JP2007294707A - 半導体装置の製造方法および半導体装置 - Google Patents
半導体装置の製造方法および半導体装置 Download PDFInfo
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 44
- 239000010410 layer Substances 0.000 claims abstract description 237
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 76
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 76
- 239000010703 silicon Substances 0.000 claims abstract description 76
- 239000012535 impurity Substances 0.000 claims abstract description 72
- 239000000758 substrate Substances 0.000 claims abstract description 60
- 238000000034 method Methods 0.000 claims abstract description 21
- 238000005530 etching Methods 0.000 claims abstract description 13
- 239000002344 surface layer Substances 0.000 claims abstract description 4
- 239000013078 crystal Substances 0.000 claims description 27
- 230000005669 field effect Effects 0.000 claims description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- 229910000577 Silicon-germanium Inorganic materials 0.000 abstract description 88
- 230000000694 effects Effects 0.000 abstract description 17
- 238000009413 insulation Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 27
- 230000015572 biosynthetic process Effects 0.000 description 18
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 16
- 229910052796 boron Inorganic materials 0.000 description 16
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 15
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 14
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 9
- 229910052581 Si3N4 Inorganic materials 0.000 description 8
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 8
- 238000009792 diffusion process Methods 0.000 description 7
- 238000002955 isolation Methods 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001312 dry etching Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- ZOCHARZZJNPSEU-UHFFFAOYSA-N diboron Chemical compound B#B ZOCHARZZJNPSEU-UHFFFAOYSA-N 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- RGGPNXQUMRMPRA-UHFFFAOYSA-N triethylgallium Chemical compound CC[Ga](CC)CC RGGPNXQUMRMPRA-UHFFFAOYSA-N 0.000 description 1
- OTRPZROOJRIMKW-UHFFFAOYSA-N triethylindigane Chemical compound CC[In](CC)CC OTRPZROOJRIMKW-UHFFFAOYSA-N 0.000 description 1
- XCZXGTMEAKBVPV-UHFFFAOYSA-N trimethylgallium Chemical compound C[Ga](C)C XCZXGTMEAKBVPV-UHFFFAOYSA-N 0.000 description 1
- IBEFSUTVZWZJEL-UHFFFAOYSA-N trimethylindium Chemical compound C[In](C)C IBEFSUTVZWZJEL-UHFFFAOYSA-N 0.000 description 1
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- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
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- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/7842—Field effect transistors with field effect produced by an insulated gate means for exerting mechanical stress on the crystal lattice of the channel region, e.g. using a flexible substrate
- H01L29/7848—Field effect transistors with field effect produced by an insulated gate means for exerting mechanical stress on the crystal lattice of the channel region, e.g. using a flexible substrate the means being located in the source/drain region, e.g. SiGe source and drain
