JP2011116580A5 - - Google Patents
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- Publication number
- JP2011116580A5 JP2011116580A5 JP2009274518A JP2009274518A JP2011116580A5 JP 2011116580 A5 JP2011116580 A5 JP 2011116580A5 JP 2009274518 A JP2009274518 A JP 2009274518A JP 2009274518 A JP2009274518 A JP 2009274518A JP 2011116580 A5 JP2011116580 A5 JP 2011116580A5
- Authority
- JP
- Japan
- Prior art keywords
- positive electrode
- electrode active
- active material
- particles
- composite hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002245 particle Substances 0.000 claims description 472
- 239000002131 composite material Substances 0.000 claims description 222
- 239000007774 positive electrode material Substances 0.000 claims description 189
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 188
- 239000007864 aqueous solution Substances 0.000 claims description 143
- 238000006243 chemical reaction Methods 0.000 claims description 141
- 239000011255 nonaqueous electrolyte Substances 0.000 claims description 114
- 230000006911 nucleation Effects 0.000 claims description 91
- 238000010899 nucleation Methods 0.000 claims description 91
- 238000004519 manufacturing process Methods 0.000 claims description 87
- KFDQGLPGKXUTMZ-UHFFFAOYSA-N [Mn].[Co].[Ni] Chemical compound [Mn].[Co].[Ni] KFDQGLPGKXUTMZ-UHFFFAOYSA-N 0.000 claims description 76
- 238000009826 distribution Methods 0.000 claims description 67
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 55
- 239000000203 mixture Substances 0.000 claims description 54
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 53
- 229910052744 lithium Inorganic materials 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 52
- 239000000654 additive Substances 0.000 claims description 40
- 230000000996 additive effect Effects 0.000 claims description 40
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 36
- 238000010304 firing Methods 0.000 claims description 34
- 229910052751 metal Inorganic materials 0.000 claims description 33
- 239000002184 metal Substances 0.000 claims description 30
- 239000011572 manganese Substances 0.000 claims description 26
- 230000008569 process Effects 0.000 claims description 26
- 238000002425 crystallisation Methods 0.000 claims description 25
- 239000007788 liquid Substances 0.000 claims description 24
- SOXUFMZTHZXOGC-UHFFFAOYSA-N [Li].[Mn].[Co].[Ni] Chemical compound [Li].[Mn].[Co].[Ni] SOXUFMZTHZXOGC-UHFFFAOYSA-N 0.000 claims description 22
- 230000008025 crystallization Effects 0.000 claims description 22
- 229910021529 ammonia Inorganic materials 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 19
- 239000011163 secondary particle Substances 0.000 claims description 19
- 239000000126 substance Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 150000002736 metal compounds Chemical class 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 229910052726 zirconium Inorganic materials 0.000 claims description 12
- 229910052804 chromium Inorganic materials 0.000 claims description 11
- 229910052735 hafnium Inorganic materials 0.000 claims description 11
- 229910052749 magnesium Inorganic materials 0.000 claims description 11
- 229910052750 molybdenum Inorganic materials 0.000 claims description 11
- 229910052758 niobium Inorganic materials 0.000 claims description 11
