JP4559004B2 - ジルコニアゾル及びその製造方法 - Google Patents
ジルコニアゾル及びその製造方法 Download PDFInfo
- Publication number
- JP4559004B2 JP4559004B2 JP2001533062A JP2001533062A JP4559004B2 JP 4559004 B2 JP4559004 B2 JP 4559004B2 JP 2001533062 A JP2001533062 A JP 2001533062A JP 2001533062 A JP2001533062 A JP 2001533062A JP 4559004 B2 JP4559004 B2 JP 4559004B2
- Authority
- JP
- Japan
- Prior art keywords
- zirconia
- sol
- acid
- polyether
- zro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title claims description 427
- 238000004519 manufacturing process Methods 0.000 title description 6
- 239000002245 particle Substances 0.000 claims description 114
- 239000002253 acid Substances 0.000 claims description 112
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 92
- 229920000570 polyether Polymers 0.000 claims description 92
- 150000003754 zirconium Chemical class 0.000 claims description 76
- 239000000203 mixture Substances 0.000 claims description 38
- 239000013078 crystal Substances 0.000 claims description 30
- 239000012071 phase Substances 0.000 claims description 28
- 239000011164 primary particle Substances 0.000 claims description 28
- 239000002131 composite material Substances 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 27
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 24
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims description 22
- 239000006185 dispersion Substances 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 11
- 229910052726 zirconium Inorganic materials 0.000 claims description 11
- 239000008346 aqueous phase Substances 0.000 claims description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 230000003301 hydrolyzing effect Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 59
- 238000010998 test method Methods 0.000 description 52
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 51
- DUFCMRCMPHIFTR-UHFFFAOYSA-N 5-(dimethylsulfamoyl)-2-methylfuran-3-carboxylic acid Chemical compound CN(C)S(=O)(=O)C1=CC(C(O)=O)=C(C)O1 DUFCMRCMPHIFTR-UHFFFAOYSA-N 0.000 description 42
- 239000011159 matrix material Substances 0.000 description 38
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 20
- 230000005540 biological transmission Effects 0.000 description 19
- 239000000463 material Substances 0.000 description 19
- 239000003607 modifier Substances 0.000 description 19
- 238000002296 dynamic light scattering Methods 0.000 description 16
- 238000006460 hydrolysis reaction Methods 0.000 description 16
- 239000012266 salt solution Substances 0.000 description 16
- 239000007787 solid Substances 0.000 description 16
- 230000005855 radiation Effects 0.000 description 15
- 229960000583 acetic acid Drugs 0.000 description 14
- 150000001735 carboxylic acids Chemical class 0.000 description 13
- 238000001704 evaporation Methods 0.000 description 13
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 12
- 239000008367 deionised water Substances 0.000 description 12
- 229910021641 deionized water Inorganic materials 0.000 description 12
- 239000011521 glass Substances 0.000 description 12
- 238000002390 rotary evaporation Methods 0.000 description 12
- 238000002441 X-ray diffraction Methods 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 11
- 239000011550 stock solution Substances 0.000 description 11
- 230000007062 hydrolysis Effects 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 238000000746 purification Methods 0.000 description 10
- 230000000007 visual effect Effects 0.000 description 10
- 238000000502 dialysis Methods 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000011541 reaction mixture Substances 0.000 description 9
- 239000007858 starting material Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 description 8
- 238000000333 X-ray scattering Methods 0.000 description 8
- 230000002776 aggregation Effects 0.000 description 8
- 238000004220 aggregation Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000010431 corundum Substances 0.000 description 8
- 229910052593 corundum Inorganic materials 0.000 description 8
- 230000006870 function Effects 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- 239000010935 stainless steel Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000004642 Polyimide Substances 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 230000035699 permeability Effects 0.000 description 7
- 229920001721 polyimide Polymers 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 5
- 239000005642 Oleic acid Substances 0.000 description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 5
- LGDAGYXJBDILKZ-UHFFFAOYSA-N [2-methyl-1,1-dioxo-3-(pyridin-2-ylcarbamoyl)-1$l^{6},2-benzothiazin-4-yl] 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=1C2=CC=CC=C2S(=O)(=O)N(C)C=1C(=O)NC1=CC=CC=N1 LGDAGYXJBDILKZ-UHFFFAOYSA-N 0.000 description 5
- 125000002843 carboxylic acid group Chemical group 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 4
- YTTFFPATQICAQN-UHFFFAOYSA-N 2-methoxypropan-1-ol Chemical compound COC(C)CO YTTFFPATQICAQN-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000006184 cosolvent Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000007970 homogeneous dispersion Substances 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 239000004570 mortar (masonry) Substances 0.000 description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- CLLLODNOQBVIMS-UHFFFAOYSA-N 2-(2-methoxyethoxy)acetic acid Chemical compound COCCOCC(O)=O CLLLODNOQBVIMS-UHFFFAOYSA-N 0.000 description 3
- YHBWXWLDOKIVCJ-UHFFFAOYSA-N 2-[2-(2-methoxyethoxy)ethoxy]acetic acid Chemical compound COCCOCCOCC(O)=O YHBWXWLDOKIVCJ-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000013480 data collection Methods 0.000 description 3
- 238000011026 diafiltration Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000000643 oven drying Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- -1 zirconium carboxylates Chemical class 0.000 description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 description 3
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical group [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000010977 jade Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000010421 standard material Substances 0.000 description 2
- 229940014800 succinic anhydride Drugs 0.000 description 2
- 238000002411 thermogravimetry Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- VNQXSTWCDUXYEZ-UHFFFAOYSA-N 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione Chemical compound C1CC2(C)C(=O)C(=O)C1C2(C)C VNQXSTWCDUXYEZ-UHFFFAOYSA-N 0.000 description 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- LBJBPGRQRGLKPL-UHFFFAOYSA-N 7-(4-chlorophenyl)-5-naphthalen-2-yl-6-sulfanylidene-2,3-dihydro-1h-pyrrolo[3,4-e][1,4]diazepin-8-one Chemical compound C1=CC(Cl)=CC=C1N1C(=S)C(C(=NCCN2)C=3C=C4C=CC=CC4=CC=3)=C2C1=O LBJBPGRQRGLKPL-UHFFFAOYSA-N 0.000 description 1