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
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- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66568—Lateral single gate silicon transistors
- H01L29/66613—Lateral single gate silicon transistors with a gate recessing step, e.g. using local oxidation
- H01L29/66628—Lateral single gate silicon transistors with a gate recessing step, e.g. using local oxidation recessing the gate by forming single crystalline semiconductor material at the source or drain location
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
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- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/7833—Field effect transistors with field effect produced by an insulated gate with lightly doped drain or source extension, e.g. LDD MOSFET's; DDD MOSFET's
- H01L29/7834—Field effect transistors with field effect produced by an insulated gate with lightly doped drain or source extension, e.g. LDD MOSFET's; DDD MOSFET's with a non-planar structure, e.g. the gate or the source or the drain being non-planar
Abstract
【解決手段】シリコン基板11上にゲート絶縁膜12を介してゲート電極13を形成する第1工程と、ゲート電極13をマスクにしたエッチングにより、シリコン基板11の表面層を掘り下げる第2工程と、掘り下げられたシリコン基板11の表面に、シリコン基板11側から表面に向かって高濃度となるような濃度勾配を有して不純物が含有されるように、SiGe層21をエピタキシャル成長させる第3工程とを有することを特徴とする半導体装置の製造方法およびこれにより得られる半導体装置である。
【選択図】図2
Description
本発明の半導体装置の製造方法に係る実施の形態の一例として、PMOSFETの製造方法を例にとり、図1〜図2の製造工程断面図を用いて説明する。なお、背景技術で説明したものと同様の構成には、同一の番号を付して説明する。
上記第1実施形態では、PMOSFETの製造方法を例にとり説明したが、本実施形態においてはNMOSFETの製造方法を例にとり、図3を用いて説明する。なお、シリコン基板11の表面を掘り下げるまでの工程は、図1(a)〜(d)を用いて説明した工程と同様に行うこととする。
なお、上記第2実施形態においては、NMOSFETのソース・ドレイン領域となるSiC層に、不純物としてAsを含有させる例について説明したが、不純物としては、上記As以外に、リン(P)を用いてもよい。
Claims (7)
- シリコン基板上にゲート絶縁膜を介してゲート電極を形成する第1工程と、
前記ゲート電極をマスクにしたエッチングにより、前記シリコン基板の表面層を掘り下げる第2工程と、
掘り下げられた前記シリコン基板の表面に、当該シリコン基板側から表面に向かって高濃度となるような濃度勾配を有して不純物が含有されるように、シリコンとシリコンとは格子定数の異なる原子とからなる混晶層をエピタキシャル成長させる第3工程とを有する
ことを特徴とする半導体装置の製造方法。 - 請求項1記載の半導体装置の製造方法において、
前記半導体装置がp型の電界効果トランジスタであり、
前記第3工程では、前記シリコン基板の表面に、前記濃度勾配を有してp型の不純物が含有されるように、シリコンとゲルマニウムとからなる前記混晶層をエピタキシャル成長させる
ことを特徴とする半導体装置の製造方法。 - 請求項1記載の半導体装置の製造方法において、
前記半導体装置がn型の電界効果トランジスタであり、
前記第3工程では、前記シリコン基板の表面に、前記濃度勾配を有してn型の不純物が含有されるように、シリコンと炭素とからなる前記混晶層をエピタキシャル成長させる
ことを特徴とする半導体装置の製造方法。 - 請求項1記載の半導体装置の製造方法において、
前記第3工程では、当該シリコン基板側から表面に向かって段階的に高濃度となるような前記濃度勾配を有して不純物が含有されるように、前記混晶層をエピタキシャル成長させる
ことを特徴とする半導体装置の製造方法。 - 請求項1記載の半導体装置の製造方法において、
前記第3工程では、当該シリコン基板側から表面に向かって連続的に高濃度となるような前記濃度勾配を有して不純物が含有されるように、前記混晶層をエピタキシャル成長させる
ことを特徴とする半導体装置の製造方法。 - 請求項1記載の半導体装置の製造方法において、
前記混晶層が、第1の層、第2の層および第3の層からなる3層を順次積層してなり、
前記第3工程では、掘り下げられた前記シリコン基板の表面に、前記3層のうちで最も低濃度の不純物が含有されるように、前記第1の層を形成する工程と、
前記第1の層上に、前記第1の層側から表面に向かって、前記第1の層の不純物濃度から前記第3の層の不純物濃度となるような濃度勾配を有して不純物が含有されるように、前記第2の層を形成する工程と、
前記第2の層上に、前記3層のうちで最も高濃度の不純物が含有されるように、前記第3の層を形成する工程とを行う
ことを特徴とする半導体装置の製造方法。 - シリコン基板上にゲート絶縁膜を介して設けられたゲート電極と、
前記ゲート電極の両側の前記シリコン基板が掘り下げられた領域に、シリコンとシリコンとは格子定数の異なる原子とからなる混晶層とを備えた半導体装置において、
