JP2011516709A5 - - Google Patents
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- Publication number
- JP2011516709A5 JP2011516709A5 JP2011504420A JP2011504420A JP2011516709A5 JP 2011516709 A5 JP2011516709 A5 JP 2011516709A5 JP 2011504420 A JP2011504420 A JP 2011504420A JP 2011504420 A JP2011504420 A JP 2011504420A JP 2011516709 A5 JP2011516709 A5 JP 2011516709A5
- Authority
- JP
- Japan
- Prior art keywords
- acid
- aliphatic
- component
- group
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229920000728 polyester Polymers 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 6
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 5
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 4
- 230000003068 static effect Effects 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 2
- 210000000707 wrist Anatomy 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 21
- 125000001931 aliphatic group Chemical group 0.000 claims 17
- 239000000203 mixture Substances 0.000 claims 13
- -1 aromatic dicarboxylic acids Chemical class 0.000 claims 11
- 150000001875 compounds Chemical class 0.000 claims 11
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 9
- 229920000229 biodegradable polyester Polymers 0.000 claims 9
- 239000004622 biodegradable polyester Substances 0.000 claims 9
- 150000002148 esters Chemical class 0.000 claims 7
- 239000003054 catalyst Substances 0.000 claims 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims 4
- 239000002861 polymer material Substances 0.000 claims 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 3
- 150000002009 diols Chemical class 0.000 claims 3
- 230000032050 esterification Effects 0.000 claims 3
- 238000005886 esterification reaction Methods 0.000 claims 3
- 239000000314 lubricant Substances 0.000 claims 3
- 238000005809 transesterification reaction Methods 0.000 claims 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims 2
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 claims 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims 2
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 claims 2
- 239000004970 Chain extender Substances 0.000 claims 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 239000001361 adipic acid Substances 0.000 claims 2
- 235000011037 adipic acid Nutrition 0.000 claims 2
- 229920003232 aliphatic polyester Polymers 0.000 claims 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 2
- 150000001718 carbodiimides Chemical class 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 150000002118 epoxides Chemical class 0.000 claims 2
- 235000011187 glycerol Nutrition 0.000 claims 2
- 239000004615 ingredient Substances 0.000 claims 2
- 239000002667 nucleating agent Substances 0.000 claims 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 2
- 239000011574 phosphorus Substances 0.000 claims 2
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims 2
- 229920000747 poly(lactic acid) Polymers 0.000 claims 2
- 229920001610 polycaprolactone Polymers 0.000 claims 2
- 239000004632 polycaprolactone Substances 0.000 claims 2
- 229920000903 polyhydroxyalkanoate Polymers 0.000 claims 2
- 239000004626 polylactic acid Substances 0.000 claims 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 claims 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 claims 1
- 229920000954 Polyglycolide Polymers 0.000 claims 1
