CN100370561C - 碳质材料、双电层电容器的可极化电极和双电层电容器 - Google Patents
碳质材料、双电层电容器的可极化电极和双电层电容器 Download PDFInfo
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- CN100370561C CN100370561C CNB011357916A CN01135791A CN100370561C CN 100370561 C CN100370561 C CN 100370561C CN B011357916 A CNB011357916 A CN B011357916A CN 01135791 A CN01135791 A CN 01135791A CN 100370561 C CN100370561 C CN 100370561C
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- Prior art keywords
- polarizable electrode
- layer capacitor
- carbonaceous material
- electric layer
- double electric
- Prior art date
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- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
- C01B32/312—Preparation
- C01B32/342—Preparation characterised by non-gaseous activating agents
- C01B32/348—Metallic compounds
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
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- H—ELECTRICITY
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- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/44—Raw materials therefor, e.g. resins or coal
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
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- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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- Power Engineering (AREA)
- Materials Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Carbon And Carbon Compounds (AREA)
- Paints Or Removers (AREA)
- Inorganic Fibers (AREA)
Abstract
Description
实施例 | 对比实施例1 | ||||
1 | 2 | 3 | |||
大于10埃的孔 | 体积(cc/g) | 0.07 | 0.05 | 0.07 | 0.13 |
体积比(%) | 70 | 83.3 | 70 | 11.3 | |
最大10埃的孔 | 体积(cc/g) | 0.03 | 0.01 | 0.03 | 1.02 |
体积比(%) | 30 | 16.7 | 30 | 88.7 | |
累计平均颗粒尺寸(微米) | 2.4 | 1.5 | 19 | 7.5 | |
BET比表面积(m<sup>2</sup>/g) | 90 | 52 | 79 | 1969 |
孔半径(A) | 实施例3 | 对比实施例1 | ||
孔体积(cc/g) | 孔比例(%) | 孔体积(cc/g) | 孔比例(%) | |
至少400,但小于500 | 0.00067 | 0.99 | 0 | 0 |
至少300,但小于400 | 0.00702 | 10.34 | 0.00481 | 3.57 |
至少200,但小于300 | 0.00618 | 9.1 | 0.00191 | 1.42 |
至少100,但小于200 | 0.01791 | 26.38 | 0.01483 | 11.02 |
至少50,但小于100 | 0.01198 | 17.64 | 0.01313 | 9.75 |
至少40,但小于50 | 0.00362 | 5.33 | 0.00538 | 4 |
至少30,但小于40 | 0.00439 | 6.47 | 0.00874 | 6.49 |
至少20,但小于30 | 0.00768 | 11.31 | 0.01763 | 13.1 |
至少10,但小于20 | 0.00841 | 12.39 | 0.06817 | 50.64 |
小于10 | - | - | - | - |
细分(pbw) | EX7 | EX8 | EX9 | EX10 | EX11 | CE2 |
碳质材料 | EX1 | EX2 | EX3 | EX1 | EX1 | CE1 |
100 | 100 | 100 | 100 | 100 | 100 | |
聚合物粘合剂 | Syn.Ex.4 | Syn.Ex.4 | Syn.Ex.4 | Syn.Ex.4 | PVDF<sup>1)</sup> | Syn.Ex.4 |
5 | 5 | 5 | 5 | 5 | 5 | |
导电材料<sup>2)</sup> | 5 | 5 | 5 | - | 5 | 5 |
实施例 | CE2 | ||||||||
4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | ||
电极密度(g/cm<sup>3</sup>) | 0.72 | 0.78 | 0.75 | 0.72 | 0.92 | 0.6 | 0.7 | 0.75 | 0.45 |
自然电势(v) | 2.3 | 2.3 | 2.2 | 2.3 | 2.6 | 2.4 | 2.3 | 2.3 | 3.0 |
容量(F/cc) | 13.8 | 13.0 | 13.7 | 15.3 | 14.0 | 8.8 | 10.8 | 15.7 | 14.9 |
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JP2000315563A JP2002128514A (ja) | 2000-10-16 | 2000-10-16 | 炭素質材料、電気二重層キャパシタ用分極性電極及び電気二重層キャパシタ |
JP315563/2000 | 2000-10-16 |
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- 2001-10-15 CA CA002358776A patent/CA2358776A1/en not_active Abandoned
- 2001-10-15 EP EP01308740A patent/EP1255261A1/en not_active Withdrawn
- 2001-10-16 KR KR1020010063675A patent/KR100604208B1/ko not_active IP Right Cessation
- 2001-10-16 TW TW090125584A patent/TW559846B/zh not_active IP Right Cessation
- 2001-10-16 CN CNB011357916A patent/CN100370561C/zh not_active Expired - Fee Related
- 2001-10-16 US US09/977,361 patent/US6574092B2/en not_active Expired - Fee Related
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104157841A (zh) * | 2014-08-14 | 2014-11-19 | 陕西理工学院 | 用于钠离子电池的复合纤维电极材料制备工艺 |
CN104157841B (zh) * | 2014-08-14 | 2016-03-23 | 陕西理工学院 | 用于钠离子电池的复合纤维电极材料制备工艺 |
Also Published As
Publication number | Publication date |
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KR20020030030A (ko) | 2002-04-22 |
EP1255261A1 (en) | 2002-11-06 |
CA2358776A1 (en) | 2002-04-16 |
KR100604208B1 (ko) | 2006-07-24 |
US20020126439A1 (en) | 2002-09-12 |
US6574092B2 (en) | 2003-06-03 |
EP1255261A8 (en) | 2003-01-08 |
TW559846B (en) | 2003-11-01 |
CN1349234A (zh) | 2002-05-15 |
JP2002128514A (ja) | 2002-05-09 |
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