BRPI0700623A - partìculas de fosfato, polifosfato e metafosfato de alumìnio e seu uso com pigmentos em tintas e método de sua produção - Google Patents

partìculas de fosfato, polifosfato e metafosfato de alumìnio e seu uso com pigmentos em tintas e método de sua produção

Info

Publication number
BRPI0700623A
BRPI0700623A BRPI0700623-3A BRPI0700623A BRPI0700623A BR PI0700623 A BRPI0700623 A BR PI0700623A BR PI0700623 A BRPI0700623 A BR PI0700623A BR PI0700623 A BRPI0700623 A BR PI0700623A
Authority
BR
Brazil
Prior art keywords
composition
aluminum
polyphosphate
aluminum phosphate
particles
Prior art date
Application number
BRPI0700623-3A
Other languages
English (en)
Inventor
Joao De Brito
Fernando Galembeck
Original Assignee
Bunge Fertilizantes Sa
Unicamp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bunge Fertilizantes Sa, Unicamp filed Critical Bunge Fertilizantes Sa
Publication of BRPI0700623A publication Critical patent/BRPI0700623A/pt
Publication of BRPI0700623B1 publication Critical patent/BRPI0700623B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40—Compounds of aluminium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/36—Aluminium phosphates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/38—Condensed phosphates
    • C01B25/40—Polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/38—Condensed phosphates
    • C01B25/44—Metaphosphates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C01B25/451—Phosphates containing plural metal, or metal and ammonium containing metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/68—Particle size between 100-1000 nm
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/327—Aluminium phosphate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

PARTìCULAS DE FOSFATO, POLIFOSFATO E METAFOSFATO DE ALUMìNIO E SEU USO COMO PIGMENTOS EM TINTAS E MéTODO DE SUA PRODUçãO. Uma composição de fosfato de alumínio que compreende fosfato de alumínio, polifosfato de alumínio, metafosfato de alumínio, ou uma mistura destes. A composição pode ser caracterizada por, quando na forma de pó, ter partículas em que algumas das partículas possuem pelo menos um ou mais vazios per partícula. Além disso, a composição é caracterizada pela apresentação de dois picos endotérmicos na Calorimetria de Varredura Diferencial entre cerca de 90 graus a cerca de 250 graus Celsius. A composição é também caracterizada por, quando na forma de pá, ter uma capacidade de dispersão de pelo menos 0,025 gramas per 1,0 grama de água. A composição é produzida por um processo que compreende o contato de ácido fosfórico com sulfato de alumínio e uma solução alcalina para produzir um produto com base em fosfato de alumínio; e opcionalmente calcinar o produto com base em fosfato, polifosfato ou metafosfato de alumínio em uma temperatura elevada. A composição é útil em tintas e como um substituto para o dióxido de titânio.
BRPI0700623-3A 2006-02-27 2007-02-27 Partículas de fosfato, polifosfato e metafosfato de alumínio e seu uso como pigmentos em tintas e método de sua produção. BRPI0700623B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/364,798 US7763359B2 (en) 2004-08-30 2006-02-27 Aluminum phosphate, polyphosphate and metaphosphate particles and their use as pigments in paints and method of making same
US11/364,798 2006-02-27

Publications (2)

Publication Number Publication Date
BRPI0700623A true BRPI0700623A (pt) 2007-10-16
BRPI0700623B1 BRPI0700623B1 (pt) 2022-09-20

Family

ID=37964851

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0700623-3A BRPI0700623B1 (pt) 2006-02-27 2007-02-27 Partículas de fosfato, polifosfato e metafosfato de alumínio e seu uso como pigmentos em tintas e método de sua produção.

Country Status (14)

