            H             CCl3
A685          H          CH2＝CH          H             CCl3
A686          H          CH2＝CHCH2       H             CCl3
A687          H          CH3SO2N(CH3)     H             CCl3
A688          H          (CH3)2N          H             CCl3
A689          H          (CH3)2NSO2       H             CCl3
A690          H          CH3SCH2          H             CCl3
A691          H          CH3SOCH2         H             CCl3
A692          H          CH3SO2CH2        H             CCl3
A693          H          CH3              CH3           CF3
A694          H          CH3CH2           CH3           CF3
A695          H          环丙基           CH3           CF3
A696          H          (CH3)3C          CH3           CF3
A697          H          (CH3)2CH         CH3           CF3
A698          H          CH3(CH2)2        CH3           CF3
A699          H          CH3OCH2          CH3           CF3
A700          H          CH3O(CH2)2       CH3           CF3
A701          H          Ph               CH3           CF3
A702          H          PhO              CH3           CF3
A703          H          PhS              CH3           CF3
A704          H          PhSO             CH3           CF3
A705          H          PhSO2            CH3           CF3
化合物.      R79          R80            R81         R82
序号
A706         H            CH3S           CH3         CF3
A707         H            CH3SO          CH3         CF3
A708         H            CF3            CH3         CF3
A709         H            F2CH           CH3         CF3
A710         H            HCC            CH3         CF3
A711         H            CH3CC          CH3         CF3
A712         H            CH2＝CH        CH3         CF3
A713         H            CH2＝CHCH2     CH3         CF3
A714         H            CH3SO2N(CH3)   CH3         CF3
A715         H            (CH3)2N        CH3         CF3
A716         H            (CH3)2NSO2     CH3         CF3
A717         H            CH3SCH2        CH3         CF3
A718         H            CH3SOCH2       CH3         CF3
A719         H            CH3SO2CH2      CH3         CF3
A720         H            CH3            CH3         CF3CF2
A721         H            CH3CH2         CH3         CF3CF2
A722         H            环丙基         CH3         CF3CF2
A723         H            (CH3)3C        CH3         CF3CF2
A724         H            (CH3)2CH       CH3         CF3CF2
A725         H            CH3(CH2)2      CH3         CF3CF2
A726         H            CH3OCH2        CH3CF       3CF2
A727         H            CH3O(CH2)2     CH3         CF3CF2
A728         H            Ph             CH3         CF3CF2
A729         H            PhO            CH3         CF3CF2
A730         H            PhS            CH3         CF3CF2
A731         H            PhSO           CH3         CF3CF2
A732         H            PhSO2          CH3         CF3CF2
A733         H            CH3S           CH3         CF3CF2
A734         H            CH3SO          CH3         CF3CF2
A735         H            CF3            CH3         CF3CF2
A736         H            F2CH           CH3         CF3CF2
A737         H            HCC            CH3         CF3CF2
化合物       R79        R80            R81           R82
序号
A738         H          CH3CC          CH3           CF3CF2
A739         H          CH2＝CH        CH3           CF3CF2
A740         H          CH2＝CHCH2     CH3           CF3CF2
A741         H          CH3SO2N(CH3)   CH3           CF3CF2
A742         H          (CH3)2N        CH3           CF3CF2
A743         H          (CH3)2NSO2     CH3           CF3CF2
A744         H          CH3SCH2        CH3           CF3CF2
A745         H          CH3SOCH2       CH3           CF3CF2
A746         H          CH3SO2CH2      CH3           CF3CF2
A747         H          CH3            CH3           CF3CF2CF2
A748         H          CH3CH2         CH3           CF3CF2CF2
A749         H          环丙基         CH3           CF3CF2CF2
A750         H          (CH3)3C        CH3           CF3CF2CF2
A751         H          (CH3)2CH       CH3           CF3CF2CF2
A752         H          CH3(CH2)2      CH3           CF3CF2CF2
A753         H          CH3OCH2        CH3           CF3CF2CF2
A754         H          CH3O(CH2)2     CH3           CF3CF2CF2
A755         H          Ph             CH3           CF3CF2CF2
A756         H          PhO            CH3           CF3CF2CF2
A757         H          PhS            CH3           CF3CF2CF2
A758         H          PhSO           CH3           CF3CF2CF2
A759         H          PhSO2          CH3           CF3CF2CF2
A760         H          CH3S           CH3           CF3CF2CF2
A761         H          CH3SO          CH3           CF3CF2CF2
A762         H          CF3            CH3           CF3CF2CF2
A763         H          F2CH           CH3           CF3CF2CF2
A764         H          HCC            CH3           CF3CF2CF2
A765         H          CH3CC          CH3           CF2CF2CF2
A766         H          CH2＝CH        CH3           CF3CF2CF2
A767         H          CH2＝CHCH2     CH3           CF2CF2CF2
A768         H          CH3SO2N(CH3)   CH3           CF3CF2CF2
A769         H          (CH3)2N        CH3           CF3CF2CF2
化合物      R79      R80             R81         R82
序号
A770        H        (CH3)2NSO2      CH3         CF3CF2CF2
A771        H        CH3SCH2         CH3         CF3CF2CF2
A772        H        CH3SOCH2        CH3         CF3CF2CF2
A773        H        CH3SO2CH2       CH3         CF3CF2CF2
A774        H        CH3             CH3         CF2Cl
A775        H        CH3CH2          CH3         CF2Cl
A776        H        环丙基          CH3         CF2Cl
A777        H        (CH3)3C         CH3         CF2Cl
A778        H        (CH3)2CH        CH3         CF2Cl
A779        H        CH3(CH2)2       CH3         CF2Cl
A780        H        CH3OCH2         CH3         CF2Cl
A781        H        CH3O(CH2)2      CH3         CF2Cl
A782        H        Ph              CH3         CF2Cl
A783        H        PhO             CH3         CF2Cl
A784        H        PhS             CH3         CF2Cl
A785        H        PhSO            CH3         CF2Cl
A786        H        PhSO2           CH3         CF2Cl
A787        H        CH3S            CH3         CF2Cl
A788        H        CH3SO           CH3         CF2Cl
A789        H        CF3             CH3         CF2Cl
A790        H        F2CH            CH3         CF2Cl
A791        H        HCC             CH3         CF2Cl
A792        H        CH3CC           CH3         CF2Cl
A793        H        CH2＝CH         CH3         CF2Cl
A794        H        CH2＝CHCH2      CH3         CF2Cl
A795        H        CH3SO2N(CH3)    CH3         CF2Cl
A796        H        (CH3)2N         CH3         CF2Cl
A797        H        (CH3)2NSO2      CH3         CF2Cl
A798        H        CH3SCH2         CH3         CF2Cl
A799        H        CH3SOCH2        CH3         CF2Cl
A800        H        CH3SO2CH2       CH3         CF2Cl
A801        H        CH3             CH3         CHF2
化合物      R79       R80         R81        R82
序号
A802        H         CH3CH2      CH3        CHF2
A803        H         环丙基      CH3        CHF2
A804        H         (CH3)3C     CH3        CHF2
A805        H         (CH3)2CH    CH3        CHF2
A806        H         CH3(CH2)2   CH3        CHF2
A807        H         CH3OCH2     CH3        CHF2
A808        H         CH3O(CH2)2  CH3        CHF2
A809        H         Ph          CH3        CHF2
A810        H         PhO         CH3        CHF2
A811        H         PhS         CH3        CHF2
A812        H         PhSO        CH3        CHF2
A813        H         PhSO2       CH3        CHF2
A814        H         CH3S        CH3        CHF2
A815        H         CH3SO       CH3        CHF2
A816        H         CF3         CH3        CHF2
A817        H         F2CH        CH3        CHF2
A818        H         HCC         CH3        CHF2
A819        H         CH3CC       CH3        CHF2
A820        H         CH2＝CH     CH3        CHF2
A821        H         CH2＝CHCH2  CH3        CHF2
A822        H         CH3SO2N(CH3)CH3        CHF2
A823        H         (CH3)2N     CH3        CHF2
A824        H         (CH3)2NSO2  CH3        CHF2
A825        H         CH3SCH2     CH3        CHF2
A826        H         CH3SOCH2    CH3        CHF2
A827        H         CH3SO2CH2   CH3        CHF2
A828        H         CH3         CH3        CCl3
A829        H         CH3CH2      CH3        CCl3
A830        H         环丙基      CH3        CCl3
A831        H         (CH3)3C     CH3        CCl3
A832        H         (CH3)2CH    CH3        CCl3
A833        H         CH3(CH2)2   CH3        CCl3
化合物      R79         R80          R81        R82
序号
A834        H           CH3OCH2      CH3C       Cl3
A835        H           CH3O(CH2)2   CH3        CCl3
A836        H           Ph           CH3        CCl3
A837        H           PhO          CH3        CCl3
A838        H           PhS          CH3        CCl3
A839        H           PhSO         CH3        CCl3
A840        H           PhSO2        CH3        CCl3
A841        H           CH3S         CH3        CCl3
A842        H           CH3SO        CH3        CCl3
A843        H           CF3          CH3        CCl3
A844        H           F2CH         CH3        CCl3
A845        H           HCC          CH3        CCl3
A846        H           CH3CC        CH3        CCl3
A847        H           CH2＝CH      CH3        CCl3
A848        H           CH2＝CHCH2   CH3        CCl3
A849        H           CH3SO2N(CH3) CH3        CCl3
A850        H           (CH3)2N      CH3        CCl3
A851        H           (CH3)2NSO2   CH3        CCl3
A852        H           CH3SCH2      CH3        CCl3
A853        H           CH3SOCH2     CH3        CCl3
A854        H           CH3SO2CH2    CH3        CCl3
A855        H           CH3          Ph         CF3
A856        H           CH3CH2       Ph         CF3
A857        H           (CH3)2CH     Ph         CF3
A858        H           (CH3)2CH     Ph         CF3
A859        H           环丙基       Ph         CF3
A860        H           CH3(CH2)2    Ph         CF3
A861        H           CH3OCH2      Ph         CF3
A862        H           CH3O(CH2)2   Ph         CF3
A863        H           Ph           Ph         CF3
A864        H           PhO          Ph         CF3
A865        H           PhS          Ph         CF3
化合物        R79            R80          R81            R82
序号
A866          H              PhSO         Ph             CF3
A867          H              PhSO2        Ph             CF3
A868          H              CH3S         Ph             CF3
A869          H              CH3SO        Ph             CF3
A870          H              CF3          Ph             CF3
A871          H              F2CH         Ph             CF3
A872          H              HCC          Ph             CF3
A873          H              CH3CC        Ph             CF3
A874          H              CH2＝CH      Ph             CF3
A875          H              CH2＝CHCH2   Ph             CF3
A876          H              CH3SO2N(CH3) Ph             CF3
A877          H              (CH3)2N      Ph             CF3
A878          H              (CH3)2NSO2   Ph             CF3
A879          H              CH3SCH2      Ph             CF3
A880          H              CH3SOCH2     Ph             CF3
A881          H              CH3SO2CH2    Ph             CF3
A882          H              CH3          Ph             CF3CF2
A883          H              CH3CH2       Ph             CF3CF2
A884          H              环丙基       Ph             CF3CF2
A885          H              (CH3)3C      Ph             CF3CF2
A886          H              (CH3)2CH     Ph             CF3CF2
A887          H              CH3(CH2)2    Ph             CF3CF2
A888          H              CH3OCH2      Ph             CF3CF2
A889          H              CH3O(CH2)2   Ph             CF3CF2
A890          H              Ph           Ph             CF3CF2
A891          H              PhO          Ph             CF3CF2
A892          H              PhS          Ph             CF3CF2
A893          H              PhSO         Ph             CF3CF2
A894          H              PhSO2        Ph             CF3CF2
A895          H              CH3S         Ph             CF3CF2
A896          H              CH3SO        Ph             CF3CF2
A897          H              CF3          Ph             CF3CF2
化合物       R79         R80         R81          R82
序号
A898         H           F2CH        Ph           CF3CF2
A899         H           HCC         Ph           CF3CF2
A900         H           CH3CC       Ph           CF3CF2
A901         H           CH2＝CH     Ph           CF3CF2
A902         H           CH2＝CHCH2  Ph           CF3CF2
A903         H           CH3SO2N(CH3)Ph           CF3CF2
A904         H           (CH3)2N     Ph           CF3CF2
A905         H           (CH3)2NSO2  Ph           CF3CF2
A906         H           CH3SCH2     Ph           CF3CF2
A907         H           CH3SOCH2    Ph           CF3CF2
A908         H           CH3SO2CH2   Ph           CF3CF2
A909         H           CH3         Ph           CF3CF2CF2
A910         H           CH3CH2      Ph           CF3CF2CF2
A911         H           环丙基      Ph           CF3CF2CF2
A912         H           (CH3)3C     Ph           CF3CF2CF2
A913         H           (CH3)2CH    Ph           CF3CF2CF2
A914         H           CH3(CH2)2   Ph           CF3CF2CF2
A915         H           CH3OCH2     Ph           CF3CF2CF2
A916         H           CH3O(CH2)2  Ph           CF3CF2CF2
A917         H           Ph          Ph           CF3CF2CF2
A918         H           PhO         Ph           CF3CF2CF2
A919         H           PhS         Ph           CF3CF2CF2
A920         H           PhSO        Ph           CF3CF2CF2
A921         H           PhSO2       Ph           CF3CF2CF2
A922         H           CH3S        Ph           CF3CF2CF2
A923         H           CH3SO       Ph           CF3CF2CF2
A924         H           CF3         Ph           CF3CF2CF2
A925         H           F2CH        Ph           CF3CF2CF2
A926         H           HCC         Ph           CF3CF2CF2
A927         H           CH3CC       Ph           CF3CF2CF2
A928         H           CH2＝CH     Ph           CF3CF2CF2
A929         H           CH2＝CHCH2  Ph           CF3CF2CF2
化合物       R79         R80         R81          R82
序号
A930         H           CH3SO2N(CH3)Ph           CF3CF2CF2
A931         H           (CH3)2N     Ph           CF3CF2CF2
A932         H           (CH3)2NSO2  Ph           CF3CF2CF2
A933         H           CH3SCH2     Ph           CF3CF2CF2
A934         H           CH3SOCH2    Ph           CF3CF2CF2
A935         H           CH3SO2CH2   Ph           CF3CF2CF2
A936         H           CH3         Ph           CF2Cl
A937         H           CH3CH2      Ph           CF2Cl
A938         H           环丙基      Ph           CF2Cl
A939         H           (CH3)3C     Ph           CF2Cl
A940         H           (CH3)2CH    Ph           CF2Cl
A941         H           CH3(CH2)2   Ph           CF2Cl
A942         H           CH3OCH2     Ph           CF2Cl
A943         H           CH3O(CH2)2  Ph           CF2Cl
A944         H           Ph          Ph           CF2Cl
A945         H           PhO         Ph           CF2Cl
A946         H           PhS         Ph           CF2Cl
A947         H           PhSO        Ph           CF2Cl
A948         H           PhSO2       Ph           CF2Cl
A949         H           CH3S        Ph           CF2Cl
A950         H           CH3SO       Ph           CF2Cl
A951         H           CF3         Ph           CF2Cl
A952         H           F2CH        Ph           CF2Cl
A953         H           HCC         Ph           CF2Cl
A954         H           CH3CC       Ph           CF2Cl
A955         H           CH2＝CH     Ph           CF2Cl
A956         H           CH2＝CHCH2  Ph           CF2Cl
A957         H           CH3SO2N(CH3)Ph           CF2Cl
A958         H           (CH3)2N     Ph           CF2Cl
A959         H           (CH3)2NSO2  Ph           CF2Cl
A960         H           CH3SCH2     Ph           CF2Cl
A961         H           CH3SOCH2    Ph           CF2Cl
化合物       R79        R80            R81           R82
序号
A962         H          CH3SO2CH2      Ph            CF2Cl
A963         H          CH3            Ph            CHF2
A964         H          CH3CH2         Ph            CHF2
A965         H          (CH3)3C        Ph            CHF2
A966         H          (CH3)2CH       Ph            CHF2
A967         H          环丙基         Ph            CHF2
A968         H          CH3(CH2)2      Ph            CHF2
A969         H          CH3OCH2        Ph            CHF2
A970         H          CH3O(CH2)2     Ph            CHF2
A971         H          Ph             Ph            CHF2
A972         H          PhO            Ph            CHF2
A973         H          PhS            Ph            CHF2
A974         H          PhSO           Ph            CHF2
A975         H          PhSO2          Ph            CHF2
A976         H          CH3S           Ph            CHF2
A977         H          CH3SO          Ph            CHF2
A978         H          CF3            Ph            CHF2
A979         H          F2CH           Ph            CHF2
A980         H          HCC            Ph            CHF2
A981         H          CH3CC          Ph            CHF2
A982         H          CH2＝CH        Ph            CHF2
A983         H          CH2＝CHCH2     Ph            CHF2
A984         H          CH3SO2N(CH3)   Ph            CHF2
A985         H          (CH3)2N        Ph            CHF2
A986         H          (CH3)2NSO2     Ph            CHF2
A987         H          CH3SCH2        Ph            CHF2
A988         H          CH3SOCH2       Ph            CHF2
A989         H          CH3SO2CH2      Ph            CHF2
A990         H          CH3            Ph            CCl3
A991         H          CH3CH2         Ph            CCl3
A992         H          (CH3)3C        Ph            CCl3
A993         H          (CH3)2CH       Ph            CCl3
化合物       R79          R80         R81          R82
序号
A994         H            环丙基      Ph           CCl3
A995         H            CH3(CH2)2   Ph           CCl3
A996         H            CH3OCH2     Ph           CCl3
A997         H            CH3O(CH2)2  Ph           CCl3
A998         H            Ph          Ph           CCl3
A999         H            PhO         Ph           CCl3
A1000        H            PhS         Ph           CCl3
A1001        H            PhSO        Ph           CCl3
A1002        H            PhSO2       Ph           CCl3
A1003        H            CH3S        Ph           CCl3
A1004        H            CH3SO       Ph           CCl3
A1005        H            CF3         Ph           CCl3
A1006        H            F2CH        Ph           CCl3
A1007        H            HCC         Ph           CCl3
A1008        H            CH3CC       Ph           CCl3
A1009        H            CH2＝CH     Ph           CCl3
A1010        H            CH2＝CHCH2  Ph           CCl3
A1011        H            CH3SO2N(CH3)Ph           CCl3
A1012        H            (CH3)2N     Ph           CCl3
A1013        H            (CH3)2NSO2  Ph           CCl3
A1014        H            CH3SCH2     Ph           CCl3
A1015        H            CH3SOCH2    Ph           CCl3
A1016        H            CH3SO2CH2   Ph           CCl3
A1017        F            H           H            CF3
A1018        Cl           H           H            CF3
A1019        Br           H           H            CF3
A1020        CN           H           H            CF3
A1021        CH3SO2O      H           H            CF3
A1022        CH3O         H           H            CF3
A1023        CH2CH3O      H           H            CF3
A1024        CH2CH＝CH2O  H           H            CF3
A1025        HCCCH2O      H           H            CF3
化合物       R79        R80        R81          R82
序号
A1026        S-苄基     H          H            CF3
A1027        SO2-苄基   H          H            CF3
A1028        ClCH2      H          H            CF3
A1029        BrCH2      H          H            CF3
A1030        FCH2       H          H            CF3
A1031        CHF2CH2    H          H            CF3
A1032        CF3CH2     H          H            CF3
A1033        三唑基甲基 H          H            CF3
A1034        CHCl2CH2   H          H            CF3
A1035        ClCH＝CH   H          H            CF3
A1036        Cl2C＝CH   H          H            CF3
A1037        CF3CH＝CH  H          H            CF3
A1038        ClCC       H          H            CF3
A1039        Ph         H          H            CF3
A1040        CH3        CH3        H            CF3
A1041        CH3        OH         H            CF3
A1042        CH3        F          H            CF3
A1043        CH3        Cl         H            CF3
A1044        F          CH3        H            CF3
A1045        Cl         CH3        H            CF3
A1046        H          F          H            CF3
A1047        H          Cl         H            CF3
A1048        H          Br         H            CF3
A1049        H          OH         H            CF3
A1050        H          OCH3       H            CF3
A1051        H          OCHF2      H            CF3
A1052        H          OSO2CH3    H            CF3
A1053        H          OSO2CF3    H            CF3
A1054        H          ClCH2      H            CF3
A1055        H          BrCH2      H            CF3
A1056        H          FCH2       H            CF3
A1057        H          CHF2CH2    H            CF3
化合物      R79         R80          R81          R82
序号
A1058       H           CF3CH2       H            CF3
A1059       H           三唑基甲基   H            CF3
A1060       H           CHCl2CH2     H            CF3
A1061       H           ClCH＝CH     H            CF3
A1062       H           Cl2C＝CH     H            CF3
A1063       H           CF3CH＝CH    H            CF3
A1064       H           ClCC         H            CF3
A1065       H           CH3C(O)      H            CF3
A1066       H           苯基         H            CF3
A1067       H           SO2CH3       H            CF3
A1068       H           SO2CF3       H            CF3
A1069       H           CN           H            CF3
A1070       H           NO2          H            CF3
A1071       CH3         H            F            CF3
A1072       CH3         H            Cl           CF3
A1073       CH3         H            Br           CF3
A1074       CH3         H            CN           CF3
A1075       CH3         H            CH3O         CF3
A1076       CH3         H            CH3S         CF3
A1077       CH3         H            CH3SO        CF3
A1078       CH3         H            CH3SO2       CF3
在下表6中，Q是Q3
Figure C01804089D01041
且Q3代表下列基团B：
表6：基团B：
基团       R44             R37          R38        R39       R40         W
B1         H               H            H          H         OH          CH2
B2         CH3             H            H          H         OH          CH2
B3         CH3CH2          H            H          H         OH          CH2
B4         CH3CH2CH2       H            H          H         OH          CH2
B5         (CH3)2CH        H            H          H         OH          CH2
B6         (CH3)3C         H            H          H         OH          CH2
B7         CH3S            H            H          H         OH          CH2
B8         CH3SO           H            H          H         OH          CH2
B9         CH3SO2          H            H          H         OH          CH2
B10        Ph              H            H          H         OH          CH2
B11        CH3O            H            H          H         OH          CH2
B12        CH3CO2          H            H          H         OH          CH2
B13        CH3CH2CO2       H            H          H         OH          CH2
B14        CH2＝CHCH2      H            H          H         OH          CH2
B15        HCCCH2          H            H          H         OH          CH2
B16        CF3             H            H          H         OH          CH2
B17        (CH3)2NSO2      H            H          H         OH          CH2
B18        (CH3)2N         H            H          H         OH          CH2
B19        PhO             H            H          H         OH          CH2
B20        PhS             H            H          H         OH          CH2
B21        PhSO            H            H          H         OH          CH2
B22        PhSO2           H            H          H         OH          CH2
B23        CN              H            H          H         OH          CH2
B24        CH3             CH3          H          H         OH          CH2
B25        CH3CH2          CH3          H          H         OH          CH2
B26        CH3CH2CH2       CH3          H          H         OH          CH2
B27        (CH3)2CH        CH3          H          H         OH          CH2
B28        (CH3)3C         CH3          H          H         OH          CH2
B29        CH3S            CH3          H          H         OH          CH2
B30        CH3SO           CH3          H          H         OH          CH2
B31        CH3SO2          CH3          H          H         OH          CH2
B32        Ph              CH3          H          H         OH          CH2
基团     R44             R37       R38       R39        R40          W
B33      CH3O            H3        H         H          OH           CH2
B34      CH3CO2          CH3       H         H          OH           CH2
B35      CH3CH2CO2       CH3       H         H          OH           CH2
B36      CH2＝CHCH2      CH3       H         H          OH           CH2
B37      HCCCH2          CH3       H         H          OH           CH2
B38      CF3             CH3       H         H          OH           CH2
B39      (CH3)2NSO2      CH3       H         H          OH           CH2
B40      (CH3)2N         CH3       H         H          OH           CH2
B41      PhO             CH3       H         H          OH           CH2
B42      PhS             CH3       H         H          OH           CH2
B43      PhSO            CH3       H         H          OH           CH2
B44      PhSO2           CH3       H         H          OH           CH2
B45      CN              CH3       H         H          OH           CH2
B46      CH3             H         CH3       H          OH           CH2
B47      CH3CH2          H         CH3       H          OH           CH2
B48      CH3CH2CH2       H         CH3       H          OH           CH2
B49      (CH3)2CH        H         CH3       H          OH           CH2
B50      (CH3)3C         H         CH3       H          OH           CH2
B51      CH3S            H         CH3       H          OH           CH2
B52      CH3SO           H         CH3       H          OH           CH2
B53      CH3SO2          H         CH3       H          OH           CH2
B54      Ph              H         CH3       H          OH           CH2
B55      CH3O            H         CH3       H          OH           CH2
B56      CH3CO2          H         CH3       H          OH           CH2
B57      CH3CH2CO2       H         CH3       H          OH           CH2
B58      CH2＝CHCH2      H         CH3       H          OH           CH2
B59      HCCCH2          H         CH3       H          OH           CH2
B60      CF3             H         CH3       H          OH           CH2
B61      (CH3)2NSO2      H         CH3       H          OH           CH2
B62      (CH3)2N         H         CH3       H          OH           CH2
B63      PhO             H         CH3       H          OH           CH2
B64      PhS             H         CH3       H          OH           CH2
B65      PhSO            H         CH3       H          OH           CH2
基团       R44           R37         R38        R39          R40       W
B66        PhSO2         H           CH3        H            OH        CH2
B67        CN            H           CH3        H            OH        CH2
B68        CH3           CH3         CH3        H            OH        CH2
B69        CH3CH2        CH3         CH3        H            OH        CH2
B70        CH3CH2CH2     CH3         CH3        H            OH        CH2
B71        (CH3)2CH      CH3         CH3        H            OH        CH2
B72        (CH3)3C       CH3         CH3        H            OH        CH2
B73        CH3S          CH3         CH3        H            OH        CH2
B74        CH3SO         CH3         CH3        H            OH        CH2
B75        CH3SO2        CH3          CH3        H            OH        CH2
B76        Ph            CH3         CH3        H            OH        CH2
B77        CH3O          CH3          CH3        H            OH        CH2
B78        CH3CO2        CH3         CH3        H            OH        CH2
B79        CH3CH2CO2     CH3         CH3        H            OH        CH2
B80        CH2＝CHCH2    CH3         CH3        H            OH        CH2
B81        HCCCH2        CH3         CH3        H            OH        CH2
B82        CF3           CH3         CH3        H            OH        CH2
B83        (CH3)2NSO2    CH3         CH3        H            OH        CH2
B84        (CH3)2N       CH3         CH3        H            OH        CH2
B85        PhO           CH3         CH3        H            OH        CH2
B86        PhS           CH3         CH3        H            OH        CH2
B87        PhSO          CH3         CH3        H            OH        CH2
B88        PhSO2         CH3         CH3        H            OH        CH2
B89        CN            CH3         CH3        H            OH        CH2
B90        CH3           CH3         CH3        CH3          OH        CH2
B91        CH3CH2        CH3         CH3        CH3          OH        CH2
B92        CH3CH2CH2     CH3         CH3        CH3          OH        CH2
B93        (CH3)2CH      CH3         CH3        CH3          OH        CH2
B94        (CH3)3C       CH3         CH3        CH3          OH        CH2
B95        CH3S          CH3         CH3        CH3          OH        CH2
B96        CH3SO         CH3         CH3        CH3          OH        CH2
B97        CH3SO2        CH3         CH3        CH3          OH        CH2
B98        Ph            CH3         CH3        CH3          OH        CH2
基团    R44          R37        R38         R39         R40       W
B99     CH3O         CH3        CH3         CH3         OH        CH2
B100    CH3CO2       CH3        CH3         CH3         OH        CH2
B101    CH3CH2CO2    CH3        CH3         CH3         OH        CH2
B102    CH2＝CHCH2   CH3        CH3         CH3         OH        CH2
B103    HCCCH2       CH3        CH3         CH3         OH        CH2
B104    CF3          CH3        CH3         CH3         OH        CH2
B105    (CH3)2NSO2   CH3        CH3         CH3         OH        CH2
B106    (CH3)2N      CH3        CH3         CH3         OH        CH2
B107    PhO          CH3        CH3         CH3         OH        CH2
B108    PhS          CH3        CH3         CH3         OH        CH2
B109    PhSO         CH3        CH3         CH3         OH        CH2
B110    PhSO2        CH3        CH3         CH3         OH        CH2
B111    CN           CH3        CH3         CH3         OH        CH2
B112    CH3CH2       CH3CH2     H           H           OH        CH2
B113    CH3CH2CH2    CH3CH2     H           H           OH        CH2
B114    (CH3)2CH     CH3CH2     H           H           OH        CH2
B115    (CH3)3C      CH3CH2     H           H           OH        CH2
B116    CH3S         CH3CH2     H           H           OH        CH2
B117    CH3SO        CH3CH2     H           H           OH        CH2
B118    CH3SO2       CH3CH2     H           H           OH        CH2
B119    Ph           CH3CH2     H           H           OH        CH2
B120    CH3O         CH3CH2      H           H           OH        CH2
B121    CH3CO2       CH3CH2     H           H           OH        CH2
B122    CH3CH2CO2    CH3CH2     H           H           OH        CH2
B123    CH2＝CHCH2   CH3CH2     H           H           OH        CH2
B124    HCCCH2       CH3CH2     H           H           OH        CH2
B125    CF3          CH3CH2     H           H           OH        CH2
B126    (CH3)2NSO2   CH3CH2     H           H           OH        CH2
B127    (CH3)2N      CH3CH2     H           H           OH        CH2
B128    PhO          CH3CH2     H           H           OH        CH2
B129    PhS          CH3CH2     H           H           OH        CH2
B130    PhSO         CH3CH2     H           H           OH        CH2
B131    PhSO2        CH3CH2     H           H           OH        CH2
基团     R44          R37           R38           R39       R40        W
B132     CN           CH3CH2        H             H         OH         CH2
B133     H            H             H             H         OH         CHCH3
B134     CH3          H             H             H         OH         CHCH3
B135     CH3CH2       H             H             H         OH         CHCH3
B136     CH3CH2CH2    H             H             H         OH         CHCH3
B137     (CH3)2CH     H             H             H         OH         CHCH3
B138     (CH3)3C      H             H             H         OH         CHCH3
B139     CH3S         H             H             H         OH         CHCH3
B140     CH3SO        H             H             H         OH         CHCH3
B141     CH3SO2       H             H             H         OH         CHCH3
B142     Ph           H             H             H         OH         CHCH3
B143     CH3O         H             H             H         OH         CHCH3
B144     CH3CO2       H             H             H         OH         CHCH3
B145     CH3CH2CO2    H             H             H         OH         CHCH3
B146     CH2＝CHCH2   H             H             H         OH         CHCH3
B147     HCCCH2       H             H             H         OH         CHCH3
B148     CF3          H             H             H         OH         CHCH3
B149     (CH3)2NSO2   H             H             H         OH         CHCH3
B150     (CH3)2N      H             H             H         OH         CHCH3
B151     PhO          H             H             H         OH         CHCH3
B152     PhS          H             H             H         OH         CHCH3
B153     PhSO         H             H             H         OH         CHCH3
B154     PhSO2        H             H             H         OH         CHCH3
B155     CN           H             H             H         OH         CHCH3
B156     CH3          CH3           H             H         OH         CHCH3
B157     CH3CH2       CH3           H             H         OH         CHCH3
B158     CH3CH2CH2    CH3           H             H         OH         CHCH3
B159     (CH3)2CH     CH3           H             H         OH         CHCH3
B160     (CH3)3C      CH3           H             H         OH         CHCH3
B161     CH3S         CH3           H             H         OH         CHCH3
B162     CH3SO        CH3           H             H         OH         CHCH3
B163     CH3SO2       CH3           H             H         OH         CHCH3
B164     Ph           CH3           H             H         OH         CHCH3
基团      R44          R37        R38        R39      R40       W
B165      CH3O         CH3        H          H        OH        CHCH3
B166      CH3CO2       CH3        H          H        OH        CHCH3
B167      CH3CH2CO2    CH3        H          H        OH        CHCH3
B168      CH2＝CHCH2   CH3        H          H        OH        CHCH3
B169      HCCCH2       CH3        H          H        OH        CHCH3
B170      CF3          CH3        H          H        OH        CHCH3
B171      (CH3)2NSO2   CH3        H          H        OH        CHCH3
B172      (CH3)2N      CH3        H          H        OH        CHCH3
B173      PhO          CH3        H          H        OH        CHCH3
B174      PhS          CH3        H          H        OH        CHCH3
B175      PhSO         CH3        H          H        OH        CHCH3
B176      PhSO2        CH3        H          H        OH        CHCH3
B177      CN           CH3        H          H        OH        CHCH3
B178      CH3          H          CH3        H        OH        CHCH3
B179      CH3CH2       H          CH3        H        OH        CHCH3
B180      CH3CH2CH2    H          CH3        H        OH        CHCH3
B181      (CH3)2CH     H          CH3        H        OH        CHCH3
B182      (CH3)3C      H          CH3        H        OH        CHCH3
B183      CH3S         H          CH3        H        OH        CHCH3
B184      CH3SO        H          CH3        H        OH        CHCH3
B185      CH3SO2       H          CH3        H        OH        CHCH3
B186      Ph           H          CH3        H        OH        CHCH3
B187      CH3O         H          CH3        H        OH        CHCH3
B188      CH3CO2       H          CH3        H        OH        CHCH3
B189      CH3CH2CO2    H          CH3        H        OH        CHCH3
B190      CH2＝CHCH2   H          CH3        H        OH        CHCH3
B191      HCCCH2       H          CH3        H        OH        CHCH3
B192      CF3          H          CH3        H        OH        CHCH3
B193      (CH3)2NSO2   H          CH3        H        OH        CHCH3
B194      (CH3)2N      H          CH3        H        OH        CHCH3
B195      PhO          H          CH3        H        OH        CHCH3
B196      PhS          H          CH3        H        OH        CHCH3
B197      PhSO         H          CH3        H        OH        CHCH3
基团      R44            R37       R38       R39       R40        W
B198      PhSO2          H         CH3       H         OH         CHCH3
B199      CN             H         CH3       H         OH         CHCH3
B200      CH3            CH3       CH3       H         OH         CHCH3
B201      CH3CH2         CH3       CH3       H         OH         CHCH3
B202      CH3CH2CH2      CH3       CH3       H         OH         CHCH3
B203      (CH3)2CH       CH3       CH3       H         OH         CHCH3
B204      (CH3)3C        CH3       CH3       H         OH         CHCH3
B205      CH3S           CH3       CH3       H         OH         CHCH3
B206      CH3SO          CH3       CH3       H         OH         CHCH3
B207      CH3SO2         CH3       CH3       H         OH         CHCH3
B208      Ph             CH3       CH3       H         OH         CHCH3
B209      CH3O           CH3       CH3       H         OH         CHCH3
B210      CH3CO2         CH3       CH3       H         OH         CHCH3
B211      CH3CH2CO2      CH3       CH3       H         OH         CHCH3
B212      CH2＝CHCH2     CH3       CH3       H         OH         CHCH3
B213      HCCCH2         CH3       CH3       H         OH         CHCH3
B214      CF3            CH3       CH3       H         OH         CHCH3
B215      (CH3)2NSO2     CH3       CH3       H         OH         CHCH3
B216      (CH3)2N        CH3       CH3       H         OH         CHCH3
B217      PhO            CH3       CH3       H         OH         CHCH3
B218      PhS            CH3       CH3       H         OH         CHCH3
B219      PhSO           CH3       CH3       H         OH         CHCH3
B220      PhSO2          CH3       CH3       H         OH         CHCH3
B221      CN             CH3       CH3       H         OH         CHCH3
B222      CH3            CH3       CH3       CH3       OH         CHCH3
B223      CH3CH2         CH3       CH3       CH3       OH         CHCH3
B224      CH3CH2CH2      CH3       CH3       CH3       OH         CHCH3
B225      (CH3)2CH       CH3       CH3       CH3       OH         CHCH3
B226      (CH3)3C        CH3       CH3       CH3       OH         CHCH3
B227      CH3S           CH3       CH3       CH3       OH         CHCH3
B228      CH3SO          CH3       CH3       CH3       OH         CHCH3
B229      CH3SO2         CH3       CH3       CH3       OH         CHCH3
B230      Ph             CH3       CH3       CH3       OH         CHCH3
基团       R44            R37          R38           R39          R40       W
B231       CH3O           CH3          CH3           CH3          OH        CHCH3
B232       CH3CO2         CH3          CH3           CH3          OH        CHCH3
B233       CH3CH2CO2      CH3          CH3           CH3          OH        CHCH3
B234       CH2＝CHCH2     CH3          CH3           CH3          OH        CHCH3
B235       HCCCH2         CH3          CH3           CH3          OH        CHCH3
B236       CF3            CH3          CH3           CH3          OH        CHCH3
B237       (CH3)2NSO2     CH3          CH3           CH3          OH        CHCH3
B238       (CH3)2N        CH3          CH3           CH3          OH        CHCH3
B239       PhO            CH3          CH3           CH3          OH        CHCH3
B240       PhS            CH3          CH3           CH3          OH        CHCH3
B241       PhSO           CH3          CH3           CH3          OH        CHCH3
B242       PhSO2          CH3          CH3           CH3          OH        CHCH3
B243       CN             CH3          CH3           CH3          OH        CHCH3
B244       CH3CH2         CH3CH2       H             H            OH        CHCH3
B245       CH3CH2CH2      CH3CH2       H             H            OH        CHCH3
B246       (CH3)2CH       CH3CH2       H             H            OH        CHCH3
B247       (CH3)3C        CH3CH2       H             H            OH        CHCH3
B248       CH3S           CH3CH2       H             H            OH        CHCH3
B249       CH3SO          CH3CH2       H             H            OH        CHCH3
B250       CH3SO2         CH3CH2       H             H            OH        CHCH3
B251       Ph             CH3CH2       H             H            OH        CHCH3
B252       CH3O           CH3CH2       H             H            OH        CHCH3
B253       CH3CO2         CH3CH2       H             H            OH        CHCH3
B254       CH3CH2CO2      CH3CH2       H             H            OH        CHCH3
B255       CH2＝CHCH2     CH3CH2       H             H            OH        CHCH3
B256       HCCCH2         CH3CH2       H             H            OH        CHCH3
B257       CF3            CH3CH2       H             H            OH        CHCH3
B258       (CH3)2NSO2     CH3CH2       H             H            OH        CHCH3
B259       (CH3)2N        CH3CH2       H             H            OH        CHCH3
B260       PhO            CH3CH2       H             H            OH        CHCH3
B261       PhS            CH3CH2       H             H            OH        CHCH3
B262       PhSO           CH3CH2       H             H            OH        CHCH3
B263       PhSO2          CH3CH2       H             H            OH        CHCH3
基团     R44          R37         R38         R39          R40         W
B264     CN           CH3CH2      H           H            OH          CHCH3
B265     H            H           H           H            OH          C＝O
B266     CH3          H           H           H            OH          C＝O
B267     CH3CH2       H           H           H            OH          C＝O
B268     CH3CH2CH2    H           H           H            OH          C＝O
B269     (CH3)2CH     H           H           H            OH          C＝O
B270     (CH3)3C      H           H           H            OH          C＝O
B271     CH3S         H           H           H            OH          C＝O
B272     CH3SO        H           H           H            OH          C＝O
B273     CH3SO2       H           H           H            OH          C＝O
B274     Ph           H           H           H            OH          C＝O
B275     CH3O         H           H           H            OH          C＝O
B276     CH3CO2       H           H           H            OH          C＝O
B277     CH3CH2CO2    H           H           H            OH          C＝O
B278     CH2＝CHCH2   H           H           H            OH          C＝O
B279     HCCCH2       H           H           H            OH          C＝O
B280     CF3          H           H           H            OH          C＝O
B281     (CH3)2NSO2   H           H           H            OH          C＝O
B282     (CH3)2N      H           H           H            OH          C＝O
B283     PhO          H           H           H            OH          C＝O
B284     PhS          H           H           H            OH          C＝O
B285     PhSO         H           H           H            OH          C＝O
B286     PhSO2        H           H           H            OH          C＝O
B287     CN           H           H           H            OH          C＝O
B288     CH3          CH3         H           H            OH          C＝O
B289     CH3CH2       CH3         H           H            OH          C＝O
B290     CH3CH2CH2    CH3         H           H            OH          C＝O
B291     (CH3)2CH     CH3         H           H            OH          C＝O
B292     (CH3)3C      CH3         H           H            OH          C＝O
B293     CH3S         CH3         H           H            OH          C＝O
B294     CH3SO        CH3         H           H            OH          C＝O
B295     CH3SO2       CH3         H           H            OH          C＝O
B296     Ph           CH3         H           H            OH          C＝O
基团       R44           R37         R38           R39          R40          W
B297       CH3O          CH3         H             H            OH           C＝O
B298       CH3CO2        CH3         H             H            OH           C＝O
B299       CH3CH2CO2     CH3         H             H            OH           C＝O
B300       CH2＝CHCH2    CH3         H             H            OH           C＝O
B301       HCCCH2        CH3         H             H            OH           C＝O
B302       CF3           CH3         H             H            OH           C＝O
B303       (CH3)2NSO2    CH3         H             H            OH           C＝O
B304       (CH3)2N       CH3         H             H            OH           C＝O
B305       PhO           CH3         H             H            OH           C＝O
B306       PhS           CH3         H             H            OH           C＝O
B307       PhSO          CH3         H             H            OH           C＝O
B308       PhSO2         CH3         H             H            OH           C＝O
B309       CN            CH3         H             H            OH           C＝O
B310       CH3           H           CH3           H            OH           C＝O
B311       CH3CH2        H           CH3           H            OH           C＝O
B312       CH3CH2CH2     H           CH3           H            OH           C＝O
B313       (CH3)2CH      H           CH3           H            OH           C＝O
B314       (CH3)3C       H           CH3           H            OH           C＝O
B315       CH3S          H           CH3           H            OH           C＝O
B316       CH3SO         H           CH3           H            OH           C＝O
B317       CH3SO2        H           CH3           H            OH           C＝O
B318       Ph            H           CH3           H            OH           C＝O
B319       CH3O          H           CH3           H            OH           C＝O
B320       CH3CO2        H           CH3           H            OH           C＝O
B321       CH3CH2CO2     H           CH3           H            OH           C＝O
B322       CH2＝CHCH2    H           CH3           H            OH           C＝O
B323       HCCCH2        H           CH3           H            OH           C＝O
B324       CF3           H           CH3           H            OH           C＝O
B325       (CH3)2NSO2    H           CH3           H            OH           C＝O
B326       (CH3)2N       H           CH3           H            OH           C＝O
B327       PhO           H           CH3           H            OH           C＝O
B328       PhS           H           CH3           H            OH           C＝O
B329       PhSO          H           CH3           H            OH           C＝O
基团        R44           R37          R38          R39       R40         W
B330        PhSO2         H            CH3          H         OH          C＝O
B331        CN            H            CH3          H         OH          C＝O
B332        CH3           CH3          CH3          H         OH          C＝O
B333        CH3CH2        CH3          CH3          H         OH          C＝O
B334        CH3CH2CH2     CH3          CH3          H         OH          C＝O
B335        (CH3)2CH      CH3          CH3          H         OH          C＝O
B336        (CH3)3C       CH3          CH3          H         OH          C＝O
B337        CH3S          CH3          CH3          H         OH          C＝O
B338        CH3SO         CH3          CH3          H         OH          C＝O
B339        CH3SO2        CH3          CH3          H         OH          C＝O
B340        Ph            CH3          CH3          H         OH          C＝O
B341        CH3O          CH3          CH3          H         OH          C＝O
B342        CH3CO2        CH3          CH3          H         OH          C＝O
B343        CH3CH2CO2     CH3          CH3          H         OH          C＝O
B344        CH2＝CHCH2    CH3          CH3          H         OH          C＝O
B345        HCCCH2        CH3          CH3          H         OH          C＝O
B346        CF3           CH3          CH3          H         OH          C＝O
B347        (CH3)2NSO2    CH3          CH3          H         OH          C＝O
B348        (CH3)2N       CH3          CH3          H         OH          C＝O
B349        PhO           CH3          CH3          H         OH          C＝O
B350        PhS           CH3          CH3          H         OH          C＝O
B351        PhSO          CH3          CH3          H         OH          C＝O
B352        PhSO2         CH3          CH3          H         OH          C＝O
B353        CN            CH3          CH3          H         OH          C＝O
B354        CH3           CH3          CH3          CH3       OH          C＝O
B355        CH3CH2        CH3          CH3          CH3       OH          C＝O
B356        CH3CH2CH2     CH3          CH3          CH3       OH          C＝O
B357        (CH3)2CH      CH3          CH3          CH3       OH          C＝O
B358        (CH3)3C       CH3          CH3          CH3       OH          C＝O
B359        CH3S          CH3          CH3          CH3       OH          C＝O
B360        CH3SO         CH3          CH3          CH3       OH          C＝O
B361        CH3SO2        CH3          CH3          CH3       OH          C＝O
B362        Ph            CH3          CH3          CH3       OH          C＝O
基团     R44          R37        R38        R39        R40        W
B363     CH3O         CH3        CH3        CH3        OH         C＝O
B364     CH3CO2       CH3        CH3        CH3        OH         C＝O
B365     CH3CH2CO2    CH3        CH3        CH3        OH         C＝O
B366     CH2＝CHCH2   CH3        CH3        CH3        OH         C＝O
B367     HCCCH2       CH3        CH3        CH3        OH         C＝O
B368     CF3          CH3        CH3        CH3        OH         C＝O
B369     (CH3)2NSO2   CH3        CH3        CH3        OH         C＝O
B370     (CH3)2N      CH3        CH3        CH3        OH         C＝O
B371     PhO          CH3        CH3        CH3        OH         C＝O
B372     PhS          CH3        CH3        CH3        OH         C＝O
B373     PhSO         CH3        CH3        CH3        OH         C＝O
B374     PhSO2        CH3        CH3        CH3        OH         C＝O
B375     CN           CH3        CH3        CH3        OH         C＝O
B376     CH3CH2       CH3CH2     H          H          OH         C＝O
B377     CH3CH2CH2    CH3CH2     H          H          OH         C＝O
B378     (CH3)2CH     CH3CH2     H          H          OH         C＝O
B379     (CH3)3C      CH3CH2     H          H          OH         C＝O
B380     CH3S         CH3CH2     H          H          OH         C＝O
B381     CH3SO        CH3CH2     H          H          OH         C＝O
B382     CH3SO2       CH3CH2     H          H          OH         C＝O
B383     Ph           CH3CH2     H          H          OH         C＝O
B384     CH3O         CH3CH2     H          H          OH         C＝O
B385     CH3CO2       CH3CH2     H          H          OH         C＝O
B386     CH3CH2CO2    CH3CH2     H          H          OH         C＝O
B387     CH2＝CHCH2   CH3CH2     H          H          OH         C＝O
B388     HCCCH2       CH3CH2     H          H          OH         C＝O
B389     CF3          CH3CH2     H          H          OH         C＝O
B390     (CH3)2NSO2   CH3CH2     H          H          OH         C＝O
B391     (CH3)2N      CH3CH2     H          H          OH         C＝O
B392     PhO          CH3CH2     H          H          OH         C＝O
B393     PhS          CH3CH2     H          H          OH         C＝O
B394     PhSO         CH3CH2     H          H          OH         C＝O
B395     PhSO2        CH3CH2     H          H          OH         C＝O
基团     R44        R37        R38        R39        R40        W
B396     CN         CH3CH2     H          H          OH         C＝O
B397     H          H          H          H          OH         N-CH3
B398     CH3        H          H          H          OH         N-CH3
B399     CH3CH2     H          H          H          OH         N-CH3
B400     CH3CH2CH2  H          H          H          OH         N-CH3
B401     (CH3)2CH   H          H          H          OH         N-CH3
B402     (CH3)3C    H          H          H          OH         N-CH3
B403     CH3S       H          H          H          OH         N-CH3
B404     CH3SO      H          H          H          OH         N-CH3
B405     CH3SO2     H          H          H          OH         N-CH3
B406     Ph         H          H          H          OH         N-CH3
B407     CH3O       H          H          H          OH         N-CH3
B408     CH3CO2     H          H          H          OH         N-CH3
B409     CH3CH2CO2  H          H          H          OH         N-CH3
B410     CH2＝CHCH2 H          H          H          OH         N-CH3
B411     HCCCH2     H          H          H          OH         N-CH3
B412     CF3        H          H          H          OH         N-CH3
B413     (CH3)2NSO2 H          H          H          OH         N-CH3
B414     (CH3)2N    H          H          H          OH         N-CH3
B415     PhO        H          H          H          OH         N-CH3
B416     PhS        H          H          H          OH         N-CH3
B417     PhSO       H          H          H          OH         N-CH3
B418     PhSO2      H          H          H          OH         N-CH3
B419     CN         H          H          H          OH         N-CH3
B420     CH3        CH3        H          H          OH         N-CH3
B421     CH3CH2     CH3        H          H          OH         N-CH3
B422     CH3CH2CH2  CH3        H          H          OH         N-CH3
B423     (CH3)2CH   CH3        H          H          OH         N-CH3
B424     (CH3)3C    CH3        H          H          OH         N-CH3
B425     CH3S       CH3        H          H          OH         N-CH3