- 239000011164 primary particle Substances 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- 229910052720 vanadium Inorganic materials 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 229910052715 tantalum Inorganic materials 0.000 claims description 9
- 229910052721 tungsten Inorganic materials 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 150000002642 lithium compounds Chemical class 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 5
- 239000011149 active material Substances 0.000 claims description 3
- 238000004220 aggregation Methods 0.000 claims description 3
- 230000002776 aggregation Effects 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- MZZUATUOLXMCEY-UHFFFAOYSA-N cobalt manganese Chemical compound [Mn].[Co] MZZUATUOLXMCEY-UHFFFAOYSA-N 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
- 239000002994 raw material Substances 0.000 description 25
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 18
- 150000003839 salts Chemical class 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- -1 and the like Substances 0.000 description 15
- 239000013078 crystal Substances 0.000 description 15
- 230000007423 decrease Effects 0.000 description 15
- 239000012298 atmosphere Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 12
- 235000011114 ammonium hydroxide Nutrition 0.000 description 12
- 239000011230 binding agent Substances 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 229910021645 metal ion Inorganic materials 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000010955 niobium Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 7
- 239000011651 chromium Substances 0.000 description 7
- 229910001416 lithium ion Inorganic materials 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 6
- 239000002033 PVDF binder Substances 0.000 description 6
- 239000004020 conductor Substances 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 6
- 239000010419 fine particle Substances 0.000 description 6
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 6
- 229910052808 lithium carbonate Inorganic materials 0.000 description 6
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000006182 cathode active material Substances 0.000 description 5
- 239000008151 electrolyte solution Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 239000007773 negative electrode material Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 3
- 239000012670 alkaline solution Substances 0.000 description 3
- 239000012295 chemical reaction liquid Substances 0.000 description 3
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 3
- 229940044175 cobalt sulfate Drugs 0.000 description 3
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229940099596 manganese sulfate Drugs 0.000 description 3
- 239000011702 manganese sulphate Substances 0.000 description 3
- 235000007079 manganese sulphate Nutrition 0.000 description 3
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 3
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 3
- 229940053662 nickel sulfate Drugs 0.000 description 3
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 229910016365 Ni0.33Co0.33Mn0.33 Inorganic materials 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- PFYQFCKUASLJLL-UHFFFAOYSA-N [Co].[Ni].[Li] Chemical compound [Co].[Ni].[Li] PFYQFCKUASLJLL-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229910021383 artificial graphite Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- RSNHXDVSISOZOB-UHFFFAOYSA-N lithium nickel Chemical compound [Li].[Ni] RSNHXDVSISOZOB-UHFFFAOYSA-N 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910021382 natural graphite Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 2