Country Link
US (3) US7763359B2 (pt)
EP (1) EP1878700B1 (pt)
JP (2) JP2007230861A (pt)
KR (1) KR101386283B1 (pt)
CN (2) CN104497687B (pt)
AR (1) AR060319A1 (pt)
AU (1) AU2007200684B2 (pt)
BR (1) BRPI0700623B1 (pt)
CA (1) CA2579268C (pt)
CO (1) CO5840269A1 (pt)
EA (1) EA024005B1 (pt)
MY (1) MY159519A (pt)
NO (1) NO20071089L (pt)
UY (1) UY30172A1 (pt)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0403713B1 (pt) * 2004-08-30 2021-01-12 Universidade Estadual De Campinas - Unicamp processo de fabricação de um pigmento branco baseado na síntese de partículas ocas de ortofosfato ou polifosfato de alumínio
US7763359B2 (en) * 2004-08-30 2010-07-27 Bunge Fertilizantes S.A. Aluminum phosphate, polyphosphate and metaphosphate particles and their use as pigments in paints and method of making same
CA2613596A1 (en) * 2005-06-27 2007-01-04 Applied Thin Films, Inc. Aluminum phosphate based microspheres
UY30532A1 (es) 2006-08-11 2008-03-31 Bunge Fertilizantes Sa Preparacion de particulas de fosfato o polifosfato de aluminio solicitudes relacionadas
US9023145B2 (en) * 2008-02-12 2015-05-05 Bunge Amorphic Solutions Llc Aluminum phosphate or polyphosphate compositions
AR075381A1 (es) * 2009-02-10 2011-03-30 Unicamp Uso de particulas de fosfato, polifosfato y metafosfato, de aluminio en aplicaciones de recubrimiento de papeles.
US9371454B2 (en) * 2010-10-15 2016-06-21 Bunge Amorphic Solutions Llc Coating compositions with anticorrosion properties
US9005355B2 (en) * 2010-10-15 2015-04-14 Bunge Amorphic Solutions Llc Coating compositions with anticorrosion properties
US20120094130A1 (en) * 2010-10-15 2012-04-19 Universidade Estadual De Campinas Coating Compositions With Anticorrosion Properties
RU2468997C1 (ru) * 2011-09-06 2012-12-10 Леонид Асхатович Мазитов Способ очистки сточных вод от ионов алюминия
US9078445B2 (en) 2012-04-16 2015-07-14 Bunge Amorphic Solutions Llc Antimicrobial chemical compositions
US9611147B2 (en) 2012-04-16 2017-04-04 Bunge Amorphic Solutions Llc Aluminum phosphates, compositions comprising aluminum phosphate, and methods for making the same
US9155311B2 (en) * 2013-03-15 2015-10-13 Bunge Amorphic Solutions Llc Antimicrobial chemical compositions
US9475942B2 (en) 2012-12-07 2016-10-25 Bunge Amorphic Solutions Llc Aluminum phosphate composite materials and compositions
KR20170010793A (ko) * 2014-05-30 2017-02-01 코닝 인코포레이티드 알루미늄 메타인산 볼 밀링 방법
EP2987834A1 (de) * 2014-08-18 2016-02-24 Kronos International, Inc. Verfahren zur Oberflächenbeschichtung von anorganischen Partikeln mit Siliciumdioxid und mindestens einer weiteren anorganischen Verbindung
EP3325571B1 (en) 2015-07-17 2019-05-01 Merck Patent GmbH Luminescent particle, ink formulation, polymer composition, optical device, fabrication thereof, and use of the luminescent particle
US10124530B2 (en) * 2015-09-22 2018-11-13 Xerox Corporation Color shift pigments for three-dimensional printing
CN106183488A (zh) * 2016-07-11 2016-12-07 鹏码实业(上海)有限公司 一种用于防伪的磁性热转印色带及其制备方法
CN115215311B (zh) * 2021-04-21 2023-12-12 中国石油化工股份有限公司 磷酸铝溶胶及其制备方法和应用以及催化裂化催化剂及其制备方法
CN113740200A (zh) * 2021-08-31 2021-12-03 广西产研院新型功能材料研究所有限公司 一种用于检测三聚磷酸铝中组分含量的方法
CN114249988A (zh) * 2021-12-10 2022-03-29 湖北富邦新材料有限公司 一种用于控制化肥颜色的耐低温水性色浆及应用
CN114715867B (zh) * 2022-04-13 2023-06-16 华南理工大学 磷酸铝粉末及其制备方法、辐射散热涂料及其制备方法和应用

