JPH0516015B2 - - Google Patents
Info
- Publication number
- JPH0516015B2 JPH0516015B2 JP57198804A JP19880482A JPH0516015B2 JP H0516015 B2 JPH0516015 B2 JP H0516015B2 JP 57198804 A JP57198804 A JP 57198804A JP 19880482 A JP19880482 A JP 19880482A JP H0516015 B2 JPH0516015 B2 JP H0516015B2
- Authority
- JP
- Japan
- Prior art keywords
- emulsion
- silver
- sensitivity
- blue
- emulsions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000839 emulsion Substances 0.000 claims description 582
- 239000002245 particle Substances 0.000 claims description 131
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 claims description 111
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 83
- 238000001556 precipitation Methods 0.000 claims description 37
- 230000015572 biosynthetic process Effects 0.000 claims description 34
- 230000005855 radiation Effects 0.000 claims description 33
- 239000002612 dispersion medium Substances 0.000 claims description 23
- 230000001747 exhibiting effect Effects 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 238000010894 electron beam technology Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 403
- 235000013339 cereals Nutrition 0.000 description 317
- 230000035945 sensitivity Effects 0.000 description 205
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 192
- 229910052709 silver Inorganic materials 0.000 description 163
- 239000004332 silver Substances 0.000 description 163
- 239000000243 solution Substances 0.000 description 132
- 238000000034 method Methods 0.000 description 120
- -1 silver halide Chemical class 0.000 description 111
- 229910001961 silver nitrate Inorganic materials 0.000 description 96
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 86
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 84
- 230000003595 spectral effect Effects 0.000 description 77
- 206010070834 Sensitisation Diseases 0.000 description 72
- 239000000975 dye Substances 0.000 description 72
- 230000008313 sensitization Effects 0.000 description 72
- 108010010803 Gelatin Proteins 0.000 description 59
- 239000008273 gelatin Substances 0.000 description 58
- 229920000159 gelatin Polymers 0.000 description 58
- 235000019322 gelatine Nutrition 0.000 description 58
- 235000011852 gelatine desserts Nutrition 0.000 description 58
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 57
- 239000000126 substance Substances 0.000 description 46
- 239000007864 aqueous solution Substances 0.000 description 37
- 239000010944 silver (metal) Substances 0.000 description 35
- 239000000463 material Substances 0.000 description 31
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 31
- 239000003795 chemical substances by application Substances 0.000 description 30
- 238000000576 coating method Methods 0.000 description 29
- 230000008569 process Effects 0.000 description 28
- 238000007792 addition Methods 0.000 description 26
- 239000011248 coating agent Substances 0.000 description 26
- 239000013078 crystal Substances 0.000 description 25
- 238000011160 research Methods 0.000 description 23
- 229910021612 Silver iodide Inorganic materials 0.000 description 22
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 21
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 21
- 229940045105 silver iodide Drugs 0.000 description 21
- 230000005070 ripening Effects 0.000 description 19
- 230000001235 sensitizing effect Effects 0.000 description 19
- 238000002360 preparation method Methods 0.000 description 18
- 239000002244 precipitate Substances 0.000 description 17
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 16
- 229910052736 halogen Inorganic materials 0.000 description 15
- 150000002367 halogens Chemical class 0.000 description 15
- 230000008901 benefit Effects 0.000 description 14
- 238000011161 development Methods 0.000 description 14