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- QLOKJRIVRGCVIM-UHFFFAOYSA-N 1-[(4-methylsulfanylphenyl)methyl]piperazine Chemical compound C1=CC(SC)=CC=C1CN1CCNCC1 QLOKJRIVRGCVIM-UHFFFAOYSA-N 0.000 description 1
- YBJCDTIWNDBNTM-UHFFFAOYSA-N 1-methylsulfonylethane Chemical compound CCS(C)(=O)=O YBJCDTIWNDBNTM-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- GKZFQPGIDVGTLZ-UHFFFAOYSA-N 4-(trifluoromethyl)-1,3-dioxolan-2-one Chemical compound FC(F)(F)C1COC(=O)O1 GKZFQPGIDVGTLZ-UHFFFAOYSA-N 0.000 description 1
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 1
- 229910013131 LiN Inorganic materials 0.000 description 1
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- 229910001228 Li[Ni1/3Co1/3Mn1/3]O2 (NCM 111) Inorganic materials 0.000 description 1
- 206010024769 Local reaction Diseases 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- MYWGVEGHKGKUMM-UHFFFAOYSA-N carbonic acid;ethene Chemical compound C=C.C=C.OC(O)=O MYWGVEGHKGKUMM-UHFFFAOYSA-N 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 150000005678 chain carbonates Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- CKFRRHLHAJZIIN-UHFFFAOYSA-N cobalt lithium Chemical compound [Li].[Co] CKFRRHLHAJZIIN-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000005676 cyclic carbonates Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 1
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000002003 electrode paste Substances 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000001989 lithium alloy Substances 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- 229910021443 lithium nickel cobalt manganese complex oxide Inorganic materials 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- XNHGKSMNCCTMFO-UHFFFAOYSA-D niobium(5+);oxalate Chemical compound [Nb+5].[Nb+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O XNHGKSMNCCTMFO-UHFFFAOYSA-D 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
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| KR1020127016853A KR101478417B1 (ko) | 2009-12-02 | 2010-12-02 | 니켈 코발트 망간 복합 수산화물 입자와 그 제조방법, 비수계 전해질 이차 전지용 정극 활물질과 그 제조방법, 및 비수계 전해질 이차 전지 |
| CN201080061860.6A CN102725232B (zh) | 2009-12-02 | 2010-12-02 | 镍钴锰复合氢氧化物粒子及其制造方法、非水电解质二次电池用正极活性物质及其制造方法以及非水电解质二次电池 |
| PCT/JP2010/007035 WO2011067935A1 (ja) | 2009-12-02 | 2010-12-02 | ニッケルコバルトマンガン複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池 |
| CN201610471292.6A CN105948141A (zh) | 2009-12-02 | 2010-12-02 | 镍钴锰复合氢氧化物粒子及其制造方法、正极活性物质及其制造方法、非水电解质二次电池 |
| US13/513,244 US9954224B2 (en) | 2009-12-02 | 2010-12-02 | Nickel-cobalt-manganese complex hydroxide particles and method for producing same, positive electrode active material for nonaqueous electrolyte secondary battery and method for producing same, and nonaqueous electrolyte secondary battery |
| US15/673,650 US10490815B2 (en) | 2009-12-02 | 2017-08-10 | Nickel-cobalt-manganese complex hydroxide particles and method for producing same, positive electrode active material for nonaqueous electrolyte secondary battery and method for producing same, and nonaqueous electrolyte second battery |
| US15/918,956 US10516165B2 (en) | 2009-12-02 | 2018-03-12 | Nickel-cobalt-manganese complex hydroxide particles and method for producing same, positive electrode active material for nonaqueous electrolyte secondary battery and method for producing same, and nonaqueous electrolyte secondary battery |