Family Cites Families (173)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1654404A (en) * 1924-12-23 1927-12-27 Stockholders Syndicate Acid metal phosphate and process of making same
US2222199A (en) 1937-07-01 1940-11-19 Paper Patents Co Pigmented paper and process of making same
US2222196A (en) 1939-05-22 1940-11-19 David Housman Radio receiving system
US2909451A (en) 1956-04-27 1959-10-20 American Cyanamid Co Process for preparing aluminum phosphate dispersion and process of treating pile fabric with the resulting dispersion
US3394987A (en) * 1964-08-04 1968-07-30 Armour & Co Reacting calcium carbonated and wet process phosphoric acid
DE1767460C3 (de) * 1968-05-13 1978-05-18 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von kondensierten Aluminiumphosphaten
GB1373627A (en) 1970-12-11 1974-11-13 Ici Ltd Coated films
US3801704A (en) * 1971-03-15 1974-04-02 Teikoku Kako Co Ltd Aluminum phosphate and a producing method therefor
GB1379562A (en) 1971-10-19 1975-01-02 Ici Ltd Complex phosphates
DE2152228C3 (de) 1971-10-20 1980-03-27 Giulini Chemie Gmbh, 6700 Ludwigshafen Verfahren zur Herstellung eines therapeutisch wirksamen Aluminiumphosphat-Gels
ES413746A1 (es) * 1972-06-21 1976-01-16 Knapsack Ag Procedimiento para la preparacion de fosfatos de aluminio condensados.
US3926905A (en) * 1973-06-13 1975-12-16 Osaka Soda Co Ltd Flame retardant hardenable composition of water glass and decorative products made by using the same
JPS5319345Y2 (pt) 1974-12-17 1978-05-23
ZA766238B (en) * 1975-11-05 1978-01-25 Thyssen Huette Ag Improvements in or relating to acid-resistant cement
JPS5281312A (en) * 1975-12-27 1977-07-07 Showa Baamikiyuraito Kk Incombustible smokeless materials and manufacture
US4054678A (en) 1976-03-30 1977-10-18 Stauffer Chemical Company Sodium aluminum phosphate
US4111884A (en) * 1976-04-19 1978-09-05 Dai Nippon Toryo Co., Ltd. Anticorrosion primer coating composition
DE2621170A1 (de) * 1976-05-13 1977-11-24 Hoechst Ag Verfahren zur herstellung von aluminiumpolyphosphat
JPS5632554Y2 (pt) 1976-07-08 1981-08-03
JPS5632556Y2 (pt) 1976-07-27 1981-08-03
US4122231A (en) * 1976-09-01 1978-10-24 Showa Vermiculite Kabushiki Kaisha Noncombustible, smokeless building composite material and its method of manufacture
JPS5632553Y2 (pt) 1976-12-02 1981-08-03
DE2709189A1 (de) * 1977-03-03 1978-09-07 Hoechst Ag Haerter fuer wasserglaskitte und verfahren zur herstellung solcher haerter
US4127157A (en) 1977-03-07 1978-11-28 Ashland Oil, Inc. Aluminum phosphate binder composition cured with ammonia and amines
US4098749A (en) * 1977-03-24 1978-07-04 Dai Nippon Toryo Co., Ltd. Anticorrosion primer coating composition
FR2386486A1 (fr) * 1977-04-07 1978-11-03 Montedison Spa Bioxyde de chrome ferromagnetique stabilise et son procede de preparation
JPS585871B2 (ja) * 1977-04-09 1983-02-02 日本坩堝株式会社 流動鋳込用耐火材
JPS5359725U (pt) 1977-09-19 1978-05-22
US4216190A (en) * 1978-12-26 1980-08-05 Ppg Industries, Inc. Method for making β-form aluminum trimetaphosphate
US4260591A (en) 1978-12-21 1981-04-07 Stauffer Chemical Company Process for preparing alkali metal aluminum phosphate
GB2042573B (en) 1978-12-21 1983-01-12 Tioxide Group Ltd Titanium dioxide pigment
US4227932A (en) * 1979-02-21 1980-10-14 Pennwalt Corporation Single component potassium silicate cement for dry gunning
JPS55160059U (pt) 1979-05-04 1980-11-17
JPS5632555U (pt) 1979-08-17 1981-03-30
FR2464921A1 (fr) * 1979-09-07 1981-03-20 Grp Franco Senegal Etud Procede de traitement d'un phosphate aluminocalcique
GB2038791B (en) 1979-12-24 1982-12-08 Ppg Industries Inc Method for making b-form aluminum trimetaphosphate
JPS56131671U (pt) 1980-03-10 1981-10-06
JPS56152765A (en) * 1980-04-30 1981-11-26 Kansai Paint Co Ltd Formation of olefin resin coating film
US4418048A (en) * 1980-06-10 1983-11-29 Laporte Industries Limited Aluminophosphorus compounds
US4898660A (en) * 1980-07-07 1990-02-06 Union Carbide Corporation Catalytic uses of crystalline metallophosphate compositions
US4333914A (en) * 1980-11-26 1982-06-08 Ppg Industries, Inc. Method for making aluminum trimetaphosphates from powder reactants
US4329327A (en) * 1980-11-26 1982-05-11 Ppg Industries, Inc. Method for making B-form aluminum trimetaphosphate from powder reactants
US4319926A (en) * 1980-12-22 1982-03-16 Ppg Industries, Inc. Curable silicate compositions containing condensed phosphate hardeners and pH controlling bases
US4364855A (en) * 1980-12-31 1982-12-21 Phillips Petroleum Company Production of aluminum phosphate from concentrated mass
US4444962A (en) * 1980-12-31 1984-04-24 Phillips Petroleum Company Polymerization process using catalysts with acid gelled aluminum phosphate base