B426     CH3SO      CH3        H          H          OH         N-CH3
B427     CH3SO2     CH3        H          H          OH         N-CH3
B428     Ph         CH3        H          H          OH         N-CH3
基团     R44        R37         R38        R39        R40       W
B429     CH3O       CH3         H          H          OH        N-CH3
B430     CH3CO2     CH3         H          H          OH        N-CH3
B431     CH3CH2CO2  CH3         H          H          OH        N-CH3
B432     CH2＝CHCH2 CH3         H          H          OH        N-CH3
B433     HCCCH2     CH3         H          H          OH        N-CH3
B434     CF3        CH3         H          H          OH        N-CH3
B435     (CH3)2NSO2 CH3         H          H          OH        N-CH3
B436     (CH3)2N    CH3         H          H          OH        N-CH3
B437     PhO        CH3         H          H          OH        N-CH3
B438     PhS        CH3         H          H          OH        N-CH3
B439     PhSO       CH3         H          H          OH        N-CH3
B440     PhSO2      CH3         H          H          OH        N-CH3
B441     CN         CH3         H          H          OH        N-CH3
B442     CH3        H           CH3        H          OH        N-CH3
B443     CH3CH2     H           CH3        H          OH        N-CH3
B444     CH3CH2CH2  H           CH3        H          OH        N-CH3
B445     (CH3)2CH   H           CH3        H          OH        N-CH3
B446     (CH3)3C    H           CH3        H          OH        N-CH3
B447     CH3S       H           CH3        H          OH        N-CH3
B448     CH3SO      H           CH3        H          OH        N-CH3
B449     CH3SO2     H           CH3        H          OH        N-CH3
B450     Ph         H           CH3        H          OH        N-CH3
B451     CH3O       H           CH3        H          OH        N-CH3
B452     CH3CO2     H           CH3        H          OH        N-CH3
B453     CH3CH2CO2  H           CH3        H          OH        N-CH3
B454     CH2＝CHCH2 H           CH3        H          OH        N-CH3
B455     HCCCH2     H           CH3        H          OH        N-CH3
B456     CF3        H           CH3        H          OH        N-CH3
B457     (CH3)2NSO2 H           CH3        H          OH        N-CH3
B458     (CH3)2N    H           CH3        H          OH        N-CH3
B459     PhO        H           CH3        H          OH        N-CH3
B460     PhS        H           CH3        H          OH        N-CH3
B461     PhSO       H           CH3        H          OH        N-CH3
基团     R44        R37          R38         R39         R40        W
B462     PhSO2      H            CH3         H           OH         N-CH3
B463     CN         H            CH3         H           OH         N-CH3
B464     CH3        CH3          CH3         H           OH         N-CH3
B465     CH3CH2     CH3          CH3         H           OH         N-CH3
B466     CH3CH2CH2  CH3          CH3         H           OH         N-CH3
B467     (CH3)2CH   CH3          CH3         H           OH         N-CH3
B468     (CH3)3C    CH3          CH3         H           OH         N-CH3
B469     CH3S       CH3          CH3         H           OH         N-CH3
B470     CH3SO      CH3          CH3         H           OH         N-CH3
B471     CH3SO2     CH3          CH3          H           OH         N-CH3
B472     Ph         CH3          CH3         H           OH         N-CH3
B473     CH3O       CH3          CH3         H           OH         N-CH3
B474     CH3CO2     CH3          CH3         H           OH         N-CH3
B475     CH3CH2CO2  CH3          CH3         H           OH         N-CH3
B476     CH2＝CHCH2 CH3          CH3         H           OH         N-CH3
B477     HCCCH2     CH3          CH3         H           OH         N-CH3
B478     CF3        CH3          CH3         H           OH         N-CH3
B479     (CH3)2NSO2 CH3          CH3         H           OH         N-CH3
B480     (CH3)2N    CH3          CH3         H           OH         N-CH3
B481     PhO        CH3          CH3         H           OH         N-CH3
B482     PhS        CH3          CH3         H           OH         N-CH3
B483     PhSO       CH3          CH3         H           OH         N-CH3
B484     PhSO2      CH3          CH3         H           OH         N-CH3
B485     CN         CH3          CH3         H           OH         N-CH3
B486     CH3        CH3          CH3         CH3         OH         N-CH3
B487     CH3CH2     CH3          CH3         CH3         OH         N-CH3
B488     CH3CH2CH2  CH3          CH3         CH3         OH         N-CH3
B489     (CH3)2CH   CH3          CH3         CH3         OH         N-CH3
B490     (CH3)3C    CH3          CH3         CH3         OH         N-CH3
B491     CH3S       CH3          CH3         CH3         OH         N-CH3
B492     CH3SO      CH3          CH3         CH3         OH         N-CH3
B493     CH3SO2     CH3          CH3         CH3         OH         N-CH3
B494     Ph         CH3          CH3         CH3         OH         N-CH3
基团      R44             R37       R38       R39       R40      W
B495      CH3O            CH3       CH3       CH3       OH       N-CH3
B496      CH3CO2          CH3       CH3       CH3       OH       N-CH3
B497      CH3CH2CO2       CH3       CH3       CH3       OH       N-CH3
B498      CH2＝CHCH2      CH3       CH3       CH3       OH       N-CH3
B499      HCCCH2          CH3       CH3       CH3       OH       N-CH3
B500      CF3             CH3       CH3       CH3       OH       N-CH3
B501      (CH3)2NSO2      CH3       CH3       CH3       OH       N-CH3
B502      (CH3)2N         CH3       CH3       CH3       OH       N-CH3
B503      PhO             CH3       CH3       CH3       OH       N-CH3
B504      PhS             CH3       CH3       CH3       OH       N-CH3
B505      PhSO            CH3       CH3       CH3       OH       N-CH3
B506      PhSO2           CH3       CH3       CH3       OH       N-CH3
B507      CN              CH3       CH3       CH3       OH       N-CH3
B508      CH3CH2          CH3CH2    H         H         OH       N-CH3
B509      CH3CH2CH2       CH3CH2    H         H         OH       N-CH3
B510      (CH3)2CH        CH3CH2    H         H         OH       N-CH3
B511      (CH3)3C         CH3CH2    H         H         OH       N-CH3
B512      CH3S            CH3CH2    H         H         OH       N-CH3
B513      CH3SO           CH3CH2    H         H         OH       N-CH3
B514      CH3SO2          CH3CH2    H         H         OH       N-CH3
B515      Ph              CH3CH2    H         H         OH       N-CH3
B516      CH3O            CH3CH2    H         H         OH       N-CH3
B517      CH3CO2          CH3CH2    H         H         OH       N-CH3
B518      CH3CH2CO2       CH3CH2    H         H         OH       N-CH3
B519      CH2＝CHCH2      CH3CH2    H         H         OH       N-CH3
B520      HCCCH2          CH3CH2    H         H         OH       N-CH3
B521      CF3             CH3CH2    H         H         OH       N-CH3
B522      (CH3)2NSO2      CH3CH2    H         H         OH       N-CH3
B523      (CH3)2N         CH3CH2    H         H         OH       N-CH3
B524      PhO             CH3CH2    H         H         OH       N-CH3
B525      PhS             CH3CH2    H         H         OH       N-CH3
B526      PhSO            CH3CH2    H         H         OH       N-CH3
B527      PhSO2           CH3CH2    H         H         OH       N-CH3
基团      R44              R37          R38         R39         R40       W
B528      CN               CH3CH2       H           H           OH        N-CH3
B529      H                H            H           H           OH        O
B530      CH3              H            H           H           OH        O
B531      CH3CH2           H            H           H           OH        O
B532      CH3CH2CH2        H            H           H           OH        O
B533      (CH3)2CH         H            H           H           OH        O
B534      (CH3)3C          H            H           H           OH        O
B535      CH3S             H            H           H           OH        O
B536      CH3SO            H            H           H           OH        O
B537      CH3SO2           H            H           H           OH        O
B538      Ph               H            H           H           OH        O
B539      CH3O             H            H           H           OH        O
B540      CH3CO2           H            H           H           OH        O
B541      CH3CH2CO2        H            H           H           OH        O
B542      CH2＝CHCH2       H            H           H           OH        O
B543      HCCCH2           H            H           H           OH        O
B544      CF3              H            H           H           OH        O
B545      (CH3)2NSO2       H            H           H           OH        O
B546      (CH3)2N          H            H           H           OH        O
B547      PhO              H            H           H           OH        O
B548      PhS              H            H           H           OH        O
B549      PhSO             H            H           H           OH        O
B550      PhSO2            H            H           H           OH        O
B551      CN               H            H           H           OH        O
B552      CH3              CH3          H           H           OH        O
B553      CH3CH2           CH3          H           H           OH        O
B554      CH3CH2CH2        CH3          H           H           OH        O
B555      (CH3)2CH         CH3          H           H           OH        O
B556      (CH3)3C          CH3          H           H           OH        O
B557      CH3S             CH3          H           H           OH        O
B558      CH3SO            CH3          H           H           OH        O
B559      CH3SO2           CH3          H           H           OH        O
B560      Ph               CH3          H           H           OH        O
基团        R44         R37         R38         R39         R40        W
B561        CH3O        CH3         H           H           OH         O
B562        CH3CO2      CH3         H           H           OH         O
B563        CH3CH2CO2   CH3         H           H           OH         O
B564        CH2＝CHCH2  CH3         H           H           OH         O
B565        HCCCH2      CH3         H           H           OH         O
B566        CF3         CH3         H           H           OH         O
B567        (CH3)2NSO2  CH3         H           H           OH         O
B568        (CH3)2N     CH3         H           H           OH         O
B569        PhO         CH3         H           H           OH         O
B570        PhS         CH3         H           H           OH         O
B571        PhSO        CH3         H           H           OH         O
B572        PhSO2       CH3         H           H           OH         O
B573        CN          CH3         H           H           OH         O
B574        CH3         H           CH3         H           OH         O
B575        CH3CH2      H           CH3         H           OH         O
B576        CH3CH2CH2   H           CH3         H           OH         O
B577        (CH3)2CH    H           CH3         H           OH         O
B578        (CH3)3C     H           CH3         H           OH         O
B579        CH3S        H           CH3         H           OH         O
B580        CH3SO       H           CH3         H           OH         O
B581        CH3SO2      H           CH3         H           OH         O
B582        Ph          H           CH3         H           OH         O
B583        CH3O        H           CH3         H           OH         O
B584        CH3CO2      H           CH3         H           OH         O
B585        CH3CH2CO2   H           CH3         H           OH         O
B586        CH2＝CHCH2  H           CH3         H           OH         O
B587        HCCCH2      H           CH3         H           OH         O
B588        CF3         H           CH3         H           OH         O
B589        (CH3)2NSO2  H           CH3         H           OH         O
B590        (CH3)2N     H           CH3         H           OH         O
B591        PhO         H           CH3         H           OH         O
B592        PhS         H           CH3         H           OH         O
B593        PhSO        H           CH3         H           OH         O
基团       R44           R37        R38         R39         R40        W
B594       PhSO2         H          CH3         H           OH         O
B595       CN            H          CH3         H           OH         O
B596       CH3           CH3        CH3         H           OH         O
B597       CH3CH2        CH3        CH3         H           OH         O
B598       CH3CH2CH2     CH3        CH3         H           OH         O
B599       (CH3)2CH      CH3        CH3         H           OH         O
B600       (CH3)3C       CH3        CH3         H           OH         O
B601       CH3S          CH3        CH3         H           OH         O
B602       CH3SO         CH3        CH3         H           OH         O
B603       CH3SO2        CH3        CH3         H           OH         O
B604       Ph            CH3        CH3         H           OH         O
B605       CH3O          CH3        CH3         H           OH         O
B606       CH3CO2        CH3        CH3         H           OH         O
B607       CH3CH2CO2     CH3        CH3         H           OH         O
B608       CH2＝CHCH2    CH3        CH3         H           OH         O
B609       HCCCH2        CH3        CH3         H           OH         O
B610       CF3           CH3        CH3         H           OH         O
B611       (CH3)2NSO2    CH3        CH3         H           OH         O
B612       (CH3)2N       CH3        CH3         H           OH         O
B613       PhO           CH3        CH3         H           OH         O
B614       PhS           CH3        CH3         H           OH         O
B615       PhSO          CH3        CH3         H           OH         O
B616       PhSO2         CH3        CH3         H           OH         O
B617       CN            CH3        CH3         H           OH         O
B618       CH3           CH3        CH3         CH3         OH         O
B619       CH3CH2        CH3        CH3         CH3         OH         O
B620       CH3CH2CH2     CH3        CH3         CH3         OH         O
B621       (CH3)2CH      CH3        CH3         CH3         OH         O
B622       (CH3)3C       CH3        CH3         CH3         OH         O
B623       CH3S          CH3        CH3         CH3         OH         O
B624       CH3SO         CH3        CH3         CH3         OH         O
B625       CH3SO2        CH3        CH3         CH3         OH         O
B626       Ph            CH3        CH3         CH3         OH         O
基团      R44           R37        R38       R39       R40         W
B627      CH3O          CH3        CH3       CH3       OH          O
B628      CH3CO2        CH3        CH3       CH3       OH          O
B629      CH3CH2CO2     CH3        CH3       CH3       OH          O
B630      CH2＝CHCH2    CH3        CH3       CH3       OH          O
B631      HCCCH2        CH3        CH3       CH3       OH          O
B632      CF3           CH3        CH3       CH3       OH          O
B633      (CH3)2NSO2    CH3        CH3       CH3       OH          O
B634      (CH3)2N       CH3        CH3       CH3       OH          O
B635      PhO           CH3        CH3       CH3       OH          O
B636      PhS           CH3        CH3       CH3       OH          O
B637      PhSO          CH3        CH3       CH3       OH          O
B638      PhSO2         CH3        CH3       CH3       OH          O
B639      CN            CH3        CH3       CH3       OH          O
B640      CH3CH2        CH3CH2     H         H         OH          O
B641      CH3CH2CH2     CH3CH2     H         H         OH          O
B642      (CH3)2CH      CH3CH2     H         H         OH          O
B643      (CH3)3C       CH3CH2     H         H         OH          O
B644      CH3S          CH3CH2     H         H         OH          O
B645      CH3SO         CH3CH2     H         H         OH          O
B646      CH3SO2        CH3CH2     H         H         OH          O
B647      Ph            CH3CH2     H         H         OH          O
B648      CH3O          CH3CH2     H         H         OH          O
B649      CH3CO2        CH3CH2     H         H         OH          O
B650      CH3CH2CO2     CH3CH2     H         H         OH          O
B651      CH2＝CHCH2    CH3CH2     H         H         OH          O
B652      HCCCH2        CH3CH2     H         H         OH          O
B653      CF3           CH3CH2     H         H         OH          O
B654      (CH3)2NSO2    CH3CH2     H         H         OH          O
B655      (CH3)2N       CH3CH2     H         H         OH          O
B656      PhO           CH3CH2     H         H         OH          O
B657      PhS           CH3CH2     H         H         OH          O
B658      PhSO          CH3CH2     H         H         OH          O
B659      PhSO2         CH3CH2     H         H         OH          O
基团        R44         R37         R38         R39        R40        W
B660        CN          CH3CH2      H           H          OH         O
B661        H           H           H           H          OH         S
B662        CH3         H           H           H          OH         S
B663        CH3CH2      H           H           H          OH         S
B664        CH3CH2CH2   H           H           H          OH         S
B665        (CH3)2CH    H           H           H          OH         S
B666        (CH3)3C     H           H           H          OH         S
B667        CH3S        H           H           H          OH         S
B668        CH3SO       H           H           H          OH         S
B669        CH3SO2      H           H           H          OH         S
B670        Ph          H           H           H          OH         S
B671        CH3O        H           H           H          OH         S
B672        CH3CO2      H           H           H          OH         S
B673        CH3CH2CO2   H           H           H          OH         S
B674        CH2＝CHCH2  H           H           H          OH         S
B675        HCCCH2      H           H           H          OH         S
B676        CF3         H           H           H          OH         S
B677        (CH3)2NSO2  H           H           H          OH         S
B678        (CH3)2N     H           H           H          OH         S
B679        PhO         H           H           H          OH         S
B680        PhS         H           H           H          OH         S
B681        PhSO        H           H           H          OH         S
B682        PhSO2       H           H           H          OH         S
B683        CN          H           H           H          OH         S
B684        CH3         CH3         H           H          OH         S
B685        CH3CH2      CH3         H           H          OH         S
B686        CH3CH2CH2   CH3         H           H          OH         S
B687        (CH3)2CH    CH3         H           H          OH         S
B688        (CH3)3C     CH3         H           H          OH         S
B689        CH3S        CH3         H           H          OH         S
B690        CH3SO       CH3         H           H          OH         S
B691        CH3SO2      CH3         H           H          OH         S
B692        Ph          CH3         H           H          OH         S
基团        R44          R37           R38         R39        R40        W
B693        CH3O         CH3           H           H          OH         S
B694        CH3CO2       CH3           H           H          OH         S
B695        CH3CH2CO2    CH3           H           H          OH         S
B696        CH2＝CHCH2   CH3           H           H          OH         S
B697        HCCCH2       CH3           H           H          OH         S
B698        CF3          CH3           H           H          OH         S
B699        (CH3)2NSO2   CH3           H           H          OH         S
B700        (CH3)2N      CH3           H           H          OH         S
B701        PhO          CH3           H           H          OH         S
B702        PhS          CH3           H           H          OH         S
B703        PhSO         CH3           H           H          OH         S
B704        PhSO2        CH3           H           H          OH         S
B705        CN           CH3           H           H          OH         S
B706        CH3          H             CH3         H          OH         S
B707        CH3CH2       H             CH3         H          OH         S
B708        CH3CH2CH2    H             CH3         H          OH         S
B709        (CH3)2CH     H             CH3         H          OH         S
B710        (CH3)3C      H             CH3         H          OH         S
B711        CH3S         H             CH3         H          OH         S
B712        CH3SO        H             CH3         H          OH         S
B713        CH3SO2       H             CH3         H          OH         S
B714        Ph           H             CH3         H          OH         S
B715        CH3O         H             CH3         H          OH         S
B716        CH3CO2       H             CH3         H          OH         S
B717        CH3CH2CO2    H             CH3         H          OH         S
B718        CH2＝CHCH2   H             CH3         H          OH         S
B719        HCCCH2       H             CH3         H          OH         S
B720        CF3          H             CH3         H          OH         S
B721        (CH3)2NSO2   H             CH3         H          OH         S
B722        (CH3)2N      H             CH3         H          OH         S
B723        PhO          H             CH3         H          OH         S
B724        PhS          H             CH3         H          OH         S
B725        PhSO         H             CH3         H          OH         S
基团         R44         R37         R38         R39           R40       W
B726         PhSO2       H           CH3         H             OH        S
B727         CN          H           CH3         H             OH        S
B728         CH3         CH3         CH3         H             OH        S
B729         CH3CH2      CH3         CH3         H             OH        S
B730         CH3CH2CH2   CH3         CH3         H             OH        S
B731         (CH3)2CH    CH3         CH3         H             OH        S
B732         (CH3)3C     CH3         CH3         H             OH        S
B733         CH3S        CH3         CH3         H             OH        S
B734         CH3SO       CH3         CH3         H             OH        S
B735         CH3SO2      CH3         CH3         H             OH        S
B736         Ph          CH3         CH3         H             OH        S
B737         CH3O        CH3         CH3         H             OH        S
B738         CH3CO2      CH3         CH3         H             OH        S
B739         CH3CH2CO2   CH3         CH3         H             OH        S
B740         CH2＝CHCH2  CH3         CH3         H             OH        S
B741         HCCCH2      CH3         CH3         H             OH        S
B742         CF3         CH3         CH3         H             OH        S
B743         (CH3)2NSO2  CH3         CH3         H             OH        S
B744         (CH3)2N     CH3         CH3         H             OH        S
B745         PhO         CH3         CH3         H             OH        S
B746         PhS         CH3         CH3         H             OH        S
B747         PhSO        CH3         CH3         H             OH        S
B748         PhSO2       CH3         CH3         H             OH        S
B749         CN          CH3         CH3         H             OH        S
B750         CH3         CH3         CH3         CH3           OH        S
B751         CH3CH2      CH3         CH3         CH3           OH        S
B752         CH3CH2CH2   CH3         CH3         CH3           OH        S
B753         (CH3)2CH    CH3         CH3         CH3           OH        S
B754         (CH3)3C     CH3         CH3         CH3           OH        S
B755         CH3S        CH3         CH3         CH3           OH        S
B756         CH3SO       CH3         CH3         CH3           OH        S
B757         CH3SO2      CH3         CH3         CH3           OH        S
B758         Ph          CH3         CH3         CH3           OH        S
基团        R44         R37         R38          R39         R40         W
B759        CH3O        CH3         CH3          CH3         OH          S
B760        CH3CO2      CH3         CH3          CH3         OH          S
B761        CH3CH2CO2   CH3         CH3          CH3         OH          S
B762        CH2＝CHCH2  CH3         CH3          CH3         OH          S
B763        HCCCH2      CH3         CH3          CH3         OH          S
B764        CF3         CH3         CH3          CH3         OH          S
B765        (CH3)2NSO2  CH3         CH3          CH3         OH          S
B766        (CH3)2N     CH3         CH3          CH3         OH          S
B767        PhO         CH3         CH3          CH3         OH          S
B768        PhS         CH3         CH3          CH3         OH          S
B769        PhSO        CH3         CH3          CH3         OH          S
B770        PhSO2       CH3         CH3          CH3         OH          S
B771        CN          CH3         CH3          CH3         OH          S
B772        CH3CH2      CH3CH2      H            H           OH          S
B773        CH3CH2CH2   CH3CH2      H            H           OH          S
B774        (CH3)2CH    CH3CH2      H            H           OH          S
B775        (CH3)3C     CH3CH2      H            H           OH          S
B776        CH3S        CH3CH2      H            H           OH          S
B777        CH3SO       CH3CH2      H            H           OH          S
B778        CH3SO2      CH3CH2      H            H           OH          S
B779        Ph          CH3CH2      H            H           OH          S
B780        CH3O        CH3CH2      H            H           OH          S
B781        CH3CO2      CH3CH2      H            H           OH          S
B782        CH3CH2CO2   CH3CH2      H            H           OH          S
B783        CH2＝CHCH2  CH3CH2      H            H           OH          S
B784        HCCCH2      CH3CH2      H            H           OH          S
B785        CF3         CH3CH2      H            H           OH          S
B786        (CH3)2NSO2  CH3CH2      H            H           OH          S
B787        (CH3)2N     CH3CH2      H            H           OH          S
B788        PhO         CH3CH2      H            H           OH          S
B789        PhS         CH3CH2      H            H           OH          S
B790        PhSO        CH3CH2      H            H           OH          S
B791        PhSO2       CH3CH2      H            H           OH          S
基团      R44         R37        R38         R39       R40        W
B792      CN          CH3CH2     H           H         OH         S
B793      H           H          H           H         OH         SO2
B794      CH3         H          H           H         OH         SO2
B795      CH3CH2      H          H           H         OH         SO2
B796      CH3CH2CH2   H          H           H         OH         SO2
B797      (CH3)2CH    H          H           H         OH         SO2
B798      (CH3)3C     H          H           H         OH         SO2
B799      CH3S        H          H           H         OH         SO2
B800      CH3SO       H          H           H         OH         SO2
B801      CH3SO2      H          H           H         OH         SO2
B802      Ph          H          H           H         OH         SO2
B803      CH3O        H          H           H         OH         SO2
B804      CH3CO2      H          H           H         OH         SO2
B805      CH3CH2CO2   H          H           H         OH         SO2
B806      CH2＝CHCH2  H          H           H         OH         SO2
B807      HCCCH2      H          H           H         OH         SO2
B808      CF3         H          H           H         OH         SO2
B809      (CH3)2NSO2  H          H           H         OH         SO2
B810      (CH3)2N     H          H           H         OH         SO2
B811      PhO         H          H           H         OH         SO2
B812      PhS         H          H           H         OH         SO2
B813      PhSO        H          H           H         OH         SO2
B814      PhSO2       H          H           H         OH         SO2
B815      CN          H          H           H         OH         SO2
B816      CH3         CH3        H           H         OH         SO2
B817      CH3CH2      CH3        H           H         OH         SO2
B818      CH3CH2CH2   CH3        H           H         OH         SO2
B819      (CH3)2CH    CH3        H           H         OH         SO2
B820      (CH3)3C     CH3        H           H         OH         SO2
B821      CH3S        CH3        H           H         OH         SO2
B822      CH3SO       CH3        H           H         OH         SO2
B823      CH3SO2      CH3        H           H         OH         SO2
B824      Ph          CH3        H           H         OH         SO2
基团      R44        R37        R38         R39       R40        W
B825      CH3O       CH3        H           H         OH         SO2
B826      CH3CO2     CH3        H           H         OH         SO2
B827      CH3CH2CO2  CH3        H           H         OH         SO2
B828      CH2＝CHCH2 CH3        H           H         OH         SO2
B829      HCCCH2     CH3        H           H         OH         SO2
B830      CF3        CH3        H           H         OH         SO2
B831      (CH3)2NSO2 CH3        H           H         OH         SO2
B832      (CH3)2N    CH3        H           H         OH         SO2
B833      PhO        CH3        H           H         OH         SO2
B834      PhS        CH3        H           H         OH         SO2
B835      PhSO       CH3        H           H         OH         SO2
B836      PhSO2      CH3        H           H         OH         SO2
B837      CN         CH3        H           H         OH         SO2
B838      CH3        H          CH3         H         OH         SO2
B839      CH3CH2     H          CH3         H         OH         SO2
B840      CH3CH2CH2  H          CH3         H         OH         SO2
B841      (CH3)2CH   H          CH3         H         OH         SO2
B842      (CH3)3C    H          CH3         H         OH         SO2
B843      CH3S       H          CH3         H         OH         SO2
B844      CH3SO      H          CH3         H         OH         SO2
B845      CH3SO2     H          CH3         H         OH         SO2
B846      Ph         H          CH3         H         OH         SO2
B847      CH3O       H          CH3         H         OH         SO2
B848      CH3CO2     H          CH3         H         OH         SO2
B849      CH3CH2CO2  H          CH3         H         OH         SO2
B850      CH2＝CHCH2 H          CH3         H         OH         SO2
B851      HCCCH2     H          CH3         H         OH         SO2
B852      CF3        H          CH3         H         OH         SO2
B853      (CH3)2NSO2 H          CH3         H         OH         SO2
B854      (CH3)2N    H          CH3         H         OH         SO2
B855      PhO        H          CH3         H         OH         SO2
B856      PhS        H          CH3         H         OH         SO2
B857      PhSO       H          CH3         H         OH         SO2
基团     R44           R37          R38          R39         R40          W
B858     PhSO3         H            CH3          H           OH          SO2
B859     CN            H            CH3          H           OH          SO2
B860     CH3           CH3          CH3          H           OH          SO2
B861     CH3CH2        CH3          CH3          H           OH          SO2
B862     CH3CH2CH2     CH3          CH3          H           OH          SO2
B863     (CH3)2CH      CH3          CH3          H           OH          SO2
B864     (CH3)3C       CH3          CH3          H           OH          SO2
B865     CH3S          CH3          CH3          H           OH          SO2
B866     CH3SO         CH3          CH3          H           OH          SO2
B867     CH3SO2        CH3          CH3          H           OH          SO2
B868     Ph            CH3          CH3          H           OH          SO2
B869     CH3O          CH3          CH3          H           OH          SO2
B870     CH3CO2        CH3          CH3          H           OH          SO2
B871     CH3CH2CO2     CH3          CH3          H           OH          SO2
B872     CH2＝CHCH2    CH3          CH3          H           OH          SO2
B873     HCCCH2        CH3          CH3          H           OH          SO2
B874     CF3           CH3          CH3          H           OH          SO2
B875     (CH3)2NSO2    CH3          CH3          H           OH          SO2
B876     (CH3)2N       CH3          CH3          H           OH          SO2
B877     PhO           CH3          CH3          H           OH          SO2
B878     PhS           CH3          CH3          H           OH          SO2
B879     PhSO          CH3          CH3          H           OH          SO2
B880     PhSO2         CH3          CH3          H           OH          SO2
B881     CN            CH3          CH3          H           OH          SO2
B882     CH3           CH3          CH3          CH3         OH          SO2
B883     CH3CH2        CH3          CH3          CH3         OH          SO2
B884     CH3CH2CH2     CH3          CH3          CH3         OH          SO2
B885     (CH3)2CH      CH3          CH3          CH3         OH          SO2
B886     (CH3)3C       CH3          CH3          CH3         OH          SO2
B887     CH3S          CH3          CH3          CH3         OH          SO2
B888     CH3SO         CH3          CH3          CH3         OH          SO2
B889     CH3SO2        CH3          CH3          CH3         OH          SO2
B890     Ph            CH3          CH3          CH3         OH          SO2
基团        R44         R37        R38         R39        R40         W
B891        CH3O        CH3        CH3         CH3        OH          SO2
B892        CH3CO2      CH3        CH3         CH3        OH          SO2
B893        CH3CH2CO2   CH3        CH3         CH3        OH          SO2
B894        CH2＝CHCH2  CH3        CH3         CH3        OH          SO2
B895        HCCCH2      CH3        CH3         CH3        OH          SO2
B896        CF3         CH3        CH3         CH3        OH          SO2
B897        (CH3)2NSO2  CH3        CH3         CH3        OH          SO2
B898        (CH3)2N     CH3        CH3         CH3        OH          SO2
B899        PhO         CH3        CH3         CH3        OH          SO2
B900        PhS         CH3        CH3         CH3        OH          SO2
B901        PhSO        CH3        CH3         CH3        OH          SO2
B902        PhSO2       CH3        CH3         CH3        OH          SO2
B903        CN          CH3        CH3         CH3        OH          SO2
B904        CH3CH2      CH3CH2     H           H          OH          SO2
B905        CH3CH2CH2   CH3CH2     H           H          OH          SO2
B906        (CH3)2CH    CH3CH2     H           H          OH          SO2
B907        (CH3)3C     CH3CH2     H           H          OH          SO2
B908        CH3S        CH3CH2     H           H          OH          SO2
B909        CH3SO       CH3CH2     H           H          OH          SO2
B910        CH3SO2      CH3CH2     H           H          OH          SO2
B911        Ph          CH3CH2     H           H          OH          SO2
B912        CH3O        CH3CH2     H           H          OH          SO2
B913        CH3CO2      CH3CH2     H           H          OH          SO2
B914        CH3CH2CO2   CH3CH2     H           H          OH          SO2
B915        CH2＝CHCH2  CH3CH2     H           H          OH          SO2
B916        HCCCH2      CH3CH2     H           H          OH          SO2
B917        CF3         CH3CH2     H           H          OH          SO2
B918        (CH3)2NSO2  CH3CH2     H           H          OH          SO2
B919        (CH3)2N     CH3CH2     H           H          OH          SO2
B920        PhO         CH3CH2     H           H          OH          SO2
B921        PhS         CH3CH2     H           H          OH          SO2
B922        PhSO        CH3CH2     H           H          OH          SO2
B923        PhSO2       CH3CH2     H           H          OH          SO2
基团           R44              R37         R38         R39         R40          W
B924           CN               CH3CH2      H           H           OH           SO2
B925           H                H           H           H           OH           CH(CO2CH2CH3)
B926           CH3              H           H           H           OH           CH(CO2CH2CH3)
B927           CH3CH2           H           H           H           OH           CH(CO2CH2CH3)
B928           CH3CH2CH2        H           H           H           OH           CH(CO2CH2CH3)
B929           (CH3)2CH         H           H           H           OH           CH(CO2CH2CH3)
B930           (CH3)3C          H           H           H           OH           CH(CO2CH2CH3)
B931           CH3S             H           H           H           OH           CH(CO2CH2CH3)
B932           CH3SO            H           H           H           OH           CH(CO2CH2CH3)
B933           CH3SO2           H           H           H           OH           CH(CO2CH2CH3)
B934           Ph               H           H           H           OH           CH(CO2CH2CH3)
B935           CH3O             H           H           H           OH           CH(CO2CH2CH3)
B936           CH3CO2           H           H           H           OH           CH(CO2CH2CH3)
B937           CH3CH2CO2        H           H           H           OH           CH(CO2CH2CH3)
B938           CH2＝CHCH2       H           H           H           OH           CH(CO2CH2CH3)
B939           HCCCH2           H           H           H           OH           CH(CO2CH2CH3)
B940           CF3              H           H           H           OH           CH(CO2CH2CH3)
B941           (CH3)2NSO2       H           H           H           OH           CH(CO2CH2CH3)
B942           (CH3)2N          H           H           H           OH           CH(CO2CH2CH3)
B943           PhO              H           H           H           OH           CH(CO2CH2CH3)
B944           PhS              H           H           H           OH           CH(CO2CH2CH3)
B945           PhSO             H           H           H           OH           CH(CO2CH2CH3)
B946           PhSO2            H           H           H           OH           CH(CO2CH2CH3)
B947           CN               H           H           H           OH           CH(CO2CH2CH3)
B948           CH3              CH3         H           H           OH           CH(CO2CH2CH3)
B949           CH3CH2           CH3         H           H           OH           CH(CO2CH2CH3)
B950           CH3CH2CH2        CH3         H           H           OH           CH(CO2CH2CH3)
B951           (CH3)2CH         CH3         H           H           OH           CH(CO2CH2CH3)
B952           (CH3)3C          CH3         H           H           OH           CH(CO2CH2CH3)
B953           CH3S             CH3         H           H           OH           CH(CO2CH2CH3)
B954           CH3SO            CH3         H           H           OH           CH(CO2CH2CH3)
B955           CH3SO2           CH3         H           H           OH           CH(CO2CH2CH3)
B956           Ph               CH3         H           H           OH           CH(CO2CH2CH3)
基团       R44         R37         R38         R39         R40          W
B957       CH3O        CH3         H           H           OH           CH(CO2CH2CH3)
B958       CH3CO2      CH3         H           H           OH           CH(CO2CH2CH3)
B959       CH3CH2CO2   CH3         H           H           OH           CH(CO2CH2CH3)
B960       CH2＝CHCH2  CH3         H           H           OH           CH(CO2CH2CH3)
B961       HCCCH2      CH3         H           H           OH           CH(CO2CH2CH3)
B962       CF3         CH3         H           H           OH           CH(CO2CH2CH3)
B963       (CH3)2NSO2  CH3         H           H           OH           CH(CO2CH2CH3)
B964       (CH3)2N     CH3         H           H           OH           CH(CO2CH2CH3)
B965       PhO         CH3         H           H           OH           CH(CO2CH2CH3)
B966       PhS         CH3         H           H           OH           CH(CO2CH2CH3)
B967       PhSO        CH3         H           H           OH           CH(CO2CH2CH3)
B968       PhSO2       CH3         H           H           OH           CH(CO2CH2CH3)
B969       CN          CH3         H           H           OH           CH(CO2CH2CH3)
B970       CH3         H           CH3         H           OH           CH(CO2CH2CH3)
B971       CH3CH2      H           CH3         H           OH           CH(CO2CH2CH3)
B972       CH3CH2CH2   H           CH3         H           OH           CH(CO2CH2CH3)
B973       (CH3)2CH    H           CH3         H           OH           CH(CO2CH2CH3)
B974       (CH3)3C     H           CH3         H           OH           CH(CO2CH2CH3)
B975       CH3S        H           CH3         H           OH           CH(CO2CH2CH3)
B976       CH3SO       H           CH3         H           OH           CH(CO2CH2CH3)
B977       CH3SO2      H           CH3         H           OH           CH(CO2CH2CH3)
B978       Ph          H           CH3         H           OH           CH(CO2CH2CH3)
B979       CH3O        H           CH3         H           OH           CH(CO2CH2CH3)
B980       CH3CO2      H           CH3         H           OH           CH(CO2CH2CH3)
B981       CH3CH2CO2   H           CH3         H           OH           CH(CO2CH2CH3)
B982       CH2＝CHCH2  H           CH3         H           OH           CH(CO2CH2CH3)
B983       HCCCH2      H           CH3         H           OH           CH(CO2CH2CH3)
B984       CF3         H           CH3         H           OH           CH(CO2CH2CH3)
B985       (CH3)2NSO2  H           CH3         H           OH           CH(CO2CH2CH3)
B986       (CH3)2N     H           CH3         H           OH           CH(CO2CH2CH3)
B987       PhO         H           CH3         H           OH           CH(CO2CH2CH3)
B988       PhS         H           CH3         H           OH           CH(CO2CH2CH3)
B989       PhSO        H           CH3         H           OH           CH(CO2CH2CH3)
基团         R44          R37       R38        R39         R40         W
B990         PhSO2        H         CH3        H           OH          CH(CO2CH2CH3)
B991         CN           H         CH3        H           OH          CH(CO2CH2CH3)
B992         CH3          CH3       CH3        H           OH          CH(CO2CH2CH3)
B993         CH3CH2       CH3       CH3        H           OH          CH(CO2CH2CH3)
B994         CH3CH2CH2    CH3       CH3        H           OH          CH(CO2CH2CH3)
B995         (CH3)2CH     CH3       CH3        H           OH          CH(CO2CH2CH3)
B996         (CH3)3C      CH3       CH3        H           OH          CH(CO2CH2CH3)
B997         CH3S         CH3       CH3        H           OH          CH(CO2CH2CH3)
B998         CH3SO        CH3       CH3        H           OH          CH(CO2CH2CH3)
B999         CH3SO2       CH3       CH3        H           OH          CH(CO2CH2CH3)
B1000        Ph           CH3       CH3        H           OH          CH(CO2CH2CH3)
B1001        CH3O         CH3       CH3        H           OH          CH(CO2CH2CH3)
B1002        CH3CO2       CH3       CH3        H           OH          CH(CO2CH2CH3)
B1003        CH3CH2CO2    CH3       CH3        H           OH          CH(CO2CH2CH3)
B1004        CH2＝CHCH2   CH3       CH3        H           OH          CH(CO2CH2CH3)
B1005        HCCCH2       CH3       CH3        H           OH          CH(CO2CH2CH3)
B1006        CF3          CH3       CH3        H           OH          CH(CO2CH2CH3)
B1007        (CH3)2NSO2   CH3       CH3        H           OH          CH(CO2CH2CH3)
B1008        (CH3)2N      CH3       CH3        H           OH          CH(CO2CH2CH3)
B1009        PhO          CH3       CH3        H           OH          CH(CO2CH2CH3)
B1010        PhS          CH3       CH3        H           OH          CH(CO2CH2CH3)
B1011        PhSO         CH3       CH3        H           OH          CH(CO2CH2CH3)
B1012        PhSO2        CH3       CH3        H           OH          CH(CO2CH2CH3)
B1013        CN           CH3       CH3        H           OH          CH(CO2CH2CH3)
B1014        CH3          CH3       CH3        CH3         OH          CH(CO2CH2CH3)
B1015        CH3CH2       CH3       CH3        CH3         OH          CH(CO2CH2CH3)
B1016        CH3CH2CH2    CH3       CH3        CH3         OH          CH(CO2CH2CH3)
B1017        (CH3)2CH     CH3       CH3        CH3         OH          CH(CO2CH2CH3)
B1018        (CH3)3C      CH3       CH3        CH3         OH          CH(CO2CH2CH3)
B1019        CH3S         CH3       CH3        CH3         OH          CH(CO2CH2CH3)
B1020        CH3SO        CH3       CH3        CH3         OH          CH(CO2CH2CH3)
B1021        CH3SO2       CH3       CH3        CH3         OH          CH(CO2CH2CH3)
B1022        Ph           CH3       CH3        CH3         OH          CH(CO2CH2CH3)
基团      R44          R37        R38         R39        R40        W
B1023     CH3O         CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1024     CH3CO2       CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1025     CH3CH2CO2    CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1026     CH2＝CHCH2   CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1027     HCCCH2       CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1028     CF3          CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1029     (CH3)2NSO2   CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1030     (CH3)2N      CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1031     PhO          CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1032     PhS          CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1033     PhSO         CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1034     PhSO2        CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1035     CN           CH3        CH3         CH3        OH         CH(CO2CH2CH3)
B1036     CH3CH2       CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1037     CH3CH2CH2    CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1038     (CH3)2CH     CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1039     (CH3)3C      CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1040     CH3S         CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1041     CH3SO        CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1042     CH3SO2       CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1043     Ph           CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1044     CH3O         CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1045     CH3CO2       CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1046     CH3CH2CO2    CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1047     CH2＝CHCH2   CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1048     HCCCH2       CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1049     CF3          CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1050     (CH3)2NSO2   CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1051     (CH3)2N      CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1052     PhO          CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1053     PhS          CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1054     PhSO         CH3CH2     H           H          OH         CH(CO2CH2CH3)
B1055     PhSO2        CH3CH2     H           H          OH         CH(CO2CH2CH3)
基团       R44              R37          R38          R39          R40        W
B1056      CN               CH3CH2       H            H            OH         CH(CO2CH2CH3)
B1057      CH3OCO           H            H            H            OH         CHPh
B1058      H                H            H            H            OH         CHPh
B1059      H                H            H            H            OH         CH(CH2CH3)
B1060      H                H            H            H            OH         CH(CH2CH2CH3)
B1061      H                H            H            H            OH         CH(CH(CH3)2)
B1062      H                H            H            H            OH         CH(C(CH3)3)
B1063      H                H            H            H            OH         C(CH3)2
B1064      H                H            H            H            OH         CH(CF3)
B1065      CH3OCO           H            H            H            OH         C(CH3)(CF3)
B1066      H                H            H            H            OH         C(CH3)(CF3)
B1067      CH3OCO           CH3O         H            H            OH         CH2
B1068      H                CH3O         H            H            OH         CH2
B1069      CH3O             CH3OCO       H            CH3          OH         CH2
B1070      CH3O             H            CH3          H            OH         CH2
B1071      Cl               H            H            H            OH         CH2
B1072      F                H            H            H            OH         CH2
B1073      H                H            H            H            OH         CH(OCH3)2
B1074      H                H            H            H            OH         CH2OSO2CH3
B1075      CH3              CH3          CH3          CH3          OH         S(O)
B1076      ClCH2CH2         H            H            H            OH         CH2
B1077      HO(CH2)2         H            H            H            OH         CH2
B1078      MsO(CH2)2        H            H            H            OH         CH2
B1079      HOCH(CH3)CH2     H            H            H            OH         CH2
B1080      MsOCH(CH3)CH2    H            H            H            OH         CH2
B1081      (CH3)2CH         H            CH3          CH3          OH         CH2
B1082      HCCCH2           H            CH3          CH3          OH         CH2
B1083      H2C＝CCH2        H            CH3          CH3          OH         CH2
在下表7中，Q是Q6
Figure C01804089D01381
且Q6代表下列基团C：
表7：基团C：
基团          R84         R85           R86        R83     p      W
C1            H           H             H          OH      1      CH2
C2            CH3         H             H          OH      1      CH2
C3            CH3CH2      H             H          OH      1      CH2
C4            CH3CH2CH2   H             H          OH      1      CH2
C5            (CH3)2CH    H             H          OH      1      CH2
C6            (CH3)3C     H             H          OH      1      CH2
C7            CH3S        H             H          OH      1      CH2
C8            CH3SO       H             H          OH      1      CH2
C9            CH3SO2      H             H          OH      1      CH2
C10           Ph          H             H          OH      1      CH2
C11           CH3O        H             H          OH      1      CH2
C12           CH3OCO2     H             H          OH      1      CH2
C13           CH3CH2OCO2  H             H          OH      1      CH2
C14           CH2＝CHCH2  H             H          OH      1      CH2
C15           HCCCH2      H             H          OH      1      CH2
C16           CF3         H             H          OH      1      CH2
C17           (CH3)2NSO2  H             H          OH      1      CH2
C18           (CH3)2N     H             H          OH      1      CH2
C19           PhO         H             H          OH      1      CH2
C20           PhS         H             H          OH      1      CH2
C21           PhSO        H             H          OH      1      CH2
C22           PhSO2       H             H          OH      1      CH2
基团     R84           R85      R86       R83     p       W
C23      CN            H        H         OH      1       CH2
C24      CH3           CH3      H         OH      1       CH2
C25      CH3CH2        CH3      H         OH      1       CH2
C26      CH3CH2CH2     CH3      H         OH      1       CH2
C27      (CH3)2CH      CH3      H         OH      1       CH2
C28      (CH3)3C       CH3      H         OH      1       CH2
C29      CH3S          CH3      H         OH      1       CH2
C30      CH3SO         CH3      H         OH      1       CH2
C31      CH3SO2        CH3      H         OH      1       CH2
C32      Ph            CH3      H         OH      1       CH2
C33      CH3O          CH3      H         OH      1       CH2
C34      CH3OCO2       CH3      H         OH      1       CH2
C35      CH3CH2OCO2    CH3      H         OH      1       CH2
C36      CH2＝CHCH2    CH3      H         OH      1       CH2
C37      HCCCH2        CH3      H         OH      1       CH2
C38      CF3           CH3      H         OH      1       CH2
C39      (CH3)2NSO2    CH3      H         OH      1       CH2
C40      (CH3)2N       CH3      H         OH      1       CH2
C41      PhO           CH3      H         OH      1       CH2
C42      PhS           CH3      H         OH      1       CH2
C43      PhSO          CH3      H         OH      1       CH2
C44      PhSO2         CH3      H         OH      1       CH2
C45      CN            CH3      H         OH      1       CH2
C46      H             H        H         OH      4       CH2
C47      CH3           H        H         OH      4       CH2
C48      CH3CH2        H        H         OH      4       CH2
C49      CH3CH2CH2     H        H         OH      4       CH2
C50      (CH3)2CH      H        H         OH      4       CH2
C51      (CH3)3C       H        H         OH      4       CH2
C52      CH3S          H        H         OH      4       CH2
C53      CH3SO         H        H         OH      4       CH2
C54      CH3SO2        H        H         OH      4       CH2
C55      Ph            H        H         OH      4       CH2
基团      R84              R85      R86      R83      p     W
C56       CH3O             H        H        OH       4     CH2
C57       CH3OCO2          H        H        OH       4     CH2
C58       CH3CH2OCO2       H        H        OH       4     CH2
C59       CH2＝CHCH2       H        H        OH       4     CH2
C60       HCCCH2           H        H        OH       4     CH2
C61       CF3              H        H        OH       4     CH2
