EP1413636A1 - Alliage d'aluminium presentant une excellente usinabilite, et materiau d'alliage d'aluminium et son procede de production - Google Patents

Alliage d'aluminium presentant une excellente usinabilite, et materiau d'alliage d'aluminium et son procede de production Download PDF

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EP1413636A1
EP1413636A1 EP02755647A EP02755647A EP1413636A1 EP 1413636 A1 EP1413636 A1 EP 1413636A1 EP 02755647 A EP02755647 A EP 02755647A EP 02755647 A EP02755647 A EP 02755647A EP 1413636 A1 EP1413636 A1 EP 1413636A1
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aluminum alloy
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manufacturing
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EP1413636A4 (fr
EP1413636B1 (fr
EP1413636B9 (fr
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Hideaki c/o Oyama Regional Office MATSUOKA
Masaki c/o Oyama Regional Office YAMANAKA
Hiroki c/o Oyama Regional Office YOSHIOKA
Yasuo c/o Aizu Regional Office OKAMOTO
Masakatsu c/o Aizu Regional Office KITAMURA
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Resonac Holdings Corp
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Showa Denko KK
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/02—Alloys based on aluminium with silicon as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/02—Alloys based on aluminium with silicon as the next major constituent
    • C22C21/04—Modified aluminium-silicon alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent

Definitions

  • the present invention relates to Al-Mg-Si series aluminum alloys excellent in machinability, and an aluminum alloy material and a method for production thereof.
  • Japanese Unexamined Laid-open Patent Publication No. 11-12705 discloses an aluminum alloy to be forged containing Si: 3 - 11 mass%
  • Japanese Unexamined Laid-open Patent Publication No. 9-249931 discloses a high corrosion resistant aluminum alloy containing Si: 1. 5 - 12.0 mass%
  • Japanese Unexamined Laid-open Patent Publication No. 2-97638 discloses an aluminum alloy for magnetic tape contact component use containing Si: 2.0 - 12.5 mass% and Cu: 1.0 - 6.5 mass%.
  • hard Si particles are dispersed in the aluminum matrix so that the Si particles can be ground at the time of cutting or the Si particles and the matrix interface thereof can be exfoliated to thereby break the chips into small pieces. Since these aluminum alloy materials do not contain low fusing point elements, they are excellent in recycling nature, and also excellent in corrosion resistance and heat resistance.
  • these aluminum alloy materials are manufactured by homogenizing a cast extruding billet of predetermined compositions, then extruding the billet at 400 - 600 °C, into an extruded article at 350 - 550 °C, and then quenching the extruded article at a die exit or performing a solution treatment after cutting the extruded article into a long cut article of 1 - 5 m length.
  • the Si particle may sometimes become 1 ⁇ m or less at the time of casting the billet, the particle tends to grow up to a size exceeding 1 ⁇ m due to a heat treatment of 300 °C or more, which is performed after the casting. Accordingly, the Si particle grows during each processing, i.e., homogenizing processing, extruding processing, quenching processing at a die exit and solution treatment processing, and finally grows up to a size of 5 - 10 ⁇ m. As a result, the alloy material obtained by performing the aforementioned series of processing is poor in cutting ability as compared to a cast member, which causes heavy abrasion or damage of a cutting tool.
  • the present invention aims to provide aluminum alloys excellent in cutting ability, capable of suppressing abrasion and damage such as chipping of a cutting tool and having better alumite processability, aluminum alloy materials and manufacturing methods thereof.
  • the present invention includes aluminum alloys roughly classified by chemical composition into four types, aluminum alloy materials each having metal texture corresponding to each chemical composition, and methods for manufacturing these aluminum alloy materials.
  • a first aluminum alloy comprises Mg: 0.3 - 6 mass%, Si: 0.3 - 10 mass%, Zn: 0.05 - 1 mass%, Sr: 0 . 001 - 0.3 mass%, and the balance being aluminum and impurities.
  • the content of Mg is 0.5 - 1.1 mass%. It is preferable that the content of Si is 1.5 - 5 mass%. It is preferable that the content of Zn is 0.1 - 0.3 mass%. It is preferable that the content of Sr is 0.005 - 0.05 mass%.
  • a second aluminum alloy comprises Mg: 0.3 - 6 mass%, Si: 0.3 - 10 mass%, Zn: 0.05 - 1 mass%, Sr: 0.001 - 0.3 mass%, one or more of selective additional elements selected from the group consisting of Cu: 0.01% or more but less than 1 mass%, Fe: 0.01 - 1 mass%, Mn: 0.01 - 1 mass%, Cr: 0.01 - 1 mass%, Zr: 0.01 - 1 mass%, Ti: 0.01 - 1 mass%, Na: 0.001 - 0.5 mass%, Ca: 0.001 - 0.5 mass%; and the balance being Aluminum and impurities.
  • the content of Mg is 0.5 - 1.1 mass%. It is preferable that the content of Si is 1.5 - 5 mass%. It is preferable that the content of Zn is 0.1 - 0.3 mass%. It is preferable that the content of Sr is 0.005 - 0.05 mass%.
  • the selective additional element is Cu. It is preferable that the selective additional element is Fe. It is preferable that the selective additional element is one or more elements selected from the group consisting Cr and Mn. It is preferable that the selective additional element is Zr. It is preferable that the selective additional element is Ti. It is preferable that the selective additional element is one or more elements selected from the group consisting of Na and Ca.
  • the content of Cu is 0.1 - 0.3 mass%. It is preferable that the content of Fe is 0.1 - 0.3 mass%. It is preferable that the content of Mn is 0.1 - 0.3 mass%. It is preferable that the content of Cr is 0.1 - 0.3 mass%. It is preferable that the content of Zr is 0.1 - 0.3 mass% . It is preferable that the content of Ti is 0.1 - 0.3 mass% . It is preferable that the content of Na is 0 . 005 - 0.3 mass% . It is preferable that the content of Ca is 0.005 - 0.3 mass%.
  • a first aluminum alloy material according to the present invention is composed of an aluminum alloy material having chemical composition of the first and second aluminum alloys as recited in any one of claims 1 - 24, and wherein a mean particle diameter of Si particle is 1 - 5 ⁇ m and a mean aspect ratio of Si particle is 1 - 3, as an alloy texture of the aluminum alloy.
  • the mean particle diameter of the Si particle is 3 ⁇ m or less.
  • the mean aspect ratio of the Si particle is preferably 2 or less.
  • a method for manufacturing the first aluminum alloy material according to the present invention comprises: making a billet composed of the first and second aluminum alloys as recited in any one of claims 1 - 24 at a casting rate of 10 - 180 mm/min., homogenizing the billet at 400 - 570°C for 6 hours or more to obtain a homogenized billet; extruding the homogenized billet at a billet temperature of 300 - 550 °C, an extrusion rate of 0.5 - 100 m/min.
  • the casting rate is 30 - 130 mm/min.
  • the homogenization is preferably performed at 500 - 545 °C for 10 hours or more.
  • the extrusion is preferably performed at the billet temperature of 350 - 500 °C, the extrusion rate of 2 - 30 m/min. and the extrusion ratio of 20 - 85.
  • the solution treatment is preferably performed at 500 - 545 °C for 3 hours or more.
  • the aging is preferably performed at 140 - 200 °C for 3 - 20 hours. It is preferable that the solution treated extruded article is drawn at a reduction rate of 5 - 30% into a predetermined configuration, and thereafter the aging is performed. Especially, the reduction rate of the drawing is preferably 10 - 20%.
  • a third aluminum alloy comprises: Mg: 0.1 - 6 mass%; Si: 0.3 - 12.5 mass%; Cu: 0.01 mass% or more but less than 1 mass%; Zn: 0.01 - 3 mass%; Sr: 0.001 - 0.5 mass%; and the balance being aluminum and impurities.
  • the content of Mg is 0.3 - 5 mass%.
  • the content of Si is preferably 0.8 - 12 mass%.
  • the content of Cu is preferably 0.1 - 0.8 mass%.
  • the content of Zn is preferably 0. 05 - 1.5 mass%.
  • the content of Sr is preferably 0.005 - 0.3 mass%.
  • a fourth aluminum alloy comprises: Mg: 0.1 - 6 mass%; Si: 0.3 - 12.5 mass%; Cu: 0.01 mass% or more but less than 1 mass%; Zn: 0.01 - 3 mass%; Sr: 0.001 - 0.5 mass%; one or more of selective additional elements selected from the group consisting of Ti: 0.001 - 1 mass%, B: 0.0001 - 0.03 mass%, C: 0.0001 - 0.5 mass%, Fe: 0.01 - 1 mass%, Cr: 0.01 - 1 mass%, Mn: 0.01 - 1 mass%; Zr: 0.01 - 1 mass%, V: 0.01 - 1 mass%, Sc: 0.0001 - 0.5 mass%, Ni: 0.005 - 1 mass%, Na: 0.001 - 0.5 mass%, Sb: 0.001 - 0.5 mass%, Ca: 0.001 - 0.5 mass%, Sn: 0.01 - 1 mass%, Bi: 0.01 - 1 mass%, In: 0.001
  • the content of Mg is 0.3 - 5 mass%.
