UA73984C2 - ??2-phenyl- substituted cyclic keto-enols as pesticides and herbicides - Google Patents
??2-phenyl- substituted cyclic keto-enols as pesticides and herbicides Download PDFInfo
- Publication number
- UA73984C2 UA73984C2 UA2002118712A UA2002118712A UA73984C2 UA 73984 C2 UA73984 C2 UA 73984C2 UA 2002118712 A UA2002118712 A UA 2002118712A UA 2002118712 A UA2002118712 A UA 2002118712A UA 73984 C2 UA73984 C2 UA 73984C2
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- UA
- Ukraine
- Prior art keywords
- carbon atoms
- alkyl
- formula
- necessary
- compounds
- Prior art date
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- 125000004122 cyclic group Chemical group 0.000 title claims abstract description 5
- 239000004009 herbicide Substances 0.000 title abstract description 16
- 239000000575 pesticide Substances 0.000 title abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 349
- 125000000217 alkyl group Chemical group 0.000 claims description 221
- 239000001257 hydrogen Substances 0.000 claims description 76
- 229910052739 hydrogen Inorganic materials 0.000 claims description 76
- 229910052760 oxygen Inorganic materials 0.000 claims description 55
- 229910052799 carbon Inorganic materials 0.000 claims description 50
- 150000002431 hydrogen Chemical class 0.000 claims description 45
- 125000003342 alkenyl group Chemical group 0.000 claims description 38
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 37
- 239000001301 oxygen Substances 0.000 claims description 35
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 33
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 31
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 31
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 28
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 23
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 17
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 17
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 16
- 125000004849 alkoxymethyl group Chemical group 0.000 claims description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims 1
- 235000011613 Pinus brutia Nutrition 0.000 claims 1
- 241000018646 Pinus brutia Species 0.000 claims 1
- 238000012876 topography Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 174
- 150000001875 compounds Chemical class 0.000 description 166
- -1 silyl ester Chemical class 0.000 description 135
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- 230000008569 process Effects 0.000 description 87
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 84
- 239000002253 acid Substances 0.000 description 81
- 241000196324 Embryophyta Species 0.000 description 79
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 78
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 63
- 238000006243 chemical reaction Methods 0.000 description 57
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 51
- 229910052736 halogen Inorganic materials 0.000 description 47
- 239000000203 mixture Substances 0.000 description 45
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- 238000002360 preparation method Methods 0.000 description 42
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 36
- 239000011230 binding agent Substances 0.000 description 36
- 239000003085 diluting agent Substances 0.000 description 36
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 34
- 125000001188 haloalkyl group Chemical group 0.000 description 34
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 33
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 33
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 31
- 239000000243 solution Substances 0.000 description 31
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 30
- 239000002585 base Substances 0.000 description 30
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 29
- 150000001721 carbon Chemical group 0.000 description 29
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- 229910052796 boron Inorganic materials 0.000 description 28
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- 229910052717 sulfur Inorganic materials 0.000 description 28
- 239000011593 sulfur Substances 0.000 description 28
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 27
- 229910052801 chlorine Inorganic materials 0.000 description 27
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 25
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 25
- 229910052794 bromium Inorganic materials 0.000 description 25
- 239000000047 product Substances 0.000 description 25
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 24
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 24
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 24
- 229940073584 methylene chloride Drugs 0.000 description 24
- 239000011734 sodium Substances 0.000 description 24
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 23
- 239000003795 chemical substances by application Substances 0.000 description 23
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 23
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- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 22
- 238000012360 testing method Methods 0.000 description 22
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- 229910052731 fluorine Inorganic materials 0.000 description 21
- 229910052708 sodium Inorganic materials 0.000 description 21