C62       (CH3)2NSO2       H        H        OH       4     CH2
C63       (CH3)2N          H        H        OH       4     CH2
C64       PhO              H        H        OH       4     CH2
C65       PhS              H        H        OH       4     CH2
C66       PhSO             H        H        OH       4     CH2
C67       PhSO2            H        H        OH       4     CH2
C68       CN               H        H        OH       4     CH2
C69       CH3              CH3      H        OH       4     CH2
C70       CH3CH2           CH3      H        OH       4     CH2
C71       CH3CH2CH2        CH3      H        OH       4     CH2
C72       (CH3)2CH         CH3      H        OH       4     CH2
C73       (CH3)3C          CH3      H        OH       4     CH2
C74       CH3S             CH3      H        OH       4     CH2
C75       CH3SO            CH3      H        OH       4     CH2
C76       CH3SO2           CH3      H        OH       4     CH2
C77       Ph               CH3      H        OH       4     CH2
C78       CH3O             CH3      H        OH       4     CH2
C79       CH3OCO2          CH3      H        OH       4     CH2
C80       CH3CH2OCO2       CH3      H        OH       4     CH2
C81       CH2＝CHCH2       CH3      H        OH       4     CH2
C82       HCCCH2           CH3      H        OH       4     CH2
C83       CF3              CH3      H        OH       4     CH2
C84       (CH3)2NSO2       CH3      H        OH       4     CH2
C85       (CH3)2N          CH3      H        OH       4     CH2
C86       PhO              CH3      H        OH       4     CH2
C87       PhS              CH3      H        OH       4     CH2
C88       PhSO             CH3      H        OH       4     CH2
基团        R84          R85           R86         R83        p       W
C89         PhSO2        CH3           H           OH         4       CH2
C90         CN           CH3           H           OH         4       CH2
C91         H            H             H           OH         3       CH2
C92         CH3          H             H           OH         3       CH2
C93         CH3CH2       H             H           OH         3       CH2
C94         CH3CH2CH2    H             H           OH         3       CH2
C95         (CH3)2CH     H             H           OH         3       CH2
C96         (CH3)3C      H             H           OH         3       CH2
C97         CH3S         H             H           OH         3       CH2
C98         CH3SO        H             H           OH         3       CH2
C99         CH3SO2       H             H           OH         3       CH2
C100        Ph           H             H           OH         3       CH2
C101        CH3O         H             H           OH         3       CH2
C102        CH3OCO2      H             H           OH         3       CH2
C103        CH3CH2OCO2   H             H           OH         3       CH2
C104        CH2＝CHCH2   H             H           OH         3       CH2
C105        HCCCH2       H             H           OH         3       CH2
C106        CF3          H             H           OH         3       CH2
C107        (CH3)2NSO2   H             H           OH         3       CH2
C108        (CH3)2N      H             H           OH         3       CH2
C109        PhO          H             H           OH         3       CH2
C110        PhS          H             H           OH         3       CH2
C111        PhSO         H             H           OH         3       CH2
C112        PhSO2        H             H           OH         3       CH2
C113        CN           H             H           OH         3       CH2
C114        CH3          CH3           H           OH         3       CH2
C115        CH3CH2       CH3           H           OH         3       CH2
C116        CH3CH2CH2    CH3           H           OH         3       CH2
C117        (CH3)2CH     CH3           H           OH         3       CH2
C118        (CH3)3C      CH3           H           OH         3       CH2
C119        CH3S         CH3           H           OH         3       CH2
C120        CH3SO        CH3           H           OH         3       CH2
C121        CH3SO2       CH3           H           OH         3       CH2
基团      R84        R85        R86        R83        p       W
C122      Ph         CH3        H          OH         3       CH2
C123      CH3O       CH3        H          OH         3       CH2
C124      CH3OCO2    CH3        H          OH         3       CH2
C125      CH3CH2OCO2 CH3        H          OH         3       CH2
C126      CH2＝CHCH2 CH3        H          OH         3       CH2
C127      HCCCH2     CH3        H          OH         3       CH2
C128      CF3        CH3        H          OH         3       CH2
C129      (CH3)2NSO2 CH3        H          OH         3       CH2
C130      (CH3)2N    CH3        H          OH         3       CH2
C131      PhO        CH3        H          OH         3       CH2
C132      PhS        CH3        H          OH         3       CH2
C133      PhSO       CH3        H          OH         3       CH2
C134      PhSO2      CH3        H          OH         3       CH2
C135      CN         CH3        H          OH         3       CH2
C136      CH3CH2     CH3CH2     H          OH         1       CH2
C137      H          H          H          OH         1       CH(CH3)
C138      CH3        H          H          OH         1       CH(CH3)
C139      CH3        CH3        H          OH         1       CH(CH3)
C140      CH2CH3      H          H          OH         1       CH(CH3)
C141      CH2CH3     CH3        H          OH         1       CH(CH3)
C142      CH3CH2     CH3CH2     H          OH         1       CH(CH3)
C143      H          H          CH3        OH         1       CH2
C144      CH3        CH3        CH3        OH         1       CH2
C145      CH3CH2     CH3CH2     CH3        OH         1       CH2
C146      H          H          H          OH         2       CH2
C147      CH3        CH3        H          OH         2       CH2
C148      CH3CH2     CH3CH2     H          OH         2       CH2
C149      H          H          H          OH         5       CH2
C150      CH3        CH3        H          OH         5       CH2
C151      CH3CH2     CH3CH2     H          OH         5       CH2
在下表8中，Q是Q8
Figure C01804089D01431
且Q8代表下列基团D：
表8：基团D：
基团       R88            R89       R90         R91        R87     o
D1         H              H         H           H          OH      2
D2         CH3            H         H           H          OH      2
D3         CH3CH2         H         H           H          OH      2
D4         CH3CH2CH2      H         H           H          OH      2
D5         (CH3)2CH       H         H           H          OH      2
D6         (CH3)3C        H         H           H          OH      2
D7         CH3S           H         H           H          OH      2
D8         CH3SO          H         H           H          OH      2
D9         CH3SO2         H         H           H          OH      2
D10        Ph             H         H           H          OH      2
D11        CH3O           H         H           H          OH      2
D12        CH2＝CHCH2     H         H           H          OH      2
D13        HCCCH2         H         H           H          OH      2
D14        CF3            H         H           H          OH      2
D15        PhO            H         H           H          OH      2
D16        PhS            H         H           H          OH      2
D17        PhSO           H         H           H          OH      2
D18        PhSO2          H         H           H          OH      2
D19        CH3            CH3       H           H          OH      2
D20        CH3CH2         CH3       H           H          OH      2
D21        CH3CH2CH2      CH3       H           H          OH      2
D22        (CH3)2CH       CH3       H           H          OH      2
D23        (CH3)3C        CH3       H           H          OH      2
基团      R88             R89        R90       R91        R87        o
D24       CH3S            CH3         H         H          OH         2
D25       CH3SO           CH3         H         H          OH         2
D26       CH3SO2          CH3         H         H          OH         2
D27       Ph              CH3         H         H          OH         2
D28       CH3O            CH3         H         H          OH         2
D29       CH2＝CHCH2      CH3         H         H          OH         2
D30       HCCCH2          CH3         H         H          OH         2
D31       CF3             CH3         H         H          OH         2
D32       PhO             CH3         H         H          OH         2
D33       PhS             CH3         H         H          OH         2
D34       PhSO            CH3         H         H          OH         2
D35       PhSO2           CH3         H         H          OH         2
D36       H               H           H         H          OH         3
D37       CH3             H           H         H          OH         3
D38       CH3CH2          H           H         H          OH         3
D39       CH3CH2CH2       H           H         H          OH         3
D40       (CH3)2CH        H           H         H          OH         3
D41       (CH3)3C         H           H         H          OH         3
D42       CH3S            H           H         H          OH         3
D43       CH3SO           H           H         H          OH         3
D44       CH3SO2          H           H         H          OH         3
D45       Ph              H           H         H          OH         3
D46       CH3O            H           H         H          OH         3
D47       CH2＝CHCH2      H           H         H          OH         3
D48       HCCCH2          H           H         H          OH         3
D49       CF3             H           H         H          OH         3
D50       PhO             H           H         H          OH         3
D51       PhS             H           H         H          OH         3
D52       PhSO            H           H         H          OH         3
D53       PhSO2           H           H         H          OH         3
D54       CH3             CH3         H         H          OH         3
D55       CH3CH2          CH3         H         H          OH         3
D56       CH3CH2CH2       CH3         H         H          OH         3
基团       R88            R89       R90         R91        R87         o
D57        (CH3)2CH       CH3       H           H          OH          3
D58        (CH3)3C        CH3       H           H          OH          3
D59        CH3S           CH3       H           H          OH          3
D60        CH3SO          CH3       H           H          OH          3
D61        CH3SO2         CH3       H           H          OH          3
D62        Ph             CH3       H           H          OH          3
D63        CH3O           CH3       H           H          OH          3
D64        CH2＝CHCH2     CH3       H           H          OH          3
D65        HCCCH2         CH3       H           H          OH          3
D66        CF3            CH3       H           H          OH          3
D67        PhO            CH3       H           H          OH          3
D68        PhS            CH3       H           H          OH          3
D69        PhSO           CH3       H           H          OH          3
D70        PhSO2          CH3       H           H          OH          3
D71        H              H         H           H          OH          4
D72        CH3            H         H           H          OH          4
D73        CH3CH2         H         H           H          OH          4
D74        CH3CH2CH2      H         H           H          OH          4
D75        (CH3)2CH       H         H           H          OH          4
D76        (CH3)3C        H         H           H          OH          4
D77        CH3S           H         H           H          OH          4
D78        CH3SO          H         H           H          OH          4
D79        CH3SO2         H         H           H          OH          4
D80        Ph             H         H           H          OH          4
D81        CH3O           H         H           H          OH          4
D82        CH2＝CHCH2     H         H           H          OH          4
D83        HCCCH2         H         H           H          OH          4
D84        CF3            H         H           H          OH          4
D85        PhO            H         H           H          OH          4
D86        PhS            H         H           H          OH          4
D87        PhSO           H         H           H          OH          4
D88        PhSO2          H         H           H          OH          4
D89        CH3            CH3       H           H          OH          4
基团      R88        R89        R90      R91        R87         o
D90       CH3CH2     CH3        H        H          OH          4
D91       CH3CH2CH2  CH3        H        H          OH          4
D92       (CH3)2CH   CH3        H        H          OH          4
D93       (CH3)3C    CH3        H        H          OH          4
D94       CH3S       CH3        H        H          OH          4
D95       CH3SO      CH3        H        H          OH          4
D96       CH3SO2     CH3        H        H          OH          4
D97       Ph         CH3        H        H          OH          4
D98       CH3O       CH3        H        H          OH          4
D99       CH2＝CHCH2 CH3        H        H          OH          4
D100      HCCCH2     CH3        H        H          OH          4
D101      CF3        CH3        H        H          OH          4
D102      PhO        CH3        H        H          OH          4
D103      PhS        CH3        H        H          OH          4
D104      PhSO       CH3        H        H          OH          4
D105      PhSO2      CH3        H        H          OH          4
D106      H          H          H        CH3        OH          4
D107      H          H          H        CH3        OH          3
D108      H          H          H        H          OH          1
D109      CH3        H          H        H          OH          1
D110      CH3OCO     CH3        H        H          OH          1
D111      CH3CH2OCO  CH3        H        H          OH          1
D112      CH3O       CH3        H        H          OH          1
D113      CH3S       CH3        H        H          OH          1
D114      CH3SO      CH3        H        H          OH          1
D115      CH3SO2     CH3        H        H          OH          1
D116      CH3CH2     H          H        H          OH          1
D117      CH3OCO     CH3CH2     H        H          OH          1
D118      CH3CH2OCO  CH3CH2     H        H          OH          1
D119      CH3O       CH3CH2     H        H          OH          1
D120      CH3S       CH3CH2     H        H          OH          1
D121      CH3SO      CH3CH2     H        H          OH          1
D122      CH3SO2     CH3CH2     H        H          OH          1
基团        R88        R89         R90      R91       R87      o
D123        CH3CH2S    CH3         H        H         OH       1
D124        CH3CH2SO   CH3         H        H         OH       1
D125        CH3CH2SO2  CH3         H        H         OH       1
D126        CH3CH2S    CH3CH2      H        H         OH       1
D127        CH3CH2SO   CH3CH2      H        H         OH       1
D128        CH3CH2SO2  CH3CH2      H        H         OH       1
D129        H          H           CH3      H         OH       1
D130        CH3        H           CH3      H         OH       1
D131        CH3OCO     CH3         CH3      H         OH       1
D132        CH3CH2OCO  CH3         CH3      H         OH       1
D133        CH3O       CH3         CH3      H         OH       1
D134        CH3S       CH3         CH3      H         OH       1
D135        CH3SO      CH3         CH3      H         OH       1
D136        CH3SO2     CH3         CH3      H         OH       1
D137        H          H           H        CH3       OH       1
D138        CH3        H           H        CH3       OH       1
D139        H          H           CH3      CH3       OH       1
D140        CH3CH2OCO  CH3         H        H         OH       4
表9：式If化合物：
Figure C01804089D01471
化合物.    R92        R93       R94      R95      Q3
序号
A1         H          H         H        CF3      B24
A2         CH3        H         H        CF3      B24
A3         CH3CH2     H         H        CF3      B24
化合物        R92                            R93         R94        R95       Q3
序号
A4            (CH3)2CH                       H           H          CF3       B24
A5            (CH3)3C                        H           H          CF3       B24
A6            环丙基                         H           H          CF3       B24
A7            CH3(CH2)2                      H           H          CF3       B24
A8            CH3OCH2                        H           H          CF3       B24
A9            CH3O(CH2)2                     H           H          CF3       B24
A10           Ph                             H           H          CF3       B24
A11           PhO                            H           H          CF3       B24
A12           PhS                            H           H          CF3       B24
A13           PhSO                           H           H          CF3       B24
A14           PhSO2                          H           H          CF3       B24
A15           CH3S                           H           H          CF3       B24
A16           CH3SO                          H           H          CF3       B24
A17           CF3                            H           H          CF3       B24
A18           F2CH                           H           H          CF3       B24
A19           HCC                            H           H          CF3       B24
A20           CH3CC                          H           H          CF3       B24
A21           CH2＝CH                        H           H          CF3       B24
A22           CH2＝CHCH2                     H           H          CF3       B24
A23           CH3SO2N(CH3)                   H           H          CF3       B24
A24           (CH3)2N                        H           H          CF3       B24
A25           (CH3)2NSO2                     H           H          CF3       B24
A26           ClCH2                          H           H          CF3       B24
A27           CH3SCH2                        H           H          CF3       B24
A28           CH3SOCH2                       H           H          CF3       B24
A29           CH3SO2CH2                      H           H          CF3       B24
A30           [1，2，4]-三唑-1-基-甲基       H           H          CF3       B24
A31           CH3                            CF3         H          CH3       B24
A32           CH3                            CH3         H          CF3       B24
A33           H                              H           H          CF3CF2    B24
A34           CH3                            H           H          CF3CF2    B24
A35           CH3CH2                         H           H          CF3CF2    B24
化合物    R92                          R93        R94        R95             Q3
序号
A36       环丙基                       H          H          CF3CF2          B24
A37       (CH3)3C                      H          H          CF3CF2          B24
A38       (CH3)2CH                     H          H          CF3CF2          B24
A39       CH3(CH2)2                    H          H          CF3CF2          B24
A40       CH3OCH2                      H          H          CF3CF2          B24
A41       CH3O(CH2)2                   H          H          CF3CF2          B24
A42       Ph                           H          H          CF3CF2          B24
A43       PhO                          H          H          CF3CF2          B24
A44       PhS                          H          H          CF3CF2          B24
A45       PhSO                         H          H          CF3CF2          B24
A46       PhSO2                        H          H          CF3CF2          B24
A47       CH3S                         H          H          CF3CF2          B24
A48       CH3SO                        H          H          CF3CF2          B24
A49       CF3                          H          H          CF3CF2          B24
A50       F2CH                         H          H          CF3CF2          B24
A51       HCC                          H          H          CF3CF2          B24
A52       CH3CC                        H          H          CF3CF2          B24
A53       CH2＝CH                      H          H          CF3CF2          B24
A54       CH2＝CHCH2                   H          H          CF3CF2          B24
A55       CH3SO2N(CH3)                 H          H          CF3CF2          B24
A56       (CH3)2N                      H          H          CF3CF2          B24
A57       (CH3)2NSO2                   H          H          CF3CF2          B24
A58       ClCH2                        H          H          CF3CF2          B24
A59       CH3SCH2                      H          H          CF3CF2          B24
A60       CH3SOCH2                     H          H          CF3CF2          B24
A61       CH3SO2CH2                    H          H          CF3CF2          B24
A62       [1，2，4]-三唑-1-基-甲基     H          H          CF3CF2          B24
A63       H                            H          H          CF3CF2CF2       B24
A64       CH3                          H          H          CF3CF2CF2       B24
A65       CH3CH2                       H          H          CF3CF2CF2       B24
A66       环丙基                       H          H          CF3CF2CF2       B24
A67       (CH3)3C                      H          H          CF3CF2CF2       B24
化合物    R92                         R93       R94       R95            Q3
序号
A68       (CH3)2CH                    H         H         CF3CF2CF2      B24
A69       CH3(CH2)2                   H         H         CF3CF2CF2      B24
A70       CH3OCH2                     H         H         CF3CF2CF2      B24
A71       CH3O(CH2)2                  H         H         CF3CF2CF2      B24
A72       Ph                          H         H         CF3CF2CF2      B24
A73       PhO                         H         H         CF3CF2CF2      B24
A74       PhS                         H         H         CF3CF2CF2      B24
A75       PhSO                        H         H         CF3CF2CF2      B24
A76       PhSO2                       H         H         CF3CF2CF2      B24
A77       CH3S                        H         H         CF3CF2CF2      B24
A78       CH3SO                       H         H         CF3CF2CF2      B24
A79       CF3                         H         H         CF3CF2CF2      B24
A80       F2CH                        H         H         CF3CF2CF2      B24
A81       HCC                         H         H         CF3CF2CF2      B24
A82       CH3CC                       H         H         CF3CF2CF2      B24
A83       CH2＝CH                     H         H         CF3CF2CF2      B24
A84       CH2＝CHCH2                  H         H         CF3CF2CF2      B24
A85       CH3SO2N(CH3)                H         H         CF3CF2CF2      B24
A86       (CH3)2N                     H         H         CF3CF2CF2      B24
A87       (CH3)2NSO2                  H         H         CF3CF2CF2      B24
A88       ClCH2                       H         H         CF3CF2CF2      B24
A89       CH3SCH2                     H         H         CF3CF2CF2      B24
A90       CH3SOCH2                    H         H         CF3CF2CF2      B24
A91       CH3SO2CH2                   H         H         CF3CF2CF2      B24
A92       [1，2，4]-三唑-1-基-甲基    H         H         CF3CF2CF2      B24
A93       H                           H         H         CF2Cl          B24
A94       CH3                         H         H         CF2Cl          B24
A95       CH3CH2                      H         H         CF2Cl          B24
A96       环丙基                      H         H         CF2Cl          B24
A97       (CH3)3C                     H         H         CF2Cl          B24
A98       (CH3)2CH                    H         H         CF2Cl          B24
A99       CH3(CH2)2                   H         H         CF2Cl          B24
化合物    R92                             R93       R94       R95      Q3
序号
A100      CH3OCH2                         H         H         CF2Cl    B24
A101      CH3O(CH2)2                      H         H         CF2Cl    B24
A102      Ph                              H         H         CF2Cl    B24
A103      PhO                             H         H         CF2Cl    B24
A104      PhS                             H         H         CF2Cl    B24
A105      PhSO                            H         H         CF2Cl    B24
A106      PhSO2                           H         H         CF2Cl    B24
A107      CH3S                            H         H         CF2Cl    B24
A108      CH3SO                           H         H         CF2Cl    B24
A109      CF3                             H         H         CF2Cl    B24
A110      F2CH                            H         H         CF2Cl    B24
A111      HCC                             H         H         CF2Cl    B24
A112      CH3CC                           H         H         CF2Cl    B24
A113      CH2＝CH                         H         H         CF2Cl    B24
A114      CH2＝CHCH2                      H         H         CF2Cl    B24
A115      CH3SO2N(CH3)                    H         H         CF2Cl    B24
A116      (CH3)2N                         H         H         CF2Cl    B24
A117      (CH3)2NSO2                      H         H         CF2Cl    B24
A118      ClCH2                           H         H         CF2Cl    B24
A119      CH3SCH2                         H         H         CF2Cl    B24
A120      CH3SOCH2                        H         H         CF2Cl    B24
A121      CH3SO2CH2                       H         H         CF2Cl    B24
A122      [1，2，4]-三唑-1-基-甲基        H         H         CF2Cl    B24
A123      H                               H         H         CHF2     B24
A124      CH3                             H         H         CHF2     B24
A125      CH3CH2                          H         H         CHF2     B24
A126      环丙基                          H         H         CHF2     B24
A127      (CH3)3C                         H         H         CHF2     B24
A128      (CH3)2CH                        H         H         CHF2     B24
A129      CH3(CH2)2                       H         H         CHF2     B24
A130      CH3OCH2                         H         H         CHF2     B24
A131      CH3O(CH2)2                      H         H         CHF2     B24
化合物     R92                          R93       R94        R95         Q3
序号
A132       Ph                           H         H          CHF2        B24
A133       PhO                          H         H          CHF2        B24
A134       PhS                          H         H          CHF2        B24
A135       PhSO                         H         H          CHF2        B24
A136       PhSO2                        H         H          CHF2        B24
A137       CH3S                         H         H          CHF2        B24
A138       CH3SO                        H         H          CHF2        B24
A139       CF3                          H         H          CHF2        B24
A140       F2CH                         H         H          CHF2        B24
A141       HCC                          H         H          CHF2        B24
A142       CH3CC                        H         H          CHF2        B24
A143       CH2＝CH                      H         H          CHF2        B24
A144       CH2＝CHCH2                   H         H          CHF2        B24
A145       CH3SO2N(CH3)                 H         H          CHF2        B24
A146       (CH3)2N                      H         H          CHF2        B24
A147       (CH3)2NSO2                   H         H          CHF2        B24
A148       ClCH2                        H         H          CHF2        B24
A149       CH3SCH2                      H         H          CHF2        B24
A150       CH3SOCH2                     H         H          CHF2        B24
A151       CH3SO2CH2                    H         H          CHF2        B24
A152       [1，2，4]-三唑-1-基-甲基     H         H          CHF2        B24
A153       H                            H         H          CCl3        B24
A154       CH3                          H         H          CCl3        B24
A155       CH3CH2                       H         H          CCl3        B24
A156       环丙基                       H         H          CCl3        B24
A157       (CH3)3C                      H         H          CCl3        B24
A158       (CH3)2CH                     H         H          CCl3        B24
A159       CH3(CH2)2                    H         H          CCl3        B24
A160       CH3OCH2                      H         H          CCl3        B24
A161       CH3O(CH2)2                   H         H          CCl3        B24
A162       Ph                           H         H          CCl3        B24
A163       PhO                          H         H          CCl3        B24
化合物    R92                          R93        R94       R95       Q3
序号
A164      PhS                          H          H         CCl3      B24
A165      PhSO                         H          H         CCl3      B24
A166      PhSO2                        H          H         CCl3      B24
A167      CH3S                         H          H         CCl3      B24
A168      CH3SO                        H          H         CCl3      B24
A169      CF3                          H          H         CCl3      B24
A170      F2CH                         H          H         CCl3      B24
A171      HCC                          H          H         CCl3      B24
A172      CH3CC                        H          H         CCl3      B24
A173      CH2＝CH                      H          H         CCl3      B24
A174      CH2＝CHCH2                   H          H         CCl3      B24
A175      CH3SO2N(CH3)                 H          H         CCl3      B24
A176      (CH3)2N                      H          H         CCl3      B24
A177      (CH3)2NSO2                   H          H         CCl3      B24
A178      ClCH2                        H          H         CCl3      B24
A179      CH3SCH2                      H          H         CCl3      B24
A180      CH3SOCH2                     H          H         CCl3      B24
A181      CH3SO2CH2                    H          H         CCl3      B24
A182      [1，2，4]-三唑-1-基-甲基     H          H         CCl3      B24
A183      H                            H          CH3       CF3       B24
A184      CH3                          H          CH3       CF3       B24
A185      CH3CH2                       H          CH3       CF3       B24
A186      环丙基                       H          CH3       CF3       B24
A187      (CH3)3C                      H          CH3       CF3       B24
A188      (CH3)2CH                     H          CH3       CF3       B24
A189      CH3(CH2)2                    H          CH3       CF3       B24
A190      CH3OCH2                      H          CH3       CF3       B24
A191      CH3O(CH2)2                   H          CH3       CF3       B24
A192      Ph                           H          CH3       CF3       B24
A193      PhO                          H          CH3       CF3       B24
A194      PhS                          H          CH3       CF3       B24
A195      PhSO                         H          CH3       CF3       B24
化合物     R92              R93        R94        R95        Q3
序号
A196       PhSO2            H          CH3        CF3        B24
A197       CH3S             H          CH3        CF3        B24
A198       CH3SO            H          CH3        CF3        B24
A199       CF3              H          CH3        CF3        B24
A200       F2CH             H          CH3        CF3        B24
A201       HCC              H          CH3        CF3        B24
A202       CH3CC            H          CH3        CF3        B24
A203       CH2＝CH          H          CH3        CF3        B24
A204       CH2＝CHCH2       H          CH3        CF3        B24
A205       CH3SO2N(CH3)     H          CH3        CF3        B24
A206       (CH3)2N          H          CH3        CF3        B24
A207       (CH3)2NSO2       H          CH3        CF3        B24
A208       ClCH2            H          CH3        CF3        B24
A209       CH3SCH2          H          CH3        CF3        B24
A210       CH3SOCH2         H          CH3        CF3        B24
A211       CH3SO2CH2        H          CH3        CF3        B24
A212       H                H          CH3        CF3CF2     B24
A213       CH3              H          CH3        CF3CF2     B24
A214       CH3CH2           H          CH3        CF3CF2     B24
A215       环丙基           H          CH3        CF3CF2     B24
A216       (CH3)3C          H          CH3        CF3CF2     B24
A217       (CH3)2CH         H          CH3        CF3CF2     B24
A218       CH3(CH2)2        H          CH3        CF3CF2     B24
A219       CH3OCH2          H          CH3        CF3CF2     B24
A220       CH3O(CH2)2       H          CH3        CF3CF2     B24
A221       Ph               H          CH3        CF3CF2     B24
A222       PhO              H          CH3        CF3CF2     B24
A223       PhS              H          CH3        CF3CF2     B24
A224       PhSO             H          CH3        CF3CF2     B24
A225       PhSO2            H          CH3        CF3CF2     B24
A226       CH3S             H          CH3        CF3CF2     B24
A227       CH3SO            H          CH3        CF3CF2     B24
化合物     R92                R93         R94        R95         Q3
序号
A228       CF3                H           CH3        CF3CF2      B24
A229       F2CH               H           CH3        CF3CF2      B24
A230       HCC                H           CH3        CF3CF2      B24
A231       CH3CC              H           CH3        CF3CF2      B24
A232       CH2＝CH            H           CH3        CF3CF2      B24
A233       CH2＝CHCH2         H           CH3        CF3CF2      B24
A234       CH3SO2N(CH3)       H           CH3        CF3CF2      B24
A235       (CH3)2N            H           CH3        CF3CF2      B24
A236       (CH3)2NSO2         H           CH3        CF3CF2      B24
A237       ClCH2              H           CH3        CF3CF2      B24
A238       CH3SCH2            H           CH3        CF3CF2      B24
A239       CH3SOCH2           H           CH3        CF3CF2      B24
A240       CH3SO2CH2          H           CH3        CF3CF2      B24
A241       H                  H           CH3        CF3CF2CF2   B24
A242       CH3                H           CH3        CF3CF2CF2   B24
A243       CH3CH2             H           CH3        CF3CF2CF2   B24
A244       环丙基             H           CH3        CF3CF2CF2   B24
A245       (CH3)3C            H           CH3        CF3CF2CF2   B24
A246       (CH3)2CH           H           CH3        CF3CF2CF2   B24
A247       CH3(CH2)2          H           CH3        CF3CF2CF2   B24
A248       CH3OCH2            H           CH3        CF3CF2CF2   B24
A249       CH3O(CH2)2         H           CH3        CF3CF2CF2   B24
A250       Ph                 H           CH3        CF3CF2CF2   B24
A251       PhO                H           CH3        CF3CF2CF2   B24
A252       PhS                H           CH3        CF3CF2CF2   B24
A253       PhSO               H           CH3        CF3CF2CF2   B24
A254       PhSO2              H           CH3        CF3CF2CF2   B24
A255       CH3S               H           CH3        CF3CF2CF2   B24
A256       CH3SO              H           CH3        CF3CF2CF2   B24
A257       CF3                H           CH3        CF3CF2CF2   B24
A258       F2CH               H           CH3        CF3CF2CF2   B24
A259       HCC                H           CH3        CF3CF2CF2   B24
化合物      R92             R93           R94            R95           Q3
序号
A260        CH3CC           H             CH3            CF3CF2CF2     B24
A261        CH2＝CH         H             CH3            CF3CF2CF2     B24
A262        CH2＝CHCH2      H             CH3            CF3CF2CF2     B24
A263        CH3SO2N(CH3)    H             CH3            CF3CF2CF2     B24
A264        (CH3)2N         H             CH3            CF3CF2CF2     B24
A265        (CH3)2NSO2      H             CH3            CF3CF2CF2     B24
A266        ClCH2           H             CH3            CF3CF2CF2     B24
A267        CH3SCH2         H             CH3            CF3CF2CF2     B24
A268        CH3SOCH2        H             CH3            CF3CF2CF2     B24
A269        CH3SO2CH2       H             CH3            CF3CF2CF2     B24
A270        H               H             CH3            CF2Cl         B24
A271        CH3             H             CH3            CF2Cl         B24
A272        CH3CH2          H             CH3            CF2Cl         B24
A273        环丙基          H             CH3            CF2Cl         B24
A274        (CH3)3C         H             CH3            CF2Cl         B24
A275        (CH3)2CH        H             CH3            CF2Cl         B24
A276        CH3(CH2)2       H             CH3            CF2Cl         B24
A277        CH3OCH2         H             CH3            CF2Cl         B24
A278        CH3O(CH2)2      H             CH3            CF2Cl         B24
A279        Ph              H             CH3            CF2Cl         B24
A280        PhO             H             CH3            CF2Cl         B24
A281        PhS             H             CH3            CF2Cl         B24
A282        PhSO            H             CH3            CF2Cl         B24
A283        PhSO2           H             CH3            CF2Cl         B24
A284        CH3S            H             CH3            CF2Cl         B24
A285        CH3SO           H             CH3            CF2Cl         B24
A286        CF3             H             CH3            CF2Cl         B24
A287        F2CH            H             CH3            CF2Cl         B24
A288        HCC             H             CH3            CF2Cl         B24
A289        CH3CC           H             CH3            CF2Cl         B24
A290        CH2＝CH         H             CH3            CF2Cl         B24
A291        CH2＝CHCH2      H             CH3            CF2Cl         B24
化合物    R92                    R93           R94          R95         Q3
序号
A292      CH3SO2N(CH3)           H             CH3          CF2Cl       B24
A293      (CH3)2N                H             CH3          CF2Cl       B24
A294      (CH3)2NSO2             H             CH3          CF2Cl       B24
A295      ClCH2                  H             CH3          CF2Cl       B24
A296      CH3SCH2                H             CH3          CF2Cl       B24
A297      CH3SOCH2               H             CH3          CF2Cl       B24
A298      CH3SO2CH2              H             CH3          CF2Cl       B24
A299      H                      H             CH3          CHF2        B24
A300      CH3                    H             CH3          CHF2        B24
A301      CH3CH2                 H             CH3          CHF2        B24
A302      环丙基                 H             CH3          CHF2        B24
A303      (CH3)3C                H             CH3          CHF2        B24
A304      (CH3)2CH               H             CH3          CHF2        B24
A305      CH3(CH2)2              H             CH3          CHF2        B24
A306      CH3OCH2                H             CH3          CHF2        B24
A307      CH3O(CH2)2             H             CH3          CHF2        B24
A308      Ph                     H             CH3          CHF2        B24
A309      PhO                    H             CH3          CHF2        B24
A310      PhS                    H             CH3          CHF2        B24
A311      PhSO                   H             CH3          CHF2        B24
A312      PhSO2                  H             CH3          CHF2        B24
A313      CH3S                   H             CH3          CHF2        B24
A314      CH3SO                  H             CH3          CHF2        B24
A315      CF3                    H             CH3          CHF2        B24
A316      F2CH                   H             CH3          CHF2        B24
A317      HCC                    H             CH3          CHF2        B24
A318      CH3CC                  H             CH3          CHF2        B24
A319      CH2＝CH                H             CH3          CHF2        B24
A320      CH2＝CHCH2             H             CH3          CHF2        B24
A321      CH3SO2N(CH3)           H             CH3          CHF2        B24
A322      (CH3)2N                H             CH3          CHF2        B24
A323      (CH3)2NSO2             H             CH3          CHF2        B24
化合物    R92             R93       R94         R95         Q3
序号
A324      ClCH2           H         CH3         CHF2        B24
A325      CH3SCH2         H         CH3         CHF2        B24
A326      CH3SOCH2        H         CH3         CHF2        B24
A327      CH3SO2CH2       H         CH3         CHF2        B24
A328      H               H         CH3         CCl3        B24
A329      CH3             H         CH3         CCl3        B24
A330      CH3CH2          H         CH3         CCl3        B24
A331      (CH3)3C         H         CH3         CCl3        B24
A332      (CH3)2CH        H         CH3         CCl3        B24
A333      环丙基          H         CH3         CCl3        B24
A334      CH3(CH2)2       H         CH3         CCl3        B24
A335      CH3OCH2         H         CH3         CCl3        B24
A336      CH3O(CH2)2      H         CH3         CCl3        B24
A337      Ph              H         CH3         CCl3        B24
A338      PhO             H         CH3         CCl3        B24
A339      PhS             H         CH3         CCl3        B24
A340      PhSO            H         CH3         CCl3        B24
A341      PhSO2           H         CH3         CCl3        B24
A342      CH3S            H         CH3         CCl3        B24
A343      CH3SO           H         CH3         CCl3        B24
A344      CF3             H         CH3         CCl3        B24
A345      F2CH            H         CH3         CCl3        B24
A346      HCC             H         CH3         CCl3        B24
A347      CH3CC           H         CH3         CCl3        B24
A348      CH2＝CH         H         CH3         CCl3        B24
A349      CH2＝CHCH2      H         CH3         CCl3        B24
A350      CH3SO2N(CH3)    H         CH3         CCl3        B24
A351      (CH3)2N         H         CH3         CCl3        B24
A352      (CH3)2NSO2      H         CH3         CCl3        B24
A353      ClCH2           H         CH3         CCl3        B24
A354      CH3SCH2         H         CH3         CCl3        B24
A355      CH3SOCH2        H         CH3         CCl3        B24
化合物    R92              R93        R94          R95         Q3
序号
A356      CH3SO2CH2        H          CH3          CCl3        B24
A357      H                H          Ph           CF3         B24
A358      CH3              H          Ph           CF3         B24
A359      CH3CH2           H          Ph           CF3         B24
A360      环丙基           H          Ph           CF3         B24
A361      (CH3)3C          H          Ph           CF3         B24
A362      (CH3)2CH         H          Ph           CF3         B24
A363      CH3(CH2)2        H          Ph           CF3         B24
A364      CH3OCH2          H          Ph           CF3         B24
A365      CH3O(CH2)2       H          Ph           CF3         B24
A366      Ph               H          Ph           CF3         B24
A367      PhO              H          Ph           CF3         B24
A368      PhS              H          Ph           CF3         B24
A369      PhSO             H          Ph           CF3         B24
A370      PhSO2            H          Ph           CF3         B24
A371      CH3S             H          Ph           CF3         B24
A372      CH3SO            H          Ph           CF3         B24
A373      CF3              H          Ph           CF3         B24
A374      F2CH             H          Ph           CF3         B24
A375      HCC              H          Ph           CF3         B24
A376      CH3CC            H          Ph           CF3         B24
A377      CH2＝CH          H          Ph           CF3         B24
A378      CH2＝CHCH2       H          Ph           CF3         B24
A379      CH3SO2N(CH3)     H          Ph           CF3         B24
A380      (CH3)2N          H          Ph           CF3         B24
A381      (CH3)2NSO2       H          Ph           CF3         B24
A382      ClCH2            H          Ph           CF3         B24
A383      CH3SCH2          H          Ph           CF3         B24
A384      CH3SOCH2         H          Ph           CF3         B24
A385      CH3SO2CH2        H          Ph           CF3         B24
A386      H                H          Ph           CF3CF2      B24
A387      CH3              H          Ph           CF3CF2      B24
化合物      R92            R93         R94         R95       Q3
序号
A388        CH3CH2         H           Ph          CF3CF2    B24
A389        环丙基         H           Ph          CF3CF2    B24
A390        (CH3)3C        H           Ph          CF3CF2    B24
A391        (CH3)2CH       H           Ph          CF3CF2    B24
A392        CH3(CH2)2      H           Ph          CF3CF2    B24
A393        CH3OCH2        H           Ph          CF3CF2    B24
A394        CH3O(CH2)2     H           Ph          CF3CF2    B24
A395        Ph             H           Ph          CF3CF2    B24
A396        PhO            H           Ph          CF3CF2    B24
A397        PhS            H           Ph          CF3CF2    B24
A398        PhSO           H           Ph          CF3CF2    B24
A399        PhSO2          H           Ph          CF3CF2    B24
A400        CH3S           H           Ph          CF3CF2    B24
A401        CH3SO          H           Ph          CF3CF2    B24
A402        CF3            H           Ph          CF3CF2    B24
A403        F2CH           H           Ph          CF3CF2    B24
A404        HCC            H           Ph          CF3CF2    B24
A405        CH3CC          H           Ph          CF3CF2    B24
A406        CH2＝CH        H           Ph          CF3CF2    B24
A407        CH2＝CHCH2     H           Ph          CF3CF2    B24
A408        CH3SO2N(CH3)   H           Ph          CF3CF2    B24
A409        (CH3)2N        H           Ph          CF3CF2    B24
A410        (CH3)2NSO2     H           Ph          CF3CF2    B24
A411        ClCH2          H           Ph          CF3CF2    B24
A412        CH3SCH2        H           Ph          CF3CF2    B24
A413        CH3SOCH2       H           Ph          CF3CF2    B24
A414        CH3SO2CH2      H           Ph          CF3CF2    B24
A415        H              H           Ph          CF3CF2CF2 B24
A416        CH3            H           Ph          CF3CF2CF2 B24
A417        CH3CH2         H           Ph          CF3CF2CF2 B24
A418        环丙基         H           Ph          CF3CF2CF2 B24
A419        (CH3)3C        H           Ph          CF3CF2CF2 B24
化合物       R92         R93        R94         R95        Q3
序号
A420         (CH3)2CH    H          Ph          CF3CF2CF2  B24
A421         CH3(CH2)2   H          Ph          CF3CF2CF2  B24
A422         CH3OCH2     H          Ph          CF3CF2CF2  B24
A423         CH3O(CH2)2  H          Ph          CF3CF2CF2  B24
A424         Ph          H          Ph          CF3CF2CF2  B24
A425         PhO         H          Ph          CF3CF2CF2  B24
A426         PhS         H          Ph          CF3CF2CF2  B24
A427         PhSO        H          Ph          CF3CF2CF2  B24
A428         PhSO2       H          Ph          CF3CF2CF2  B24
A429         CH3S        H          Ph          CF3CF2CF2  B24
A430         CH3SO       H          Ph          CF3CF2CF2  B24
A431         CF3         H          Ph          CF3CF2CF2  B24
A432         F2CH        H          Ph          CF3CF2CF2  B24
A433         HCC         H          Ph          CF3CF2CF2  B24
A434         CH3CC       H          Ph          CF3CF2CF2  B24
A435         CH2＝CH     H          Ph          CF3CF2CF2  B24
A436         CH2＝CHCH2  H          Ph          CF3CF2CF2  B24
A437         CH3SO2N(CH3)H          Ph          CF3CF2CF2  B24
A438         (CH3)2N     H          Ph          CF3CF2CF2  B24
A439         (CH3)2NSO2  H          Ph          CF3CF2CF2  B24
A440         ClCH2       H          Ph          CF3CF2CF2  B24
A441         CH3SCH2     H          Ph          CF3CF2CF2  B24
A442         CH3SOCH2    H          Ph          CF3CF2CF2  B24
A443         CH3SO2CH2   H          Ph          CF3CF2CF2  B24
A444         H           H          Ph          CF2Cl      B24
A445         CH3         H          Ph          CF2Cl      B24
A446         CH3CH2      H          Ph          CF2Cl      B24
A447         环丙基      H          Ph          CF2Cl      B24
A448         (CH3)3C     H          Ph          CF2Cl      B24
A449         (CH3)2CH    H          Ph          CF2Cl      B24
A450         CH3(CH2)2   H          Ph          CF2Cl      B24
A451         CH3OCH2     H          Ph          CF2Cl      B24
化合物      R92           R93        R94       R95         Q3
序号
A452        CH3O(CH2)2    H          Ph        CF2Cl       B24
A453        Ph            H          Ph        CF2Cl       B24
A454        PhO           H          Ph        CF2Cl       B24
A455        PhS           H          Ph        CF2Cl       B24
A456        PhSO          H          Ph        CF2Cl       B24
A457        PhSO2         H          Ph        CF2Cl       B24
A458        CH3S          H          Ph        CF2Cl       B24
A459        CH3SO         H          Ph        CF2Cl       B24
A460        CF3           H          Ph        CF2Cl       B24
A461        F2CH          H          Ph        CF2Cl       B24
A462        HCC           H          Ph        CF2Cl       B24
A463        CH3CC         H          Ph        CF2Cl       B24
A464        CH2＝CH       H          Ph        CF2Cl       B24
A465        CH2＝CHCH2    H          Ph        CF2Cl       B24
A466        CH3SO2N(CH3)  H          Ph        CF2Cl       B24
A467        (CH3)2N       H          Ph        CF2Cl       B24
A468        (CH3)2NSO2    H          Ph        CF2Cl       B24
A469        ClCH2         H          Ph        CF2Cl       B24
A470        CH3SCH2       H          Ph        CF2Cl       B24
A471        CH3SOCH2      H          Ph        CF2Cl       B24
A472        CH3SO2CH2     H          Ph        CF2Cl       B24
A473        H             H          Ph        CHF2        B24
A474        CH3           H          Ph        CHF2        B24
A475        CH3CH2        H          Ph        CHF2        B24
A476        环丙基        H          Ph        CHF2        B24
A477        (CH3)3C       H          Ph        CHF2        B24
A478        (CH3)2CH      H          Ph        CHF2        B24
A479        CH3(CH2)2     H          Ph        CHF2        B24
A480        CH3OCH2       H          Ph        CHF2        B24
A481        CH3O(CH2)2    H          Ph        CHF2        B24
A482        Ph            H          Ph        CHF2        B24
A483        PhO           H          Ph        CHF2        B24
化合物     R92               R93        R94        R95          Q3
序号
A484       PhS               H          Ph         CHF2         B24
A485       PhSO              H          Ph         CHF2         B24
A486       PhSO2             H          Ph         CHF2         B24
A487       CH3S              H          Ph         CHF2         B24
A488       CH3SO             H          Ph         CHF2         B24
A489       CF3               H          Ph         CHF2         B24
A490       F2CH              H          Ph         CHF2         B24
A491       HCC               H          Ph         CHF2         B24
A492       CH3CC             H          Ph         CHF2         B24
A493       CH2＝CH           H          Ph         CHF2         B24
A494       CH2＝CHCH2        H          Ph         CHF2         B24
A495       CH3SO2N(CH3)      H          Ph         CHF2         B24
A496       (CH3)2N           H          Ph         CHF2         B24
A497       (CH3)2NSO2        H          Ph         CHF2         B24
A498       ClCH2             H          Ph         CHF2         B24
A499       CH3SCH2           H          Ph         CHF2         B24
A500       CH3SOCH2          H          Ph         CHF2         B24
A501       CH3SO2CH2         H          Ph         CHF2         B24
A502       H                 H          Ph         CCl3         B24
A503       CH3               H          Ph         CCl3         B24
A504       CH3CH2            H          Ph         CCl3         B24
A505       环丙基            H          Ph         CCl3         B24
A506       (CH3)3C           H          Ph         CCl3         B24
A507       (CH3)2CH          H          Ph         CCl3         B24
A508       CH3(CH2)2         H          Ph         CCl3         B24
A509       CH3OCH2           H          Ph         CCl3         B24
A510       CH3O(CH2)2        H          Ph         CCl3         B24
A511       Ph                H          Ph         CCl3         B24
A512       PhO               H          Ph         CCl3         B24
A513       PhS               H          Ph         CCl3         B24
A514       PhSO              H          Ph         CCl3         B24
A515       PhSO2             H          Ph         CCl3         B24
化合物      R92                R93        R94        R95         Q3
序号
A516        CH3S               H          Ph         CCl3        B24
A517        CH3SO              H          Ph         CCl3        B24
A518        CF3                H          Ph         CCl3        B24
A519        F2CH               H          Ph         CCl3        B24
A520        HCC                H          Ph         CCl3        B24
A521        CH3CC              H          Ph         CCl3        B24
A522        CH2＝CH            H          Ph         CCl3        B24
A523        CH2＝CHCH2         H          Ph         CCl3        B24
A524        CH3SO2N(CH3)       H          Ph         CCl3        B24
A525        (CH3)2N            H          Ph         CCl3        B24
A526        (CH3)2NSO2         H          Ph         CCl3        B24
A527        ClCH2              H          Ph         CCl3        B24
A528        CH3SCH2            H          Ph         CCl3        B24
A529        CH3SOCH2           H          Ph         CCl3        B24
A530        CH3SO2CH2          H          Ph         CCl3        B24
A531        H                  CH3        H          CF3         B24
A532        H                  CH3CH2     H          CF3         B24
A533        H                  环丙基     H          CF3         B24
A534        H                  (CH3)3CH   H          CF3         B24
A535        H                  (CH3)2CH   H          CF3         B24
