JP5031987B2 - 耐酸化性が良好な次世代ダマシンバリヤ適用のための二層膜 - Google Patents
耐酸化性が良好な次世代ダマシンバリヤ適用のための二層膜 Download PDFInfo
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- JP5031987B2 JP5031987B2 JP2004543368A JP2004543368A JP5031987B2 JP 5031987 B2 JP5031987 B2 JP 5031987B2 JP 2004543368 A JP2004543368 A JP 2004543368A JP 2004543368 A JP2004543368 A JP 2004543368A JP 5031987 B2 JP5031987 B2 JP 5031987B2
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- silicon carbide
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
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- H01L21/02167—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon carbide not containing oxygen, e.g. SiC, SiC:H or silicon carbonitrides
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
- C23C16/505—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using radio frequency discharges
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Description
[0001]本発明は、集積回路の製造、更に詳細には、基板上に誘電体層を堆積させる方法、及び誘電体層によって形成された構造に関する。本発明は、更に、基板上にバリヤ層を堆積させる方法、およびバリヤ層によって形成された構造に関する。
関連技術の説明
デュアルダマシン構造に対するバリヤ層の堆積
[0048]バリヤ層として本明細書に記載されるシリコンカーバイド物質を用いて形成されたダマシン構造50の例を図1に示す。シリコンカーバイドバリヤ層10は、一般的には、基板と続いて堆積した物質との間の中間レベルの拡散を排除するために基板表面上に本明細書に記載されたプロセスに従って前駆物質を用いて堆積される。基板表面は、誘電物質5中に形成された金属特徴部7を含むことができる。
実施例
[0063]本明細書に記載された有機シリコン化合物を、基板表面上にバリヤ層として堆積させ、解析した。一例においては、シリコンカーバイドバリヤ膜を、ジフェニルシラン化合物から堆積させ、従来のシリコンカーバイド前駆物質であるトリメチルシランからのシリコンカーバイドバリヤ膜と比較した。
50…ダマシン構造。
Claims (33)
- 基板を処理する方法であって、
有機シリコン化合物を含む第一処理ガス混合物を処理チャンバへ導入し、ここで、該有機シリコン化合物は式SiHa(CH3)b(C6H5)c(式中、aは0〜3であり、bは0〜3であり、cは1〜4である。)を有する、該第一処理ガス混合物を反応させてシリコンカーバイドバリヤ層を堆積させることにより、シリコンカーバイドバリヤ層を、誘電物質中に形成された金属特徴部を含む基板表面に堆積させるステップであって、該シリコンカーバイドバリヤ層は、4未満の誘電率を有しており、シリコン原子に結合したフェニル基を含有する、前記ステップと、
第二有機シリコン化合物を含む第二処理ガス混合物を処理チャンバへ導入し、該第二処理ガス混合物を反応させてシリコンカーバイドキャップ層を堆積させることにより、該シリコンカーバイドバリヤ層に接するシリコンカーバイドキャップ層を堆積させるステップであって、該シリコンカーバイドキャップ層がシリコン原子に結合したフェニル基を有しない、前記ステップと、を含む、前記方法。 - 該第二処理ガス混合物の該第二有機シリコン化合物がトリメチルシランであり、該第二処理ガス混合物がヘリウムを更に含んでいる、請求項1記載の方法。
- 該シリコンカーバイドキャップ層を、約0.02W/cm2〜約5W/cm2の高周波RF電力密度を含むプラズマ条件下で堆積させる、請求項1記載の方法。
- 該第二処理ガス混合物の該第二有機シリコン化合物が約50sccm〜約800sccmの流量で該チャンバへ流される、請求項1記載の方法。
- 該第二処理ガス混合物が、アルゴン、ヘリウム、窒素、及びアンモニアの群より選ばれた、酸素を含まないガスを更に含んでいる、請求項1記載の方法。
- 該第二処理ガス混合物の該酸素を含まないガスが約50sccm〜約2000sccmの流量で該チャンバへ流される、請求項5記載の方法。
- 該第一処理ガス混合物の該有機シリコン化合物がジフェニルメチルシラン、ジメチルフェニルシラン、ジフェニルシラン、又はその混合物を含んでいる、請求項1記載の方法。
- 該第一処理ガス混合物が、酸素含有化合物、窒素含有化合物、ホウ素含有化合物、リン含有化合物、及びその組合わせの群より選ばれたドーパント成分を更に含んでいる、請求項1記載の方法。
- 該酸素含有化合物が、酸素、オゾン、シロキサン、及びその組合わせの群より選ばれる、請求項8記載の方法。
- 該窒素含有化合物が、窒素ガス、アンモニア、シラザン、及びその組合わせの群より選ばれる、請求項8記載の方法。
- 該第一処理ガス混合物が、アルゴン、ヘリウム、ネオン、キセノン、クリプトン、又はその組合わせの群より選ばれた不活性ガスを更に含んでいる、請求項1記載の方法。
- 該バリヤ層が約15原子パーセント未満の酸素を含んでいる、請求項1記載の方法。
- aが1又は2であり、bが1又は2であり、cが1又は2である、請求項1記載の方法。
- 前記シリコンカーバイドキャップ層は、50Åから100Åの間の厚さを有する、請求項1から13のいずれか1項に記載の方法。
