BR112015015394A2 - procatalisador, sistema catalisador, processo de polimerização e polímero baseado em olefina - Google Patents
procatalisador, sistema catalisador, processo de polimerização e polímero baseado em olefinaInfo
- Publication number
- BR112015015394A2 BR112015015394A2 BR112015015394A BR112015015394A BR112015015394A2 BR 112015015394 A2 BR112015015394 A2 BR 112015015394A2 BR 112015015394 A BR112015015394 A BR 112015015394A BR 112015015394 A BR112015015394 A BR 112015015394A BR 112015015394 A2 BR112015015394 A2 BR 112015015394A2
- Authority
- BR
- Brazil
- Prior art keywords
- procatalyst
- olefin
- based polymer
- catalyst system
- polymerization process
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 239000003446 ligand Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D51/00—Closures not otherwise provided for
- B65D51/24—Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes
- B65D51/26—Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes with means for keeping contents in position, e.g. resilient means
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/64168—Tetra- or multi-dentate ligand
- C08F4/64186—Dianionic ligand
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/64168—Tetra- or multi-dentate ligand
- C08F4/64186—Dianionic ligand
- C08F4/64193—OOOO
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/60003—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/60168—Tetra- or multi-dentate ligand
- C08F4/60186—Dianionic ligand
- C08F4/60193—OOOO
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Wrappers (AREA)
Abstract
resumo procatalisador, sistema catalisador, processo de polimerização e polímero baseado em olefina (i) a presente invenção provê procatalisadores e sistemas catalisadores para a polimerização de olefinas, polímeros baseados em olefina polimerizados com estes, e processos para produzi-los. em uma concretização, a presente invenção provê um procatalisador compreendendo um complexo de metal-ligante de fórmula (i).
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261746151P | 2012-12-27 | 2012-12-27 | |
US61/746,151 | 2012-12-27 | ||
PCT/US2013/073976 WO2014105411A1 (en) | 2012-12-27 | 2013-12-10 | Catalyst systems for olefin polymerization |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112015015394A2 true BR112015015394A2 (pt) | 2017-07-11 |
BR112015015394B1 BR112015015394B1 (pt) | 2021-09-28 |
Family
ID=49877054
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015015394-1A BR112015015394B1 (pt) | 2012-12-27 | 2013-12-10 | Procatalisador, sistema catalisador e processo de polimerização |
BR112015015167-1A BR112015015167B1 (pt) | 2012-12-27 | 2013-12-27 | composição de poliolefina apropriada para aplicações em moldagem por injeção e dispositivo de fechamento |
BR112015015172-8A BR112015015172B1 (pt) | 2012-12-27 | 2013-12-27 | composição de poliolefina apropriada para aplicações em embalagens, película, folha e dispositivo de embalagem |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015015167-1A BR112015015167B1 (pt) | 2012-12-27 | 2013-12-27 | composição de poliolefina apropriada para aplicações em moldagem por injeção e dispositivo de fechamento |
BR112015015172-8A BR112015015172B1 (pt) | 2012-12-27 | 2013-12-27 | composição de poliolefina apropriada para aplicações em embalagens, película, folha e dispositivo de embalagem |
Country Status (10)
Country | Link |
---|---|
US (6) | US9751998B2 (pt) |
EP (3) | EP2938643B1 (pt) |
JP (3) | JP6393693B2 (pt) |
KR (4) | KR20150100694A (pt) |
CN (3) | CN104870489B (pt) |
AR (1) | AR094336A1 (pt) |
BR (3) | BR112015015394B1 (pt) |
ES (3) | ES2665586T3 (pt) |
SG (3) | SG11201503581PA (pt) |
WO (3) | WO2014105411A1 (pt) |
Families Citing this family (128)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2807196B1 (en) * | 2012-01-24 | 2017-12-27 | Total Research & Technology Feluy | Method for processing polyethylene |
SG11201502783RA (en) * | 2012-10-09 | 2015-05-28 | Dow Global Technologies Llc | Sealant composition |
ES2731574T3 (es) | 2012-12-27 | 2019-11-18 | Dow Global Technologies Llc | Un proceso de polimerización para producir polímeros a base de etileno |