- 241000722947 Acanthocybium Species 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229910052580 B4C Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- UUEYEUDSRFNIQJ-UHFFFAOYSA-N CCOC(N)=O.CCOC(N)=O.CC(=C)C(O)=O.CC(=C)C(O)=O Chemical compound CCOC(N)=O.CCOC(N)=O.CC(=C)C(O)=O.CC(=C)C(O)=O UUEYEUDSRFNIQJ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- AMFGWXWBFGVCKG-UHFFFAOYSA-N Panavia opaque Chemical compound C1=CC(OCC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OCC(O)COC(=O)C(C)=C)C=C1 AMFGWXWBFGVCKG-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 159000000021 acetate salts Chemical class 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004164 analytical calibration Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 229930006711 bornane-2,3-dione Natural products 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000002447 crystallographic data Methods 0.000 description 1
- 239000005548 dental material Substances 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- WAIVDDQSCZRZRZ-UHFFFAOYSA-K diphenyliodanium phosphate Chemical compound P(=O)([O-])([O-])[O-].C1(=CC=CC=C1)[I+]C1=CC=CC=C1.C1(=CC=CC=C1)[I+]C1=CC=CC=C1.C1(=CC=CC=C1)[I+]C1=CC=CC=C1 WAIVDDQSCZRZRZ-UHFFFAOYSA-K 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000011363 dried mixture Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 238000012682 free radical photopolymerization Methods 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000004442 gravimetric analysis Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- CPBQJMYROZQQJC-UHFFFAOYSA-N helium neon Chemical compound [He].[Ne] CPBQJMYROZQQJC-UHFFFAOYSA-N 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- UJVRJBAUJYZFIX-UHFFFAOYSA-N nitric acid;oxozirconium Chemical compound [Zr]=O.O[N+]([O-])=O.O[N+]([O-])=O UJVRJBAUJYZFIX-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 description 1
- FZUGPQWGEGAKET-UHFFFAOYSA-N parbenate Chemical compound CCOC(=O)C1=CC=C(N(C)C)C=C1 FZUGPQWGEGAKET-UHFFFAOYSA-N 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 102220247977 rs758942502 Human genes 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
- XJUNLJFOHNHSAR-UHFFFAOYSA-J zirconium(4+);dicarbonate Chemical compound [Zr+4].[O-]C([O-])=O.[O-]C([O-])=O XJUNLJFOHNHSAR-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0004—Preparation of sols
- B01J13/0008—Sols of inorganic materials in water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/428,374 US6376590B2 (en) | 1999-10-28 | 1999-10-28 | Zirconia sol, process of making and composite material |
| US09/428,374 | 1999-10-28 | ||
| PCT/US2000/008796 WO2001030702A1 (en) | 1999-10-28 | 2000-04-03 | Zirconia sol and process of making same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003512287A JP2003512287A (ja) | 2003-04-02 |
| JP2003512287A5 JP2003512287A5 (https=) | 2007-04-12 |
| JP4559004B2 true JP4559004B2 (ja) | 2010-10-06 |
Family
ID=23698626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001533062A Expired - Fee Related JP4559004B2 (ja) | 1999-10-28 | 2000-04-03 | ジルコニアゾル及びその製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6376590B2 (https=) |
| EP (1) | EP1232118B1 (https=) |
| JP (1) | JP4559004B2 (https=) |
| AU (1) | AU4065200A (https=) |
| CA (1) | CA2388876C (https=) |
| DE (1) | DE60023023T2 (https=) |
| WO (1) | WO2001030702A1 (https=) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9202688B2 (en) | 2010-04-23 | 2015-12-01 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US9359689B2 (en) | 2011-10-26 | 2016-06-07 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US10753012B2 (en) | 2010-10-27 | 2020-08-25 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| CN113165900A (zh) * | 2018-11-30 | 2021-07-23 | 马蒂姆有限公司 | 一种在氨基酸存在下制备二氧化锆纳米颗粒的方法 |
| CN114656818A (zh) * | 2020-12-03 | 2022-06-24 | 凯斯科技股份有限公司 | 金属氧化物分散液 |
| CN115124074A (zh) * | 2022-07-26 | 2022-09-30 | 宣城市晶纳环保科技有限公司 | 一种高分散复合纳米二氧化锆的制备方法 |
Families Citing this family (211)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090000007A1 (en) * | 1998-12-07 | 2009-01-01 | Meridian Research And Development, Inc. | Nonwoven radiopaque material for medical garments and method for making same |
| US7476889B2 (en) * | 1998-12-07 | 2009-01-13 | Meridian Research And Development | Radiation detectable and protective articles |
| US6194481B1 (en) * | 1999-05-19 | 2001-02-27 | Board Of Regents Of The University Of Texas System | Mechanically strong and transparent or translucent composites made using zirconium oxide nanoparticles |
| AU3505400A (en) * | 1999-10-28 | 2001-05-08 | 3M Innovative Properties Company | Dental materials with nano-sized silica particles |
| WO2002014433A1 (en) * | 2000-08-11 | 2002-02-21 | Sun Medical Co., Ltd. | Polymerizable composition, cured object obtained therefrom, and composite material |
| US6982073B2 (en) * | 2001-11-02 | 2006-01-03 | Altair Nanomaterials Inc. | Process for making nano-sized stabilized zirconia |
| US7393882B2 (en) * | 2002-01-31 | 2008-07-01 | 3M Innovative Properties Company | Dental pastes, dental articles, and methods |
| DE10219879A1 (de) * | 2002-05-03 | 2003-11-20 | Basf Ag | Katalysatorträger und Verfahren zu seiner Herstellung |
| US7091259B2 (en) * | 2002-07-03 | 2006-08-15 | 3M Innovative Properties Company | Dental fillers, pastes, and compositions prepared therefrom |
| WO2004020362A1 (de) * | 2002-08-30 | 2004-03-11 | Itn Nanovation Gmbh | Keramische hohlfasern hergestellt aus nanoskaligen pulverteilchen |
| US7288324B1 (en) | 2002-09-05 | 2007-10-30 | University Of Central Florida Research Foundation, Inc. | Synthesis of tetragonal phase stabilized nano and submicron sized nanoparticles |
| US7297731B2 (en) * | 2003-03-11 | 2007-11-20 | 3M Innovative Properties Company | Coating dispersions for optical fibers |
| TWI252215B (en) * | 2003-03-27 | 2006-04-01 | Univ Nat Central | Zirconia sol and method of preparing the same |
| US7282272B2 (en) * | 2003-09-12 | 2007-10-16 | 3M Innovative Properties Company | Polymerizable compositions comprising nanoparticles |
| US7289202B2 (en) | 2004-09-10 | 2007-10-30 | 3M Innovative Properties Company | Methods for testing durable optical elements |
| US7074463B2 (en) * | 2003-09-12 | 2006-07-11 | 3M Innovative Properties Company | Durable optical element |
| DE10359659A1 (de) * | 2003-12-18 | 2005-07-21 | Institut für Neue Materialien Gemeinnützige GmbH | Verwendung von nanoskaligen ZrO2-Teilchen |
| US7803347B2 (en) * | 2005-07-01 | 2010-09-28 | Tohoku Techno Arch Co., Ltd. | Organically modified fine particles |
| DE102004008275A1 (de) * | 2004-02-18 | 2005-09-15 | Heraeus Kulzer Gmbh | Dispersionen nanoskaliger, nicht-agglomerierte Metalloxid-Teilchen zum Einsatz in Dentalmaterialien |
| DE102004008772A1 (de) * | 2004-02-23 | 2005-09-08 | Institut für Neue Materialien Gemeinnützige GmbH | Abriebbeständige und alkalibeständige Beschichtungen oder Formkörper mit Niedrigenergieoberfläche |
| DE102004009287A1 (de) * | 2004-02-26 | 2005-09-15 | Institut Für Neue Materialien Gem. Gmbh | Amphiphile Nanopartikel |
| DE102004017124B4 (de) * | 2004-04-07 | 2008-07-10 | Ivoclar Vivadent Ag | Härtbare Dentalmaterialien mit einer einstellbaren Transluzenz und hohen Opaleszenz |
