RU2011132141A - Получение замещенных фенилен-ароматических сложных диэфиров - Google Patents

Получение замещенных фенилен-ароматических сложных диэфиров Download PDF

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RU2011132141A
RU2011132141A RU2011132141/04A RU2011132141A RU2011132141A RU 2011132141 A RU2011132141 A RU 2011132141A RU 2011132141/04 A RU2011132141/04 A RU 2011132141/04A RU 2011132141 A RU2011132141 A RU 2011132141A RU 2011132141 A RU2011132141 A RU 2011132141A
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tert
butyl
bmpd
formation
methylcatechol
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Так В. ЛЕУНГ
Гари А. РОТ
Тао ТАО
Куаньцян ГАО
Линьфэн ЧЭНЬ
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ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи.
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Abstract

1. Способ, включающий:взаимодействие в реакционных условиях 5-трет-бутил-3-метилкатехина (ВМС) с соединением, выбранным из группы, состоящей из ароматической карбоновой кислоты и производного ароматической карбоновой кислоты; иобразование 5-трет-бутил-3-метил-1,2-фенилен дибензоата (BMPD).2. Способ по п.1, включающий очистку BMPD и образование композиции BMPD, содержащей более 98% BMPD.3. Способ по п.1, включающий добавление бензоилхлорида к реакционной смеси, содержащей ВМС, ацетонитрил и триэтиламин и образование BMPD.4. Способ по п.1, включающий добавление воды к реакционной смеси и осаждение BMPD.5. Способ по п.1, включающий растворение осажденного BMPD и экстракцию водой.6. Способ по п.5, включающий образование композиции BMPD, содержащей более 98 мас.% BMPD.7. Способ по п.1, включающий:алкилирование в реакционных условиях 3-метилкатехина соединением, выбранным из группы, состоящей из трет-бутанола и изобутилена; иобразование 5-трет-бутил-3-метилкатехина.8. Способ по п.1, включающий:окисление в реакционных условиях 5-трет-бутил-3-метил-2-гидроксибензальдегида; иобразование 5-трет-бутил-3-метилкатехина.9. Способ по п.1, включающий:окисление в реакционных условиях 4-трет-бутил-2-метилфенола; иобразование 5-трет-бутил-3-метилкатехина.10. Способ по п.1, включающий:гидролиз в реакционных условиях 2-галоген-4-трет-бутил-6-метилфенола; иобразование 5-трет-бутил-3-метилкатехина.

Claims (10)

1. Способ, включающий:
взаимодействие в реакционных условиях 5-трет-бутил-3-метилкатехина (ВМС) с соединением, выбранным из группы, состоящей из ароматической карбоновой кислоты и производного ароматической карбоновой кислоты; и
образование 5-трет-бутил-3-метил-1,2-фенилен дибензоата (BMPD).
2. Способ по п.1, включающий очистку BMPD и образование композиции BMPD, содержащей более 98% BMPD.
3. Способ по п.1, включающий добавление бензоилхлорида к реакционной смеси, содержащей ВМС, ацетонитрил и триэтиламин и образование BMPD.
4. Способ по п.1, включающий добавление воды к реакционной смеси и осаждение BMPD.
5. Способ по п.1, включающий растворение осажденного BMPD и экстракцию водой.
6. Способ по п.5, включающий образование композиции BMPD, содержащей более 98 мас.% BMPD.
7. Способ по п.1, включающий:
алкилирование в реакционных условиях 3-метилкатехина соединением, выбранным из группы, состоящей из трет-бутанола и изобутилена; и
образование 5-трет-бутил-3-метилкатехина.
8. Способ по п.1, включающий:
окисление в реакционных условиях 5-трет-бутил-3-метил-2-гидроксибензальдегида; и
образование 5-трет-бутил-3-метилкатехина.
9. Способ по п.1, включающий:
окисление в реакционных условиях 4-трет-бутил-2-метилфенола; и
образование 5-трет-бутил-3-метилкатехина.
10. Способ по п.1, включающий:
гидролиз в реакционных условиях 2-галоген-4-трет-бутил-6-метилфенола; и
образование 5-трет-бутил-3-метилкатехина.
RU2011132141/04A 2008-12-31 2009-12-31 Получение замещенных фенилен ароматических сложных диэфиров RU2553475C2 (ru)

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US14190208P 2008-12-31 2008-12-31
US14195908P 2008-12-31 2008-12-31
US61/141,959 2008-12-31
US61/141,902 2008-12-31
PCT/US2009/069942 WO2010078512A2 (en) 2008-12-31 2009-12-31 Production of substituted phenylene aromatic diesters

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RU2011132063/04A RU2518067C2 (ru) 2008-12-31 2009-12-31 Ударопрочный пропиленовый сополимер и способ его получения
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