| US16/592,365 US11394024B2 (en) | 2009-12-02 | 2019-10-03 | Nickel-cobalt-manganese complex hydroxide particles and method for producing same, positive electrode active material for nonaqueous electrolyte secondary battery and method for producing same, and nonaqueous electrolyte secondary battery |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5464348B2 (ja) * | 2010-02-26 | 2014-04-09 | 住友金属鉱山株式会社 | 非水系電解質二次電池正極活物質用ニッケル−コバルト複合水酸化物およびその製造方法、ならびに該ニッケル−コバルト複合水酸化物を用いた非水系電解質二次電池正極活物質の製造方法 |
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| CN102388490B (zh) | 2010-06-21 | 2014-11-12 | 丰田自动车株式会社 | 锂二次电池 |
| US8911902B2 (en) * | 2010-07-06 | 2014-12-16 | Samsung Sdi Co., Ltd. | Nickel-based positive electrode active material, method of preparing the same, and lithium battery using the nickel-based positive electrode active material |
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| JP5741899B2 (ja) * | 2010-11-18 | 2015-07-01 | トヨタ自動車株式会社 | 二次電池 |
| US9559351B2 (en) * | 2011-03-31 | 2017-01-31 | Sumitomo Metal Mining Co., Ltd. | Nickel composite hydroxide particles and nonaqueous electrolyte secondary battery |
| WO2012164752A1 (ja) * | 2011-05-30 | 2012-12-06 | 住友金属鉱山株式会社 | 非水系二次電池用正極活物質とその製造方法、ならびに該正極活物質を用いた非水系電解質二次電池 |
| US9126845B2 (en) | 2011-05-31 | 2015-09-08 | Toyota Jidosha Kabushiki Kaisha | Lithium secondary battery |
| JP5741932B2 (ja) | 2011-06-01 | 2015-07-01 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質の前駆体となる遷移金属複合水酸化物とその製造方法、及び非水系電解質二次電池用正極活物質の製造方法 |
| US10128501B2 (en) | 2011-06-07 | 2018-11-13 | Sumitomo Metal Mining Co., Ltd. | Nickel composite hydroxide and manufacturing method thereof, cathode active material for nonaqueous-electrolyte secondary battery and manufacturing method thereof, and nonaqueous-electrolyte secondary battery |
| JP4894969B1 (ja) | 2011-06-07 | 2012-03-14 | 住友金属鉱山株式会社 | ニッケルマンガン複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、ならびに、非水系電解質二次電池 |
| KR101920484B1 (ko) * | 2011-09-26 | 2019-02-11 | 전자부품연구원 | 리튬 이차전지용 양극 활물질의 전구체 및 그의 제조방법, 양극 활물질 및 이를 포함하는 리튬 이차전지 |
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| CN102347483B (zh) * | 2011-10-11 | 2014-09-24 | 上海中兴派能能源科技有限公司 | 一种多层复合三元材料及其前驱体以及它们的制备方法 |
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| JP5858279B2 (ja) | 2011-12-05 | 2016-02-10 | トヨタ自動車株式会社 | リチウムイオン二次電池 |
| KR101689212B1 (ko) * | 2011-12-07 | 2016-12-26 | 삼성에스디아이 주식회사 | 리튬 이차전지용 양극 활물질, 이의 제조방법 및 이를 포함하는 리튬 이차 전지 |
| JP5971109B2 (ja) * | 2011-12-20 | 2016-08-17 | 住友金属鉱山株式会社 | ニッケル複合水酸化物とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池 |
| JP5641362B2 (ja) * | 2011-12-26 | 2014-12-17 | トヨタ自動車株式会社 | 正極活物質の製造方法 |
| JP5682796B2 (ja) * | 2012-01-12 | 2015-03-11 | トヨタ自動車株式会社 | リチウム二次電池 |
| JP2013144625A (ja) * | 2012-01-16 | 2013-07-25 | Tanaka Chemical Corp | ニッケルコバルトマンガン複合水酸化物及びその製造方法、非水電解質二次電池用の正極活物質、並びに非水電解質二次電池 |
| JP5365711B2 (ja) * | 2012-02-21 | 2013-12-11 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物及びその製造方法 |
| CN104144880B (zh) * | 2012-02-23 | 2016-03-30 | 住友金属矿山株式会社 | 镍复合氢氧化物及其制造方法、非水电解质二次电池用正极活性物质及其制造方法以及非水电解质二次电池 |
| JP5754416B2 (ja) * | 2012-05-25 | 2015-07-29 | 住友金属鉱山株式会社 | ニッケルコバルト複合水酸化物の製造方法 |
| WO2013183711A1 (ja) | 2012-06-06 | 2013-12-12 | 住友金属鉱山株式会社 | ニッケル複合水酸化物、非水系電解質二次電池用正極活物質、非水系電解質二次電池、およびこれらの製造方法 |