- 229920002472 Starch Polymers 0.000 claims 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 229960002684 aminocaproic acid Drugs 0.000 claims 1
- 230000001588 bifunctional effect Effects 0.000 claims 1
- 229920002988 biodegradable polymer Polymers 0.000 claims 1
- 239000004621 biodegradable polymer Substances 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical group CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 239000011552 falling film Substances 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 238000011065 in-situ storage Methods 0.000 claims 1
- 239000012948 isocyanate Substances 0.000 claims 1
- 150000002513 isocyanates Chemical class 0.000 claims 1
- 150000003951 lactams Chemical class 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims 1
- 239000004633 polyglycolic acid Substances 0.000 claims 1
- 239000002516 radical scavenger Substances 0.000 claims 1
- 239000008107 starch Substances 0.000 claims 1
- 235000019698 starch Nutrition 0.000 claims 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08154541.0 | 2008-04-15 | ||
| EP08154541 | 2008-04-15 | ||
| PCT/EP2009/054116 WO2009127556A1 (de) | 2008-04-15 | 2009-04-07 | Verfahren zur kontinuierlichen herstellung von biologisch abbaubaren polyestern |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011516709A JP2011516709A (ja) | 2011-05-26 |
| JP2011516709A5 true JP2011516709A5 (enExample) | 2013-10-24 |
| JP5675587B2 JP5675587B2 (ja) | 2015-02-25 |
Family
ID=40790978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011504420A Active JP5675587B2 (ja) | 2008-04-15 | 2009-04-07 | 生分解可能なポリエステルを連続的に製造する方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US8614280B2 (enExample) |
| EP (1) | EP2268702B1 (enExample) |
| JP (1) | JP5675587B2 (enExample) |
| KR (1) | KR101543489B1 (enExample) |
| CN (1) | CN102007159B (enExample) |
| BR (1) | BRPI0911045B8 (enExample) |
| ES (1) | ES2397765T3 (enExample) |
| MX (1) | MX2010011149A (enExample) |
| WO (1) | WO2009127556A1 (enExample) |
Families Citing this family (118)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110187029A1 (en) * | 2008-09-29 | 2011-08-04 | Basf Se | Aliphatic-aromatic polyester |
| EP2350162B1 (de) | 2008-09-29 | 2017-11-15 | Basf Se | Aliphatische polyester |
| WO2010034689A1 (de) | 2008-09-29 | 2010-04-01 | Basf Se | Biologisch abbaubare polymermischung |
| EP2331602B2 (de) † | 2008-09-29 | 2017-11-01 | Basf Se | Verfahren zur beschichtung von papier |
| US8691127B2 (en) | 2008-12-19 | 2014-04-08 | Basf Se | Method for producing a composite component by multi-component injection molding |
| KR101760965B1 (ko) | 2009-10-15 | 2017-07-24 | 바스프 에스이 | 폴리에스테르 혼합물의 연속 제조 방법 |
| US8658069B2 (en) | 2009-11-09 | 2014-02-25 | Basf Se | Method for producing shrink films |
| ES2558062T3 (es) | 2010-01-14 | 2016-02-01 | Basf Se | Método para la producción de granulados que contienen poliácido láctico que pueden expandirse |
| US20110237750A1 (en) * | 2010-03-24 | 2011-09-29 | Basf Se | Process for film production |
| US20110237743A1 (en) * | 2010-03-24 | 2011-09-29 | Basf Se | Process for producing clingfilms |
| CA2791220A1 (en) * | 2010-03-24 | 2011-09-29 | Basf Se | Process for producing aqueous dispersions of thermoplastic polyesters |
| CA2792845A1 (en) | 2010-03-24 | 2011-09-29 | Basf Se | Process for producing clingfilms |
| US8604101B2 (en) | 2010-03-24 | 2013-12-10 | Basf Se | Process for producing aqueous dispersions of thermoplastic polyesters |