  • the content of Si is preferably 0.8 - 12 mass%.
  • the content of Cu is preferably 0.1 - 0.8 mass%.
  • the content of Zn is preferably 0.05 - 1.5 mass%.
  • the content of Sr is preferably 0.005 - 0.3 mass%.
  • the selective additional element is one or more elements selected from the group consisting of Ti, B, C and Sc.
  • the selective additional element is preferably Fe.
  • the selective additional element is preferably one or more elements selected from the group consisting Cr and Mn.
  • the selective additional element is preferably one or more elements selected from the group consisting Zr and V.
  • the selective additional element is preferably Ni.
  • the selective additional element is preferably one or more elements selected from the group consisting Na, Sb and Ca.
  • the selective additional element is preferably one or more elements selected from the group consisting Sn, Bi and In.
  • the content of Ti is 0 . 003 - 0.5 mass%.
  • the content of B is preferably 0.0005 - 0.01 mass%.
  • the content of C is preferably 0.001 - 0.3 mass%.
  • the content of Fe is preferably 0.05 - 0.7 mass%.
  • the content of Cr is preferably 0.03 - 0.7 mass%.
  • the content of Mn is preferably 0 . 03 - 0.7 mass%.
  • the content of Zr is preferably 0 . 03 - 0.7 mass%.
  • the content of V is preferably 0.03 - 0.7 mass%.
  • the content of Sc is preferably 0.01 - 0.3 mass%.
  • the content of Ni is preferably 0 . 03 - 0.7 mass%.
  • the content of Na is preferably 0 . 005 - 0.3 mass%.
  • the content of Sb is preferably 0.005 - 0.3 mass%.
  • the content of Ca is preferably 0 . 005 - 0.3 mass%.
  • the content of Sn is preferably 0.05 - 0.5 mass%.
  • the content of Bi is preferably 0.05 - 0.5 mass%.
  • the content of In is preferably 0.01 - 0.3 mass%.
  • the other aluminum alloy material according to the present invention is composed of an aluminum alloy material having chemical composition of the third or the fourth alloy as recited in any one of claims 36 - 70 and wherein, in metal texture, a mean dendrite arm spacing is 1 - 200 ⁇ m, a dendrite boundary zone includes eutectic Si particles of 0.01 - 5 ⁇ m of mean particle diameters and other second phase particles, and an eutectic lamella texture in which a mean skeleton line length (Lm) in a longitudinal direction is 0.5 ⁇ m or more and a mean width (Wm) is 0.5 ⁇ m or more is formed in a shape of a network.
  • Lm mean skeleton line length
  • Wm mean width
  • the eutectic Si particles and other second phase particles exist 500 pieces/mm 2 or more in total, and the area share of these particles is 0.1 - 50%.
  • the mean dendrite arm spacing is preferably 3 - 100 ⁇ m.
  • the mean particle diameter of the eutectic Si particle is preferably 0.1 - 3 ⁇ m.
  • the eutectic lamella texture has a mean skeleton line length (Lm) of 3 ⁇ m or more and a mean width (Wm) of 1 ⁇ m or more.
  • the mean ratio (L/Wm) of the skeleton line length to the skeleton width in the eutectic lamella texture is preferably 3 or more.
  • the eutectic Si particles and other second phase particles exist 1,000 pieces/mm 2 or more in total.
  • the area share of the eutectic Si particles and other second phase particles is preferably 0.3 - 40%.
  • a method for manufacturing the other aluminum alloy material is a method for suitably used to manufacture the aluminum alloy material. That is, a method for manufacturing an aluminum alloy material, the method comprises: continuously casting molten the third or the fourth aluminum alloy as recited in any one of claims 36 - 70 to obtain a shape member having a prescribed cross section at a casting rate of 30 - 5000 mm/min. and a cooling rate of 10 - 600 °C/sec., the molten aluminum alloy and held at the solidus temperature or more; thereafter aging the shape member at 100 - 300 °C for 0.5 - 100 hours.
  • the casting rate is 100 - 2000 mm/min.
  • the cooling rate is preferably 30 - 300 °C/sec.
  • the aging is preferably performed at 120 - 220°C for 1 - 30 hours.
  • the shape member is a non-hollow member. It is preferable that the shape member circumscribes to a circle with a diameter of 10 - 150 mm in cross section. It is preferable that the method further comprises a step of removing a surface layer portion of a 0.1 - 10 mm depth from the continuously cast shape member. The removed surface layer portion is preferably 0.2 - 5 mm in depth.
  • the method further comprises the step of performing a secondary forming processing of a cross-sectional area decreasing ratio of 30% or less to the shape member after the continuous casting at a temperature of 400 °C or below.
  • the processing temperature is preferably 250 °C or below.
  • the cross-sectional area decreasing ratio is preferably 20% or less.
  • first to fourth aluminum alloys will be detailed by classifying them into the first and second aluminum alloys containing Mg, Si, Zn and Sr as common indispensable elements and the third and fourth aluminum alloys containing Mg, Si, Cu, Zn and Sr as common indispensable elements.
  • first and second aluminum alloys containing Mg, Si, Zn and Sr as common indispensable elements
  • third and fourth aluminum alloys containing Mg, Si, Cu, Zn and Sr as common indispensable elements.
  • the first and second aluminum alloys and the alloy materials having the chemical compositions thereof suppress abrasion and damage of a cutting tool by rounding and fining Si particles while securing good cutting ability caused by the enhanced chip breakable nature due to the Si particles. Furthermore, in addition to the strengthening by the main deposit, Mg 2 Si, the strength of the alloys are notably improved by the excessive Si particles, as compared to conventional alloys.
  • the first aluminum alloy (claims 1 - 5) according to the present invention comprises these 4 elements and the balance being aluminum and impurities.
  • Mg is dissolved in an alloy matrix and dispersed as deposits such as Mg 2 Si created by bonding with excessive Si, etc. in the matrix, to thereby enhance the mechanical property, especially proof strength and further improve the cutting ability of the alloy by the synergistic effect with other solid solution type elements.
  • the Mg content is less than 0.3 mass%, the aforementioned effects cannot be obtained sufficiently.
  • the Mg content exceeds 6.0 mass%, oxidation of an alloy molten metal is promoted and plastic-working nature deteriorates. Accordingly, the Mg content should be 0.3 - 6 mass%.
  • the Mg content is 0.5 - 1.1 mass%.
  • Si Since only few amount of Si can be dissolved in an aluminum, Si is dispersed in the matrix as a single particle of Si except for the amount required for compound formation. In the alloy texture in which Si particles are dispersed, since the Si particles are ground by a cutting tool and/or the Si particle and the aluminum base phase are peeled at the interface, the chips can be easily broken, resulting in improved cutting ability. Furthermore, the Si particles become round and fine by Sr added as an essential element, or Na and Ca added as an arbitrary element, which also improves the cutting ability. If Si content is less than 0.3 mass%, sufficient chip breaking effects cannot be obtained.
  • Si content exceeds 10 mass%, although the chip breaking effects can be improved, a cutting tool will be abraded heavily, causing deteriorated productivity. Accordingly, it is necessary that Si content is 0.3 - 10 mass%. From this point of view, the preferable Si content is 1.5 - 5 mass%.
  • Zn dissolves in an alloy matrix, while Zn bonds with Mg and disperses in a matrix as deposit of MgZn 2 . This improves the mechanical property of the aluminum alloy and the cutting ability of the alloy by the synergistic effects of other dissolve type elements. If Zn content is less than 0.05 mass%, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Zn content exceeds 1 mass%, the corrosion resistance may deteriorate. Accordingly, it is necessary that Zn content is 0.05 - 1 mass%. Furthermore, if the Zn content falls within the range, it is effective in improving an alumite coat generation rate, and therefore the alloy can be suitably used for a product to which alumite processing is performed for the purpose of improving the abrasion resistance. The preferable Zn content is 0.1 - 0.3 mass%.
  • Sr makes eutectic Si at the time of solidification and proeutectic Si round and fine when Sr coexists with Si. This indirectly improves the chip breaking nature, which in turn improves the cutting ability and suppresses abrasion and damage on a cutting tool. Furthermore, Sr has effects of making Si particles disperse uniformly and finely at the steps of continuous casting, extrusion, drawing, etc., thereby further improving the cutting ability. If Sr content is less than 0.001 mass%, the aforementioned effects cannot be obtained sufficiently and the Si particle cannot be rounded, causing acute portions, which results in heavy abrasion of a cutting tool. To the contrary, if Sr exceeds 0.3 mass%, the aforementioned effects will be saturated, resulting in fruitless addition. Accordingly, Sr should be 0.001 - 0.3 mass%. Preferably, the Sr content is 0.005 - 0.05 mass%.