US4444965A (en) * 1980-12-31 1984-04-24 Phillips Petroleum Company Olefin polymerization using chromium on an aluminum phosphate produced from a concentrated mass
US4364854A (en) * 1980-12-31 1982-12-21 Phillips Petroleum Company Acid gelling aluminum phosphate from concentrated mass and catalyst containing same
JPS57158267U (pt) 1981-03-31 1982-10-05
US4383866A (en) * 1981-05-04 1983-05-17 Ppg Industries, Inc. Metal condensed phosphate hardener coated with reaction product from a metal aluminate and/or a metal borate
US4328033A (en) * 1981-05-04 1982-05-04 Ppg Industries, Inc. Curable silicate composition containing metal condensed phosphate hardener coated with reaction product from a metal aluminate and/or a metal borate
US4375496A (en) * 1981-05-04 1983-03-01 Ppg Industries, Inc. Metal condensed phosphate hardener coated with reaction product from a metal aluminate and/or a metal borate
FR2507920B1 (fr) * 1981-06-22 1986-05-16 Rhone Poulenc Spec Chim Support de catalyseur, notamment de catalyseur de post-combustion et procede de fabrication de ce support
DE3133354A1 (de) * 1981-08-22 1983-03-24 Hoechst Ag, 6000 Frankfurt "haerter fuer wasserglaskitte"
US4395387A (en) * 1981-10-13 1983-07-26 Pennwalt Corporation Method for manufacturing water glass cement hardeners
US4457899A (en) * 1981-11-23 1984-07-03 Mobil Oil Corporation Process for removal of residual organic matter from purified phosphoric acid
US4487862A (en) * 1982-03-12 1984-12-11 Nissan Motor Company, Limited Thermosetting resin composition for injection molding and article formed by using the composition
US4435219A (en) * 1982-06-02 1984-03-06 Ppg Industries, Inc. Stable inorganic coating composition for adherent, inorganic coatings
US4518513A (en) * 1982-11-03 1985-05-21 Schiedel Gmbh & Co. Pasty damping medium method for preparing and using same
JPS59123571A (ja) * 1982-12-28 1984-07-17 Dainippon Toryo Co Ltd 防食性の優れた厚膜型塗膜を形成する方法
JPS59147943U (ja) 1983-03-24 1984-10-03 バンドー化学株式会社 多突条ベルト伝動装置
DE3327176A1 (de) * 1983-07-28 1985-02-07 Hoechst Ag, 6230 Frankfurt Einkomponenten-alkalisilikat- zementzusammensetzung
US4542001A (en) * 1983-08-22 1985-09-17 Mitsui Toatsu Chemicals, Inc. Fine particulate crystalline aluminum orthophosphate and method for preparing same
JPS60215091A (ja) 1984-04-11 1985-10-28 Hayakawa Rubber Co Ltd シ−ル材
US4547479A (en) * 1984-07-02 1985-10-15 Phillips Petroleum Company Polyphosphate in chromium catalyst support
US4640964A (en) * 1984-07-02 1987-02-03 Phillips Petroleum Company Olefin polymerization with polyphosphate supported chromium catalysts
JPS6198773A (ja) * 1984-08-28 1986-05-17 Honda Motor Co Ltd 耐熱被覆組成物
JPS61101566U (pt) 1984-12-10 1986-06-28
US4567152A (en) 1984-12-13 1986-01-28 Exxon Research And Engineering Co. Co-matrixed zeolite and p/alumina
BR8506634A (pt) * 1984-12-20 1986-09-09 Rhone Poulenc Sante Composicoes para o revestimento de aditivos alimentares destinados aos ruminantes e granulados sob forma de microcapsulas assim revestidos
US4717701A (en) * 1985-01-04 1988-01-05 Phillips Petroleum Company Olefin polymerization
US4622371A (en) * 1985-01-04 1986-11-11 Phillips Petroleum Company Olefin polymerization
JPS61286209A (ja) 1985-06-11 1986-12-16 Teikoku Kako Kk 縮合リン酸アルミニウムの製造方法
US5030431A (en) 1985-08-29 1991-07-09 W. R. Grace & Co.-Conn. High pore volume and pore diameter aluminum phosphate
FR2595344B1 (fr) * 1986-03-04 1988-06-24 Centre Nat Rech Scient Procede de preparation de cristaux de berlinite a haut coefficient de surtension
JPS62207705A (ja) * 1986-03-04 1987-09-12 Taki Chem Co Ltd 結晶質りん酸アルミニウム及びその製造方法
US4782109A (en) 1986-06-26 1988-11-01 Lindsay Finishes, Incorporated Latex paint formulations and methods
US4758281A (en) * 1986-09-12 1988-07-19 International Minerals & Chemical Corp. Anti-corrosive protective coatings
JPS63105023A (ja) * 1986-10-20 1988-05-10 Sunstar Giken Kk エポキシ樹脂組成物の製造法
DE3636604A1 (de) * 1986-10-28 1988-05-05 Bayer Ag Verfahren zur herstellung von polyurethanformkoerpern
US4743572A (en) 1986-12-05 1988-05-10 Mobil Oil Corporation Magnesia-alumina-aluminum phosphate catalyst and catalyst product thereof
JPS63101454U (pt) 1986-12-22 1988-07-01
JP2740222B2 (ja) * 1987-02-13 1998-04-15 フイナ・リサーチ・ソシエテ・アノニム 改良されたシヨツプ・プライマー組成物の製造方法
US5374411A (en) 1987-08-28 1994-12-20 The Dow Chemical Company Crystalline aluminumphosphate compositions
JPH01110567A (ja) 1987-10-23 1989-04-27 Teikoku Kako Co Ltd 防錆顔料組成物
JPH0660296B2 (ja) 1988-03-15 1994-08-10 住友軽金属工業株式会社 熱交換器用内面防食塗装皮膜付き銅合金管
CA1312533C (en) 1988-03-25 1993-01-12 Paul Blattler Chromate-free wash primer
JPH01249638A (ja) 1988-03-30 1989-10-04 Seto Yogyo Genryo Kk 水ガラス用硬化剤の製法
JPH01167381U (pt) 1988-05-11 1989-11-24
DE3824354A1 (de) * 1988-07-19 1990-01-25 Basf Ag Verfahren zur herstellung von zellhaltigen kunststoffen nach dem polyisocyanat-polyadditionsverfahren mittels lagerstabiler, treibmittelhaltiger emulsionen und diese emulsionen