| CN102800857B (zh) * | 2012-09-11 | 2014-07-09 | 贵州红星发展股份有限公司 | 三元正极材料前驱体的制备方法 |
| CN103178257A (zh) * | 2012-12-10 | 2013-06-26 | 深圳市天骄科技开发有限公司 | 镍钴锰多元锂离子电池正极材料前驱体的制备方法 |
| KR101522668B1 (ko) * | 2012-12-12 | 2015-05-26 | 제이에이치화학공업(주) | 양극 활물질 전구체, 이의 제조 방법, 양극 활물질의 제조 방법 및 이를 이용한 리튬 이차전지 |
| KR101372622B1 (ko) * | 2012-12-21 | 2014-03-26 | 재단법인 포항산업과학연구원 | 니켈 광석으로부터 ＮＭＣ(Ｎｉ-Ｃｏ-Ｍｎ) 수산화물을 제조하는 방법 |
| JP5880426B2 (ja) * | 2012-12-28 | 2016-03-09 | 住友金属鉱山株式会社 | ニッケル複合水酸化物及びその製造方法、並びに正極活物質の製造方法 |
| JP5998924B2 (ja) | 2012-12-28 | 2016-09-28 | 日産自動車株式会社 | 二次電池システムおよび二次電池制御装置 |
| JP6017978B2 (ja) | 2013-01-24 | 2016-11-02 | トヨタ自動車株式会社 | 正極活物質及び該活物質を用いたリチウム二次電池 |
| JP5607189B2 (ja) * | 2013-01-28 | 2014-10-15 | 三洋電機株式会社 | ニッケル複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池 |
| JP5626382B2 (ja) | 2013-01-30 | 2014-11-19 | 住友金属鉱山株式会社 | ニッケルコバルト複合水酸化物及びその製造方法 |
| JP6510402B2 (ja) * | 2013-04-25 | 2019-05-08 | 住友化学株式会社 | 複合化合物、リチウム含有複合酸化物、及びそれらの製造方法 |
| KR102203425B1 (ko) | 2013-05-10 | 2021-01-15 | 스미토모 긴조쿠 고잔 가부시키가이샤 | 전이 금속 복합 수산화물 입자와 그의 제조 방법, 비수전해질 이차 전지용 정극 활물질과 그의 제조 방법, 및 비수전해질 이차 전지 |
| JP6186919B2 (ja) * | 2013-06-17 | 2017-08-30 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物及びその製造方法 |
| JP6044463B2 (ja) * | 2013-06-19 | 2016-12-14 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物及びその製造方法 |
| JP6244713B2 (ja) * | 2013-07-24 | 2017-12-13 | 住友金属鉱山株式会社 | 非水電解質二次電池用正極活物質の製造方法 |
| JP6133720B2 (ja) | 2013-07-24 | 2017-05-24 | 住友金属鉱山株式会社 | 非水電解質二次電池用正極活物質とその製造方法、並びに、非水電解質二次電池 |
| DE102013215257A1 (de) * | 2013-08-02 | 2015-02-05 | Wacker Chemie Ag | Verfahren zum Zerkleinern von Silicium und Verwendung des zerkleinerten Siliciums in einer Lithium-Ionen-Batterie |
| KR20180069137A (ko) * | 2013-09-25 | 2018-06-22 | 후지필름 가부시키가이샤 | 고체 전해질 조성물, 이를 이용한 전지용 전극 시트 및 전고체 이차전지 |
| JP6393974B2 (ja) * | 2013-11-01 | 2018-09-26 | セントラル硝子株式会社 | 固体電解質前駆体、その製造方法、固体電解質の製造方法、及び固体電解質−電極活物質複合体の製造方法 |
| CN103633311A (zh) * | 2013-11-22 | 2014-03-12 | 武汉工程大学 | 锂离子电池三元正极材料前躯体的制备方法 |
| KR102273779B1 (ko) * | 2014-04-04 | 2021-07-06 | 삼성에스디아이 주식회사 | 복합양극활물질 제조방법, 복합양극활물질 및 이를 채용한 양극과 리튬전지 |
| JP6245081B2 (ja) * | 2014-05-30 | 2017-12-13 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物とその製造方法 |
| JP6168004B2 (ja) | 2014-06-27 | 2017-07-26 | 住友金属鉱山株式会社 | マンガン複合水酸化物及びその製造方法、正極活物質及びその製造方法、並びに非水系電解質二次電池 |
| JP6252384B2 (ja) * | 2014-06-27 | 2017-12-27 | 住友金属鉱山株式会社 | ニッケル複合水酸化物及びその製造方法、正極活物質及びその製造方法、並びに非水系電解質二次電池 |
| JP6252383B2 (ja) * | 2014-06-27 | 2017-12-27 | 住友金属鉱山株式会社 | マンガンコバルト複合水酸化物及びその製造方法、正極活物質及びその製造方法、並びに非水系電解質二次電池 |
| CN106575761B (zh) * | 2014-07-31 | 2021-06-11 | 住友金属矿山株式会社 | 非水系电解质二次电池用正极活性物质及其制造方法 |
| JP6318956B2 (ja) | 2014-07-31 | 2018-05-09 | 住友金属鉱山株式会社 | 非水系電解質二次電池用の正極活物質及びその製造方法、並びに非水系電解質二次電池 |
| JP6603058B2 (ja) | 2014-08-20 | 2019-11-06 | 住友化学株式会社 | リチウム含有複合酸化物の製造方法およびリチウム含有複合酸化物 |
| JP5831772B2 (ja) * | 2014-10-14 | 2015-12-09 | トヨタ自動車株式会社 | リチウム二次電池 |
| EP3215462A1 (de) * | 2014-11-07 | 2017-09-13 | Basf Se | Übergangsmetall-mischoxide für lithiumionen-batterien |
| JP6417888B2 (ja) | 2014-11-20 | 2018-11-07 | 戸田工業株式会社 | 非水電解質二次電池用正極活物質粒子粉末とその製造方法、および非水電解質二次電池 |
| JP6428192B2 (ja) * | 2014-11-20 | 2018-11-28 | 戸田工業株式会社 | 非水電解質二次電池用正極活物質粒子粉末とその製造方法、および非水電解質二次電池 |
| CN105789609A (zh) * | 2014-12-15 | 2016-07-20 | 上海兆维科技发展有限公司 | 一种正极材料及其制备方法和用途 |
| JP6265117B2 (ja) * | 2014-12-22 | 2018-01-24 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物とその製造方法 |