CN104884485B (zh) | 2012-12-27 | 2017-11-21 | 陶氏环球技术有限责任公司 | 用于产生乙烯类聚合物的聚合方法 |
BR112015015394B1 (pt) * | 2012-12-27 | 2021-09-28 | Dow Global Technologies Llc | Procatalisador, sistema catalisador e processo de polimerização |
US9534070B2 (en) * | 2013-01-18 | 2017-01-03 | Dow Global Technologies Llc | Polymerization processes for high molecular weight polymers |
ES2934177T3 (es) | 2013-06-28 | 2023-02-17 | Dow Global Technologies Llc | Control de peso molecular de poliolefinas usando catalizadores de bis-fenilfenoxilo halogenados |
US9605099B2 (en) * | 2013-10-30 | 2017-03-28 | Lg Chem, Ltd. | Olefin resin |
WO2015200743A1 (en) | 2014-06-26 | 2015-12-30 | Dow Global Technologies Llc | Blown films with improved toughness |
EP3160742A1 (en) | 2014-06-26 | 2017-05-03 | Dow Global Technologies LLC | Cast films with improved toughness |
US20170152377A1 (en) | 2014-06-26 | 2017-06-01 | Dow Global Technologies Llc | Breathable films and articles incorporating same |
EP3161022A1 (en) | 2014-06-30 | 2017-05-03 | Dow Global Technologies LLC | Ethylene-based polymers |
US10519260B2 (en) | 2014-06-30 | 2019-12-31 | Dow Global Technologies Llc | Polymerizations for olefin-based polymers |
SG11201700372SA (en) * | 2014-07-24 | 2017-02-27 | Dow Global Technologies Llc | Bis-biphenylphenoxy catalysts for polymerization of low molecular weight ethylene-based polymers |
KR102533991B1 (ko) * | 2014-12-31 | 2023-05-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올레핀 조성물 및 그 제조방법 |
US10300685B2 (en) * | 2015-04-29 | 2019-05-28 | Dow Quimica Mexicana S.A. De C.V. | Multi-layer film and articles made therefrom |
US11041027B2 (en) | 2015-06-30 | 2021-06-22 | Dow Global Technologies Llc | Polymerization process for producing ethylene based polymers |
EP3317312B1 (en) * | 2015-06-30 | 2020-06-10 | Dow Global Technologies LLC | A polymerization process for producing ethylene based polymers |
WO2017040127A1 (en) * | 2015-08-28 | 2017-03-09 | Dow Global Technologies Llc | Chromatography of polymers with reduced co-crystallization |
WO2017058858A1 (en) | 2015-09-30 | 2017-04-06 | Dow Global Technologies Llc | A polymerization process for producing ethylene based polymers |
KR102646587B1 (ko) | 2015-09-30 | 2024-03-13 | 다우 글로벌 테크놀로지스 엘엘씨 | 전촉매 및 이를 사용한 중합 방법 |
CN108137738B (zh) | 2015-09-30 | 2020-11-06 | 陶氏环球技术有限责任公司 | 通过向醛部分加成氨基和聚合物基来制备官能性聚合物的方法 |
KR102606500B1 (ko) | 2015-09-30 | 2023-11-28 | 다우 글로벌 테크놀로지스 엘엘씨 | 사슬 왕복에 유용한 다중-헤드 또는 이중-헤드 조성물 및 이를 제조하는 방법 |
WO2017139096A1 (en) * | 2016-02-12 | 2017-08-17 | Dow Global Technologies Llc | Cast films, and articles made therefrom |
EP3214124B2 (en) | 2016-03-02 | 2022-06-08 | Dow Global Technologies LLC | An ethylene/alpha-olefin copolymer composition, and articles comprising the same |
EP3214115B1 (en) * | 2016-03-03 | 2018-10-03 | Dow Global Technologies LLC | Polyethylene composition, method of making the same, and films made therefrom |
ES2919998T3 (es) * | 2016-03-31 | 2022-07-29 | Dow Global Technologies Llc | Un catalizador de polimerización de olefinas |
SG10202101020PA (en) | 2016-07-29 | 2021-03-30 | Dow Global Technologies Llc | Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization |
US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
CN109963888A (zh) | 2016-09-30 | 2019-07-02 | 陶氏环球技术有限责任公司 | 用于制备适用于链梭移的多头或双头组合物的方法 |
KR102490785B1 (ko) | 2016-09-30 | 2023-01-20 | 다우 글로벌 테크놀로지스 엘엘씨 | 사슬 왕복에 유용한 캡핑된 다중- 또는 이중-헤드형 조성물 및 이의 제조 방법 |
EP3519455B1 (en) | 2016-09-30 | 2024-04-10 | Dow Global Technologies Llc | Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same |
CN110023353B (zh) * | 2016-12-16 | 2022-07-22 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃互聚物组合物 |
JP7006677B2 (ja) * | 2017-03-10 | 2022-01-24 | 住友化学株式会社 | フィルム |
BR112019019129A2 (pt) | 2017-03-15 | 2020-04-14 | Dow Global Technologies Llc | sistema catalisador para formação de copolímero de múltiplos blocos |
CN110603271A (zh) | 2017-03-15 | 2019-12-20 | 陶氏环球技术有限责任公司 | 用于形成多嵌段共聚物的催化剂体系 |
US11897992B2 (en) | 2017-03-15 | 2024-02-13 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
EP3596141B1 (en) | 2017-03-15 | 2021-07-28 | Dow Global Technologies LLC | Catalyst system for multi-block copolymer formation |