| US7090721B2 (en) * | 2004-05-17 | 2006-08-15 | 3M Innovative Properties Company | Use of nanoparticles to adjust refractive index of dental compositions |
| US7649029B2 (en) * | 2004-05-17 | 2010-01-19 | 3M Innovative Properties Company | Dental compositions containing nanozirconia fillers |
| US7090722B2 (en) * | 2004-05-17 | 2006-08-15 | 3M Innovative Properties Company | Acid-reactive dental fillers, compositions, and methods |
| US7156911B2 (en) | 2004-05-17 | 2007-01-02 | 3M Innovative Properties Company | Dental compositions containing nanofillers and related methods |
| KR101245946B1 (ko) * | 2004-06-17 | 2013-03-21 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 광학 필름, 어셈블리 및 디스플레이 장치 |
| US20060009536A1 (en) * | 2004-07-12 | 2006-01-12 | Guang-Way Jang | Functionalized sol-gel material, sol-gel film derived therefrom, and method for preparing the same |
| AU2005271781A1 (en) * | 2004-07-13 | 2006-02-16 | Altairnano, Inc. | Ceramic structures for prevention of drug diversion |
| DE102004048230A1 (de) * | 2004-10-04 | 2006-04-06 | Institut für Neue Materialien Gemeinnützige GmbH | Verfahren zur Herstellung von Nanopartikeln mit maßgeschneiderter Oberflächenchemie und entsprechenden Kolloiden |
| US7491441B2 (en) | 2004-12-30 | 2009-02-17 | 3M Innovative Properties Company | High refractive index, durable hard coats |
| US7241437B2 (en) * | 2004-12-30 | 2007-07-10 | 3M Innovative Properties Company | Zirconia particles |
| US7297810B2 (en) * | 2004-12-30 | 2007-11-20 | 3M Innovative Properties Company | High refractive index monomers for optical applications |
| US7264872B2 (en) * | 2004-12-30 | 2007-09-04 | 3M Innovative Properties Company | Durable high index nanocomposites for AR coatings |
| US7326448B2 (en) * | 2005-02-17 | 2008-02-05 | 3M Innovative Properties Company | Polymerizable oligomeric urethane compositions comprising nanoparticles |
| WO2006088930A2 (en) * | 2005-02-17 | 2006-08-24 | 3M Innovative Properties Company | Brightness enhancement film comprising polymerized organic phase having low glass transition temperature |
| US20060204676A1 (en) * | 2005-03-11 | 2006-09-14 | Jones Clinton L | Polymerizable composition comprising low molecular weight organic component |
| TW200704680A (en) * | 2005-03-11 | 2007-02-01 | 3M Innovative Properties Co | Polymerizable compositions comprising nanoparticles |
| US20060204745A1 (en) * | 2005-03-14 | 2006-09-14 | Jones Clint L | Light management films with zirconia particles |
| JP2008533525A (ja) * | 2005-03-11 | 2008-08-21 | スリーエム イノベイティブ プロパティズ カンパニー | ジルコニア粒子を有する調光フィルム |
| WO2006115043A1 (ja) * | 2005-04-18 | 2006-11-02 | Nissan Chemical Industries, Ltd. | 酸性ジルコニアゾル及びその製造方法 |
| FR2885308B1 (fr) * | 2005-05-04 | 2007-07-06 | Eastman Kodak Co | Procede pour maintenir l'etat de dispersion d'une solution colloidale de particules d'oxyde metallique |
| US7400445B2 (en) * | 2005-05-31 | 2008-07-15 | 3M Innovative Properties Company | Optical filters for accelerated weathering devices |
| GB0512666D0 (en) * | 2005-06-22 | 2005-07-27 | Univ Loughborough | Method for concentrating nanosuspensions |
| JP4961829B2 (ja) * | 2005-08-09 | 2012-06-27 | ソニー株式会社 | ナノ粒子−樹脂複合材料の製造方法 |
| EP1928814A2 (en) * | 2005-08-23 | 2008-06-11 | Altairnano, Inc | HIGHLY PHOTOCATALYTIC PHOSPHORUS-DOPED ANATASE-TiO2 COMPOSITION AND RELATED MANUFACTURING METHODS |
| JP4963820B2 (ja) * | 2005-09-02 | 2012-06-27 | 第一稀元素化学工業株式会社 | Ｚｒ−Ｏ系粒子を分散質とするゾルの製造方法 |
| WO2007033934A2 (de) * | 2005-09-20 | 2007-03-29 | Basf Se | Verfahren zur ermittlung der tortuosität, katalysatorträger, katalysator und verfahren zur dehydrierung von kohlenwasserstoffen |
| JP2007103708A (ja) * | 2005-10-05 | 2007-04-19 | Sumitomo Osaka Cement Co Ltd | 発光素子封止用組成物及び発光素子並びに光半導体装置 |
| JP5011695B2 (ja) * | 2005-10-05 | 2012-08-29 | 住友大阪セメント株式会社 | ジルコニア透明分散液及び透明複合体並びに透明複合体の製造方法 |
| EP1950239B1 (en) * | 2005-10-28 | 2017-01-04 | Sumitomo Osaka Cement Co., Ltd. | Transparent inorganic-oxide dispersion, resin composition containing inorganic oxide particles, composition for encapsulating luminescent element, luminescent element, hard coat, optical functional film, optical part, and process for producing resin composition containing inorganic oxide particles |
| JP5540458B2 (ja) * | 2006-02-17 | 2014-07-02 | 住友大阪セメント株式会社 | 無機酸化物透明分散液と樹脂組成物、透明複合体、発光素子封止用組成物及び発光素子並びに透明複合体の製造方法 |
| DE112006002940T5 (de) | 2005-11-05 | 2008-12-11 | 3M Innovative Properties Co., St. Paul | Optische Filme, umfassend einen hohen Brechungsindex aufweisende und antireflektierende Beschichtungen |
| TWI417324B (zh) * | 2005-11-15 | 2013-12-01 | 3M Innovative Properties Co | 增亮膜及無機奈米粒子之表面處理方法 |
| US20070190314A1 (en) * | 2006-01-13 | 2007-08-16 | Fujifilm Corporation | Transparent article and method for producing it, and lens substrate |
| JP2007213022A (ja) * | 2006-01-13 | 2007-08-23 | Fujifilm Corp | 透明成形体とその製造方法、およびレンズ基材 |
| US20080038482A1 (en) * | 2006-03-02 | 2008-02-14 | Fred Ratel | Method for Low Temperature Production of Nano-Structured Iron Oxide Coatings |
| WO2007103820A1 (en) * | 2006-03-02 | 2007-09-13 | Altairnano, Inc. | Nanostructured indium-doped iron oxide |
| WO2007103824A1 (en) * | 2006-03-02 | 2007-09-13 | Altairnano, Inc. | Nanostructured metal oxides |
| JP2007314773A (ja) * | 2006-04-28 | 2007-12-06 | Mitsubishi Chemicals Corp | 高屈折率粒子含有樹脂組成物 |
| US20100119697A1 (en) * | 2006-05-10 | 2010-05-13 | 3M Innovative Properties Company | Compositions and coatings containing fluorescent, inorganic nanoparticles |
| JP4961828B2 (ja) * | 2006-05-12 | 2012-06-27 | ソニー株式会社 | ナノ粒子−樹脂複合材料の製造方法 |
| US20070286994A1 (en) | 2006-06-13 | 2007-12-13 | Walker Christopher B | Durable antireflective film |
| US7897526B1 (en) | 2006-07-13 | 2011-03-01 | NEI, Corp | Silicone nanocomposite coatings for fabrics |
| WO2008010533A1 (fr) * | 2006-07-18 | 2008-01-24 | Nippon Shokubai Co., Ltd. | Nanoparticule d'oxyde métallique et son procédé de production |
| JP5030694B2 (ja) * | 2006-07-18 | 2012-09-19 | 株式会社日本触媒 | 酸化ジルコニウムナノ粒子 |
| JP5177970B2 (ja) * | 2006-07-18 | 2013-04-10 | 株式会社日本触媒 | 金属酸化物ナノ粒子の製造方法、金属ナノ粒子、処理金属ナノ粒子およびその用途 |
| JP5019826B2 (ja) * | 2006-07-28 | 2012-09-05 | 第一稀元素化学工業株式会社 | ジルコニアゾル及びその製造方法 |
| JP4952906B2 (ja) * | 2006-11-15 | 2012-06-13 | ソニーケミカル＆インフォメーションデバイス株式会社 | 封止樹脂組成物及び発光素子 |
| WO2008064070A1 (en) * | 2006-11-17 | 2008-05-29 | 3M Innovative Properties Company | Optical bonding composition for led light source |
| CN101536201A (zh) * | 2006-11-17 | 2009-09-16 | 3M创新有限公司 | 具有光学提取器的平面化发光二极管 |
| JP4561732B2 (ja) * | 2006-11-20 | 2010-10-13 | トヨタ自動車株式会社 | 移動体位置測位装置 |
| JP2010510685A (ja) * | 2006-11-20 | 2010-04-02 | スリーエム イノベイティブ プロパティズ カンパニー | Ｌｅｄ光源用の光学接着組成物 |
| US20080124555A1 (en) | 2006-11-29 | 2008-05-29 | 3M Innovative Properties Company | Polymerizable composition comprising perfluoropolyether urethane having ethylene oxide repeat units |
| JP4817254B2 (ja) * | 2006-12-01 | 2011-11-16 | 大日本塗料株式会社 | 酸化ジルコニウム粒子分散液、酸化ジルコニウム粒子含有光硬化性組成物及び硬化膜 |