| PL3100981T3 (pl) | 2015-04-28 | 2019-05-31 | Nichia Corp | Cząstki wodorotlenku kompleksu niklu i kobaltu i sposób ich otrzymywania, aktywny materiał elektrody dodatniej do zastosowań w akumulatorach z niewodnym elektrolitem i sposób jego otrzymywania oraz akumulator z niewodnym elektrolitem |
| JP6164332B2 (ja) | 2015-04-28 | 2017-07-19 | 日亜化学工業株式会社 | ニッケルコバルト複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、ならびに、非水系電解質二次電池 |
| CN104779388B (zh) * | 2015-04-30 | 2017-03-01 | 湖南瑞翔新材料股份有限公司 | 镍钴二元正极材料前驱体制备方法以及该法制得镍钴二元正极材料前驱体 |
| JP6582824B2 (ja) * | 2015-09-30 | 2019-10-02 | 住友金属鉱山株式会社 | ニッケルマンガン含有複合水酸化物およびその製造方法 |
| JP6020700B2 (ja) * | 2015-11-25 | 2016-11-02 | 住友金属鉱山株式会社 | 正極活物質及びその製造方法、並びに非水系電解質二次電池 |
| JP6882912B2 (ja) * | 2016-06-28 | 2021-06-02 | Ｄｏｗａエレクトロニクス株式会社 | 溶液およびその製造方法、ならびに二次電池用活物質の製造方法 |
| JP6250853B2 (ja) | 2016-03-31 | 2017-12-20 | 本田技研工業株式会社 | 非水系電解質二次電池用正極活物質 |
| EP3594182A1 (en) | 2016-03-31 | 2020-01-15 | Honda Motor Co., Ltd. | Positive electrode active material for nonaqueous electrolyte secondary battery |
| JP6378246B2 (ja) | 2016-05-09 | 2018-08-22 | トヨタ自動車株式会社 | 正極活物質、及び、当該正極活物質を用いたリチウムイオン二次電池 |
| US10483541B2 (en) | 2016-05-09 | 2019-11-19 | Nichia Corporation | Method of producing nickel-cobalt composite hydroxide and method of producing positive electrode active material for non-aqueous electrolyte secondary battery |
| KR102026918B1 (ko) | 2016-07-04 | 2019-09-30 | 주식회사 엘지화학 | 이차전지용 양극활물질의 제조방법 및 이에 따라 제조된 이차전지용 양극활물질 |
| WO2018021557A1 (ja) | 2016-07-29 | 2018-02-01 | 住友金属鉱山株式会社 | ニッケルマンガン複合水酸化物とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池 |
| JP6848249B2 (ja) | 2016-07-29 | 2021-03-24 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質とその製造方法、及び非水系電解質二次電池 |
| JP7215169B2 (ja) | 2016-07-29 | 2023-01-31 | 住友金属鉱山株式会社 | ニッケルマンガン複合水酸化物とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池 |
| US11476460B2 (en) | 2016-07-29 | 2022-10-18 | Sumitomo Metal Mining Co., Ltd. | Nickel manganese composite hydroxide and method for producing same, positive electrode active material for nonaqueous electrolyte secondary battery and method for producing same, and nonaqueous electrolyte secondary battery |
| CN109843811B (zh) | 2016-07-29 | 2022-08-26 | 住友金属矿山株式会社 | 镍锰复合氢氧化物及其制造方法、非水系电解质二次电池用正极活性物质及其制造方法 |
| PL3279977T3 (pl) * | 2016-08-02 | 2020-08-24 | Ecopro Bm Co., Ltd. | Tlenek kompleksu litu do dodatniego materiału aktywnego baterii litowych ogniw wtórnych i sposób jego przygotowania |
| CN106549150B (zh) * | 2016-11-07 | 2019-05-21 | 多氟多新能源科技有限公司 | 一种镍锰钴复合氢氧化物的制备方法和用于制备镍锰钴复合氢氧化物的反应釜 |
| KR102462060B1 (ko) | 2016-11-08 | 2022-11-01 | 혼다 기켄 고교 가부시키가이샤 | 비수계 전해질 2차 전지용 전극 및 이것을 구비하는 비수계 전해질 2차 전지 |
| CN106517359B (zh) * | 2016-11-15 | 2018-06-22 | 大连理工大学 | 一种一步合成大层间距钴锰层状双金属氢氧化物的方法 |
| JP2018092931A (ja) * | 2016-11-30 | 2018-06-14 | 三星エスディアイ株式会社Samsung SDI Co., Ltd. | リチウム二次電池用ニッケル系活物質、その製造方法、及びそれを含んだ正極を含んだリチウム二次電池 |
| KR101918719B1 (ko) | 2016-12-12 | 2018-11-14 | 주식회사 포스코 | 리튬 이차전지용 양극 활물질, 이의 제조 방법, 및 이를 포함하는 리튬 이차전지 |
| CN108987682B (zh) * | 2017-06-02 | 2021-05-25 | 杉杉能源（宁夏）有限公司 | 可防止颗粒破裂的富镍基前驱体材料的制备方法 |
| JP7031150B2 (ja) | 2017-07-05 | 2022-03-08 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質、非水系電解質二次電池用正極活物質の製造方法、および該正極活物質を用いた非水系電解質二次電池 |
| JP6583359B2 (ja) * | 2017-07-27 | 2019-10-02 | 住友金属鉱山株式会社 | ニッケルコバルトマンガン複合水酸化物 |
| CN109422297B (zh) * | 2017-08-28 | 2021-08-31 | 湖南杉杉能源科技股份有限公司 | 一种镍钴锰前驱体结晶过程中调控成核的方法 |