KR102631009B1 (ko) | 2017-03-15 | 2024-01-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중-블록 공중합체 형성을 위한 촉매 시스템 |
KR102567217B1 (ko) * | 2017-03-31 | 2023-08-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 비스-바이페닐-페녹시 촉매 |
SG11201908639XA (en) * | 2017-03-31 | 2019-10-30 | Dow Global Technologies Llc | Germanium-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization |
US10442920B2 (en) * | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
US10442921B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations |
CN108864338B (zh) * | 2017-05-12 | 2020-11-10 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组合物及烯烃聚合的方法 |
WO2018236863A1 (en) * | 2017-06-20 | 2018-12-27 | Dow Global Technologies Llc | GROUP IV TRANSITION METAL BIARYLPHENOXY CATALYSTS FOR OLEFIN POLYMERIZATION |
WO2018236738A1 (en) * | 2017-06-20 | 2018-12-27 | Dow Global Technologies Llc | GROUP IV TRANSITION PHENOXYBIARYL-METAL CATALYSTS FOR OLEFIN POLYMERIZATION |
US11535011B2 (en) * | 2017-06-22 | 2022-12-27 | Liqui-Box Corporation | Bag-in-box film for packaging refrigerated liquids |
SG11202002720WA (en) | 2017-09-29 | 2020-04-29 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having two methylenetrialkylsilicon ligands on the metal for improved solubility |
WO2019067280A1 (en) * | 2017-09-29 | 2019-04-04 | Dow Global Technologies Llc | BIS-PHENYL-PHENOXY-POLYOLEFIN CATALYSTS HAVING ALKOXY OR AMIDO-TYPE LIGAND ON METAL FOR ENHANCED SOLUBILITY |
ES2911503T3 (es) | 2017-09-29 | 2022-05-19 | Dow Global Technologies Llc | Catalizadores de bis-fenil-fenoxi-poliolefina que tienen un ligando de metilentrialquilsilicio en el metal para mejorar la solubilidad |
AR113268A1 (es) * | 2017-10-10 | 2020-03-11 | Dow Global Technologies Llc | Películas poliméricas orientadas de manera uniaxial y artículos fabricados a partir de estas |
US10903435B2 (en) * | 2017-10-18 | 2021-01-26 | Dongwoo Fine-Chem Co., Ltd. | Flexible display device |
US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
KR102100142B1 (ko) | 2017-12-21 | 2020-04-14 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 금속-리간드 착체, 이를 포함하는 에틸렌계 중합용 촉매 조성물 및 이를 이용한 에틸렌계 중합체의 제조방법 |
WO2019123028A1 (ko) * | 2017-12-21 | 2019-06-27 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 금속-리간드 착체, 이를 포함하는 에틸렌계 중합용 촉매 조성물 및 이를 이용한 에틸렌계 중합체의 제조방법 |
US11603452B2 (en) | 2017-12-26 | 2023-03-14 | Dow Global Technologies Llc | Multimodal ethylene-based polymer compositions having improved toughness |
US11680120B2 (en) | 2017-12-26 | 2023-06-20 | Dow Global Technologies Llc | Dual reactor solution process for the production of multimodal ethylene-based polymer |
US11680119B2 (en) | 2017-12-26 | 2023-06-20 | Dow Global Technologies Llc | Process for the production of multimodal ethylene-based polymers |
JP7381464B2 (ja) | 2017-12-29 | 2023-11-15 | ダウ グローバル テクノロジーズ エルエルシー | 末端保護された双頭型有機アルミニウム組成物 |
CN111448200A (zh) | 2017-12-29 | 2020-07-24 | 陶氏环球技术有限责任公司 | 双头有机铝组合物 |
CA3101628A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Hot melt adhesive composition containing a polyolefin - polydiorganoosiloxane copolymer and methods for the preparation and use thereof |
JP7378411B2 (ja) | 2018-03-19 | 2023-11-13 | ダウ シリコーンズ コーポレーション | ポリオレフィン-ポリジオルガノシロキサンブロックコポリマーおよびその合成のための加水分解反応方法 |
SG11202009175RA (en) | 2018-03-19 | 2020-10-29 | Dow Global Technologies Llc | Silicon-terminated organo-metal compounds and processes for preparing the same |
BR112020019174A2 (pt) | 2018-03-19 | 2021-01-05 | Dow Global Technologies Llc | Composições de poliolefina telequélica terminadas com silício e processos para a preparação das mesmas |
WO2019182988A1 (en) | 2018-03-19 | 2019-09-26 | Dow Global Technologies Llc | Silicon-terminated organo-metal compounds and processes for preparing the same |
WO2019182720A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Polyolefin-polydiorganosiioxane block copolymer and method for the synthesis thereof |
KR20200135419A (ko) | 2018-03-19 | 2020-12-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 실릴계 작용화제로 오르가노-금속 화합물을 작용화하는 방법 및 이에 의해 제조된 실릴계 작용화제 화합물 |