| WO2008079800A1 (en) * | 2006-12-21 | 2008-07-03 | 3M Innovative Properties Company | Process for producing nanoparticles |
| JP4315195B2 (ja) * | 2006-12-21 | 2009-08-19 | ソニー株式会社 | 硬化性樹脂材料−微粒子複合材料及びその製造方法、光学材料、並びに発光装置 |
| JP5512280B2 (ja) * | 2006-12-28 | 2014-06-04 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科充填剤及び方法 |
| EP2104654A2 (en) | 2006-12-29 | 2009-09-30 | 3M Innovative Properties Company | Zirconia body and methods |
| US7709092B2 (en) * | 2007-01-19 | 2010-05-04 | 3M Innovative Properties Company | Solar control multilayer film |
| JP2008201634A (ja) * | 2007-02-21 | 2008-09-04 | Fujifilm Corp | ジルコニア微粒子分散液、該分散剤から製造される有機無機複合材料および光学部品 |
| US7939578B2 (en) * | 2007-02-23 | 2011-05-10 | 3M Innovative Properties Company | Polymeric fibers and methods of making |
| WO2008121465A1 (en) * | 2007-02-27 | 2008-10-09 | 3M Innovative Properties Company | Brightness enhancing film comprising nanocomposite structure having improved crack resistance |
| ATE510800T1 (de) * | 2007-04-04 | 2011-06-15 | Essilor Int | Verfahren zur herstellung einer kolloidalen zirkoniumlösung |
| US20080254258A1 (en) * | 2007-04-12 | 2008-10-16 | Altairnano, Inc. | Teflon® replacements and related production methods |
| US8513322B2 (en) * | 2007-05-31 | 2013-08-20 | 3M Innovative Properties Company | Polymeric beads and methods of making polymeric beads |
| DE102007036998A1 (de) | 2007-08-06 | 2009-02-19 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung von amorphen metallorganischen Makromolekülen, mit diesem Verfahren erhaltenes Material und seine Verwendung |
| JP2009137774A (ja) * | 2007-12-03 | 2009-06-25 | Sumitomo Osaka Cement Co Ltd | ジルコニア粒子とその製造方法及びジルコニア透明分散液、並びに透明複合体及びその製造方法 |
| US20100266794A1 (en) | 2007-12-12 | 2010-10-21 | Wright Robin E | Hydrophilic gel materials and methods of making |
| BRPI0820704A2 (pt) * | 2007-12-12 | 2015-06-16 | 3M Innovative Proferties Company | Métodos de fabricação de materiais poliméricos moldados |
| US8834832B2 (en) * | 2007-12-21 | 2014-09-16 | 3M Innovative Properties Company | Process for producing nanoparticles |
| EP2620413B1 (en) | 2007-12-28 | 2020-07-01 | 3M Innovative Properties Company | Continuous hydrothermal reactor system comprising a fluorinated polymer tubular reactor |
| JP5445140B2 (ja) * | 2008-01-09 | 2014-03-19 | 旭硝子株式会社 | 表面修飾ジルコニア粒子、その製造方法及び樹脂組成物 |
| FR2927005B1 (fr) * | 2008-02-05 | 2011-12-23 | Commissariat Energie Atomique | Materiau hybride organique-inorganique, couche mince optique de ce materiau, materiau optique les comprenant, et leur procede de fabrication |
| JP5037393B2 (ja) * | 2008-03-12 | 2012-09-26 | 富士フイルム株式会社 | 金属酸化物微粒子分散液及び成形体 |
| US7981986B2 (en) * | 2008-04-29 | 2011-07-19 | 3M Innovative Properties Company | Optical films comprising fluorenol (meth)acrylate monomer |
| US20090275720A1 (en) * | 2008-04-30 | 2009-11-05 | 3M Innovative Properties Company | Ortho-benzylphenol mono(meth)acrylate monomers suitable for microstructured optical films |
| JP5701474B2 (ja) * | 2008-06-13 | 2015-04-15 | 富士フイルム株式会社 | 無機微粒子分散液、有機無機複合組成物、成形体および光学部品 |
| US8343622B2 (en) * | 2008-07-01 | 2013-01-01 | 3M Innovative Properties Company | Flexible high refractive index hardcoat |
| US8611010B2 (en) * | 2008-09-30 | 2013-12-17 | 3M Innovative Properties Company | Substrate comprising unmatched refractive index primer at optically significant thickness |
| CN102224106A (zh) | 2008-10-15 | 2011-10-19 | 3M创新有限公司 | 具有氧化锆和二氧化硅纳米粒子的填料和复合材料 |
| JP5397829B2 (ja) * | 2008-12-04 | 2014-01-22 | 堺化学工業株式会社 | 酸化ジルコニウム分散液の製造方法 |
| JP5407324B2 (ja) * | 2008-12-24 | 2014-02-05 | 堺化学工業株式会社 | 酸化ジルコニウム分散液の製造方法 |
| WO2010074862A1 (en) | 2008-12-15 | 2010-07-01 | 3M Innovative Properties Company | High refractive index inorganic oxide nanoparticles comprising surface treatment, polymerizable resin, and articles |
| WO2010123528A2 (en) | 2008-12-30 | 2010-10-28 | 3M Innovative Properties Company | Nanostructured articles and methods of making nanostructured articles |
| KR20110110240A (ko) | 2008-12-30 | 2011-10-06 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 반사방지 용품 및 이의 제조 방법 |
| US8829079B2 (en) | 2009-01-22 | 2014-09-09 | 3M Innovative Properties Company | Surface-modified zirconia nanoparticles |
| US9291752B2 (en) | 2013-08-19 | 2016-03-22 | 3M Innovative Properties Company | Retroreflecting optical construction |
| WO2010121054A1 (en) | 2009-04-15 | 2010-10-21 | 3M Innovative Properties Company | Retroreflective sheeting including a low index coating |
| TWI605276B (zh) | 2009-04-15 | 2017-11-11 | ３Ｍ新設資產公司 | 光學結構及包含該光學結構之顯示系統 |
| WO2010121056A1 (en) | 2009-04-15 | 2010-10-21 | 3M Innovative Properties Company | Retroreflective articles including printed areas |
| CN102458819B (zh) | 2009-04-15 | 2014-09-03 | 3M创新有限公司 | 回射光学构造 |
| WO2010120845A2 (en) | 2009-04-15 | 2010-10-21 | 3M Innovative Properties Company | Backlight and display system incorporating same |
| JP5727460B2 (ja) | 2009-04-15 | 2015-06-03 | スリーエム イノベイティブ プロパティズ カンパニー | 光結合を防止するための光学フィルム |
| RU2557961C2 (ru) | 2009-12-22 | 2015-07-27 | 3М Инновейтив Пропертиз Компани | Стоматологические композиции, заготовки для стоматологического протезирования и способы |
| WO2011082031A1 (en) * | 2009-12-29 | 2011-07-07 | 3M Innovative Properties Company | Zirconia-based particles doped with a lanthanide element |
| US8598058B2 (en) | 2009-12-29 | 2013-12-03 | 3M Innovative Properties Company | Zirconia-based material doped with yttrium and lanthanum |
| EP2558290B1 (en) | 2010-04-15 | 2019-01-23 | 3M Innovative Properties Company | Retroreflective articles including optically active areas and optically inactive areas |
| US9791604B2 (en) | 2010-04-15 | 2017-10-17 | 3M Innovative Properties Company | Retroreflective articles including optically active areas and optically inactive areas |
| MX341955B (es) | 2010-04-15 | 2016-09-08 | 3M Innovative Properties Co | Articulos retrorreflectantes que incluyen areas opticamente activas y areas opticamente inactivas. |
| US8298329B2 (en) | 2010-04-29 | 2012-10-30 | James R. Glidewell Dental Ceramics, Inc. | Nano-crystalline dental ceramics |
| CN102884453B (zh) | 2010-05-07 | 2015-04-01 | 3M创新有限公司 | 包括微结构化表面的抗反射膜 |
| KR101639082B1 (ko) * | 2010-10-20 | 2016-07-13 | 코오롱인더스트리 주식회사 | 광중합성 조성물 및 이로부터 형성된 수지 경화층을 포함하는 광학시트 |
| US9296904B2 (en) | 2010-12-20 | 2016-03-29 | 3M Innovative Properties Company | Coating compositions comprising non-ionic surfactant exhibiting reduced fingerprint visibility |
| US8742022B2 (en) | 2010-12-20 | 2014-06-03 | 3M Innovative Properties Company | Coating compositions comprising non-ionic surfactant exhibiting reduced fingerprint visibility |
| JP2014509291A (ja) * | 2010-12-22 | 2014-04-17 | スリーエム イノベイティブ プロパティズ カンパニー | 表面修飾ジルコニアナノ粒子 |
| EP2670802B1 (en) | 2011-02-04 | 2018-04-25 | 3M Innovative Properties Company | Amorphous perfluoropolymers comprising zirconium oxide nanoparticles |
| CN103518148B (zh) | 2011-03-09 | 2016-01-20 | 3M创新有限公司 | 包含大粒度热解法二氧化硅的抗反射膜 |