| CN107946591A (zh) * | 2017-11-21 | 2018-04-20 | 山东理工大学 | 一种钠离子电池高镍前驱体及其与正极材料的制备方法 |
| KR102387062B1 (ko) * | 2017-11-21 | 2022-04-15 | 히타치 긴조쿠 가부시키가이샤 | 리튬 이온 이차 전지용 정극 활물질의 제조 방법 및 열처리 장치 |
| CN107834064B (zh) * | 2017-12-04 | 2021-09-17 | 宁波容百新能源科技股份有限公司 | 一种高镍小粒径镍钴锰氢氧化物及其制备方法 |
| JP6943985B2 (ja) | 2018-02-02 | 2021-10-06 | 本田技研工業株式会社 | 固体電池用正極電極、固体電池、及び固体電池の製造方法 |
| WO2019163847A1 (ja) * | 2018-02-22 | 2019-08-29 | 住友金属鉱山株式会社 | 金属複合水酸化物とその製造方法、非水電解質二次電池用正極活物質とその製造方法、および非水電解質二次電池 |
| US11251430B2 (en) | 2018-03-05 | 2022-02-15 | The Research Foundation For The State University Of New York | ϵ-VOPO4 cathode for lithium ion batteries |
| KR102713885B1 (ko) | 2018-03-07 | 2024-10-08 | 가부시키가이샤 프로테리아루 | 리튬 이온 이차 전지용 정극 활물질 및 리튬 이온 이차 전지 |
| JP7254830B2 (ja) | 2018-03-26 | 2023-04-10 | ビーエーエスエフ ソシエタス・ヨーロピア | 混合金属酸化物の製造方法 |
| JP7276324B2 (ja) * | 2018-04-02 | 2023-05-18 | 住友金属鉱山株式会社 | リチウムイオン二次電池用正極活物質及びその製造方法 |
| CN108365216A (zh) * | 2018-04-18 | 2018-08-03 | 西南石油大学 | 一种新型高镍三元正极材料及制备 |
| JP7273260B2 (ja) * | 2018-06-20 | 2023-05-15 | 住友金属鉱山株式会社 | リチウムイオン二次電池用正極活物質とその製造方法およびリチウムイオン二次電池 |
| JP6888588B2 (ja) | 2018-06-26 | 2021-06-16 | 日亜化学工業株式会社 | 非水電解質二次電池用正極活物質 |
| CN109216037A (zh) * | 2018-08-14 | 2019-01-15 | 南京理工大学 | 基于细菌纤维素的三元复合电极材料及其制备方法 |
| JP6901689B2 (ja) | 2018-09-28 | 2021-07-14 | 日亜化学工業株式会社 | 非水電解質二次電池用正極活物質及びその製造方法 |
| US11837723B2 (en) | 2019-02-20 | 2023-12-05 | Nichia Corporation | Positive electrode active material for nonaqueous secondary battery, and method for manufacturing same |
| KR102553588B1 (ko) | 2019-02-28 | 2023-07-11 | 주식회사 엘지화학 | 이차전지용 양극 활물질 전구체, 양극 활물질, 그 제조방법 및 이를 포함하는 리튬 이차전지 |
| JP7215261B2 (ja) * | 2019-03-15 | 2023-01-31 | 株式会社豊田自動織機 | 層状岩塩構造を示し、リチウム、ニッケル、コバルト、タングステン、ジルコニウム及び酸素を含有する正極活物質、並びに、その製造方法 |
| US12237507B2 (en) | 2019-04-26 | 2025-02-25 | Sumitomo Metal Mining Co., Ltd. | Nickel composite hydroxide, method for producing nickel composite hydroxide, positive electrode active material for lithium ion secondary battery, method for producing positive electrode active material for lithium ion secondary battery, and lithium ion secondary battery |
| JP7274125B2 (ja) * | 2019-05-31 | 2023-05-16 | 住友金属鉱山株式会社 | 全固体リチウムイオン二次電池用正極活物質および全固体リチウムイオン二次電池 |
| US11715826B2 (en) | 2019-06-25 | 2023-08-01 | Nichia Corporation | Method for producing electrode for non-aqueous secondary battery |
| JP7007610B2 (ja) | 2019-07-11 | 2022-01-24 | 日亜化学工業株式会社 | 正極活物質及びその製造方法 |
| JP7648908B2 (ja) | 2019-11-29 | 2025-03-19 | 日亜化学工業株式会社 | 非水電解質二次電池用正極活物質及びその製造方法 |
| CN110957482B (zh) * | 2019-11-30 | 2021-08-03 | 华友新能源科技（衢州）有限公司 | 一种添加六价元素的镍钴锰复合氢氧化物及其制备方法 |
| CN112978809B (zh) * | 2019-12-18 | 2023-05-09 | 格林美股份有限公司 | 一种核壳结构铝掺杂镍钴锰正极材料前驱体及其制备方法 |
| JP7824507B2 (ja) | 2020-01-27 | 2026-03-05 | 日亜化学工業株式会社 | 非水電解質二次電池用正極活物質及びその製造方法 |
| CN111682196B (zh) * | 2020-05-20 | 2023-03-10 | 欣旺达电动汽车电池有限公司 | 正极材料及其制备方法和锂离子电池 |
| US12119492B2 (en) | 2020-07-30 | 2024-10-15 | Sumitomo Metal Mining Co., Ltd. | Positive electrode active material for all-solid-state lithium ion secondary battery and method for manufacturing the same |
| CN114988490B (zh) * | 2021-03-01 | 2024-03-12 | 中国石油化工股份有限公司 | 一种锂离子电池正极材料前驱体及其制备方法和应用 |
| JP7417135B2 (ja) | 2021-07-21 | 2024-01-18 | 日亜化学工業株式会社 | 非水電解質二次電池用正極活物質及びその製造方法 |
| JP7473828B2 (ja) | 2021-07-26 | 2024-04-24 | 日亜化学工業株式会社 | 非水電解質二次電池用正極及びその製造方法 |
| CN114394631B (zh) * | 2021-12-31 | 2023-07-07 | 宜宾光原锂电材料有限公司 | 一种三元正极材料前驱体的制备方法 |