- 基板を処理する方法であって、
第一有機シリコン化合物を含む第一処理ガス混合物を処理チャンバへ導入し、ここで、該第一有機シリコン化合物は式SiHa(CH3)b(C6H5)c(式中、aは0〜3であり、bは0〜3であり、cは1〜4である。)を有する、該処理ガスを反応させてシリコンカーバイドバリヤ層を堆積させることにより、該基板上にシリコンカーバイドバリヤ層を、誘電物質中に形成された金属特徴部を含む基板表面に堆積させるステップであって、該シリコンカーバイドバリヤ層は、4未満の誘電率を有しており、シリコン原子に結合したフェニル基を含有する、前記ステップと、
式SiHx(CH3)y(C2H5)z(式中、xは1〜3であり、yは0〜3であり、zは0〜3である。)を有する第二有機シリコン化合物を含む第二処理ガス混合物を該処理チャンバへ導入し、該第二処理ガス混合物を反応させてシリコンカーバイドキャップ層を堆積させることにより、該シリコンカーバイドバリヤ層上にシリコンカーバイドキャップ層を堆積させるステップであって、該シリコンカーバイドキャップ層がシリコン原子に結合したフェニル基を有しない、前記ステップと、を含む、前記方法。 - 該第二処理ガス混合物の第二有機シリコン化合物がトリメチルシランであり、該第二処理ガス混合物がヘリウムを更に含んでいる、請求項15記載の方法。
- 該シリコンカーバイドキャップ層を、約0.02W/cm2〜約5W/cm2の高周波RF電力密度を含むプラズマ条件下で堆積させる、請求項15記載の方法。
- 該第二処理ガス混合物の該第二有機シリコン化合物が約50sccm〜約800sccmの流量で該チャンバへ流される、請求項15記載の方法。
- 該第二処理ガス混合物が、アルゴン、ヘリウム、窒素、及びアンモニアの群より選ばれた酸素を含まないガスを更に含んでいる、請求項15記載の方法。
- 該第二処理ガス混合物の該酸素を含まないガスが約50sccm〜約2000sccmの流量で該チャンバへ流される、請求項19記載の方法。
- 該第一処理ガス混合物の該第一有機シリコン化合物がジフェニルメチルシラン、ジメチルフェニルシラン、ジフェニルシラン、又はその組合わせを含んでいる、請求項15記載の方法。
- 該第一処理ガス混合物を反応させるステップが、該第一処理ガス混合物の該第一有機シリコン化合物と酸素、オゾン、シロキサン、及びその組合わせの群より選ばれた酸素含有化合物とを反応させる工程を含んでいる、請求項15記載の方法。
- 該酸素含有化合物が、酸素、オゾン、シロキサン、及びその組合わせの群より選ばれる、請求項22記載の方法。
- 該第一処理ガス混合物が、窒素含有化合物、ホウ素含有化合物、リン含有化合物、及びその組合わせの群より選ばれたドーパント成分を更に含んでいる、請求項15記載の方法。
- 該窒素含有化合物が、窒素ガス、アンモニア、シラザン、及びその組合わせの群より選ばれる、請求項24記載の方法。
- 該第一処理ガス混合物が、アルゴン、ヘリウム、ネオン、キセノン、又はクリプトン、及びその組合わせの群より選ばれた不活性ガスを更に含んでいる、請求項15記載の方法。
- 該バリヤ層が約15原子パーセント未満の酸素を含んでいる、請求項15記載の方法。
- aが1又は2であり、bが1又は2であり、cが1又は2である、請求項15記載の方法。
- 該キャップ層上に誘電体層を堆積させるステップを更に含み、該誘電体層の誘電率が約4未満である、請求項15記載の方法。
- 該誘電体層の炭素含量が水素原子を除く約5〜約30原子パーセントである、請求項29記載の方法。
- 該誘電体層を、有機シラン又は有機シロキサン化合物をプラズマ増強化学気相堆積技術において酸化することにより堆積させる、請求項30記載の方法。
- 該誘電体層を、トリメチルシランと酸素をプラズマ増強化学気相堆積技術において反応させることにより堆積させる、請求項31記載の方法。
- 該誘電体層を、約0.16W/cm2〜約0.48W/cm2の高周波RF電力密度を含むプラズマ条件下で堆積させる、請求項32記載の方法。
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US10/266,551 US7749563B2 (en) | 2002-10-07 | 2002-10-07 | Two-layer film for next generation damascene barrier application with good oxidation resistance |
PCT/US2003/031559 WO2004033752A2 (en) | 2002-10-07 | 2003-10-07 | Two-layer film for next generation damascene barrier application with good oxidation resistance |
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WO2004033752A3 (en) | 2004-12-09 |
US20040067308A1 (en) | 2004-04-08 |
KR20050062596A (ko) | 2005-06-23 |
KR20110134521A (ko) | 2011-12-14 |
WO2004033752A2 (en) | 2004-04-22 |
AU2003279839A8 (en) | 2004-05-04 |
JP2006502586A (ja) | 2006-01-19 |
US7749563B2 (en) | 2010-07-06 |
EP1558784A2 (en) | 2005-08-03 |
KR101122458B1 (ko) | 2012-02-29 |
KR101214995B1 (ko) | 2012-12-26 |
AU2003279839A1 (en) | 2004-05-04 |
CN1714168A (zh) | 2005-12-28 |
CN100510168C (zh) | 2009-07-08 |
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