  • the second aluminum alloy according to the present invention (Claims 6 - 24) is an aluminum alloy containing the aforementioned four essential elements as basic compositions and further containing one or more arbitrary combined elements selected from the group consisting of eight elements, Cu, Fe, Mn, Cr, Zr, Ti, Na and Ca for the purpose of further improving various characteristics of the alloy.
  • Cu dissolves in an alloy matrix, while Cu bonds with Al and disperses in a matrix as deposit of CuAl 2 . This improves the mechanical property and cutting ability of an aluminum alloy by the synergistic effects with other dissolve type elements. If Cu content is less than 0.01 mass%, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Cu content exceeds 1 mass%, there is a possibility that corrosion resistance deteriorates. Accordingly, it is preferable that Cu content is 0.01 or more but less than 1 mass% . More preferably, the Cu content is 0.1 - 0.3 mass%.
  • Fe is an inevitable element contained in an aluminum alloy.
  • the content falling within the range of 0.01 - 1 mass% is a normal amount contained during manufacturing an aluminum alloy. Therefore, no special step for decreasing Fe content is required.
  • Fe content falls within the aforementioned range since only a few amount of Fe bonds with Si, which is effective to improve chip breaking effect, can be distributed as an individual particle, which can maintain outstanding chip breaking nature.
  • the cost increases.
  • Fe content exceeds 1 mass% Fe compounds with Si increase and Si individual particles decrease, resulting in deteriorated chip breaking nature. It is preferable that Fe content is 0.1 - 0.3 mass%.
  • Mn and Cr are elements to be added in order to improve mechanical strength by suppressing recrystallization in an aluminum alloy and enhance corrosion resistance. If Mn content and Cr content is less than 0.01 mass% respectively, it is difficult to obtain sufficient recrystallization inhibition effect and improve mechanical property and corrosion resistance. Furthermore, the chip breaking nature in the cross-sectional direction becomes unstable because of the recrystallized large particles. To the contrary, if the content exceeds 1 mass%, the hot deformation resistance at the time of extrusion increases, resulting in deteriorated productivity. Therefore, it is preferable that Mn content and Cr content are 0.01 - 1 mass% respectively.
  • Mn and Cr content falls within the aforementioned range, since only a few amount thereof bonds with Si, which is effective in improving chip breaking effect, can be distributed as an individual particle, which can maintain outstanding chip breaking nature. More preferable Mn content and Cr content are 0.1 - 0.3 mass%, respectively.
  • Zr is an elements to be added in order to improve mechanical strength by suppressing generation of large particle due to recrystallization in an aluminum alloy and enhance corrosion resistance. Furthermore, intermetallic compounds are formed by Zr and Al, and dispersed in a matrix. This improves cutting ability. If Zr content is less than 0.01 mass%, it is difficult to obtain sufficient recrystallization inhibition effect and improve mechanical property and corrosion resistance. Furthermore, the chip breaking nature in the cross-sectional direction becomes unstable because of the recrystallized large particles, and the cutting improvement effect is poor. To the contrary, if the content exceeds 1 mass%, the extrusion nature and/or castability deteriorates remarkably. Therefore, it is preferable that Zr content is 0.01 - 1 mass% . From this view point, more preferable Zr content is 0.1 - 0.3 mass%.
  • Ti is, similar to Zr, an elements to be added in order to improve mechanical strength by suppressing generation of large particle due to recrystallization in an aluminum alloy and enhance corrosion resistance. If Ti content is less than 0.01 mass%, it is difficult to obtain sufficient recrystallization inhibition effect and improve mechanical property and corrosion resistance. Furthermore, the chip breaking nature in the cross-sectional direction becomes unstable because of the recrystallized large particles, and the cutting improvement effect is poor. To the contrary, if the content exceeds 1 mass%, the extrusion nature and/or castability deteriorates remarkably. Therefore, it is preferable that Ti content is 0.01 - 1 mass%. From this view point, more preferable Ti content is 0.1 - 0.3 mass%.
  • Na and Ca are elements to be added, similar to the aforementioned Sr, in order to round Si particle and disperse Si particles uniformly. If Na content is less than 0.001 mass%, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Na content exceeds 0.5 mass%, the effects will be saturated. Accordingly, it is preferable that Na content is 0.001 - 0.5 mass%. If Ca content is less than 0.001 mass%, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Ca content exceeds 0.5 mass%, the effects will be saturated. Accordingly, it is preferable that Ca content is 0 . 001 - 0.5 mass% . More preferably, Malcontent is 0.005 - 0.3 mass%, Ca content is 0.005 - 0.3 mass%.
  • the aforementioned effects can be obtained by adding at least one element or two or more arbitrarily combined elements to the essential four elements.
  • the aluminum alloys as recited in claims 11 - 16 include selective additional element (s) in order to obtain a predetermined effect. In cases where two or more elements are added, it is also preferable to selectively combine two or more elements different in effect.
  • these selective additional elements are classified into: A group element (Cu) which improves mechanical property by deposit such as CuAl 2 ; B group element (Fe) which distributes Si as individual particles; C group element (Cr, Mn) which improves mechanical strength by suppressing recrystallization; D group element (Ti) which improves mechanical strength by suppressing generation of large and rough particles due to recrystallization and also improves corrosion resistance; E group element (Zr) which improves mechanical strength by suppressing generation of large and rough particles due to recrystallization, improves corrosion resistance and also improves cutting ability by forming intermetallic compounds; and F group elements (Na, Ca) which are effective in rounding Si particle and making Si particle into small pieces.
  • a group element (Cu) which improves mechanical property by deposit such as CuAl 2
  • B group element (Fe) which distributes Si as individual particles
  • C group element (Cr, Mn) which improves mechanical strength by suppressing recrystallization
  • D group element (Ti) which improves mechanical strength by suppressing generation of large
  • one or two or more arbitrarily combined groups are added to the essential elements.
  • the group comprising plural elements one or more elements are arbitrarily selected within the group. In cases where arbitrary additional elements are selected per one group, the content of each element should fall within the aforementioned range.
  • the aluminum alloy materials defines the chemical compositions of an alloy falling within the range of the aforementioned aluminum alloys (claims 1 - 24) and the mean particle diameter and mean aspect ratio of Si particle in an alloy texture.
  • Si particles improve cutting ability by serving as chip breaking origins at the time of cutting, it is required that Si particle is fine and spherical in order to suppress abrasion of a tool and that the mean particle diameter is 1 - 5 ⁇ m and the mean aspect ratio is 1 - 3.
  • Si particle has a tendency that the mean particle diameter and the mean aspect ratio become larger as the Si content increases. Although good cutting ability can be obtained even if the mean particle diameter exceeds 5 ⁇ m, a tool will be abraded heavily if the mean aspect ratio becomes larger. Accordingly, in this invention, in order to realize both good cutting ability and suppressed abrasion of a tool, the mean particle diameter and mean aspect ratio of Si particle are specified within the aforementioned range. From the viewpoint of obtaining outstanding cutting ability and suppressing abrasion of a tool, the preferable mean particle diameter of Si particle is 3 ⁇ m or less, and the preferable mean aspect ratio is two or less.
  • the aluminum alloys mentioned above can be manufactured by the method for manufacturing the first and second aluminum alloy materials respectively (Claims 28 - 35). That is, the alloy material in which fined and rounded Si particles are distributed uniformly can be manufactured by using an alloy having predetermined chemical compositions and specifying the processing conditions of from a casting and extrusion of a billet to a drawing of the extruded article and heat treatment conditions.
  • a billet is formed at the casting rate of 10 - 180 mm/min.
  • the Si-Sr compound in a molten metal serves as a nucleus, and rounded proeutectic Si and eutectic Si are dispersed in the aluminum.
  • fined and rounded Si particles can be obtained by the following heat treatment and extruding processing, or the drawing processing.
  • stable chip breaking nature can be obtained. If the casting rate is less than 10 mm/min., Si particle becomes larger and the particle distribution becomes rough. Therefore, stable chip breaking nature cannot be obtained. To the contrary, if the casting rate exceeds 180 mm/min., a casting surface may become bad or solidification crack may occur.
  • the preferable casting rate is 30 - 130 mm/min.
  • the homogenization processing of the billet is performed by holding the billet at 400 - 570 °C for 6 hours or more. Since this homogenization processing causes stable growth of Si particles and dissolving of other dissolve type elements, no partial segregation at the dendrite boundary zone or the crystal grain boundary occurs. Accordingly, the cutting ability, mechanical property and corrosion resistance of the finally obtained alloy material become good. If the homogenization processing performed at less than 400 °C, or for less than 6 hours, Si particle does not stably grows, and dissolve type elements are not dispersed, and not dissolved in the aluminum. Accordingly, corrosion resistance deteriorates at the segregated portion, and stable chip breaking nature cannot be obtained.