CA3093558A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Polyorganosiloxane hot melt adhesive compositions containing polyolefin - polydiorganoosiloxane copolymers and methods for the preparation and use thereof |
EP3778669A4 (en) * | 2018-05-04 | 2021-07-28 | Lg Chem, Ltd. | ADHESIVE COMPOSITION CONTAINING AN ETHYLENE / ALPHA-OLEFIN COPOLYMER |
SG11202012176XA (en) | 2018-06-15 | 2021-01-28 | Dow Global Technologies Llc | Process for the production of bimodal ethylene-based polymers having high molecular weight high density fractions |
EP3807329A1 (en) | 2018-06-15 | 2021-04-21 | Dow Global Technologies Llc | Bimodal ethylene-based polymers having high molecular weight high density fractions |
BR112020025383A2 (pt) | 2018-06-15 | 2021-03-09 | Dow Global Technologies Llc | Filme fundido, e, estrutura de filme fundido em camadas |
JP7419269B2 (ja) | 2018-06-15 | 2024-01-22 | ダウ グローバル テクノロジーズ エルエルシー | 高分子量高密度画分を有する二峰性エチレン系ポリマーを含むインフレーションフィルム |
CN112334515B (zh) | 2018-07-17 | 2022-08-09 | 美国陶氏有机硅公司 | 聚硅氧烷树脂-聚烯烃共聚物及其制备和使用方法 |
US11066494B2 (en) | 2018-09-20 | 2021-07-20 | Exxonmobil Chemical Patents Inc. | Amine bridged anilide phenolate catalyst compounds |
CN112639009B (zh) | 2018-10-05 | 2023-08-01 | 陶氏环球技术有限责任公司 | 介电增强的聚乙烯配制物 |
AR117126A1 (es) * | 2018-11-20 | 2021-07-14 | Dow Global Technologies Llc | UNA TELA NO TEJIDA QUE TIENE FIBRAS DE POLÍMEROS DE ETILENO / a-OLEFINA |
AR117125A1 (es) * | 2018-11-20 | 2021-07-14 | Dow Global Technologies Llc | Método de fabricación de fibras rizadas y bandas no tejidas que tienen tales fibras |
AR117108A1 (es) * | 2018-11-20 | 2021-07-14 | Dow Global Technologies Llc | Fibras multicomponentes onduladas |
KR20210121027A (ko) | 2018-12-28 | 2021-10-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 불포화 폴리올레핀을 포함하는 경화성 조성물 |
SG11202107051UA (en) | 2018-12-28 | 2021-07-29 | Dow Global Technologies Llc | Telechelic polyolefins and processes for preparing the same |
JP2022516119A (ja) | 2018-12-28 | 2022-02-24 | ダウ グローバル テクノロジーズ エルエルシー | テレケリックポリオレフィンを含む硬化性組成物 |
KR20210121031A (ko) | 2018-12-28 | 2021-10-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 불포화 폴리올레핀을 포함하는 경화성 조성물 |
WO2020140064A1 (en) | 2018-12-28 | 2020-07-02 | Dow Global Technologies Llc | Organometallic chain transfer agents |
US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
BR112021023227A2 (pt) | 2019-05-31 | 2022-02-08 | Dow Global Technologies Llc | Polímero de polietileno de baixa densidade linear, filme soprado, e, filme fundido |
US11046843B2 (en) | 2019-07-29 | 2021-06-29 | Nova Chemicals (International) S.A. | Ethylene copolymers and films with excellent sealing properties |
CN114222782B (zh) * | 2019-08-06 | 2024-07-09 | 陶氏环球技术有限责任公司 | 聚乙烯组合物 |
ES2938408T3 (es) * | 2019-08-06 | 2023-04-10 | Dow Global Technologies Llc | Películas multicapa que comprenden polietileno y capas de barrera y métodos para producir las mismas |
BR112022001979A2 (pt) | 2019-08-06 | 2022-05-10 | Dow Global Technologies Llc | Filme de múltiplas camadas |
MX2020008168A (es) | 2019-08-06 | 2021-02-08 | Dow Global Technologies Llc | Composiciones de polietileno. |
JP2022542660A (ja) * | 2019-08-06 | 2022-10-06 | ダウ グローバル テクノロジーズ エルエルシー | 少なくとも3つの層を有する多層フィルムおよびその生成方法 |
MX2022004862A (es) | 2019-11-01 | 2022-05-19 | Nova Chem Int Sa | Polietileno de alta densidad lineal con alta tenacidad y alta resistencia al agrietamiento por tension ambiental (escr). |
KR20220097897A (ko) | 2019-11-04 | 2022-07-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 티타늄 바이페닐페놀 중합 촉매 |
EP4055069A1 (en) | 2019-11-04 | 2022-09-14 | Dow Global Technologies LLC | Biphenylphenol polymerization catalysts |
MX2022006503A (es) * | 2019-12-10 | 2022-07-04 | Dow Global Technologies Llc | Peliculas de polietileno orientado y articulos que las comprenden. |
BR112022011778A2 (pt) | 2019-12-19 | 2022-08-30 | Dow Global Technologies Llc | Uso de um catalisador de polimerização de bifenilfenol em fase gasosa, sistema de catalisador de polimerização, método de polimerização, e, composição de polietileno |
WO2021133613A1 (en) * | 2019-12-26 | 2021-07-01 | Dow Global Technologies Llc | Process for the production of polymer compositions with excellent processability |
