JP6122165B2 - 半導体装置 - Google Patents
半導体装置 Download PDFInfo
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- JP6122165B2 JP6122165B2 JP2016040619A JP2016040619A JP6122165B2 JP 6122165 B2 JP6122165 B2 JP 6122165B2 JP 2016040619 A JP2016040619 A JP 2016040619A JP 2016040619 A JP2016040619 A JP 2016040619A JP 6122165 B2 JP6122165 B2 JP 6122165B2
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- 239000004065 semiconductor Substances 0.000 title claims description 257
- 239000000758 substrate Substances 0.000 claims description 107
- 239000010410 layer Substances 0.000 claims description 81
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 49
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 49
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 41
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 41
- 238000003860 storage Methods 0.000 claims description 35
- 239000011229 interlayer Substances 0.000 claims description 31
- 238000002955 isolation Methods 0.000 claims description 21
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 239000004020 conductor Substances 0.000 claims description 2
- 229920005591 polysilicon Polymers 0.000 claims description 2
- 238000000034 method Methods 0.000 description 56
- 238000004519 manufacturing process Methods 0.000 description 52
- 229910021332 silicide Inorganic materials 0.000 description 41
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 41
- 230000002093 peripheral effect Effects 0.000 description 39
- 239000012535 impurity Substances 0.000 description 25
- 238000005229 chemical vapour deposition Methods 0.000 description 15
- 238000005530 etching Methods 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 230000004048 modification Effects 0.000 description 11
- 238000012986 modification Methods 0.000 description 11
- 238000001312 dry etching Methods 0.000 description 10
- 229920002120 photoresistant polymer Polymers 0.000 description 9
- 229910052785 arsenic Inorganic materials 0.000 description 8
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 8
- 239000003990 capacitor Substances 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 7
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- 238000007254 oxidation reaction Methods 0.000 description 7
- 230000006870 function Effects 0.000 description 6
- 238000001459 lithography Methods 0.000 description 6
- 238000005468 ion implantation Methods 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 230000010354 integration Effects 0.000 description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- 229910015900 BF3 Inorganic materials 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 3
- 229910021417 amorphous silicon Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012212 insulator Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 238000000206 photolithography Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241000080590 Niso Species 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005669 field effect Effects 0.000 description 2
- 230000012447 hatching Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910019001 CoSi Inorganic materials 0.000 description 1
