AU2008314512B2 - Process for the preparation of graphene - Google Patents
Process for the preparation of graphene Download PDFInfo
- Publication number
- AU2008314512B2 AU2008314512B2 AU2008314512A AU2008314512A AU2008314512B2 AU 2008314512 B2 AU2008314512 B2 AU 2008314512B2 AU 2008314512 A AU2008314512 A AU 2008314512A AU 2008314512 A AU2008314512 A AU 2008314512A AU 2008314512 B2 AU2008314512 B2 AU 2008314512B2
- Authority
- AU
- Australia
- Prior art keywords
- graphene
- process according
- dispersion
- paper
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 303
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 239
- 238000000034 method Methods 0.000 title claims abstract description 53
- 230000008569 process Effects 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 49
- 239000010439 graphite Substances 0.000 claims abstract description 49
- 239000002131 composite material Substances 0.000 claims abstract description 11
- 239000006185 dispersion Substances 0.000 claims description 85
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine group Chemical group NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 229910001868 water Inorganic materials 0.000 claims description 36
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 24
- 230000009467 reduction Effects 0.000 claims description 18
- 239000003638 chemical reducing agent Substances 0.000 claims description 16
- 229910021529 ammonia Inorganic materials 0.000 claims description 12
- 238000000137 annealing Methods 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000000502 dialysis Methods 0.000 claims description 6
- 238000002525 ultrasonication Methods 0.000 claims description 6
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 5
- 238000005119 centrifugation Methods 0.000 claims description 5
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N 1,4-Benzenediol Natural products OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000007529 inorganic bases Chemical class 0.000 claims description 3
- 150000007530 organic bases Chemical class 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- TUNFVOGZVQVQPE-UHFFFAOYSA-N 2-aminoethanol;methanamine Chemical group NC.NCCO TUNFVOGZVQVQPE-UHFFFAOYSA-N 0.000 claims description 2
- 229920001174 Diethylhydroxylamine Polymers 0.000 claims description 2
- 238000010907 mechanical stirring Methods 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 claims 1
- 239000002114 nanocomposite Substances 0.000 abstract description 7
- 238000011161 development Methods 0.000 abstract description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001257 hydrogen Substances 0.000 abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 4
- 238000003860 storage Methods 0.000 abstract description 4
- 239000010408 film Substances 0.000 description 23
- 238000006722 reduction reaction Methods 0.000 description 20
- 239000010410 layer Substances 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 13
- 238000005259 measurement Methods 0.000 description 11
- 239000002041 carbon nanotube Substances 0.000 description 10
- 229910021393 carbon nanotube Inorganic materials 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 230000002829 reductive effect Effects 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 210000004027 cell Anatomy 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 239000000523 sample Substances 0.000 description 7
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- 239000000084 colloidal system Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 238000003828 vacuum filtration Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 230000001419 dependent effect Effects 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 4
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 238000004220 aggregation Methods 0.000 description 4
- 238000013459 approach Methods 0.000 description 4
- 238000012512 characterization method Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 239000002086 nanomaterial Substances 0.000 description 4
- 239000002064 nanoplatelet Substances 0.000 description 4
- 229910021382 natural graphite Inorganic materials 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002109 single walled nanotube Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000002411 thermogravimetry Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000000862 absorption spectrum Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000004630 atomic force microscopy Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000004113 cell culture Methods 0.000 description 3