前記混晶層には、前記シリコン基板側から表面に向かって高濃度となるような濃度勾配を有して不純物が含有されている
ことを特徴とする半導体装置。
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JP2006121605A JP4345774B2 (ja) | 2006-04-26 | 2006-04-26 | 半導体装置の製造方法 |
TW096112761A TWI344212B (en) | 2006-04-26 | 2007-04-11 | Method of manufacturing semiconductor device, and semiconductor device |
US11/739,792 US7510925B2 (en) | 2006-04-26 | 2007-04-25 | Method of manufacturing semiconductor device, and semiconductor device |
CNA2007101010655A CN101064257A (zh) | 2006-04-26 | 2007-04-26 | 制造半导体器件的方法和半导体器件 |
KR1020070040877A KR101358949B1 (ko) | 2006-04-26 | 2007-04-26 | 반도체 장치의 제조 방법 및 반도체 장치 |
US16/184,766 USRE49803E1 (en) | 2006-04-26 | 2018-11-08 | Method of manufacturing semiconductor device, and semiconductor device |
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WO2009122542A1 (ja) * | 2008-03-31 | 2009-10-08 | 富士通マイクロエレクトロニクス株式会社 | 半導体装置及びその製造方法 |
JP2011061042A (ja) * | 2009-09-10 | 2011-03-24 | Fujitsu Semiconductor Ltd | 半導体装置 |
JP2012510720A (ja) * | 2008-12-11 | 2012-05-10 | インテル コーポレイション | 歪み半導体デバイス用のゲルマニウム含有量が漸次変化した高ゲルマニウム化合物膜 |
JP2012516557A (ja) * | 2009-01-30 | 2012-07-19 | アドバンスト・マイクロ・ディバイシズ・インコーポレイテッド | 歪誘起合金及び段階的なドーパントプロファイルを含むその場で形成されるドレイン及びソース領域 |
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JP2004260132A (ja) | 2003-02-05 | 2004-09-16 | Nec Electronics Corp | 半導体装置の製造方法 |
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JP5091403B2 (ja) | 2005-12-15 | 2012-12-05 | ルネサスエレクトロニクス株式会社 | 半導体装置およびその製造方法 |
US8017487B2 (en) * | 2006-04-05 | 2011-09-13 | Globalfoundries Singapore Pte. Ltd. | Method to control source/drain stressor profiles for stress engineering |
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- 2007-04-26 KR KR1020070040877A patent/KR101358949B1/ko active IP Right Grant
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Cited By (7)
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WO2009122542A1 (ja) * | 2008-03-31 | 2009-10-08 | 富士通マイクロエレクトロニクス株式会社 | 半導体装置及びその製造方法 |
US8288757B2 (en) | 2008-03-31 | 2012-10-16 | Fujitsu Semiconductor Limited | Semiconductor device and manufacturing method thereof |
JP5120448B2 (ja) * | 2008-03-31 | 2013-01-16 | 富士通セミコンダクター株式会社 | 半導体装置及びその製造方法 |
JP2012510720A (ja) * | 2008-12-11 | 2012-05-10 | インテル コーポレイション | 歪み半導体デバイス用のゲルマニウム含有量が漸次変化した高ゲルマニウム化合物膜 |
JP2012516557A (ja) * | 2009-01-30 | 2012-07-19 | アドバンスト・マイクロ・ディバイシズ・インコーポレイテッド | 歪誘起合金及び段階的なドーパントプロファイルを含むその場で形成されるドレイン及びソース領域 |
JP2011061042A (ja) * | 2009-09-10 | 2011-03-24 | Fujitsu Semiconductor Ltd | 半導体装置 |
JP2013534052A (ja) * | 2010-06-25 | 2013-08-29 | インターナショナル・ビジネス・マシーンズ・コーポレーション | 埋め込みストレッサ要素を含む半導体構造およびその製造方法 |
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TW200746430A (en) | 2007-12-16 |
KR20070105911A (ko) | 2007-10-31 |
CN101064257A (zh) | 2007-10-31 |
US20070254414A1 (en) | 2007-11-01 |
USRE49803E1 (en) | 2024-01-16 |
KR101358949B1 (ko) | 2014-02-06 |
JP4345774B2 (ja) | 2009-10-14 |
US7510925B2 (en) | 2009-03-31 |
TWI344212B (en) | 2011-06-21 |
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