  • the preferable homogenization processing condition is to hold the billet at 500 - 545 °C for 10 hours or more.
  • the extrusion is performed at the billet temperature of 300 - 550 °C, the extrusion product rate of 0.5 - 100 m/min. and the extrusion ratio of 10 - 200.
  • Si particles will be dispersed uniformly at the crystal grain boundary without causing partial segregation, which does not spoil the cutting ability, mechanical property and corrosion resistance of the finally obtained alloy material.
  • the productivity will be also good. If the billet temperature is less than 300 °C, the extrusion rate will deteriorate, resulting in poor productivity. The productivity will also deteriorate when the extrusion product rate is less than 0.5 m/min.
  • the extrusion ratio is less than 10, the distributed state of Si particles will not become uniform, and Si particles will be partially segregated at the old dendrite boundary zone. This causes unstable cutting ability and deteriorated mechanical property and corrosion resistance.
  • the billet temperature exceeds 550 °C, the extrusion product rate exceeds 100 m/min. or the extrusion ratio exceeds 200, tears, pickups and the like arise on the surface of the extruded member, resulting in deteriorated surface quality.
  • the preferable billet temperature is 350 - 500 °C, the preferable extrusion product rate is 2 - 30 m/min., and the preferable extrusion ratio is 20 - 85.
  • the solution treatment after the extrusion is performed by holding the billet at 400 - 570 °C for 1 hour or more.
  • This solution treatment rounds Si particle, and therefore stable chip breaking nature can be obtained.
  • the solution treatment decreases the partial segregation at the crystal grain boundary of the additional element, and therefore high mechanical property and high corrosion resistance can be obtained.
  • the solution treatment condition is less than 400 °C or less than 1 hour, mechanical strength becomes insufficient and chip breaking nature becomes poor.
  • the temperature exceeds 570 °C partial fusion at the crystal grain boundary occurs, and mechanical property deteriorates remarkably.
  • the preferable solution treatment is performed by holding the billet at 500 - 545 °C at 3 hours or more.
  • the aging treatment is performed by holding the billet at 90 - 300 °C for 1 - 30 hours. This causes the maximum strength and good chip breaking nature of the aluminum alloy material. If the aging temperature is less than 90 °C or the holding time is less than 1 hour, the aging becomes insufficient, the finished surface at the time of cutting becomes rough and the mechanical property deteriorates. To the contrary, if the aging temperature exceeds 300°C or the aging time exceeds 30 hours , the aging becomes excessive, which deteriorates chip breaking nature and mechanical property. The preferable aging is performed by holding the billet at 140 - 200 °C for 3 - 20 hours.
  • the extruded member after the solution treatment is preferably drawn at a reduction rate of 5 - 30% into a predetermined configuration.
  • This drawing forms a predetermined configuration, and also can improve the mechanical property by fining the recrystallized structure of the surface formed at the time of extrusion. Furthermore, high dimensional accuracy in the longitudinal direction can be obtained. If the drawing reduction rate is less than 5%, the aforementioned effect becomes poor. To the contrary, if it exceeds 30%, tension breaks may occur at the time of drawing.
  • the preferable reduction is 10 - 20%.
  • the third and fourth aluminum alloys and the aluminum alloy materials including the chemical compositions thereof can further enhance the cutting ability due to Si particles obtained by the predetermined chemical compositions by further specifying the metal texture, and can suppress abrasion and damage on a cutting tool by controlling Si particle size.
  • the third aluminum alloy (claims 36 - 41) according to the present invention comprises these five elements and the balance being aluminum and impurities.
  • Mg is dissolved in an alloy matrix and dispersed as deposits such as Mg 2 Si created by bonding with Si, etc. in the matrix, to thereby enhance the mechanical property, especially proof strength and further improve the cutting ability of the alloy by the synergistic effect with other solid solution type elements.
  • the Mg content is less than 0.1 mass%, the aforementioned effects cannot be obtained sufficiently.
  • the Mg content exceeds 6 mass%, oxidation of an alloy molten metal is promoted and plastic-working nature also deteriorates. Accordingly, the Mg content should be 0.1 - 6 mass% .
  • the Mg content is 0.3 - 5 mass%.
  • Si Since only a few amount of Si can be dissolved in an aluminum, Si is dispersed in the matrix as a single particle of Si except for the amount required for compound formation. Especially, the eutectic Si particles solidified and formed by the quick cooling at the time of the continuous casting of this invention become fine particles of 5 ⁇ m or less, and form eutectic lamella texture together with other second phase particles at the dendrite boundary zone.
  • a cutting tool causes separation of the eutectic lamella texture, grinding of the eutectic Si particles, and/or interfacial peeling between the eutectic Si particles and the aluminum host phase. As a result, the chips become easy-to-break, which improves cutting ability remarkably.
  • the Si particles are rounded and fined by Sr added as an essential element or Na, Sb and Ca added as an arbitrary element, which also improves the cutting ability. If Si content is less than 0.3 mass%, chip breaking nature, i.e., cutting ability improving effects, cannot be obtained sufficiently. To the contrary, if Si content exceeds 12.5 mass%, although the cutting ability can be improved, many big and rough eutectic Si particles are formed. Therefore, cutting tool damages such as abrasion and/or chipping occur heavily, causing deteriorated productivity. Accordingly, it is necessary that Si content is 0.3 - 12.5 mass%. From this point of view, the preferable Si content is 0.8 - 12 mass%, more preferably 1.2 - 8.5 mass%.
  • Cu dissolves in an alloy matrix, while Cu bonds with Al and disperses in a matrix as deposit of CuAl 2 , etc. This improves the mechanical property and cutting ability of an aluminum alloy by the synergistic effects with other dissolve type elements. Furthermore, the CuAl 2 also exists in the eutectic lamella texture, and improves cutting ability by participating the separation of the eutectic lamella texture at the time of cutting. If Cu content is less than 0.01 mass%, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Cu content exceeds 1 mass%, corrosion resistance may deteriorate. Accordingly, the Cu content is 0.01 or more but less than 1 mass%. More preferably, the Cu content is 0.1 - 0.8 mass%.
  • Zn dissolves in an alloy matrix, while Zn bonds with Mg and disperses in a matrix as deposit of MgZn 2 , etc. This improves the mechanical property of the aluminum alloy and the cutting ability of the alloy by the synergistic effects of other dissolve type elements. If Zn content is less than 0.01 mass%, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Zn content exceeds 3 mass%, there is a possibility that corrosion resistance deteriorates. Accordingly, it is necessary that Zn content is 0.01 - 3 mass%.
  • the Zn content falls within the range, it is effective in improving an alumite coat generation rate, and therefore the alloy can'be suitably used for a product to which alumite processing is performed for the purpose of improving the abrasion resistance.
  • the preferable Zn content is 0.05 - 1.5 mass%.
  • Sr makes eutectic Si at the time of solidification and proeutectic Si round and fine when Sr coexists with Si. This indirectly improves the chip breaking nature, which in turn improves the cutting ability and suppresses abrasion and damage such as chipping on a cutting tool. Furthermore, Sr has effects of making Si particles disperse uniformly and finely at the steps of continuous casting and/or the following secondary forming processing, thereby further improving the cutting ability. If Sr content is less than 0.001 mass%, the aforementioned effects cannot be obtained sufficiently, and the Si particle cannot be rounded, causing acute portions, which results in heavy abrasion or damage such as chipping of a cutting tool. To the contrary, if Sr exceeds 0. 5 mass%, the aforementioned effects will be saturated, resulting in fruitless addition. The preferable Sr content is 0.005 - 0.3 mass%.
  • the fourth aluminum alloy according to the present invention is an aluminum alloy containing the aforementioned five essential elements as basic compositions and further containing one or more arbitrary combined elements selected from the group consisting of sixteen elements, Ti, B, C, Fe, Cr, Mn, Zr, V, Sc, Ni, Na, Sb, Ca, Sn, Bi and In for the purpose of further improving various characteristics of the alloy.
  • Ti makes an ingot texture fine, and suppresses appearance of macro patterns and/or solidification cracks, which will be generated on the cut surface when the ingot texture is rough. If Ti content is less than 0.001 mass%, an ingot fining effect is poor. To the contrary, if it exceeds 1 mass%, rough Ti-A1 series compounds will be formed, which may deteriorate castability and/or ductility of the aluminum alloy. Accordingly, it is preferable that Ti content is 0. 001 - 1 mass% . The more preferable Ti content is 0.003 - 0.5 mass%.
