BR112012020720A2 - processo para polimerizar um monômero olefínico, complexo de ligante-metal catalisador e ligante - Google Patents

processo para polimerizar um monômero olefínico, complexo de ligante-metal catalisador e ligante

Info

Publication number
BR112012020720A2
BR112012020720A2 BR112012020720A BR112012020720A BR112012020720A2 BR 112012020720 A2 BR112012020720 A2 BR 112012020720A2 BR 112012020720 A BR112012020720 A BR 112012020720A BR 112012020720 A BR112012020720 A BR 112012020720A BR 112012020720 A2 BR112012020720 A2 BR 112012020720A2
Authority
BR
Brazil
Prior art keywords
binder
polymerizing
metal catalyst
olefin monomer
catalyst complex
Prior art date
Application number
BR112012020720A
Other languages
English (en)
Other versions
BR112012020720B1 (pt
Inventor
Philip P Fontaine
Roger L Kuhlman
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=44059025&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR112012020720(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of BR112012020720A2 publication Critical patent/BR112012020720A2/pt
Publication of BR112012020720B1 publication Critical patent/BR112012020720B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
BR112012020720A 2010-02-19 2011-02-08 processo para polimerizar um monômero olefínico BR112012020720B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US30615310P 2010-02-19 2010-02-19
PCT/US2011/024013 WO2011102990A2 (en) 2010-02-19 2011-02-08 Process for polymerizing an olefin monomer and catalyst therefor

Publications (2)

Publication Number Publication Date
BR112012020720A2 true BR112012020720A2 (pt) 2016-04-26
BR112012020720B1 BR112012020720B1 (pt) 2020-01-21

Family

ID=44059025

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012020720A BR112012020720B1 (pt) 2010-02-19 2011-02-08 processo para polimerizar um monômero olefínico

Country Status (8)