- 230000018109 developmental process Effects 0.000 description 14
- 230000007935 neutral effect Effects 0.000 description 14
- 238000012545 processing Methods 0.000 description 14
- 239000000654 additive Substances 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 13
- 230000012010 growth Effects 0.000 description 13
- 239000011247 coating layer Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- 230000007423 decrease Effects 0.000 description 12
- 230000006872 improvement Effects 0.000 description 12
- 150000004694 iodide salts Chemical class 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 230000009102 absorption Effects 0.000 description 11
- 238000010521 absorption reaction Methods 0.000 description 11
- 238000000354 decomposition reaction Methods 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- 229910052740 iodine Inorganic materials 0.000 description 10
- 239000011630 iodine Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 230000009467 reduction Effects 0.000 description 10
- 238000001228 spectrum Methods 0.000 description 10
- 229910052717 sulfur Inorganic materials 0.000 description 10
- 239000011593 sulfur Substances 0.000 description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 9
- 238000000149 argon plasma sintering Methods 0.000 description 9
- 238000009826 distribution Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 9
- 229910052737 gold Inorganic materials 0.000 description 9
- 239000010931 gold Substances 0.000 description 9
- 238000005259 measurement Methods 0.000 description 9
- 239000011591 potassium Substances 0.000 description 9
- 229910052700 potassium Inorganic materials 0.000 description 9
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 9
- 150000003842 bromide salts Chemical class 0.000 description 8
- 239000000049 pigment Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 150000003378 silver Chemical class 0.000 description 8
- 229910001923 silver oxide Inorganic materials 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 7
- JDUHXLSMNANTJB-UHFFFAOYSA-N germide(4-) Chemical compound [Ge-4] JDUHXLSMNANTJB-UHFFFAOYSA-N 0.000 description 7
- 125000001475 halogen functional group Chemical group 0.000 description 7
- 235000013336 milk Nutrition 0.000 description 7
- 239000008267 milk Substances 0.000 description 7
- 210000004080 milk Anatomy 0.000 description 7
- 239000004848 polyfunctional curative Substances 0.000 description 7
- 210000002784 stomach Anatomy 0.000 description 7
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 6
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 6
- 210000000988 bone and bone Anatomy 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 6
- 238000010899 nucleation Methods 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
- 229910052711 selenium Inorganic materials 0.000 description 6
- 239000011669 selenium Substances 0.000 description 6
- 239000002356 single layer Substances 0.000 description 6
- PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 6
- 238000001429 visible spectrum Methods 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 5
- 229940006460 bromide ion Drugs 0.000 description 5
- 238000000586 desensitisation Methods 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 150000004820 halides Chemical class 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 239000011229 interlayer Substances 0.000 description 5
- CBEQRNSPHCCXSH-UHFFFAOYSA-N iodine monobromide Chemical compound IBr CBEQRNSPHCCXSH-UHFFFAOYSA-N 0.000 description 5
- 230000007246 mechanism Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 235000002492 Rungia klossii Nutrition 0.000 description 4
- 244000117054 Rungia klossii Species 0.000 description 4
- 229910021607 Silver chloride Inorganic materials 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 230000001186 cumulative effect Effects 0.000 description 4