  • B makes an ingot texture fine like Ti, and suppresses appearance of macro patterns and/or solidification cracks, which will be generated on the cut surface when the ingot texture is rough. If B content is less than 0.0001 mass%, an ingot fining effect is poor. To the contrary, if it exceeds 0.03 mass%, hard particles will be formed, which may increase abrasion and/or damages such as chipping. Accordingly, it is preferable that B content is 0 . 0001 - 0. 03 mass% . The more preferable Ti content is 0.0005 - 0.01 mass%.
  • Fe is an element inevitably contained in an aluminum alloy.
  • the content falling within the range of 0.01 - 1 mass% is a normal amount contained during manufacturing an aluminum alloy. Therefore, no special step for decreasing Fe content is required.
  • Fe content falls within the aforementioned range since only a few amount of Fe bonds with Si, which is effective to improve chip breaking effect, can be distributed as an individual particle, which can maintain outstanding chip breaking nature.
  • the cost increases.
  • Fe content exceeds 1 mass% Fe compounds with Si increase and Si individual particles decrease, resulting in deteriorated chip breaking nature.
  • the more preferable Fe content is 0.05 - 0.7 mass%.
  • Zr and V make an ingot texture fine, and suppresses appearance of macro patterns and/or solidification cracks, which will be generated on the cut surface when the ingot texture is rough, like Ti and B. Furthermore, an intermetallic compound is formed between aluminum and cutting ability improves because they disperse to a matrix. If the content of each element is less than 0.01 mass%, the aforementioned effect is poor. To the contrary, if it exceeds 1 mass%, castability deteriorates. Accordingly, it is preferable that the content of each element is 0.01 - 1 mass% . The preferable content is 0.03 - 0.7 mass%. Furthermore, Zr has an effect of improving mechanical strength by suppressing the recrystallization and enhancing corrosion resistance, like below-mentioned Cr and Mn.
  • Zr content is 0.01 - 1 mass%, more preferably 0.03 - 0.7 mass%.
  • Cr and Mn are elements to be added in order to improve mechanical strength by suppressing recrystallization in an aluminum alloy and enhance corrosion resistance. If Cr content and Mn content are less than 0.01 mass% respectively, it is difficult to obtain sufficient recrystallization inhibition effect and improve mechanical property and corrosion resistance. Furthermore, the chip breaking nature in the cross-sectional direction becomes unstable because of the recrystallized large particles. To the contrary, if the content exceeds 1 mass%, the hot deformation resistance at the time of extrusion increases, resulting in deteriorated productivity. Therefore, it is preferable that Mn content and Cr content are 0.01 - 1 mass% respectively.
  • Mn and Cr content fall within the aforementioned range, since only a few amount thereof bonds with Si, which is effective in improving chip breaking effect, can be distributed as an individual particle, which can maintain outstanding chip breaking nature. More preferable Mn content and Cr content are 0.03 - 0.7 mass%, respectively.
  • Sc and C make an ingot texture fine, and suppresses appearance of macro patterns and/or solidification cracks, which will be generated on the cut surface when the ingot texture is rough, like Zr, V, B and Ti. If these elements are less than 0.0001 mass% respectively, the aforementioned effect cannot be obtained sufficiently. To the contrary, if they exceed 0.5 mass% respectively, they bond with aluminum or other elements to form hard particles, which causes heavy abrasion or damage on a cutting tool. Accordingly, it is preferable that the contents are 0.0001 - 0.5 mass%. Their more preferable contents are 0.01 - 0.3 mass%, respectively.
  • Ni forms Ni-Al series intermetallic compounds to improve cutting ability. If Ni content is less than 0.005 mass%, the aforementioned effect cannot be obtained sufficiently. To the contrary, if the content exceeds 1 mass%, castability and corrosion resistance deteriorates. Accordingly, it is preferable that Ni content is 0.005 - 1 mass%, more preferably 0.03 - 0.7 mass%.
  • each of these elements is less than 0.001 mass%, the aforementioned effects cannot be obtained sufficiently. To the contrary, if it exceeds 0. 5 mass%, the aforementioned effects will be saturated, resulting in fruitless addition. Accordingly, it is preferable that each content is 0.001 - 0.5 mass%, more preferably 0.005 - 0.3 mass%.
  • Sn, Bi and In further improve cutting ability when they coexist with Si.
  • the content thereof should be Sn: 0.01 - 1 mass%, Bi: 0.01 - 1 mass% and In: 0.001 - 0.5 mass%. If each content is below the lower limit, the aforementioned effects cannot be obtained sufficiently. To the contrary, if it exceeds the upper limit, the corrosion resistance deteriorates, and the quality of the finished surface also deteriorates since tears will be generated at the time of cutting, especially at the time of deep cutting. Furthermore, cracks will be induced at the time of the hot deformation.
  • Their preferable content is Sn: 0.05 - 0.5 mass%, Bi: 0.05 - 0.5 mass%, and In: 0.01 - 0.3 mass%.
  • the aforementioned effects can be obtained by adding at least one element or two or more arbitrarily combined elements to the essential five elements.
  • the aluminum alloys as recited in claims 48 - 54 include selective additional element(s) in order to obtain predetermined effects. In cases where two or more elements are added, it is also preferable to selectively combine two or more elements different in effect.
  • these selective additional elements are classified into: A group element (Ti, B, C and Sc) which has an effect of fining an ingot texture and suppressing an appearance of a macro pattern and solidification cracks; B group element (Fe) which distributes Si as individual particles; C group element (Cr and Mn) which improves mechanical strength by suppressing recrystallization; D group element (Zr and V) which has effects of fining an ingot texture and of suppressing an appearance of a macro pattern and solidification cracks, and further improves cutting ability due to the formation of intermetallic compounds; E group element (Ni) which improves cutting ability by forming intermetallic compounds; F group element (Na, Sb and Ca) which has an effect of rounding and fining Si particle; and G group element (Sn, Bi and In) which improves cutting ability when it coexists with Si.
  • a group element Ti, B, C and Sc
  • B group element (Fe) which distributes Si as individual particles
  • C group element (Cr and Mn) which improves mechanical strength by
  • one or more arbitrarily combined groups are added to the essential elements.
  • the group comprising plural elements one or more elements are arbitrarily selected within the group. In cases where arbitrary additional elements are selected per one group, the content of each element should fall within the aforementioned range.
  • the aluminum alloy materials as recited in claims 71 - 78 define the chemical compositions of an alloy so as to fall within the range of the aforementioned aluminum alloys as recited in claims 36 - 70, and specify the metal texture.
  • Figs. 1 and 2 show an example of metal texture of an aluminum alloy material manufactured by casting according to the present invention.
  • Fig. 3 shows an example of metal texture of an aluminum alloy material manufactured by performing processing such as heat treatment and extrusion after casting.
  • the aluminum alloy material shown in Fig. 3 corresponds to the alloy material mentioned in the paragraph entitled "BACKGROUND ART" and pointed out that a further improvement is required in respect of cutting ability and abrasion of a tool.
  • Figs. 1 and 2 the portion shown with light color (in Fig. 1, the portion indicated as proeutectic ⁇ -Al) is a dendrite.
  • eutectic lamella texture shown as dark colored portion
  • eutectic Si particles indicated as eutectic Si in Fig. 1
  • Fig. 3 showing the conventional aluminum alloy material reveals that the second phase of the dendrite boundary zone has been divided and Si particles have been changed to an independently distributed texture form.
  • the aluminum alloy material according to the present invention is made by considering the fact that the differences of the aforementioned metal textures influence cutting ability and abrasion and/or damage on a cutting tool. Concretely, the aluminum alloy material defines the dendrite arm spacing (hereinafter referred as "DAS") and the eutectic lamella texture formed at the dendrite boundary zone.
  • DAS dendrite arm spacing
  • the average DAS (see Fig. 1) is 1 - 200 ⁇ m.
  • the reason for limiting the average DAS within the aforementioned range is as follows. If the average DAS is less than 1 ⁇ m, although the cooling rate at the time of casting should be 1,000 °C/sec. or more, the cooling rate exceeds the manufacture limitation as an ingot member. To the contrary, if the average DAS exceeds 200 ⁇ m, cutting ability and mechanical property will remarkably deteriorate.
  • the preferable average DAS is 3 - 100 ⁇ m.
  • an eutectic lamella texture containing the eutectic Si particles each having a mean particle diameter of 0.01 - 5 ⁇ m and other second phase particles is formed in the aluminum host phase.
  • the eutectic Si particles even a single Si particle, become chip breaking origins, which improves cutting ability.
  • the eutectic Si particles form layer-like eutectic lamella texture, and the eutectic lamella texture can be separated as if the eutectic lamella texture is peeled off, which improves cutting ability. Since such eutectic lamella texture is distributed in a continuous three-dimensional network, the aforementioned separation occurs continuously.