WO2021128126A1 (en) * | 2019-12-26 | 2021-07-01 | Dow Global Technologies Llc | Alpha-olefin interpolymers with improved molecular design for photovoltaic encapsulants |
JP2023508013A (ja) | 2019-12-30 | 2023-02-28 | ダウ グローバル テクノロジーズ エルエルシー | アルファ-置換アクリレートを調製するためのプロセス |
US20220402856A1 (en) | 2019-12-30 | 2022-12-22 | Dow Global Technologies Llc | Process for preparing an alpha-substituted acrylate |
BR112022012900A2 (pt) * | 2019-12-31 | 2022-09-06 | Dow Global Technologies Llc | Composição de polietileno, filme multicamadas, e, método de produção de um artigo |
US20230348641A1 (en) | 2020-01-31 | 2023-11-02 | Dow Global Technologies Llc | Polymerization process that include group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes and chain transfer agents |
BR112022015190A2 (pt) | 2020-01-31 | 2022-10-11 | Dow Global Technologies Llc | Complexo de metal-ligante, e, processo de polimerização |
BR112022018407A2 (pt) * | 2020-03-31 | 2022-11-08 | Dow Global Technologies Llc | Agente redutor de arrasto |
KR20220162725A (ko) * | 2020-03-31 | 2022-12-08 | 다우 글로벌 테크놀로지스 엘엘씨 | C6-C14 a-올레핀 단량체의 중합 및 이의 중합체 |
US20230118316A1 (en) * | 2020-05-29 | 2023-04-20 | Dow Global Technologies Llc | Oriented polyethylene films and articles comprising the same |
BR112022023862A2 (pt) | 2020-05-29 | 2022-12-20 | Dow Global Technologies Llc | Procatalisador, sistema catalisador, método para a produção de um sistema catalisador, e, processo para a produção de polietileno |
EP4157896A1 (en) | 2020-05-29 | 2023-04-05 | Dow Global Technologies LLC | Attenuated post-metallocene catalysts |
KR20230017245A (ko) | 2020-05-29 | 2023-02-03 | 다우 글로벌 테크놀로지스 엘엘씨 | 감쇠된 포스트-메탈로센 촉매 |
US20230242695A1 (en) | 2020-05-29 | 2023-08-03 | Dow Global Technologies Llc | Chemically converted catalysts |
BR112022023953A2 (pt) | 2020-05-29 | 2022-12-20 | Dow Global Technologies Llc | Métodos para fazer um catalisador híbrido atenuado, de alimentação de um catalisador híbrido para um reator de polimerização em fase de pasta ou em fase gasosa e de fabricação de um polímero de poliolefina, catalisador híbrido atenuado, e, sistema de catalisador multimodal |
CA3102574A1 (en) * | 2020-06-29 | 2021-12-29 | Nova Chemicals Corporation | Ethylene copolymer for biaxial orientation |
CN116323686A (zh) | 2020-07-17 | 2023-06-23 | 陶氏环球技术有限责任公司 | 双苯基苯氧基金属-配体络合物的烃基改性的甲基铝氧烷助催化剂 |
US20230287152A1 (en) | 2020-07-17 | 2023-09-14 | Dow Global Technologies Llc | Hydrocarbyl-modified methylaluminoxane cocatalysts for bis-phenylphenoxy metal-ligand complexes |
WO2022015370A1 (en) | 2020-07-17 | 2022-01-20 | Dow Global Technologies Llc | Hydrocarbyl-modified methylaluminoxane cocatalyst for bis-phenylphenoxy metal-ligand complexes |
WO2022069411A1 (en) * | 2020-09-30 | 2022-04-07 | Borealis Ag | Ethylene-octene copolymers with improved property profile |
JP7388331B2 (ja) | 2020-10-09 | 2023-11-29 | トヨタ自動車株式会社 | 車両の制御装置 |
WO2022103800A1 (en) | 2020-11-10 | 2022-05-19 | Dow Global Technologies Llc | Preparation of polyolefin-polyacrylate block copolymers additives for increasing surface energy of polyethylene |
CN116348502A (zh) | 2020-11-10 | 2023-06-27 | 陶氏环球技术有限责任公司 | 经由乙烯基封端的聚烯烃制备非极性-极性嵌段共聚物 |
WO2022173905A1 (en) | 2021-02-15 | 2022-08-18 | Dow Global Technologies Llc | Biphenylphenol polymerization catalysts |
JP2024507756A (ja) | 2021-02-15 | 2024-02-21 | ダウ グローバル テクノロジーズ エルエルシー | 改良された速度論的誘導時間を有するビフェニルフェノール重合触媒 |
US11850830B2 (en) | 2021-07-19 | 2023-12-26 | Liqui-Box Corporation | Recyclable flexible high barrier films and bags for packaging flowable materials |
US20230092207A1 (en) * | 2021-09-10 | 2023-03-23 | Braskem S.A. | Polyethylene-based composition and biaxially oriented polyethylene-based articles |
WO2023130032A1 (en) * | 2021-12-30 | 2023-07-06 | Dow Global Technologies Llc | Multimodal ethylene-based copolymer compositions and processes of producing |
WO2024050359A1 (en) | 2022-08-29 | 2024-03-07 | Dow Global Technologies Llc | Group iii-halide or lanthanide-halide bis(phenylphenoxy) metal−ligand complexes |