A536        H                  CH3(CH2)2  H          CF3         B24
A537        H                  CH3OCH2    H          CF3         B24
A538        H                  CH3O(CH2)2 H          CF3         B24
A539        H                  Ph         H          CF3         B24
A540        H                  PhO        H          CF3         B24
A541        H                  PhS        H          CF3         B24
A542        H                  PhSO       H          CF3         B24
A543        H                  PhSO2      H          CF3         B24
A544        H                  CH3S       H          CF3         B24
A545        H                  CH3SO      H          CF3         B24
A546        H                  CF3        H          CF3         B24
A547        H                  F2CH       H          CF3         B24
化合物    R92              R93          R94      R95     Q3
序号
A548      H                HCC          H        CF3     B24
A549      H                CH3CC        H        CF3     B24
A550      H                CH2＝CH      H        CF3     B24
A551      H                CH2＝CHCH2   H        CF3     B24
A552      H                CH3SO2N(CH3) H        CF3     B24
A553      H                (CH3)2N      H        CF3     B24
A554      H                (CH3)2NSO2   H        CF3     B24
A555      H                CH3SCH2      H        CF3     B24
A556      H                CH3SOCH2     H        CF3     B24
A557      H                CH3SO2CH2    H        CF3     B24
A558      H                CH3          H        CF3CF2  B24
A559      H                CH3CH2       H        CF3CF2  B24
A560      H                环丙基       H        CF3CF2  B24
A561      H                (CH3)3C      H        CF3CF2  B24
A562      H                (CH3)2CH     H        CF3CF2  B24
A563      H                CH3(CH2)2    H        CF3CF2  B24
A564      H                CH3OCH2      H        CF3CF2  B24
A565      H                CH3O(CH2)2   H        CF3CF2  B24
A566      H                Ph           H        CF3CF2  B24
A567      H                PhO          H        CF3CF2  B24
A568      H                PhS          H        CF3CF2  B24
A569      H                PhSO         H        CF3CF2  B24
A570      H                PhSO2        H        CF3CF2  B24
A571      H                CH3S         H        CF3CF2  B24
A572      H                CH3SO        H        CF3CF2  B24
A573      H                CF3          H        CF3CF2  B24
A574      H                F2CH         H        CF3CF2  B24
A575      H                HCC          H        CF3CF2  B24
A576      H                CH3CC        H        CF3CF2  B24
A577      H                CH2＝CH      H        CF3CF2  B24
A578      H                CH2＝CHCH2   H        CF3CF2  B24
A579      H                CH3SO2N(CH3) H        CF3CF2  B24
化合物    R92           R93         R94        R95        Q3
序号
A580      H             (CH3)2N     H          CF3CF2     B24
A581      H             (CH3)2NSO2  H          CF3CF2     B24
A582      H             CH3SCH2     H          CF3CF2     B24
A583      H             CH3SOCH2    H          CF3CF2     B24
A584      H             CH3SO2CH2   H          CF3CF2     B24
A585      H             CH3         H          CF3CF2CF2  B24
A586      H             CH3CH2      H          CF3CF2CF2  B24
A587      H             环丙基      H          CF3CF2CF2  B24
A588      H             (CH3)3C     H          CF3CF2CF2  B24
A589      H             (CH3)2CH    H          CF3CF2CF2  B24
A590      H             CH3(CH2)2   H          CF3CF2CF2  B24
A591      H             CH3OCH2     H          CF3CF2CF2  B24
A592      H             CH3O(CH2)2  H          CF3CF2CF2  B24
A593      H             Ph          H          CF3CF2CF2  B24
A594      H             PhO         H          CF3CF2CF2  B24
A595      H             PhS         H          CF3CF2CF2  B24
A596      H             PhSO        H          CF3CF2CF2  B24
A597      H             PhSO2       H          CF3CF2CF2  B24
A598      H             CH3S        H          CF3CF2CF2  B24
A599      H             CH3SO       H          CF3CF2CF2  B24
A600      H             CF3         H          CF3CF2CF2  B24
A601      H             F2CH        H          CF3CF2CF2  B24
A602      H             HCC         H          CF3CF2CF2  B24
A603      H             CH3CC       H          CF3CF2CF2  B24
A604      H             CH2＝CH     H          CF3CF2CF2  B24
A605      H             CH2＝CHCH2  H          CF3CF2CF2  B24
A606      H             CH3SO2N(CH3)H          CF3CF2CF2  B24
A607      H             (CH3)2N     H          CF3CF2CF2  B24
A608      H             (CH3)2NSO2  H          CF3CF2CF2  B24
A609      H             CH3SCH2     H          CF3CF2CF2  B24
A610      H             CH3SOCH2    H          CF3CF2CF2  B24
A611      H             CH3SO2CH2   H          CF3CF2CF2  B24
化合物     R92       R93               R94        R95      Q3
序号
A612       H         CH3               H          CF2Cl    B24
A613       H         CH3CH2            H          CF2Cl    B24
A614       H         环丙基            H          CF2Cl    B24
A615       H         (CH3)3C           H          CF2Cl    B24
A616       H         (CH3)2CH          H          CF2Cl    B24
A617       H         CH3(CH2)2         H          CF2Cl    B24
A618       H         CH3OCH2           H          CF2Cl    B24
A619       H         CH3O(CH2)2        H          CF2Cl    B24
A620       H         Ph                H          CF2Cl    B24
A621       H         PhO               H          CF2Cl    B24
A622       H         PhS               H          CF2Cl    B24
A623       H         PhSO              H          CF2Cl    B24
A624       H         PhSO2             H          CF2Cl    B24
A625       H         CH3S              H          CF2Cl    B24
A626       H         CH3SO             H          CF2Cl    B24
A627       H         CF3               H          CF2Cl    B24
A628       H         F2CH              H          CF2Cl    B24
A629       H         HCC               H          CF2Cl    B24
A630       H         CH3CC             H          CF2Cl    B24
A631       H         CH2＝CH           H          CF2Cl    B24
A632       H         CH2＝CHCH2        H          CF2Cl    B24
A633       H         CH3SO2N(CH3)      H          CF2Cl    B24
A634       H         (CH3)2N           H          CF2Cl    B24
A635       H         (CH3)2NSO2        H          CF2Cl    B24
A636       H         CH3SCH2           H          CF2Cl    B24
A637       H         CH3SOCH2          H          CF2Cl    B24
A638       H         CH3SO2CH2         H          CF2Cl    B24
A639       H         CH3               H          CHF2     B24
A640       H         CH3CH2            H          CHF2     B24
A641       H         环丙基            H          CHF2     B24
A642       H         (CH3)3C           H          CHF2     B24
A643       H         (CH3)2CH          H          CHF2     B24
化合物     R92     R93               R94       R95        Q3
序号
A644       H       CH3(CH2)2         H         CHF2       B24
A645       H       CH3OCH2           H         CHF2       B24
A646       H       CH3O(CH2)2        H         CHF2       B24
A647       H       Ph                H         CHF2       B24
A648       H       PhO               H         CHF2       B24
A649       H       PhS               H         CHF2       B24
A650       H       PhSO              H         CHF2       B24
A651       H       PhSO2             H         CHF2       B24
A652       H       CH3S              H         CHF2       B24
A653       H       CH3SO             H         CHF2       B24
A654       H       CF3               H         CHF2       B24
A655       H       F2CH              H         CHF2       B24
A656       H       HCC               H         CHF2       B24
A657       H       CH3CC             H         CHF2       B24
A658       H       CH2＝CH           H         CHF2       B24
A659       H       CH2＝CHCH2        H         CHF2       B24
A660       H       CH3SO2N(CH3)      H         CHF2       B24
A661       H       (CH3)2N           H         CHF2       B24
A662       H       (CH3)2NSO2        H         CHF2       B24
A663       H       CH3SCH2           H         CHF2       B24
A664       H       CH3SOCH2          H         CHF2       B24
A665       H       CH3SO2CH2         H         CHF2       B24
A666       H       CH3               H         CCl3       B24
A667       H       CH3CH2            H         CCl3       B24
A668       H       环丙基            H         CCl3       B24
A669       H       (CH3)3C           H         CCl3       B24
A670       H       (CH3)2CH          H         CCl3       B24
A671       H       CH3(CH2)2         H         CCl3       B24
A672       H       CH3OCH2           H         CCl3       B24
A673       H       CH3O(CH2)2        H         CCl3       B24
A674       H       Ph                H         CCl3       B24
A675       H       PhO               H         CCl3       B24
化合物      R92      R93               R94        R95         Q3
序号
A676        H        PhS               H          CCl3        B24
A677        H        PhSO              H          CCl3        B24
A678        H        PhSO2             H          CCl3        B24
A679        H        CH3S              H          CCl3        B24
A680        H        CH3SO             H          CCl3        B24
A681        H        CF3               H          CCl3        B24
A682        H        F2CH              H          CCl3        B24
A683        H        HCC               H          CCl3        B24
A684        H        CH3CC             H          CCl        B24
A685        H        CH2＝CH           H          CCl3        B24
A686        H        CH2＝CHCH2        H          CCl3        B24
A687        H        CH3SO2N(CH3)      H          CCl3        B24
A688        H        (CH3)2N           H          CCl3        B24
A689        H        (CH3)2NSO2        H          CCl3        B24
A690        H        CH3SCH2           H          CCl3        B24
A691        H        CH3SOCH2          H          CCl3        B24
A692        H        CH3SO2CH2         H          CCl3        B24
A693        H        CH3               CH3        CF3         B24
A694        H        CH3CH2            CH3        CF3         B24
A695        H        环丙基            CH3        CF3         B24
A696        H        (CH3)3C           CH3        CF3         B24
A697        H        (CH3)2CH          CH3        CF3         B24
A698        H        CH3(CH2)2         CH3        CF3         B24
A699        H        CH3OCH2           CH3        CF3         B24
A700        H        CH3O(CH2)2        CH3        CF3         B24
A701        H        Ph                CH3        CF3         B24
A702        H        PhO               CH3        CF3         B24
A703        H        PhS               CH3        CF3         B24
A704        H        PhSO              CH3        CF3         B24
A705        H        PhSO2             CH3        CF3         B24
A706        H        CH3S              CH3        CF3         B24
A707        H        CH3SO             CH3        CF3         B24
化合物      R92     R93            R94       R95       Q3
序号
A708        H       CF3            CH3       CF3       B24
A709        H       F2CH           CH3       CF3       B24
A710        H       HCC            CH3       CF3       B24
A711        H       CH3CC          CH3       CF3       B24
A712        H       CH2＝CH        CH3       CF3       B24
A713        H       CH2＝CHCH2     CH3       CF3       B24
A714        H       CH3SO2N(CH3)   CF3       CF3       B24
A715        H       (CH3)2N        CH3       CF3       B24
A716        H       (CH3)2NSO2     CH3       CF3       B24
A717        H       CH3SCH2        CH3       CF3       B24
A718        H       CH3SOCH2       CH3       CF3       B24
A719        H       CH3SO2CH2      CH3       CF3       B24
A720        H       CH3            CH3       CF3CF2    B24
A721        H       CH3CH2         CH3       CF3CF2    B24
A722        H       环丙基         CH3       CF3CF2    B24
A723        H       (CH3)3C        CH3       CF3CF2    B24
A724        H       (CH3)2CH       CH3       CF3CF2    B24
A725        H       CH3(CH2)2      CH3       CF3CF2    B24
A726        H       CH3OCH2        CH3       CF3CF2    B24
A727        H       CH3O(CH2)2     CH3       CF3CF2    B24
A728        H       Ph             CH3       CF3CF2    B24
A729        H       PhO            CH3       CF3CF2    B24
A730        H       PhS            CH3       CF3CF2    B24
A731        H       PhSO           CH3       CF3CF2    B24
A732        H       PhSO2          CH3       CF3CF2    B24
A733        H       CH3S           CH3       CF3CF2    B24
A734        H       CH3SO          CH3       CF3CF2    B24
A735        H       CF3            CH3       CF3CF2    B24
A736        H       F2CH           CH3       CF3CF2    B24
A737        H       HCC            CH3       CF3CF2    B24
A738        H       CH3CC          CH3       CF3CF2    B24
A739        H       CH2＝CH        CH3       CF3CF2    B24
化合物       R92     R93             R94        R95         Q3
序号
A740         H       CH2＝CHCH2      CH3        CF3CF2      B24
A741         H       CH3SO2N(CH3)    CH3        CF3CF2      B24
A742         H       (CH3)2N         CH3        CF3CF2      B24
A743         H       (CH3)2NSO2      CH3        CF3CF2      B24
A744         H       CH3SCH2         CH3        CF3CF2      B24
A745         H       CH3SOCH2        CH3        CF3CF2      B24
A746         H       CH3SO2CH2       CH3        CF3CF2      B24
A747         H       CH3             CH3        CF3CF2CF2   B24
A748         H       CH3CH2          CH3        CF3CF2CF2   B24
A749         H       环丙基          CH3        CF3CF2CF2   B24
A750         H       (CH3)3C         CH3        CF3CF2CF2   B24
A751         H       (CH3)2CH        CH3        CF3CF2CF2   B24
A752         H       CH3(CH2)2       CH3        CF3CF2CF2   B24
A753         H       CH3OCH2         CH3        CF3CF2CF2   B24
A754         H       CH3O(CH2)2      CH3        CF3CF2CF2   B24
A755         H       Ph              CH3        CF3CF2CF2   B24
A756         H       PhO             CH3        CF3CF2CF2   B24
A757         H       PhS             CH3        CF3CF2CF2   B24
A758         H       PhSO            CH3        CF3CF2CF2   B24
A759         H       PhSO2           CH3        CF3CF2CF2   B24
A760         H       CH3S            CH3        CF3CF2CF2   B24
A761         H       CH3SO           CH3        CF3CF2CF2   B24
A762         H       CF3             CH3        CF3CF2CF2   B24
A763         H       F2CH            CH3        CF3CF2CF2   B24
A764         H       HCC             CH3        CF3CF2CF2   B24
A765         H       CH3CC           CH3        CF3CF2CF2   B24
A766         H       CH2＝CH         CH3        CF3CF2CF2   B24
A767         H       CH2＝CHCH2      CH3        CF3CF2CF2   B24
A768         H       CH3SO2N(CH3)    CH3        CF3CF2CF2   B24
A769         H       (CH3)2N         CH3        CF3CF2CF2   B24
A770         H       (CH3)2NSO2      CH3        CF3CF2CF2   B24
A771         H       CH3SCH2         CH3        CF3CF2CF2   B24
化合物    R92      R93               R94        R95      Q3
序号
A772      H        CH3SOCH2          CH3        CF3CF2CF2B24
A773      H        CH3SO2CH2         CH3        CF3CF2CF2B24
A774      H        CH3               CH3        CF2Cl    B24
A775      H        CH3CH2            CH3        CF2Cl    B24
A776      H        环丙基            CH3        CF2Cl    B24
A777      H        (CH3)3C           CH3        CF2Cl    B24
A778      H        (CH3)2CH          CH3        CF2Cl    B24
A779      H        CH3(CH2)2         CH3        CF2Cl    B24
A780      H        CH3OCH2           CH3        CF2Cl    B24
A781      H        CH3O(CH2)2        CH3        CF2Cl    B24
A782      H        Ph                CH3        CF2Cl    B24
A783      H        PhO               CH3        CF2Cl    B24
A784      H        PhS               CH3        CF2Cl    B24
A785      H        PhSO              CH3        CF2Cl    B24
A786      H        PhSO2             CH3        CF2Cl    B24
A787      H        CH3S              CH3        CF2Cl    B24
A788      H        CH3SO             CH3        CF2Cl    B24
A789      H        CF3               CH3        CF2Cl    B24
A790      H        F2CH              CH3        CF2Cl    B24
A791      H        HCC               CH3        CF2Cl    B24
A792      H        CH3CC             CH3        CF2Cl    B24
A793      H        CH2＝CH           CH3        CF2Cl    B24
A794      H        CH2＝CHCH2        CH3        CF2Cl    B24
A795      H        CH3SO2N(CH3)      CH3        CF2Cl    B24
A796      H        (CH3)2N           CH3        CF2Cl    B24
A797      H        (CH3)2NSO2        CH3        CF2Cl    B24
A798      H        CH3SCH2           CH3        CF2Cl    B24
A799      H        CH3SOCH2          CH3        CF2Cl    B24
A800      H        CH3SO2CH2         CH3        CF2Cl    B24
A801      H        CH3               CH3        CHF2     B24
A802      H        CH3CH2            CH3        CHF2     B24
A803      H        环丙基            CH3        CHF2     B24
化合物       R92     R93                R94          R95          Q3
序号
A804         H       (CH3)3C            CH3          CHF2         B24
A805         H       (CH3)2CH           CH3          CHF2         B24
A806         H       CH3(CH2)2          CH3          CHF2         B24
A807         H       CH3OCH2            CH3          CHF2         B24
A808         H       CH3O(CH2)2         CH3          CHF2         B24
A809         H       Ph                 CH3          CHF2         B24
A810         H       PhO                CH3          CHF2         B24
A811         H       PhS                CH3          CHF2         B24
A812         H       PhSO               CH3          CHF2         B24
A813         H       PhSO2              CH3          CHF2         B24
A814         H       CH3S               CH3          CHF2         B24
A815         H       CH3SO              CH3          CHF2         B24
A816         H       CF3                CH3          CHF2         B24
A817         H       F2CH               CH3          CHF2         B24
A818         H       HCC                CH3          CHF2         B24
A819         H       CH3CC              CH3          CHF2         B24
A820         H       CH2＝CH            CH3          CHF2         B24
A821         H       CH2＝CHCH2         CH3          CHF2         B24
A822         H       CH3SO2N(CH3)       CH3          CHF2         B24
A823         H       (CH3)2N            CH3          CHF2         B24
A824         H       (CH3)2NSO2         CH3          CHF2         B24
A825         H       CH3SCH2            CH3          CHF2         B24
A826         H       CH3SOCH2           CH3          CHF2         B24
A827         H       CH3SO2CH2          CH3          CHF2         B24
A828         H       CH3                CH3          CCl3         B24
A829         H       CH3CH2             CH3          CCl3         B24
A830         H       环丙基             CH3          CCl3         B24
A831         H       (CH3)3C            CH3          CCl3         B24
A832         H       (CH3)2CH           CH3          CCl3         B24
A833         H       CH3(CH2)2          CH3          CCl3         B24
A834         H       CH3OCH2            CH3          CCl3         B24
A835         H       CH3O(CH2)2         CH3          CCl3         B24
化合物    R92     R93             R94       R95          Q3
序号
A836      H       Ph              CH3       CCl3         B24
A837      H       PhO             CH3       CCl3         B24
A838      H       PhS             CH3       CCl3         B24
A839      H       PhSO            CH3       CCl3         B24
A840      H       PhSO2           CH3       CCl3         B24
A841      H       CH3S            CH3       CCl3         B24
A842      H       CH3SO           CH3       CCl3         B24
A843      H       CF3             CH3       CCl3         B24
A844      H       F2CH            CH3       CCl3         B24
A845      H       HCC             CH3       CCl3         B24
A846      H       CH3CC           CH3       CCl3         B24
A847      H       CH2＝CH         CH3       CCl3         B24
A848      H       CH2＝CHCH2      CH3       CCl3         B24
A849      H       CH3SO2N(CH3)    CH3       CCl3         B24
A850      H       (CH3)2N         CH3       CCl3         B24
A851      H       (CH3)2NSO2      CH3       CCl3         B24
A852      H       CH3SCH2         CH3       CCl3         B24
A853      H       CH3SOCH2        CH3       CCl3         B24
A854      H       CH3SO2CH2       CH3       CCl3         B24
A855      H       CH3             Ph        CF3          B24
A856      H       CH3CH2          Ph        CF3          B24
A857      H       (CH3)2CH        Ph        CF3          B24
A858      H       (CH3)2CH        Ph        CF3          B24
A859      H       环丙基          Ph        CF3          B24
A860      H       CH3(CH2)2       Ph        CF3          B24
A861      H       CH3OCH2         Ph        CF3          B24
A862      H       CH3O(CH2)2      Ph        CF3          B24
A863      H       Ph              Ph        CF3          B24
A864      H       PhO             Ph        CF3          B24
A865      H       PhS             Ph        CF3          B24
A866      H       PhSO            Ph        CF3          B24
A867      H       PhSO2           Ph        CF3          B24
化合物       R92      R93            R94       R95      Q3
序号
A868         H        CH3S           Ph        CF3      B24
A869         H        CH3SO          Ph        CF3      B24
A870         H        CF3            Ph        CF3      B24
A871         H        F2CH           Ph        CF3      B24
A872         H        HCC            Ph        CF3      B24
A873         H        CH3CC          Ph        CF3      B24
A874         H        CH2＝CH        Ph        CF3      B24
A875         H        CH2＝CHCH2     Ph        CF3      B24
A876         H        CH3SO2N(CH3)   Ph        CF3      B24
A877         H        (CH3)2N        Ph        CF3      B24
A878         H        (CH3)2NSO2     Ph        CF3      B24
A879         H        CH3SCH2        Ph        CF3      B24
A880         H        CH3SOCH2       Ph        CF3      B24
A881         H        CH3SO2CH2      Ph        CF3      B24
A882         H        CH3            Ph        CF3CF2   B24
A883         H        CH3CH2         Ph        CF3CF2   B24
A884         H        环丙基         Ph        CF3CF2   B24
A885         H        (CH3)3C        Ph        CF3CF2   B24
A886         H        (CH3)2CH       Ph        CF3CF2   B24
A887         H        CH3(CH2)2      Ph        CF3CF2   B24
A888         H        CH3OCH2        Ph        CF3CF2   B24
A889         H        CH3O(CH2)2     Ph        CF3CF2   B24
A890         H        Ph             Ph        CF3CF2   B24
A891         H        PhO            Ph        CF3CF2   B24
A892         H        PhS            Ph        CF3CF2   B24
A893         H        PhSO           Ph        CF3CF2   B24
A894         H        PhSO2          Ph        CF3CF2   B24
A895         H        CH3S           Ph        CF3CF2   B24
A896         H        CH3SO          Ph        CF3CF2   B24
A897         H        CF3            Ph        CF3CF2   B24
A898         H        F2CH           Ph        CF3CF2   B24
A899         H        HCC            Ph        CF3CF2   B24
化合物     R92        R93             R94           R95          Q3
序号
A900       H          CH3CC           Ph            CF3CF2       B24
A901       H          CH2＝CH         Ph            CF3CF2       B24
A902       H          CH2＝CHCH2      Ph            CF3CF2       B24
A903       H          CH3SO2N(CH3)    Ph            CF3CF2       B24
A904       H          (CH3)2N         Ph            CF3CF2       B24
A905       H          (CH3)2NSO2      Ph            CF3CF2       B24
A906       H          CH3SCH2         Ph            CF3CF2       B24
A907       H          CH3SOCH2        Ph            CF3CF2       B24
A908       H          CH3SO2CH2       Ph            CF3CF2       B24
A909       H          CH3             Ph            CF3CF2CF2    B24
A910       H          CH3CH2          Ph            CF3CF2CF2    B24
A911       H          环丙基          Ph            CF3CF2CF2    B24
A912       H          (CH3)3C         Ph            CF3CF2CF2    B24
A913       H          (CH3)2CH        Ph            CF3CF2CF2    B24
A914       H          CH3(CH2)2       Ph            CF3CF2CF2    B24
A915       H          CH3OCH2         Ph            CF3CF2CF2    B24
A916       H          CH3O(CH2)2      Ph            CF3CF2CF2    B24
A917       H          Ph              Ph            CF3CF2CF2    B24
A918       H          PhO             Ph            CF3CF2CF2    B24
A919       H          PhS             Ph            CF3CF2CF2    B24
A920       H          PhSO            Ph            CF3CF2CF2    B24
A921       H          PhSO2           Ph            CF3CF2CF2    B24
A922       H          CH3S            Ph            CF3CF2CF2    B24
A923       H          CH3SO           Ph            CF3CF2CF2    B24
A924       H          CF3             Ph            CF3CF2CF2    B24
A925       H          F2CH            Ph            CF3CF2CF2    B24
A926       H          HCC             Ph            CF3CF2CF2    B24
A927       H          CH3CC           Ph            CF3CF2CF2    B24
A928       H          CH2＝CH         Ph            CF3CF2CF2    B24
A929       H          CH2＝CHCH2      Ph            CF3CF2CF2    B24
A930       H          CH3SO2N(CH3)    Ph            CF3CF2CF2    B24
A931       H          (CH3)2N         Ph            CF3CF2CF2    B24
化合物     R92        R93           R94         R95        Q3
序号
A932       H          (CH3)2NSO2    Ph          CF3CF2CF2  B24
A933       H          CH3SCH2       Ph          CF3CF2CF2  B24
A934       H          CH3SOCH2      Ph          CF3CF2CF2  B24
A935       H          CH3SO2CH2     Ph          CF3CF2CF2  B24
A936       H          CH3           Ph          CF2Cl      B24
A937       H          CH3CH2        Ph          CF2Cl      B24
A938       H          环丙基        Ph          CF2Cl      B24
A939       H          (CH3)3C       Ph          CF2Cl      B24
A940       H          (CH3)2CH      Ph          CF2Cl      B24
A941       H          CH3(CH2)2     Ph          CF2Cl      B24
A942       H          CH3OCH2       Ph          CF2Cl      B24
A943       H          CH3O(CH2)2    Ph          CF2Cl      B24
A944       H          Ph            Ph          CF2Cl      B24
A945       H          PhO           Ph          CF2Cl      B24
A946       H          PhS           Ph          CF2Cl      B24
A947       H          PhSO          Ph          CF2Cl      B24
A948       H          PhSO2         Ph          CF2Cl      B24
A949       H          CH3S          Ph          CF2Cl      B24
A950       H          CH3SO         Ph          CF2Cl      B24
A951       H          CF3           Ph          CF2Cl      B24
A952       H          F2CH          Ph          CF2Cl      B24
A953       H          HCC           Ph          CF2Cl      B24
A954       H          CH3CC         Ph          CF2Cl      B24
A955       H          CH2＝CH       Ph          CF2Cl      B24
A956       H          CH2＝CHCH2    Ph          CF2Cl      B24
A957       H          CH3SO2N(CH3)  Ph          CF2Cl      B24
A958       H          (CH3)2N       Ph          CF2Cl      B24
A959       H          (CH3)2NSO2    Ph          CF2Cl      B24
A960       H          CH3SCH2       Ph          CF2Cl      B24
A961       H          CH3SOCH2      Ph          CF2Cl      B24
A962       H          CH3SO2CH2     Ph          CF2Cl      B24
A963       H          CH3           Ph          CHF2       B24
化合物     R92          R93         R94        R95       Q3
序号
A964       H            CH3CH2      Ph         CHF2      B24
A965       H            (CH3)3C     Ph         CHF2      B24
A966       H            (CH3)2CH    Ph         CHF2      B24
A967       H            环丙基      Ph         CHF2      B24
A968       H            CH3(CH2)2   Ph         CHF2      B24
A969       H            CH3OCH2     Ph         CHF2      B24
A970       H            CH3O(CH2)2  Ph         CHF2     B24
A971       H            Ph          Ph         CHF2      B24
A972       H            PhO         Ph         CHF2      B24
A973       H            PhS         Ph         CHF2      B24
A974       H            PhSO        Ph         CHF2      B24
A975       H            PhSO2       Ph         CHF2      B24
A976       H            CH3S        Ph         CHF2      B24
A977       H            CH3SO       Ph         CHF2      B24
A978       H            CF3         Ph         CHF2      B24
A979       H            F2CH        Ph         CHF2      B24
A980       H            HCC         Ph         CHF2      B24
A981       H            CH3CC       Ph         CHF2      B24
A982       H            CH2＝CH     Ph         CHF2      B24
A983       H            CH2＝CHCH2  Ph         CHF2      B24
A984       H            CH3SO2N(CH3)Ph         CHF2      B24
A985       H            (CH3)2N     Ph         CHF2      B24
A986       H            (CH3)2NSO2  Ph         CHF2      B24
A987       H            CH3SCH2     Ph         CHF2      B24
A988       H            CH3SOCH2    Ph         CHF2      B24
A989       H            CH3SO2CH2   Ph         CHF2      B24
A990       H            CH3         Ph         CCl3      B24
A991       H            CH3CH2      Ph         CCl3      B24
A992       H            (CH3)3C     Ph         CCl3      B24
A993       H            (CH3)2CH    Ph         CCl3      B24
A994       H            环丙基      Ph         CCl3      B24
A995       H            CH3(CH2)2   Ph         CCl3      B24
化合物      R92          R93             R94       R95        Q3
序号
A996        H            CH3OCH2         Ph        CCl3       B24
A997        H            CH3O(CH2)2      Ph        CCl3       B24
A998        H            Ph              Ph        CCl3       B24
A999        H            PhO             Ph        CCl3       B24
A1000       H            PhS             Ph        CCl3       B24
A1001       H            PhSO            Ph        CCl3       B24
A1002       H            PhSO2           Ph        CCl3       B24
A1003       H            CH3S            Ph        CCl3       B24
A1004       H            CH3SO           Ph        CCl3       B24
A1005       H            CF3             Ph        CCl3       B24
A1006       H            F2CH            Ph        CCl3       B24
A1007       H            HCC             Ph        CCl3       B24
A1008       H            CH3CC           Ph        CCl3       B24
A1009       H            CH2＝CH         Ph        CCl3       B24
A1010       H            CH2＝CHCH2      Ph        CCl3       B24
A1011       H            CH3SO2N(CH3)    Ph        CCl3       B24
A1012       H            (CH3)2N         Ph        CCl3       B24
A1013       H            (CH3)2NSO2      Ph        CCl3       B24
A1014       H            CH3SCH2         Ph        CCl3       B24
A1015       H            CH3SOCH2        Ph        CCl3       B24
A1016       H            CH3SO2CH2       Ph        CCl3       B24
A1017       F            H               H         CF3        B24
A1018       Cl           H               H         CF3        B24
A1019       Br           H               H         CF3        B24
A1020       CN           H               H         CF3        B24
A1021       CH3SO2O      H               H         CF3        B24
A1022       CH3O         H               H         CF3        B24
A1023       CH2CH3O      H               H         CF3        B24
A1024       CH2CH＝CH2O  H               H         CF3        B24
A1025       HCCCH2O      H               H         CF3        B24
A1026       S-苄基       H               H         CF3        B24
A1027       SO2-苄基     H               H         CF3        B24
化合物     R92         R93        R94          R95        Q3
序号
A1028      ClCH2       H          H            CF3        B24
A1029      BrCH2       H          H            CF3        B24
A1030      FCH2        H          H            CF3        B24
A1031      CHF2CH2     H          H            CF3        B24
A1032      CF3CH2      H          H            CF3        B24
A1033      三唑基甲基  H          H            CF3        B24
A1034      CHCl2CH2    H          H            CF3        B24
A1035      ClCH＝CH    H          H            CF3        B24
A1036      Cl2C＝CH    H          H            CF3        B24
A1037      CF3CH＝CH   H          H            CF3        B24
A1038      ClCC        H          H            CF3        B24
A1039      Ph          H          H            CF3        B24
A1040      CH3         CH3        H            CF3        B24
A1041      CH3         OH         H            CF3        B24
A1042      CH3         F          H            CF3        B24
A1043      CH3         Cl         H            CF3        B24
A1044      F           CH3        H            CF3        B24
A1045      Cl          CH3        H            CF3        B24
A1046      H           F          H            CF3        B24
A1047      H           Cl         H            CF3        B24
A1048      H           Br         H            CF3        B24
A1049      H           OH         H            CF3        B24
A1050      H           OCH3       H            CF3        B24
A1051      H           OCHF2      H            CF3        B24
A1052      H           OSO2CH3    H            CF3        B24
A1053      H           OSO2CF3    H            CF3        B24
A1054      H           ClCH2      H            CF3        B24
A1055      H           BrCH2      H            CF3        B24
A1056      H           FCH2       H            CF3        B24
A1057      H           CHF2CH2    H            CF3        B24
A1058      H           CF3CH2     H            CF3        B24
A1059      H           三唑基甲基 H            CF3        B24
化合物      R92       R93        R94        R95        Q3
序号
A1060       H         CHCl2CH2   H          CF3        B24
A1061       H         ClCH＝CH   H          CF3        B24
A1062       H         Cl2C＝CH   H          CF3        B24
A1063       H         CF3CH＝CH  H          CF3        B24
A1064       H         ClCC       H          CF3        B24
A1065       H         CH3C(O)    H          CF3        B24
A1066       H         苯基       H          CF3        B24
A1067       H         SO2CH3     H          CF3        B24
A1068       H         SO2CF3     H          CF3        B24
A1069       H         CN         H          CF3        B24
A1070       H         NO2        H          CF3        B24
A1071       CH3       H          F          CF3        B24
A1072       CH3       H          Cl         CF3        B24
A1073       CH3       H          Br         CF3        B24
A1074       CH3       H          CN         CF3        B24
A1075       CH3       H          CH3O       CF3        B24
A1076       CH3       H          CH3S       CF3        B24
A1077       CH3       H          CH3SO      CF3        B24
A1078       CH3       H          CH3SO2     CF3        B24
表9a：式Ig化合物：
Figure C01804089D01811
Q 3     Q 3     Q 3     Q 3     Q 3     Q 3      Q 3     Q 3     Q 3     Q 3     Q 3     Q 3
B1    B2    B3    B4    B5    B6     B7    B8    B9    B10   B11   B12
B13   B14   B15   B16   B17   B18    B19   B20   B21   B22   B23   B24
B25   B26   B27   B28   B29   B30    B31   B32   B33   B34   B35   B36
B37   B38   B39   B40   B41   B42    B43   B44   B45   B46   B47   B48
Q 3     Q 3     Q 3     Q 3     Q 3     Q 3     Q 3     Q 3     Q 3     Q 3     Q 3     Q 3
B49   B50   B51   B52   B53   B54   B55   B56   B57   B58   B59   B60
B61   B62   B63   B64   B65   B66   B67   B68   B69   B70   B71   B72
B73   B74   B75   B76   B77   B78   B79   B80   B81   B82   B83   B84
B85   B86   B87   B88   B89   B90   B91   B92   B93   B94   B95   B96
B97   B98   B99   B100  B101  B102  B103  B104  B105  B106  B107  B108
B109  B110  B111  B112  B113  B114  B115  B116  B117  B118  B119  B120
B121  B122  B123  B124  B125  B126  B127  B128  B129  B130  B131  B132
B133  B134  B135  B136  B137  B138  B139  B140  B141  B142  B143  B144
B145  B146  B147  B148  B149  B150  B151  B152  B153  B154  B155  B156
B157  B158  B159  B160  B161  B162  B163  B164  B165  B166  B167  B168
B169  B170  B171  B172  B173  B174  B175  B176  B177  B178  B179  B180
B181  B182  B183  B184  B185  B186  B187  B188  B189  B190  B191  B192
B193  B194  B195  B196  B197  B198  B199  B200  B201  B202  B203  B204
B205  B206  B207  B208  B209  B210  B211  B212  B213  B214  B215  B216
B217  B218  B219  B220  B221  B222  B223  B224  B225  B226  B227  B228
B229  B230  B231  B232  B233  B234  B235  B236  B237  B238  B239  B240
B241  B242  B243  B244  B245  B246  B247  B248  B249  B250  B251  B252
B253  B254  B255  B256  B257  B258  B259  B260  B261  B262  B263  B264
B265  B266  B267  B268  B269  B270  B271  B272  B273  B274  B275  B276
B277  B278  B279  B280  B281  B282  B283  B284  B285  B286  B287  B288
B289  B290  B291  B292  B293  B294  B295  B296  B297  B298  B299  B300
B301  B302  B303  B304  B305  B306  B307  B308  B309  B310  B311  B312
B313  B314  B315  B316  B317  B318  B319  B320  B321  B322  B323  B324
B325  B326  B327  B328  B329  B330  B331  B332  B333  B334  B335  B336
B337  B338  B339  B340  B341  B342  B343  B344  B345  B346  B347  B348
B349  B350  B351  B352  B353  B354  B355  B356  B357  B358  B359  B360
B361  B362  B363  B364  B365  B366  B367  B368  B369  B370  B371  B372
B373  B374  B375  B376  B377  B378  B379  B380  B381  B382  B383  B384
B385  B386  B387  B388  B389  B390  B391  B392  B393  B394  B395  B396
B397  B398  B399  B400  B401  B402  B403  B404  B405  B406  B407  B408
B409  B410  B411  B412  B413  B414  B415  B416  B417  B418  B419  B420
B421  B422  B423  B424  B425  B426  B427  B428  B429  B430  B431  B432
B433  B434  B435  B436  B437  B438  B439  B440  B441  B442  B443  B444
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B445    B446    B447    B448    B449    B450    B451    B452    B453    B454    B455    B456
B457    B458    B459    B460    B461    B462    B463    B464    B465    B466    B467    B468
B469    B470    B471    B472    B473    B474    B475    B476    B477    B478    B479    B480
B481    B482    B483    B484    B485    B486    B487    B488    B489    B490    B491    B492
B493    B494    B495    B496    B497    B498    B499    B500    B501    B502    B503    B504
B505    B506    B507    B508    B509    B510    B511    B512    B513    B514    B515    B516
B517    B518    B519    B520    B521    B522    B523    B524    B525    B526    B527    B528
B529    B530    B531    B532    B533    B534    B535    B536    B537    B538    B539    B540
B541    B542    B543    B544    B545    B546    B547    B548    B549    B550    B551    B552
B553    B554    B555    B556    B557    B558    B559    B560    B561    B562    B563    B564
B565    B566    B567    B568    B569    B570    B571    B572    B573    B574    B575    B576
B577    B578    B579    B580    B581    B582    B583    B584    B585    B586    B587    B588
B589    B590    B591    B592    B593    B594    B595    B596    B597    B598    B599    B600
B601    B602    B603    B604    B605    B606    B607    B608    B609    B610    B611    B612
B613    B614    B615    B616    B617    B618    B619    B620    B621    B622    B623    B624
B625    B626    B627    B628    B629    B630    B631    B632    B633    B634    B635    B636
B637    B638    B639    B640    B641    B642    B643    B644    B645    B646    B647    B648
B649    B650    B651    B652    B653    B654    B655    B656    B657    B658    B659    B660
B661    B662    B663    B664    B665    B666    B667    B668    B669    B670    B671    B672
B773    B774    B775    B776    B777    B778    B779    B780    B781    B782    B783    B784
B785    B786    B787    B788    B789    B790    B791    B792    B793    B794    B795    B796
B797    B798    B799    B800    B801    B802    B803    B804    B805    B806    B807    B808
B809    B810    B811    B812    B813    B814    B815    B816    B817    B818    B819    B820
B821    B822    B823    B824    B825    B826    B827    B828    B829    B830    B831    B832
B833    B834    B835    B836    B837    B838    B839    B840    B841    B842    B843    B844
B845    B846    B847    B848    B849    B850    B851    B852    B853    B854    B855    B856
B857    B858    B859    B860    B861    B862    B863    B864    B865    B866    B867    B868
B869    B870    B871    B872    B873    B874    B875    B876    B877    B878    B879    B880
B881    B882    B883    B884    B885    B886    B887    B888    B889    B890    B891    B892
B893    B894    B895    B896    B897    B898    B899    B900    B901    B902    B903    B904
B905    B906    B907    B908    B909    B910    B911    B912    B913    B914    B915    B916
B917    B918    B919    B920    B921    B922    B923    B924    B925    B926    B927    B928
B929    B930    B931    B932    B933    B934    B935    B936    B937    B938    B939    B940
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B941    B942    B943    B944    B945    B946    B947    B948    B949    B950    B951    B952
B953    B954    B955    B956    B957    B958    B959    B960    B961    B962    B963    B964
B965    B966    B967    B968    B969    B970    B971    B972    B973    B974    B975    B976
B977    B978    B979    B980    B981    B982    B983    B984    B985    B986    B987    B988
B989    B990    B991    B992    B993    B994    B995    B996    B997    B998    B999    B1000
B1001   B1002   B1003   B1004   B1005   B1006   B1007   B1008   B1009   B1010   B1011   B1012
B1013   B1014   B1015   B1016   B1017   B1018   B1019   B1020   B1021   B1022   B1023   B1024
B1025   B1026   B1027   B1028   B1029   B1030   B1031   B1032   B1033   B1034   B1035   B1036
B1037   B1038   B1039   B1040   B1041   B1042   B1043   B1044   B1045   B1046   B1047   B1048
B1049   B1050   B1051   B1052   B1053   B1054   B1055   B1056   B1057   B1058   B1059   B1060
B1061   B1062   B1063   B1064   B1065   B1066   B1067   B1068   B1069   B1070   B1071   B1072
B1073   B1074   B1075   B1076   B1077   B1078   B1079   B1080   B1081   B1082   B1083
表10：式Ih化合物：
Figure C01804089D01841
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B1      B2      B3      B4      B5      B6      B7      B8      B9      B10     B11     B12
B13     B14     B15     B16     B17     B18     B19     B20     B21     B22     B23     B24
B25     B26     B27     B28     B29     B30     B31     B32     B33     B34     B35     B36
B37     B38     B39     B40     B41     B42     B43     B44     B45     B46     B47     B48
B49     B50     B51     B52     B53     B54     B55     B56     B57     B58     B59     B60
B61     B62     B63     B64     B65     B66     B67     B68     B69     B70     B71     B72
B73     B74     B75     B76     B77     B78     B79     B80     B81     B82     B83     B84
B85     B86     B87     B88     B89     B90     B91     B92     B93     B94     B95     B96
B97     B98     B99     B100    B101    B102    B103    B104    B105    B106    B107    B108
B109    B110    B111    B112    B113    B114    B115    B116    B117    B118    B119    B120
B121    B122    B123    B124    B125    B126    B127    B128    B129    B130    B131    B132
B133    B134    B135    B136    B137    B138    B139    B140    B141    B142    B143    B144
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B145    B146    B147    B148    B149    B150    B151    B152    B153    B154    B155    B156
B157    B158    B159    B160    B161    B162    B163    B164    B165    B166    B167    B168
B169    B170    B171    B172    B173    B174    B175    B176    B177    B178    B179    B180
B181    B182    B183    B184    B185    B186    B187    B188    B189    B190    B191    B192
B193    B194    B195    B196    B197    B198    B199    B200    B201    B202    B203    B204
B205    B206    B207    B208    B209    B210    B211    B212    B213    B214    B215    B216
B217    B218    B219    B220    B221    B222    B223    B224    B225    B226    B227    B228
B229    B230    B231    B232    B233    B234    B235    B236    B237    B238    B239    B240
B241    B242    B243    B244    B245    B246    B247    B248    B249    B250    B251    B252
B253    B254    B255    B256    B257    B258    B259    B260    B261    B262    B263    B264
B265    B266    B267    B268    B269    B270    B271    B272    B273    B274    B275    B276
B277    B278    B279    B280    B281    B282    B283    B284    B285    B286    B287    B288
B289    B290    B291    B292    B293    B294    B295    B296    B297    B298    B299    B300
B301    B302    B303    B304    B305    B306    B307    B308    B309    B310    B311    B312
B313    B314    B315    B316    B317    B318    B319    B320    B321    B322    B323    B324
B325    B326    B327    B328    B329    B330    B331    B332    B333    B334    B335    B336
B337    B338    B339    B340    B341    B342    B343    B344    B345    B346    B347    B348
B349    B350    B351    B352    B353    B354    B355    B356    B357    B358    B359    B360
B361    B362    B363    B364    B365    B366    B367    B368    B369    B370    B371    B372
B373    B374    B375    B376    B377    B378    B379    B380    B381    B382    B383    B384
B385    B386    B387    B388    B389    B390    B391    B392    B393    B394    B395    B396
B397    B398    B399    B400    B401    B402    B403    B404    B405    B406    B407    B408
B409    B410    B411    B412    B413    B414    B415    B416    B417    B418    B419    B420
B421    B422    B423    B424    B425    B426    B427    B428    B429    B430    B431    B432
B433    B434    B435    B436    B437    B438    B439    B440    B441    B442    B443    B444
B445    B446    B447    B448    B449    B450    B451    B452    B453    B454    B455    B456
B457    B458    B459    B460    B461    B462    B463    B464    B465    B466    B467    B468
B469    B470    B471    B472    B473    B474    B475    B476    B477    B478    B479    B480
B481    B482    B483    B484    B485    B486    B487    B488    B489    B490    B491    B492
B493    B494    B495    B496    B497    B498    B499    B500    B501    B502    B503    B504
B505    B506    B507    B508    B509    B510    B511    B512    B513    B514    B515    B516
B517    B518    B519    B520    B521    B522    B523    B524    B525    B526    B527    B528
B529    B530    B531    B532    B533    B534    B535    B536    B537    B538    B539    B540
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B541    B542    B543    B544    B545    B546    B547    B548    B549    B550    B551    B552
B553    B554    B555    B556    B557    B558    B559    B560    B561    B562    B563    B564
B565    B566    B567    B568    B569    B570    B571    B572    B573    B574    B575    B576
B577    B578    B579    B580    B581    B582    B583    B584    B585    B586    B587    B588
B589    B590    B591    B592    B593    B594    B595    B596    B597    B598    B599    B600
B601    B602    B603    B604    B605    B606    B607    B608    B609    B610    B611    B612
B613    B614    B615    B616    B617    B618    B619    B620    B621    B622    B623    B624
B625    B626    B627    B628    B629    B630    B631    B632    B633    B634    B635    B636
B637    B638    B639    B640    B641    B642    B643    B644    B645    B646    B647    B648
B649    B650    B651    B652    B653    B654    B655    B656    B657    B658    B659    B660
B661    B662    B663    B664    B665    B666    B667    B668    B669    B670    B671    B672
B773    B774    B775    B776    B777    B778    B779    B780    B781    B782    B783    B784
B785    B786    B787    B788    B789    B790    B791    B792    B793    B794    B795    B796
B797    B798    B799    B800    B801    B802    B803    B804    B805    B806    B807    B808
B809    B810    B811    B812    B813    B814    B815    B816    B817    B818    B819    B820
B821    B822    B823    B824    B825    B826    B827    B828    B829    B830    B831    B832
B833    B834    B835    B836    B837    B838    B839    B840    B841    B842    B843    B844
B845    B846    B847    B848    B849    B850    B851    B852    B853    B854    B855    B856
B857    B858    B859    B860    B861    B862    B863    B864    B865    B866    B867    B868
B869    B870    B871    B872    B873    B874    B875    B876    B877    B878    B879    B880
B881    B882    B883    B884    B885    B886    B887    B888    B889    B890    B891    B892
B893    B894    B895    B896    B897    B898    B899    B900    B901    B902    B903    B904
B905    B906    B907    B908    B909    B910    B911    B912    B913    B914    B915    B916
B917    B918    B919    B920    B921    B922    B923    B924    B925    B926    B927    B928
B929    B930    B931    B932    B933    B934    B935    B936    B937    B938    B939    B940
B941    B942    B943    B944    B945    B946    B947    B948    B949    B950    B951    B952
B953    B954    B955    B956    B957    B958    B959    B960    B961    B962    B963    B964
B965    B966    B967    B968    B969    B970    B971    B972    B973    B974    B975    B976
B977    B978    B979    B980    B981    B982    B983    B984    B985    B986    B987    B988
B989    B990    B991    B992    B993    B994    B995    B996    B997    B998    B999    B1000
B1001   B1002   B1003   B1004   B1005   B1006   B1007   B1008   B1009   B1010   B1011   B1012
B1013   B1014   B1015   B1016   B1017   B1018   B1019   B1020   B1021   B1022   B1023   B1024
B1025   B1026   B1027   B1028   B1029   B1030   B1031   B1032   B1033   B1034   B1035   B1036
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B1037   B1038   B1039   B1040   B1041   B1042   B1043   B1044   B1045   B1046   B1047   B1048
B1049   B1050   B1051   B1052   B1053   B1054   B1055   B1056   B1057   B1058   B1059   B1060
B1061   B1062   B1063   B1064   B1065   B1066   B1067   B1068   B1069   B1070   B1071   B1072
B1073   B1074   B1075   B1076   B1077   B1078   B1079   B1080   B1081   B1082   B1083
表11：式Ik化合物：
Figure C01804089D01871
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B1      B2      B3      B4      B5      B6      B7      B8      B9      B10     B11     B12
B13     B14     B15     B16     B17     B18     B19     B20     B21     B22     B23     B24
B25     B26     B27     B28     B29     B30     B31     B32     B33     B34     B35     B36
B37     B38     B39     B40     B41     B42     B43     B44     B45     B46     B47     B48
B49     B50     B51     B52     B53     B54     B55     B56     B57     B58     B59     B60
B61     B62     B63     B64     B65     B66     B67     B68     B69     B70     B71     B72
B73     B74     B75     B76     B77     B78     B79     B80     B81     B82     B83     B84
B85     B86     B87     B88     B89     B90     B91     B92     B93     B94     B95     B96
B97     B98     B99     B100    B101    B102    B103    B104    B105    B106    B107    B108
B109    B110    B111    B112    B113    B114    B115    B116    B117    B118    B119    B120
B121    B122    B123    B124    B125    B126    B127    B128    B129    B130    B131    B132
B133    B134    B135    B136    B137    B138    B139    B140    B141    B142    B143    B144
B145    B146    B147    B148    B149    B150    B151    B152    B153    B154    B155    B156
B157    B158    B159    B160    B161    B162    B163    B164    B165    B166    B167    B168
B169    B170    B171    B172    B173    B174    B175    B176    B177    B178    B179    B180
B181    B182    B183    B184    B185    B186    B187    B188    B189    B190    B191    B192
B193    B194    B195    B196    B197    B198    B199    B200    B201    B202    B203    B204
B205    B206    B207    B208    B209    B210    B211    B212    B213    B214    B215    B216
B217    B218    B219    B220    B221    B222    B223    B224    B225    B226    B227    B228
B229    B230    B231    B232    B233    B234    B235    B236    B237    B238    B239    B240
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B241    B242    B243    B244    B245    B246    B247    B248    B249    B250    B251    B252
B253    B254    B255    B256    B257    B258    B259    B260    B261    B262    B263    B264
B265    B266    B267    B268    B269    B270    B271    B272    B273    B274    B275    B276
B277    B278    B279    B280    B281    B282    B283    B284    B285    B286    B287    B288
B289    B290    B291    B292    B293    B294    B295    B296    B297    B298    B299    B300
B301    B302    B303    B304    B305    B306    B307    B308    B309    B310    B311    B312
B313    B314    B315    B316    B317    B318    B319    B320    B321    B322    B323    B324
B325    B326    B327    B328    B329    B330    B331    B332    B333    B334    B335    B336
B337    B338    B339    B340    B341    B342    B343    B344    B345    B346    B347    B348
B349    B350    B351    B352    B353    B354    B355    B356    B357    B358    B359    B360
B361    B362    B363    B364    B365    B366    B367    B368    B369    B370    B371    B372
B373    B374    B375    B376    B377    B378    B379    B380    B381    B382    B383    B384
B385    B386    B387    B388    B389    B390    B391    B392    B393    B394    B395    B396
B397    B398    B399    B400    B401    B402    B403    B404    B405    B406    B407    B408
B409    B410    B411    B412    B413    B414    B415    B416    B417    B418    B419    B420
B421    B422    B423    B424    B425    B426    B427    B428    B429    B430    B431    B432
B433    B434    B435    B436    B437    B438    B439    B440    B441    B442    B443    B444
B445    B446    B447    B448    B449    B450    B451    B452    B453    B454    B455    B456
B457    B458    B459    B460    B461    B462    B463    B464    B465    B466    B467    B468
B469    B470    B471    B472    B473    B474    B475    B476    B477    B478    B479    B480
B481    B482    B483    B484    B485    B486    B487    B488    B489    B490    B491    B492
B493    B494    B495    B496    B497    B498    B499    B500    B501    B502    B503    B504
B505    B506    B507    B508    B509    B510    B511    B512    B513    B514    B515    B516
B517    B518    B519    B520    B521    B522    B523    B524    B525    B526    B527    B528
B529    B530    B531    B532    B533    B534    B535    B536    B537    B538    B539    B540
B541    B542    B543    B544    B545    B546    B547    B548    B549    B550    B551    B552
B553    B554    B555    B556    B557    B558    B559    B560    B561    B562    B563    B564
B565    B566    B567    B568    B569    B570    B571    B572    B573    B574    B575    B576
B577    B578    B579    B580    B581    B582    B583    B584    B585    B586    B587    B588
B589    B590    B591    B592    B593    B594    B595    B596    B597    B598    B599    B600
B601    B602    B603    B604    B605    B606    B607    B608    B609    B610    B611    B612
B613    B614    B615    B616    B617    B618    B619    B620    B621    B622    B623    B624
B625    B626    B627    B628    B629    B630    B631    B632    B633    B634    B635    B636
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B637    B638    B639    B640    B641    B642    B643    B644    B645    B646    B647    B648
B649    B650    B651    B652    B653    B654    B655    B656    B657    B658    B659    B660
B661    B662    B663    B664    B665    B666    B667    B668    B669    B670    B671    B672