  • the mean particle diameter of the eutectic Si particle is less than 0.01 ⁇ m, the cutting ability improvement effect is poor. Furthermore, The eutectic Si particle tends to increase in size as the Si content increases. If the mean particle diameter exceeds 5 ⁇ m, although good cutting ability can be obtained, a tool will be heavily abraded or damaged such as chipped as the grain size becomes larger. Accordingly, in order to realize both good cutting ability and suppression of tool damage, the mean particle diameter of eutectic Si particle is limited to 0.01 - 5 ⁇ m. Especially, from the viewpoint of suppressing tool damage, the preferable mean particle diameter is 0.1 - 3 ⁇ m.
  • the aforementioned other second phase particles are particles generated between Al, such as a CuAl 2 and Al-Fe-Si series, Al-Mn-Si series, Al-Cr-Si series and Al-Fe series, and an additional element.
  • the preferable mean particle diameter is 0.1 - 0.3 ⁇ m.
  • the size the eutectic lamella texture is represented by the skeleton line length (L) in the longitudinal direction and the width (W).
  • the skeleton line length (L) is the length of the skeleton line showing the frame of the eutectic lamella texture
  • the width (W) is the maximum width in the direction perpendicular to the skeleton line.
  • the eutectic lamella texture is defined by the mean values of the aforementioned length and width and the ratio thereof, wherein the mean skeleton line length (Lm) is 0.5 ⁇ m or more, and the mean width (Wm) is 0.5 ⁇ m or more.
  • the preferable average skeleton line length (Lm) is 3 ⁇ m or more, and the preferable average width (Wm) is 1 ⁇ m or more. Furthermore, it is preferable to be a long and slender configuration in which the mean value (L/Wm) of the ratio (L/W) of the skeleton line length (L) to the mean width (W) is 3 or more, because this configuration is excellent in continuous separation.
  • the eutectic Si particles and the other second phase particles constituting the eutectic lamella texture and the area share are specified, more excellent cutting ability can be obtained. That is, in the eutectic lamella texture, it is preferable that the eutectic Si particles and other second phase particles exist 500 pieces/mm 2 or more in total, and the area share of these particles is 0.1 - 50%. If the total number of particles is less than 500 pieces/mm 2 or the area share is less than 0.1%, the cutting ability improving effect becomes poor.
  • the number of eutectic Si particles and the area share tend to become larger as the Si content increases, and even if the area share exceeds 50%, good cutting ability can be obtained.
  • the area share exceeds 50%, the mechanical strength of the alloy material, especially the ductility ability (tensile strength) and the corrosion resistance, deteriorates. Therefore, the upper limit of the area share should be 50%.
  • the especially preferable total number of the eutectic Si particles and other second phase particles is 1,000 pieces/mm 2 or more, and the especially preferable area share is 0.3 - 40%.
  • the aluminum alloy material having the aforementioned metal texture is manufactured by the methods according to claims 79 - 89. That is, the alloy material having network-shaped eutectic lamella texture can be manufactured by using an alloy having a predetermined chemical compositions and specifying the terms and conditions of casting.
  • a molten aluminum alloy having predetermined chemical compositions and held at not less than the solidus temperature is continuously cast at the casting rate of 30 - 5,000 mm/min. and the cooling rate of 10 - 600 °C/sec. to form a shape member having a predetermined cross-section.
  • fine and rounded eutectic Si particles each having a nucleus of Si-Sr compound in a molten metal are dispersed in the aluminum, and dendrite grows up to mean DAS in the aforementioned range.
  • eutectic lamella texture containing eutectic Si particles and other second phase particles is formed in the shape of a network of a certain size.
  • the preferable casting rate is 50 - 3,000 mm/min., more preferably 100 - 2,000 mm/min.
  • the preferable cooling rate is 30 - 500 °C/sec., more preferably 30 - 300 °C/sec.
  • the continuous casting method is not limited to a specific one as long as the aforementioned casting conditions can be attained.
  • a vertical-type continuous casting process and a horizontal continuous casting process can be exemplified.
  • direct cooling can be recommended in order to attain the aforementioned cooling rate.
  • the cross-sectional configuration of the shape member to be cast is not limited at all.
  • a circular cross-section configuration, a polygonal cross-sectional configuration and, other heteromorphic cross-sectional configuration can be exemplified.
  • a non-hollow member can be recommended.
  • a hollow member which includes a hollow portion in a cross section is also included in the present invention.
  • the member has a cross section circumscribed to a circle with a diameter of 10 - 150 mm. If the diameter of the circumscribed circle is less than 10 mm, the molten metal flow deteriorates remarkably, which makes it difficult to form a predetermined configuration. To the contrary, if the diameter exceeds 150 mm, the cooling becomes insufficient due to the increased cross-section, which makes it difficult to attain the aforementioned cooling rate. As a result, it becomes difficult to form a network-shaped eutectic lamella texture, which in turn may cause deterioration of cutting ability.
  • the aging treatment to the continuously cast shape member is performed by holding the member at 100 - 300 °C for 0.5 - 100 hours. During this period, the element dissolved at the time of casting is deposited in the host phase, causing maximum mechanical strength and excellent cutting ability. If the aging temperature is less than 100 °C or the holding time is less than 0.5 hours, the aging becomes insufficient. Thus, the quality of the finished surface at the time of cutting deteriorates, and neither cutting ability nor mechanical strength increases. Furthermore, if the aging temperature exceeds 300 °C or the holding time exceeds 100 hours, the aging will be excessive, resulting in deteriorated cutting ability and decreased mechanical strength.
  • the preferable aging conditions are to hold the member at 120 - 220 °C for 1 - 30 hours.
  • the surface layer of the cast shape member includes heterogeneous layers, such as an inverse-segregation layer, a chill layer and a rough cell layer, which are formed at the time of solidification. Since the heterogeneous layers deteriorate the quality of shape member, it is preferable to remove the heterogeneous layers by eliminating the surface depth of 0.1 - 10 mm. If the elimination amount of the surface layers is less than 0.1 mm, the heterogeneous layer cannot be removed sufficiently. The elimination of 10 mm depth can exclude the heterogeneous layers assuredly. Elimination of more than 10 mm depth has no significance, and the materials will be wasted. The preferable elimination amount is 0.2 - 5 mm in depth. The surface layer elimination may be performed after the casting but before the aging, or after the aging but before the secondary-forming processing. Furthermore, the elimination method is not limited, and peeling processing and scalping processing can be exemplified.
  • the cast shape member may be subjected to secondary forming processing to form a predetermined shape before or after the aging.
  • the secondary forming processing method is not limited to a specific so long as the method is a plastic working method by which a cross-section area decreases. Drawing, extruding and rolling can be exemplified. It is preferable that the processing is performed under the conditions of: the working temperature of 400 °C or less; and the cross-sectional area reduction ratio (i.e. , cross-sectional area before processing/ cross-sectional area after processing) is 30% or less.
  • the eutectic Si particles dispersed in the eutectic lamella texture condenses to become rough and spherical shape, which deteriorates cutting ability. Furthermore, if the processing is performed so that the cross-sectional area reduction ratio exceeds 30%, the eutectic lamella texture is fractured, which deteriorates cutting ability and alloy material quality.
  • the preferable conditions of the secondary forming processing are: the working temperature of 250 °C or less and the cross-sectional area reduction ratio of 20% or less.
  • the heat treatment such as homogenization processing and solution treatment, before the aging treatment or before the secondary forming processing may be performed appropriately.
  • the aluminum alloy material cast according to the present invention or the member to which the secondary forming processing was performed after the casting is cut by a saw, a shear, etc.
  • the member may be cut into a short member less than 1 m in length, a long member 1 - 10 m in length or a blank member, these cut members are included in this invention irrespective of length.
  • the aluminum alloy more excellent in mechanical property can be obtained.
  • an aluminum alloy is more excellent in cutting ability can be obtained.
  • an aluminum alloy more excellent in mechanical property and alumite processability can be obtained.
  • Si particle can be further rounded and fined by Sr, or by Sr, Na and Ca
  • an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.
  • An aluminum alloy excellent in mechanical property, corrosion resistance, alumite processability and plastic-working nature because of the existence of Mg and Zn can be obtained.
  • Cu improves mechanical property.
  • Fe promotes dispersion of Si as an individual particle, which improves cutting ability.
  • Cr and Mn enhance mechanical strength.
  • Zr enhances mechanical strength, corrosion resistance and cutting ability.
  • Ti enhances mechanical strength and corrosion resistance.
  • the aluminum alloy more excellent in mechanical property can be obtained.
  • an aluminum alloy which is more excellent in cutting ability can be obtained.
  • an aluminum alloy which is more excellent in mechanical property and alumite processability can be obtained.
  • an aluminum alloy more excellent in mechanical property can be obtained.
  • an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.
  • an aluminum alloy more excellent in mechanical property, corrosion resistance and cutting ability can be obtained.
  • an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.
  • Si particle can be further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.