Family Cites Families (66)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1069848A (en) | 1965-05-17 | 1967-05-24 | Imp Chemical Imdustries Ltd | Process for the polymerisation of vinyl chloride |
US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US7163907B1 (en) | 1987-01-30 | 2007-01-16 | Exxonmobil Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
US5372682A (en) | 1993-06-24 | 1994-12-13 | The Dow Chemical Company | Electrochemical preparation of addition polymerization catalysts |
US5631069A (en) * | 1994-05-09 | 1997-05-20 | The Dow Chemical Company | Medium modulus molded material comprising substantially linear polyethlene and fabrication method |
US5625087A (en) | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
US6506866B2 (en) * | 1994-11-17 | 2003-01-14 | Dow Global Technologies Inc. | Ethylene copolymer compositions |
KR20000005027A (ko) | 1996-03-27 | 2000-01-25 | 그레이스 스티븐 에스. | 분산된 촉매 활성화제를 사용하는 용액 중합 방법 |
KR100437238B1 (ko) | 1996-03-27 | 2004-08-16 | 다우 글로벌 테크놀로지스 인크. | 고가용성올레핀중합촉매활성화제 |
DE69705398T2 (de) | 1996-05-02 | 2002-05-02 | Equistar Chem Lp | Katalysatorsystem der dos reaktionprodukt einer flüssigen silikon und einer polyamine enthält |
US5783512A (en) | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
US6696379B1 (en) | 1997-09-19 | 2004-02-24 | The Dow Chemical Company | Supported modified alumoxane catalyst activator |
US6323285B1 (en) * | 1998-01-09 | 2001-11-27 | The Dow Chemical Company | Heteromorphic polymer compositions |
US5936058A (en) * | 1998-05-15 | 1999-08-10 | Exxon Chemical Patents, Inc. | Impact modified thermoplastic polymer blends |
JP2000159829A (ja) | 1998-11-27 | 2000-06-13 | Tosoh Corp | オレフィン重合用触媒およびそれを用いたポリオレフィンの製造方法 |
ES2379243T3 (es) | 1999-12-10 | 2012-04-24 | Dow Global Technologies Llc | Complejos de metal del grupo 4 sustituidos, catalizadores y procedimiento de polimerización de olefinas |
US6897276B2 (en) * | 2002-04-24 | 2005-05-24 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
US7060848B2 (en) | 2002-04-24 | 2006-06-13 | Symyx Technologies, Inc. | Bridged bi-aromatic catalysts, complexes, and methods of using the same |
US7396878B2 (en) * | 2002-10-01 | 2008-07-08 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions for injection molding |
US20060046048A1 (en) * | 2003-02-04 | 2006-03-02 | Mridula Kapur | Film layers made from polymer blends |
GB0317012D0 (en) * | 2003-07-21 | 2003-08-27 | Borealis Tech Oy | Injection moulding polymer |
AU2005224257B2 (en) * | 2004-03-17 | 2010-08-19 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
EP1674523A1 (en) * | 2004-12-22 | 2006-06-28 | Total Petrochemicals Research Feluy | Caps and closures |
EP1674490A1 (en) | 2004-12-23 | 2006-06-28 | Borealis Technology Oy | Copolymer |
CN104725535A (zh) * | 2006-05-17 | 2015-06-24 | 陶氏环球技术有限责任公司 | 高效溶液聚合法 |
CN102015874B (zh) | 2008-02-29 | 2014-08-27 | 陶氏环球技术有限责任公司 | 包括乙烯/α-烯烃嵌段互聚物的取向膜 |
CA2629576C (en) * | 2008-04-21 | 2016-01-05 | Nova Chemicals Corporation | Closures for bottles |
US8372930B2 (en) | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
CN102224192B (zh) | 2008-11-28 | 2013-06-12 | 三菱丽阳株式会社 | 发泡成型用加工助剂、发泡成型用氯乙烯系树脂组合物及发泡成型体 |
US8101685B2 (en) * | 2008-12-15 | 2012-01-24 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom |
US8106127B2 (en) * | 2008-12-15 | 2012-01-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-reactor polymer blends |
US20110003940A1 (en) * | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
US20110054122A1 (en) | 2009-08-31 | 2011-03-03 | Jerzy Klosin | Catalyst and process for polymerizing an olefin and polyolefin prepared thereby |
WO2011041696A1 (en) | 2009-10-02 | 2011-04-07 | Dow Global Technologies Inc. | Block composites and impact modified compositions |
US8686087B2 (en) | 2009-10-02 | 2014-04-01 | Dow Global Technologies Llc | Block composites in soft compounds |
US20110172354A1 (en) | 2010-01-04 | 2011-07-14 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use in fiber applications |
KR101854480B1 (ko) | 2010-02-19 | 2018-05-03 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 단량체의 중합 방법 및 이를 위한 촉매 |
CN103038281B (zh) * | 2010-03-02 | 2015-11-25 | 陶氏环球技术有限责任公司 | 基于乙烯的聚合物组合物 |