- -1 Metal Oxide Nitride Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000013500 data storage Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 description 1
- 229910021334 nickel silicide Inorganic materials 0.000 description 1
- PEUPIGGLJVUNEU-UHFFFAOYSA-N nickel silicon Chemical compound [Si].[Ni] PEUPIGGLJVUNEU-UHFFFAOYSA-N 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
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Description
本発明の実施の形態1による不揮発性メモリセルの構造の一例を図1によって説明し、不揮発性メモリセルを構成するメモリゲート電極および選択ゲート電極の給電領域の構造の一例を図2および図3によって説明する。図1はチャネルをメモリゲート電極に対して交差する方向に沿って切断した不揮発性メモリセルの要部断面図、図2は給電領域の要部平面図、図3(a)および(b)はそれぞれ図2のA−A′線に沿った要部断面図(メモリゲート電極のシャント部の要部断面図)および図2のB−B′線に沿った要部断面図(選択ゲート電極のシャント部の要部断面図)である。ここでは、サイドウォール形状のメモリゲート電極を採用したスプリットゲート構造のMONOS型不揮発性メモリセルを例示している。
前述の実施の形態1と相違する点は、MGシャント部の選択ゲート電極CGとキャップ絶縁膜CAPとの間に熱酸化膜が形成されていることである。すなわち、前述した実施の形態1では、MGシャント部の選択ゲート電極CGに接してキャップ絶縁膜CAPが形成されている。しかし、本実施の形態2では、MGシャント部の選択ゲート電極CGと、例えば窒化シリコン、酸化シリコン、窒素を含んだ酸化シリコン、炭化シリコンからなるキャップ絶縁膜CAPとの間に、例えば厚さ5〜10nm程度の酸化シリコンからなる熱酸化膜が形成されている。熱酸化膜は選択ゲート電極CGを構成する導電膜10nに対して熱酸化処理を施すことにより形成され、キャップ絶縁膜CAPはCVD法により形成されるので、熱酸化膜のエッチング速度とキャップ絶縁膜CAPのエッチング速度とを互いに異なる値とすることができる。従って、MGシャント部においてメモリゲート電極MG上のシリサイド層3に達するコンタクトホールCMを層間絶縁膜9に形成する際に、窒化シリコン膜9aのオーバーエッチングにより選択ゲート電極CG上のキャップ絶縁膜CAPが削れても、この熱酸化膜をエッチングストッパ膜として機能させることができるので、コンタクトホールCMが選択ゲート電極CGに達するのを防いで、コンタクトホールCM内のプラグPMと選択ゲート電極CGとの電気的な接続を防ぐことができる。
前述の実施の形態1と相違する点は、メモリ領域のドレイン領域Drm上のシリサイド層3に達するコンタクトホールCNTが、選択ゲート電極CGの上面に形成されたキャップ絶縁膜CAP上に乗り上げた形状となっていることである。
2ad、2as n−型の半導体領域
2b n+型の半導体領域
3 シリサイド層
4、4A ゲート絶縁膜
5 半導体領域
6b、6t 絶縁膜
7b、7t 酸化シリコン膜
7m 窒化シリコン膜
8 半導体領域
9 層間絶縁膜
9a 窒化シリコン膜
9b 酸化シリコン膜
10 導電膜
10E 下部電極
10n、10na、10p 導電膜
11 サイドウォール
11E 上部電極
13 n−型の半導体領域
14 p−型の半導体領域
15 サイドウォール
16 レジストパターン
17 レジストパターン
18 n−型の半導体領域
19 p−型の半導体領域
20 レジストパターン
21 p+型の半導体領域
22 レジストパターン
23 n+型の半導体領域
25 熱酸化膜
51 パッド電極
52 コンタクトホール
ACT 活性領域
CA、CB、CC、CM、CNT、CNTS コンタクトホール
CAP キャップ絶縁膜
CG 選択ゲート電極
CSL 電荷蓄積層
Dc 半導体領域
Drm ドレイン領域
GHn、GHp、GLn、GLp ゲート電極
HNW nウェル
HPW pウェル
M1 第1層配線
MC、MC2 メモリセル
MG メモリゲート電極
NISO 埋め込みnウェル
NW nウェル
PA、PB、PC、PLG、PM プラグ
PW pウェル
Qnc 選択用nMIS
Qnm メモリ用nMIS
RP レジストパターン
SD ソース・ドレイン領域
Srm ソース領域
STI 素子分離部
SW サイドウォール
Claims (7)
- 主面に第1領域および平面視において前記第1領域と異なる第2領域を有する半導体基板と、
前記第1領域の前記半導体基板の前記主面上に形成された第1ゲート絶縁膜と、
前記第2領域の前記半導体基板の前記主面に形成された素子分離部と、
前記第1領域から前記第2領域に亘って連続的に形成された選択ゲート電極と、
前記選択ゲート電極の上面を覆う第1絶縁膜と、
前記第1領域から前記第2領域の前記素子分離部の直上に亘って連続的に形成され、前記選択ゲート電極の側壁に沿って延在するメモリゲート電極と、
前記メモリゲート電極および前記半導体基板の主面の間に形成され、電荷蓄積部を有する第2ゲート絶縁膜と、
前記選択ゲート電極の横の一方の前記半導体基板の主面に形成された第1半導体領域と、
前記選択ゲート電極の横の他方であって、前記メモリゲート電極の横の一方の前記半導体基板の主面に形成された第2半導体領域と、
前記第2領域において前記メモリゲート電極と隣り合う位置に形成された、前記第1絶縁膜と同層の第2絶縁膜と、
前記メモリゲート電極の側面のうち、前記第2ゲート絶縁膜と接する第1側面の反対側の第2側面に接し、前記第2側面を覆う第4絶縁膜からなるサイドウォールと、
前記第1絶縁膜、前記選択ゲート電極および前記メモリゲート電極を覆うように、前記半導体基板の主面上に形成された層間絶縁膜と、
前記第2領域において、前記メモリゲート電極の上面上の前記層間絶縁膜中に配置され、前記メモリゲート電極に電気的に接続されたコンタクトプラグと、
を有し、
前記コンタクトプラグは、前記第2絶縁膜の上面に接する、半導体装置。 - 請求項1に記載の半導体装置において、
前記第1絶縁膜は、窒化シリコン膜を含む、半導体装置。 - 請求項2に記載の半導体装置において、
前記第1絶縁膜は、前記窒化シリコン膜と前記選択ゲート電極との間に形成された酸化シリコン膜をさらに含む、半導体装置。 - 請求項2に記載の半導体装置において、
前記層間絶縁膜は、酸化シリコン膜を含む、半導体装置。 - 請求項1に記載の半導体装置において、
前記素子分離部は、前記半導体基板の主面の溝に埋め込まれた第3絶縁膜により構成されている、半導体装置。 - 請求項1に記載の半導体装置において、
前記選択ゲート電極および前記メモリゲート電極のそれぞれは、ポリシリコン膜を含む、半導体装置。 - 請求項1に記載の半導体装置において、
前記コンタクトプラグは、タングステンまたはアルミニウムのいずれかの導電材料を含む、半導体装置。
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