B773    B774    B775    B776    B777    B778    B779    B780    B781    B782    B783    B784
B785    B786    B787    B788    B789    B790    B791    B792    B793    B794    B795    B796
B797    B798    B799    B800    B801    B802    B803    B804    B805    B806    B807    B808
B809    B810    B811    B812    B813    B814    B815    B816    B817    B818    B819    B820
B821    B822    B823    B824    B825    B826    B827    B828    B829    B830    B831    B832
B833    B834    B835    B836    B837    B838    B839    B840    B841    B842    B843    B844
B845    B846    B847    B848    B849    B850    B851    B852    B853    B854    B855    B856
B857    B858    B859    B860    B861    B862    B863    B864    B865    B866    B867    B868
B869    B870    B871    B872    B873    B874    B875    B876    B877    B878    B879    B880
B881    B882    B883    B884    B885    B886    B887    B888    B889    B890    B891    B892
B893    B894    B895    B896    B897    B898    B899    B900    B901    B902    B903    B904
B905    B906    B907    B908    B909    B910    B911    B912    B913    B914    B915    B916
B917    B918    B919    B920    B921    B922    B923    B924    B925    B926    B927    B928
B929    B930    B931    B932    B933    B934    B935    B936    B937    B938    B939    B940
B941    B942    B943    B944    B945    B946    B947    B948    B949    B950    B951    B952
B953    B954    B955    B956    B957    B958    B959    B960    B961    B962    B963    B964
B965    B966    B967    B968    B969    B970    B971    B972    B973    B974    B975    B976
B977    B978    B979    B980    B981    B982    B983    B984    B985    B986    B987    B988
B989    B990    B991    B992    B993    B994    B995    B996    B997    B998    B999    B1000
B1001   B1002   B1003   B1004   B1005   B1006   B1007   B1008   B1009   B1010   B1011   B1012
B1013   B1014   B1015   B1016   B1017   B1018   B1019   B1020   B1021   B1022   B1023   B1024
B1025   B1026   B1027   B1028   B1029   B1030   B1031   B1032   B1033   B1034   B1035   B1036
B1037   B1038   B1039   B1040   B1041   B1042   B1043   B1044   B1045   B1046   B1047   B1048
B1049   B1050   B1051   B1052   B1053   B1054   B1055   B1056   B1057   B1058   B1059   B1060
B1061   B1062   B1063   B1064   B1065   B1066   B1067   B1068   B1069   B1070   B1071   B1072
B1073   B1074   B1075   B1076   B1077   B1078   B1079   B1080   B1081   B1082   B1083
表12：式Im化合物：
Figure C01804089D01901
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B1      B2      B3      B4      B5      B6      B7      B8      B9      B10     B11     B12
B13     B14     B15     B16     B17     B18     B19     B20     B21     B22     B23     B24
B25     B26     B27     B28     B29     B30     B31     B32     B33     B34     B35     B36
B37     B38     B39     B40     B41     B42     B43     B44     B45     B46     B47     B48
B49     B50     B51     B52     B53     B54     B55     B56     B57     B58     B59     B60
B61     B62     B63     B64     B65     B66     B67     B68     B69     B70     B71     B72
B73     B74     B75     B76     B77     B78     B79     B80     B81     B82     B83     B84
B85     B86     B87     B88     B89     B90     B91     B92     B93     B94     B95     B96
B97     B98     B99     B100    B101    B102    B103    B104    B105    B106    B107    B108
B109    B110    B111    B112    B113    B114    B115    B116    B117    B118    B119    B120
B121    B122    B123    B124    B125    B126    B127    B128    B129    B130    B131    B132
B133    B134    B135    B136    B137    B138    B139    B140    B141    B142    B143    B144
B145    B146    B147    B148    B149    B150    B151    B152    B153    B154    B155    B156
B157    B158    B159    B160    B161    B162    B163    B164    B165    B166    B167    B168
B169    B170    B171    B172    B173    B174    B175    B176    B177    B178    B179    B180
B181    B182    B183    B184    B185    B186    B187    B188    B189    B190    B191    B192
B193    B194    B195    B196    B197    B198    B199    B200    B201    B202    B203    B204
B205    B206    B207    B208    B209    B210    B211    B212    B213    B214    B215    B216
B217    B218    B219    B220    B221    B222    B223    B224    B225    B226    B227    B228
B229    B230    B231    B232    B233    B234    B235    B236    B237    B238    B239    B240
B241    B242    B243    B244    B245    B246    B247    B248    B249    B250    B251    B252
B253    B254    B255    B256    B257    B258    B259    B260    B261    B262    B263    B264
B265    B266    B267    B268    B269    B270    B271    B272    B273    B274    B275    B276
B277    B278    B279    B280    B281    B282    B283    B284    B285    B286    B287    B288
B289    B290    B291    B292    B293    B294    B295    B296    B297    B298    B299    B300
B301    B302    B303    B304    B305    B306    B307    B308    B309    B310    B311    B312
B313    B314    B315    B316    B317    B318    B319    B320    B321    B322    B323    B324
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B325    B326    B327    B328    B329    B330    B331    B332    B333    B334    B335    B336
B337    B338    B339    B340    B341    B342    B343    B344    B345    B346    B347    B348
B349    B350    B351    B352    B353    B354    B355    B356    B357    B358    B359    B360
B361    B362    B363    B364    B365    B366    B367    B368    B369    B370    B371    B372
B373    B374    B375    B376    B377    B378    B379    B380    B381    B382    B383    B384
B385    B386    B387    B388    B389    B390    B391    B392    B393    B394    B395    B396
B397    B398    B399    B400    B401    B402    B403    B404    B405    B406    B407    B408
B409    B410    B411    B412    B413    B414    B415    B416    B417    B418    B419    B420
B421    B422    B423    B424    B425    B426    B427    B428    B429    B430    B431    B432
B433    B434    B435    B436    B437    B438    B439    B440    B441    B442    B443    B444
B445    B446    B447    B448    B449    B450    B451    B452    B453    B454    B455    B456
B457    B458    B459    B460    B461    B462    B463    B464    B465    B466    B467    B468
B469    B470    B471    B472    B473    B474    B475    B476    B477    B478    B479    B480
B481    B482    B483    B484    B485    B486    B487    B488    B489    B490    B491    B492
B493    B494    B495    B496    B497    B498    B499    B500    B501    B502    B503    B504
B505    B506    B507    B508    B509    B510    B511    B512    B513    B514    B515    B516
B517    B518    B519    B520    B521    B522    B523    B524    B525    B526    B527    B528
B529    B530    B531    B532    B533    B534    B535    B536    B537    B538    B539    B540
B541    B542    B543    B544    B545    B546    B547    B548    B549    B550    B551    B552
B553    B554    B555    B556    B557    B558    B559    B560    B561    B562    B563    B564
B565    B566    B567    B568    B569    B570    B571    B572    B573    B574    B575    B576
B577    B578    B579    B580    B581    B582    B583    B584    B585    B586    B587    B588
B589    B590    B591    B592    B593    B594    B595    B596    B597    B598    B599    B600
B601    B602    B603    B604    B605    B606    B607    B608    B609    B610    B611    B612
B613    B614    B615    B616    B617    B618    B619    B620    B621    B622    B623    B624
B625    B626    B627    B628    B629    B630    B631    B632    B633    B634    B635    B636
B637    B638    B639    B640    B641    B642    B643    B644    B645    B646    B647    B648
B649    B650    B651    B652    B653    B654    B655    B656    B657    B658    B659    B660
B661    B662    B663    B664    B665    B666    B667    B668    B669    B670    B671    B672
B773    B774    B775    B776    B777    B778    B779    B780    B781    B782    B783    B784
B785    B786    B787    B788    B789    B790    B791    B792    B793    B794    B795    B796
B797    B798    B799    B800    B801    B802    B803    B804    B805    B806    B807    B808
B809    B810    B811    B812    B813    B814    B815    B816    B817    B818    B819    B820
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B821    B822    B823    B824    B825    B826    B827    B828    B829    B830    B831    B832
B833    B834    B835    B836    B837    B838    B839    B840    B841    B842    B843    B844
B845    B846    B847    B848    B849    B850    B851    B852    B853    B854    B855    B856
B857    B858    B859    B860    B861    B862    B863    B864    B865    B866    B867    B868
B869    B870    B871    B872    B873    B874    B875    B876    B877    B878    B879    B880
B881    B882    B883    B884    B885    B886    B887    B888    B889    B890    B891    B892
B893    B894    B895    B896    B897    B898    B899    B900    B901    B902    B903    B904
B905    B906    B907    B908    B909    B910    B911    B912    B913    B914    B915    B916
B917    B918    B919    B920    B921    B922    B923    B924    B925    B926    B927    B928
B929    B930    B931    B932    B933    B934    B935    B936    B937    B938    B939    B940
B941    B942    B943    B944    B945    B946    B947    B948    B949    B950    B951    B952
B953    B954    B955    B956    B957    B958    B959    B960    B961    B962    B963    B964
B965    B966    B967    B968    B969    B970    B971    B972    B973    B974    B975    B976
B977    B978    B979    B980    B981    B982    B983    B984    B985    B986    B987    B988
B989    B990    B991    B992    B993    B994    B995    B996    B997    B998    B999    B1000
B1001   B1002   B1003   B1004   B1005   B1006   B1007   B1008   B1009   B1010   B1011   B1012
B1013   B1014   B1015   B1016   B1017   B1018   B1019   B1020   B1021   B1022   B1023   B1024
B1025   B1026   B1027   B1028   B1029   B1030   B1031   B1032   B1033   B1034   B1035   B1036
B1037   B1038   B1039   B1040   B1041   B1042   B1043   B1044   B1045   B1046   B1047   B1048
B1049   B1050   B1051   B1052   B1053   B1054   B1055   B1056   B1057   B1058   B1059   B1060
B1061   B1062   B1063   B1064   B1065   B1066   B1067   B1068   B1069   B1070   B1071   B1072
B1073   B1074   B1075   B1076   B1077   B1078   B1079   B1080   B1081   B1082   B1083
表13：式In化合物：
Figure C01804089D01921
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B1      B2      B3      B4      B5      B6      B7      B8      B9      B10     B11     B12
B13     B14     B15     B16     B17     B18     B19     B20     B21     B22     B23     B24
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B25     B26     B27     B28     B29     B30     B31     B32     B33     B34     B35     B36
B37     B38     B39     B40     B41     B42     B43     B44     B45     B46     B47     B48
B49     B50     B51     B52     B53     B54     B55     B56     B57     B58     B59     B60
B61     B62     B63     B64     B65     B66     B67     B68     B69     B70     B71     B72
B73     B74     B75     B76     B77     B78     B79     B80     B81     B82     B83     B84
B85     B86     B87     B88     B89     B90     B91     B92     B93     B94     B95     B96
B97     B98     B99     B100    B101    B102    B103    B104    B105    B106    B107    B108
B109    B110    B111    B112    B113    B114    B115    B116    B117    B118    B119    B120
B121    B122    B123    B124    B125    B126    B127    B128    B129    B130    B131    B132
B133    B134    B135    B136    B137    B138    B139    B140    B141    B142    B143    B144
B145    B146    B147    B148    B149    B150    B151    B152    B153    B154    B155    B156
B157    B158    B159    B160    B161    B162    B163    B164    B165    B166    B167    B168
B169    B170    B171    B172    B173    B174    B175    B176    B177    B178    B179    B180
B181    B182    B183    B184    B185    B186    B187    B188    B189    B190    B191    B192
B193    B194    B195    B196    B197    B198    B199    B200    B201    B202    B203    B204
B205    B206    B207    B208    B209    B210    B211    B212    B213    B214    B215    B216
B217    B218    B219    B220    B221    B222    B223    B224    B225    B226    B227    B228
B229    B230    B231    B232    B233    B234    B235    B236    B237    B238    B239    B240
B241    B242    B243    B244    B245    B246    B247    B248    B249    B250    B251    B252
B253    B254    B255    B256    B257    B258    B259    B260    B261    B262    B263    B264
B265    B266    B267    B268    B269    B270    B271    B272    B273    B274    B275    B276
B277    B278    B279    B280    B281    B282    B283    B284    B285    B286    B287    B288
B289    B290    B291    B292    B293    B294    B295    B296    B297    B298    B299    B300
B301    B302    B303    B304    B305    B306    B307    B308    B309    B310    B311    B312
B313    B314    B315    B316    B317    B318    B319    B320    B321    B322    B323    B324
B325    B326    B327    B328    B329    B330    B331    B332    B333    B334    B335    B336
B337    B338    B339    B340    B341    B342    B343    B344    B345    B346    B347    B348
B349    B350    B351    B352    B353    B354    B355    B356    B357    B358    B359    B360
B361    B362    B363    B364    B365    B366    B367    B368    B369    B370    B371    B372
B373    B374    B375    B376    B377    B378    B379    B380    B381    B382    B383    B384
B385    B386    B387    B388    B389    B390    B391    B392    B393    B394    B395    B396
B397    B398    B399    B400    B401    B402    B403    B404    B405    B406    B407    B408
B409    B410    B411    B412    B413    B414    B415    B416    B417    B418    B419    B420
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B421    B422    B423    B424    B425    B426    B427    B428    B429    B430    B431    B432
B433    B434    B435    B436    B437    B438    B439    B440    B441    B442    B443    B444
B445    B446    B447    B448    B449    B450    B451    B452    B453    B454    B455    B456
B457    B458    B459    B460    B461    B462    B463    B464    B465    B466    B467    B468
B469    B470    B471    B472    B473    B474    B475    B476    B477    B478    B479    B480
B481    B482    B483    B484    B485    B486    B487    B488    B489    B490    B491    B492
B493    B494    B495    B496    B497    B498    B499    B500    B501    B502    B503    B504
B505    B506    B507    B508    B509    B510    B511    B512    B513    B514    B515    B516
B517    B518    B519    B520    B521    B522    B523    B524    B525    B526    B527    B528
B529    B530    B531    B532    B533    B534    B535    B536    B537    B538    B539    B540
B541    B542    B543    B544    B545    B546    B547    B548    B549    B550    B551    B552
B553    B554    B555    B556    B557    B558    B559    B560    B561    B562    B563    B564
B565    B566    B567    B568    B569    B570    B571    B572    B573    B574    B575    B576
B577    B578    B579    B580    B581    B582    B583    B584    B585    B586    B587    B588
B589    B590    B591    B592    B593    B594    B595    B596    B597    B598    B599    B600
B601    B602    B603    B604    B605    B606    B607    B608    B609    B610    B611    B612
B613    B614    B615    B616    B617    B618    B619    B620    B621    B622    B623    B624
B625    B626    B627    B628    B629    B630    B631    B632    B633    B634    B635    B636
B637    B638    B639    B640    B641    B642    B643    B644    B645    B646    B647    B648
B649    B650    B651    B652    B653    B654    B655    B656    B657    B658    B659    B660
B661    B662    B663    B664    B665    B666    B667    B668    B669    B670    B671    B672
B773    B774    B775    B776    B777    B778    B779    B780    B781    B782    B783    B784
B785    B786    B787    B788    B789    B790    B791    B792    B793    B794    B795    B796
B797    B798    B799    B800    B801    B802    B803    B804    B805    B806    B807    B808
B809    B810    B811    B812    B813    B814    B815    B816    B817    B818    B819    B820
B821    B822    B823    B824    B825    B826    B827    B828    B829    B830    B831    B832
B833    B834    B835    B836    B837    B838    B839    B840    B841    B842    B843    B844
B845    B846    B847    B848    B849    B850    B851    B852    B853    B854    B855    B856
B857    B858    B859    B860    B861    B862    B863    B864    B865    B866    B867    B868
B869    B870    B871    B872    B873    B874    B875    B876    B877    B878    B879    B880
B881    B882    B883    B884    B885    B886    B887    B888    B889    B890    B891    B892
B893    B894    B895    B896    B897    B898    B899    B900    B901    B902    B903    B904
B905    B906    B907    B908    B909    B910    B911    B912    B913    B914    B915    B916
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B917    B918    B919    B920    B921    B922    B923    B924    B925    B926    B927    B928
B929    B930    B931    B932    B933    B934    B935    B936    B937    B938    B939    B940
B941    B942    B943    B944    B945    B946    B947    B948    B949    B950    B951    B952
B953    B954    B955    B956    B957    B958    B959    B960    B961    B962    B963    B964
B965    B966    B967    B968    B969    B970    B971    B972    B973    B974    B975    B976
B977    B978    B979    B980    B981    B982    B983    B984    B985    B986    B987    B988
B989    B990    B991    B992    B993    B994    B995    B996    B997    B998    B999    B1000
B1001   B1002   B1003   B1004   B1005   B1006   B1007   B1008   B1009   B1010   B1011   B1012
B1013   B1014   B1015   B1016   B1017   B1018   B1019   B1020   B1021   B1022   B1023   B1024
B1025   B1026   B1027   B1028   B1029   B1030   B1031   B1032   B1033   B1034   B1035   B1036
B1037   B1038   B1039   B1040   B1041   B1042   B1043   B1044   B1045   B1046   B1047   B1048
B1049   B1050   B1051   B1052   B1053   B1054   B1055   B1056   B1057   B1058   B1059   B1060
B1061   B1062   B1063   B1064   B1065   B1066   B1067   B1068   B1069   B1070   B1071   B1072
B1073   B1074   B1075   B1076   B1077   B1078   B1079   B1080   B1081   B1082   B1083
表14：式Io化合物：
Figure C01804089D01951
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B1      B2      B3      B4      B5      B6      B7      B8      B9      B10     B11     B12
B13     B14     B15     B16     B17     B18     B19     B20     B21     B22     B23     B24
B25     B26     B27     B28     B29     B30     B31     B32     B33     B34     B35     B36
B37     B38     B39     B40     B41     B42     B43     B44     B45     B46     B47     B48
B49     B50     B51     B52     B53     B54     B55     B56     B57     B58     B59     B60
B61     B62     B63     B64     B65     B66     B67     B68     B69     B70     B71     B72
B73     B74     B75     B76     B77     B78     B79     B80     B81     B82     B83     B84
B85     B86     B87     B88     B89     B90     B91     B92     B93     B94     B95     B96
B97     B98     B99     B100    B101    B102    B103    B104    B105    B106    B107    B108
B109    B110    B111    B112    B113    B114    B115    B116    B117    B118    B119    B120
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B121    B122    B123    B124    B125    B126    B127    B128    B129    B130    B131    B132
B133    B134    B135    B136    B137    B138    B139    B140    B141    B142    B143    B144
B145    B146    B147    B148    B149    B150    B151    B152    B153    B154    B155    B156
B157    B158    B159    B160    B161    B162    B163    B164    B165    B166    B167    B168
B169    B170    B171    B172    B173    B174    B175    B176    B177    B178    B179    B180
B181    B182    B183    B184    B185    B186    B187    B188    B189    B190    B191    B192
B193    B194    B195    B196    B197    B198    B199    B200    B201    B202    B203    B204
B205    B206    B207    B208    B209    B210    B211    B212    B213    B214    B215    B216
B217    B218    B219    B220    B221    B222    B223    B224    B225    B226    B227    B228
B229    B230    B231    B232    B233    B234    B235    B236    B237    B238    B239    B240
B241    B242    B243    B244    B245    B246    B247    B248    B249    B250    B251    B252
B253    B254    B255    B256    B257    B258    B259    B260    B261    B262    B263    B264
B265    B266    B267    B268    B269    B270    B271    B272    B273    B274    B275    B276
B277    B278    B279    B280    B281    B282    B283    B284    B285    B286    B287    B288
B289    B290    B291    B292    B293    B294    B295    B296    B297    B298    B299    B300
B301    B302    B303    B304    B305    B306    B307    B308    B309    B310    B311    B312
B313    B314    B315    B316    B317    B318    B319    B320    B321    B322    B323    B324
B325    B326    B327    B328    B329    B330    B331    B332    B333    B334    B335    B336
B337    B338    B339    B340    B341    B342    B343    B344    B345    B346    B347    B348
B349    B350    B351    B352    B353    B354    B355    B356    B357    B358    B359    B360
B361    B362    B363    B364    B365    B366    B367    B368    B369    B370    B371    B372
B373    B374    B375    B376    B377    B378    B379    B380    B381    B382    B383    B384
B385    B386    B387    B388    B389    B390    B391    B392    B393    B394    B395    B396
B397    B398    B399    B400    B401    B402    B403    B404    B405    B406    B407    B408
B409    B410    B411    B412    B413    B414    B415    B416    B417    B418    B419    B420
B421    B422    B423    B424    B425    B426    B427    B428    B429    B430    B431    B432
B433    B434    B435    B436    B437    B438    B439    B440    B441    B442    B443    B444
B445    B446    B447    B448    B449    B450    B451    B452    B453    B454    B455    B456
B457    B458    B459    B460    B461    B462    B463    B464    B465    B466    B467    B468
B469    B470    B471    B472    B473    B474    B475    B476    B477    B478    B479    B480
B481    B482    B483    B484    B485    B486    B487    B488    B489    B490    B491    B492
B493    B494    B495    B496    B497    B498    B499    B500    B501    B502    B503    B504
B505    B506    B507    B508    B509    B510    B511    B512    B513    B514    B515    B516
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B517    B518    B519    B520    B521    B522    B523    B524    B525    B526    B527    B528
B529    B530    B531    B532    B533    B534    B535    B536    B537    B538    B539    B540
B541    B542    B543    B544    B545    B546    B547    B548    B549    B550    B551    B552
B553    B554    B555    B556    B557    B558    B559    B560    B561    B562    B563    B564
B565    B566    B567    B568    B569    B570    B571    B572    B573    B574    B575    B576
B577    B578    B579    B580    B581    B582    B583    B584    B585    B586    B587    B588
B589    B590    B591    B592    B593    B594    B595    B596    B597    B598    B599    B600
B601    B602    B603    B604    B605    B606    B607    B608    B609    B610    B611    B612
B613    B614    B615    B616    B617    B618    B619    B620    B621    B622    B623    B624
B625    B626    B627    B628    B629    B630    B631    B632    B633    B634    B635    B636
B637    B638    B639    B640    B641    B642    B643    B644    B645    B646    B647    B648
B649    B650    B651    B652    B653    B654    B655    B656    B657    B658    B659    B660
B661    B662    B663    B664    B665    B666    B667    B668    B669    B670    B671    B672
B773    B774    B775    B776    B777    B778    B779    B780    B781    B782    B783    B784
B785    B786    B787    B788    B789    B790    B791    B792    B793    B794    B795    B796
B797    B798    B799    B800    B801    B802    B803    B804    B805    B806    B807    B808
B809    B810    B811    B812    B813    B814    B815    B816    B817    B818    B819    B820
B821    B822    B823    B824    B825    B826    B827    B828    B829    B830    B831    B832
B833    B834    B835    B836    B837    B838    B839    B840    B841    B842    B843    B844
B845    B846    B847    B848    B849    B850    B851    B852    B853    B854    B855    B856
B857    B858    B859    B860    B861    B862    B863    B864    B865    B866    B867    B868
B869    B870    B871    B872    B873    B874    B875    B876    B877    B878    B879    B880
B881    B882    B883    B884    B885    B886    B887    B888    B889    B890    B891    B892
B893    B894    B895    B896    B897    B898    B899    B900    B901    B902    B903    B904
B905    B906    B907    B908    B909    B910    B911    B912    B913    B914    B915    B916
B917    B918    B919    B920    B921    B922    B923    B924    B925    B926    B927    B928
B929    B930    B931    B932    B933    B934    B935    B936    B937    B938    B939    B940
B941    B942    B943    B944    B945    B946    B947    B948    B949    B950    B951    B952
B953    B954    B955    B956    B957    B958    B959    B960    B961    B962    B963    B964
B965    B966    B967    B968    B969    B970    B971    B972    B973    B974    B975    B976
B977    B978    B979    B980    B981    B982    B983    B984    B985    B986    B987    B988
B989    B990    B991    B992    B993    B994    B995    B996    B997    B998    B999    B1000
B1001   B1002   B1003   B1004   B1005   B1006   B1007   B1008   B1009   B1010   B1011   B1012
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B1013   B1014   B1015   B1016   B1017   B1018   B1019   B1020   B1021   B1022   B1023   B1024
B1025   B1026   B1027   B1028   B1029   B1030   B1031   B1032   B1033   B1034   B1035   B1036
B1037   B1038   B1039   B1040   B1041   B1042   B1043   B1044   B1045   B1046   B1047   B1048
B1049   B1050   B1051   B1052   B1053   B1054   B1055   B1056   B1057   B1058   B1059   B1060
B1061   B1062   B1063   B1064   B1065   B1066   B1067   B1068   B1069   B1070   B1071   B1072
B1073   B1074   B1075   B1076   B1077   B1078   B1079   B1080   B1081   B1082   B1083
表15：式Ip化合物：
Figure C01804089D01981
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B1      B2      B3      B4      B5      B6      B7      B8      B9      B10     B11     B12
B13     B14     B15     B16     B17     B18     B19     B20     B21     B22     B23     B24
B25     B26     B27     B28     B29     B30     B31     B32     B33     B34     B35     B36
B37     B38     B39     B40     B41     B42     B43     B44     B45     B46     B47     B48
B49     B50     B51     B52     B53     B54     B55     B56     B57     B58     B59     B60
B61     B62     B63     B64     B65     B66     B67     B68     B69     B70     B71     B72
B73     B74     B75     B76     B77     B78     B79     B80     B81     B82     B83     B84
B85     B86     B87     B88     B89     B90     B91     B92     B93     B94     B95     B96
B97     B98     B99     B100    B101    B102    B103    B104    B105    B106    B107    B108
B109    B110    B111    B112    B113    B114    B115    B116    B117    B118    B119    B120
B121    B122    B123    B124    B125    B126    B127    B128    B129    B130    B131    B132
B133    B134    B135    B136    B137    B138    B139    B140    B141    B142    B143    B144
B145    B146    B147    B148    B149    B150    B151    B152    B153    B154    B155    B156
B157    B158    B159    B160    B161    B162    B163    B164    B165    B166    B167    B168
B169    B170    B171    B172    B173    B174    B175    B176    B177    B178    B179    B180
B181    B182    B183    B184    B185    B186    B187    B188    B189    B190    B191    B192
B193    B194    B195    B196    B197    B198    B199    B200    B201    B202    B203    B204
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B205    B206    B207    B208    B209    B210    B211    B212    B213    B214    B215    B216
B217    B218    B219    B220    B221    B222    B223    B224    B225    B226    B227    B228
B229    B230    B231    B232    B233    B234    B235    B236    B237    B238    B239    B240
B241    B242    B243    B244    B245    B246    B247    B248    B249    B250    B251    B252
B253    B254    B255    B256    B257    B258    B259    B260    B261    B262    B263    B264
B265    B266    B267    B268    B269    B270    B271    B272    B273    B274    B275    B276
B277    B278    B279    B280    B281    B282    B283    B284    B285    B286    B287    B288
B289    B290    B291    B292    B293    B294    B295    B296    B297    B298    B299    B300
B301    B302    B303    B304    B305    B306    B307    B308    B309    B310    B311    B312
B313    B314    B315    B316    B317    B318    B319    B320    B321    B322    B323    B324
B325    B326    B327    B328    B329    B330    B331    B332    B333    B334    B335    B336
B337    B338    B339    B340    B341    B342    B343    B344    B345    B346    B347    B348
B349    B350    B351    B352    B353    B354    B355    B356    B357    B358    B359    B360
B361    B362    B363    B364    B365    B366    B367    B368    B369    B370    B371    B372
B373    B374    B375    B376    B377    B378    B379    B380    B381    B382    B383    B384
B385    B386    B387    B388    B389    B390    B391    B392    B393    B394    B395    B396
B397    B398    B399    B400    B401    B402    B403    B404    B405    B406    B407    B408
B409    B410    B411    B412    B413    B414    B415    B416    B417    B418    B419    B420
B421    B422    B423    B424    B425    B426    B427    B428    B429    B430    B431    B432
B433    B434    B435    B436    B437    B438    B439    B440    B441    B442    B443    B444
B445    B446    B447    B448    B449    B450    B451    B452    B453    B454    B455    B456
B457    B458    B459    B460    B461    B462    B463    B464    B465    B466    B467    B468
B469    B470    B471    B472    B473    B474    B475    B476    B477    B478    B479    B480
B481    B482    B483    B484    B485    B486    B487    B488    B489    B490    B491    B492
B493    B494    B495    B496    B497    B498    B499    B500    B501    B502    B503    B504
B505    B506    B507    B508    B509    B510    B511    B512    B513    B514    B515    B516
B517    B518    B519    B520    B521    B522    B523    B524    B525    B526    B527    B528
B529    B530    B531    B532    B533    B534    B535    B536    B537    B538    B539    B540
B541    B542    B543    B544    B545    B546    B547    B548    B549    B550    B551    B552
B553    B554    B555    B556    B557    B558    B559    B560    B561    B562    B563    B564
B565    B566    B567    B568    B569    B570    B571    B572    B573    B574    B575    B576
B577    B578    B579    B580    B581    B582    B583    B584    B585    B586    B587    B588
B589    B590    B591    B592    B593    B594    B595    B596    B597    B598    B599    B600
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B601    B602    B603    B604    B605    B606    B607    B608    B609    B610    B611    B612
B613    B614    B615    B616    B617    B618    B619    B620    B621    B622    B623    B624
B625    B626    B627    B628    B629    B630    B631    B632    B633    B634    B635    B636
B637    B638    B639    B640    B641    B642    B643    B644    B645    B646    B647    B648
B649    B650    B651    B652    B653    B654    B655    B656    B657    B658    B659    B660
B661    B662    B663    B664    B665    B666    B667    B668    B669    B670    B671    B672
B773    B774    B775    B776    B777    B778    B779    B780    B781    B782    B783    B784
B785    B786    B787    B788    B789    B790    B791    B792    B793    B794    B795    B796
B797    B798    B799    B800    B801    B802    B803    B804    B805    B806    B807    B808
B809    B810    B811    B812    B813    B814    B815    B816    B817    B818    B819    B820
B821    B822    B823    B824    B825    B826    B827    B828    B829    B830    B831    B832
B833    B834    B835    B836    B837    B838    B839    B840    B841    B842    B843    B844
B845    B846    B847    B848    B849    B850    B851    B852    B853    B854    B855    B856
B857    B858    B859    B860    B861    B862    B863    B864    B865    B866    B867    B868
B869    B870    B871    B872    B873    B874    B875    B876    B877    B878    B879    B880
B881    B882    B883    B884    B885    B886    B887    B888    B889    B890    B891    B892
B893    B894    B895    B896    B897    B898    B899    B900    B901    B902    B903    B904
B905    B906    B907    B908    B909    B910    B911    B912    B913    B914    B915    B916
B917    B918    B919    B920    B921    B922    B923    B924    B925    B926    B927    B928
B929    B930    B931    B932    B933    B934    B935    B936    B937    B938    B939    B940
B941    B942    B943    B944    B945    B946    B947    B948    B949    B950    B951    B952
B953    B954    B955    B956    B957    B958    B959    B960    B961    B962    B963    B964
B965    B966    B967    B968    B969    B970    B971    B972    B973    B974    B975    B976
B977    B978    B979    B980    B981    B982    B983    B984    B985    B986    B987    B988
B989    B990    B991    B992    B993    B994    B995    B996    B997    B998    B999    B1000
B1001   B1002   B1003   B1004   B1005   B1006   B1007   B1008   B1009   B1010   B1011   B1012
B1013   B1014   B1015   B1016   B1017   B1018   B1019   B1020   B1021   B1022   B1023   B1024
B1025   B1026   B1027   B1028   B1029   B1030   B1031   B1032   B1033   B1034   B1035   B1036
B1037   B1038   B1039   B1040   B1041   B1042   B1043   B1044   B1045   B1046   B1047   B1048
B1049   B1050   B1051   B1052   B1053   B1054   B1055   B1056   B1057   B1058   B1059   B1060
B1061   B1062   B1063   B1064   B1065   B1066   B1067   B1068   B1069   B1070   B1071   B1072
B1073   B1074   B1075   B1076   B1077   B1078   B1079   B1080   B1081   B1082   B1083
表16：式Iq化合物：
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B1      B2      B3      B4      B5      B6      B7      B8      B9      B10     B11     B12
B13     B14     B15     B16     B17     B18     B19     B20     B21     B22     B23     B24
B25     B26     B27     B28     B29     B30     B31     B32     B33     B34     B35     B36
B37     B38     B39     B40     B41     B42     B43     B44     B45     B46     B47     B48
B49     B50     B51     B52     B53     B54     B55     B56     B57     B58     B59     B60
B61     B62     B63     B64     B65     B66     B67     B68     B69     B70     B71     B72
B73     B74     B75     B76     B77     B78     B79     B80     B81     B82     B83     B84
B85     B86     B87     B88     B89     B90     B91     B92     B93     B94     B95     B96
B97     B98     B99     B100    B101    B102    B103    B104    B105    B106    B107    B108
B109    B110    B111    B112    B113    B114    B115    B116    B117    B118    B119    B120
B121    B122    B123    B124    B125    B126    B127    B128    B129    B130    B131    B132
B133    B134    B135    B136    B137    B138    B139    B140    B141    B142    B143    B144
B145    B146    B147    B148    B149    B150    B151    B152    B153    B154    B155    B156
B157    B158    B159    B160    B161    B162    B163    B164    B165    B166    B167    B168
B169    B170    B171    B172    B173    B174    B175    B176    B177    B178    B179    B180
B181    B182    B183    B184    B185    B186    B187    B188    B189    B190    B191    B192
B193    B194    B195    B196    B197    B198    B199    B200    B201    B202    B203    B204
B205    B206    B207    B208    B209    B210    B211    B212    B213    B214    B215    B216
B217    B218    B219    B220    B221    B222    B223    B224    B225    B226    B227    B228
B229    B230    B231    B232    B233    B234    B235    B236    B237    B238    B239    B240
B241    B242    B243    B244    B245    B246    B247    B248    B249    B250    B251    B252
B253    B254    B255    B256    B257    B258    B259    B260    B261    B262    B263    B264
B265    B266    B267    B268    B269    B270    B271    B272    B273    B274    B275    B276
B277    B278    B279    B280    B281    B282    B283    B284    B285    B286    B287    B288
B289    B290    B291    B292    B293    B294    B295    B296    B297    B298    B299    B300
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B301    B302    B303    B304    B305    B306    B307    B308    B309    B310    B311    B312
B313    B314    B315    B316    B317    B318    B319    B320    B321    B322    B323    B324
B325    B326    B327    B328    B329    B330    B331    B332    B333    B334    B335    B336
B337    B338    B339    B340    B341    B342    B343    B344    B345    B346    B347    B348
B349    B350    B351    B352    B353    B354    B355    B356    B357    B358    B359    B360
B361    B362    B363    B364    B365    B366    B367    B368    B369    B370    B371    B372
B373    B374    B375    B376    B377    B378    B379    B380    B381    B382    B383    B384
B385    B386    B387    B388    B389    B390    B391    B392    B393    B394    B395    B396
B397    B398    B399    B400    B401    B402    B403    B404    B405    B406    B407    B408
B409    B410    B411    B412    B413    B414    B415    B416    B417    B418    B419    B420
B421    B422    B423    B424    B425    B426    B427    B428    B429    B430    B431    B432
B433    B434    B435    B436    B437    B438    B439    B440    B441    B442    B443    B444
B445    B446    B447    B448    B449    B450    B451    B452    B453    B454    B455    B456
B457    B458    B459    B460    B461    B462    B463    B464    B465    B466    B467    B468
B469    B470    B471    B472    B473    B474    B475    B476    B477    B478    B479    B480
B481    B482    B483    B484    B485    B486    B487    B488    B489    B490    B491    B492
B493    B494    B495    B496    B497    B498    B499    B500    B501    B502    B503    B504
B505    B506    B507    B508    B509    B510    B511    B512    B513    B514    B515    B516
B517    B518    B519    B520    B521    B522    B523    B524    B525    B526    B527    B528
B529    B530    B531    B532    B533    B534    B535    B536    B537    B538    B539    B540
B541    B542    B543    B544    B545    B546    B547    B548    B549    B550    B551    B552
B553    B554    B555    B556    B557    B558    B559    B560    B561    B562    B563    B564
B565    B566    B567    B568    B569    B570    B571    B572    B573    B574    B575    B576
B577    B578    B579    B580    B581    B582    B583    B584    B585    B586    B587    B588
B589    B590    B591    B592    B593    B594    B595    B596    B597    B598    B599    B600
B601    B602    B603    B604    B605    B606    B607    B608    B609    B610    B611    B612
B613    B614    B615    B616    B617    B618    B619    B620    B621    B622    B623    B624
B625    B626    B627    B628    B629    B630    B631    B632    B633    B634    B635    B636
B637    B638    B639    B640    B641    B642    B643    B644    B645    B646    B647    B648
B649    B650    B651    B652    B653    B654    B655    B656    B657    B658    B659    B660
B661    B662    B663    B664    B665    B666    B667    B668    B669    B670    B671    B672
B773    B774    B775    B776    B777    B778    B779    B780    B781    B782    B783    B784
B785    B786    B787    B788    B789    B790    B791    B792    B793    B794    B795    B796
Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3       Q 3
B797    B798    B799    B800    B801    B802    B803    B804    B805    B806    B807    B808
B809    B810    B811    B812    B813    B814    B815    B816    B817    B818    B819    B820
B821    B822    B823    B824    B825    B826    B827    B828    B829    B830    B831    B832
B833    B834    B835    B836    B837    B838    B839    B840    B841    B842    B843    B844
B845    B846    B847    B848    B849    B850    B851    B852    B853    B854    B855    B856
B857    B858    B859    B860    B861    B862    B863    B864    B865    B866    B867    B868
B869    B870    B871    B872    B873    B874    B875    B876    B877    B878    B879    B880
B881    B882    B883    B884    B885    B886    B887    B888    B889    B890    B891    B892
B893    B894    B895    B896    B897    B898    B899    B900    B901    B902    B903    B904
B905    B906    B907    B908    B909    B910    B911    B912    B913    B914    B915    B916
B917    B918    B919    B920    B921    B922    B923    B924    B925    B926    B927    B928
B929    B930    B931    B932    B933    B934    B935    B936    B937    B938    B939    B940
B941    B942    B943    B944    B945    B946    B947    B948    B949    B950    B951    B952
B953    B954    B955    B956    B957    B958    B959    B960    B961    B962    B963    B964
B965    B966    B967    B968    B969    B970    B971    B972    B973    B974    B975    B976
B977    B978    B979    B980    B981    B982    B983    B984    B985    B986    B987    B988
B989    B990    B991    B992    B993    B994    B995    B996    B997    B998    B999    B1000
B1001   B1002   B1003   B1004   B1005   B1006   B1007   B1008   B1009   B1010   B1011   B1012
B1013   B1014   B1015   B1016   B1017   B1018   B1019   B1020   B1021   B1022   B1023   B1024
B1025   B1026   B1027   B1028   B1029   B1030   B1031   B1032   B1033   B1034   B1035   B1036
B1037   B1038   B1039   B1040   B1041   B1042   B1043   B1044   B1045   B1046   B1047   B1048
B1049   B1050   B1051   B1052   B1053   B1054   B1055   B1056   B1057   B1058   B1059   B1060
B1061   B1062   B1063   B1064   B1065   B1066   B1067   B1068   B1069   B1070   B1071   B1072
B1073   B1074   B1075   B1076   B1077   B1078   B1079   B1080   B1081   B1082   B1083
表17：式Ir化合物：
Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6
Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6       Q 6
C1      C2      C3      C4      C5      C6      C7      C8      C9      C10     C11     C12
C13     C14     C15     C16     C17     C18     C19     C20     C21     C22     C23     C24
C25     C26     C27     C28     C29     C30     C31     C32     C33     C34     C35     C36
C37     C38     C39     C40     C41     C42     C43     C44     C45     C46     C47     C48
C49     C50     C51     C52     C53     C54     C55     C56     C57     C58     C59     C60
C61     C62     C63     C64     C65     C66     C67     C68     C69     C70     C71     C72
C73     C74     C75     C76     C77     C78     C79     C80     C81     C82     C83     C84
C85     C86     C87     C88     C89     C90     C91     C92     C93     C94     C95     C96
C97     C98     C99     C100    C101    C102    C103    C104    C105    C106    C107    C108
C109    C110    C111    C112    C113    C114    C115    C116    C117    C118    C119    C120
C121    C122    C123    C124    C125    C126    C127    C128    C129    C130    C131    C132
C133    C134    C135    C136    C137    C138    C139    C140    C141    C142    C143    C144
C145    C146    C147    C148    C149    C150    C151
表18：式Is化合物：
Figure C01804089D02041
Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7
D1      D2      D3      D4      D5      D6      D7      D8      D9      D10     D11     D12
D13     D14     D15     D16     D17     D18     D19     D20     D21     D22     D23     D24
D25     D26     D27     D28     D29     D30     D31     D32     D33     D34     D35     D36
D37     D38     D39     D40     D41     D42     D43     D44     D45     D46     D47     D48
D49     D50     D51     D52     D53     D54     D55     D56     D57     D58     D59     D60
D61     D62     D63     D64     D65     D66     D67     D68     D69     D70     D71     D72
D73     D74     D75     D76     D77     D78     D79     D80     D81     D82     D83     D84
D85     D86     D87     D88     D89     D90     D91     D92     D93     D94     D95     D96
D97     D98     D99     D100    D101    D102    D103    D104    D105    D106    D107    D108
D109    D110    D111    D112    D113    D114    D115    D116    D117    D118    D119    D120
Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7       Q 7
D121    D122    D123    D124    D125    D126    D127    D128    D129    D130    D131    D132
D133    D134    D135    D136    D137    D138    D139    D140
表19：式Iv化合物：
Figure C01804089D02051
化合物序号               R75
E1                       CH2OCH3
E2                       CH2OC2H5
E3                       CH2O-正丙基
E4                       CH2O-异丙基
E5                       CH2O-正丁基
E6                       CH2O-异丁基
E7                       CH2O-叔丁基
E8                       (CH2)2OCH3
E9                       (CH2)2O-乙基
E10                      (CH2)2O-正丙基
E11                      (CH2)2O-异丙基
E12                      (CH2)2O-正丁基
E13                      (CH2)2O-异丁基
E14                      (CH2)2O-叔丁基
E15                      (CH2)2O(CH2)2OCH3
E16                      (CH2)2O(CH2)2OCH3
E17                      C2H5
表20：表5-19的物理数据(数据＝m.p.，单位为℃)：
化合物       物理数据        化合物        物理数据          化合物        物理数据
A2           150-151         C46           159-161           A2-B1058      88-89
A3           148-149         C91           141-143           A2-B1066      粘稠物
A4           143-144         C146          99-101            A2-B1067      树脂油状物
A5           81-82           C149          148-150           A2-B1069      油状物
A6           148-150         A2-B1         90-92             A2-B1069      粘稠油状物
A7           105-106         A2-B68        120-121           A8-B1         97-98
A8           123-124         A2-B2         树脂状物          A7-B1         油状物
A9           73-74           A2-B90        树脂状物          A3-B1         42-44
A10          165-167         A2-B93        95-96             A94-B1        57-58
A15          164-166         A2-B46        61-62顺式-rac     A66-B24       80-82
A17          99-100          A2-B46        83-84反式-rac     A64-B1        49-51
A26          143-144         A2-B91        树脂状物          A154-B1       94-95
A27          107-108         A2-B1081      油状物            A6-B1         123-124
A29          173-174         A2-B1082      树脂状物          A6-B24        油状物
A30          178-181         A2-B1083      树脂状物          A34-B1        53-54
A31          209-210         A2-B29        87-88             A2-B25        油状物
A32          145-146         A2-B73        树脂状物          A2-B925       油状物
A34          170-171         A2-B95        106-107           E8            55-56
A64          134-135         A2-B31        151-153           E17           99-101
A94          134-135         A2-B75        无定形物
A154         108-110         A2-B24        油状物
B1057        166-167         A2-B5         树脂状物
B1058        结晶            A2-C91        树脂状物
B1061        结晶            A2-C146       油状物
B1063        结晶            A2-B112       树脂状物
B1065        油状物          A2-D140       油状物
B1066        150-152         A2-B1057      无定形物
B1067        122-123         A2-B1063      油状物
B1069        117-118         A2-B1061      油状物
B1070        结晶            A2-B133       油状物
式2.1和2.3-2.13.c化合物的名称是甲氧咪草烟、咪唑乙烟酸、咪唑喹啉酸、咪唑烟酸、二甲吩草胺、莠去津、特丁津、西玛津、特丁净、氰乙酰肼、莠灭净、甲氧去草净、调环酸钙、稀禾定、烯草酮、吡喃草酮(tepraloxydim)、唑嘧磺草胺、磺草唑胺、哒草特、溴苯腈、碘苯腈、磺草酮、唑酮草酯(carfentrazone)、甲磺草胺、异噁唑草酮、草铵膦、氟嘧磺隆、氟磺隆、砜嘧磺隆、氯吡嘧磺隆、烟嘧磺隆、乙氧嘧磺隆、啶嘧磺隆和噻吩磺隆，并且以下列条目号描述在《农药手册》(PesticideManual)，第11版，英国作物保护委员会(British Crop ProtectionCouncil)，1997中：412、415、414、413、240、34、692、651、693、168、20、691、595、648、146、49、339、495、626、88、425、664、112、665、436、382、589、613、644、389、519、287、325和704。其中Y1、Y3和Y4是次甲基，Y2是C-I，R74是C00Me，Y5是氮，Y6是甲基，且Y7是甲氧基的式2.13化合物以名称碘甲磺隆(尤其是钠盐)描述在AGROWNo.296，16th 1月1998，p.22中。其中Y1、Y2、Y3和Y4是次甲基，R74是三氟甲基，Y5是氮，Y6是三氟甲基，且Y7是甲氧基的式2.13化合物的名称是甲酰氨磺隆，并描述在DE-A-40 38 430中。其中Y1是NH-CHO，Y2、Y3和Y4是次甲基，R74是CONMe2，Y5是次甲基，且Y6和Y7是甲氧基的式2.13化合物描述在例如WO 95/29899中。
式2.12化合物的S对映体以CAS-Reg.No.[35597-44-5]登记。通式2.2化合物，aRS，1’S(-)N-(1’-甲基-2’-甲氧基-乙基)-N-氯乙酰基-2-乙基-6-甲基苯胺，和通式2.3化合物，(1S，aRS)-2-氯-N-(2，4-二甲基-3-噻吩基)-N-(2-甲氧基-1-甲基乙基)-乙酰胺描述在例如WO97/34485中。其中R69是NO2的式2.9化合物的名称是甲基磺草酮，并且描述在例如US-A-5 006 158中。其中R62是乙氧基，R63是氟，Y是次甲基，R64是甲氧基羰基，R65是氢，且R66是氯的式2.6化合物的名称是氯酯磺草胺(cloransulam)，并描述在例如AGROW No.261，2nd 8月1996，p.21中。其中R62是甲氧基，R63是氢，Y是C-F，R64是氟，R65是氢，且R66是氟的式2.6化合物的名称是双氟磺草胺，并描述在US-A-5 163 995中。
此外，本发明组合物的下列化合物描述在《农药手册》(PesticideManual)，第11版，英国作物保护委员会(British Crop ProtectionCouncil)，1997中：
式化合物(名称)           《农药手册》第11版，条目号
2.14(嗪草酮)              497
2.15(苯草醚)              8
2.16(草甘膦)              383
2.17(灭草松)              65
2.18(二甲戊灵)            557
2.19(麦草畏)              210
2.20(丁草敌)              100
2.22(异恶草松)            150
2.23(2，4-D)              192
2.24(氟烯草酸)            340
2.25(氟噻甲草酯)          359
2.26(呋草酮)              356
2.27(丙炔氟草胺)          341
2.28(百草枯)              550
2.29(唑啶草酮)            37
2.30(fluthiamid)          51
2.33(sulfosate)           383
2.34(磺草灵)              33
2.35(氟草敏)              526
2.36(特草定)              689
2.37(噻唑烟酸)            702
2.38(氟硫草定)            259
2.39(环嗪酮)              400
2.40(敌草隆)              260
2.41(MCPA)                455
2.42(甲氯丙酸)            459
2.43(丁噻隆)              683
其中R67是氢的式2.7化合物及其制备描述在US-A-3 790 571中；其中R62是乙氧基，Z是氮，R63是氟，R64是氯，R65是氢，且R66是氯的式2.6化合物描述在US-A-5 498 773中。式2.21化合物及其制备描述在US-A-5 183 492中；式2.22化合物以名称双环磺草酮描述在AGROW No.296，16th 1月1998，p.22中。式2.31化合物以名称四唑酰草胺描述在1997年英国作物保护会议-杂草，会议论文集(The 1997 British CropProtection Conference-Weeds，Conference Proceedings)Vol.1，2-8，p.67-72中；式2.32化合物以名称JV 485(isoxapropazol)描述在1997年英国作物保护会议-杂草，会议论文集Vol.1，3A-2，p.93-98中。式2.44化合物的名称是pethoxamid，并描述在EP-A-O 206 251中。式2.45化合物的名称是丙苯磺隆，并描述在EP-A-O 507 171中；式2.46化合物的名称是异丙吡草酯，并描述在例如US-A-5 530 126中。式2.47化合物的名称是吲哚酮草酯，并描述在例如DE-A-4 037 840中。式2.48化合物的名称是双苯嘧草酮，并描述在例如WO 97/08953中。式2.49化合物的名称是氟吡草腙，并描述在例如EP-A-O 646 315中。式2.50化合物(氨唑草酮)及其制备公开在DD 298 393和US-A-5 194 085中。式2.51化合物(flufenpyr-ethyl)描述在美国化学会论文文摘(Abstractsof Papers American Chemical Society)，(2000)Vol.220，No.部分1，pp.AGRO 174中。
非常令人惊奇的是，式I活性组分与一种或多种选自式2.1-2.51的活性组分的组合对欲控制杂草的作用超过了一般所预计的加和作用，因此扩大了单独活性组分的作用范围，尤其是在下列两个方面：首先，减小了单独的式2.1-2.51化合物的施用量，同时保持了良好的作用水平，其次，对于单独的活性物质以低施用量不可用的情况(从农学角度来看)，本发明组合物亦可获得良好的杂草控制水平。该结果是杂草谱的显著拓宽，并且提高了在有用植物农作物方面的选择性，如果发生了活性组分的非故意剂量过多，这样的结果是必须的并且希望的。在保持良好控制有用植物农作物中的杂草的同时，本发明组合物还使得在继代农作物中有更大的灵活性。
本发明组合物可用于抗大量在农业上很重要的杂草，例如繁缕属、豆瓣菜属、剪股颖属、马唐属、燕麦属、狗尾草属、芥属、毒麦属、茄属、菜豆属、稗属、藨草属、雨久花属、慈菇属、雀麦属、看麦娘属、石茅高梁、筒轴茅属、莎草属、苘麻属植物、黄花稔属、苍耳属、苋属、藜属、番薯属、苘蒿属、猪殃殃属、堇菜属和婆婆纳属。本发明组合物适用于农业中的所有常用施用方法，例如芽前施用、苗后施用和种子包衣。本发明组合物尤其适用于控制有用植物农作物例如禾谷类植物、油菜、甜菜、甘蔗、种植园农作物、稻、玉米和大豆中的杂草，以及适用于非选择性杂草控制。“农作物”还指通过常规育种或基因工程方法使其对除草剂或除草剂类别耐受的农作物。本发明还提供了控制有用植物农作物中不希望的植物生长的方法。该方法包括将除草有效量的本发明组合物作用于农作物植物或其场所。
本发明组合物包含任意混合比例的式I活性组分和式2.1-2.51活性组分，但是其中一种组分的量通常超过另一种组分的量。式I活性组分与式2.1-2.51混合配伍的混合比例(重量比)一般为1:2000-2000:1、尤其是200:1-1:200。
施用量可在宽的限度内变化，并取决于土壤性质、施用方法(芽前或苗后；种子包衣；播沟施用；非耕种施用等)、农作物植物、欲控制的杂草、主要的气候条件、和由施用方法控制的其它因素、施用时间和目标农作物。本发明活性组分混合物一般可以以1-5000g活性组分混合物/公顷的比例施用。
式I化合物与式式2.1-2.51化合物的混合物可以以未改性的形式使用，也就是说，以合成所获得的形式使用。然而，优选以常规方式将它们与制剂技术常用的助剂例如溶剂、固体载体或表面活性剂一起加工配制，例如配制成乳油、可直接喷雾或稀释的溶液、稀的乳剂、可湿性粉剂、可溶性粉剂、粉尘剂、粒剂或微胶囊。根据使用目的和主要环境来选择作为组合物性质的施用方法例如喷雾、雾化、撒布、润湿、撒施或浇泼。
制剂，即包含式I和式2.1-2.51化合物(活性组分)、以及适当时一种或多种固体或液体制剂助剂的组合物、制剂或混合物是以自身已知的方式制得的，例如通过将活性组分与制剂助剂例如溶剂或固体载体充分混合和/或研磨而制得。此外，在制剂的制备中可使用表面活性化合物(表面活性剂)。
溶剂和固体载体的实例描述在例如WO 97/34485第6页中。
根据欲配制的式I化合物的性质，合适的表面活性化合物是具有良好乳化、分散和润湿性质的非离子、阳离子和/或阴离子表面活性剂以及表面活性剂混合物。
合适的阴离子、非离子和阳离子表面活性剂描述在例如WO 97/34485第7和8页中。
制剂技术常用的表面活性剂也适用于本发明除草组合物的制备，这些表面活性剂特别描述在《McCutcheon洗涤剂和乳化剂年鉴》(″McCutcheon’s Detergents and Emulsifiers Annual″)MC PublishingCorp.，Ridgewood New Jersey，1981，Stache，H.，″Tensid-Taschenbuch″，Carl Hanser Verlag，Munich/Nienna，1981以及M.和J.Ash，《表面活性剂大全》(″Encyclopedia of Surfactants″)，Vol 1-111，Chemical Publishing Co.，New York，1980-81中。
除草制剂通常含有0.1-99％重量、尤其是0.1-95％重量的包含式I化合物和式2.1-2.51化合物的活性组分混合物，1-99.9％重量的固体或液体制剂助剂，和0-25％重量、尤其是0.1-25％重量的表面活性剂。
然而，市售产品一般是配制成浓缩物，最终的使用者通常使用稀释的制剂。组合物还可以含有其它组分，例如稳定剂如植物油或环氧化植物油(环氧化椰子油、菜籽油或豆油)，消泡剂例如硅油，防腐剂，粘度调节剂，粘合剂，增粘剂，以及肥料和其它活性组分。优选的制剂具有尤其是下列组成：
(％＝重量百分比)
乳油：
活性组分混合物：1-90％、优选5-20％
表面活性剂：    1-30％、优选10-20％
液体载体：      5-94％、优选70-85％
粉剂：
活性组分混合物：0.1-10％、优选0.1-5％
固体载体：      99.9-90％、优选99.9-99％
胶悬剂：
活性组分混合物：5-75％、优选10-50％
水：            94-24％、优选88-30％
表面活性剂：    1-40％、优选2-30％
可湿性粉剂：
活性组分混合物：0.5-90％、优选1-80％
表面活性剂：    0.5-20％、优选1-15％
固体载体：      5-95％、优选15-90％
粒剂：
活性组分混合物：0.1-30％、优选0.1-15％
固体载体：      99.5-70％、优选97-85％
下列实施例进一步举例说明了本发明，但不是限制本发明。
F1.乳油            a)          b)          c)            d)
活性组分混合物     5％         10％        25％          50％
十二烷基苯磺酸钙   6％         8％         6％           8％
蓖麻油聚乙二醇醚   4％         -           4％           4％
(36mol氧化乙烯)
辛基苯酚聚乙二醇醚 -           4％         -             2％
(7-8mol氧化乙烯)
环己酮             -           -           10％          20％
芳烃混合物         85％        78％        55％          16％
C9-C12
通过用水稀释，可由这样的乳油获得任意所需浓度的乳剂。
F2.溶液                           a)          b)          c)         d)
活性组分混合物                    5％         10％        50％       90％
1-甲氧基-3-(3-甲氧基丙氧基)-丙烷  -           20％        20％       -
聚乙二醇MW 400                    20％        10％        -          -
N-甲基-2-吡咯烷酮                 -           -           30％       10％
芳烃混合物                        75％        60％        -          -
C9-C12
该溶液适于以微滴的形式使用。
F3.可湿性粉剂        a)          b)         c)        d)
活性组分混合物       5％         25％       50％      80％
木质素磺酸钠         4％         -          3％       -
十二烷基硫酸钠       2％         3％        -         4％
二异丁基萘磺酸钠     -           6％        5％       6％
辛基苯酚聚乙二醇醚   -           1％        2％       -
(7-8mol氧化乙烯)
高度分散的硅酸       1％         3％        5％       10％
高岭土               88％        62％       35％      -
将活性组分与助剂充分混合，并将该混合物在合适的研磨机中磨碎，获得了可湿性粉剂，可以用水稀释以获得任意所需浓度的悬浮剂。
F4.包衣粒剂           a)            b)           c)
活性组分混合物        0.1％         5％          15％
高度分散的硅酸        0.9％         2％          2％
无机载体              99.0％        93％         83％
(φ0.1-1mm)
例如CaCO3或SiO2
将活性组分溶解在二氯甲烷中，通过喷雾施加到载体上，然后将溶剂真空蒸发。
F5.包衣粒剂             a)         b)         c)
活性组分混合物          0.1％      5％        15％
聚乙二醇MW200           1.0％      2％        3％
高度分散的硅酸          0.9％      1％        2％
无机载体                98.0％     92％       80％
(φ0.1-1mm)
例如CaCO3或SiO2
在混合器中将细研磨的活性组分均匀地施加到用聚乙二醇润湿的载体上。以该方式获得了无粉尘的包衣粒剂。
F6.挤出粒剂             a)          b)         c)         d)
活性组分混合物          0.1％       3％        5％        15％
木质素磺酸钠            1.5％       2％        3％        4％
羧甲基纤维素            1.4％       2％        2％        2％
高岭土                  97.0％      93％       90％       79％
将活性组分混合，与助剂研磨，用水将该混合物润湿。将该混合物挤出，然后在气流中干燥。
F7.粉剂                 a)          b)            c)
活性组分混合物          0.1％       1％           5％
滑石粉                  39.9％      49％          35％
高岭土                  60.0％      50％          60％
即用型粉尘剂是通过将活性组分与载体混合、并将混合物在合适的研磨机中研磨而获得的。
F8.胶悬剂          a)        b)       c)        d)
活性组分混合物       3％        10％       25％        50％
乙二醇               5％        5％        5％         5％
壬基苯酚聚乙二醇醚   -          1％        2％         -
(15mol氧化乙烯)
木质素磺酸钠         3％        3％        4％         5％
羧甲基纤维素         1％        1％        1％         1％
37％甲醛水溶液       0.2％      0.2％      0.2％       0.2％
硅油乳液             0.8％      0.8％      0.8％       0.8％
水                   87％       79％       62％        38％
将细研磨的活性组分与助剂充分混合，获得了胶悬剂，通过用水稀释可由其获得任意所需浓度的悬浮液。
实际上更经常将式I化合物与式2.1-2.51混合伴侣单独配制，临用前在施用器中将其以所需混合比例以“桶混”的形式混合在一起。
生物实施例：
当式I与2.1-2.51化合物的活性组分组合的作用大于单独施用的活性组分的作用之和时，即存在协同作用。
对于给定的两种除草剂组合，预计的除草作用We可如下计算(参见COLBY，S.R.，″计算除草剂组合的协同和拮抗反应″，《杂草》(Weeds)15，p.20-22，1967)：
We＝X+[Y·(100-X)/100]
其中：
X＝与未处理的对照(＝0％)相比，在用式I化合物以p kg/公顷的施用量处理时的除草作用百分比。
Y＝与未处理的对照相比，在用式2.1-2.51化合物以q kg/公顷的施用量处理时的除草作用百分比。
We＝在用式I和2.1-2.51化合物以p+q kg/公顷的施用量处理后，预计的除草作用(与未处理的对照相比，除草作用百分比)。
当实际上观测到的作用大于预计的We的值时，即存在协同作用。
在下列实施例中证实了式I化合物与式2.1-2.51化合物的组合的协同作用。
实验描述-芽前测试：
将塑料盆内的标准土壤中播种单子叶和双子叶测试植物。播种后，立即通过喷雾施用水悬浮液形式的测试物(500升水/ha)。施用量取决于在大田条件和温室条件下确定的最适剂量。然后让测试植物在温室中于最适条件下生长。36天后评价测试(％作用，100％＝植物已经死亡，0％＝没有植物毒害作用)。本发明组合物的协同作用的实例如下表B1-B6所示：
混合物A含有915g/升式2.2a化合物和45g/升式3.1化合物作为活性组分。
表B1：
 