- 238000006073 displacement reaction Methods 0.000 description 4
- 238000000635 electron micrograph Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000003607 modifier Substances 0.000 description 4
- 230000006911 nucleation Effects 0.000 description 4
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 4
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 3
- KAMCBFNNGGVPPW-UHFFFAOYSA-N 1-(ethenylsulfonylmethoxymethylsulfonyl)ethene Chemical compound C=CS(=O)(=O)COCS(=O)(=O)C=C KAMCBFNNGGVPPW-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 241000257465 Echinoidea Species 0.000 description 3
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 241000276425 Xiphophorus maculatus Species 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 3
- 229910052798 chalcogen Inorganic materials 0.000 description 3
- 150000001787 chalcogens Chemical class 0.000 description 3
- 230000000295 complement effect Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000010946 fine silver Substances 0.000 description 3
- 235000020268 grain milk Nutrition 0.000 description 3
- 230000026030 halogenation Effects 0.000 description 3
- 238000005658 halogenation reaction Methods 0.000 description 3
- 125000000623 heterocyclic group Chemical group 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical class [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 3
- 239000002516 radical scavenger Substances 0.000 description 3
- 230000033458 reproduction Effects 0.000 description 3
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 3
- 238000004611 spectroscopical analysis Methods 0.000 description 3
- 229940071240 tetrachloroaurate Drugs 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 description 2
- SGYIRNXZLWJMCR-UHFFFAOYSA-M 3-methyl-1,3-benzothiazol-3-ium;iodide Chemical compound [I-].C1=CC=C2[N+](C)=CSC2=C1 SGYIRNXZLWJMCR-UHFFFAOYSA-M 0.000 description 2
- 241000473391 Archosargus rhomboidalis Species 0.000 description 2
- 229920002284 Cellulose triacetate Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229940090898 Desensitizer Drugs 0.000 description 2
- RZSYLLSAWYUBPE-UHFFFAOYSA-L Fast green FCF Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC(O)=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 RZSYLLSAWYUBPE-UHFFFAOYSA-L 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910000806 Latten Inorganic materials 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 238000001016 Ostwald ripening Methods 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 241000700159 Rattus Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 2
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229940107816 ammonium iodide Drugs 0.000 description 2
- UDGLEEJNZQQJOJ-UHFFFAOYSA-N benzene-1,4-diol [4-(methylamino)phenyl] hydrogen sulfate Chemical compound S(=O)(=O)(O)OC1=CC=C(C=C1)NC.C1(O)=CC=C(O)C=C1 UDGLEEJNZQQJOJ-UHFFFAOYSA-N 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000012992 electron transfer agent Substances 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 229940006461 iodide ion Drugs 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000031700 light absorption Effects 0.000 description 2
- 230000035800 maturation Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000013081 microcrystal Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229940116357 potassium thiocyanate Drugs 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 238000006862 quantum yield reaction Methods 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- XQLMNMQWVCXIKR-UHFFFAOYSA-M silver bromate Chemical compound [Ag+].[O-]Br(=O)=O XQLMNMQWVCXIKR-UHFFFAOYSA-M 0.000 description 2
- RHUVFRWZKMEWNS-UHFFFAOYSA-M silver thiocyanate Chemical compound [Ag+].[S-]C#N RHUVFRWZKMEWNS-UHFFFAOYSA-M 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