- 210000002950 fibroblast Anatomy 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000010850 salt effect Methods 0.000 description 3
- 238000001878 scanning electron micrograph Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000000411 transmission spectrum Methods 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 229920000547 conjugated polymer Polymers 0.000 description 2
- 230000021615 conjugation Effects 0.000 description 2
- 238000006392 deoxygenation reaction Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000007943 implant Substances 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 238000000707 layer-by-layer assembly Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920000867 polyelectrolyte Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 230000035755 proliferation Effects 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 238000002371 ultraviolet--visible spectrum Methods 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- DIIIISSCIXVANO-UHFFFAOYSA-N 1,2-Dimethylhydrazine Chemical compound CNNC DIIIISSCIXVANO-UHFFFAOYSA-N 0.000 description 1
- 241001323501 Apamea zeta Species 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 101100510326 Caenorhabditis elegans tpa-1 gene Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910002483 Cu Ka Inorganic materials 0.000 description 1
- 239000006144 Dulbecco’s modified Eagle's medium Substances 0.000 description 1
- 108010043121 Green Fluorescent Proteins Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000001237 Raman spectrum Methods 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 238000000089 atomic force micrograph Methods 0.000 description 1
- 238000005102 attenuated total reflection Methods 0.000 description 1
- 239000000560 biocompatible material Substances 0.000 description 1
- 230000003592 biomimetic effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000012769 bulk production Methods 0.000 description 1
- DEGAKNSWVGKMLS-UHFFFAOYSA-N calcein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC(CN(CC(O)=O)CC(O)=O)=C(O)C=C1OC1=C2C=C(CN(CC(O)=O)CC(=O)O)C(O)=C1 DEGAKNSWVGKMLS-UHFFFAOYSA-N 0.000 description 1
- BQRGNLJZBFXNCZ-UHFFFAOYSA-N calcein am Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC(CN(CC(=O)OCOC(C)=O)CC(=O)OCOC(C)=O)=C(OC(C)=O)C=C1OC1=C2C=C(CN(CC(=O)OCOC(C)=O)CC(=O)OCOC(=O)C)C(OC(C)=O)=C1 BQRGNLJZBFXNCZ-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000010261 cell growth Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 231100000135 cytotoxicity Toxicity 0.000 description 1
- 230000003013 cytotoxicity Effects 0.000 description 1
- 231100000263 cytotoxicity test Toxicity 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001473 dynamic force microscopy Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000002073 fluorescence micrograph Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 239000003102 growth factor Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 239000007952 growth promoter Substances 0.000 description 1
- 210000003709 heart valve Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000008292 lyophobic colloid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 210000001178 neural stem cell Anatomy 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 229960002378 oftasceine Drugs 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- -1 poly(diallyldimethylammonium chloride) Polymers 0.000 description 1
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000036316 preload Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000007847 structural defect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000000733 zeta-potential measurement Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/84—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by UV- or VIS- data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
- C01P2004/24—Nanoplates, i.e. plate-like particles with a thickness from 1-100 nanometer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Carbon And Carbon Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2008314512A AU2008314512B2 (en) | 2007-10-19 | 2008-10-17 | Process for the preparation of graphene |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2007905796A AU2007905796A0 (en) | 2007-10-19 | Process for the preparation of graphene | |
| AU2007905796 | 2007-10-19 | ||