WO2011146044A1 (en) * | 2010-05-17 | 2011-11-24 | Dow Global Technologies Llc | Process for selectively polymerizing ethylene and catalyst therefor |
KR101788892B1 (ko) | 2010-05-17 | 2017-11-15 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌의 선택적 중합 방법 및 그를 위한 촉매 |
EP2591021A2 (en) | 2010-07-06 | 2013-05-15 | Ticona GmbH | Ultra-high molecular weight polyethylene, its production and use |
SG187848A1 (en) | 2010-08-25 | 2013-03-28 | Dow Global Technologies Llc | Process for polymerizing a polymerizable olefin and catalyst therefor |
BR112012005698B1 (pt) | 2010-11-02 | 2021-05-25 | Dow Global Technologies Llc | composição seladora, método para produzir uma composição seladora, camada selante, artigo e método para formar um artigo |
US20120116034A1 (en) * | 2010-11-08 | 2012-05-10 | Dow Global Technologies, Inc. | Solution polymerization process and procatalyst carrier systems useful therein |
EP2813545A1 (en) | 2010-12-03 | 2014-12-17 | Dow Global Technologies LLC | Processes to prepare ethylene-based polymer compositions |
WO2014209927A1 (en) | 2013-06-28 | 2014-12-31 | Dow Global Technologies Llc | Hyperbranched ethylene-based oligomers |
ES2835807T3 (es) * | 2011-12-20 | 2021-06-23 | Dow Global Technologies Llc | Interpolímeros de etileno/alfa-olefina/polieno no conjugado y procesos para formar los mismos |
CN104024284B (zh) * | 2011-12-29 | 2016-08-31 | 陶氏环球技术有限责任公司 | 低分子量的基于乙烯和α-烯烃的材料的制备方法 |
WO2013101376A1 (en) * | 2011-12-29 | 2013-07-04 | Dow Global Technologies Llc | Hyperbranched olefin oil-based dielectric fluid |
EP2817343A4 (en) * | 2012-02-22 | 2015-10-21 | Exxonmobil Chem Patents Inc | VINYL-TERMINATED MACROMONOMER OLIGOMERIZATION |
EP2908655B1 (en) | 2012-10-18 | 2016-09-07 | Dow Global Technologies LLC | Oleic and medium chain length triglyceride based, low viscosity, high flash point dielectric fluids |
JP6653173B2 (ja) * | 2012-12-27 | 2020-02-26 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマー |
BR112015015394B1 (pt) * | 2012-12-27 | 2021-09-28 | Dow Global Technologies Llc | Procatalisador, sistema catalisador e processo de polimerização |
ES2731574T3 (es) * | 2012-12-27 | 2019-11-18 | Dow Global Technologies Llc | Un proceso de polimerización para producir polímeros a base de etileno |
CN104884485B (zh) * | 2012-12-27 | 2017-11-21 | 陶氏环球技术有限责任公司 | 用于产生乙烯类聚合物的聚合方法 |
BR112015015545B1 (pt) | 2012-12-27 | 2021-11-16 | Dow Global Technologies Llc | Processo para produzir um polímero a base de etileno |
US9534070B2 (en) * | 2013-01-18 | 2017-01-03 | Dow Global Technologies Llc | Polymerization processes for high molecular weight polymers |
ES2934177T3 (es) * | 2013-06-28 | 2023-02-17 | Dow Global Technologies Llc | Control de peso molecular de poliolefinas usando catalizadores de bis-fenilfenoxilo halogenados |
EP3050922A4 (en) | 2013-09-25 | 2016-09-28 | Mitsubishi Rayon Co | SOFT VINYL CHLORIDE RESIN COMPOSITION, FORM BODY, ELECTRIC CABLE COATING MATERIAL AND COATED ELECTRICAL CABLE |
CN105723471B (zh) | 2013-09-25 | 2019-01-11 | 三菱化学株式会社 | 电线包覆材及经包覆的电线 |
-
2013
- 2013-12-10 BR BR112015015394-1A patent/BR112015015394B1/pt active IP Right Grant
- 2013-12-10 SG SG11201503581PA patent/SG11201503581PA/en unknown
- 2013-12-10 KR KR1020157016829A patent/KR20150100694A/ko active Application Filing
- 2013-12-10 US US14/437,543 patent/US9751998B2/en active Active
- 2013-12-10 EP EP13811736.1A patent/EP2938643B1/en active Active
- 2013-12-10 JP JP2015550430A patent/JP6393693B2/ja active Active
- 2013-12-10 ES ES13811736.1T patent/ES2665586T3/es active Active
- 2013-12-10 KR KR1020207014897A patent/KR20200062369A/ko not_active Application Discontinuation
- 2013-12-10 CN CN201380067367.9A patent/CN104870489B/zh active Active
- 2013-12-10 WO PCT/US2013/073976 patent/WO2014105411A1/en active Application Filing
- 2013-12-27 WO PCT/US2013/077991 patent/WO2014106052A1/en active Application Filing
- 2013-12-27 SG SG11201505074PA patent/SG11201505074PA/en unknown
- 2013-12-27 CN CN201380065822.1A patent/CN104870488B/zh active Active
- 2013-12-27 US US14/653,329 patent/US20150344681A1/en not_active Abandoned
- 2013-12-27 BR BR112015015167-1A patent/BR112015015167B1/pt active IP Right Grant