| KR20130008592A (ko) | 2010-03-24 | 2013-01-22 | 바스프 에스이 | 필름 제조 방법 |
| ES2734266T3 (es) * | 2010-07-29 | 2019-12-05 | Basf Se | Películas compuestas biológicamente desintegrables |
| CN101979423B (zh) * | 2010-10-15 | 2012-02-22 | 济南大学 | 一种水基聚合物-聚氨酯预聚物制备方法和应用 |
| EP2632985B1 (de) | 2010-10-27 | 2015-01-28 | Basf Se | Verwendung von polymermischungen zur herstellung von folienbändchen |
| TWI405778B (zh) * | 2010-11-04 | 2013-08-21 | Far Eastern New Century Corp | A copolyester composition having thermal stability |
| CN102477153B (zh) * | 2010-11-23 | 2014-01-08 | 远东新世纪股份有限公司 | 具有热安定性的共聚酯组成物 |
| WO2012113744A1 (de) | 2011-02-23 | 2012-08-30 | Basf Se | Polyesterfolie enthaltend nährsalze |
| US8546472B2 (en) | 2011-03-23 | 2013-10-01 | Basf Se | Polyesters based on 2-methylsuccinic acid |
| EP2688956A1 (de) | 2011-03-23 | 2014-01-29 | Basf Se | Polyester auf basis von 2-methylbernsteinsaeure |
| KR101068030B1 (ko) * | 2011-06-03 | 2011-09-28 | 주식회사 지오솔테크 | 내가수분해성 및 생분해성 지방족/방향족 코폴리에스테르 수지 조성물 |
| KR101200823B1 (ko) | 2011-06-03 | 2012-11-13 | 주식회사 지오솔테크 | 내가수분해성 및 생분해성 지방족 폴리에스테르수지 조성물 |
| CN102863626B (zh) * | 2011-07-07 | 2014-04-16 | 中国石油化工股份有限公司 | 一种生物质改性聚合物及其制备方法和应用 |
| US9334360B2 (en) | 2011-07-15 | 2016-05-10 | Sabic Global Technologies B.V. | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| US8933162B2 (en) * | 2011-07-15 | 2015-01-13 | Saudi Basic Industries Corporation | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| US8946345B2 (en) | 2011-08-30 | 2015-02-03 | Saudi Basic Industries Corporation | Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst |
| KR20130027095A (ko) * | 2011-09-02 | 2013-03-15 | 삼성정밀화학 주식회사 | 생분해성 폴리에스테르 공중합체 수지의 제조방법 |
| EP2573142A1 (de) | 2011-09-21 | 2013-03-27 | Basf Se | Thermoplastische Formmasse mit verbesserter Kerbschlagzähigkeit |
| EP2573138A1 (de) | 2011-09-21 | 2013-03-27 | Basf Se | Polyamid-Formmassen |
| WO2013101992A1 (en) * | 2011-12-28 | 2013-07-04 | E. I. Du Pont De Nemours And Company | Copolyester blends with improved melt strength |
| US8889820B2 (en) | 2012-02-15 | 2014-11-18 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
| US8969506B2 (en) | 2012-02-15 | 2015-03-03 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
| US8901273B2 (en) | 2012-02-15 | 2014-12-02 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
| DE102012003417A1 (de) | 2012-02-17 | 2013-08-22 | Uhde Inventa-Fischer Gmbh | Verfahren zur Herstellung eines hochmolekularen, heteroaromatischen Polyesters oder Copolyesters |
| EP2628761B1 (en) | 2012-02-17 | 2015-04-15 | Sociedad Anónima Minera Catalano-Aragonesa | Biodegradable polyesteretheramide |
| US8895660B2 (en) | 2012-03-01 | 2014-11-25 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture, and uses thereof |
| US9034983B2 (en) * | 2012-03-01 | 2015-05-19 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof |
| US9828461B2 (en) | 2012-03-01 | 2017-11-28 | Sabic Global Technologies B.V. | Poly(alkylene co-adipate terephthalate) prepared from recycled polyethylene terephthalate having low impurity levels |
| US8901243B2 (en) | 2012-03-30 | 2014-12-02 | Saudi Basic Industries Corporation | Biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| WO2013153147A1 (en) * | 2012-04-11 | 2013-10-17 | Novamont S.P.A. | Polyesters comprising 2-methylglutaric acid, process for production of the said polyesters and products obtained therewith |