| KR20250011965A (ko) | 2022-05-23 | 2025-01-22 | 스미토모 긴조쿠 고잔 가부시키가이샤 | 전고체 리튬 이온 이차 전지용 정극 활물질과 그 제조 방법 |
| KR20250016205A (ko) | 2022-05-23 | 2025-02-03 | 스미토모 긴조쿠 고잔 가부시키가이샤 | 전고체 리튬 이온 이차 전지용 정극 활물질과 그 제조 방법 |
| CN115124087B (zh) * | 2022-07-18 | 2024-02-20 | 衢州华友钴新材料有限公司 | 掺铝四氧化三钴与制备方法及钴酸锂正极材料 |
| KR20240068187A (ko) | 2022-11-10 | 2024-05-17 | 주식회사 에코앤드림 | 리튬이차전지용 고밀도 니켈-코발트-망간 복합전구체의 제조 방법 |
| CN115893527B (zh) * | 2022-12-26 | 2024-08-06 | 荆门市格林美新材料有限公司 | 一种大颗粒镍钴锰三元前驱体合成方法 |
| EP4393887A1 (en) * | 2022-12-27 | 2024-07-03 | Umicore Finland OY | Powderous material comprising a hydroxide and method for manufacturing the same |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5700596A (en) * | 1991-07-08 | 1997-12-23 | Matsushita Electric Industrial Co., Ltd. | Nickel hydroxide active material powder and nickel positive electrode and alkali storage battery using them |
| JP3884796B2 (ja) * | 1996-07-12 | 2007-02-21 | 日本化学工業株式会社 | Ｎｉ−Ｃｏ系複合水酸化物の製造方法 |
| JP3609229B2 (ja) | 1997-01-29 | 2005-01-12 | 株式会社田中化学研究所 | 非水系二次電池用正極活物質の製造方法及びそれを使用したリチウム二次電池 |
| US7585435B2 (en) * | 2000-11-06 | 2009-09-08 | Tanaka Chemical Corporation | High density cobalt-manganese coprecipitated nickel hydroxide and process for its production |
| JP4498647B2 (ja) | 2000-11-09 | 2010-07-07 | 株式会社豊田中央研究所 | アルカリ二次電池正極活物質用水酸化ニッケル、それを用いたアルカリ二次電池、その特性評価方法およびその製造方法 |
| JP2003081639A (ja) * | 2001-06-29 | 2003-03-19 | Mitsui Mining & Smelting Co Ltd | マンガン含有層状リチウム−遷移金属複合酸化物及びその製造方法 |
| JP3827545B2 (ja) | 2001-09-13 | 2006-09-27 | 松下電器産業株式会社 | 正極活物質、その製造方法および非水電解質二次電池 |
| JP2004193115A (ja) | 2002-11-27 | 2004-07-08 | Nichia Chem Ind Ltd | 非水電解質二次電池用正極活物質および非水電解質二次電池 |
| WO2004090273A1 (ja) | 2003-04-09 | 2004-10-21 | Matsushita Electric Industrial Co., Ltd. | 移動装置及び移動体開閉制御装置 |
| JP2004311297A (ja) | 2003-04-09 | 2004-11-04 | Mitsubishi Chemicals Corp | 粉体状リチウム二次電池正極材料、リチウム二次電池正極、及びリチウム二次電池 |
| NZ538480A (en) * | 2003-04-17 | 2007-12-21 | Seimi Chem Kk | Lithium-nickel-cobalt-manganese containing composite oxide, material for positive electrode active material for lithium secondary battery, and methods for producing these |
| JP2005332713A (ja) * | 2004-05-20 | 2005-12-02 | Toyota Motor Corp | リチウム二次電池及び該二次電池用正極活物質 |
| JP4781004B2 (ja) * | 2005-04-28 | 2011-09-28 | パナソニック株式会社 | 非水電解液二次電池 |
| JP4846309B2 (ja) * | 2005-09-09 | 2011-12-28 | 株式会社田中化学研究所 | ニッケルマンガンコバルト複合酸化物の製造方法 |
| CN100503453C (zh) * | 2005-11-17 | 2009-06-24 | 比亚迪股份有限公司 | 一种镍锰钴氢氧化物的制备方法 |
| JP2008147068A (ja) | 2006-12-12 | 2008-06-26 | Ise Chemicals Corp | 非水電解液二次電池用リチウム複合酸化物 |
| JP5245835B2 (ja) | 2007-02-13 | 2013-07-24 | 日本電気株式会社 | 鍵生成装置、鍵導出装置、暗号化装置、復号化装置、方法、及び、プログラム |
| JP5428251B2 (ja) * | 2007-09-04 | 2014-02-26 | 三菱化学株式会社 | リチウム遷移金属系化合物粉体、それを用いたリチウム二次電池用正極及びリチウム二次電池 |
| EP2466671A3 (en) | 2007-09-04 | 2012-08-22 | Mitsubishi Chemical Corporation | Lithium transition metal-based compound powder, method for manufacturing the same, spray-dried substance serving as firing precursor thereof, and lithium secondary battery positive electrode and lithium secondary battery using the same |
| CN101425605B (zh) * | 2007-11-01 | 2011-09-21 | 深圳市慧通天下科技股份有限公司 | 一种镍钴锰酸锂高功率锂离子电池 |
| US8795898B2 (en) * | 2008-12-24 | 2014-08-05 | Ngk Insulators, Ltd. | Plate-like particle for cathode active material of a lithium secondary battery, a cathode active material film of a lithium secondary battery, and a lithium secondary battery |
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