DE3913328A1 (de) * 1989-04-22 1990-10-25 Basf Ag Verbundelemente mit verbesserter bestaendigkeit gegen spannungsrisskorrosion, insbesondere fuer kuehlmoebelgehaeuse
US5108755A (en) 1989-04-27 1992-04-28 Sri International Biodegradable composites for internal medical use
DE3933335C2 (de) 1989-10-06 1998-08-06 Basf Ag Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen mit geringer Wärmeleitfähigkeit und ihre Verwendung
DE4021086A1 (de) 1990-07-03 1992-01-09 Heubach Hans Dr Gmbh Co Kg Korrosionsschutzpigmente auf der basis von tertiaeren erdalkali-aluminium-phosphaten und verfahren zu ihrer herstellung
JP2941014B2 (ja) 1990-08-03 1999-08-25 神東塗料株式会社 高防蝕塗膜の形成方法
JP3033995B2 (ja) 1990-08-03 2000-04-17 オキツモ株式会社 脱臭材およびそれを用いた製品
CA2055693A1 (en) 1990-12-20 1992-06-21 Hermann L. Rittler Phosphorous polymers
US5242744A (en) 1991-10-11 1993-09-07 General Electric Company Silicone flame retardants for thermoplastics
BR9104581A (pt) * 1991-10-23 1993-04-27 Unicamp Processo de obtencao de pigmentos brancos
JPH06179866A (ja) 1991-11-19 1994-06-28 Teika Corp 変色防止剤含有シーリング組成物
US5296027A (en) 1992-01-28 1994-03-22 Hoechst Aktiengesellschaft Single-component alkali metal silicate cement composition
US5256253A (en) 1992-08-24 1993-10-26 Betz Paperchem Inc. Methods for inhibiting barium sulfate deposition using a poly(amine)compound or its salts in papermaking systems
US5208271A (en) 1992-11-02 1993-05-04 Basf Corporation Flexible polyurethane foams with reduced tendency for shrinkage
US5552361A (en) * 1993-11-04 1996-09-03 W. R. Grace & Co.-Conn. Aluminum phosphate composition with high pore volume and large pore diameter, process for its production and use thereof
DE4237145A1 (de) 1992-11-04 1994-05-11 Grace Gmbh Aluminiumphosphatzusammensetzung mit hohem Porenvolumen und großem Porendurchmesser, Verfahren zu deren Herstellung und deren Verwendung
FR2702757B1 (fr) 1993-03-17 1995-06-16 Rhone Poulenc Chimie Nouveau phosphate d'aluminium, son procede de preparation et son utilisation dans la preparation de materiaux comprenant un liant et de pieces ceramiques .
JP3014561B2 (ja) 1993-04-02 2000-02-28 東洋鋼鈑株式会社 加工性および耐食性に優れた潤滑鋼板
JP3046198B2 (ja) 1994-03-01 2000-05-29 東洋鋼鈑株式会社 耐摩耗性，耐指紋性および耐白化性に優れた表面処理鋼板
US5534130A (en) 1994-06-07 1996-07-09 Moltech Invent S.A. Application of phosphates of aluminum to carbonaceous components of aluminum production cells
JPH07330451A (ja) 1994-06-10 1995-12-19 Kurosaki Refract Co Ltd 熱硬化性不定形耐火物とその施工方法
US5486232A (en) 1994-08-08 1996-01-23 Monsanto Company Glass fiber tacking agent and process
JP3051642B2 (ja) 1994-09-05 2000-06-12 東洋鋼鈑株式会社 深絞り性に優れた潤滑鋼板
JPH08268704A (ja) 1995-03-28 1996-10-15 Teika Corp 防錆顔料組成物
JPH08283619A (ja) 1995-04-14 1996-10-29 Teika Corp 防錆顔料組成物およびそれを含有する防錆塗料
US5783510A (en) 1995-07-04 1998-07-21 Asahi Glass Company Ltd. Monolithic refractory composition wall
GB9514388D0 (en) 1995-07-13 1995-09-13 Tioxide Group Services Ltd Titanium dioxide pigments
JPH0959562A (ja) 1995-08-29 1997-03-04 Dainippon Toryo Co Ltd 塗料組成物
JP2729935B2 (ja) 1995-10-31 1998-03-18 大日本塗料株式会社 溶射被膜の封孔処理方法及び封孔材料
FR2754541B1 (fr) 1996-10-15 1998-12-24 Air Liquide Procede et installation pour la separation d'un melange d'hydrogene et/ou d'au moins un hydrocarbure et/ou d'azote et/ou d'oxyde de carbone
US6022513A (en) * 1996-10-31 2000-02-08 Pecoraro; Theresa A. Aluminophosphates and their method of preparation
JPH10139923A (ja) 1996-11-13 1998-05-26 Inax Corp 抗菌性樹脂組成物
JP3440325B2 (ja) 1996-12-02 2003-08-25 テイカ株式会社 防錆顔料及び塗料組成物
JPH10195179A (ja) 1997-01-08 1998-07-28 Shin Etsu Chem Co Ltd 半導体封止用エポキシ樹脂組成物及び半導体装置
JPH10235782A (ja) 1997-02-28 1998-09-08 Nisshin Steel Co Ltd 意匠性に優れたフィルムラミネート鋼板
KR100241127B1 (ko) 1997-05-01 2000-02-01 전성도 자동차용 내장재의 성형방법
JP3340946B2 (ja) 1997-07-18 2002-11-05 キョーワ株式会社 メッシュシート用難燃剤とこれを用いた防炎メッシュシート
EP0930347B1 (en) 1997-07-31 2008-10-08 Nippon Chemical Industrial Company Limited Rust-preventive pigment composition and rust-preventive paints containing the same
ATA40398A (de) 1998-03-09 1999-09-15 Wolfgang Dr Schwarz Elektrisch leitende mikrokapillare verbundmatrix und verfahren zu deren herstellung
TWI221861B (en) 1998-04-22 2004-10-11 Toyo Boseki Agent for treating metallic surface, surface-treated metal material and coated metal material
DE19826624A1 (de) 1998-06-18 1999-12-23 Merck Patent Gmbh Pigmentpräparation
US6002513A (en) * 1998-06-22 1999-12-14 Lucent Technologies Inc. Optical modulator providing independent control of attenuation and spectral tilt
ES2141062B1 (es) 1998-06-25 2000-11-01 Erplip S A Procedimiento para la fabricacion de carton estucado para envasado de liquidos.
EP1050603B1 (en) 1998-11-08 2007-01-10 JFE Steel Corporation Surface treated steel sheet having excellent corrosion resistance