| BR112013023128A2 (pt) | 2011-03-14 | 2019-09-24 | 3M Innovative Properties Co | artigos nanoestruturados |
| US20140004304A1 (en) | 2011-03-14 | 2014-01-02 | 3M Innovative Properties Company | Multilayer nanostructured articles |
| EP2710519B1 (en) | 2011-05-20 | 2019-07-17 | Gemalto SA | Laser-personalized security articles |
| US9289962B2 (en) | 2011-05-20 | 2016-03-22 | 3M Innovative Properties Company | Laser-personalizable security articles |
| WO2013028397A2 (en) | 2011-08-23 | 2013-02-28 | 3M Innovative Properties Company | Dental compositions comprising addition-fragmentation agents |
| US8980969B2 (en) | 2011-08-23 | 2015-03-17 | 3M Innovative Properties Company | Addition-fragmentation agents |
| EP2610318A1 (en) | 2011-12-30 | 2013-07-03 | Essilor International (Compagnie Générale D'Optique) | Coating composition for an optical article, comprising a colloidal suspension of zirconia particles |
| CN104662689B (zh) | 2012-02-28 | 2017-06-27 | 3M创新有限公司 | 适于光学耦合层的包含表面改性高折射率纳米粒子的组合物 |
| US11133118B2 (en) | 2012-05-22 | 2021-09-28 | University Of Massachusetts | Patterned nanoparticle structures |
| CN104755562B (zh) | 2012-06-19 | 2017-05-17 | 3M创新有限公司 | 包含低表面能基团和羟基基团的添加剂以及涂料组合物 |
| JP6218820B2 (ja) | 2012-06-19 | 2017-10-25 | スリーエム イノベイティブ プロパティズ カンパニー | 低い指紋視認性を呈する重合性非イオン性界面活性剤を含むコーティング組成物 |
| US20150132583A1 (en) | 2012-07-13 | 2015-05-14 | 3M Innovative Properties Company | Hardcoats comprising alkoxylated multi (meth)acrylate monomers |
| US9410030B2 (en) | 2012-11-12 | 2016-08-09 | 3M Innovative Properties Company | Addition-fragmentation agents |
| JP6351608B2 (ja) | 2012-11-12 | 2018-07-04 | スリーエム イノベイティブ プロパティズ カンパニー | 付加開裂剤を含む歯科用組成物 |
| US9477354B2 (en) | 2012-11-16 | 2016-10-25 | 3M Innovative Properties Company | Conductive trace hiding materials, articles, and methods |
| CN104871035B (zh) | 2012-12-20 | 2018-01-30 | 3M创新有限公司 | 制备包括层层自组装层的多层光学膜的方法以及制品 |
| JP2013075824A (ja) * | 2012-12-25 | 2013-04-25 | Sumitomo Osaka Cement Co Ltd | 透明複合体及びその製造方法 |
| US9802174B2 (en) | 2012-12-26 | 2017-10-31 | Essilor International (Compagnie Generale D'optique) | Method for producing zirconia colloids |
| US20140242343A1 (en) | 2013-02-27 | 2014-08-28 | 3M Innovative Properties Company | Lamination transfer films for forming embedded nanostructures |
| CN105229090A (zh) | 2013-05-31 | 2016-01-06 | 3M创新有限公司 | 逐层自组装包含光吸收或光稳定化合物的高分子电解质的方法和制品 |
| US10004668B2 (en) | 2013-06-27 | 2018-06-26 | Ivoclar Vivadent, Inc. | Nanocrystalline zirconia and methods of processing thereof |
| US10185058B2 (en) | 2013-07-01 | 2019-01-22 | 3M Innovative Properties Company | Protection film suitable for illuminated display devices |
| CN105612438B (zh) | 2013-10-02 | 2018-12-14 | 3M创新有限公司 | 包括第一微结构化层和涂层的微结构化漫射体、光学叠堆以及方法 |
| KR102280969B1 (ko) | 2013-10-02 | 2021-07-26 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 질소-함유 중합체를 갖는 폴리아크릴레이트 프라이머를 포함하는 물품 및 방법 |
| JP6453864B2 (ja) | 2013-10-02 | 2019-01-16 | スリーエム イノベイティブ プロパティズ カンパニー | ポリアクリレート感圧性プライマーと、ポリアクリレート成分を含む接着剤と、を含む物品 |
| CN105705112B (zh) | 2013-10-04 | 2018-02-27 | 3M创新有限公司 | 牙科研磨坯料、牙科修复体以及形成牙科研磨坯料的方法 |
| WO2015095317A1 (en) | 2013-12-19 | 2015-06-25 | 3M Innovative Properties Company | Articles comprising self-assembled layers comprising nanoparticles with a phosphorous surface treatment |
| JP2017507803A (ja) | 2013-12-19 | 2017-03-23 | スリーエム イノベイティブ プロパティズ カンパニー | 多層複合材料物品 |
| WO2015108834A1 (en) | 2014-01-15 | 2015-07-23 | 3M Innovative Properties Company | Hardcoats comprising alkoxylated multi(meth)acrylate monomers and surface treated nanoparticles |
| US10220600B2 (en) | 2014-01-20 | 2019-03-05 | 3M Innovative Properties Company | Lamination transfer films for forming reentrant structures |
| US20150202834A1 (en) | 2014-01-20 | 2015-07-23 | 3M Innovative Properties Company | Lamination transfer films for forming antireflective structures |
| US9246134B2 (en) | 2014-01-20 | 2016-01-26 | 3M Innovative Properties Company | Lamination transfer films for forming articles with engineered voids |
| KR102456918B1 (ko) | 2014-01-22 | 2022-10-19 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 글레이징을 위한 미세광학체 |
| JP6757314B2 (ja) | 2014-05-09 | 2020-09-16 | スリーエム イノベイティブ プロパティズ カンパニー | ハードコートを有する物品及び該物品の製造方法 |
| TWI543938B (zh) | 2014-05-13 | 2016-08-01 | 國立中央大學 | 金屬氧化物奈米顆粒材料 |
| US11247501B2 (en) | 2014-08-27 | 2022-02-15 | 3M Innovative Properties Company | Layer-by-layer assembled multilayer lamination transfer films |
| WO2016033211A2 (en) | 2014-08-27 | 2016-03-03 | 3M Innovative Properties Company | Electrical multilayer lamination transfer films |
| US9586385B2 (en) | 2014-08-27 | 2017-03-07 | 3M Innovative Properties Company | Inorganic multilayer lamination transfer films |
| WO2016032795A1 (en) | 2014-08-29 | 2016-03-03 | 3M Innovative Properties Company | Inductively curable composition |
| WO2016039820A1 (en) | 2014-09-10 | 2016-03-17 | 3M Innovative Properties Company | Exposed lens retroreflective articles comprising a self-assembled dielectric mirror |
| US20170307786A1 (en) | 2014-12-15 | 2017-10-26 | 3M Innovative Properties Company | Article with hardcoat and method of making the same |
| JP6659716B2 (ja) | 2015-03-05 | 2020-03-04 | スリーエム イノベイティブ プロパティズ カンパニー | セラミック繊維を有する複合材料 |
| EP3277741A4 (en) | 2015-03-30 | 2018-11-14 | Pixelligent Technologies, LLC | High refractive index solvent free silicone nanocomposites |
| CN107896491B (zh) | 2015-06-25 | 2020-12-29 | 3M创新有限公司 | 制造金属粘结磨料制品的方法和金属粘结磨料制品 |
| GB201518996D0 (en) * | 2015-10-27 | 2015-12-09 | Magnesium Elektron Ltd | Zirconia-based compositions for use as three-way catalysts |
| WO2017142744A1 (en) | 2016-02-18 | 2017-08-24 | 3M Innovative Properties Company | 3-d printing surface |
| JP6851740B2 (ja) * | 2016-03-25 | 2021-03-31 | 株式会社日本触媒 | 酸化ジルコニウムナノ粒子 |
| US11208562B2 (en) * | 2016-03-25 | 2021-12-28 | Nippon Shokubai Co., Ltd. | Zirconium oxide nanoparticles |
| US12344720B2 (en) | 2016-06-09 | 2025-07-01 | 3M Innovative Properties Company | Polyurethane acrylate protective display film |
| CN109415577A (zh) | 2016-06-27 | 2019-03-01 | 3M创新有限公司 | 包含用α-羟基酸或盐官能化的纳米粒子的组合物、制品和方法 |
| CN109414915B (zh) | 2016-07-01 | 2021-10-22 | 3M创新有限公司 | 低Tg聚氨酯保护显示膜 |
| US11285702B2 (en) | 2016-07-22 | 2022-03-29 | 3M Innovative Properties Company | Siloxane-based adhesive layers as ceramic precursors |
| CN109476964B (zh) | 2016-07-22 | 2022-04-26 | 3M创新有限公司 | 作为陶瓷前体的聚合物粘合剂层 |
| US9822039B1 (en) * | 2016-08-18 | 2017-11-21 | Ivoclar Vivadent Ag | Metal oxide ceramic nanomaterials and methods of making and using same |
| EP3515703A1 (en) | 2016-09-21 | 2019-07-31 | 3M Innovative Properties Company | Protective display film with glass |
| KR102427116B1 (ko) | 2016-10-25 | 2022-08-01 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 배향된 연마 입자를 포함하는 접합된 연마 용품, 및 그의 제조 방법 |
| US10941313B2 (en) | 2016-11-21 | 2021-03-09 | 3M Innovative Properties Company | Flexible hardcoat comprising urethane oligomer hydrogen bonded to an acrylic polymer |
| TW201832930A (zh) | 2016-12-01 | 2018-09-16 | 美商3M新設資產公司 | 雙重曲形保護顯示膜 |