  • an aluminum alloy more excellent in mechanical property can be obtained.
  • Si can be dispersed as an individual particle, more excellent chip-breaking nature can be maintained.
  • an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.
  • an aluminum alloy more excellent in mechanical property, corrosion resistance and cutting ability can be obtained.
  • an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.
  • the aluminum alloy material since Si particle is fined and rounded, the aluminum alloy material has good chip breaking nature, and causes less abrasion and damage on a cutting tool. Furthermore, it is also excellent in mechanical property, alumite processability and plastic working nature by other additional elements.
  • the aluminum alloy material which has fined and rounded Si particles, has good chip breaking nature, causes less abrasion and damage on a cutting tool, and is excellent in mechanical property, alumite processability and plastic working nature.
  • an aluminum alloy material with the best cutting ability can be manufactured.
  • an aluminum alloy material with the best cutting ability, mechanical property and corrosion resistance can be manufactured.
  • an aluminum alloy material with the best cutting ability, mechanical property and corrosion resistance can be manufactured. Furthermore, productivity is also excellent.
  • an aluminum alloy material with the best mechanical property and corrosion resistance can be manufactured.
  • an aluminum alloy material with the best mechanical property can be manufactured.
  • an aluminum alloy material which has fined surface recrystallized structure, and is excellent especially in mechanical property can be manufactured.
  • an aluminum alloy material whose mechanical property is further improved can be manufactured.
  • an aluminum alloy more excellent in mechanical property can be obtained.
  • an aluminum alloy more excellent in mechanical property and cutting ability can be obtained.
  • an aluminum alloy more excellent in mechanical property and alumite processability can be obtained.
  • Si particle can be further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.
  • Si particle is fined and rounded by Sr, or Sr and any one of Na, Sb and Ca, and eutectic lamella texture is formed at the dendrite boundary zone, it is possible to obtain an aluminum alloy material comprised of this alloy which is excellent in cutting ability and causes less abrasion and damage on a cutting tool.
  • Mg, Zn and Cu improve mechanical property, especially tensile characteristics, corrosion resistance, alumite processability and plastic working nature.
  • any one of Ti, B, C and Sc causes fined ingot texture and suppresses appearance of macro patterns and solidification cracks.
  • Fe promotes dispersion of Si as an individual particle, which improves cutting ability.
  • Cr and Mn improve mechanical strength.
  • Zr or V fines ingot texture suppresses appearance of macro patterns and solidification cracks, and further improves cutting ability by forming intermetallic compounds.
  • Ni forms intermetallic compounds, which improves cutting ability. Any one of Sn, Bi and In improves cutting ability.
  • an aluminum alloy more excellent in mechanical property can be obtained.
  • an aluminum alloy more excellent in cutting ability can be obtained.
  • an aluminum alloy more excellent in mechanical property and cutting ability can be obtained.
  • an aluminum alloy more excellent in mechanical property and alumite processability can be obtained.
  • Si particle can be further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.
  • an aluminum alloy in which ingot texture is fined and appearance of macro patterns and solidification cracks are suppressed can be obtained.
  • Si can be dispersed as an individual particle, more excellent chip-breaking nature can be maintained.
  • an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.
  • an aluminum alloy in which ingot texture is fined, appearance of macro patterns and solidification cracks are suppressed and cutting ability is excellent, can be obtained.
  • an aluminum alloy more excellent in cutting ability can be obtained.
  • Si particle can be further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.
  • an aluminum alloy more excellent in cutting ability can be obtained.
  • Si can be dispersed as an individual particle, more excellent chip-breaking nature can be maintained.
  • an, aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.
  • an aluminum alloy in which ingot texture is fined, appearance of macro patterns and solidification cracks are suppressed and cutting ability is excellent, can be obtained.
  • an aluminum alloy in which ingot texture is fined and appearance of macro patterns and solidification cracks are suppressed can be obtained.
  • an aluminum alloy more excellent in cutting ability can be obtained.
  • eutectic Si particles can be served as chip breaking origins independently, cutting ability is improved. Furthermore, since eutectic lamella texture can be continuously separated, cutting ability is improved. Furthermore, since the eutectic Si particles are fined and rounded, abrasion and damage on a cutting tool can be suppressed. Furthermore, this aluminum alloy is also excellent in mechanical property, especially tensile characteristics, corrosion resistance, alumite processability and plastic-working nature.
  • an aluminum alloy material which is more excellent in cutting ability and capable of suppressing abrasion and damage on a cutting tool can be obtained.
  • an aluminum alloy material which is further improved in cutting ability and mechanical characteristics can be obtained.
  • abrasion and damage on a cutting tool can be suppressed while keeping excellent cutting ability.
  • an aluminum alloy material which is further improved in cutting ability can be obtained.
  • an aluminum alloy material which is further improved in cutting ability can be obtained.
  • cutting ability can be further improved, and abrasion and damage on a cutting tool can be suppressed.
  • cutting ability can be further improved, and abrasion and damage on a cutting tool can be suppressed.
  • the aluminum alloy material that has eutectic Si particles and eutectic lamella texture, causes less abrasion and damage on a cutting tool while keeping outstanding cutting ability, and is excellent in mechanical property, especially tensile characteristics, corrosion resistance, alumite processability and plastic-working nature.
  • the aforementioned eutectic Si particles and aforementioned eutectic lamella texture can be formed assuredly.
  • a non-hollow member having the aforementioned eutectic Si particles and eutectic lamella texture can be manufactured.
  • Aluminum alloys of compositions of Al Nos. I-1 - I-17 shown in Table 1 were prepared.
  • the alloy Nos. I-1 and I-2 include Mg, Si, Zn and Sr, and the balance being aluminum and impurities, and the compositions correspond to claims 1 - 5 of the present invention.
  • the alloys Nos. I-3 to I-12 include eight optional selective elements in the aforementioned elements, and the compositions correspond to claims 6 - 24.
  • the alloys Nos. I-13 to I-17 are comparative compositions.
  • round bars were made by billet casting, extrusion, and drawing.
  • a billet was made at the casting rate of 80 mm/min. by DC casting.
  • the billet was homogenized by holding at 520 °C for 10 hours, and then extruded into a round bar with a diameter of 15 mm at the billet temperature of 450 °C, the extrusion product rate of 12 m/min., and the extrusion ratio of 35.
  • This extruded member is held at 540 °C for 3 hours for a solution treatment, then drawn at the reduction rate of 25%, and aged by holding at 160 °C for 5 hours to thereby obtain a test piece.
  • test piece was wet cut using a superhard chip at the cutting rate of 150 m/min., the feeding rate of 0.2 mm/rev. to form a slit of 1.0 mm depth.
  • the chip breaking nature was evaluated by chip number/100g.
  • a salt spray test based on JIS Z2371 was performed, and the corrosion resistance was measured by the corrosion weight loss due to 1,000 hours spray.
  • Continuous cutting for 5 minutes is performed under the conditions of cutting rate of 200 m/min. , feeding rate of 0. 2 mm/rev., and slitting of 10 mm by dry type cutting using a high-speed slab cutting-edge byte, and the abrasion width of the byte's flank was measured.
  • Sulfuric acid alumite processing was conducted by a conventional method, and evaluation was performed by the thickness of the generated alumite coat.
  • Aluminum alloys having compositions of alloy Nos. IIA-1 to IIA-129 shown in Tables 3 - 8 were prepared. Each of the alloy Nos. IIA-1 to IIA-30 includes Mg, Si, Cu, Zn, Sr and the balance being aluminum and impurities. The compositions correspond to claims 36 - 41 of the invention. Alloys Nos. IIA-1 to IIA-10 are comparative compositions. Alloys Nos. IIA-41 to IIA-108 (except for IIA-93, 94 and 97) have the basic compositions of Alloy No. IIA-30, and Alloys Nos. IIA-109 to IIA-129 have the basic compositions of Alloy No. IIA-10. Furthermore, sixteen optional selective elements are added to the above alloys.
  • Alloy No. IIA-94 has basic compositions of Alloy No. IIA-7 (Mg: 1 mass%, Si: 0.8 mass%, Cu: 0.2 mass%, Zn: 0.2 mass%, Sr: 0.03 mass%), Alloys Nos. IIA-93 and 97 have basic compositions of Alloy (Mg: 1 mass%, Si: 1.5 mass%, Cu: 0.2 mass%, Zn: 0.2 mass%, Sr: 0.03 mass%). Optional additional elements are added to the above alloys. Alloys Nos. IIA-41 to IIA-129 are compositions corresponding to claims 42 - 70.
  • the reference numeral "1" denotes a mold for forming the external periphery of an ingot
  • "2" denotes a cylindrical molten metal receiving tub disposed at the upper portion of the mold 1.
  • the mold 1 has an annular cavernous portion 3 for circulating a cooling medium such as water therein.