- 150000003567 thiocyanates Chemical class 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- ZXSQEZNORDWBGZ-UHFFFAOYSA-N 1,3-dihydropyrrolo[2,3-b]pyridin-2-one Chemical compound C1=CN=C2NC(=O)CC2=C1 ZXSQEZNORDWBGZ-UHFFFAOYSA-N 0.000 description 1
- XJDDLMJULQGRLU-UHFFFAOYSA-N 1,3-dioxane-4,6-dione Chemical compound O=C1CC(=O)OCO1 XJDDLMJULQGRLU-UHFFFAOYSA-N 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- ZKAMEFMDQNTDFK-UHFFFAOYSA-N 1h-imidazo[4,5-b]pyrazine Chemical compound C1=CN=C2NC=NC2=N1 ZKAMEFMDQNTDFK-UHFFFAOYSA-N 0.000 description 1
- PVKCAQKXTLCSBC-UHFFFAOYSA-N 1h-isoquinolin-4-one Chemical compound C1=CC=C2C(=O)C=NCC2=C1 PVKCAQKXTLCSBC-UHFFFAOYSA-N 0.000 description 1
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical compound O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical compound O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
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-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C2200/00—Details
- G03C2200/03—111 crystal face
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/3022—Materials with specific emulsion characteristics, e.g. thickness of the layers, silver content, shape of AgX grains
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32090581A | 1981-11-12 | 1981-11-12 | |
| US320909 | 1981-11-12 | ||
| US320905 | 1981-11-12 | ||
| US431913 | 1982-09-30 | ||
| US429420 | 1982-09-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58113927A JPS58113927A (ja) | 1983-07-07 |
| JPH0516015B2 true JPH0516015B2 (US06863391-20050308-C00001.png) | 1993-03-03 |
Family
ID=23248344
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57198805A Granted JPS58113928A (ja) | 1981-11-12 | 1982-11-12 | 高アスペクト比平板状粒子ヨウ臭化銀乳剤の調製方法 |
| JP57198804A Granted JPS58113927A (ja) | 1981-11-12 | 1982-11-12 | 高アスペクト比平板状粒子ヨウ臭化銀乳剤 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57198805A Granted JPS58113928A (ja) | 1981-11-12 | 1982-11-12 | 高アスペクト比平板状粒子ヨウ臭化銀乳剤の調製方法 |
Country Status (3)
| Country | Link |
|---|---|
| JP (2) | JPS58113928A (US06863391-20050308-C00001.png) |
| BE (1) | BE894965A (US06863391-20050308-C00001.png) |
| ZA (1) | ZA828344B (US06863391-20050308-C00001.png) |
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|---|---|---|---|---|
| US6720041B2 (en) | 1998-11-20 | 2004-04-13 | Canon Kabushiki Kaisha | Recording medium, and method for producing image using the same |
| US6719420B2 (en) | 2001-05-10 | 2004-04-13 | Canon Kabushiki Kaisha | Liquid composition, ink set, method for forming colored portion on recording medium, and ink-jet recording apparatus |
| US6729718B2 (en) | 2001-05-09 | 2004-05-04 | Canon Kabushiki Kaisha | Recording method, recording apparatus, method for manufacturing recorded article, and recorded article |
| US6746114B2 (en) | 2001-05-10 | 2004-06-08 | Canon Kabushiki Kaisha | Ink set, process for forming colored portion and ink-jet recording apparatus |
| US6821328B2 (en) | 2001-05-10 | 2004-11-23 | Canon Kabushiki Kaisha | Liquid composition, ink set, method of forming colored portion in recording medium and ink-jet recording apparatus |
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| WO2008130045A1 (ja) | 2007-04-18 | 2008-10-30 | Canon Kabushiki Kaisha | インクジェット記録媒体およびその製造方法 |
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| US9662921B2 (en) | 2015-03-02 | 2017-05-30 | Canon Kabushiki Kaisha | Recording medium |
| US9701147B2 (en) | 2015-03-02 | 2017-07-11 | Canon Kabushiki Kaisha | Recording medium with enhanced flexibility |
| US9713932B2 (en) | 2015-03-02 | 2017-07-25 | Canon Kabushiki Kaisha | Recording medium with enhanced flexibility |
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| US11413897B2 (en) | 2019-05-10 | 2022-08-16 | Canon Kabushiki Kaisha | Inkjet recording medium |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60118833A (ja) * | 1983-11-30 | 1985-06-26 | Fuji Photo Film Co Ltd | ハロゲン化銀写真乳剤 |