测试植物： 化合物1.001[25g/ha]    混合物A[900g/ha] 化合物1.001[25g/ha]+混合物A[900g/ha]      依据Colby的We
高粱 30 20 90 44
藜 0 0 100 0
黄花稔 0 70 100 70
表B2：
 
测试植物： 化合物1.001[12.5g/ha]  混合物A[900g/ha] 化合物1.001[12.5g/ha]+混合物A[900g/ha]        依据Colby的We        
高粱 0 20 80 20
藜 0 0 95 0
黄花稔 0 70 95 70
表B3：
 
测试植物： 化合物1.001[6.25g/ha]  混合物A[900g/ha] 化合物1.001[6.25g/ha]+混合物A[900g/ha]        依据Colby的We        
高粱 0 20 70 20
藜 0 0 95 0
黄花稔 0 70 95 70
表B4：
 
测试植物： 化合物1.001[25g/ha]    混合物A[300g/ha] 化合物1.001[25g/ha]+混合物A[300g/ha]      依据Colby的We
藜 0 0 90 0
番薯 30 0 100 30
黄花稔 0 0 40 0
表B5：
 
测试植物： 化合物1.001[12.5g/ha]  混合物A[300g/ha] 化合物1.001[12.5g/ha]+混合物A[300g/ha]        依据Colby的We        
藜 0 0 80 0
番薯 0 0 60 0
黄花稔 0 0 40 0
表B6：
 