Country Link
US (1) US8729201B2 (pt)
EP (2) EP3549960B1 (pt)
KR (1) KR101854480B1 (pt)
CN (1) CN102781981B (pt)
BR (1) BR112012020720B1 (pt)
ES (2) ES2738498T3 (pt)
SG (3) SG183310A1 (pt)
WO (1) WO2011102990A2 (pt)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101706797B1 (ko) 2009-03-31 2017-02-15 다우 테크놀로지 인베스트먼츠 엘엘씨. 이중 개방 말단의 비스포스파이트 리간드를 사용한 하이드로포밀화 방법
EP2536735B1 (en) * 2010-02-19 2018-08-01 Dow Global Technologies LLC Metal-ligand complexes and catalysts
CN103153462B (zh) 2010-10-05 2016-06-01 陶氏技术投资有限责任公司 加氢甲酰基化方法
JP5826035B2 (ja) * 2011-01-22 2015-12-02 三菱樹脂株式会社 ストレッチ包装用フィルム
US9000115B2 (en) * 2011-01-27 2015-04-07 Lg Chem, Ltd. Olefin block copolymers and production methods thereof
KR102251151B1 (ko) 2012-12-27 2021-05-13 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 중합체를 제조하기 위한 중합 방법
EP2938643B1 (en) 2012-12-27 2018-01-31 Dow Global Technologies LLC Catalyst systems for olefin polymerization
KR20150103082A (ko) 2012-12-27 2015-09-09 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 중합체를 제조하기 위한 중합 방법
EP3013871B1 (en) 2013-06-28 2022-10-19 Dow Global Technologies LLC Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts
KR101725945B1 (ko) * 2014-02-18 2017-04-11 주식회사 엘지화학 아미노 퀴놀린 골격을 가지는 포스트 메탈로센 촉매
KR101914326B1 (ko) * 2014-08-28 2018-11-02 한화케미칼 주식회사 신규한 4족 전이금속 화합물 및 이의 용도
KR102588243B1 (ko) 2015-06-30 2023-10-13 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 폴리머를 제조하는 중합 방법
EP3317312B1 (en) 2015-06-30 2020-06-10 Dow Global Technologies LLC A polymerization process for producing ethylene based polymers
US10870713B2 (en) 2015-09-30 2020-12-22 Dow Global Technologies Llc Procatalyst and polymerization process using the same
BR112018005909B1 (pt) 2015-09-30 2022-05-03 Dow Global Technologies Llc Pró-catalisador para a polimerização de etileno e processo de polimerização para a produção de polímeros à base de etileno
WO2017106392A1 (en) * 2015-12-16 2017-06-22 Dow Global Technologies Llc Method for isomer reduction during polymerization and system for accomplishing the same
WO2018063799A1 (en) * 2016-09-30 2018-04-05 Dow Global Technologies Llc Thiourea group iv transition metal catalysts and polymerization systems
KR102448251B1 (ko) * 2016-09-30 2022-09-28 다우 글로벌 테크놀로지스 엘엘씨 티오구아니딘 iv 족 전이 금속 촉매 및 중합 시스템
WO2018155982A1 (ko) * 2017-02-27 2018-08-30 에스케이이노베이션 주식회사 금속 착체, 상기 금속 착체를 포함하는 금속 촉매 조성물 및 상기 금속 촉매 조성물을 이용한 에틸렌, 알파-올레핀 및 디엔을 포함하는 공중합체의 제조방법
US11066428B2 (en) 2017-09-29 2021-07-20 Dow Global Technologies Llc Bis-phenyl-phenoxy polyolefin catalysts having a methylenetrialkylsilicon ligand on the metal for improved solubility
KR102590973B1 (ko) 2017-09-29 2023-10-19 다우 글로벌 테크놀로지스 엘엘씨 개선된 용해도를 위한 금속 상에 알콕시 리간드 또는 아미도 리간드를 갖는 비스-페닐-페녹시 폴리올레핀 촉매
WO2019067274A1 (en) 2017-09-29 2019-04-04 Dow Global Technologies Llc BIS-PHENYL-PHENOXY-POLYOLEFIN CATALYSTS HAVING TWO METHYLENETRIALKYLSILICIUM-TYPE LIGANDS ON METAL FOR ENHANCED SOLUBILITY
WO2020205361A1 (en) * 2019-03-29 2020-10-08 Exxonmobil Chemical Patents Inc. Benzazole and pseudoindole diamido transition metal complexes and use thereof in olefin polymerization
CN110698513B (zh) * 2019-10-11 2022-06-17 青岛科技大学 一种三氢喹啉胺金属化合物的制备及其烯烃高温溶液聚合的应用

Family Cites Families (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US204017A (en) 1878-05-21 Improvement in cartridge-packages
CA849081A (en) 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US7163907B1 (en) 1987-01-30 2007-01-16 Exxonmobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
US5032463A (en) 1988-07-18 1991-07-16 Viskase Corporation Very low density polyethylene film from blends
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5847053A (en) 1991-10-15 1998-12-08 The Dow Chemical Company Ethylene polymer film made from ethylene polymer blends
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
WO1994000500A1 (en) 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
PT681592E (pt) 1993-01-29 2001-01-31 Dow Chemical Co Interpolimerizacoes de etileno
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
US5470993A (en) 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
EP0797612B1 (de) 1994-12-12 1999-01-13 Hüls Silicone Gesellschaft mit beschränkter Haftung Verfahren zur herstellung von im wesentlichen cyclenfreien polyorgano-siloxanen und organofunktionellen siloxanen
EP0805826B1 (en) 1995-01-24 2003-04-23 E.I. Du Pont De Nemours And Company Olefin polymers
US5637660A (en) * 1995-04-17 1997-06-10 Lyondell Petrochemical Company Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
RU2178422C2 (ru) 1996-03-27 2002-01-20 Дзе Дау Кемикал Компани Активатор катализаторов полимеризации олефинов, каталитическая система и способ полимеризации
WO1997035892A1 (en) 1996-03-27 1997-10-02 The Dow Chemical Company Solution polymerization process with dispersed catalyst activator
KR100528754B1 (ko) 1996-08-08 2006-01-09 다우 글로벌 테크놀로지스 인크. 3-헤테로원자 치환된 사이클로펜타디에닐-함유 금속 착체 및 올레핀 중합 방법
US6015868A (en) 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
JP2001506260A (ja) 1996-12-19 2001-05-15 ザ ダウ ケミカル カンパニー ３―アリール置換インデニル含有金属錯体及び重合方法
US5965756A (en) 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6096676A (en) * 1997-07-02 2000-08-01 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
CA2215444C (en) * 1997-09-15 2005-08-02 Stephen John Brown Catalyst having a ketimide ligand
US6150297A (en) 1997-09-15 2000-11-21 The Dow Chemical Company Cyclopentaphenanthrenyl metal complexes and polymerization process
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
US6555634B1 (en) 1999-05-13 2003-04-29 The Dow Chemical Company Di- and tri-heteroatom substituted indenyl metal complexes
US6340730B1 (en) 1999-12-06 2002-01-22 Univation Technologies, Llc Multiple catalyst system
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
CN1495188A (zh) 1999-12-10 2004-05-12 取代的第4族金属配合物，催化剂和烯烃聚合方法
DE60138708D1 (de) 2000-06-30 2009-06-25 Dow Global Technologies Inc Polyzyklische, kondensierte ringverbindungen, meta
AU2002225662A1 (en) 2000-11-07 2002-05-21 Symyx Technologies, Inc. Substituted pyridyl amine ligands, complexes and catalysts therefrom; processes for producing polyolefins therewith
WO2002079207A2 (en) 2001-04-02 2002-10-10 California Institute Of Technology Tri-and bidentate amido ligands prepared by palladium0 coupling and metallation thereof to form metal-amido catalysts
JP2004529187A (ja) 2001-05-14 2004-09-24 ダウ・グローバル・テクノロジーズ・インコーポレイテッド ３−アリール置換シクロペンタジエニル金属錯体及び重合方法
KR100440480B1 (ko) * 2001-08-31 2004-07-14 주식회사 엘지화학 폴리올레핀 제조용 촉매 및 이를 이용한 폴리올레핀의제조방법
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6919467B2 (en) * 2001-12-18 2005-07-19 Univation Technologies, Llc Imino-amide catalyst compositions for the polymerization of olefins
US6864205B2 (en) * 2001-12-18 2005-03-08 Univation Technologies, Llc Heterocyclic-amide catalyst compositions for the polymerization of olefins
US7199255B2 (en) 2001-12-18 2007-04-03 Univation Technologies, Llc Imino-amide catalysts for olefin polymerization
US20050010039A1 (en) 2002-03-14 2005-01-13 Graf David D Polycyclic fused heteroring compounds metal complexes and polymerization process