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 20
- 235000019441 ethanol Nutrition 0.000 description 20
- 150000002170 ethers Chemical class 0.000 description 20
- 239000011737 fluorine Substances 0.000 description 20
- 239000000126 substance Substances 0.000 description 20
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 19
- 230000003993 interaction Effects 0.000 description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 125000001153 fluoro group Chemical group F* 0.000 description 18
- 239000003054 catalyst Substances 0.000 description 17
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- 230000034994 death Effects 0.000 description 16
- 231100000517 death Toxicity 0.000 description 16
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- 239000007858 starting material Substances 0.000 description 15
- 125000001424 substituent group Chemical group 0.000 description 15
- 239000008096 xylene Substances 0.000 description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 14
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 14
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 14
- 230000000895 acaricidal effect Effects 0.000 description 14
- 125000004414 alkyl thio group Chemical group 0.000 description 14
- 125000004093 cyano group Chemical group *C#N 0.000 description 14
- 230000002363 herbicidal effect Effects 0.000 description 14
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 14
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 13
- 240000008042 Zea mays Species 0.000 description 13
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 13
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 13
- 239000000370 acceptor Substances 0.000 description 13
- 235000005822 corn Nutrition 0.000 description 13
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 13
- 230000007958 sleep Effects 0.000 description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 12
- 241000238631 Hexapoda Species 0.000 description 12
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 12
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- 239000000463 material Substances 0.000 description 12
- 229920000151 polyglycol Polymers 0.000 description 12
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- 229910052700 potassium Inorganic materials 0.000 description 12
- 235000011181 potassium carbonates Nutrition 0.000 description 12
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 12
- 241001465754 Metazoa Species 0.000 description 11
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 11
- 150000001342 alkaline earth metals Chemical class 0.000 description 11
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 11
- 125000004429 atom Chemical group 0.000 description 11
- 239000000417 fungicide Substances 0.000 description 11
- 239000011591 potassium Substances 0.000 description 11
- 229910000027 potassium carbonate Inorganic materials 0.000 description 11
- 239000000843 powder Substances 0.000 description 11
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 11
- 241000894007 species Species 0.000 description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 11
- 229920002554 vinyl polymer Polymers 0.000 description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 10
- 241000607479 Yersinia pestis Species 0.000 description 10
- 150000001298 alcohols Chemical class 0.000 description 10
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 10
- 150000004679 hydroxides Chemical class 0.000 description 10
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 10
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 10
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Classifications
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- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
- C07D491/10—Spiro-condensed systems
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/45—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups
- C07C233/46—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
- C07C233/51—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by carboxyl groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to an acyclic carbon atom of a carbon skeleton containing six-membered aromatic rings
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
- C07C45/46—Friedel-Crafts reactions
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
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- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
- C07C49/747—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
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- C07C69/013—Esters of alcohols having the esterified hydroxy group bound to a carbon atom of a ring other than a six-membered aromatic ring
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- C07C69/612—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/738—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
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- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C69/757—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/36—Oxygen or sulfur atoms
- C07D207/38—2-Pyrrolones
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/54—Spiro-condensed
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/94—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom spiro-condensed with carbocyclic rings or ring systems, e.g. griseofulvins
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- C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
- C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D309/08—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D309/14—Nitrogen atoms not forming part of a nitro radical
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- C07D309/34—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D309/36—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms
- C07D309/38—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms one oxygen atom in position 2 or 4, e.g. pyrones
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- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
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- Chemical & Material Sciences (AREA)
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- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
- Indole Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Furan Compounds (AREA)
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Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10016544A DE10016544A1 (de) | 2000-04-03 | 2000-04-03 | C2-phenylsubstituierte Ketoenole |
PCT/EP2001/003215 WO2001074770A1 (de) | 2000-04-03 | 2001-03-21 | C2-phenylsubstituierte cyclische ketoenole als schädlingsbekämpfungsmittel und herbizide |
Publications (1)
Publication Number | Publication Date |
---|---|
UA73984C2 true UA73984C2 (en) | 2005-10-17 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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UA2002118712A UA73984C2 (en) | 2000-04-03 | 2001-03-21 | ??2-phenyl- substituted cyclic keto-enols as pesticides and herbicides |
Country Status (18)
Country | Link |
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US (4) | US7915282B2 (zh) |
EP (1) | EP1280770B1 (zh) |
JP (2) | JP4947868B2 (zh) |
KR (1) | KR100704719B1 (zh) |
CN (7) | CN1880293A (zh) |
AT (1) | ATE471929T1 (zh) |
AU (1) | AU782557C (zh) |
BR (3) | BR0117375B1 (zh) |
CA (2) | CA2829534C (zh) |
DE (2) | DE10016544A1 (zh) |
ES (1) | ES2346039T3 (zh) |
HK (1) | HK1057369A1 (zh) |
MX (1) | MXPA02009730A (zh) |
PL (1) | PL362703A1 (zh) |
RU (1) | RU2280643C2 (zh) |
UA (1) | UA73984C2 (zh) |
WO (1) | WO2001074770A1 (zh) |
ZA (1) | ZA200206836B (zh) |
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WO2021209486A1 (de) | 2020-04-15 | 2021-10-21 | Bayer Aktiengesellschaft | Speziell substituierte pyrrolin-2-one und deren verwendung als herbizide |
KR20230015975A (ko) | 2020-05-27 | 2023-01-31 | 바이엘 악티엔게젤샤프트 | 치환된 피롤린-2-온 및 제초제로서의 그의 용도 |
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-
2000
- 2000-04-03 DE DE10016544A patent/DE10016544A1/de not_active Withdrawn
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2001
- 2001-03-21 PL PL01362703A patent/PL362703A1/xx not_active Application Discontinuation
- 2001-03-21 CN CNA2006101014026A patent/CN1880293A/zh active Pending
- 2001-03-21 BR BRPI0117375-8A patent/BR0117375B1/pt active IP Right Grant
- 2001-03-21 AT AT01917102T patent/ATE471929T1/de active
- 2001-03-21 BR BRPI0117376-6A patent/BRPI0117376B1/pt not_active IP Right Cessation
- 2001-03-21 BR BRPI0109750-4A patent/BR0109750B1/pt not_active IP Right Cessation
- 2001-03-21 CN CN200910175740A patent/CN101676258A/zh active Pending
- 2001-03-21 CN CN2004100974842A patent/CN1631878B/zh not_active Expired - Lifetime
- 2001-03-21 DE DE50115530T patent/DE50115530D1/de not_active Expired - Lifetime
- 2001-03-21 CN CNB2005100712543A patent/CN100526287C/zh not_active Expired - Lifetime
- 2001-03-21 EP EP01917102A patent/EP1280770B1/de not_active Revoked
- 2001-03-21 CA CA2829534A patent/CA2829534C/en not_active Expired - Lifetime
- 2001-03-21 MX MXPA02009730A patent/MXPA02009730A/es active IP Right Grant
- 2001-03-21 WO PCT/EP2001/003215 patent/WO2001074770A1/de active IP Right Grant
- 2001-03-21 CN CNA2006101728204A patent/CN1982296A/zh active Pending
- 2001-03-21 ES ES01917102T patent/ES2346039T3/es not_active Expired - Lifetime
- 2001-03-21 CN CNB01810651XA patent/CN1309709C/zh not_active Expired - Lifetime
- 2001-03-21 AU AU44215/01A patent/AU782557C/en not_active Expired
- 2001-03-21 CN CN2011102105146A patent/CN102408369A/zh active Pending
- 2001-03-21 JP JP2001572465A patent/JP4947868B2/ja not_active Expired - Fee Related
- 2001-03-21 UA UA2002118712A patent/UA73984C2/uk unknown
- 2001-03-21 RU RU2002129566/04A patent/RU2280643C2/ru not_active IP Right Cessation
- 2001-03-21 US US10/239,331 patent/US7915282B2/en not_active Expired - Fee Related
- 2001-03-21 KR KR1020027012218A patent/KR100704719B1/ko active IP Right Grant
- 2001-03-21 CA CA2404868A patent/CA2404868C/en not_active Expired - Lifetime
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2002
- 2002-08-27 ZA ZA200206836A patent/ZA200206836B/en unknown
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2004
- 2004-01-12 HK HK04100217A patent/HK1057369A1/xx not_active IP Right Cessation
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2011
- 2011-02-17 US US13/029,497 patent/US8193120B2/en not_active Expired - Fee Related
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- 2011-06-20 JP JP2011136575A patent/JP5685153B2/ja not_active Expired - Fee Related
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