测试植物： 化合物1.001[6.25g/ha]  混合物A[300g/ha] 化合物1.001[6.25g/ha]+混合物A[300g/ha]        依据Colby的We        
藜 0 0 80 0
番薯 0 0 60 0
黄花稔 0 0 40 0
实验描述-苗后测试：
将测试植物在塑料盆中于温室条件下生长至2-叶-3-叶期。使用标准土壤作为栽培基质。在2-叶-3-叶期，将除草剂以自身的形式并作为混合物施加到测试植物上。施加是用测试物在500升水/ha中的水悬浮液进行的。施用量取决于在大田条件和温室条件下确定的最适剂量。33天后评价测试(％作用，100％＝植物已经死亡，0％＝没有植物毒害作用)。本发明组合物的协同作用的实例如下表B7-B10所示：
混合物A含有915g/升式2.2a化合物和45g/升式3.1化合物作为活性组分。
表B7：苗后测试：
 
测试植物： 化合物1.001[12.5g/ha]  混合物A[900g/ha] 化合物1.001[12.5g/ha]+混合物A[900g/ha]        依据Colby的We        
番薯 0 0 80 0
蓼 0 20 100 20
苍耳 80 0 100 80
表B8：苗后测试：
 
测试植物： 化合物1.001[12.5g/ha]  混合物A[300g/ha] 化合物1.001[12.5g/ha]+混合物A[300g/ha]        依据Colby的We        
番薯 0 0 80 0
蓼 0 0 70 0
苍耳 80 0 98 80
表B9：苗后测试：
 
测试植物： 化合物1.001[6.25g/ha]  混合物A[900g/ha] 化合物1.001[6.25g/ha]+混合物A[900g/ha]        依据Colby的We        
番薯 0 0 70 0
蓼 0 20 70 20
苍耳 70 0 80 70
表B10：苗后测试：
 
测试植物： 化合物1.001[6.25g/ha]  混合物A[300g/ha] 化合物1.001[6.25g/ha]+混合物A[300g/ha]        依据Colby的We        
番薯 0 0 80 0
蓼 0 0 70 0
苍耳 70 0 70 70
在下表中，是在14天后进行评价：
表B11：芽前作用：
 
测试植物： 化合物E8[50g/ha] 化合物2.18[500g/ha]  化合物E8[50g/ha]+化合物2.18[500g/ha] 依据Colby的We
蓼 50 80 95 90
表B12：芽前作用：
 
测试植物： 化合物E8[100g/ha] 化合物2.14[250g/ha]  化合物E8[100g/ha]+化合物2.14[250g/ha] 依据Colby的We
蓼 50 50 90 75
表B13：芽前作用：
 
测试植物： 化合物E8[100g/ha] 化合物2.14[125g/ha]  化合物E8[100g/ha]+化合物2.14[125g/ha] 依据Colby的We
蓼 50 30 90 65
表B14：芽前作用：化合物2.13a相当于这样的式2.13化合物，其中R74是-CH2CH2CF3，Y1、Y2、Y3和Y4各是次甲基，Y5是氮，且Y6是甲基。
 
测试植物： 化合物E8[100g/ha] 化合物2.13a[60g/ha]    化合物E8[100g/ha]+化合物2.13a[60g/ha] 依据Colby的We
蓼 50 80 95 90
表B15：芽前作用：
 
测试植物： 化合物E8[50g/ha] 化合物2.30[60g/ha]   化合物E8[50g/ha]+化合物2.30[60g/ha] 依据Colby的We
蓼 50 30 90 65
表B16：芽前作用：
 
测试植物： 化合物E8[50g/ha] 化合物2.21[30g/ha]   化合物E8[50g/ha]+化合物2.21[30g/ha] 依据Colby的We
蓼 50 50 100 75
表B17：芽前作用：化合物2.4.a相当于其中R57是氯、R58是乙基、且R59是叔丁基的式2.4化合物。
 
测试植物： 化合物E8[50g/ha] 化合物2.4.a[125g/ha]   化合物E8[50g/ha]+化合物2.4.a[125g/ha] 依据Colby的We
蓼 50 30 85 65
表B18：芽前作用：
 
测试植物： 化合物1.001[25g/ha]    化合物2.2.b[300g/ha]   化合物1.001[25g/ha]+化合物2.2.b[300g/ha]         依据Colby的We        
藜 80 0 95 80
茄 80 40 98 88
莎草 0 0 50 0
表B19：芽前作用：
化合物2.3.a相当于其中R56是CH(Me)-CH2OMe的式2.3化合物。
 
测试植物： 化合物1.001[12.5g/ha]  化合物2.3.a[100g/ha]   化合物1.001[12.5g/ha]+化合物2.3.a[100g/ha]         依据Colby的We        
藜 80 20 90 84
茄 75 60 90 90
莎草 0 20 60 20
表B20：芽前作用：
化合物2.2.c相当于其中R53和R54是乙基，且R55是CH2OMe的式2.2化合物。
 
测试植物： 化合物1.001[12.5g/ha]  化合物2.2.c[100g/ha]   化合物1.001[12.5g/ha]+化合物2.2.c[100g/ha]         依据C0lby的We        
藜 80 20 90 84
茄 75 50 95 88
莎草 0 0 30 0
表B21：芽前作用：
化合物2.2.d相当于其中R53是乙基、R54是甲基、且R55是CH2O-CH2CH3的式2.2化合物。
 
测试植物： 化合物1.001[12.5g/ha]  化合物2.2.d[100g/ha]   化合物1.001[12.5g/ha]+化合物2.2.d[100g/ha]         依据Colby的We        
茄 75 60 95 90
表B22：芽前作用：
 
测试植物： 化合物1.001[25g/ha]    化合物2.30[100g/ha]  化合物1.001[25g/ha]+化合物2.30[100g/ha]  依据Colby的We
莎草 10 0 60 10
在下表中，是在31天后进行评价：
表B23：芽前作用：化合物2.4.a相当于其中R57是氯、R58是乙基、且R59是异丙基的式2.4化合物。
 
测试植物： 化合物1.001[25g/ha]    化合物2.4.a[250g/ha]   化合物1.001[25g/ha]+化合物2.4.a[250g/ha]         依据Colby的We        
蓼 0 20 80 20
表B24：芽前作用：化合物2.4.b相当于其中R57是氯、R58是乙基、且R59是乙基的式2.4化合物。
 
测试植物： 化合物1.001[25g/ha]    化合物2.4.b[125g/ha]   化合物1.001[25g/ha]+化合物2.4.b[125g/ha]         依据Colby的We        
蓼 0 0 40 0
表B25：芽前作用：化合物2.4.c相当于其中R57是氯、R58是乙基、且R59是叔丁基的式2.4化合物。
 
测试植物： 化合物1.001[25g/ha]    化合物2.4.c[250g/ha]   化合物1.001[25g/ha]+化合物2.4.c[250g/ha]         依据Colby的We        
番薯 70 0 90 70
苍耳 80 0 100 80
表B26：芽前作用：化合物2.4.d相当于其中R57是甲硫基、R58是乙基、且R59是叔丁基的式2.4化合物。
 
测试植物： 化合物1.001[25g/ha]    化合物2.4.d[250g/ha]   化合物1.001[25g/ha]+化合物2.4.d[250g/ha]         依据Colby的We        
番薯 70 0 80 70
苍耳 80 10 95 82
表B27：芽前作用：
 
测试植物： 化合物1.001[25g/ha]    化合物2.14[125g/ha]  化合物1.001[25g/ha]+化合物2.14[125g/ha]  依据Colby的We
番薯 70 0 85 70
苍耳 80 20 100 84
表B28：芽前作用：化合物2.6.a相当于这样的式2.6化合物，其中R62是氢、R63是甲基、R64是氟、R65是氢、Y是氮、Z是次甲基、且R66是氟。
 
测试植物： 化合物1.001[50g/ha]    化合物2.6.a[30g/ha]    化合物1.001[50g/ha]+化合物2.6.a[30g/ha]  依据Colby的We
蓼 0 30 90 30
在下表中，是在21天后进行评价。
表B29：苗后作用：化合物2.7.a相当于其中R67是-C(O)-S-正辛基的式2.7化合物。
 
测试植物： 化合物1.001[25g/ha]    化合物2.7.a[250g/ha]   化合物1.001[25g/ha]+化合物2.7.a[250g/ha]         依据Colby的We        
番薯 30 10 80 30
蓼 75 0 95 75
苍耳 90 10 100 91
表B30：苗后作用：
 
测试植物： 化合物1.001[25g/ha]    化合物2.19[250g/ha]  化合物1.001[25g/ha]+化合物2.19[250g/ha]  依据Colby的We
番薯 30 60 95 72
表B31：苗后作用：
 
测试植物： 化合物1.001[25g/ha]    化合物2.16[360g/ha]  化合物1.001[25g/ha]+化合物2.16[360g/ha]  依据Colby的We
番薯 30 20 70 46
蓼 75 10 90 84
表B32：苗后作用：
 
测试植物： 化合物1.001[12.5g/ha]  化合物2.33[360g/ha]  化合物1.001[12.5g/ha]+化合物2.33[360g/ha]  依据Colby的We        
蓼 30 0 90 30
表B33：苗后作用：化合物2.12.a相当于其中R73是NH2的式2.12化合物。
 
测试植物： 化合物1.001[25g/ha]    化合物2.12.a[400g/ha]    化合物1.001[25g/ha]+化合物2.33.a[400g/ha] 依据Colby的We        
番薯 30 20 90 44
表B34：苗后作用：
 
测试植物： 化合物1.001[12.5g/ha]  化合物2.25[2g/ha]    化合物1.001[12.5g/ha]+化合物2.25[2g/ha]    依据Colby的We        
番薯 30 0 50 30
蓼 30 0 40 30
表B35：苗后作用：化合物2.1.a相当于其中R52是氢、且R51是乙基的式2.1化合物。
 
测试植物： 化合物1.001[12.5g/ha]  化合物2.1.a[30g/ha]    化合物1.001[12.5g/ha]+化合物2.1.a[30g/ha]  依据Co1by的We         
蓼 30 30 70 51
表B36：苗后作用：化合物2.1.b相当于其中R51是CH2OMe、且R52是氢的式2.1化合物。
 
测试植物： 化合物1.001[25g/ha]    化合物2.1.b[30g/ha]    化合物1.001[25g/ha]+化合物2.1.b[30g/ha]  依据Colby的We        
蓼 75 30 90 83
在下表中，是在23天后进行评价：
表B37：芽前作用：化合物2.13.b相当于这样的式2.13化合物，其中R74是-COOMe，Y1、Y2、Y3和Y4各是次甲基，Y5是次甲基，且Y6和Y7是二氟甲氧基。
 
测试植物： 化合物1.001[6g/ha]     化合物2.13.b[15g/ha]     化合物1.001[6g/ha]+化合物2.13.b[15g/ha] 依据Co1by的We         
藜 50 70 95 85
表B38：芽前作用：
 
测试植物： 化合物1.001[6g/ha]     化合物2.13.c[60g/ha]     化合物1.001[6g/ha]+化合物2.13.c[60g/ha] 依据Colby的We        
藜 50 10 85 55
表B39：芽前作用：化合物2.13.d相当于这样的式2.13化合物，其中Y1、Y2、Y3和Y4是次甲基，R74是三氟甲基，Y5是氮，Y6是三氟甲基，且Y7是甲氧基。
 
测试植物： 化合物1.001[6g/ha]     化合物2.13.d[7.5g/ha]    化合物1.001[6g/ha]+化合物2.13.d[7.5g/ha] 依据Colby的We        
苋 10 80 95 82
已经令人惊奇地表明，特定的安全剂适于和本发明协同组合物混合。因此，本发明还涉及用于控制有用植物农作物、尤其是玉米农作物中的禾草和杂草的选择性除草组合物，所述组合物包含式I化合物、一种或多种选自式2.1-2.51化合物的化合物、和安全剂(对抗剂、解毒剂)，所述组合物保护有用植物、但是不保护杂草，并对抗除草剂的植物毒害作用，以及这样的组合物在控制有用植物中的杂草中的应用。
本发明还提供了选择性除草组合物，所述组合物除了包含常用惰性制剂助剂例如载体、溶剂和润湿剂以外，还包含下列组分的混合物作为活性组分：
a)除草协同有效量的式I化合物和一种或多种选自式2.1-2.51化合物的化合物，和
b)除草拮抗有效量的选自下列的化合物：
式3.1化合物
和式3.2化合物
Figure C01804089D02261
和式3.3化合物
和式3.4化合物
Figure C01804089D02263
和式3.5化合物
Figure C01804089D02264
和式3.6化合物
Figure C01804089D02265
和式3.7化合物
Figure C01804089D02271
和式3.8化合物
Figure C01804089D02272
和式3.9化合物
Cl2CHCON(CH2CH＝CH2)2(3.9)，
和式3.10化合物
Figure C01804089D02273
和式3.11化合物
Figure C01804089D02274
和式3.12化合物
Figure C01804089D02281
及其乙酯
和式3.13化合物
Figure C01804089D02282
和式3.14化合物
Figure C01804089D02283
和式3.15化合物
和式3.16化合物
Figure C01804089D02291
本发明还提供了选择性除草组合物，所述组合物除了包含常用惰性制剂助剂例如载体、溶剂和润湿剂以外，还包含下列组分的混合物作为活性组分：
a)除草有效量的式I化合物，和
b)除草拮抗有效量的选自式3.1、3.2、3.3、3.4、3.5、3.6、3.7、3.8、3.9、3.10、3.11、3.12、3.13、3.14、3.15和3.16化合物的化合物。
优选的本发明组合物包含选自式3.1、3.3和3.8化合物的化合物作为安全剂。这样安全剂尤其适用于包含上述优选的式I化合物和任选的式2.1-2.51化合物的本发明组合物。
已经表明，式I化合物与式3.1化合物的组合是特别有效的组合物，化合物1.001是特别优选的式I化合物。该组合物优选与式2.2a化合物一起使用
Figure C01804089D02292
(2.2a，aRS，1’S(-)N-(1’-甲基-2’-甲氧基乙基)-N-氯乙酰基-2-乙基-6-甲基苯胺)。
本发明还涉及选择性地控制有用植物农作物中的杂草的方法，所述方法包括用除草有效量的式I除草剂、视情况而定的一种或多种选自式2.1-2.51化合物的除草剂、和除草拮抗有效量的式3.1-3.16安全剂来处理有用植物、种子或其切条、或其耕作区域。
式3.1-3.16化合物是已知的，并描述在例如《农药手册》，第11版，英国作物保护委员会，1997中，条目号为61(式3.1，解草嗪)、304(式3.2，解草啶)、154(式3.3，解草酯)、462(式3.4，吡咯解草酯)、377(式3.5，解草恶唑)、363(式3.8，氟草肟)、213(式3.9，烯丙酰草胺)和350(式3.10，解草胺)。式3.11化合物的名称是MON 4660(Monsanto)，并描述在例如EP-A-O 436 483中。
式3.6化合物(AC 304 415)描述在例如EP-A-0 613 618中，式3.7化合物描述在DE-A-2 948 535中。式3.12化合物描述在DE-A-4 331 448中，式3.13化合物描述在DE-A-3 525 205中。式3.14化合物是已知的，描述在例如US-A-5 215 570中，式3.15化合物描述在例如EP-A-O 929543中。式3.16化合物描述在WO 99/00020中。除了式3.16化合物以外，描述在WO 99/00020中的其它3-(5-四唑基-羰基)-2-喹诺酮，尤其是在第21-29页的表1和2中具体公开的化合物也适于保护农作物植物抗式I化合物的植物毒害作用。
作为可通过式3.1-3.16安全剂拮抗上述除草剂损害作用而得以保护的农作物植物，可尤其提及的有禾谷类植物、棉花、大豆、甜菜、甘蔗、种植园农作物、油菜、玉米和稻，更尤其是玉米。“农作物”还指通过常规育种或基因工程方法使其对除草剂或除草剂类别耐受的农作物。
欲控制的杂草既可以是单子叶杂草，也可以是双子叶杂草，例如繁缕属、剪股颖属、马唐属、燕麦属、阿披拉草属、臂形草属、草属、狗尾草属、芥属、毒麦属、茄属、稗属、藨草属、雨久花属、慈菇属、黍属、雀麦属、看麦娘属、石茅高梁、双色高梁、筒轴茅属、莎草属、苘麻属、黄花稔属、苍耳属、苋属、藜属、番薯属、苘蒿属、猪殃殃属、堇菜属和婆婆纳属。
耕作区域包括农作物植物已经生长或者已经将这些农作物植物的种子播种的土地区域，以及准备用这样的农作物植物耕作的土地。
根据预期应用，式3.1-3.16安全剂可以在农作物植物种子的预处理中使用(种子或切条的包衣)，或者可以在播种前或播种后引入到土壤中。然而，其可以在植物出芽后单独施用或者与除草剂一起施用。因此，用安全剂处理植物或种子一般可以在独立于施用除草剂的时间进行。然而，也可以通过同时施用除草剂和安全剂(例如以桶混的形式)来处理植物。安全剂的施用量与除草剂的施用量的比例主要取决于施用方法。对于通过使用包含安全剂和除草剂的组合的桶混物或者通过单独施用安全剂和除草剂来进行的大田处理，除草剂与安全剂的比例一般为100:1-1:10、优选20:1-1:1。对于大田处理，通常施用0.001-0.5千克安全剂/公顷、优选0.001-0.25千克安全剂/公顷。
除草剂的施用量一般为0.001-5kg/ha，但是优选为0.005-0.5kg/ha。
本发明组合物适用于农业中的所有常用方法，例如芽前施用、苗后施用和种子包衣。
对于种子包衣，一般施用0.001-10g安全剂/kg种子、优选0.05-2g安全剂/kg种子。当在播种前不久安全剂以液体形式通过浸泡施用时，有利起见，所用的安全剂溶液含有浓度为1-10 000ppm、优选为100-1000ppm的安全剂。
为了施用，有利起见，将式3.1-3.16安全剂或者这些安全剂与式I除草剂以及视情况而定的一种或多种选自式2.1-2.51的除草剂的组合与制剂技术中的常用制剂一起加工配制，例如配制成乳油、可包衣糊剂、可直接喷雾或稀释的溶液、可湿性粉剂、可溶性粉剂、粉剂、粒剂或微胶囊。
这样的制剂描述在例如WO 97/34485第9-13页中。制剂是以自身已知的方式制得的，例如通过将活性组分与制剂助剂例如溶剂或固体载体充分混合和/或研磨而制得。此外，在制剂的制备中可使用表面活性化合物(表面活性剂)。溶剂和固体载体的实例描述在例如WO 97/34485第6页中。
根据欲配制的式I、2.1-2.51和3.1-3.16化合物的性质，可使用的表面活性化合物是具有良好乳化、分散和润湿性质的非离子、阳离子和/或阴离子表面活性剂以及表面活性剂混合物。合适的阴离子、非离子和阳离子表面活性剂描述在例如WO 97/34485第7和8页中。制剂技术常用的表面活性剂也适用于本发明除草组合物的制备，这些表面活性剂特别描述在《McCutcheon洗涤剂和乳化剂年鉴》″McCutcheon’s Detergentsand Emulsifiers Annual″MC Publishing Corp.，Ridgewood New Jersey，1981，Stache，H.，″Tensid-Taschenbuch″，Carl Hanser Verlag，Munich/Nienna，1981和M.and J.Ash，《表面活性剂大全》(″Encyclopedia of Surfactants″)，Vol 1-111，Chemical PublishingCo.，New York，1980-81中。
除草制剂通常含有0.1-99％重量、尤其是0.1-95％重量的包含式I化合物、选自式2.1-2.51化合物的化合物、和式3.1-3.16化合物的活性组分混合物，1-99.9％重量的固体或液体制剂助剂，和0-25％重量、尤其是0.1-25％重量的表面活性剂。然而，市售产品一般是配制成浓缩物，最终的使用者通常使用稀释的制剂。
组合物还可以含有其它组分，例如稳定剂如植物油或环氧化植物油(环氧化椰子油、菜籽油或豆油)，消泡剂例如硅油，防腐剂，粘度调节剂，粘合剂，增粘剂，以及肥料和其它活性组分。在保护植物以对抗式I和2.1-2.51除草剂的损害作用的过程中，为了使用式3.1-3.16安全剂或包含它们的组合物，可使用多种不同的方法和技术，例如下列：
i)种子包衣
a)通过在容器中振摇用式3.1-3.16化合物的可湿性粉剂将种子包衣，直至粉剂在种子表面上分布均匀(干法包衣)。在该方法中，每100kg种子使用大约1-500g式3.1-3.16化合物(4g-2kg可湿性粉剂)。
b)按照a)的方法，用式3.1-3.16化合物的乳油将种子包衣(湿法包衣)。
c)通过将种子在含有100-1000ppm式3.1-3.16化合物的液体中浸泡1-72小时，然后任选将种子干燥来进行包衣(浸泡包衣)。
给种子包衣或处理发芽的幼苗是优选的施用方法，因为用活性组分处理完全是针对目标农作物。通常每100kg种子使用1-1000g解毒剂、优选5-250g解毒剂，但是根据使得能够还加入其它组分或微量营养素的方法，该浓度限度可向上或向下改变(重复包衣)。
ii)作为桶混物施用
使用解毒剂与除草剂的混合物(二者的重量比为10:1-1:100)的液体制剂，除草剂的施用量为0.005-5.0kg/公顷。这样的桶混物在播种之前或之后施用。
iii)施用到播沟中
将式3.1-3.16混合物以乳油、可湿性粉剂或粒剂的形式施加到开放的播种种子的犁沟内。一旦种子犁沟已覆盖，即以常规方式采用芽前法施用除草剂。
iv)控制活性组分的释放
将在溶液中的式3.1-3.16化合物施加到无机物载体或聚合颗粒(尿素/甲醛)上，并干燥。如果需要的话，还可以施加上使得活性组分在特定时间内以计量的量释放的包衣(包衣粒剂)。
优选的制剂尤其具有下列组成：
(％＝重量百分比)
乳油：
活性组分混合物：1-90％、优选5-20％
表面活性剂：    1-30％、优选10-20％
液体载体：      5-94％、优选70-85％
粉剂：
活性组分混合物：0.1-10％、优选0.1-5％
固体载体：      99.9-90％、优选99.9-99％
胶悬剂：
活性组分混合物：5-75％、优选10-50％
水：            94-24％、优选88-30％
表面活性剂：    1-40％、优选2-30％
可湿性粉剂：
活性组分混合物：0.5-90％、优选1-80％
表面活性剂：    0.5-20％、优选1-15％
固体载体：      5-95％、优选15-90％
粒剂：
活性组分混合物：0.1-30％、优选0.1-15％
固体载体：      99.5-70％、优选97-85％
下列实施例进一步举例说明了本发明，但不是限制本发明。
式I除草剂、任选的式2.1-2.51除草剂、和式3.1-3.16安全剂的混合物的制剂实施例(％＝重量百分比)
F1.乳油             a)            b)         c)        d)
活性组分混合物      5％           10％       25％      50％
十二烷基苯磺酸钙    6％           8％        6％       8％
蓖麻油聚乙二醇醚    4％           -          4％       4％
(36mol氧化乙烯)
辛基苯酚聚乙二醇醚  -             4％        -         2％
(7-8mol氧化乙烯)
环己酮              -             -          10％      20％
芳烃混合物          85％          78％       55％      16％
C9-C12
通过用水稀释，可由这样的乳油获得任意所需浓度的乳剂。
F2.溶液                a)            b)           c)          d)
活性组分混合物         5％           10％         50％        90％
1-甲氧基-3-(3-甲氧基-  -             20％         20％        -
丙氧基)-丙烷
聚乙二醇MW 400         20％          10％         -           -
N-甲基-2-吡咯烷酮      -             -            30％        10％
芳烃混合物             75％          60％         -           -
C9-C12
该溶液适于以微滴的形式使用。
F3.可湿性粉剂           a)           b)           c)           d)
活性组分混合物          5％          25％         50％         80％
木质素磺酸钠            4％          -            3％          -
十二烷基硫酸钠          2％          3％          -            4％
二异丁基萘磺酸钠        -            6％          5％          6％
辛基苯酚聚乙二醇醚      -            1％          2％          -
(7-8mol氧化乙烯)
高度分散的硅酸          1％          3％          5％          10％
高岭土                  88％         62％         35％         -
将活性组分与助剂充分混合，并将该混合物在合适的研磨机中磨碎，获得了可湿性粉剂，可以用水稀释以获得任意所需浓度的悬浮剂。
F4.包衣粒剂           a)           b)           c)
活性组分混合物        0.1％        5％          15％
高度分散的硅酸        0.9％        2％          2％
无机载体              99.0％       93％         83％
(φ0.1-1mm)
例如CaCO3或SiO2
将活性组分溶解在二氯甲烷中，通过喷雾施加到载体上，然后将溶剂真空蒸发。
F5.包衣粒剂           a)           b)           c)
活性组分混合物        0.1％        5％          15％
聚乙二醇MW 200        1.0％        2％          3％
高度分散的硅酸        0.9％        1％          2％
无机载体              98.0％       92％         80％
(φ0.1-1mm)
例如CaCO3或SiO2
在混合器中将细研磨的活性组分均匀地施加到用聚乙二醇润湿的载体上。以该方式获得了无粉尘的包衣粒剂。
F6.挤出粒剂           a)           b)           c)           d)
活性组分混合物        0.1％        3％          5％          15％
木质素磺酸钠          1.5％        2％          3％          4％
羧甲基纤维素          1.4％        2％          2％          2％
高岭土                97.0％       93％         90％         79％
将活性组分混合，与助剂研磨，用水将该混合物润湿。将该混合物挤出，然后在气流中干燥。
F7.粉尘剂           a)           b)           c)
活性组分混合物      0.1％        1％          5％
滑石粉              39.9％       49％         35％
高岭土              60.0％       50％         60％
即用型粉尘剂是通过将活性组分与载体混合、并将混合物在合适的研磨机中研磨而获得的。
F8.胶悬剂           a)           b)           c)           d)
活性组分混合物      3％          10％         25％         50％
乙二醇              5％          5％          5％          5％
壬基苯酚聚乙二醇醚  -            1％          2％          -
(15mol氧化乙烯)
木质素磺酸钠        3％          3％          4％          5％
羧甲基纤维素        1％          1％          1％          1％
37％甲醛水溶液      0.2％        0.2％        0.2％        0.2％
硅油乳液            0.8％        0.8％        0.8％        0.8％
水                  87％         79％         62％         38％
将细研磨的活性组分与助剂充分混合，获得了胶悬剂，通过用水稀释可由其获得任意所需浓度的悬浮液。
实际上更经常将式I化合物、式2.1-2.51化合物和式3.1-3.16化合物单独配制，临用前在施用器中将其以所需混合比例以“桶混”的形式混合在一起。
下列实施例举例说明了式3.1-3.16安全剂保护农作物植物对抗式I除草剂的植物毒害作用的能力。
生物实施例：安全作用
将测试植物在塑料盆中于温室条件下生长至4-叶期。在该阶段将单独的除草剂、除草剂与作为安全剂测试的化合物的混合物施加到测试植物上。以用500升水/公顷由25％可湿性粉剂(实施例F3，b)制得的测试化合物的水悬浮液的形式施用。施用4周后，使用百分比标度评价除草剂对农作物植物例如玉米和禾谷类植物的毒害作用，100％是指测试植物已经死亡，0％是指没有任何植物毒害作用。
在该测试中获得的结果证实了式3.1-3.16化合物可显著减轻由式I除草剂与一种或多种式2.1-2.51除草剂的组合所引起的农作物植物损害。安全作用的实例如下表B40所示：
表B40：
 
测试植物 化合物1.001[50g/ha]          化合物1.001[50g/ha]+化合物3.3[50g/ha]    化合物1.001[50g/ha]+化合物3.1[50g/ha]    化合物1.001[50g/ha]+化合物3.8[50g/ha]
玉米 50 5 5 0
苘麻 100 100 100 100
狗尾草 100 100 100 100
当依据实施例F1、F2和F4-F8配制混合物时，获得了相同结果。

Claims (4)