- 2013-12-27 KR KR1020157019959A patent/KR102077364B1/ko active IP Right Grant
- 2013-12-27 ES ES13821405.1T patent/ES2630378T3/es active Active
- 2013-12-27 ES ES13824073.4T patent/ES2634639T3/es active Active
- 2013-12-27 US US14/141,835 patent/US9115275B2/en active Active
- 2013-12-27 US US14/142,014 patent/US9102819B2/en active Active
- 2013-12-27 WO PCT/US2013/077936 patent/WO2014106017A1/en active Application Filing
- 2013-12-27 CN CN201380067372.XA patent/CN104870490B/zh active Active
- 2013-12-27 US US14/653,352 patent/US9631059B2/en active Active
- 2013-12-27 KR KR1020157019960A patent/KR102077365B1/ko active IP Right Grant
- 2013-12-27 EP EP13824073.4A patent/EP2938647B1/en active Active
- 2013-12-27 EP EP13821405.1A patent/EP2938646B1/en active Active
- 2013-12-27 JP JP2015550787A patent/JP6294350B2/ja active Active
- 2013-12-27 JP JP2015550800A patent/JP6364023B2/ja active Active
- 2013-12-27 SG SG11201505081RA patent/SG11201505081RA/en unknown
- 2013-12-27 BR BR112015015172-8A patent/BR112015015172B1/pt active IP Right Grant
- 2013-12-27 AR ARP130105093A patent/AR094336A1/es unknown
-
2017
- 2017-07-18 US US15/652,606 patent/US10214622B2/en active Active
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
BR112015015394A2 (pt) | procatalisador, sistema catalisador, processo de polimerização e polímero baseado em olefina | |
BR112015015550A2 (pt) | processo de polimerização para a produção de polímeros a base de etileno | |
BR112015015548A2 (pt) | processo de polimerização para a produção de polímeros a base de etileno | |
BR112013008476A2 (pt) | sistema de catalisador de metaloceno ligado em ponte com hidrogênio permutável e efeitos de comonômero | |
BR112016029439A2 (pt) | processo para polimerização de olefinas | |
BR112015015544A2 (pt) | polímero a base de etileno | |
MX359522B (es) | Metodos para controlar polimerizaciones de olefina de doble catalizador. | |
BR112017028174A2 (pt) | processo de polimerização para produzir polímeros à base de etileno | |
AR094324A1 (es) | Un polímero a base de etileno | |
BR112014024572A2 (pt) | sistemas catalisadores contendo um metaloceno em ponte | |
MX2016008041A (es) | Sistema catalizador para polimerizacion de una olefina. | |
BR112016029266A2 (pt) | sistemas de catalisador para polimerização de olefinas | |
CO6480946A2 (es) | Sistemas catalizadores duales de metaloceno para disminuuir el índice de fusión e incrementar las velocidades de producción de polímero. | |
BR112014031937A8 (pt) | catalisadores compreendendo ligantes salen, sistema de catalisador, poliolefina e processo para polimerizar olefinas | |
BR112012021399A2 (pt) | composição de pró-catalisador, composição de catalisador e processo para produzir um polímero baseado em olefina | |
MX2013009105A (es) | Carbocatalizadores para polimerizacion. | |
BR112013000397A2 (pt) | catalisadores para produzir poliolefinas de ampla distribuição de peso molecular na ausencia de hidrogênio adicionado | |
BR112013016433A2 (pt) | iniciadores de aluminoxano e polímeros funcionalizados preparados a partir dos mesmos | |
BR112012020720A2 (pt) | processo para polimerizar um monômero olefínico, complexo de ligante-metal catalisador e ligante | |
MX338141B (es) | Procedimiento de polimerizacion del acido (met) acrilico en solucion, soluciones de polimeros obtenidas y sus utilizaciones. | |
BR112014019408A8 (pt) | Processo para produzir um polímero de dieno, polímero e produto | |
BR112016028539A2 (pt) | polímeros de látex de múltiplos estágios, processos dos mesmos e composições de revestimento produzidas a partir dos mesmos | |
IN2012DN01854A (pt) | ||
BR112014002551A2 (pt) | processo para preparar homo ou copolímeros de isobuteno de alta reatividade, e, polímeros de isobuteno | |
BR112013015853A2 (pt) | composição de procatalisador, composição de catalisador, processo de polimerização e composição polimérica |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B06I | Publication of requirement cancelled [chapter 6.9 patent gazette] |
Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |
|
B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 10/12/2013, OBSERVADAS AS CONDICOES LEGAIS. |