| JP2651566B2 (ja) * | 1984-06-29 | 1997-09-10 | コニカ株式会社 | ハロゲン化銀乳剤及びハロゲン化銀カラー写真感光材料 |
| JPH0614176B2 (ja) * | 1984-07-09 | 1994-02-23 | コニカ株式会社 | ハロゲン化銀カラ−写真感光材料 |
| JPS6172234A (ja) * | 1984-09-14 | 1986-04-14 | Konishiroku Photo Ind Co Ltd | ハロゲン化銀カラ−写真感光材料 |
| JPS6172235A (ja) * | 1984-09-14 | 1986-04-14 | Konishiroku Photo Ind Co Ltd | ハロゲン化銀カラ−写真感光材料 |
| JPS6173148A (ja) * | 1984-09-18 | 1986-04-15 | Konishiroku Photo Ind Co Ltd | ハロゲン化銀カラ−写真感光材料 |
| JPS61245151A (ja) | 1985-04-23 | 1986-10-31 | Konishiroku Photo Ind Co Ltd | ハロゲン化銀写真感光材料 |
| JPS61250645A (ja) | 1985-04-30 | 1986-11-07 | Konishiroku Photo Ind Co Ltd | ハロゲン化銀写真感光材料 |
| JPS61250643A (ja) | 1985-04-30 | 1986-11-07 | Konishiroku Photo Ind Co Ltd | ハロゲン化銀写真感光材料 |
| JPH0610754B2 (ja) * | 1985-09-14 | 1994-02-09 | コニカ株式会社 | 多色写真要素 |
| JPS62151840A (ja) * | 1985-12-26 | 1987-07-06 | Fuji Photo Film Co Ltd | 高アスペクト比のヨウ臭化銀乳剤の調製方法 |
| AU591540B2 (en) | 1985-12-28 | 1989-12-07 | Konishiroku Photo Industry Co., Ltd. | Method of processing light-sensitive silver halide color photographic material |
| JP2727072B2 (ja) * | 1986-01-20 | 1998-03-11 | コニカ株式会社 | ハロゲン化銀写真感光材料 |
| DE3782351T2 (de) | 1986-03-25 | 1993-05-27 | Konishiroku Photo Ind | Lichtempfindliches photographisches silberhalogenidmaterial, das fuer schnelle entwicklung verwendbar ist. |
| JPH07119946B2 (ja) * | 1986-12-19 | 1995-12-20 | コニカ株式会社 | 銀画像の色調を改良したハロゲン化銀写真感光材料 |
| JPH07101291B2 (ja) * | 1987-09-02 | 1995-11-01 | 富士写真フイルム株式会社 | ハロゲン化銀乳剤及びその製造方法 |
| JPH0789205B2 (ja) * | 1987-10-05 | 1995-09-27 | 富士写真フイルム株式会社 | ハロゲン化銀乳剤 |
| DE3855361T2 (de) | 1987-10-20 | 1997-01-02 | Fuji Photo Film Co Ltd | Photographisches Silberhalogenidmaterial |
| JPH01183644A (ja) * | 1988-01-18 | 1989-07-21 | Fuji Photo Film Co Ltd | ハロゲン化銀写真乳剤 |
| EP0370116B1 (en) * | 1988-01-18 | 1995-11-02 | Fuji Photo Film Co., Ltd. | Silver halide photographic material and process for its preparation |
| US4865964A (en) * | 1988-03-25 | 1989-09-12 | Eastman Kodak Company | Blended emulsions exhibiting improved speed-granularity relationship |
| JP2670847B2 (ja) * | 1988-04-11 | 1997-10-29 | 富士写真フイルム株式会社 | ハロゲン化銀写真乳剤およびその製造方法 |
| JP2587282B2 (ja) * | 1989-01-09 | 1997-03-05 | 富士写真フイルム株式会社 | ハロゲン化銀写真感光材料 |
| JP2534118B2 (ja) * | 1989-01-09 | 1996-09-11 | 富士写真フイルム株式会社 | ハロゲン化銀写真感光材料及びその製造方法 |
| JP2587287B2 (ja) * | 1989-02-15 | 1997-03-05 | 富士写真フイルム株式会社 | ハロゲン化銀写真感光材料及びその製造方法 |
| JP2587288B2 (ja) * | 1989-02-15 | 1997-03-05 | 富士写真フイルム株式会社 | ハロゲン化銀写真感光材料及びその製造方法 |
| JP2681529B2 (ja) * | 1989-07-11 | 1997-11-26 | 富士写真フイルム株式会社 | ハロゲン化銀乳剤 |
| JPH0375631A (ja) * | 1989-08-17 | 1991-03-29 | Fuji Photo Film Co Ltd | ハロゲン化銀カラー反転感光材料 |
| JP2833795B2 (ja) * | 1989-09-30 | 1998-12-09 | 麒麟麦酒株式会社 | ナデシコ属植物のプロトプラスト調製方法及び植物体再生方法 |
| US5035990A (en) * | 1989-11-28 | 1991-07-30 | E. I. Du Pont De Nemours And Company | Radiographic elements with improved covering power |
| JPH03198040A (ja) * | 1989-12-27 | 1991-08-29 | Fuji Photo Film Co Ltd | ハロゲン化銀写真乳剤の製造方法 |
| JP2687184B2 (ja) * | 1990-10-25 | 1997-12-08 | 富士写真フイルム株式会社 | 写真用ハロゲン化銀乳剤の製造方法及びそれを用いた感光材料の現像処理方法 |
| JPH04336536A (ja) * | 1991-05-14 | 1992-11-24 | Konica Corp | ハロゲン化銀写真乳剤 |
| US5418124A (en) | 1992-03-19 | 1995-05-23 | Fuji Photo Film Co. Ltd. | Silver halide photographic emulsion and a photographic light-sensitive material |
| DE69328884T2 (de) | 1992-03-19 | 2000-12-07 | Fuji Photo Film Co Ltd | Verfahren zur Herstellung einer photographischen Silberhalogenidemulsion |
| JPH0675343A (ja) | 1992-07-06 | 1994-03-18 | Fuji Photo Film Co Ltd | ハロゲン化銀カラー写真感光材料及びカラー画像形成方法 |
| JP2824717B2 (ja) | 1992-07-10 | 1998-11-18 | 富士写真フイルム株式会社 | ハロゲン化銀写真感光材料の処理方法 |
| EP0589460B1 (en) | 1992-09-24 | 2000-08-09 | Fuji Photo Film Co., Ltd. | Method for processing a black & white silver halide light-sensitive material |