| US9540661B2 (en) | 2012-07-09 | 2017-01-10 | Basf Se | Method for the complete anaerobic digestion of polymer mixtures |
| WO2014009176A1 (de) | 2012-07-10 | 2014-01-16 | Basf Se | Verfahren zum vollständigen anaeroben abbau von polymermischungen |
| KR20140018468A (ko) * | 2012-07-30 | 2014-02-13 | 삼성정밀화학 주식회사 | 방향족 디카르복실산 화합물의 분할 투입에 의한 생분해성 폴리에스테르 공중합체의 제조방법 |
| KR20140024503A (ko) * | 2012-08-17 | 2014-03-03 | 삼성정밀화학 주식회사 | 내가수분해성이 향상된 생분해성 지방족-방향족 폴리에스테르 공중합체 수지의 제조방법 |
| KR20140031011A (ko) | 2012-09-04 | 2014-03-12 | 삼성정밀화학 주식회사 | 생분해성 지방족 폴리에스테르의 연속 제조방법 |
| KR101992391B1 (ko) * | 2012-09-04 | 2019-09-30 | (주)새한폴리머 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
| ES2599165T3 (es) * | 2012-10-29 | 2017-01-31 | Uhde Inventa-Fischer Gmbh | Procedimiento para la preparación de un poliéster o un copoliéster de alto peso molecular así como mezclas poliméricas que los contienen |
| US9056979B2 (en) | 2012-11-15 | 2015-06-16 | Basf Se | Biodegradable polyester mixture |
| WO2014075998A1 (de) * | 2012-11-15 | 2014-05-22 | Basf Se | Biologisch abbaubare polyestermischung |
| KR20140065279A (ko) * | 2012-11-21 | 2014-05-29 | 삼성정밀화학 주식회사 | 생분해성 폴리에스테르계 중합체의 제조방법 및 이러한 방법으로 제조된 생분해성 폴리에스테르계 중합체 |
| KR20140076354A (ko) * | 2012-12-12 | 2014-06-20 | 삼성정밀화학 주식회사 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
| KR20140076355A (ko) | 2012-12-12 | 2014-06-20 | 삼성정밀화학 주식회사 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
| JP2014114418A (ja) * | 2012-12-12 | 2014-06-26 | Mitsubishi Chemicals Corp | 脂肪族ポリエステルの製造方法 |
| KR101992392B1 (ko) | 2012-12-12 | 2019-09-30 | (주)새한폴리머 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
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| CN104968716A (zh) * | 2012-12-20 | 2015-10-07 | 陶氏环球技术有限责任公司 | 乙交酯基聚酯 |
| WO2014100257A2 (en) * | 2012-12-20 | 2014-06-26 | Dow Global Technologies Llc | Fdca-based polyesters made with isosorbide |
| CN103881072B (zh) * | 2012-12-22 | 2016-05-11 | 北京化工大学 | 可生物降解脂肪族—芳香族嵌段混合聚酯的制备方法 |
| CN103254411A (zh) * | 2013-06-07 | 2013-08-21 | 北京理工大学 | 一种高分子量聚乳酸的直接缩聚扩链制备方法 |
| CN103467713B (zh) * | 2013-09-04 | 2017-01-25 | 新疆蓝山屯河化工股份有限公司 | 低羧基生物降解聚酯及其生产方法 |
| CN103755941B (zh) * | 2014-01-08 | 2015-10-21 | 中国纺织科学研究院 | 扩链改性聚酯连续聚合的方法 |
| CN106164170B (zh) | 2014-04-02 | 2018-08-03 | 巴斯夫欧洲公司 | 聚酯混合物 |
| DE102015205191A1 (de) | 2014-04-02 | 2015-10-08 | Basf Se | Polyestermischung |
| CN104194551A (zh) * | 2014-09-28 | 2014-12-10 | 芜湖县双宝建材有限公司 | 一种阻燃耐冲击涂料 |
| CN105524258A (zh) * | 2014-10-22 | 2016-04-27 | 中国石油化工股份有限公司 | 一种生物可降解的脂肪族/芳香族共聚酯的连续生产工艺 |
| GB201418762D0 (en) * | 2014-10-22 | 2014-12-03 | Croda Int Plc | Polyesters |
| KR20160052906A (ko) * | 2014-10-29 | 2016-05-13 | 롯데정밀화학 주식회사 | 생분해성 폴리에스테르 수지의 제조방법 및 그로부터 제조된 생분해성 수지 |
| CN104725616B (zh) * | 2015-04-13 | 2017-01-11 | 南京大学 | 有机胍催化熔融-固相缩聚合成聚(己二酸-共-对苯二甲酸丁二醇酯) |
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- 2009-04-07 EP EP09733143A patent/EP2268702B1/de active Active
- 2009-04-07 MX MX2010011149A patent/MX2010011149A/es active IP Right Grant
- 2009-04-07 WO PCT/EP2009/054116 patent/WO2009127556A1/de not_active Ceased
- 2009-04-07 KR KR1020107025423A patent/KR101543489B1/ko active Active
- 2009-04-07 BR BRPI0911045A patent/BRPI0911045B8/pt not_active IP Right Cessation
- 2009-04-07 JP JP2011504420A patent/JP5675587B2/ja active Active
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