JP2014534902A - 担持活性金属触媒および前駆体を製造および形成する方法 - Google Patents
担持活性金属触媒および前駆体を製造および形成する方法 Download PDFInfo
- Publication number
- JP2014534902A JP2014534902A JP2014536285A JP2014536285A JP2014534902A JP 2014534902 A JP2014534902 A JP 2014534902A JP 2014536285 A JP2014536285 A JP 2014536285A JP 2014536285 A JP2014536285 A JP 2014536285A JP 2014534902 A JP2014534902 A JP 2014534902A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- catalytically active
- active metal
- framework
- catalyst support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 346
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 188
- 239000002184 metal Substances 0.000 title claims abstract description 188
- 238000000034 method Methods 0.000 title claims abstract description 134
- 230000008569 process Effects 0.000 title claims abstract description 68
- 239000002243 precursor Substances 0.000 title description 6
- 239000011148 porous material Substances 0.000 claims abstract description 86
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 46
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 45
- 239000000725 suspension Substances 0.000 claims abstract description 38
- 239000002245 particle Substances 0.000 claims abstract description 31
- 230000001376 precipitating effect Effects 0.000 claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 claims abstract description 25
- 230000003197 catalytic effect Effects 0.000 claims abstract description 22
- 239000002244 precipitate Substances 0.000 claims abstract description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 117
- 239000010457 zeolite Substances 0.000 claims description 105
- 150000001768 cations Chemical class 0.000 claims description 100
- 229910021536 Zeolite Inorganic materials 0.000 claims description 92
- 239000000463 material Substances 0.000 claims description 48
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 45
- 150000002739 metals Chemical class 0.000 claims description 38
- 238000005342 ion exchange Methods 0.000 claims description 37
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 27
- 238000005470 impregnation Methods 0.000 claims description 26
- 229910052700 potassium Inorganic materials 0.000 claims description 26
- 229910052742 iron Inorganic materials 0.000 claims description 22
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 21
- 239000011591 potassium Substances 0.000 claims description 21
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 20
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 14
- 239000010949 copper Substances 0.000 claims description 14
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 14
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 14
- 239000011736 potassium bicarbonate Substances 0.000 claims description 14
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 14
- 235000011181 potassium carbonates Nutrition 0.000 claims description 14
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052596 spinel Inorganic materials 0.000 claims description 9
- 239000011029 spinel Substances 0.000 claims description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- -1 alkaline earth metal cations Chemical class 0.000 claims description 8
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- 150000001340 alkali metals Chemical class 0.000 claims description 6
- 229910052746 lanthanum Inorganic materials 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 4
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 239000011572 manganese Substances 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 229910052741 iridium Inorganic materials 0.000 claims description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 3
- 150000002602 lanthanoids Chemical class 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052762 osmium Inorganic materials 0.000 claims description 3
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 229910052702 rhenium Inorganic materials 0.000 claims description 3
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052703 rhodium Inorganic materials 0.000 claims description 3
- 239000010948 rhodium Substances 0.000 claims description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 238000001311 chemical methods and process Methods 0.000 claims 2
- 125000005587 carbonate group Chemical group 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 abstract description 27
- 238000003786 synthesis reaction Methods 0.000 abstract description 19
- 239000000243 solution Substances 0.000 description 65
- 238000006243 chemical reaction Methods 0.000 description 57
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 34
- 239000000047 product Substances 0.000 description 31
- 239000004215 Carbon black (E152) Substances 0.000 description 30
- 229910044991 metal oxide Inorganic materials 0.000 description 29
- 150000004706 metal oxides Chemical class 0.000 description 29
- 230000000694 effects Effects 0.000 description 25
- 230000001588 bifunctional effect Effects 0.000 description 23
- 238000001556 precipitation Methods 0.000 description 23
- 150000003839 salts Chemical class 0.000 description 22
- 230000002378 acidificating effect Effects 0.000 description 20
- 229960003975 potassium Drugs 0.000 description 20
- 239000007789 gas Substances 0.000 description 19
- 238000005245 sintering Methods 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 229910002092 carbon dioxide Inorganic materials 0.000 description 16
- 239000001569 carbon dioxide Substances 0.000 description 16
- 239000011800 void material Substances 0.000 description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
- 229910002091 carbon monoxide Inorganic materials 0.000 description 13
- 239000012013 faujasite Substances 0.000 description 13
- 239000007788 liquid Substances 0.000 description 13
- 238000011068 loading method Methods 0.000 description 13
- 230000005012 migration Effects 0.000 description 13
- 238000013508 migration Methods 0.000 description 13
- 229940093956 potassium carbonate Drugs 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
- 238000005984 hydrogenation reaction Methods 0.000 description 11
- 230000002776 aggregation Effects 0.000 description 10
- 230000009849 deactivation Effects 0.000 description 10
- 238000001035 drying Methods 0.000 description 10
- 239000012266 salt solution Substances 0.000 description 10
- 230000006378 damage Effects 0.000 description 9
- 230000006870 function Effects 0.000 description 9
- 230000002829 reductive effect Effects 0.000 description 9
- 238000011282 treatment Methods 0.000 description 9
- 238000001354 calcination Methods 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 125000004429 atom Chemical group 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 238000006722 reduction reaction Methods 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 239000011973 solid acid Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 238000005054 agglomeration Methods 0.000 description 5
- 238000004220 aggregation Methods 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 238000012856 packing Methods 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 230000001737 promoting effect Effects 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 4
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 4
- 230000001627 detrimental effect Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000003502 gasoline Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 238000006384 oligomerization reaction Methods 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 230000036961 partial effect Effects 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003377 acid catalyst Substances 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000009881 electrostatic interaction Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 238000006317 isomerization reaction Methods 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- 230000000607 poisoning effect Effects 0.000 description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 3
- 238000000629 steam reforming Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000005899 aromatization reaction Methods 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000007327 hydrogenolysis reaction Methods 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 230000003204 osmotic effect Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910020068 MgAl Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical class OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 125000005595 acetylacetonate group Chemical group 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000011952 anionic catalyst Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000012769 bulk production Methods 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 230000002925 chemical effect Effects 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 238000001165 gas chromatography-thermal conductivity detection Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010952 in-situ formation Methods 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229910021644 lanthanide ion Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000001883 metal evaporation Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000008450 motivation Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002091 nanocage Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000003901 oxalic acid esters Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000036619 pore blockages Effects 0.000 description 1
- 239000013354 porous framework Substances 0.000 description 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000006057 reforming reaction Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052665 sodalite Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/068—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/072—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/12—Noble metals
- B01J29/126—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/14—Iron group metals or copper
- B01J29/146—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/166—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/7215—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/7276—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
- B01J29/7415—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
- B01J29/7476—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/7615—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/7676—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/7815—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/7876—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0211—Impregnation using a colloidal suspension
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
- B01J37/033—Using Hydrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
- B01J37/035—Precipitation on carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/38—Base treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
- B01J2523/13—Potassium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
- B01J2523/17—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
- B01J2523/31—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
- B01J2523/37—Lanthanides
- B01J2523/3712—Cerium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
- B01J2523/41—Silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
- B01J2523/84—Metals of the iron group
- B01J2523/842—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
(i)内部ポア構造を有するフレームワークを含む多孔性触媒担体(porous catalyst support)であって、該内部ポア構造が沈殿剤を含む多孔性触媒担体を提供すること;
(ii)該沈殿剤と接触することによって触媒活性金属(catalytically active metal)を含む粒子が該触媒担体のフレームワークの内部ポア構造内に沈殿するように、該触媒担体を、触媒活性金属を含む溶液またはコロイド性懸濁液と接触させること
のステップを特徴とする方法。
触媒担体のフレームワーク内部ポア構造に、触媒担体の合成の間に例えば沈殿剤を触媒担体合成混合物またはゲルへ組み込むことによって、沈殿剤を充填することができる。あるいは、例えば沈殿剤を含む溶液を用いる含浸法(初期湿潤含浸法など)によって、沈殿剤を触媒担体の後処置によって充填することができる。その結果、フレームワークの内部ポア構造内に沈殿剤が位置する触媒担体ができる。
ゼオライトフレームワークを含む触媒担体であって、該ゼオライトフレームワークが、第1族もしくは第2族金属またはそれらの組み合わせの少なくとも1つの電荷平衡カチオン含有する触媒担体を提供し;
上記グループAおよびその組み合わせから選択される金属の第1塩;上記グループBおよびその組み合わせから選択される金属の第2塩;および上記グループCおよびその組み合わせから選択される金属の第3塩;を含む金属塩溶液を提供し;
ゼオライトフレームワークを初期湿潤含浸法によって金属塩溶液で含浸させ;並びに
浸透ゼオライトフレームワーク担体をか焼して、ゼオライトフレームワーク担体中に混合金属酸化物クラスターを形成させる[ここで、混合金属酸化物クラスターは式AxByCzOnを有し、式中、x、yおよびzは各々、酸化物中の金属A、BおよびCの相対的比率であり、x+y+zは整数であり、nは酸化物を中性に帯電させる酸素の相対的比率である]
ことを特徴とする。
本発明は、炭化水素生成または製造において使用するための触媒の製造によって例証することができ、有用な炭化水素を形成するための一酸化炭素および二酸化炭素の水素化反応に関する処理における非限定の例を参照しながら記載される。本発明は幅広い適用があり、本発明の原理は、関連する理論および本発明者らによる理論の応用に言及しながら説明される。
以下では、本発明の態様の実施例を詳細に記載する。実施例は、図6で模式的に示される実験セットアップによって試験された。実験セットアップ90には、注水によって重量測定法で決定された840mLの容量の反応器92が含まれる。
以下のステップを行って、触媒A(Fe/Ce/Cu/KY)を製造した。
上述で記載の通り、本発明の触媒は、ニ官能性触媒を製造するのにも適した構成成分である。本実施例においては、触媒Eを、5gの触媒Aを5gのZSM−5ゼオライト成形品(80%H−ZSM−5ゼオライト、20%アルミナ結合剤)と組み合わせ、それをSTIRR反応器の触媒バスケット中、触媒Aの上部に置くことによって製造した。この配置(arrangement)は、触媒AおよびH−ZSM−5ゼオライトを含むニ官能性触媒に等しい。
Claims (34)
- 担持触媒の製造方法であって、
該方法が以下:
(i)一またはそれ以上のポアを含む内部ポア構造を有するフレームワークを含む多孔性触媒担体であって、該内部ポア構造が沈殿剤を含む多孔性触媒担体を提供すること;
(ii)該沈殿剤と接触することによって触媒活性金属を含む粒子が該触媒担体のフレームワークの内部ポア構造内に沈殿するように、該触媒担体を、触媒活性金属を含む溶液またはコロイド性懸濁液と接触させること
のステップを特徴とする方法。 - 触媒担体が酸化物である、請求項1の方法。
- 内部ポア構造が、より小さい直径セクションのポアまたは「ウィンドウ」を通してアクセス可能な、一またはそれ以上の領域または「ケージ」を有する、請求項1または2の方法。
- 触媒活性金属含有のクラスターが、より小さい直径セクションのポアよりも大きい有効径を有する、請求項3の方法。
- ポア直径またはポア「ウィンドウ」の直径が、0.2nmよりも大きい、請求項1〜4のいずれか一つの方法。
- 触媒担体がゼオタイプ構造を有する、請求項1〜5のいずれか一つの方法。
- 触媒担体がアルミノケイ酸塩ゼオライトである、請求項6の方法。
- アルミノケイ酸塩ゼオライトが、10未満、例えば2〜5の範囲のケイ素とアルミニウムのモル比を有する、請求項7の方法。
- 触媒担体フレームワークが、ゼオライト構造の国際ゼオライト学会データベースに従うFAU、BEAまたはMWW構造を採用する、請求項1〜8のいずれか一つの方法。
- 触媒担体が、一またはそれ以上の電荷平衡カチオンによって平衡化される、負電荷を持つフレームワークを含む、請求項1〜9のいずれか一つの方法。
- 電荷平衡カチオンが、アルカリ金属またはアルカリ土類金属カチオンから選択され、好ましくはカリウムである、請求項10の方法。
- フレームワークの電荷平衡カチオンが、プロモーターまたは共触媒として作用できる、請求項10または11の方法。
- 沈殿剤が電荷平衡カチオンと同じカチオンを含み、また担持触媒中のカチオンの全含有量が触媒担体の全イオン交換能力よりも大きい、請求項11または12の方法。
- 触媒活性金属含有粒子が、結晶構造を有する、請求項1〜13のいずれか一つの方法。
- 触媒活性金属が、ニッケル、コバルト、鉄、ルテニウム、オスミウム、白金、イリジウム、レニウム、モリブデン、クロム、タングステン、バナジウム、ロジウム、およびマンガンからなる群より選択される一またはそれ以上の要素である、請求項1〜14のいずれか一つの方法。
- さらに、触媒担体を、触媒活性金属含有粒子の一部も形成する、イットリウム、ランタン、セリウム、および他のあらゆるランタニド金属からなる群より選択される金属の一またはそれ以上を含む溶液またはコロイド性懸濁液と接触することを特徴とする、請求項15の方法。
- さらに、触媒担体を、触媒活性金属含有粒子の一部も形成する、銅、亜鉛、ガリウム、ジルコニウム、およびパラジウムからなる群より選択される要素の一またはそれ以上と接触することを特徴とする、請求項15または16の方法。
- 触媒担体を触媒活性金属含有粒子と含む得られた物質を空気中か焼し、得られた物質の乾燥後に適宜行ってもよい、さらなるステップを含む、請求項1〜17のいずれか一つの方法。
- 触媒活性金属を含む粒子が結晶構造を有する、請求項1〜18のいずれか一つの方法。
- 触媒活性金属を含む粒子が、スピネルまたはペロブスカイト構造を有する、請求項19の方法。
- 触媒活性金属を含む粒子の構造が、カチオン空きを含む、請求項1〜20のいずれか一つの方法。
- 触媒活性金属を含む粒子が、触媒担体フレームワークの電荷平衡カチオンと静電気的に相互作用する、請求項21の方法。
- 担持触媒が、Fe、Cu、Kを含む、請求項1〜22のいずれか一つの方法。
- 触媒活性金属含有粒子を、例えば高温で水素ガスの存在下で、化学的に還元する、さらなるステップを含む、請求項1〜23のいずれか一つの方法。
- 沈殿剤が、触媒担体フレームワークの内部ポア構造に最初に充填される、請求項1〜24のいずれか一つの方法。
- 沈殿剤が塩基性である、請求項1〜25のいずれか一つの方法。
- 沈殿剤が炭酸塩または炭酸水素塩であり、例えば炭酸カリウムまたは炭酸水素カリウムである、請求項1〜26のいずれか一つの方法。
- 触媒担体が、初期湿潤含浸法を用いて、触媒活性金属を含む溶液またはコロイド性懸濁液接触される、請求項1〜27のいずれか一つの方法。
- 触媒担体が、触媒活性金属の溶液と接触される、請求項1〜28のいずれか一つの方法。
- 担持触媒が、フィッシャー・トロプシュ触媒である、請求項1〜29のいずれか一つの方法。
- 請求項1〜30のいずれか一つの方法によって製造される担持触媒。
- 触媒化学プロセスにおける触媒としての、請求項31の担持触媒の使用。
- 触媒化学プロセスがフィッシャー・トロプシュ法である、請求項32の使用。
- 請求項31の触媒の存在下、酸化炭素の一またはそれ以上を水素と接触させることを特徴とする、酸化炭素の一またはそれ以上および水素から、炭化水素の一またはそれ以上を生成するプロセス。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1118228.4 | 2011-10-21 | ||
GB201118228A GB201118228D0 (en) | 2011-10-21 | 2011-10-21 | Methods of preparation and forming supported active metal catalysts and precursors |
GBPCT/GB2012/000803 | 2012-10-19 | ||
GB2012000803 | 2012-10-19 | ||
PCT/EP2012/070897 WO2013057319A2 (en) | 2011-10-21 | 2012-10-22 | Methods of preparation and forming supported active metal catalysts and precursors |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2014534902A true JP2014534902A (ja) | 2014-12-25 |
JP2014534902A5 JP2014534902A5 (ja) | 2015-12-10 |
JP6180421B2 JP6180421B2 (ja) | 2017-08-16 |
Family
ID=47148735
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014536285A Active JP6180421B2 (ja) | 2011-10-21 | 2012-10-22 | 担持活性金属触媒および前駆体を製造および形成する方法 |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2768612A2 (ja) |
JP (1) | JP6180421B2 (ja) |
CN (2) | CN106964391A (ja) |
AU (2) | AU2012324802B2 (ja) |
BR (1) | BR112014009541B1 (ja) |
CA (1) | CA2851988C (ja) |
EA (1) | EA027722B1 (ja) |
GB (1) | GB2513488A (ja) |
WO (1) | WO2013057319A2 (ja) |
ZA (2) | ZA201403535B (ja) |
Cited By (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017523113A (ja) * | 2014-07-23 | 2017-08-17 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | Sda非存在下におけるゼオライト転換及び金属内包 |
JP2018158279A (ja) * | 2017-03-22 | 2018-10-11 | 岩谷産業株式会社 | 炭化水素合成触媒、炭化水素合成触媒の製造方法、炭化水素製造装置、炭化水素製造方法 |
WO2018221700A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | フィッシャー・トロプシュ合成触媒構造体、その製造方法及び該触媒構造体を用いた液体炭化水素の製造方法、並びに該触媒構造体を有する炭化水素製造装置 |
WO2018221707A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | 水蒸気改質用触媒構造体、該水蒸気改質用触媒構造体を備える改質装置、及び水蒸気改質用触媒構造体の製造方法 |
WO2018221699A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | アンモニア合成触媒構造体及びその製造方法、アンモニア合成装置並びにアンモニアの合成方法 |
WO2018221692A1 (ja) * | 2017-05-31 | 2018-12-06 | 国立大学法人北海道大学 | 機能性構造体及び機能性構造体の製造方法 |
WO2018221697A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | 合成ガス製造用触媒構造体、該合成ガス製造用触媒構造体を備える合成ガス製造装置及び合成ガス製造用触媒構造体の製造方法 |
WO2018221695A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | 流動接触分解用構造体及びその製造方法、並びに、これを備える流動接触分解用装置 |
WO2018221698A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | Coシフトもしくは逆シフト触媒構造体及びその製造方法、coシフトまたは逆シフト反応装置、二酸化炭素と水素の製造方法、並びに一酸化炭素と水の製造方法 |
JP2018202387A (ja) * | 2017-05-31 | 2018-12-27 | 国立大学法人北海道大学 | 機能性構造体およびその製造方法 |
WO2019004318A1 (ja) * | 2017-06-27 | 2019-01-03 | トヨタ自動車株式会社 | クラスター担持多孔質担体及びその製造方法 |
JP2019005720A (ja) * | 2017-06-27 | 2019-01-17 | トヨタ自動車株式会社 | クラスター担持触媒及びその製造方法 |
KR20190018652A (ko) * | 2016-05-25 | 2019-02-25 | 더 리전츠 오브 더 유니버시티 오브 캘리포니아 | 캡슐화된 바이메탈 클러스터를 갖는 제올라이트성 물질 |
WO2020009318A1 (ko) * | 2018-07-04 | 2020-01-09 | 에스케이가스 주식회사 | 전환율 및 선택도가 향상된 올레핀 제조용 촉매 및 그 제조방법 |
WO2020027321A1 (ja) * | 2018-08-03 | 2020-02-06 | 古河電気工業株式会社 | 軽質炭化水素合成触媒構造体、軽質炭化水素製造装置及び軽質炭化水素の製造方法 |
JPWO2018221691A1 (ja) * | 2017-05-31 | 2020-05-21 | 国立大学法人北海道大学 | 機能性構造体及び機能性構造体の製造方法 |
WO2020116474A1 (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | 低級オレフィン含有ガスの製造装置および低級オレフィン含有ガスの製造方法 |
JP2020089814A (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | フィッシャー・トロプシュ合成触媒構造体およびその製造方法、ならびに該触媒構造体を用いた炭化水素の製造方法 |
WO2020116472A1 (ja) * | 2018-12-03 | 2020-06-11 | 国立大学法人北海道大学 | 機能性構造体 |
WO2020116470A1 (ja) * | 2018-12-03 | 2020-06-11 | 国立大学法人北海道大学 | 機能性構造体 |
JP2020089813A (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | フィッシャー・トロプシュ合成触媒構造体およびその製造方法、ならびに該触媒構造体を用いた炭化水素の製造方法 |
JP2020089810A (ja) * | 2018-12-03 | 2020-06-11 | 国立大学法人北海道大学 | 機能性構造体及びその製造方法 |
JP2020089811A (ja) * | 2018-12-03 | 2020-06-11 | 国立大学法人北海道大学 | 機能性構造体、触媒、エチレンガス酸化用触媒 |
WO2020116478A1 (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | 炭化水素の製造装置および炭化水素の製造方法 |
WO2020116476A1 (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | 炭化水素の製造装置および炭化水素の製造方法 |
WO2020116473A1 (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | 合成ガス製造用触媒構造体及びその前駆体並びに合成ガス製造装置及び合成ガス製造用触媒構造体の製造方法 |
JPWO2021193438A1 (ja) * | 2020-03-23 | 2021-09-30 | ||
US11161101B2 (en) | 2017-05-31 | 2021-11-02 | Furukawa Electric Co., Ltd. | Catalyst structure and method for producing the catalyst structure |
US11547987B2 (en) | 2017-05-31 | 2023-01-10 | Furukawa Electric Co., Ltd. | Structured catalyst for oxidation for exhaust gas purification, method for producing same, automobile exhaust gas treatment device, catalytic molding, and gas purification method |
JP2023013551A (ja) * | 2021-07-16 | 2023-01-26 | 本田技研工業株式会社 | 二酸化炭素還元触媒 |
US11648542B2 (en) | 2017-05-31 | 2023-05-16 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11654422B2 (en) | 2017-05-31 | 2023-05-23 | Furukawa Electric Co., Ltd. | Structured catalyst for catalytic cracking or hydrodesulfurization, catalytic cracking apparatus and hydrodesulfurization apparatus including the structured catalyst, and method for producing structured catalyst for catalytic cracking or hydrodesulfurization |
US11655157B2 (en) | 2017-05-31 | 2023-05-23 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11680211B2 (en) | 2017-05-31 | 2023-06-20 | Furukawa Electric Co., Ltd. | Structured catalyst for hydrodesulfurization, hydrodesulfurization device including the structured catalyst, and method for producing structured catalyst for hydrodesulfurization |
US11684909B2 (en) | 2017-05-31 | 2023-06-27 | Furukawa Electric Co., Ltd. | Structured catalyst for methanol reforming, methanol reforming device, method for producing structured catalyst for methanol reforming, and method for producing at least one of olefin or aromatic hydrocarbon |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2768612A2 (en) * | 2011-10-21 | 2014-08-27 | IGTL Technology Ltd | Methods of preparation and forming supported active metal catalysts and precursors |
CN103611537B (zh) * | 2013-11-01 | 2016-04-20 | 中国石油化工股份有限公司 | 一种铁基费托合成催化剂及其制备方法和应用 |
JP6344052B2 (ja) * | 2014-05-20 | 2018-06-20 | 株式会社Ihi | アンモニア合成触媒およびアンモニア合成方法 |
CN106660034A (zh) | 2014-05-22 | 2017-05-10 | 沙特阿拉伯石油公司 | 用于流化催化裂化的骨架取代沸石催化剂,和用于流化催化裂化的方法 |
KR102017207B1 (ko) * | 2015-12-09 | 2019-09-02 | 주식회사 엘지화학 | 산화적 탈수소화 반응용 촉매 및 이의 제조방법 |
CN107405612B (zh) * | 2015-12-28 | 2020-09-15 | 丰田自动车株式会社 | 簇载持催化剂及其制造方法 |
CN105944751B (zh) * | 2016-05-24 | 2019-06-21 | 江南大学 | 一种用于合成气直接制备芳香族化合物的催化剂及其制备与应用 |
US9687825B1 (en) | 2016-06-27 | 2017-06-27 | Chevron U.S.A. Inc. | Stable tungsten-phosphorus modified support for a Fischer-Tropsch catalyst |
EP3618955A1 (en) * | 2017-05-05 | 2020-03-11 | ExxonMobil Chemical Patents Inc. | Polyoxometalates comprising noble metals and carboxylate-based capping groups and metal clusters thereof |
JPWO2018221702A1 (ja) * | 2017-05-31 | 2020-03-26 | 古河電気工業株式会社 | 光触媒構造体、光触媒構造体組成物、光触媒被覆材、光触媒構造体の製造方法及びアルデヒド類の分解方法 |
EP3632553A4 (en) * | 2017-05-31 | 2021-01-06 | Furukawa Electric Co., Ltd. | CATALYST STRUCTURE FOR THE PRODUCTION OF AROMATIC HYDROCARBONS WITH THE CATALYST STRUCTURE FOR THE PRODUCTION OF AROMATIC HYDROCARBONS PROVIDED DEVICE FOR PRODUCING AROMATIC HYDROCARBONS, PROCESS FOR PRODUCING A CATALYST STRUCTURE FOR THE PRODUCTION OF AROMATIC HYDROCARBONS AND PROCESS FOR AROMATIC HYDROCARBONS |
WO2018221701A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | アンモニア分解触媒構造体及び燃料電池 |
CN110496639B (zh) * | 2018-05-17 | 2022-05-27 | 中国科学院大连化学物理研究所 | 一种芳烃合成用催化剂及其制备方法和应用 |
GB201813334D0 (en) * | 2018-08-15 | 2018-09-26 | Wang Tiesheng | Nanocomposite materials and methods of manufacture thereof |
CN109513457B (zh) * | 2018-11-22 | 2021-08-13 | 中国石油大学(华东) | 以改性镁铝尖晶石为载体的分子筛催化剂及其制备方法 |
CN109351182A (zh) * | 2018-11-27 | 2019-02-19 | 蓝天环保设备工程股份有限公司 | 一种具有VOCs脱除功能的烧结板除尘器 |
WO2020116477A1 (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | 触媒構造体およびその製造方法、ならびに該触媒構造体を用いた炭化水素の製造方法 |
WO2020116469A1 (ja) * | 2018-12-03 | 2020-06-11 | 国立大学法人北海道大学 | 機能性構造体 |
US20220016608A1 (en) * | 2018-12-03 | 2022-01-20 | Furukawa Electric Co., Ltd. | Catalyst structure and method for producing same, and method for producing hydrocarbon by use of catalyst structure |
CN113164934A (zh) * | 2018-12-03 | 2021-07-23 | 国立大学法人北海道大学 | 功能性结构体 |
JPWO2020116471A1 (ja) * | 2018-12-03 | 2021-12-23 | 国立大学法人北海道大学 | 機能性構造体の前駆体および機能性構造体 |
JP2023523123A (ja) * | 2020-04-30 | 2023-06-02 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニー | 触媒物品を形成する方法 |
US11446645B2 (en) | 2020-07-02 | 2022-09-20 | Saudi Arabian Oil Company | FCC catalyst compositions for fluid catalytic cracking and methods of using the FCC catalyst compositions |
US11274068B2 (en) | 2020-07-23 | 2022-03-15 | Saudi Arabian Oil Company | Process for interconversion of olefins with modified beta zeolite |
US11332678B2 (en) | 2020-07-23 | 2022-05-17 | Saudi Arabian Oil Company | Processing of paraffinic naphtha with modified USY zeolite dehydrogenation catalyst |
US11154845B1 (en) | 2020-07-28 | 2021-10-26 | Saudi Arabian Oil Company | Hydrocracking catalysts containing USY and beta zeolites for hydrocarbon oil and method for hydrocracking hydrocarbon oil with hydrocracking catalysts |
US11420192B2 (en) | 2020-07-28 | 2022-08-23 | Saudi Arabian Oil Company | Hydrocracking catalysts containing rare earth containing post-modified USY zeolite, method for preparing hydrocracking catalysts, and methods for hydrocracking hydrocarbon oil with hydrocracking catalysts |
US11142703B1 (en) | 2020-08-05 | 2021-10-12 | Saudi Arabian Oil Company | Fluid catalytic cracking with catalyst system containing modified beta zeolite additive |
CN114345396B (zh) * | 2021-11-30 | 2023-06-30 | 西安交通大学 | 分子筛原位封装活性组分型载氧体及其制备方法和应用 |
US11618858B1 (en) | 2021-12-06 | 2023-04-04 | Saudi Arabian Oil Company | Hydrodearylation catalysts for aromatic bottoms oil, method for producing hydrodearylation catalysts, and method for hydrodearylating aromatic bottoms oil with hydrodearylation catalysts |
US20230321645A1 (en) * | 2022-04-08 | 2023-10-12 | The Shepherd Chemical Company | Acid-base mediated ion-exchange metal loaded zeolite |
US11725149B1 (en) | 2022-06-13 | 2023-08-15 | Saudi Arabian Oil Company | Fluidized catalytic cracking processes and additives for improving gasoline yield and quality |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02172813A (ja) * | 1988-11-23 | 1990-07-04 | Shell Internatl Res Maatschappij Bv | 塩基性金属ゼオライト組成物、その製造方法および塩基触媒反応におけるその使用 |
JPH07316120A (ja) * | 1994-05-23 | 1995-12-05 | Tonen Corp | 2−フェニルブチロニトリルの製造方法 |
JP2003511230A (ja) * | 1999-10-12 | 2003-03-25 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | フィッシャー−トロプシュタイプの炭化水素合成触媒の調製およびその使用 |
JP2006263614A (ja) * | 2005-03-24 | 2006-10-05 | Nippon Steel Corp | 合成ガスから炭化水素を製造する触媒及び触媒の製造方法、並びに当該触媒を用いた合成ガスから炭化水素を製造する方法 |
JP2009106863A (ja) * | 2007-10-30 | 2009-05-21 | Toyama Univ | Ft合成用触媒及びft合成方法 |
WO2011042451A1 (de) * | 2009-10-08 | 2011-04-14 | Basf Se | Verfahren zur herstellung eines si-gebundenen wirbelschicht-katalysators |
GB2475492A (en) * | 2009-11-18 | 2011-05-25 | Gtl F1 Ag | Fischer-Tropsch catalyst with an alkaline earth metal content of less than 2000 ppm |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4113658A (en) | 1967-04-14 | 1978-09-12 | Stamicarbon, N.V. | Process for homogeneous deposition precipitation of metal compounds on support or carrier materials |
US4192777A (en) | 1978-03-01 | 1980-03-11 | Exxon Research & Engineering Co. | Preparation and use of supported potassium (or rubidium)-Group VIII-metal cluster catalysts in CO/H2 Fischer-Tropsch synthesis reactions |
CA1176228A (en) * | 1981-05-18 | 1984-10-16 | Minoru Koikeda | Catalyst for the production of hydrocarbons from the synthesis gas |
US4552855A (en) | 1982-12-30 | 1985-11-12 | Ozin Geoffrey A | Metal zeolite catalyst preparation |
US4537867A (en) | 1983-12-14 | 1985-08-27 | Exxon Research And Engineering Co. | Promoted iron-cobalt spinel catalyst for Fischer-Tropsch processes |
US5194244A (en) * | 1988-11-23 | 1993-03-16 | Shell Oil Company | Basic alkali metal-zeolite compositions |
ZA996280B (en) | 1999-10-04 | 2000-10-03 | Sasol Tech Pty Ltd | A method of modifying and controlling catalyst selectivity in a Fischer-Tropsch process. |
WO2003087265A1 (en) | 2002-04-16 | 2003-10-23 | Sasol Technology (Proprietary) Limited | Hydrocarbon synthesis process using an alkali promoted iron catalyst |
TW200600190A (en) * | 2004-04-01 | 2006-01-01 | Shell Int Research | Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation |
US7393876B2 (en) | 2005-12-16 | 2008-07-01 | Eltron Research, Inc. | Fischer-tropsch catalysts |
CN100351013C (zh) * | 2006-02-27 | 2007-11-28 | 西安交通大学 | CdS/Ti-MCM-41载铂光催化剂及制备方法 |
KR100903439B1 (ko) * | 2007-10-15 | 2009-06-18 | 한국화학연구원 | 천연가스로부터 경질탄화수소의 직접 제조방법 |
WO2010078371A2 (en) * | 2008-12-29 | 2010-07-08 | Chevron U.S.A. Inc. | Preparation of cobalt-containing acidic support-based fischer-tropsch catalysts |
EP2314557A1 (en) | 2009-10-23 | 2011-04-27 | Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) | Production of lower olefins from synthesis gas |
EP2768612A2 (en) * | 2011-10-21 | 2014-08-27 | IGTL Technology Ltd | Methods of preparation and forming supported active metal catalysts and precursors |
-
2012
- 2012-10-22 EP EP12783914.0A patent/EP2768612A2/en not_active Withdrawn
- 2012-10-22 CN CN201710229557.6A patent/CN106964391A/zh active Pending
- 2012-10-22 JP JP2014536285A patent/JP6180421B2/ja active Active
- 2012-10-22 EA EA201400487A patent/EA027722B1/ru unknown
- 2012-10-22 WO PCT/EP2012/070897 patent/WO2013057319A2/en active Application Filing
- 2012-10-22 AU AU2012324802A patent/AU2012324802B2/en active Active
- 2012-10-22 BR BR112014009541-8A patent/BR112014009541B1/pt active IP Right Grant
- 2012-10-22 CN CN201280051673.9A patent/CN103889577B/zh active Active
- 2012-10-22 CA CA2851988A patent/CA2851988C/en active Active
- 2012-10-22 GB GB1408450.3A patent/GB2513488A/en not_active Withdrawn
-
2014
- 2014-05-15 ZA ZA2014/03535A patent/ZA201403535B/en unknown
-
2016
- 2016-10-03 ZA ZA2016/06806A patent/ZA201606806B/en unknown
-
2017
- 2017-02-16 AU AU2017201067A patent/AU2017201067B2/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02172813A (ja) * | 1988-11-23 | 1990-07-04 | Shell Internatl Res Maatschappij Bv | 塩基性金属ゼオライト組成物、その製造方法および塩基触媒反応におけるその使用 |
JPH07316120A (ja) * | 1994-05-23 | 1995-12-05 | Tonen Corp | 2−フェニルブチロニトリルの製造方法 |
JP2003511230A (ja) * | 1999-10-12 | 2003-03-25 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | フィッシャー−トロプシュタイプの炭化水素合成触媒の調製およびその使用 |
JP2006263614A (ja) * | 2005-03-24 | 2006-10-05 | Nippon Steel Corp | 合成ガスから炭化水素を製造する触媒及び触媒の製造方法、並びに当該触媒を用いた合成ガスから炭化水素を製造する方法 |
JP2009106863A (ja) * | 2007-10-30 | 2009-05-21 | Toyama Univ | Ft合成用触媒及びft合成方法 |
WO2011042451A1 (de) * | 2009-10-08 | 2011-04-14 | Basf Se | Verfahren zur herstellung eines si-gebundenen wirbelschicht-katalysators |
GB2475492A (en) * | 2009-11-18 | 2011-05-25 | Gtl F1 Ag | Fischer-Tropsch catalyst with an alkaline earth metal content of less than 2000 ppm |
Cited By (73)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017523113A (ja) * | 2014-07-23 | 2017-08-17 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | Sda非存在下におけるゼオライト転換及び金属内包 |
KR20190018652A (ko) * | 2016-05-25 | 2019-02-25 | 더 리전츠 오브 더 유니버시티 오브 캘리포니아 | 캡슐화된 바이메탈 클러스터를 갖는 제올라이트성 물질 |
JP7060523B2 (ja) | 2016-05-25 | 2022-04-26 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | 封入された二元金属クラスターを有するゼオライト材料 |
KR102374452B1 (ko) * | 2016-05-25 | 2022-03-16 | 더 리전츠 오브 더 유니버시티 오브 캘리포니아 | 캡슐화된 바이메탈 클러스터를 갖는 제올라이트성 물질 |
JP2019523204A (ja) * | 2016-05-25 | 2019-08-22 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア | 封入された二元金属クラスターを有するゼオライト材料 |
JP2018158279A (ja) * | 2017-03-22 | 2018-10-11 | 岩谷産業株式会社 | 炭化水素合成触媒、炭化水素合成触媒の製造方法、炭化水素製造装置、炭化水素製造方法 |
US11680211B2 (en) | 2017-05-31 | 2023-06-20 | Furukawa Electric Co., Ltd. | Structured catalyst for hydrodesulfurization, hydrodesulfurization device including the structured catalyst, and method for producing structured catalyst for hydrodesulfurization |
JPWO2018221698A1 (ja) * | 2017-05-31 | 2020-04-02 | 古河電気工業株式会社 | Coシフトもしくは逆シフト触媒構造体及びその製造方法、coシフトまたは逆シフト反応装置、二酸化炭素と水素の製造方法、並びに一酸化炭素と水の製造方法 |
WO2018221698A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | Coシフトもしくは逆シフト触媒構造体及びその製造方法、coシフトまたは逆シフト反応装置、二酸化炭素と水素の製造方法、並びに一酸化炭素と水の製造方法 |
JP2018202387A (ja) * | 2017-05-31 | 2018-12-27 | 国立大学法人北海道大学 | 機能性構造体およびその製造方法 |
US11904306B2 (en) | 2017-05-31 | 2024-02-20 | Furukawa Electric Co., Ltd. | Catalyst structure and method for producing the catalyst structure |
JP7382828B2 (ja) | 2017-05-31 | 2023-11-17 | 古河電気工業株式会社 | 合成ガス製造用触媒構造体、該合成ガス製造用触媒構造体を備える合成ガス製造装置及び合成ガス製造用触媒構造体の製造方法 |
WO2018221697A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | 合成ガス製造用触媒構造体、該合成ガス製造用触媒構造体を備える合成ガス製造装置及び合成ガス製造用触媒構造体の製造方法 |
JP7361604B2 (ja) | 2017-05-31 | 2023-10-16 | 古河電気工業株式会社 | フィッシャー・トロプシュ合成触媒構造体、その製造方法及び該触媒構造体を用いた液体炭化水素の製造方法、並びに該触媒構造体を有する炭化水素製造装置 |
JP7352909B2 (ja) | 2017-05-31 | 2023-09-29 | 国立大学法人北海道大学 | 機能性構造体及び機能性構造体の製造方法 |
JP7348836B2 (ja) | 2017-05-31 | 2023-09-21 | 古河電気工業株式会社 | 流動接触分解用構造体及びその製造方法、並びに、これを備える流動接触分解用装置 |
JP7340198B2 (ja) | 2017-05-31 | 2023-09-07 | 国立大学法人北海道大学 | 機能性構造体及び機能性構造体の製造方法 |
JPWO2018221707A1 (ja) * | 2017-05-31 | 2020-03-26 | 古河電気工業株式会社 | 水蒸気改質用触媒構造体、該水蒸気改質用触媒構造体を備える改質装置、及び水蒸気改質用触媒構造体の製造方法 |
JPWO2018221700A1 (ja) * | 2017-05-31 | 2020-03-26 | 古河電気工業株式会社 | フィッシャー・トロプシュ合成触媒構造体、その製造方法及び該触媒構造体を用いた液体炭化水素の製造方法、並びに該触媒構造体を有する炭化水素製造装置 |
JP7328145B2 (ja) | 2017-05-31 | 2023-08-16 | 古河電気工業株式会社 | 水蒸気改質用触媒構造体、該水蒸気改質用触媒構造体を備える改質装置、及び水蒸気改質用触媒構造体の製造方法 |
JPWO2018221699A1 (ja) * | 2017-05-31 | 2020-04-02 | 古河電気工業株式会社 | アンモニア合成触媒構造体及びその製造方法、アンモニア合成装置並びにアンモニアの合成方法 |
JPWO2018221697A1 (ja) * | 2017-05-31 | 2020-04-02 | 古河電気工業株式会社 | 合成ガス製造用触媒構造体、該合成ガス製造用触媒構造体を備える合成ガス製造装置及び合成ガス製造用触媒構造体の製造方法 |
JPWO2018221695A1 (ja) * | 2017-05-31 | 2020-04-02 | 古河電気工業株式会社 | 流動接触分解用構造体及びその製造方法、並びに、これを備える流動接触分解用装置 |
JP7323115B2 (ja) | 2017-05-31 | 2023-08-08 | 国立大学法人北海道大学 | 機能性構造体およびその製造方法 |
JPWO2018221692A1 (ja) * | 2017-05-31 | 2020-05-28 | 国立大学法人北海道大学 | 機能性構造体及び機能性構造体の製造方法 |
JP7306990B2 (ja) | 2017-05-31 | 2023-07-11 | 古河電気工業株式会社 | Coシフトもしくは逆シフト触媒構造体及びその製造方法、coシフトまたは逆シフト反応装置、二酸化炭素と水素の製造方法、並びに一酸化炭素と水の製造方法 |
US11684909B2 (en) | 2017-05-31 | 2023-06-27 | Furukawa Electric Co., Ltd. | Structured catalyst for methanol reforming, methanol reforming device, method for producing structured catalyst for methanol reforming, and method for producing at least one of olefin or aromatic hydrocarbon |
WO2018221700A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | フィッシャー・トロプシュ合成触媒構造体、その製造方法及び該触媒構造体を用いた液体炭化水素の製造方法、並びに該触媒構造体を有する炭化水素製造装置 |
US11666894B2 (en) | 2017-05-31 | 2023-06-06 | Furukawa Electric Co., Ltd. | Structured catalyst for CO shift or reverse shift and method for producing same, CO shift or reverse shift reactor, method for producing carbon dioxide and hydrogen, and method for producing carbon monoxide and water |
JP7282026B2 (ja) | 2017-05-31 | 2023-05-26 | 古河電気工業株式会社 | アンモニア合成触媒構造体及びその製造方法、アンモニア合成装置並びにアンモニアの合成方法 |
US11655157B2 (en) | 2017-05-31 | 2023-05-23 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11654422B2 (en) | 2017-05-31 | 2023-05-23 | Furukawa Electric Co., Ltd. | Structured catalyst for catalytic cracking or hydrodesulfurization, catalytic cracking apparatus and hydrodesulfurization apparatus including the structured catalyst, and method for producing structured catalyst for catalytic cracking or hydrodesulfurization |
US11648538B2 (en) | 2017-05-31 | 2023-05-16 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11648542B2 (en) | 2017-05-31 | 2023-05-16 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
US11648543B2 (en) | 2017-05-31 | 2023-05-16 | National University Corporation Hokkaido University | Functional structural body and method for making functional structural body |
AU2018276618B2 (en) * | 2017-05-31 | 2021-05-27 | Furukawa Electric Co., Ltd. | Functional structure and production method for functional structure |
US11547987B2 (en) | 2017-05-31 | 2023-01-10 | Furukawa Electric Co., Ltd. | Structured catalyst for oxidation for exhaust gas purification, method for producing same, automobile exhaust gas treatment device, catalytic molding, and gas purification method |
WO2018221707A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | 水蒸気改質用触媒構造体、該水蒸気改質用触媒構造体を備える改質装置、及び水蒸気改質用触媒構造体の製造方法 |
WO2018221692A1 (ja) * | 2017-05-31 | 2018-12-06 | 国立大学法人北海道大学 | 機能性構造体及び機能性構造体の製造方法 |
WO2018221695A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | 流動接触分解用構造体及びその製造方法、並びに、これを備える流動接触分解用装置 |
JPWO2018221691A1 (ja) * | 2017-05-31 | 2020-05-21 | 国立大学法人北海道大学 | 機能性構造体及び機能性構造体の製造方法 |
WO2018221699A1 (ja) * | 2017-05-31 | 2018-12-06 | 古河電気工業株式会社 | アンモニア合成触媒構造体及びその製造方法、アンモニア合成装置並びにアンモニアの合成方法 |
US11161101B2 (en) | 2017-05-31 | 2021-11-02 | Furukawa Electric Co., Ltd. | Catalyst structure and method for producing the catalyst structure |
US11673126B2 (en) | 2017-06-27 | 2023-06-13 | Toyota Jidosha Kabushiki Kaisha | Cluster-supporting porous carrier and method for producing same |
WO2019004318A1 (ja) * | 2017-06-27 | 2019-01-03 | トヨタ自動車株式会社 | クラスター担持多孔質担体及びその製造方法 |
JP2019005720A (ja) * | 2017-06-27 | 2019-01-17 | トヨタ自動車株式会社 | クラスター担持触媒及びその製造方法 |
JPWO2019004318A1 (ja) * | 2017-06-27 | 2019-11-07 | トヨタ自動車株式会社 | クラスター担持多孔質担体及びその製造方法 |
US11684907B2 (en) | 2018-07-04 | 2023-06-27 | Sk Gas Co., Ltd. | Catalyst having enhanced conversion and selectivity for manufacturing olefin, and manufacturing method therof |
WO2020009318A1 (ko) * | 2018-07-04 | 2020-01-09 | 에스케이가스 주식회사 | 전환율 및 선택도가 향상된 올레핀 제조용 촉매 및 그 제조방법 |
JPWO2020027321A1 (ja) * | 2018-08-03 | 2021-08-19 | 古河電気工業株式会社 | 軽質炭化水素合成触媒構造体、軽質炭化水素製造装置及び軽質炭化水素の製造方法 |
JP7407713B2 (ja) | 2018-08-03 | 2024-01-04 | 古河電気工業株式会社 | 軽質炭化水素合成触媒構造体、軽質炭化水素製造装置及び軽質炭化水素の製造方法 |
WO2020027321A1 (ja) * | 2018-08-03 | 2020-02-06 | 古河電気工業株式会社 | 軽質炭化水素合成触媒構造体、軽質炭化水素製造装置及び軽質炭化水素の製造方法 |
JP7449525B2 (ja) | 2018-12-03 | 2024-03-14 | 国立大学法人北海道大学 | 機能性構造体及びその製造方法 |
WO2020116478A1 (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | 炭化水素の製造装置および炭化水素の製造方法 |
JP2020089813A (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | フィッシャー・トロプシュ合成触媒構造体およびその製造方法、ならびに該触媒構造体を用いた炭化水素の製造方法 |
WO2020116472A1 (ja) * | 2018-12-03 | 2020-06-11 | 国立大学法人北海道大学 | 機能性構造体 |
JP2020089814A (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | フィッシャー・トロプシュ合成触媒構造体およびその製造方法、ならびに該触媒構造体を用いた炭化水素の製造方法 |
WO2020116474A1 (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | 低級オレフィン含有ガスの製造装置および低級オレフィン含有ガスの製造方法 |
JPWO2020116478A1 (ja) * | 2018-12-03 | 2021-10-21 | 古河電気工業株式会社 | 炭化水素の製造装置および炭化水素の製造方法 |
JPWO2020116474A1 (ja) * | 2018-12-03 | 2021-10-21 | 古河電気工業株式会社 | 低級オレフィン含有ガスの製造装置および低級オレフィン含有ガスの製造方法 |
JPWO2020116473A1 (ja) * | 2018-12-03 | 2021-10-21 | 古河電気工業株式会社 | 合成ガス製造用触媒構造体及びその前駆体並びに合成ガス製造装置及び合成ガス製造用触媒構造体の製造方法 |
JP2020089810A (ja) * | 2018-12-03 | 2020-06-11 | 国立大学法人北海道大学 | 機能性構造体及びその製造方法 |
JP2020089811A (ja) * | 2018-12-03 | 2020-06-11 | 国立大学法人北海道大学 | 機能性構造体、触媒、エチレンガス酸化用触媒 |
WO2020116470A1 (ja) * | 2018-12-03 | 2020-06-11 | 国立大学法人北海道大学 | 機能性構造体 |
JP7353751B2 (ja) | 2018-12-03 | 2023-10-02 | 古河電気工業株式会社 | フィッシャー・トロプシュ合成触媒構造体およびその製造方法、ならびに該触媒構造体を用いた炭化水素の製造方法 |
US11925930B2 (en) | 2018-12-03 | 2024-03-12 | Furukawa Electric Co., Ltd. | Apparatus for producing lower olefin-containing gas and method for producing lower olefin-containing gas |
JPWO2020116476A1 (ja) * | 2018-12-03 | 2021-10-14 | 古河電気工業株式会社 | 炭化水素の製造装置および炭化水素の製造方法 |
WO2020116473A1 (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | 合成ガス製造用触媒構造体及びその前駆体並びに合成ガス製造装置及び合成ガス製造用触媒構造体の製造方法 |
WO2020116476A1 (ja) * | 2018-12-03 | 2020-06-11 | 古河電気工業株式会社 | 炭化水素の製造装置および炭化水素の製造方法 |
US11795121B2 (en) | 2020-03-23 | 2023-10-24 | Ihi Corporation | Hydrocarbon generation system and hydrocarbon generation method |
JPWO2021193438A1 (ja) * | 2020-03-23 | 2021-09-30 | ||
JP2023013551A (ja) * | 2021-07-16 | 2023-01-26 | 本田技研工業株式会社 | 二酸化炭素還元触媒 |
JP7361072B2 (ja) | 2021-07-16 | 2023-10-13 | 本田技研工業株式会社 | 二酸化炭素還元触媒 |
Also Published As
Publication number | Publication date |
---|---|
AU2017201067A1 (en) | 2017-03-09 |
ZA201606806B (en) | 2019-01-30 |
GB201408450D0 (en) | 2014-06-25 |
AU2012324802A1 (en) | 2014-06-05 |
GB2513488A (en) | 2014-10-29 |
CN103889577B (zh) | 2017-05-03 |
BR112014009541A2 (pt) | 2017-04-18 |
CN106964391A (zh) | 2017-07-21 |
AU2012324802B2 (en) | 2017-01-12 |
JP6180421B2 (ja) | 2017-08-16 |
AU2012324802A8 (en) | 2014-07-17 |
CA2851988A1 (en) | 2013-04-25 |
ZA201403535B (en) | 2018-11-28 |
EP2768612A2 (en) | 2014-08-27 |
CA2851988C (en) | 2019-05-21 |
WO2013057319A3 (en) | 2013-06-06 |
EA027722B1 (ru) | 2017-08-31 |
WO2013057319A2 (en) | 2013-04-25 |
CN103889577A (zh) | 2014-06-25 |
EA201400487A1 (ru) | 2014-11-28 |
AU2017201067B2 (en) | 2018-11-08 |
BR112014009541B1 (pt) | 2019-08-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6180421B2 (ja) | 担持活性金属触媒および前駆体を製造および形成する方法 | |
US9908110B2 (en) | Methods of preparation and forming supported active metal catalysts and precursors | |
KR101539784B1 (ko) | 게르마늄-제올라이트 촉매를 이용한 알칸의 방향족화 | |
AU2009215687B2 (en) | Process for the conversion of ethane to aromatic hydrocarbons | |
De Cola et al. | Non-oxidative propane dehydrogenation over Pt–Zn-containing zeolites | |
TWI375592B (en) | Heavy aromatics conversion catalyst composition and processes therefor and therewith | |
TW200950883A (en) | Hydroisomerization catalyst, process for producing the same, method of dewaxing hydrocarbon oil, and process for producing lube base oil | |
EA018593B1 (ru) | Способ получения модифицированных молекулярных сит | |
JP2013511591A (ja) | コバルト担持ゼオライトのハイブリッドフィッシャー・トロプシュ触媒 | |
CN108816271B (zh) | ZnO改性全硅沸石分子筛负载Pt催化剂及制备方法和应用 | |
JP7041883B2 (ja) | Lpg合成用触媒 | |
Zhang et al. | Total oxidation of toluene and propane over supported Co3O4 catalysts: effect of structure/acidity of MWW zeolite and cobalt loading | |
RU2425091C1 (ru) | Способ получения высокооктанового бензина и/или ароматических углеводородов с низким содержанием бензола | |
CN106925339B (zh) | 用于碳八芳烃中二甲苯异构化反应的多级孔分子筛催化剂的制备方法 | |
RU2372988C1 (ru) | Катализатор для превращения алифатических углеводородов c2-c12 и/или алифатических кислородсодержащих соединений c1-c12, способ его получения и способ получения высокооктанового бензина или ароматических углеводородов | |
JP6979615B2 (ja) | 低級オレフィンの製造方法 | |
Wu et al. | Si-modified Cs/Al2O3 for aldol condensation of methyl acetate with formaldehyde to methyl acrylate by chemical liquid deposition | |
EP3145865B1 (en) | Processes using molecular sieve ssz-95 | |
RU2799070C1 (ru) | Мезопористый биметаллический катализатор синтеза фишера-тропша | |
RU2775691C1 (ru) | Катализатор для синтеза углеводородов из co и h2 и способ его получения | |
CA2962095C (en) | Forming light hydrocarbons | |
CN105582975B (zh) | 一种改性沸石催化剂及其在异丙基甲苯裂解制甲苯中的应用 | |
JP2008169356A (ja) | 液体燃料の製造方法 | |
JP2000256674A (ja) | 軽質接触改質油の低ベンゼン高オクタン価ガソリン基材化方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20151019 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20151019 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20160219 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20160905 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160913 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20161118 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170207 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20170307 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170602 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20170620 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20170718 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6180421 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |