CN102333749B - 取代的亚苯基芳族二酯的生产方法 - Google Patents

取代的亚苯基芳族二酯的生产方法 Download PDF

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Publication number
CN102333749B
CN102333749B CN200980157529.1A CN200980157529A CN102333749B CN 102333749 B CN102333749 B CN 102333749B CN 200980157529 A CN200980157529 A CN 200980157529A CN 102333749 B CN102333749 B CN 102333749B
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China
Prior art keywords
tert
butyl
methyl
methylcatechol
aromatic
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Expired - Fee Related
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Chinese (zh)
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CN102333749A (zh
Inventor
T.W.里昂
G.A.罗思
T.陶
K.高
陈林枫
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WR Grace and Co
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Dow Global Technologies LLC
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/14—Preparation of carboxylic acid esters from carboxylic acid halides
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/01—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis
    • C07C37/02—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis by substitution of halogen
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    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
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    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by condensation involving hydroxy groups of phenols or alcohols or the ether or mineral ester group derived therefrom
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
    • C07C37/56—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms by replacing a carboxyl or aldehyde group by a hydroxy group
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
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    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/653—Pretreating with metals or metal-containing compounds with metals of C08F4/64 or compounds thereof
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    • C08F4/00—Polymerisation catalysts
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
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    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
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    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Catalysts (AREA)
  • Emergency Medicine (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CN200980157529.1A 2008-12-31 2009-12-31 取代的亚苯基芳族二酯的生产方法 Expired - Fee Related CN102333749B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US14195908P 2008-12-31 2008-12-31
US14190208P 2008-12-31 2008-12-31
US61/141,902 2008-12-31
US61/141,959 2008-12-31
PCT/US2009/069942 WO2010078512A2 (en) 2008-12-31 2009-12-31 Production of substituted phenylene aromatic diesters

Publications (2)

Publication Number Publication Date
CN102333749A CN102333749A (zh) 2012-01-25
CN102333749B true CN102333749B (zh) 2015-04-22

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Application Number Title Priority Date Filing Date
CN200980157533.8A Active CN102741341B (zh) 2008-12-31 2009-12-31 丙烯抗冲共聚物和方法
CN200980157206.2A Expired - Fee Related CN102325809B (zh) 2008-12-31 2009-12-31 提高的前催化剂组合物和方法
CN2009801574975A Expired - Fee Related CN102333796B (zh) 2008-12-31 2009-12-31 基于丙烯的聚合物、制品、和生产它们的方法
CN201510373023.1A Active CN105037590B (zh) 2008-12-31 2009-12-31 丙烯抗冲共聚物和方法
CN200980157530.4A Expired - Fee Related CN102482376B (zh) 2008-12-31 2009-12-31 丙烯无规共聚物组合物，制品及方法
CN200980157529.1A Expired - Fee Related CN102333749B (zh) 2008-12-31 2009-12-31 取代的亚苯基芳族二酯的生产方法

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Application Number Title Priority Date Filing Date
CN200980157533.8A Active CN102741341B (zh) 2008-12-31 2009-12-31 丙烯抗冲共聚物和方法
CN200980157206.2A Expired - Fee Related CN102325809B (zh) 2008-12-31 2009-12-31 提高的前催化剂组合物和方法
CN2009801574975A Expired - Fee Related CN102333796B (zh) 2008-12-31 2009-12-31 基于丙烯的聚合物、制品、和生产它们的方法
CN201510373023.1A Active CN105037590B (zh) 2008-12-31 2009-12-31 丙烯抗冲共聚物和方法
CN200980157530.4A Expired - Fee Related CN102482376B (zh) 2008-12-31 2009-12-31 丙烯无规共聚物组合物，制品及方法

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Country Link
US (7) US8106138B2 (OSRAM)
EP (5) EP2373703B1 (OSRAM)
JP (7) JP5607647B2 (OSRAM)
KR (5) KR101695995B1 (OSRAM)
CN (6) CN102741341B (OSRAM)
BR (5) BRPI0918697A8 (OSRAM)
MX (6) MX2011007151A (OSRAM)
MY (5) MY159677A (OSRAM)
RU (5) RU2527036C2 (OSRAM)
SG (5) SG172438A1 (OSRAM)
WO (5) WO2010078503A1 (OSRAM)

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