| TW201830102A (zh) | 2016-12-14 | 2018-08-16 | 美商3M新設資產公司 | 分段保護顯示膜 |
| KR102458318B1 (ko) | 2016-12-23 | 2022-10-24 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 중합체 접합제 연마 물품 및 그의 제조 방법 |
| WO2018217519A1 (en) | 2017-05-25 | 2018-11-29 | 3M Innovative Properties Company | Cube corner retroreflective articles with tailored retroreflectivity and methods of making |
| KR102731347B1 (ko) | 2017-12-08 | 2024-11-15 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 가요성 하드코트 |
| EP3743472A1 (en) | 2018-01-24 | 2020-12-02 | 3M Innovative Properties Company | Flexible hardcoat comprising urethane oligomer hydrogen bonded to an acrylic polymer suitable for stretchable films |
| WO2020035802A1 (en) | 2018-08-14 | 2020-02-20 | 3M Innovative Properties Company | Flexible hardcoat disposed between organic base member and siliceous layer and cleanable articles |
| CN112673035B (zh) | 2018-09-14 | 2024-04-19 | 舒万诺知识产权公司 | 包含陶瓷纤维和纳米团簇的复合材料、牙科产品、套件盒及其制备和使用方法 |
| US20230220239A1 (en) | 2019-03-18 | 2023-07-13 | Basf Se | Uv curable compositions for dirt pick-up resistance |
| KR102914528B1 (ko) | 2019-05-09 | 2026-01-16 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 가요성 하드코트 |
| WO2020225703A1 (en) | 2019-05-09 | 2020-11-12 | 3M Innovative Properties Company | Flexible hardcoat |
| CN114072468A (zh) | 2019-05-09 | 2022-02-18 | 3M创新有限公司 | 柔性硬质涂层 |
| US12339471B2 (en) | 2019-05-31 | 2025-06-24 | 3M Innovative Properties Company | Composite cooling film and article including the same |
| CN113874208B (zh) | 2019-05-31 | 2023-10-10 | 3M创新有限公司 | 复合冷却膜和包括该复合冷却膜的制品 |
| US20220266421A1 (en) | 2019-07-15 | 2022-08-25 | 3M Innovative Properties Company | Abrasive articles having internal coolant features and methods of manufacturing the same |
| BR112022017042A2 (pt) * | 2020-02-26 | 2022-11-08 | Carefusion Corp | Sistemas e métodos para esterilizar composições de iodóforo |
| CN116745069A (zh) | 2020-10-28 | 2023-09-12 | 3M创新有限公司 | 用于向主动磨削区域提供冷却剂的系统和方法 |
| US12404419B2 (en) | 2020-11-05 | 2025-09-02 | 3M Innovative Properties Company | Imide addition-fragmentation agents |
| KR20230122001A (ko) * | 2020-12-24 | 2023-08-22 | 쿠라레 노리타케 덴탈 가부시키가이샤 | 지르코니아 소결체 |
| EP4301552A4 (en) | 2021-03-05 | 2025-03-05 | Saint-gobain Abrasives, Inc | Abrasive articles and methods for forming same |
| US12473475B2 (en) | 2021-03-05 | 2025-11-18 | Saint-Gobain Abrasives, Inc. | Abrasive articles and methods for forming same |
| EP4444809A1 (en) | 2021-12-06 | 2024-10-16 | 3M Innovative Properties Company | Adhesives comprising cyclic imide addition-fragmentation and adhesion agents |
| US12296434B2 (en) | 2021-12-30 | 2025-05-13 | Saint-Gobain Abrasives, Inc. | Abrasive articles and methods for forming same |
| US12064850B2 (en) | 2021-12-30 | 2024-08-20 | Saint-Gobain Abrasives, Inc. | Abrasive articles and methods for forming same |
| JP2025540069A (ja) | 2022-12-06 | 2025-12-11 | ソルベンタム インテレクチュアル プロパティズ カンパニー | 表面処理された充填剤、このような充填剤を含有する歯科用組成物、その製造方法及び使用 |
| CN116102060A (zh) * | 2023-02-10 | 2023-05-12 | 广州市汉宵科研技术有限公司 | 一种纳米级氧化锆颗粒材料及其制备方法 |
Family Cites Families (100)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2984628A (en) | 1956-11-29 | 1961-05-16 | Du Pont | Concentrated zirconia and hafnia aquasols and their preparation |
| US3018262A (en) | 1957-05-01 | 1962-01-23 | Shell Oil Co | Curing polyepoxides with certain metal salts of inorganic acids |
| US3066112A (en) | 1959-01-30 | 1962-11-27 | Rafael L Bowen | Dental filling material comprising vinyl silane treated fused silica and a binder consisting of the reaction product of bis phenol and glycidyl acrylate |
| NL128404C (https=) | 1959-12-24 | |||
| US3442817A (en) | 1966-04-15 | 1969-05-06 | Du Pont | Preparation of zirconia and hafnia sols |
| US3514252A (en) | 1967-07-07 | 1970-05-26 | Grace W R & Co | Process for the preparation of stabilized zirconia powders |
| US3860556A (en) | 1968-03-15 | 1975-01-14 | Minnesota Mining & Mfg | Low water absorption dental restorative |
| US3539533A (en) | 1968-06-14 | 1970-11-10 | Johnson & Johnson | Dental filling material |
| US3708296A (en) | 1968-08-20 | 1973-01-02 | American Can Co | Photopolymerization of epoxy monomers |
| US3709706A (en) | 1969-05-16 | 1973-01-09 | Minnesota Mining & Mfg | Refractory fibers and other articles of zirconia and silica mixtures |
| US3629187A (en) | 1969-06-25 | 1971-12-21 | Dentsply Int Inc | Dental compositions containing adduct of 2 2' - propane bis 3-(4-phenoxy)-1 2-hydroxy propane - 1 - methacrylate and isocyanate |
| US3709866A (en) | 1970-06-01 | 1973-01-09 | Dentsply Int Inc | Photopolymerizable dental products |
| US3766132A (en) | 1971-02-12 | 1973-10-16 | Lee Pharmaceuticals | Diacrylate esters of low viscosity and the use thereof as binders in dental restorative compositions |
| US3751399A (en) | 1971-05-24 | 1973-08-07 | Lee Pharmaceuticals | Polyacrylate resin compositions |
| US3729113A (en) | 1971-07-08 | 1973-04-24 | Reflector Hardware Corp | Modular cabinet assembly, and components and subassemblies therefor |
| GB1408265A (en) | 1971-10-18 | 1975-10-01 | Ici Ltd | Photopolymerisable composition |
| US3808006A (en) | 1971-12-06 | 1974-04-30 | Minnesota Mining & Mfg | Photosensitive material containing a diaryliodium compound, a sensitizer and a color former |
| US3741769A (en) | 1972-10-24 | 1973-06-26 | Minnesota Mining & Mfg | Novel photosensitive polymerizable systems and their use |
| US4115346A (en) | 1974-02-12 | 1978-09-19 | Kulzer & Co. Gmbh | Hydroxy group containing diesters of acrylic acids and their use in dental material |
| DE2406557C3 (de) | 1974-02-12 | 1981-02-19 | Kulzer & Co Gmbh, 6380 Bad Homburg | Hydroxyl-Gruppen enthaltende Diester von Acrylsäuren und diese enthaltendes Zahnfüllungsmaterial |
| AU497960B2 (en) | 1974-04-11 | 1979-01-25 | Minnesota Mining And Manufacturing Company | Photopolymerizable compositions |
| US4250311A (en) | 1974-05-02 | 1981-02-10 | General Electric Company | P, As, and Sb hexafluoride onium salts as photoinitiators |
| GB1512982A (en) | 1974-05-02 | 1978-06-01 | Gen Electric | Salts |
| GB1569021A (en) | 1976-03-17 | 1980-06-11 | Kuraray Co | Adhesive cementing agents containing partial phosphonic orphosphonic acid esters |
| JPS5940953B2 (ja) * | 1977-11-30 | 1984-10-03 | 東邦化学工業株式会社 | ポリエステル系合成繊維の染色法 |
| US4292029A (en) | 1978-05-15 | 1981-09-29 | University Of Michigan | Hydrophobic composite restorative materials and their use in tooth treatment |
| US4387240A (en) | 1978-06-02 | 1983-06-07 | Minnesota Mining And Manufacturing Company | Oligomeric methacryl substituted alkylsiloxanes |
| US4216288A (en) | 1978-09-08 | 1980-08-05 | General Electric Company | Heat curable cationically polymerizable compositions and method of curing same with onium salts and reducing agents |
| DE2850917A1 (de) | 1978-11-24 | 1980-06-04 | Bayer Ag | Dentalwerkstoffe auf basis von organischen kunststoffen in pastoeser form |
| US4327014A (en) | 1979-04-11 | 1982-04-27 | Kanebo Ltd. | Resin-forming material, implant material and compositions for restorative material suitable for medical or dental use |