JP3054866B1 (ja) 1998-12-14 2000-06-19 キョーワ株式会社 建設工事現場に展張するメッシュシート用難燃剤とこれを用いた建設工事現場に展張する防炎メッシュシート
JP3380858B2 (ja) 1999-03-31 2003-02-24 旭ファイバーグラス株式会社 無機質系成形品の製造方法
JP4662213B2 (ja) 1999-04-21 2011-03-30 関西ペイント株式会社 カチオン電着塗料
CA2305973C (en) 1999-04-21 2008-10-07 Kansai Paint Co., Ltd. Cationically electrodepositable coating material
KR100416086B1 (ko) 1999-11-17 2004-01-31 삼성에스디아이 주식회사 크로스 토크를 방지하는 플라즈마 디스플레이 패널의 격벽평탄화 방법
US6797155B1 (en) 1999-12-21 2004-09-28 Exxonmobil Research & Engineering Co. Catalytic cracking process using a modified mesoporous aluminophosphate material
US6447741B1 (en) 1999-12-21 2002-09-10 Exxonmobil Oil Corporation Thermally stable, high surface area, modified mesoporous aluminophosphate material
DE10001437A1 (de) 2000-01-15 2001-07-19 Eckart Standard Bronzepulver Fließ- und pumpfähiges Metallpigment-Halbfabrikat zur Herstellung von Farben und Lacken
US6890648B2 (en) 2000-02-03 2005-05-10 Nisshin Steel Co., Ltd. CR-free paint compositions and painted metal sheets
CA2380384C (en) 2000-04-21 2005-08-02 Nkk Corporation Surface treated steel plate and method for production thereof
CA2344836A1 (en) 2000-04-24 2001-10-24 Kansai Paint Co., Ltd. Electrodeposition coating composition
JP4693207B2 (ja) 2000-05-23 2011-06-01 関西ペイント株式会社 カチオン電着塗料
US6461415B1 (en) 2000-08-23 2002-10-08 Applied Thin Films, Inc. High temperature amorphous composition based on aluminum phosphate
US6983571B2 (en) 2000-09-29 2006-01-10 Teel Plastics, Inc. Composite roofing panel
JP3636666B2 (ja) 2001-01-29 2005-04-06 独立行政法人科学技術振興機構 多孔質体及びその製造方法
WO2002060999A1 (en) 2001-02-02 2002-08-08 Primex Metal Coatings, Ltd. Anti-rust coating
US6646058B1 (en) 2001-02-21 2003-11-11 The Sherwin-Williams Company Water-borne paint composition having improved hiding and scrub-resistance
US6749769B2 (en) 2001-03-09 2004-06-15 E. I. Du Pont De Nemours And Company Crystalline compositions of doped aluminum phosphate
DE10113287A1 (de) 2001-03-16 2002-10-02 Bk Giulini Chem Gmbh & Co Ohg Verwendung von polymeren Aluminiumphosphaten in Putzformulierungen
JP2003202643A (ja) 2001-10-23 2003-07-18 Konica Corp 写真フィルム収納容器用金属材料および写真フィルム収納容器
JP4162884B2 (ja) 2001-11-20 2008-10-08 信越化学工業株式会社 耐食性希土類磁石
US7101820B2 (en) 2002-03-06 2006-09-05 E. I. Du Pont De Nemours And Company Crystalline compositions of doped aluminum phosphate
JP3935012B2 (ja) 2002-07-18 2007-06-20 日本化学工業株式会社 改質赤燐、その製造方法、消色化赤燐組成物及び難燃性高分子組成物
US7678465B2 (en) 2002-07-24 2010-03-16 Applied Thin Films, Inc. Aluminum phosphate compounds, compositions, materials and related metal coatings
JP2005535554A (ja) * 2002-08-14 2005-11-24 アプライド シン フィルムズ，インコーポレイティッド リン酸アルミニウム化合物、組成物、材料及び関連複合体
US20040071887A1 (en) 2002-10-10 2004-04-15 Basf Corporation Coating compositions having improved "direct to metal" adhesion and method therefore
US6881782B2 (en) 2002-11-06 2005-04-19 3M Innovative Properties Company Latex paint compositions and coatings
US20040092637A1 (en) 2002-11-12 2004-05-13 Basf Corporation Electronic display of automotive colors
US8021758B2 (en) 2002-12-23 2011-09-20 Applied Thin Films, Inc. Aluminum phosphate compounds, coatings, related composites and applications
WO2005003033A2 (en) 2002-12-23 2005-01-13 Applied Thin Films, Inc. Aluminum phosphate coatings
US7763359B2 (en) 2004-08-30 2010-07-27 Bunge Fertilizantes S.A. Aluminum phosphate, polyphosphate and metaphosphate particles and their use as pigments in paints and method of making same
BRPI0403713B1 (pt) 2004-08-30 2021-01-12 Universidade Estadual De Campinas - Unicamp processo de fabricação de um pigmento branco baseado na síntese de partículas ocas de ortofosfato ou polifosfato de alumínio
US20080085965A1 (en) 2004-10-06 2008-04-10 Kansai Paint Co., Ltd Thermosetting Powder Coating Composition
GB0517258D0 (en) 2005-08-24 2005-10-05 Johnson Matthey Plc Tagging system
JP2009525936A (ja) 2005-11-08 2009-07-16 アルベマール・ネーザーランズ・ベーブイ 燐酸アルミニウム含有触媒組成物の製造方法
DE102006012564B4 (de) 2006-03-16 2008-11-06 Kronos International, Inc. Mit Mikrohohlkugeln beschichtetes Titandioxid-Pigment und Verfahren zur Herstellung
US7288146B1 (en) 2006-03-16 2007-10-30 Kronos International, Inc. Titanium dioxide pigment coated with hollow bodies and method for its manufacture
DE102006024869A1 (de) 2006-05-24 2007-11-29 Bk Giulini Gmbh Korrosionsschutzpigmente
UY30532A1 (es) 2006-08-11 2008-03-31 Bunge Fertilizantes Sa Preparacion de particulas de fosfato o polifosfato de aluminio solicitudes relacionadas
DE102007031960B4 (de) 2007-07-10 2009-10-01 Bk Giulini Gmbh Verwendung von Aluminiumphosphat Dihydrat als Weißpigment in Anstrichmitteln
US9023145B2 (en) 2008-02-12 2015-05-05 Bunge Amorphic Solutions Llc Aluminum phosphate or polyphosphate compositions

Also Published As

Publication number Publication date
US20060211798A1 (en) 2006-09-21
EP1878700A1 (en) 2008-01-16
CN104497687B (zh) 2017-12-19
MY159519A (en) 2017-01-13
KR20070089076A (ko) 2007-08-30
AU2007200684A1 (en) 2007-09-13
UY30172A1 (es) 2007-09-28
BRPI0700623B1 (pt) 2022-09-20
AU2007200684B2 (en) 2013-03-28
EA200700356A3 (ru) 2007-12-28
CO5840269A1 (es) 2007-12-31
CA2579268C (en) 2013-06-11
NO20071089L (no) 2007-08-28
CA2579268A1 (en) 2007-08-27
EP1878700B1 (en) 2018-02-14
EA024005B1 (ru) 2016-08-31
CN104497687A (zh) 2015-04-08
CN101029188A (zh) 2007-09-05
JP2013230973A (ja) 2013-11-14
AR060319A1 (es) 2008-06-11
KR101386283B1 (ko) 2014-04-17
US20100292382A1 (en) 2010-11-18
JP2007230861A (ja) 2007-09-13
US20160177110A1 (en) 2016-06-23
US7763359B2 (en) 2010-07-27
US9187653B2 (en) 2015-11-17
JP5646691B2 (ja) 2014-12-24
EA200700356A2 (ru) 2007-08-31