  • This cavernous portion 3 is provided with a plurality of port mouths 4 opening toward the outside.
  • the cooling medium C introduced into the cavernous portion 3 through an introductory tubing which is not illustrated performs a primary cooling of the cast member S by cooling the mold 1, and is spouted from the port mouths 4 to perform a secondary cooling of the casting S.
  • the inner upper surface 1a of the mold 1 is lower than the exterior upper surface 1b, to thereby form a gap 6 opened to a gas passage 5 between the inner upper surface 1a and the lower surface of the molten metal tub 2.
  • the lower inner part of the molten metal tub 2 is protruded horizontally toward the inner side of the mold 1 to form an over hang portion 7. Accordingly, the pressurized gas F introduced into the gas passage 5 through the gas introduction passage 8 from the exterior is introduced under the overhang portion 7 from the gap 6. This excludes the molten metal from the region immediately under the over hang portion 7 to thereby make the molten metal contact to the inner peripheral surface of the mold 1 at the position far below the upper end of the mold 1.
  • the contact distance between the molten metal and the mold 1 is controlled by the flow rate of the pressurized gas F, which in turn controls the primary cooling time and the solidification process to obtain a cast member S excellent in metal texture.
  • "M" shows the overhang amount of the overhang portion 7.
  • lubricating oil is introduced into a supply passage 9 from the exterior through a passage which is not illustrated, and supplied to the inner peripheral surface of the mold 1 through numeral fine feed mouths 10 branched from the supply passage 9.
  • "11" denotes a heat-resistant packing member fitted in the slot cut in the upper surface of the mold 1 to prevent the leak of the gas passing through the gap 6.
  • the casting rate and cooling rate of the present invention can be attained, and a cast member with outstanding characteristics, such as cutting ability, can be manufactured.
  • the casting conditions were the casting conditions b shown in the following Table 9, and all of the alloys were continuously cast successfully.
  • the mechanical properties such as 0.2% proof strength, tensile strength, fracture elongation (tensile characteristics), were measured, and the homogeneity of metal texture, plastic-working nature, cutting ability, abrasion of a tool, quality of the machined surface, corrosion resistance, alumite processability were examined by the following method. Then, except for the mechanical properties, they were evaluated relatively by comparing with various characteristics of the extruded member consist of JIS A6262 alloy in the five following grades.
  • Continuous cutting for 5 minutes is performed under the conditions of cutting rate of 200 m/min. , feeding rate of 0. 2 mm/rev. , and slitting of 10 mm by dry type cutting using a high-speed slab cutting-edge byte, and the abrasion width of the byte's flank was measured.
  • a salt spray test based on JIS Z2371 was performed, and the corrosion resistance was measured by the corrosion weight loss due to 1,000 hours spray.
  • Sulfuric acid alumite processing was conducted by a conventional method, and evaluation was performed by the thickness of the generated alumite coat.
  • the aluminum alloy of compositions according to the present invention has outstanding homogeneity of metal texture, plastic-working nature, cutting ability (including quality of finished surface and cutting crack nature), corrosion resistance and alumite processability, and that abrasion of a tool can also be suppressed at the time of cutting.
  • the manufacturing test of aluminum alloy materials were performed using IIA-30 (Table 4) and IIA-127 (Table 8) among the alloys of the above-mentioned compositions.
  • casting Nos. IIB-1, IIB-2, IIB-5 and IIB-6 they were cast by the vertical-type continuous casting method.
  • casting Nos. IIB-3, IIB-4, IIB-7 and IIB-8 they were cast by the horizontal continuous casting method.
  • Each cast member was formed into a non-hollow member (round bar) having a round cross-section.
  • the detail of the casting method and casting conditions are as follows.
  • casting Nos. IIB-9, IIB-10 were cast by a metal mold.
  • the reference numeral "20" denotes a mold
  • "21” denotes a tundish
  • "22” denotes a fire resistance conductor for introducing molten metal into the mold 20 from the tundish 21.
  • "23” and “24” denote fire resistance plates for specifying the opening diameter of the molten metal inlet 32 from the conductor 22 to the mold 20.
  • the mold 20 has an annular cavernous portion 25 in which cooling medium C such as water circulates, and is provided with a plurality of port mouths 26 opened from the cavernous portion 25 toward the outside.
  • the mold 20 has the annular cavernous portion 25 which circulates cooling mediums C, such as water, to the inside, and a plurality of port mouths 26 which perform opening outside from this cavernous portion 25 are formed.
  • the cooling medium C introduced into the cavernous portion 25 through an introductory tubing which is not illustrated performs a primary cooling of the cast member S by cooling the mold 20, and is blown off from the port mouth 26 to perform a secondary cooling of the casting S.
  • lubricating oil is introduced into a supply passage 28 via a passage 27 from the exterior, and is supplied to the inner peripheral surface 20a of the mold 20 via a number of supply canaliculus 29 branched from the supply passage 28.
  • the casting rate and cooling rate of the present invention can be attained, and a cast member having outstanding characteristics, such as cutting ability, can be manufactured.
  • the cast molds Nos. IIB-9 and IIB-10 which are comparative examples, are ingots obtained by the sand-mold type test mold (ISO mold) under the casting conditions shown in the following Table 11.
  • the metal texture of each of these test pieces was observed, and the average DAS, the distribution state of the particle in the eutectic lamella texture, (the mean particle diameter of the eutectic Si particle, the number of particles and the area share of the eutectic Si particles and the second phase particles), the eutectic lamella texture size (the mean skeleton line length Lm, the mean width Wm, these ratio L/Wm) were examined.
  • the main points of the manufacture conditions of each casting example are again shown in Table 11, the observation results of the metal texture are shown in Table 11.
  • the aluminum alloy material manufactured by the method of this invention has an eutectic lamella texture where Si particles are dispersed finely in the metal texture, and therefore has outstanding cutting ability (including quality of finished surface and cutting crack nature) and corrosion resistance.
  • the metallic material impact test based on JIS Z2202 and JIS Z2242 was performed, and the impact property was evaluated by the charpy impact.
  • the aluminum alloy material of the invention is excellent in cutting ability, the member can be applied to materials of various kinds of member accompanied by cutting processing. Furthermore, since no toxic Pb is contained, not bad influence is given to the environment and recycle nature is also preferable. Therefore, the material is excellent from the viewpoint of earth environment protection.

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EP02755647A 2001-07-25 2002-07-25 Alliage d'aluminium presentant une excellente usinabilite, et materiau d'alliage d'aluminium et son procede de production Revoked EP1413636B9 (fr)

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PCT/JP2002/007517 WO2003010349A1 (fr) 2001-07-25 2002-07-25 Alliage d'aluminium presentant une excellente usinabilite, et materiau d'alliage d'aluminium et son procede de production

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WO2011134486A1 (fr) * 2010-04-26 2011-11-03 Sapa Ab Matériau à base d'aluminium tolérant aux dommages à microstructure stratifiée
CN103025901A (zh) * 2010-04-26 2013-04-03 萨帕有限公司 具有分层的微结构的损伤容限性铝材料
CN103025901B (zh) * 2010-04-26 2017-03-08 萨帕有限公司 具有分层的微结构的损伤容限性铝材料
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WO2012075993A3 (fr) * 2010-12-02 2012-08-23 Eads Deutschland Gmbh Procédé de fabrication d'un alliage alscca et alliage alscca
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US9982329B2 (en) 2013-02-06 2018-05-29 Ksm Castings Group Gmbh Aluminum casting alloy
US20180087132A1 (en) * 2016-09-29 2018-03-29 Samsung Electronics Co., Ltd. Aluminum alloy for die casting and method for manufacturing the same
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CN112921215A (zh) * 2021-01-19 2021-06-08 江苏大学 一种可铸旋和锻旋加工的汽车轮毂铝合金、制备方法、汽车轮毂及其制备方法
CN112921215B (zh) * 2021-01-19 2022-02-15 江苏大学 一种可铸旋和锻旋加工的汽车轮毂铝合金、制备方法、汽车轮毂及其制备方法
NO20220521A1 (en) * 2022-05-05 2023-11-06 Norsk Hydro As AlSiMgX MASTER ALLOY AND USE OF THE MASTER ALLOY IN THE PRODUCTION OF AN ALUMINIUM FOUNDRY ALLOY

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CN1555423A (zh) 2004-12-15
EP1413636A4 (fr) 2005-11-16
CA2454509A1 (fr) 2003-02-06
JPWO2003010349A1 (ja) 2004-11-18
DE60231046D1 (de) 2009-03-19
EP1413636B1 (fr) 2009-01-28
ATE422000T1 (de) 2009-02-15
EP1413636B9 (fr) 2009-10-21
WO2003010349A1 (fr) 2003-02-06
JP2009024265A (ja) 2009-02-05
JP4227014B2 (ja) 2009-02-18

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