| US4250053A (en) | 1979-05-21 | 1981-02-10 | Minnesota Mining And Manufacturing Company | Sensitized aromatic iodonium or aromatic sulfonium salt photoinitiator systems |
| US4379695A (en) | 1980-06-02 | 1983-04-12 | Scientific Pharmaceuticals, Inc. | Dental material comprising dimethyacrylate adducts of glycidyl methacrylate with diesters of bis(hydroxymethyl) tricyclo[5.2.1.02,6 ]decane and dicarboxylic acids |
| JPS5828878B2 (ja) | 1980-08-20 | 1983-06-18 | 三金工業株式会社 | 環状ピロ燐酸エステル誘導体 |
| EP0060911B1 (de) | 1981-03-24 | 1985-06-19 | Blendax-Werke R. Schneider GmbH & Co. | Dentales Füllungsmaterial |
| EP0094915B1 (de) | 1982-05-19 | 1987-01-21 | Ciba-Geigy Ag | Härtbare, Metallocenkomplexe enthaltende Zusammensetzungen, daraus erhältliche aktivierte Vorstufen und deren Verwendung |
| US5089536A (en) | 1982-11-22 | 1992-02-18 | Minnesota Mining And Manufacturing Company | Energy polmerizable compositions containing organometallic initiators |
| US5073476A (en) | 1983-05-18 | 1991-12-17 | Ciba-Geigy Corporation | Curable composition and the use thereof |
| US4545924A (en) | 1983-06-13 | 1985-10-08 | Owens-Corning Fiberglas Corporation | Production of a magnesium chloride gel system useful in ceramics and fiber production |
| US4612138A (en) * | 1983-08-04 | 1986-09-16 | Nalco Chemical Company | Stable acidic and alkaline metal oxide sols |
| DE3341888A1 (de) | 1983-11-19 | 1985-05-30 | Bayer Ag, 5090 Leverkusen | Anorganisch-organische fuellstoffe, verfahren zu deren herstellung sowie deren verwendung in polymerisierbaren massen |
| DE3342601C1 (de) | 1983-11-25 | 1985-03-14 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Verwendung von bromierten aromatischen Diacrylsaeure- bzw. Dimethacrylsaeureestern in dentalen Fuellungsmaterialien |
| US4544359A (en) | 1984-01-13 | 1985-10-01 | Pentron Corporation | Dental restorative material |
| DE3403040A1 (de) | 1984-01-30 | 1985-08-08 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Dentales fuellungsmaterial |
| US4503169A (en) | 1984-04-19 | 1985-03-05 | Minnesota Mining And Manufacturing Company | Radiopaque, low visual opacity dental composites containing non-vitreous microparticles |
| US4746685A (en) | 1984-08-31 | 1988-05-24 | Nippon Oil And Fats Co., Ltd. | Light curable dental composition |
| DE3443221A1 (de) | 1984-11-27 | 1986-06-05 | ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld | Bisacylphosphinoxide, ihre herstellung und verwendung |
| EP0184467A3 (en) | 1984-12-06 | 1988-06-08 | Berger, Jenson and Nicholson Limited | Water reducible coating compositions |
| US4661540A (en) | 1984-12-06 | 1987-04-28 | Berger, Jenson & Nicholson Limited | Water reducible coating compositions |
| US4642126A (en) | 1985-02-11 | 1987-02-10 | Norton Company | Coated abrasives with rapidly curable adhesives and controllable curvature |
| US4619817A (en) | 1985-03-27 | 1986-10-28 | Battelle Memorial Institute | Hydrothermal method for producing stabilized zirconia |
| US4652274A (en) | 1985-08-07 | 1987-03-24 | Minnesota Mining And Manufacturing Company | Coated abrasive product having radiation curable binder |
| US4772530A (en) | 1986-05-06 | 1988-09-20 | The Mead Corporation | Photosensitive materials containing ionic dye compounds as initiators |
| US4772511A (en) | 1985-11-22 | 1988-09-20 | Minnesota Mining And Manufacturing Company | Transparent non-vitreous zirconia microspheres |
| JPH0729771B2 (ja) | 1986-01-14 | 1995-04-05 | 悦朗 加藤 | 単斜ジルコニア超微結晶の高分散ゾルまたはゲルおよび製造方法 |
| JPS62260718A (ja) | 1986-05-06 | 1987-11-13 | Shigeyuki Somiya | 水熱法による高純度ジルコニア−アルミナ系超微粉末の製造方法 |
| US4719091A (en) | 1986-07-01 | 1988-01-12 | Corning Glass Works | Preparation of mono-sized zirconia powders by forced hydrolysis |
| US4778671A (en) | 1986-07-14 | 1988-10-18 | Corning Glass Works | Preparation of unagglomerated metal oxide particles with uniform particle size |
| EP0262579B1 (en) | 1986-09-27 | 1992-04-01 | Nissan Chemical Industries Ltd. | Process for manufacturing fine zirconium oxide powder |
| US4874450A (en) | 1987-01-29 | 1989-10-17 | The Mead Corporation | Laminating transparent or translucent materials using ionic dye-counter ion complexes |
| DE3863940D1 (de) | 1987-02-25 | 1991-09-05 | Nippon Catalytic Chem Ind | Verfahren zur erzeugung sehr kleiner, anorganischer, kugelfoermiger teilchen. |
| CA1323949C (en) | 1987-04-02 | 1993-11-02 | Michael C. Palazzotto | Ternary photoinitiator system for addition polymerization |
| US4886624A (en) | 1987-08-19 | 1989-12-12 | Rhone-Poulenc, Inc. | Colloidal alcohol-dispersible association complexes of ceric dioxide and a hydroxyphenyl carboxylic acid |
| FR2629071B1 (fr) * | 1988-03-22 | 1991-03-15 | Produits Refractaires | Oxyde de zirconium reactif et sa preparation |
| US4985340A (en) | 1988-06-01 | 1991-01-15 | Minnesota Mining And Manufacturing Company | Energy curable compositions: two component curing agents |
| US5234870A (en) | 1988-07-21 | 1993-08-10 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Zirconia sol and method for production thereof |
| US4954414A (en) | 1988-11-08 | 1990-09-04 | The Mead Corporation | Photosensitive composition containing a transition metal coordination complex cation and a borate anion and photosensitive materials employing the same |
| US5275759A (en) | 1989-02-10 | 1994-01-04 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Zirconia sol, method for production thereof, porous ceramic-producing slurry, and porous ceramic product obtained by use thereof |
| US5057393A (en) | 1989-07-10 | 1991-10-15 | The Mead Corporation | Dye branched-alkyl borate photoinitiators |
| JPH077895B2 (ja) | 1989-07-14 | 1995-01-30 | 日本電気株式会社 | 可変利得増幅器 |
| US5190583A (en) * | 1989-12-04 | 1993-03-02 | Transfer-Electric Gesellschaft Fur | Aqueous coating composition and the use thereof for coating to be protected from light, especially ultraviolet radiation |
| US5084586A (en) | 1990-02-12 | 1992-01-28 | Minnesota Mining And Manufacturing Company | Novel initiators for cationic polymerization |
| US5037579A (en) | 1990-02-12 | 1991-08-06 | Nalco Chemical Company | Hydrothermal process for producing zirconia sol |
| US5124417A (en) | 1990-02-12 | 1992-06-23 | Minnesota Mining And Manufacturing Company | Initiators for cationic polymerization |
| US5055372A (en) | 1990-04-23 | 1991-10-08 | The Mead Corporation | Photohardenable composition containing borate salts and ketone initiators |
| JPH0472768A (ja) | 1990-07-13 | 1992-03-06 | Meidensha Corp | 自己消弧型半導体装置 |
| JPH0764564B2 (ja) * | 1991-02-20 | 1995-07-12 | 株式会社槌屋 | 酸化ジルコニウム系前駆体ゲル状物及びその製造方法 |
| US5332429A (en) | 1991-05-31 | 1994-07-26 | Minnesota Mining And Manufacturing Company | Method for treating fluoroaluminosilicate glass |
| FR2681534B1 (fr) | 1991-09-20 | 1995-01-27 | Rhone Poulenc Chimie | Solutions collouidales concentrees de particules monocristallines non agregees d'oxydes de metaux, leur procede de preparation et leur application a l'obtention de films. |
| DE4133621A1 (de) | 1991-10-10 | 1993-04-22 | Inst Neue Mat Gemein Gmbh | Nanoskalige teilchen enthaltende kompositmaterialien, verfahren zu deren herstellung und deren verwendung fuer optische elemente |
| DE4212633A1 (de) | 1992-04-15 | 1993-10-21 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung oberflächenmodifizierter nanoskaliger keramischer Pulver |
| WO1993023333A1 (en) * | 1992-05-20 | 1993-11-25 | E.I. Du Pont De Nemours And Company | Process for making inorganic gels |
| US5460701A (en) | 1993-07-27 | 1995-10-24 | Nanophase Technologies Corporation | Method of making nanostructured materials |
| TW343961B (en) | 1994-06-17 | 1998-11-01 | Nissan Chemical Ind Ltd | Aqueous zirconia sol and method of preparing same |
| JP3214982B2 (ja) | 1994-07-04 | 2001-10-02 | 株式会社トクヤマ | 無機組成物 |
| US5856373A (en) | 1994-10-31 | 1999-01-05 | Minnesota Mining And Manufacturing Company | Dental visible light curable epoxy system with enhanced depth of cure |
| JP3542425B2 (ja) | 1994-11-17 | 2004-07-14 | キヤノン株式会社 | インクジェット記録用水系分散インク、これを用いるインクジェット記録方法、インクカートリッジ、記録ユニットおよび記録装置 |
| CN1083400C (zh) | 1995-03-15 | 2002-04-24 | 霍亚株式会社 | 金属氧化物析出物的制造方法 |
| US5698483A (en) | 1995-03-17 | 1997-12-16 | Institute Of Gas Technology | Process for preparing nanosized powder |
| DE19515820A1 (de) | 1995-04-29 | 1996-10-31 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung schwach agglomerierter nanoskaliger Teilchen |
| US5648407A (en) | 1995-05-16 | 1997-07-15 | Minnesota Mining And Manufacturing Company | Curable resin sols and fiber-reinforced composites derived therefrom |
| WO1997015526A1 (en) | 1995-10-27 | 1997-05-01 | E.I. Du Pont De Nemours And Company | Hydrothermal process for making ultrafine metal oxide powders |
| DE19540623A1 (de) | 1995-10-31 | 1997-05-07 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung von Kompositmaterialien mit hohem Grenzflächenanteil und dadurch erhältliche Kompositmaterialien |
| US5886069A (en) | 1995-11-13 | 1999-03-23 | E. I. Du Pont De Nemours And Company | Titanium dioxide particles having substantially discrete inorganic particles dispersed on their surfaces |
| DE19617931C5 (de) | 1996-04-26 | 2010-07-22 | Ivoclar Vivadent Ag | Verwendung eines gefüllten und polymerisierbaren Materials als Dentalmaterial |
| US5942559A (en) | 1996-08-26 | 1999-08-24 | Ivoclar Ag | Dental light-curing opaquer |
| US6030914A (en) | 1996-11-12 | 2000-02-29 | Tosoh Corporation | Zirconia fine powder and method for its production |
| JP4086338B2 (ja) | 1996-12-06 | 2008-05-14 | 株式会社松風 | 歯科用弾性修復材料並びにそれを用いた歯科補綴材料の作製方法 |
| US5760126A (en) | 1996-12-20 | 1998-06-02 | Minnesota Mining And Manufacturing Company | Aqueous fluorochemical compositions and abrasion-resistant coatings therefrom |
| US6025406A (en) | 1997-04-11 | 2000-02-15 | 3M Innovative Properties Company | Ternary photoinitiator system for curing of epoxy resins |
| US5879715A (en) | 1997-09-02 | 1999-03-09 | Ceramem Corporation | Process and system for production of inorganic nanoparticles |
-
1999
- 1999-10-28 US US09/428,374 patent/US6376590B2/en not_active Expired - Lifetime
-
2000
- 2000-04-03 CA CA002388876A patent/CA2388876C/en not_active Expired - Fee Related
- 2000-04-03 AU AU40652/00A patent/AU4065200A/en not_active Abandoned
- 2000-04-03 DE DE60023023T patent/DE60023023T2/de not_active Expired - Lifetime
- 2000-04-03 WO PCT/US2000/008796 patent/WO2001030702A1/en not_active Ceased
- 2000-04-03 EP EP00920055A patent/EP1232118B1/en not_active Expired - Lifetime
- 2000-04-03 JP JP2001533062A patent/JP4559004B2/ja not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9202688B2 (en) | 2010-04-23 | 2015-12-01 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US9328432B2 (en) | 2010-04-23 | 2016-05-03 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US9617657B2 (en) | 2010-04-23 | 2017-04-11 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US9856581B2 (en) | 2010-04-23 | 2018-01-02 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US10753012B2 (en) | 2010-10-27 | 2020-08-25 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| US9359689B2 (en) | 2011-10-26 | 2016-06-07 | Pixelligent Technologies, Llc | Synthesis, capping and dispersion of nanocrystals |
| CN113165900A (zh) * | 2018-11-30 | 2021-07-23 | 马蒂姆有限公司 | 一种在氨基酸存在下制备二氧化锆纳米颗粒的方法 |
| CN113165900B (zh) * | 2018-11-30 | 2023-07-18 | 马蒂姆有限公司 | 一种在氨基酸存在下制备二氧化锆纳米颗粒的方法 |
| CN114656818A (zh) * | 2020-12-03 | 2022-06-24 | 凯斯科技股份有限公司 | 金属氧化物分散液 |
| CN114656818B (zh) * | 2020-12-03 | 2023-11-17 | 凯斯科技股份有限公司 | 金属氧化物分散液 |
| CN115124074A (zh) * | 2022-07-26 | 2022-09-30 | 宣城市晶纳环保科技有限公司 | 一种高分散复合纳米二氧化锆的制备方法 |
| CN115124074B (zh) * | 2022-07-26 | 2024-02-06 | 宣城市晶纳环保科技有限公司 | 一种高分散复合纳米二氧化锆的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2388876C (en) | 2009-10-27 |
| DE60023023T2 (de) | 2006-06-14 |
| JP2003512287A (ja) | 2003-04-02 |
| CA2388876A1 (en) | 2001-05-03 |
| US6376590B2 (en) | 2002-04-23 |
| EP1232118A1 (en) | 2002-08-21 |
| US20020004544A1 (en) | 2002-01-10 |
| WO2001030702A1 (en) | 2001-05-03 |
| AU4065200A (en) | 2001-05-08 |
| DE60023023D1 (de) | 2006-02-16 |
| EP1232118B1 (en) | 2005-10-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4559004B2 (ja) | ジルコニアゾル及びその製造方法 | |
| EP2244982B1 (en) | Method of making zirconia-containing nanoparticles | |
| US7241437B2 (en) | Zirconia particles | |
| RU2571151C2 (ru) | Аэрогели, кальцинированные изделия, изделия с кристаллической структурой и способы их получения | |
| JP4773017B2 (ja) | 美的歯科材料 | |
| JP4842269B2 (ja) | 酸反応性歯科用フィラー、組成物、および方法 | |
| US6194481B1 (en) | Mechanically strong and transparent or translucent composites made using zirconium oxide nanoparticles | |
| JP4276077B2 (ja) | ルチル様結晶相を有するナノ粒子およびその調製方法 | |
| EP2370841B1 (en) | High refractive index inorganic oxide nanoparticles comprising surface treatment and microstructured film | |
| US20120264899A1 (en) | Brightness enhancing film comprising nanocomposite structure having improved crack resistance | |
| CN113165900B (zh) | 一种在氨基酸存在下制备二氧化锆纳米颗粒的方法 | |
| TWI363062B (en) | Polymerizable compositions comprising nanoparticles | |
| JPH10306008A (ja) | 歯科用充填組成物 | |
| Aydınoğlu et al. | Production Methods Effect on Nanosilica Properties | |
| TW202402681A (zh) | 粒子的分散液及其製造方法、塗布液及帶膜基材的製造方法 | |
| Acar | INSIGHT INTO THE EFFECT OF TI/ZR OXIDE HYBRID PARTICLES ON DENTAL COMPOSITES: PARTICLE SYNTHESIS AND CHARACTERIZATION AND THE MECHANICAL BEHAVIOR OF COMPOSITES |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070221 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070221 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100316 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100527 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100622 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100722 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4559004 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130730 Year of fee payment: 3 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |