GB2513488A - Methods of preparation and forming supported active metal catalysts and precursors - Google Patents
Methods of preparation and forming supported active metal catalysts and precursors Download PDFInfo
- Publication number
- GB2513488A GB2513488A GB1408450.3A GB201408450A GB2513488A GB 2513488 A GB2513488 A GB 2513488A GB 201408450 A GB201408450 A GB 201408450A GB 2513488 A GB2513488 A GB 2513488A
- Authority
- GB
- United Kingdom
- Prior art keywords
- active metal
- precursors
- preparation
- methods
- metal catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003054 catalyst Substances 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 4
- 239000002184 metal Substances 0.000 title abstract 3
- 239000002243 precursor Substances 0.000 title 1
- 239000011148 porous material Substances 0.000 abstract 4
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
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- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/38—Base treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
- B01J2523/13—Potassium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
- B01J2523/17—Copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
- B01J2523/31—Aluminium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
- B01J2523/37—Lanthanides
- B01J2523/3712—Cerium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
- B01J2523/41—Silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
- B01J2523/84—Metals of the iron group
- B01J2523/842—Iron
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- Chemical & Material Sciences (AREA)
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- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The invention relates to a method of preparing a supported catalyst, which method comprises the steps of; (i) providing a porous catalyst support comprising a framework having an internal pore structure comprising one or more pores which internal pore structure comprises a precipitant; (ii) contacting the catalyst support with a solution or colloidal suspension comprising a catalytically active metal such that, on contact with the precipitant, particles comprising the catalytically active metal are precipitated within the internal pore structure of the framework of the catalyst support. The invention also relates to supported catalysts made according to the above method, and to use of the catalysts in catalysing chemical reactions, for example in the Fischer Tropsch synthesis of hydrocarbons.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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GB201118228A GB201118228D0 (en) | 2011-10-21 | 2011-10-21 | Methods of preparation and forming supported active metal catalysts and precursors |
GB2012000803 | 2012-10-19 | ||
PCT/EP2012/070897 WO2013057319A2 (en) | 2011-10-21 | 2012-10-22 | Methods of preparation and forming supported active metal catalysts and precursors |
Publications (2)
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GB201408450D0 GB201408450D0 (en) | 2014-06-25 |
GB2513488A true GB2513488A (en) | 2014-10-29 |
Family
ID=47148735
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GB1408450.3A Withdrawn GB2513488A (en) | 2011-10-21 | 2012-10-22 | Methods of preparation and forming supported active metal catalysts and precursors |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2768612A2 (en) |
JP (1) | JP6180421B2 (en) |
CN (2) | CN103889577B (en) |
AU (2) | AU2012324802B2 (en) |
BR (1) | BR112014009541B1 (en) |
CA (1) | CA2851988C (en) |
EA (1) | EA027722B1 (en) |
GB (1) | GB2513488A (en) |
WO (1) | WO2013057319A2 (en) |
ZA (2) | ZA201403535B (en) |
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WO2009051353A2 (en) * | 2007-10-15 | 2009-04-23 | Korea Research Institute Of Chemical Technology | Method of direct synthesis of light hydrocarbons from natural gas |
US20100168258A1 (en) * | 2008-12-29 | 2010-07-01 | Chevron U.S.A Inc. | Preparation of Cobalt-Ruthenium/zeolite fischer-tropsch catalysts |
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US11680211B2 (en) | 2017-05-31 | 2023-06-20 | Furukawa Electric Co., Ltd. | Structured catalyst for hydrodesulfurization, hydrodesulfurization device including the structured catalyst, and method for producing structured catalyst for hydrodesulfurization |
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AU2012324802B2 (en) | 2017-01-12 |
AU2017201067B2 (en) | 2018-11-08 |
ZA201606806B (en) | 2019-01-30 |
JP6180421B2 (en) | 2017-08-16 |
EA201400487A1 (en) | 2014-11-28 |
WO2013057319A3 (en) | 2013-06-06 |
EA027722B1 (en) | 2017-08-31 |
GB201408450D0 (en) | 2014-06-25 |
BR112014009541A2 (en) | 2017-04-18 |
CN103889577B (en) | 2017-05-03 |
AU2012324802A8 (en) | 2014-07-17 |
EP2768612A2 (en) | 2014-08-27 |
CA2851988C (en) | 2019-05-21 |
CA2851988A1 (en) | 2013-04-25 |
WO2013057319A2 (en) | 2013-04-25 |
AU2017201067A1 (en) | 2017-03-09 |
BR112014009541B1 (en) | 2019-08-06 |
JP2014534902A (en) | 2014-12-25 |
CN103889577A (en) | 2014-06-25 |
CN106964391A (en) | 2017-07-21 |
ZA201403535B (en) | 2018-11-28 |
AU2012324802A1 (en) | 2014-06-05 |
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