KR101021991B1 - 리튬 이차 전지용 양극 재료 및 그 제조방법 - Google Patents

리튬 이차 전지용 양극 재료 및 그 제조방법 Download PDF

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KR101021991B1
KR101021991B1 KR1020057005039A KR20057005039A KR101021991B1 KR 101021991 B1 KR101021991 B1 KR 101021991B1 KR 1020057005039 A KR1020057005039 A KR 1020057005039A KR 20057005039 A KR20057005039 A KR 20057005039A KR 101021991 B1 KR101021991 B1 KR 101021991B1
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positive electrode
active material
particles
lithium
electrode active
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KR20050057566A (ko
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고지 다츠미
마나부 수하라
나오시 사이토
가즈시게 호리치
유키오 지츠기리
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에이지씨 세이미 케미칼 가부시키가이샤
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/32—Spheres
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/10—Solid density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
KR1020057005039A 2002-09-25 2003-06-06 리튬 이차 전지용 양극 재료 및 그 제조방법 Expired - Fee Related KR101021991B1 (ko)

Applications Claiming Priority (2)

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JP2002279198 2002-09-25
JPJP-P-2002-00279198 2002-09-25

Publications (2)

Publication Number Publication Date
KR20050057566A KR20050057566A (ko) 2005-06-16
KR101021991B1 true KR101021991B1 (ko) 2011-03-16

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Country Status (6)

Country Link
US (1) US7504180B2 (https=)
JP (1) JP4221371B2 (https=)
KR (1) KR101021991B1 (https=)
CN (1) CN100517818C (https=)
TW (1) TW200410437A (https=)
WO (1) WO2004030126A1 (https=)

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WO2003069702A1 (en) 2002-02-15 2003-08-21 Seimi Chemical Co., Ltd. Particulate positive electrode active material for lithium secondary cell
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JP4424949B2 (ja) * 2003-09-09 2010-03-03 三洋電機株式会社 非水電解質二次電池
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JP4669214B2 (ja) * 2003-09-30 2011-04-13 株式会社田中化学研究所 オキシ水酸化コバルト粒子及びその製造方法
JP4721729B2 (ja) * 2004-11-12 2011-07-13 三洋電機株式会社 非水電解質二次電池
JP4841133B2 (ja) * 2004-11-16 2011-12-21 三洋電機株式会社 非水電解質二次電池
JP4530822B2 (ja) * 2004-11-30 2010-08-25 三洋電機株式会社 非水電解質二次電池及びその充電方法
JP4652791B2 (ja) * 2004-12-08 2011-03-16 株式会社田中化学研究所 Ｍｇ固溶オキシ水酸化コバルト粒子及びその製造方法
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JP4530845B2 (ja) * 2004-12-28 2010-08-25 三洋電機株式会社 非水電解質二次電池及びその充電方法
JP4530844B2 (ja) * 2004-12-28 2010-08-25 三洋電機株式会社 非水電解質二次電池及びその充電方法
JP4794172B2 (ja) * 2005-01-18 2011-10-19 三洋電機株式会社 非水電解液二次電池及びその充電方法
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JP4794192B2 (ja) * 2005-03-31 2011-10-19 三洋電機株式会社 非水電解質二次電池及びその充電方法
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JP4813165B2 (ja) * 2005-12-07 2011-11-09 Ａｇｃセイミケミカル株式会社 非水電解質二次電池用正極活物質およびその製造方法
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JP5610178B2 (ja) * 2008-10-02 2014-10-22 戸田工業株式会社 リチウム複合化合物粒子粉末及びその製造方法、非水電解質二次電池
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JP2009164139A (ja) * 2009-04-20 2009-07-23 Toyo Tanso Kk 非水電解液二次電池用正極活物質の製造方法
JP5434278B2 (ja) 2009-05-29 2014-03-05 Ｔｄｋ株式会社 活物質及び電極の製造方法、活物質及び電極
JP5147891B2 (ja) * 2010-04-16 2013-02-20 三洋電機株式会社 非水電解質二次電池及びその充電方法
JP5147892B2 (ja) * 2010-04-16 2013-02-20 三洋電機株式会社 非水電解質二次電池及びその充電方法
JP5147890B2 (ja) * 2010-04-16 2013-02-20 三洋電機株式会社 非水電解質二次電池及びその充電方法
JP5241766B2 (ja) * 2010-04-16 2013-07-17 三洋電機株式会社 非水電解質二次電池及びその充電方法
US9882206B2 (en) * 2010-10-20 2018-01-30 Council Of Scientific & Industrial Research Cathode material and lithium ion battery therefrom
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JP5741969B2 (ja) * 2013-08-05 2015-07-01 戸田工業株式会社 リチウム複合化合物粒子粉末及びその製造方法、非水電解質二次電池
WO2015122690A1 (ko) * 2014-02-11 2015-08-20 주식회사 엘앤에프신소재 리튬 이차 전지용 양극 활물질, 이의 제조 방법 및 이를 포함하는 리튬 이차 전지
GB2539612B (en) * 2014-09-03 2021-12-01 Mitsui Mining & Smelting Co Ltd Positive electrode active material for lithium secondary cell
CN105651647B (zh) * 2016-04-13 2019-06-21 天津巴莫科技股份有限公司 正极材料中三氧化二铝含量的测试方法
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CN116454360A (zh) 2016-10-12 2023-07-18 株式会社半导体能源研究所 正极活性物质粒子以及正极活性物质粒子的制造方法
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CN119943936A (zh) 2017-05-12 2025-05-06 株式会社半导体能源研究所 正极活性物质粒子
KR102932867B1 (ko) 2017-05-19 2026-02-27 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극 활물질, 양극 활물질의 제작 방법, 및 이차 전지
CN118335885A (zh) 2017-06-26 2024-07-12 株式会社半导体能源研究所 正极活性物质的制造方法及二次电池
KR102264634B1 (ko) * 2017-09-08 2021-06-15 주식회사 엘지에너지솔루션 리튬 이차전지용 양극 활물질, 이의 제조 방법, 이를 포함하는 리튬 이차전지용 양극 및 리튬 이차전지
KR20250048814A (ko) 2018-06-22 2025-04-10 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극 활물질, 양극, 이차 전지, 및 양극의 제작 방법
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