Similar Documents

Publication Publication Date Title
BRPI0700623A (pt) partìculas de fosfato, polifosfato e metafosfato de alumìnio e seu uso com pigmentos em tintas e método de sua produção
UY29090A1 (es) Particulas de fosfato o polifosfato de aluminio para uso como pigmentos en pinturas y metodo para obtener las mismas
WO2006014886A3 (en) Calcium phosphate cements and methods for using the same
EA200970191A1 (ru) Получение частиц фосфата или полифосфата алюминия
Prokof'ev et al. Preparation of granulated LTA and SOD zeolites from mechanically activated mixtures of metakaolin and sodium hydroxide
Charkhi et al. Optimized experimental design for natural clinoptilolite zeolite ball milling to produce nano powders
BRPI0810238A8 (pt) Processo para produção de pcc
BRPI0511996A (pt) pigmento mineral seco contendo carbonato de cálcio, suspensão aquosa contendo-os e seu uso
BR112015002266A2 (pt) reciclagem ambientalmente benéfica de salmoura no processo de redução de atrito resultante de fluxo turbulento
BR112014010920A2 (pt) composição, e, método para preparar um (co)telômero
BR112018013341A2 (pt) composição adesiva, método de preparação de uma composição adesiva e produto adesivo
BR112012029271A2 (pt) fungo isolado, método para produzir e kit para fabricar pelo menos um composto selecionado do grupo que consite de 1, 8-cineol, 1-metil-1,4-cicloexadieno, e (+) -a-metileno-a-fenchocanforona, molécula de ácido nucleico isolada de um fungo,e, método para gerar cepas mutantes de um fungo.
BRPI0900880A2 (pt) processo para produzir uma dispersão de materiais minerais adequada para o uso como pigmentos, dispersão de sólidos minerais particulados em um meio contendo água e pelo menos um agente dispersante
EA201491888A1 (ru) Фосфаты алюминия, составы, включающие фосфат алюминия, и способы их получения
CN101787237B (zh) 一种粉体内墙乳胶漆
WO2005048877A3 (en) Calcium phosphate cements comprising an osteoclastogenic agent
JPWO2009037901A1 (ja) 粉体化粧料およびこれに用いる平板状硫酸カルシウム２水塩の製造方法
CN102796414A (zh) 类轻质碳酸钙、活性类轻质碳酸钙及其制备方法和用途
Souza et al. Liming and fertilization with boron in production of bean.
BR102012012961A2 (pt) tinta ecológica a base de fosfogesso
WO2015094919A3 (en) Graphite exfoliation method
Schiefer et al. Solventless Mechanochemical Synthesis of Phase Pure Syngenite
BRPI0514279A (pt) partìculas de fosfato ou polifosfato de alumìnio para uso como pigmentos em tintas e método para fabricar as mesmas
Seesanong et al. Conversion of Bivalve Shells to Advanced Calcium Phosphate Materials: A Simple, Rapid, Environmentally Benign, and Cost-effective Approach to Recycle Seafood Wastes
MY152063A (en) Aluminum phosphate or polyphosphate paticles for use as pigments in paints and method of making same

Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09R Decision of refusal: republication [chapter 9.2.3 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: ANULADA A PUBLICACAO CODIGO 9.2.4 NA RPI NO 2478 DE 03/07/2018 POR TER SIDO INDEVIDA.

B12B Appeal against refusal [chapter 12.2 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 27/02/2007, OBSERVADAS AS CONDICOES LEGAIS. PATENTE CONCEDIDA CONFORME ADI 5.529/DF, QUE DETERMINA A ALTERACAO DO PRAZO DE CONCESSAO.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 16A ANUIDADE.

B22N Request dismissed because no representative was appointed within the time-limit [chapter 22.14 patent gazette]

Free format text: ARQUIVAMENTO DA PETICAO ART.216 2O DA LPI (NAO APRESENTADA PROCURACAO) - REFERENTE A PETICAO 800230025968, DE 17/01/2023, UMA VEZ QUE NAO FOI APRESENTADA A DEVIDA PROCURACAO POR PARTE DO DEPOSITANTE HABILITANDO O PROCURADOR ?RENATO DA ROCHA LOPES? PARA AGIR NOS AUTOS DO PROCESSO, NO PRAZO DE 60 DIAS CONTADOS DA PRATICA DO REFERIDO ATO, CONFORME ART. 216, PARAGRAFO 2O, DA LPI. DESTA DATA CORRE O PRAZO DE 60 DIAS PARA EVENTUAL RECURSO DO INTERESSADO.

B12F Other appeals [chapter 12.6 patent gazette]

Free format text: RECURSO: 870230066661 - 28/7/2023

B22T Previous entry in chapter 22 of patent gazette cancelled [chapter 22.20 patent gazette]

Free format text: ANULADA A PUBLICACAO CODIGO 22.14 NA RPI NO 2734 DE 30/05/2023, TENDO EM VISTA A DECISAO PROFERIDA EM GRAU DE RECURSO PUBLICADA NA RPI 2758 DE 14/11/2023.

B24B Patent annual fee: requirement for complementing annual fee

Free format text: APRESENTE DOCUMENTACAO QUE COMPROVE QUE O DEPOSITANTE BUNGE FERTILIZANTES S.A., INSCRITO NO CNPJ NO 61.082.822/0001-53, FAZ JUS A REDUCAO NO VALOR DA RETRIBUICAO DEFINIDA NA RESOLUCAO NO 251 DE 02/10/2019.NO CASO DE NAO FAZER JUS A REDUCAO ESTIPULADA, CONFORME RESOLUCAO 113/2013, O DEPOSITANTE DEVERA COMPLEMENTAR A RETRIBUICAO DA 16A ANUIDADE, DE ACORDO COM TABELA VIGENTE, REFERENTE AS GUIAS DE RECOLHIMENTO 29409161960549196, REFERENTE A ANUIDADE, E 29409161960548980, REFERENTE A RESTAURACAO.