WO2003078483A1 (en) 2002-03-14 2003-09-25 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
JP4371305B2 (ja) 2002-04-24 2009-11-25 シミックス・ソルーションズ・インコーポレーテッド 架橋ビス芳香族リガンド、錯体、触媒、または、重合方法およびそれにより得られるポリマー
JP2005539060A (ja) 2002-09-12 2005-12-22 ダウ・グローバル・テクノロジーズ・インコーポレイテッド 金属錯体の製造方法
WO2004074333A2 (en) 2003-02-18 2004-09-02 Dow Global Technologies Inc. Process for homo- or copolymerizationof conjugated olefines
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
RU2386646C2 (ru) 2004-01-22 2010-04-20 Дау Глобал Текнолоджиз Инк. Функционализированные эластомерные композиции
US7622529B2 (en) 2004-03-17 2009-11-24 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility
US7355089B2 (en) * 2004-03-17 2008-04-08 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US7645716B2 (en) * 2004-03-17 2010-01-12 Georg-August-Universitaet Goettingen Oxygen-bridged bimetallic complex, the production thereof and its utilization for polymerization catalysis
WO2005090427A2 (en) 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
EP1727840B1 (en) 2004-03-17 2012-10-24 Dow Global Technologies LLC Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
AR048817A1 (es) 2004-03-17 2006-05-31 Dow Global Technologies Inc Composicion catalizadora que comprende agente de enlace para la formacion de copolimeros de multiples bloques de etileno
AR053693A1 (es) 2004-03-17 2007-05-16 Dow Global Technologies Inc Composiciones de interpolimero de etileno/alfa-olefina multibloque adecuado para peliculas
US7608668B2 (en) 2004-03-17 2009-10-27 Dow Global Technologies Inc. Ethylene/α-olefins block interpolymers
KR20070028530A (ko) 2004-06-22 2007-03-12 디에스엠 아이피 어셋츠 비.브이. 중합체 제조 방법
RU2007138504A (ru) 2005-03-17 2009-04-27 Дау Глобал Текнолоджиз Инк. (Us) Композиция катализатора, содержащая челночный агент передачи кинетической цепи, предназначенная для получения регионерегулярного многоблочного сополимера
US7067686B1 (en) * 2005-07-21 2006-06-27 Univation Technologies, Llc Synthesis of benzyl-metal compounds
FR2889525A1 (fr) * 2005-08-04 2007-02-09 Palumed Sa Nouveaux derives de polyquinoleines et leur utilisation therapeutique.
CA2622711A1 (en) 2005-09-15 2007-03-29 Dow Global Technologies Inc. Catalytic olefin block copolymers with controlled block sequence distribution
BRPI0617042B1 (pt) 2005-09-15 2018-05-15 Dow Global Technologies Inc. Processo para preparar um polímero ramificado, processo para preparar um copolímero em pseudo-bloco multi-ramificado e polímero em pseudo-bloco ramificado
KR20080055838A (ko) 2005-09-15 2008-06-19 다우 글로벌 테크놀로지스 인크. 다중심 셔틀링제를 통한 중합체 구성 및 분자량 분포의제어
EP2057205B1 (en) 2006-08-25 2017-02-08 Dow Global Technologies LLC Production of meta-block copolymers by polymer segment interchange
EP2170604B1 (en) 2007-07-13 2019-05-15 Dow Global Technologies LLC Ethylene/alpha-olefin interpolymers having low crystallinity hard blocks
WO2009097560A1 (en) 2008-01-30 2009-08-06 Dow Global Technologies Inc. ETHYLENE/α-OLEFIN BLOCK INTERPOLYMERS
BRPI0912921A2 (pt) * 2008-08-21 2017-05-23 Dow Global Technologies Llc complexo metal-ligante, catalisador e processo para preparo de uma poliolefina
US7858718B1 (en) * 2009-07-22 2010-12-28 Equistar Chemicals, Lp Catalysts based on 2-aryl-8-anilinoquinoline ligands
US8530593B2 (en) * 2009-10-28 2013-09-10 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof

Also Published As

Publication number Publication date
WO2011102990A2 (en) 2011-08-25
KR101854480B1 (ko) 2018-05-03
EP2536770A2 (en) 2012-12-26
ES2738498T3 (es) 2020-01-23
ES2874670T3 (es) 2021-11-05
US8729201B2 (en) 2014-05-20
CN102781981B (zh) 2015-09-16
SG10201702989VA (en) 2017-05-30
SG2014006266A (en) 2014-03-28
BR112012020720B1 (pt) 2020-01-21
US20110207903A1 (en) 2011-08-25
CN102781981A (zh) 2012-11-14
EP2536770B1 (en) 2019-06-05
SG183310A1 (en) 2012-09-27
KR20130008559A (ko) 2013-01-22
EP3549960B1 (en) 2021-03-24
EP3549960A1 (en) 2019-10-09
WO2011102990A3 (en) 2011-10-13

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