1.一种选择性除草组合物，所述组合物除了含有常规惰性制剂助剂以外，还含有下列组分的混合物作为活性组分：
a)除草有效量的式Ia化合物或其农业可接受盐
Figure C01804089C00021
其中
R48是-CH3或-CH2OCH2CH2OCH3；
R49是氢；
R50是-CF3；以及
Q是基团Q2
Figure C01804089C00022
其中R23是羟基；以及
Y是C1亚烷基桥；
和
b)协同有效量的一种或多种选自下述的化合物：
式2.2化合物
Figure C01804089C00023
其中R53是乙基，R54是甲基或乙基，且R55是-CH(Me)-CH2OMe、<S>-CH(Me)-CH2OMe、CH2OMe或CH2O-CH2CH3；
其中a)和b)的混合比例为200:1-1:200。
2.一种控制有用植物中不希望的植物生长的方法，所述方法包括将除草有效量的权利要求1的组合物作用于植物或其场所。
3.权利要求2的方法，其中所述有用植物是玉米或甘蔗。
4.权利要求2的方法，其中用所述组合物以1-5000g活性组分混合物/公顷总量的施用量处理有用植物。
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Families Citing this family (370)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CZ304537B6 (cs) * 2000-01-25 2014-06-25 Syngenta Participations Ag Herbicidně selektivní kompozice a způsob kontroly nežádoucího rostlinného růstu
GT200100103A (es) * 2000-06-09 2002-02-21 Nuevos herbicidas
AU2002365631A1 (en) * 2001-12-03 2003-06-17 Syngenta Participations Ag Herbicidal composition
CA2466554A1 (en) * 2001-12-03 2003-06-12 Syngenta Participations Ag Herbicidal composition
DE10219036A1 (de) * 2002-04-29 2003-11-06 Bayer Cropscience Ag Substituierte Pyridylketone
AU2003213473A1 (en) * 2002-08-07 2004-02-26 Syngenta Participations Ag Herbicidal composition
WO2005077178A2 (en) * 2004-02-16 2005-08-25 Syngenta Participations Ag Herbicidal composition
US8883683B2 (en) * 2005-12-06 2014-11-11 Bayer Cropscience Lp Stabilized herbicidal composition
US8883689B2 (en) 2005-12-06 2014-11-11 Bayer Cropscience Lp Stabilized herbicidal compositions
US20070129250A1 (en) * 2005-12-06 2007-06-07 Tai-Teh Wu Stabilized herbicidal composition
AR064300A1 (es) * 2006-12-14 2009-03-25 Syngenta Participations Ag Pirandionas,tiopirandionas y ciclohexanotrionas como herbicidas
JP5300225B2 (ja) * 2007-08-03 2013-09-25 バイエル・クロップサイエンス・アーゲー 除草剤トリアゾリルピリジンケトン類
EP2184985A2 (en) * 2007-08-06 2010-05-19 Syngenta Limited Herbicidal compositions
WO2009019432A2 (en) * 2007-08-06 2009-02-12 Syngenta Limited Herbicidal composition and method of use thereof
CA2726590C (en) * 2008-06-09 2016-08-30 Gavin John Hall Weed control method and herbicidal composition
TW201002202A (en) * 2008-06-27 2010-01-16 Du Pont Fungicidal pyridines
WO2010103065A1 (en) 2009-03-11 2010-09-16 Basf Se Fungicidal compositions and their use
WO2010115721A2 (en) 2009-04-02 2010-10-14 Basf Se Method for reducing sunburn damage in plants
WO2010142779A1 (en) 2009-06-12 2010-12-16 Basf Se Antifungal 1,2,4-triazolyl derivatives having a 5- sulfur substituent
WO2010146032A2 (de) 2009-06-16 2010-12-23 Basf Se Fungizide mischungen
AU2010261888A1 (en) 2009-06-18 2012-01-19 Basf Se Fungicidal mixtures
WO2010146115A1 (en) 2009-06-18 2010-12-23 Basf Se Triazole compounds carrying a sulfur substituent
WO2010146116A1 (en) 2009-06-18 2010-12-23 Basf Se Triazole compounds carrying a sulfur substituent
US20120088664A1 (en) 2009-06-18 2012-04-12 Basf Se Antifungal 1,2,4-triazolyl derivatives having a 5-sulfur subtituent
KR20120062679A (ko) 2009-06-18 2012-06-14 바스프 에스이 황 치환기를 보유하는 트리아졸 화합물
US20120108422A1 (en) 2009-06-18 2012-05-03 Basf Se Antifungal 1,2,4-triazolyl Derivatives
JP2012530110A (ja) 2009-06-18 2012-11-29 ビーエーエスエフ ソシエタス・ヨーロピア 抗菌性１，２，４−トリアゾリル誘導体
WO2010149758A1 (en) 2009-06-25 2010-12-29 Basf Se Antifungal 1, 2, 4-triazolyl derivatives
BR112012001001A2 (pt) 2009-07-14 2016-11-16 Basf Se compositos azol das formulas i e ii, compostos das formulas i e i, compostos de formula ix, composição agricola, uso de um composto farmaceutica, metodo para tratar infecções de câncer ou virus para combater fungos zoopatigênicos ou humanopatogenicos
EA020385B1 (ru) 2009-07-28 2014-10-30 Басф Се Пестицидные суспоэмульсионные композиции
WO2011026796A1 (en) 2009-09-01 2011-03-10 Basf Se Synergistic fungicidal mixtures comprising lactylates and method for combating phytopathogenic fungi
WO2011069912A1 (de) 2009-12-07 2011-06-16 Basf Se Triazolverbindungen, ihre verwendung sowie sie enthaltende mittel
WO2011069916A1 (de) 2009-12-08 2011-06-16 Basf Se Triazolverbindungen, ihre verwendung als fungizide sowie sie enthaltende mittel
WO2011069894A1 (de) 2009-12-08 2011-06-16 Basf Se Triazolverbindungen, ihre verwendung sowie sie enthaltende mittel
WO2011110583A2 (en) 2010-03-10 2011-09-15 Basf Se Fungicidal mixtures comprising triazole derivatives
US9288996B2 (en) 2010-03-18 2016-03-22 Basf Se Fungicidal compositions comprising a phosphate solubilizing microorganism and a fungicidally active compound
EP2366289A1 (en) 2010-03-18 2011-09-21 Basf Se Synergistic fungicidal mixtures
DE102011017669A1 (de) 2010-04-29 2011-11-03 Basf Se Synergistische fungizide Mischungen
DE102011017670A1 (de) 2010-04-29 2011-11-03 Basf Se Synergistische fungizide Mischungen
DE102011017716A1 (de) 2010-04-29 2011-11-03 Basf Se Synergistische fungizide Mischungen
DE102011017715A1 (de) 2010-04-29 2012-03-08 Basf Se Synergistische fungizide Mischungen
EP2402344A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazole fused bicyclic compounds
EP2402336A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402345A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazole fused bicyclic compounds
EP2401915A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402338A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402339A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402337A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402343A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazole-fused bicyclic compounds
EP2402335A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402340A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
WO2012016989A2 (en) 2010-08-03 2012-02-09 Basf Se Fungicidal compositions
WO2012039141A1 (ja) * 2010-09-24 2012-03-29 クミアイ化学工業株式会社 ６－アシルピリジン－２－オン誘導体及び除草剤
EP2447261A1 (en) 2010-10-29 2012-05-02 Basf Se Pyrrole, furane and thiophene derivatives and their use as fungicides
EP2447262A1 (en) 2010-10-29 2012-05-02 Basf Se Pyrrole, furane and thiophene derivatives and their use as fungicides
EP2465350A1 (en) 2010-12-15 2012-06-20 Basf Se Pesticidal mixtures
EP2481284A3 (en) 2011-01-27 2012-10-17 Basf Se Pesticidal mixtures
BR112013023603A2 (pt) 2011-03-15 2016-08-02 Bayer Ip Gmbh n-(1,2,5-oxadiazol-3-il)piridinacarboxamidas e seu emprego como herbicidas
EP2688405B1 (en) 2011-03-23 2017-11-22 Basf Se Compositions containing polymeric, ionic compounds comprising imidazolium groups
US9253980B2 (en) 2011-04-15 2016-02-09 Basf Se Use of substituted dithiine-tetracarboximides for combating phytopathogenic fungi
JP2014513081A (ja) 2011-04-15 2014-05-29 ビーエーエスエフ ソシエタス・ヨーロピア 植物病原性菌類を駆除するための置換されたジチイン−ジカルボキシイミドの使用
JP2014512373A (ja) 2011-04-21 2014-05-22 ビーエーエスエフ ソシエタス・ヨーロピア ３，４−二置換ピロール２，５−ジオン及び殺菌剤としてのそれらの使用
EP2720541A1 (en) 2011-06-17 2014-04-23 Basf Se Compositions comprising fungicidal substituted dithiines and further actives
PE20140826A1 (es) 2011-07-13 2014-07-09 Basf Se Compuestos sustituidos fungicidas de 2-[2-halogenalquil-4-(fenoxi)-fenil]-1-[1,2,4]triazol-1-il-etanol
WO2013010885A1 (en) 2011-07-15 2013-01-24 Basf Se Fungicidal alkyl- and aryl-substituted 2-[2-chloro-4-(dihalo-phenoxy)-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds
EP2731936A1 (en) 2011-07-15 2014-05-21 Basf Se Fungicidal phenylalkyl-substituted 2-[2-chloro-4-(4-chloro-phenoxy)-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds
CN103648281B (zh) 2011-07-15 2016-05-25 巴斯夫欧洲公司 杀真菌的烷基取代的2-[2-氯-4-(4-氯苯氧基)苯基]-1-[1,2,4]三唑-1-基乙醇化合物
JP2014524430A (ja) 2011-08-15 2014-09-22 ビーエーエスエフ ソシエタス・ヨーロピア 殺菌性置換１−｛２−［２−ハロ−４−（４−ハロゲン−フェノキシ）−フェニル］−２−エトキシ−エチル｝−１ｈ−［１，２，４］トリアゾール化合物
UY34257A (es) 2011-08-15 2013-02-28 Basf Se Compuestos fungicidas de 1-{2-[2-halo-4-(4-halogen-fenoxi)-fenil]-2-alquiniloxi-etil}-1h-[1,2,4]triazol sustituidos
JP2014525407A (ja) 2011-08-15 2014-09-29 ビーエーエスエフ ソシエタス・ヨーロピア 殺菌性置換１−｛２−［２−ハロ−４−（４−ハロゲン−フェノキシ）−フェニル］−２−アルコキシ−２−アルキニル／アルケニル−エチル｝−１ｈ−［１，２，４］トリアゾール化合物
EP2559688A1 (en) 2011-08-15 2013-02-20 Basf Se Fungicidal substituted 1-{2-[2-halo-4-(4-halogen-phenoxy)-phenyl]-2-butoxy-ethyl}-1h [1,2,4]triazole compounds
US20140187423A1 (en) 2011-08-15 2014-07-03 Basf Se Fungicidal substituted 1--1H-[1,2,4]triazole compounds
CN103717579B (zh) 2011-08-15 2016-10-12 巴斯夫欧洲公司 杀真菌的取代的1-{2-[2-卤代-4-(4-卤代苯氧基)苯基]-2-烷氧基-2-环基乙基}-1h-[1,2,4]三唑化合物
US9247746B2 (en) 2011-08-15 2016-02-02 Basf Se Fungicidal substituted 1-{2-cyclyloxy-2-[2-halo-4-(4-halogen-phenoxy)-phenyl]-ethyl}-1H-[1,2,4]triazole compounds
MX2014000824A (es) 2011-08-15 2014-02-27 Basf Se Compuestos fungicidas de 1-{2-[2-halo-4-(4-halogen-fenoxi)-fenil]- 2-alcoxi-3-metil-butil}-1h-[1,2,4]triazol sustituidos.
UA123760C2 (uk) 2011-11-11 2021-06-02 Гіліад Аполло, Ллс Сполука (варіанти) та композиція, що містить сполуку
UY34480A (es) * 2011-11-30 2013-06-28 Syngenta Ltd Compuestos de 2-(fenilo sustituido)-ciclopentan-1,3-diona y derivados de los mismos, composiciones y métodos para controlar malezas.
CA2856954C (en) 2011-12-21 2020-09-22 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi resistant to qo inhibitors
IN2014DN07220A (zh) 2012-02-03 2015-04-24 Basf Se
WO2013113781A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds i
WO2013113788A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013113778A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013113776A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
JP2015508752A (ja) 2012-02-03 2015-03-23 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 殺菌性ピリミジン化合物
WO2013113719A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds ii
WO2013113720A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013113716A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013113782A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013113773A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013124250A2 (en) 2012-02-20 2013-08-29 Basf Se Fungicidal substituted thiophenes
EP2825533B1 (en) 2012-03-13 2016-10-19 Basf Se Fungicidal pyrimidine compounds
WO2013135672A1 (en) 2012-03-13 2013-09-19 Basf Se Fungicidal pyrimidine compounds
CN104202981B (zh) 2012-03-30 2018-01-30 巴斯夫欧洲公司 防治动物害虫的n‑取代的吡啶亚基化合物和衍生物
WO2013144223A1 (en) 2012-03-30 2013-10-03 Basf Se N-substituted pyrimidinylidene compounds and derivatives for combating animal pests
WO2013149940A1 (en) 2012-04-02 2013-10-10 Basf Se Acrylamide compounds for combating invertebrate pests
WO2013149903A1 (en) 2012-04-03 2013-10-10 Basf Se N- substituted hetero - bicyclic furanone derivatives for combating animal
WO2013150115A1 (en) 2012-04-05 2013-10-10 Basf Se N- substituted hetero - bicyclic compounds and derivatives for combating animal pests
CA2868385A1 (en) 2012-05-04 2013-11-07 Basf Se Substituted pyrazole-containing compounds and their use as pesticides
EA201401304A1 (ru) 2012-05-24 2015-08-31 Басф Се Соединения n-тиоантраниламида и их применение в качестве пестицидов
JP2015525223A (ja) 2012-06-14 2015-09-03 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 動物有害生物を駆除するための置換３−ピリジルチアゾール化合物および誘導体を使用する有害生物防除方法
EP2871960A1 (en) 2012-07-13 2015-05-20 Basf Se Substituted thiadiazoles and their use as fungicides
WO2014009293A1 (en) 2012-07-13 2014-01-16 Basf Se New substituted thiadiazoles and their use as fungicides
WO2014053404A1 (en) 2012-10-01 2014-04-10 Basf Se Pesticidally active mixtures comprising anthranilamide compounds
US20150237858A1 (en) 2012-10-01 2015-08-27 Basf Se Method of controlling ryanodine-modulator insecticide resistant insects
WO2014053407A1 (en) 2012-10-01 2014-04-10 Basf Se N-thio-anthranilamide compounds and their use as pesticides
US20150250173A1 (en) 2012-10-01 2015-09-10 Basf Se Pesticidally active mixtures comprising anthranilamide compounds
WO2014053401A2 (en) 2012-10-01 2014-04-10 Basf Se Method of improving plant health
WO2014053395A1 (en) 2012-10-01 2014-04-10 Basf Se Use of n-thio-anthranilamide compounds on cultivated plants
WO2014053403A1 (en) 2012-10-01 2014-04-10 Basf Se Method of controlling insecticide resistant insects
WO2014056780A1 (en) 2012-10-12 2014-04-17 Basf Se A method for combating phytopathogenic harmful microbes on cultivated plants or plant propagation material
WO2014079820A1 (en) 2012-11-22 2014-05-30 Basf Se Use of anthranilamide compounds for reducing insect-vectored viral infections
WO2014082879A1 (en) 2012-11-27 2014-06-05 Basf Se Substituted [1,2,4]triazole compounds
CN105008336A (zh) 2012-11-27 2015-10-28 巴斯夫欧洲公司 取代2-[苯氧基苯基]-1-[1,2,4]三唑-1-基乙醇化合物及其作为杀真菌剂的用途
CN104955813A (zh) 2012-11-27 2015-09-30 巴斯夫欧洲公司 取代的[1,2,4]三唑化合物
US20160029630A1 (en) 2012-11-27 2016-02-04 Basf Se Substituted 2-[phenoxy-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds and their use as fungicides
WO2014086856A1 (en) 2012-12-04 2014-06-12 Basf Agro B.V., Arnhem (Nl) Compositions comprising a quillay extract and a biopesticide
WO2014086850A1 (en) 2012-12-04 2014-06-12 Basf Agro B.V., Arnhem (Nl) Compositions comprising a quillay extract and a fungicidal inhibitor of respiratory complex ii
CA2889768A1 (en) 2012-12-04 2014-06-12 Basf Se New substituted 1,4-dithiine derivatives and their use as fungicides
WO2014086854A1 (en) 2012-12-04 2014-06-12 Basf Agro B.V., Arnhem (Nl) Compositions comprising a quillay extract and a plant growth regulator
EP2745691A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted imidazole compounds and their use as fungicides
CN104981459A (zh) 2012-12-19 2015-10-14 巴斯夫欧洲公司 新型取代三唑类和咪唑类及其作为杀真菌剂的用途
EP2746275A1 (en) 2012-12-19 2014-06-25 Basf Se New substituted triazoles and imidazoles and their use as fungicides
EP2746263A1 (en) 2012-12-19 2014-06-25 Basf Se Alpha-substituted triazoles and imidazoles
EP2746279A1 (en) 2012-12-19 2014-06-25 Basf Se Fungicidal imidazolyl and triazolyl compounds
EP2746278A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746277A1 (en) 2012-12-19 2014-06-25 Basf Se Fungicidal imidazolyl and triazolyl compounds
EP2746266A1 (en) 2012-12-19 2014-06-25 Basf Se New substituted triazoles and imidazoles and their use as fungicides
EP2746276A1 (en) 2012-12-19 2014-06-25 Basf Se New substituted triazoles and imidazoles and their use as fungicides
WO2014095381A1 (en) 2012-12-19 2014-06-26 Basf Se Fungicidal imidazolyl and triazolyl compounds
WO2014095534A1 (en) 2012-12-19 2014-06-26 Basf Se New substituted triazoles and imidazoles and their use as fungicides
EP2746264A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746255A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
WO2014095548A1 (en) 2012-12-19 2014-06-26 Basf Se Substituted [1,2,4]triazole compounds and their use as fungicides
WO2014095672A1 (en) 2012-12-19 2014-06-26 Basf Se Substituted [1,2,4]triazole compounds and their use as fungicides
EP2746262A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds for combating phytopathogenic fungi
EP2746274A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted [1,2,4]triazole compounds
EP2746256A1 (en) 2012-12-19 2014-06-25 Basf Se Fungicidal imidazolyl and triazolyl compounds
WO2014095555A1 (en) 2012-12-19 2014-06-26 Basf Se New substituted triazoles and imidazoles and their use as fungicides
BR112015014753B8 (pt) 2012-12-20 2020-03-03 Basf Agro Bv composições, uso de uma composição, método para o combate de fungos fitopatogênicos e uso dos componentes
EP2746260A1 (en) 2012-12-21 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746257A1 (en) 2012-12-21 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746258A1 (en) 2012-12-21 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746259A1 (en) 2012-12-21 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2938611A1 (en) 2012-12-27 2015-11-04 Basf Se 2-(pyridin-3-yl)-5-hetaryl-thiazole compounds carrying an imine or imine-derived substituent for combating invertebrate pests
WO2014118099A1 (en) 2013-01-30 2014-08-07 Basf Se Fungicidal naphthoquinones and derivatives
WO2014124850A1 (en) 2013-02-14 2014-08-21 Basf Se Substituted [1,2,4]triazole and imidazole compounds
WO2014147528A1 (en) 2013-03-20 2014-09-25 Basf Corporation Synergistic compositions comprising a bacillus subtilis strain and a biopesticide
EA031644B1 (ru) 2013-03-20 2019-02-28 Басф Корпорейшн Синергетические композиции, содержащие штамм bacillus subtilis и пестицид
EP2783569A1 (en) 2013-03-28 2014-10-01 Basf Se Compositions comprising a triazole compound
JP2016522173A (ja) 2013-04-19 2016-07-28 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 有害動物を駆除するためのｎ−置換アシル−イミノ−ピリジン化合物および誘導体
AU2014262546B2 (en) 2013-05-10 2018-11-08 Gilead Apollo, Llc ACC inhibitors and uses thereof
CN105358154A (zh) 2013-05-10 2016-02-24 尼普斯阿波罗有限公司 Acc抑制剂和其用途
EP2813499A1 (en) 2013-06-12 2014-12-17 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2815649A1 (en) 2013-06-18 2014-12-24 Basf Se Fungicidal mixtures II comprising strobilurin-type fungicides
EP2815647A1 (en) 2013-06-18 2014-12-24 Basf Se Novel strobilurin-type compounds for combating phytopathogenic fungi
BR112015031439A2 (pt) 2013-06-21 2017-07-25 Basf Se métodos para o combate ou controle das pragas, para o tratamento, prevenção e proteção de culturas de soja, para o controle e proteção do material de propagação dos vegetais de soja, para o combate ou controle das pragas e utilização de um composto de fórmula i
BR112016000869B1 (pt) 2013-07-15 2021-07-06 Basf Se composto, composição agrícola, composição veterinária e usos de um composto
WO2015011615A1 (en) 2013-07-22 2015-01-29 Basf Corporation Mixtures comprising a trichoderma strain and a pesticide
EP2835052A1 (en) 2013-08-07 2015-02-11 Basf Se Fungicidal mixtures comprising pyrimidine fungicides
EP2839745A1 (en) 2013-08-21 2015-02-25 Basf Se Agrochemical formulations comprising a 2-ethyl-hexanol alkoxylate
WO2015036058A1 (en) 2013-09-16 2015-03-19 Basf Se Fungicidal pyrimidine compounds
WO2015036059A1 (en) 2013-09-16 2015-03-19 Basf Se Fungicidal pyrimidine compounds
CR20160180A (es) 2013-09-19 2016-10-03 Basf Se Compuestos heterocíclicos de n-acilimino
ES2715660T3 (es) 2013-10-18 2019-06-05 Basf Agrochemical Products Bv Uso de un derivado de carboxamida activo como pesticida en el suelo y métodos de aplicación y tratamiento de semillas
WO2015086462A1 (en) 2013-12-12 2015-06-18 Basf Se Substituted [1,2,4]triazole and imidazole compounds
US20160326153A1 (en) 2013-12-18 2016-11-10 Basf Se N-substituted imino heterocyclic compounds
US20160318897A1 (en) 2013-12-18 2016-11-03 Basf Se Azole compounds carrying an imine-derived substituent
WO2015104422A1 (en) 2014-01-13 2015-07-16 Basf Se Dihydrothiophene compounds for controlling invertebrate pests
KR20160137619A (ko) 2014-03-26 2016-11-30 바스프 에스이 살진균제로서의 치환된 [1,2,4]트리아졸 및 이미다졸 화합물
EP2924027A1 (en) 2014-03-28 2015-09-30 Basf Se Substituted [1,2,4]triazole and imidazole fungicidal compounds
EP2949649A1 (en) 2014-05-30 2015-12-02 Basf Se Fungicide substituted [1,2,4]triazole and imidazole compounds
EP2949216A1 (en) 2014-05-30 2015-12-02 Basf Se Fungicidal substituted alkynyl [1,2,4]triazole and imidazole compounds
EP2952507A1 (en) 2014-06-06 2015-12-09 Basf Se Substituted [1,2,4]triazole compounds
EP2952506A1 (en) 2014-06-06 2015-12-09 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2952512A1 (en) 2014-06-06 2015-12-09 Basf Se Substituted [1,2,4]triazole compounds
AR100743A1 (es) 2014-06-06 2016-10-26 Basf Se Compuestos de [1,2,4]triazol sustituido
BR122021017881B1 (pt) 2014-06-06 2021-11-23 Basf Se Uso dos compostos, composição agroquímica e método para o combate dos fungos fitopatogênicos
EP2979549A1 (en) 2014-07-31 2016-02-03 Basf Se Method for improving the health of a plant
US10149477B2 (en) 2014-10-06 2018-12-11 Basf Se Substituted pyrimidinium compounds for combating animal pests
CN107075712A (zh) 2014-10-24 2017-08-18 巴斯夫欧洲公司 改变固体颗粒的表面电荷的非两性、可季化和水溶性聚合物
WO2016071499A1 (en) 2014-11-06 2016-05-12 Basf Se 3-pyridyl heterobicyclic compound for controlling invertebrate pests
EP3028573A1 (en) 2014-12-05 2016-06-08 Basf Se Use of a triazole fungicide on transgenic plants
EP3253209A1 (en) 2015-02-06 2017-12-13 Basf Se Pyrazole compounds as nitrification inhibitors
WO2016128240A1 (en) 2015-02-11 2016-08-18 Basf Se Pesticidal mixture comprising a pyrazole compound and two fungicides
US10701937B2 (en) 2015-02-11 2020-07-07 Basf Se Pesticidal mixture comprising a pyrazole compound, an insecticide and a fungicide
CA2980505A1 (en) 2015-04-07 2016-10-13 Basf Agrochemical Products B.V. Use of an insecticidal carboxamide compound against pests on cultivated plants
US11053175B2 (en) 2015-05-12 2021-07-06 Basf Se Thioether compounds as nitrification inhibitors
WO2016198613A1 (en) 2015-06-11 2016-12-15 Basf Se N-(thio)acylimino compounds
WO2016198611A1 (en) 2015-06-11 2016-12-15 Basf Se N-(thio)acylimino heterocyclic compounds
WO2017016883A1 (en) 2015-07-24 2017-02-02 Basf Se Process for preparation of cyclopentene compounds
KR20180059891A (ko) 2015-10-02 2018-06-05 바스프 에스이 해충 방지제로서의 2-클로로피리미딘-5-일 치환기를 갖는 이미노 화합물
US20180279615A1 (en) 2015-10-05 2018-10-04 Basf Se Pyridine derivatives for combating phytopathogenic fungi
EP3371177A1 (en) 2015-11-02 2018-09-12 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3165094A1 (en) 2015-11-03 2017-05-10 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
BR112018008288A2 (pt) 2015-11-04 2018-10-30 Basf Se uso de compostos de fórmula, compostos de fórmula, mistura, composição agroquímica e método para combater fungos
EP3165093A1 (en) 2015-11-05 2017-05-10 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3167716A1 (en) 2015-11-10 2017-05-17 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US20180354921A1 (en) 2015-11-13 2018-12-13 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
BR112018009566A2 (pt) 2015-11-13 2018-11-06 Basf Se compostos, mistura, composição agroquímica, uso de compostos e método para combater fungos nocivos fitopatogênicos
CA3003949A1 (en) 2015-11-19 2017-05-26 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3376867A1 (en) 2015-11-19 2018-09-26 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
CN108290902B (zh) 2015-11-25 2021-08-31 吉利德阿波罗公司 酯类acc抑制剂及其用途
BR112018010453B1 (pt) 2015-11-25 2022-06-14 Gilead Apollo, Llc Compostos triazólicos inibindores de acetil coa carboxilase (acc)
BR112018010113B1 (pt) 2015-11-25 2022-06-14 Gilead Apollo, Llc Composto de pirazol útil como inibidor da acetil-coa carboxilase (acc)
CN113303339A (zh) 2015-11-30 2021-08-27 巴斯夫欧洲公司 顺式-茉莉酮和解淀粉芽孢杆菌的混合物
BR112018010140A8 (pt) 2015-12-01 2019-02-26 Basf Se compostos de fórmula, composição, utilização de um composto de fórmula, método para o combate de fungos fitopatogênicos e semente
WO2017093167A1 (en) 2015-12-01 2017-06-08 Basf Se Pyridine compounds as fungicides
EP3205208A1 (en) 2016-02-09 2017-08-16 Basf Se Mixtures and compositions comprising paenibacillus strains or fusaricidins and chemical pesticides
BR112018068034A2 (pt) 2016-03-09 2019-01-08 Basf Se compostos espiro da fórmula i, composição, composição agrícola para combater pragas animais, método de combate ou controle de pragas invertebradas, método de proteção de plantas, semente e uso dos compostos
BR112018017034A2 (pt) 2016-03-10 2018-12-26 Basf Se misturas e seu uso, composição agroquímica, método de controle de fungos daninhos fitopatogênicos e material de propagação vegetal
US20190082696A1 (en) 2016-03-11 2019-03-21 Basf Se Method for controlling pests of plants
KR102411744B1 (ko) 2016-04-01 2022-06-21 바스프 에스이 바이시클릭 화합물
CN108884062A (zh) 2016-04-11 2018-11-23 巴斯夫欧洲公司 用于防治植物病原性真菌的取代噁二唑类
AU2017267129A1 (en) 2016-05-18 2018-11-22 Basf Se Capsules comprising benzylpropargylethers for use as nitrification inhibitors
US20190200612A1 (en) 2016-09-13 2019-07-04 Basf Se Fungicidal mixtures i comprising quinoline fungicides
WO2018054721A1 (en) 2016-09-26 2018-03-29 Basf Se Pyridine compounds for controlling phytopathogenic harmful fungi
WO2018054723A1 (en) 2016-09-26 2018-03-29 Basf Se Pyridine compounds for controlling phytopathogenic harmful fungi
WO2018054711A1 (en) 2016-09-26 2018-03-29 Basf Se Pyridine compounds for controlling phytopathogenic harmful fungi
WO2018065182A1 (en) 2016-10-04 2018-04-12 Basf Se Reduced quinoline compounds as antifuni agents
WO2018073110A1 (en) 2016-10-20 2018-04-26 Basf Se Quinoline compounds as fungicides
KR20190092539A (ko) 2016-12-16 2019-08-07 바스프 에스이 살충 화합물
US20190322631A1 (en) 2016-12-19 2019-10-24 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3339297A1 (en) 2016-12-20 2018-06-27 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3338552A1 (en) 2016-12-21 2018-06-27 Basf Se Use of a tetrazolinone fungicide on transgenic plants
WO2018134127A1 (en) 2017-01-23 2018-07-26 Basf Se Fungicidal pyridine compounds
WO2018149754A1 (en) 2017-02-16 2018-08-23 Basf Se Pyridine compounds
BR112019015338B1 (pt) 2017-02-21 2023-03-14 Basf Se Compostos de fórmula i, composição agroquímica, semente revestida, uso dos compostos e método para combater fungos nocivos fitopatogênicos
WO2018162312A1 (en) 2017-03-10 2018-09-13 Basf Se Spirocyclic derivatives
WO2018166855A1 (en) 2017-03-16 2018-09-20 Basf Se Heterobicyclic substituted dihydroisoxazoles
CN110506038B (zh) 2017-03-28 2023-11-24 巴斯夫欧洲公司 杀害虫化合物
RU2765370C2 (ru) 2017-03-31 2022-01-28 Басф Се Соединения пиримидиния и их смеси для подавления животных-вредителей
CN110475772A (zh) 2017-04-06 2019-11-19 巴斯夫欧洲公司 吡啶化合物
AU2018247768A1 (en) 2017-04-07 2019-10-03 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
WO2018188962A1 (en) 2017-04-11 2018-10-18 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
WO2018192793A1 (en) 2017-04-20 2018-10-25 Basf Se Substituted rhodanine derivatives
US11524934B2 (en) 2017-04-20 2022-12-13 Pi Industries Ltd Phenylamine compounds
MX2019012813A (es) 2017-04-26 2020-01-14 Basf Se Derivados de succinimida sustituida como plaguicidas.
EA201992550A1 (ru) 2017-05-02 2020-04-14 Басф Се Фунгицидные смеси, содержащие замещенные 3-фенил-5-(трифторметил)-1,2,4-оксадиазолы
JP7160487B2 (ja) 2017-05-04 2022-10-25 ビーエーエスエフ ソシエタス・ヨーロピア 植物病原菌を駆除するための置換５－（ハロアルキル）－５－ヒドロキシ－イソオキサゾール
WO2018202491A1 (en) 2017-05-04 2018-11-08 Basf Se Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi
BR112019022206A2 (pt) 2017-05-05 2020-05-12 Basf Se Misturas fungicidas, composição agroquímica, uso da mistura, métodos para controlar fungos nocivos fitopatogênicos e para a proteção de material de propagação de plantas e material de propagação vegetal
CA3059282A1 (en) 2017-05-10 2018-11-15 Basf Se Bicyclic pesticidal compounds
WO2018210658A1 (en) 2017-05-15 2018-11-22 Basf Se Heteroaryl compounds as agrochemical fungicides
WO2018210660A1 (en) 2017-05-15 2018-11-22 Basf Se Heteroaryl compounds as agrochemical fungicides
WO2018210659A1 (en) 2017-05-15 2018-11-22 Basf Se Heteroaryl compounds as agrochemical fungicides
WO2018210661A1 (en) 2017-05-15 2018-11-22 Basf Se Heteroaryl compounds as agrochemical fungicides
BR112019023453A2 (pt) 2017-05-18 2020-06-16 Pi Industries Ltd. Compostos de formimidamidina úteis contra microorganismos fitopatogênicos
CN110691776A (zh) 2017-05-30 2020-01-14 巴斯夫欧洲公司 吡啶和吡嗪化合物
WO2018219797A1 (en) 2017-06-02 2018-12-06 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
WO2018224455A1 (en) 2017-06-07 2018-12-13 Basf Se Substituted cyclopropyl derivatives
WO2018229202A1 (en) 2017-06-16 2018-12-20 Basf Se Mesoionic imidazolium compounds and derivatives for combating animal pests
US11542280B2 (en) 2017-06-19 2023-01-03 Basf Se Substituted pyrimidinium compounds and derivatives for combating animal pests
WO2018234139A1 (en) 2017-06-19 2018-12-27 Basf Se 2 - [[5- (TRIFLUOROMETHYL) -1,2,4-OXADIAZOL-3-YL] ARYLOXY] (THIO) ACETAMIDES FOR THE CONTROL OF PHYTOPATHOGENIC FUNGI
WO2018234488A1 (en) 2017-06-23 2018-12-27 Basf Se SUBSTITUTED CYCLOPROPYL DERIVATIVES
WO2019002158A1 (en) 2017-06-30 2019-01-03 Basf Se SUBSTITUTED TRIFLUOROMETHYLOXADIAZOLES FOR THE CONTROL OF PHYTOPATHOGENIC FUNGI
WO2019025250A1 (en) 2017-08-04 2019-02-07 Basf Se SUBSTITUTED TRIFLUOROMETHYLOXADIAZOLES FOR COMBATING PHYTOPATHOGENIC FUNGI
WO2019038042A1 (en) 2017-08-21 2019-02-28 Basf Se SUBSTITUTED TRIFLUOROMETHYLOXADIAZOLES FOR THE CONTROL OF PHYTOPATHOGENIC FUNGI
EP3675638A1 (en) 2017-08-29 2020-07-08 Basf Se Pesticidal mixtures
WO2019042932A1 (en) 2017-08-31 2019-03-07 Basf Se METHOD FOR CONTROLLING RICE PARASITES IN RICE
EP3453706A1 (en) 2017-09-08 2019-03-13 Basf Se Pesticidal imidazole compounds
WO2019052932A1 (en) 2017-09-18 2019-03-21 Basf Se SUBSTITUTED TRIFLUOROMETHYLOXADIAZOLES FOR COMBATING PHYTOPATHOGENIC FUNGI
WO2019057660A1 (en) 2017-09-25 2019-03-28 Basf Se INDOLE AND AZAINDOLE COMPOUNDS HAVING 6-CHANNEL SUBSTITUTED ARYL AND HETEROARYL CYCLES AS AGROCHEMICAL FUNGICIDES
US11399543B2 (en) 2017-10-13 2022-08-02 Basf Se Substituted 1,2,3,5-tetrahydroimidazo[1,2-a]pyrimidiniumolates for combating animal pests
WO2019101511A1 (en) 2017-11-23 2019-05-31 Basf Se Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi
WO2019115511A1 (en) 2017-12-14 2019-06-20 Basf Se Fungicidal mixture comprising substituted 3-phenyl-5-(trifluoromethyl)-1,2,4-oxadiazoles
EP3723485A1 (en) 2017-12-15 2020-10-21 Basf Se Fungicidal mixture comprising substituted pyridines
WO2019121143A1 (en) 2017-12-20 2019-06-27 Basf Se Substituted cyclopropyl derivatives
CN111670180A (zh) 2017-12-20 2020-09-15 Pi工业有限公司 氟烯基化合物，制备方法及其用途
WO2019121159A1 (en) 2017-12-21 2019-06-27 Basf Se Pesticidal compounds
KR102705587B1 (ko) 2018-01-09 2024-09-10 바스프 에스이 질화작용 저해제로서의 실릴에티닐 헤타릴 화합물
WO2019137995A1 (en) 2018-01-11 2019-07-18 Basf Se Novel pyridazine compounds for controlling invertebrate pests
WO2019150219A2 (en) 2018-01-30 2019-08-08 Pi Industries Ltd. Novel oxadiazoles
WO2019150311A1 (en) 2018-02-02 2019-08-08 Pi Industries Ltd. 1-3 dithiol compounds and their use for the protection of crops from phytopathogenic microorganisms
WO2019154663A1 (en) 2018-02-07 2019-08-15 Basf Se New pyridine carboxamides
WO2019154665A1 (en) 2018-02-07 2019-08-15 Basf Se New pyridine carboxamides
EP3530118A1 (en) 2018-02-26 2019-08-28 Basf Se Fungicidal mixtures
EP3530116A1 (en) 2018-02-27 2019-08-28 Basf Se Fungicidal mixtures comprising xemium
WO2019166252A1 (en) 2018-02-28 2019-09-06 Basf Se Fungicidal mixtures comprising fenpropidin
IL276745B2 (en) 2018-02-28 2023-10-01 Basf Se Use of N-functional alkoxy pyrazole compounds as nitrification inhibitors
AU2019226360A1 (en) 2018-02-28 2020-08-27 Basf Se Use of alkoxypyrazoles as nitrification inhibitors
US11498885B2 (en) 2018-02-28 2022-11-15 Basf Se Use of pyrazole propargyl ethers as nitrification inhibitors
EA202092018A1 (ru) 2018-03-01 2021-02-01 Басф Агро Б.В. Фунгицидные композиции мефентрифлуконазола
EP3533333A1 (en) 2018-03-02 2019-09-04 Basf Se Fungicidal mixtures comprising pydiflumetofen
EP3533331A1 (en) 2018-03-02 2019-09-04 Basf Se Fungicidal mixtures comprising pydiflumetofen
EP3536150A1 (en) 2018-03-06 2019-09-11 Basf Se Fungicidal mixtures comprising fluxapyroxad
BR112020018403A2 (pt) 2018-03-09 2020-12-22 Pi Industries Ltd. Compostos heterocíclicoscomo fungicidas
WO2019175713A1 (en) 2018-03-14 2019-09-19 Basf Corporation New catechol molecules and their use as inhibitors to p450 related metabolic pathways
WO2019175712A1 (en) 2018-03-14 2019-09-19 Basf Corporation New uses for catechol molecules as inhibitors to glutathione s-transferase metabolic pathways
WO2019185413A1 (en) 2018-03-27 2019-10-03 Basf Se Pesticidal substituted cyclopropyl derivatives
BR112020020959A2 (pt) 2018-04-16 2021-01-19 Pi Industries Ltd. Uso de compostos de fenilamidina 4-substituídospara controlar doenças de ferrugem em vegetais
JP7433244B2 (ja) 2018-05-15 2024-02-19 ビーエーエスエフ ソシエタス・ヨーロピア ベンズピリモキサン及びオキサゾスルフィルを含む混合物並びにその使用及び施用方法
WO2019219464A1 (en) 2018-05-15 2019-11-21 Basf Se Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi
WO2019224092A1 (en) 2018-05-22 2019-11-28 Basf Se Pesticidally active c15-derivatives of ginkgolides
WO2020002472A1 (en) 2018-06-28 2020-01-02 Basf Se Use of alkynylthiophenes as nitrification inhibitors
CN112424148B (zh) 2018-07-23 2023-08-11 巴斯夫欧洲公司 取代2-噻唑啉作为硝化抑制剂的用途
CA3104254A1 (en) 2018-07-23 2020-01-30 Basf Se Use of a substituted thiazolidine compound as nitrification inhibitor
WO2020035826A1 (en) 2018-08-17 2020-02-20 Pi Industries Ltd. 1,2-dithiolone compounds and use thereof
EP3613736A1 (en) 2018-08-22 2020-02-26 Basf Se Substituted glutarimide derivatives
EP3628158A1 (en) 2018-09-28 2020-04-01 Basf Se Pesticidal mixture comprising a mesoionic compound and a biopesticide
EP3628156A1 (en) 2018-09-28 2020-04-01 Basf Se Method for controlling pests of sugarcane, citrus, rapeseed, and potato plants
EP3628157A1 (en) 2018-09-28 2020-04-01 Basf Se Method of controlling insecticide resistant insects and virus transmission to plants
AU2019348280A1 (en) 2018-09-28 2021-04-22 Basf Se Method of controlling pests by seed treatment application of a mesoionic compound or mixture thereof
CN113195461A (zh) 2018-10-01 2021-07-30 Pi工业有限公司 新型恶二唑类化合物
AU2019353092A1 (en) 2018-10-01 2021-04-08 Pi Industries Ltd. Novel oxadiazoles
EP3643705A1 (en) 2018-10-24 2020-04-29 Basf Se Pesticidal compounds
WO2020095161A1 (en) 2018-11-05 2020-05-14 Pi Industries Ltd. Nitrone compounds and use thereof
BR112021008491A2 (pt) 2018-11-28 2021-08-03 Basf Se composto da fórmula i, composição, método de combate ou controle de pragas invertebradas, método de proteção de plantas em crescimento, semente, uso de composto da fórmula i e método de tratamento ou proteção de animais
EP3670501A1 (en) 2018-12-17 2020-06-24 Basf Se Substituted [1,2,4]triazole compounds as fungicides
EP3898623A1 (en) 2018-12-18 2021-10-27 Basf Se Substituted pyrimidinium compounds for combating animal pests
EP3696177A1 (en) 2019-02-12 2020-08-19 Basf Se Heterocyclic compounds for the control of invertebrate pests
KR20210150405A (ko) 2019-04-08 2021-12-10 피아이 인더스트리스 엘티디. 식물병원성 진균을 방제 또는 예방하기 위한 신규한 옥사디아졸 화합물
JP7550786B2 (ja) 2019-04-08 2024-09-13 ピーアイ インダストリーズ リミテッド 植物病原性真菌を制御又は予防するための新規オキサジアゾール化合物、組成物、および方法
US20220135531A1 (en) 2019-04-08 2022-05-05 Pi Industries Ltd. Novel oxadiazole compounds for controlling or preventing phytopathogenic fungi
EP3730489A1 (en) 2019-04-25 2020-10-28 Basf Se Heteroaryl compounds as agrochemical fungicides
EP3769623A1 (en) 2019-07-22 2021-01-27 Basf Se Mesoionic imidazolium compounds and derivatives for combating animal pests
WO2020239517A1 (en) 2019-05-29 2020-12-03 Basf Se Mesoionic imidazolium compounds and derivatives for combating animal pests
WO2020244969A1 (en) 2019-06-06 2020-12-10 Basf Se Pyridine derivatives and their use as fungicides
MX2021014864A (es) 2019-06-06 2022-01-18 Basf Se N-(pirid-3-il)carboxamidas fungicidas.
WO2020244970A1 (en) 2019-06-06 2020-12-10 Basf Se New carbocyclic pyridine carboxamides
EP3766879A1 (en) 2019-07-19 2021-01-20 Basf Se Pesticidal pyrazole derivatives
AR119774A1 (es) 2019-08-19 2022-01-12 Pi Industries Ltd Compuestos de oxadiazol que contienen un anillo heteroaromático de 5 miembros para controlar o prevenir hongos fitopatogénicos
WO2021063736A1 (en) 2019-10-02 2021-04-08 Basf Se Bicyclic pyridine derivatives
WO2021063735A1 (en) 2019-10-02 2021-04-08 Basf Se New bicyclic pyridine derivatives
AR120374A1 (es) 2019-11-08 2022-02-09 Pi Industries Ltd Compuestos de oxadiazol que contienen anillos de heterociclilo fusionados para controlar o prevenir hongos fitopatogénicos
EP4081037A1 (en) 2019-12-23 2022-11-02 Basf Se Enzyme enhanced root uptake of agrochemical active compound
US20230106291A1 (en) 2020-02-28 2023-04-06 BASF Agro B.V. Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for controlling invertebrate pests in t
BR112022017563A2 (pt) 2020-03-04 2022-10-18 Basf Se Uso de compostos, composição agroquímica e método para combater fungos fitopatogênicos nocivos
BR112022020612A2 (pt) 2020-04-14 2022-11-29 Basf Se Mistura fungicida, composição agroquímica, uso não terapêutico da mistura e método para controlar fungos fitopatogênicos nocivos
EP3903584A1 (en) 2020-04-28 2021-11-03 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors iv
EP3903581A1 (en) 2020-04-28 2021-11-03 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors i
US20230157287A1 (en) 2020-04-28 2023-05-25 Basf Se Pesticidal compounds
EP3903583A1 (en) 2020-04-28 2021-11-03 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors iii
EP3903582A1 (en) 2020-04-28 2021-11-03 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors ii
EP3909950A1 (en) 2020-05-13 2021-11-17 Basf Se Heterocyclic compounds for the control of invertebrate pests
WO2021249800A1 (en) 2020-06-10 2021-12-16 Basf Se Substituted [1,2,4]triazole compounds as fungicides
EP3945089A1 (en) 2020-07-31 2022-02-02 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors v
EP3960727A1 (en) 2020-08-28 2022-03-02 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors vi
EP3939961A1 (en) 2020-07-16 2022-01-19 Basf Se Strobilurin type compounds and their use for combating phytopathogenic fungi
WO2022017836A1 (en) 2020-07-20 2022-01-27 BASF Agro B.V. Fungicidal compositions comprising (r)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1- (1,2,4-triazol-1-yl)propan-2-ol
EP3970494A1 (en) 2020-09-21 2022-03-23 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors viii
AR123264A1 (es) 2020-08-18 2022-11-16 Pi Industries Ltd Nuevos compuestos heterocíclicos para combatir los hongos fitopatógenos
UY39423A (es) 2020-09-15 2022-03-31 Pi Industries Ltd Nuevos compuestos de picolinamida para combatir hongos fitopatógenos
WO2022058878A1 (en) 2020-09-15 2022-03-24 Pi Industries Limited Novel picolinamide compounds for combating phytopathogenic fungi
AR123594A1 (es) 2020-09-26 2022-12-21 Pi Industries Ltd Compuestos nematicidas y uso de los mismos
WO2022089969A1 (en) 2020-10-27 2022-05-05 BASF Agro B.V. Compositions comprising mefentrifluconazole
EP4018830A1 (en) 2020-12-23 2022-06-29 Basf Se Pesticidal mixtures
EP4043444A1 (en) 2021-02-11 2022-08-17 Basf Se Substituted isoxazoline derivatives
BR112023022854A2 (pt) 2021-05-05 2024-01-23 Pi Industries Ltd Compostos heterocíclicos fusionados inovadores para combater fungos fitopatogênicos
BR112023023592A2 (pt) 2021-05-11 2024-03-12 Basf Se Mistura fungicida, composição agroquímica, uso da mistura e método para controlar fungos nocivos fitopatogênicos
EP4341257A1 (en) 2021-05-18 2024-03-27 Basf Se New substituted quinolines as fungicides
US20240294544A1 (en) 2021-05-18 2024-09-05 Basf Se New substituted pyridines as fungicides
UY39780A (es) 2021-05-26 2022-11-30 Pi Industries Ltd Composición fungicida que contiene compuestos de oxadiazol
EP4094579A1 (en) 2021-05-28 2022-11-30 Basf Se Pesticidal mixtures comprising metyltetraprole
EP4119547A1 (en) 2021-07-12 2023-01-18 Basf Se Triazole compounds for the control of invertebrate pests
MX2024001593A (es) 2021-08-02 2024-02-15 Basf Se (3-piridil)-quinazolina.
EP4140986A1 (en) 2021-08-23 2023-03-01 Basf Se Pyrazine compounds for the control of invertebrate pests
EP4140995A1 (en) 2021-08-27 2023-03-01 Basf Se Pyrazine compounds for the control of invertebrate pests
EP4151631A1 (en) 2021-09-20 2023-03-22 Basf Se Heterocyclic compounds for the control of invertebrate pests
WO2023072671A1 (en) 2021-10-28 2023-05-04 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors ix
WO2023072670A1 (en) 2021-10-28 2023-05-04 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors x
EP4194453A1 (en) 2021-12-08 2023-06-14 Basf Se Pyrazine compounds for the control of invertebrate pests
EP4198033A1 (en) 2021-12-14 2023-06-21 Basf Se Heterocyclic compounds for the control of invertebrate pests
EP4198023A1 (en) 2021-12-16 2023-06-21 Basf Se Pesticidally active thiosemicarbazone compounds
AR127972A1 (es) 2021-12-17 2024-03-13 Pi Industries Ltd Novedosos compuestos de piridina carboxamida bicíclica sustituida fusionada para combatir hongos fitopatogénicos
US12096772B2 (en) * 2022-02-04 2024-09-24 Syngenta Crop Protection Ag Herbicidal compositions
EP4238971A1 (en) 2022-03-02 2023-09-06 Basf Se Substituted isoxazoline derivatives
WO2023203066A1 (en) 2022-04-21 2023-10-26 Basf Se Synergistic action as nitrification inhibitors of dcd oligomers with alkoxypyrazole and its oligomers
WO2024028243A1 (en) 2022-08-02 2024-02-08 Basf Se Pyrazolo pesticidal compounds
EP4361126A1 (en) 2022-10-24 2024-05-01 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors xv
EP4389210A1 (en) 2022-12-21 2024-06-26 Basf Se Heteroaryl compounds for the control of invertebrate pests

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0338992A2 (en) * 1988-04-18 1989-10-25 Sandoz Ag Substituted aryl and heteroaryl bicyclodiones
US4995902A (en) * 1988-07-25 1991-02-26 Ciba-Geigy Corporation Novel herbicides

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2129109C3 (de) 1971-06-11 1979-06-07 Lentia Gmbh Phenylpyridazine, ihre Herstellung und sie enthaltende herbizide Mittel
DE2948535A1 (de) 1979-12-03 1981-06-25 Basf Ag, 6700 Ludwigshafen Dichloracetamide, herbizide mittel, die acetanilide als herbizide wirkstoffe und diese dichloracetamide als antagonistische mittel enthalten, sowie ihre verwendung zur bekaempfung unerwuenschten pflanzenwuchses
DE3525205A1 (de) 1984-09-11 1986-03-20 Hoechst Ag, 6230 Frankfurt Pflanzenschuetzende mittel auf basis von 1,2,4-triazolderivaten sowie neue derivate des 1,2,4-triazols
JPS61293956A (ja) 1985-06-21 1986-12-24 Tokuyama Soda Co Ltd クロロアセトアミド化合物及びその製造方法
US5194085A (en) 1987-06-12 1993-03-16 Bayer Aktiengesellschaft Herbicidal substituted triazolinones
US5256625A (en) 1987-08-13 1993-10-26 Monsanto Company Safening imidazolinone herbicides
CN1038093A (zh) * 1988-04-18 1989-12-20 山道士有限公司 对有机化合物和关于有机化合物的改进
DE4110795A1 (de) 1991-04-04 1992-10-08 Bayer Ag Sulfonylaminocarbonyltriazolinone mit ueber sauerstoff gebundenen substituenten
US5215570A (en) 1988-10-20 1993-06-01 Ciba-Geigy Corporation Sulfamoylphenylureas
AU630980B2 (en) 1989-06-29 1992-11-12 Syngenta Participations Ag Heterocyclic compounds
JPH0352862A (ja) * 1989-07-20 1991-03-07 Nippon Soda Co Ltd 置換ピリジン誘導体、その製造法及び除草剤
US5281571A (en) 1990-10-18 1994-01-25 Monsanto Company Herbicidal benzoxazinone- and benzothiazinone-substituted pyrazoles
DE4037840A1 (de) 1990-11-28 1992-06-11 Basf Ag 2-amino-zimtsaeureester
US5498773A (en) 1991-05-03 1996-03-12 Dowelanco Herbicidal compositions with increased crop safety
EP0551650B1 (de) * 1991-12-31 1999-10-13 Hoechst Schering AgrEvo GmbH Kombinationen aus Herbiziden und pflanzenschützenden Stoffen
EP0569944B1 (de) 1992-05-15 1999-03-31 Hoechst Schering AgrEvo GmbH Synergistisch wirksame Herbizidkombinationen
US5674810A (en) 1995-09-05 1997-10-07 Fmc Corporation Herbicidal compositions comprising 2- (4-heterocyclic-phenoxymethyl)Phenoxy!-alkanoates
EP0646315B1 (en) 1992-11-05 1999-05-12 Novartis AG Novel compositions containing an auxin transport inhibitor and another herbicide
US5407897A (en) 1993-03-03 1995-04-18 American Cyanamid Company Method for safening herbicides in crops using substituted benzopyran and tetrahydronaphthalene compounds
DE4331448A1 (de) 1993-09-16 1995-03-23 Hoechst Schering Agrevo Gmbh Substituierte Isoxazoline, Verfahren zu deren Herstellung, diese enthaltende Mittel und deren Verwendung als Safener
US5741756A (en) * 1995-07-19 1998-04-21 Zeneca Limited Synergistic herbicidal composition comprising triketones and chloroacetanilides, and method of use thereof
AU715538B2 (en) * 1996-03-15 2000-02-03 Syngenta Participations Ag Herbicidal synergistic composition and method of weed control
WO1998013361A1 (en) 1996-09-26 1998-04-02 Novartis Ag Herbicidal composition
DE19727410A1 (de) 1997-06-27 1999-01-07 Hoechst Schering Agrevo Gmbh 3-(5-Tetrazolylcarbonyl)-2-chinolone und diese enthaltende nutzpflanzenschützende Mittel
WO2000000029A1 (en) * 1998-06-26 2000-01-06 Novartis Pharma Ag. Herbicidal composition
EP1089628A1 (de) 1998-06-26 2001-04-11 Novartis Pharma AG. Herbizides mittel
ATE296803T1 (de) * 1998-09-15 2005-06-15 Syngenta Participations Ag Als herbicide verwendbare pyridin-ketone
CZ304537B6 (cs) * 2000-01-25 2014-06-25 Syngenta Participations Ag Herbicidně selektivní kompozice a způsob kontroly nežádoucího rostlinného růstu

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0338992A2 (en) * 1988-04-18 1989-10-25 Sandoz Ag Substituted aryl and heteroaryl bicyclodiones
US4995902A (en) * 1988-07-25 1991-02-26 Ciba-Geigy Corporation Novel herbicides

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