| JP2824889B2 (ja) * | 1992-12-17 | 1998-11-18 | 富士写真フイルム株式会社 | ハロゲン化銀写真感光材料 |
| EP0662632B1 (en) * | 1994-01-11 | 2004-04-07 | Fuji Photo Film Co., Ltd. | Silver halide light-sensitive emulsion and silver halide light-sensitive material |
| JPH086191A (ja) | 1994-06-17 | 1996-01-12 | Konica Corp | ハロゲン化銀粒子、該粒子を含有するハロゲン化銀乳剤及び該乳剤を含有するハロゲン化銀写真感光材料 |
| JPH09152696A (ja) | 1995-11-30 | 1997-06-10 | Fuji Photo Film Co Ltd | ハロゲン化銀カラー写真感光材料 |
| JP3817787B2 (ja) | 1996-02-09 | 2006-09-06 | コニカミノルタホールディングス株式会社 | ロイコ染料、ハロゲン化銀写真感光材料、その画像形成方法およびその処理方法 |
| US6787296B2 (en) | 2001-05-29 | 2004-09-07 | Konica Corporation | Silver halide emulsion and silver halide photographic material by the use thereof |
| JP4887201B2 (ja) | 2007-04-13 | 2012-02-29 | 富士フイルム株式会社 | ハロゲン化銀写真感光材料及びこれを用いた画像形成方法 |
-
1982
- 1982-11-09 BE BE0/209441A patent/BE894965A/fr not_active IP Right Cessation
- 1982-11-12 JP JP57198805A patent/JPS58113928A/ja active Granted
- 1982-11-12 JP JP57198804A patent/JPS58113927A/ja active Granted
- 1982-11-12 ZA ZA828344A patent/ZA828344B/xx unknown
Non-Patent Citations (1)
| Title |
|---|
| THE THEORY OF THE PHOTOGRAPHIC PROCESS THIRD EDITION=1967 * |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6720041B2 (en) | 1998-11-20 | 2004-04-13 | Canon Kabushiki Kaisha | Recording medium, and method for producing image using the same |
| US6830709B2 (en) | 2000-10-06 | 2004-12-14 | Canon Kabushiki Kaisha | Method of measuring liquid composition, liquid composition, ink set, method for forming colored portion on recording medium, and ink-jet recording apparatus |
| US6729718B2 (en) | 2001-05-09 | 2004-05-04 | Canon Kabushiki Kaisha | Recording method, recording apparatus, method for manufacturing recorded article, and recorded article |
| US6719420B2 (en) | 2001-05-10 | 2004-04-13 | Canon Kabushiki Kaisha | Liquid composition, ink set, method for forming colored portion on recording medium, and ink-jet recording apparatus |
| US6746114B2 (en) | 2001-05-10 | 2004-06-08 | Canon Kabushiki Kaisha | Ink set, process for forming colored portion and ink-jet recording apparatus |
| US6821328B2 (en) | 2001-05-10 | 2004-11-23 | Canon Kabushiki Kaisha | Liquid composition, ink set, method of forming colored portion in recording medium and ink-jet recording apparatus |
| US6863391B2 (en) | 2001-05-10 | 2005-03-08 | Canon Kabushiki Kaisha | Liquid composition, ink set, method of forming a colored section on recording medium and ink-jet recording apparatus |
| WO2008130045A1 (ja) | 2007-04-18 | 2008-10-30 | Canon Kabushiki Kaisha | インクジェット記録媒体およびその製造方法 |
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| EP2332734A1 (en) | 2009-12-08 | 2011-06-15 | Canon Kabushiki Kaisha | Recording medium and method for producing recording medium |
| EP2363295A1 (en) | 2010-03-03 | 2011-09-07 | Canon Kabushiki Kaisha | Recording medium |
| US8236394B2 (en) | 2010-03-03 | 2012-08-07 | Canon Kabushiki Kaisha | Recording medium |
| EP2390105A1 (en) | 2010-05-31 | 2011-11-30 | Canon Kabushiki Kaisha | Ink-jet recording medium |
| US9662921B2 (en) | 2015-03-02 | 2017-05-30 | Canon Kabushiki Kaisha | Recording medium |
| US9701147B2 (en) | 2015-03-02 | 2017-07-11 | Canon Kabushiki Kaisha | Recording medium with enhanced flexibility |
| US9713932B2 (en) | 2015-03-02 | 2017-07-25 | Canon Kabushiki Kaisha | Recording medium with enhanced flexibility |
| US10981405B2 (en) | 2017-11-10 | 2021-04-20 | Canon Kabushiki Kaisha | Recording medium substrate and recording medium |
| US11413897B2 (en) | 2019-05-10 | 2022-08-16 | Canon Kabushiki Kaisha | Inkjet recording medium |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA828344B (en) | 1983-09-28 |
| JPH0522902B2 (US06863391-20050308-C00001.png) | 1993-03-31 |
| BE894965A (fr) | 1983-05-09 |
| JPS58113928A (ja) | 1983-07-07 |
| JPS58113927A (ja) | 1983-07-07 |
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