| PCT/AU2008/001543 WO2009049375A1 (en) | 2007-10-19 | 2008-10-17 | Process for the preparation of graphene |
| AU2008314512A AU2008314512B2 (en) | 2007-10-19 | 2008-10-17 | Process for the preparation of graphene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2008314512A1 AU2008314512A1 (en) | 2009-04-23 |
| AU2008314512B2 true AU2008314512B2 (en) | 2014-07-24 |
Family
ID=40566933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2008314512A Ceased AU2008314512B2 (en) | 2007-10-19 | 2008-10-17 | Process for the preparation of graphene |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8715610B2 (enExample) |
| EP (1) | EP2212248B1 (enExample) |
| JP (1) | JP5605650B2 (enExample) |
| CN (1) | CN102066245B (enExample) |
| AU (1) | AU2008314512B2 (enExample) |
| WO (1) | WO2009049375A1 (enExample) |
Families Citing this family (170)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050077503A1 (en) * | 2003-07-23 | 2005-04-14 | Takuya Gotou | Dispersion comprising thin particles having a skeleton consisting of carbons, electroconductive coating film, electroconductive composite material, and a process for producing them |
| CN101383231B (zh) * | 2008-10-24 | 2011-04-06 | 南开大学 | 以单层石墨材料为电极材料的超级电容器 |
| CA2762430A1 (en) * | 2009-05-22 | 2011-02-10 | William Marsh Rice University | Highly oxidized graphene oxide and methods for production thereof |
| EP3865454A3 (en) * | 2009-05-26 | 2021-11-24 | Belenos Clean Power Holding AG | Stable dispersions of single and multiple graphene layers in solution |
| JP2011032156A (ja) * | 2009-07-06 | 2011-02-17 | Kaneka Corp | グラフェンまたは薄膜グラファイトの製造方法 |
| JP2011018415A (ja) * | 2009-07-10 | 2011-01-27 | Tdk Corp | 磁気センサ |
| US8507797B2 (en) | 2009-08-07 | 2013-08-13 | Guardian Industries Corp. | Large area deposition and doping of graphene, and products including the same |
| US10167572B2 (en) | 2009-08-07 | 2019-01-01 | Guardian Glass, LLC | Large area deposition of graphene via hetero-epitaxial growth, and products including the same |
| US10164135B2 (en) | 2009-08-07 | 2018-12-25 | Guardian Glass, LLC | Electronic device including graphene-based layer(s), and/or method or making the same |
| CN102471068B (zh) * | 2009-08-10 | 2014-09-17 | Idt国际株式会社 | 纳米尺寸的石墨烯类材料的制造方法及其制造设备 |
| CN101654243B (zh) * | 2009-08-28 | 2011-11-23 | 青岛大学 | 一种功能纳米石墨烯的制备方法 |
| RU2403207C1 (ru) * | 2009-09-17 | 2010-11-10 | Учреждение Российской академии наук Институт физики полупроводников им. А.В. Ржанова Сибирского отделения РАН (ИФП СО РАН) | Способ получения углеродного слоя на непроводящей подложке |
| IT1396193B1 (it) | 2009-10-07 | 2012-11-16 | Polimeri Europa Spa | Composizioni polimeriche nanocomposite termoplastiche espansibili con migliorata capacita' di isolamento termico. |
| IT1396918B1 (it) | 2009-11-03 | 2012-12-20 | Polimeri Europa Spa | Procedimento per la preparazione di nanopiastrine grafeniche ad elevata disperdibilita' in matrici polimeriche a bassa polarita' e relative composizioni polimeriche |
| FR2962121B1 (fr) | 2009-11-03 | 2012-07-13 | Centre Nat Rech Scient | Preparation de graphene par amincissement mecanique de materiaux graphitiques |
| JP2011111367A (ja) * | 2009-11-27 | 2011-06-09 | Sekisui Chem Co Ltd | 薄片化黒鉛分散液の製造方法、薄片化黒鉛分散液及び薄膜の製造方法 |
| CN101702345B (zh) * | 2009-11-27 | 2011-08-03 | 南京邮电大学 | 一种叠层石墨烯导电薄膜的制备方法 |
| JP5276026B2 (ja) * | 2010-01-13 | 2013-08-28 | 積水化学工業株式会社 | 薄片化黒鉛分散液の製造方法、薄片化黒鉛の製造方法、及び、複合材料の製造方法 |
| JP5337062B2 (ja) * | 2010-01-14 | 2013-11-06 | 積水化学工業株式会社 | 薄片化黒鉛分散液の製造方法、薄片化黒鉛分散液及び薄膜の製造方法 |
| JP5477037B2 (ja) * | 2010-02-19 | 2014-04-23 | 富士電機株式会社 | グラフェン膜の製造方法 |
| JP2011184264A (ja) * | 2010-03-10 | 2011-09-22 | Sekisui Chem Co Ltd | 薄片化黒鉛分散液の製造方法、薄片化黒鉛分散液及び薄膜の製造方法 |
| KR101154482B1 (ko) * | 2010-04-27 | 2012-06-13 | 한국과학기술연구원 | 그라펜을 이용한 투명 대전방지 코팅의 제조방법 및 이에 의해 제조된 투명 대전방지 코팅 |
| CN101844761B (zh) * | 2010-05-28 | 2012-08-15 | 上海师范大学 | 激光照射法制备还原氧化石墨烯 |
| JP5856609B2 (ja) | 2010-05-28 | 2016-02-10 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | リチウム硫黄電流生成セルの正極に使用される固体複合材料及びその製造方法並びにリチウム硫黄電流生成セル |
| JP2012015481A (ja) * | 2010-06-01 | 2012-01-19 | Sony Corp | 電界効果トランジスタの製造方法、電界効果トランジスタおよび半導体酸化グラフェンの製造方法 |
| CN101844763B (zh) * | 2010-06-24 | 2012-05-30 | 上海交通大学 | 基于酚酞啉的石墨烯制备方法 |
| EP2593403B1 (en) | 2010-07-14 | 2020-03-04 | Monash University | Method for producing a gel film and filtration membrane prepared with this method |
| JP5499980B2 (ja) * | 2010-08-02 | 2014-05-21 | 富士電機株式会社 | グラフェン薄膜の製造方法 |
| CN102403050B (zh) * | 2010-09-08 | 2013-12-18 | 中国科学院金属研究所 | 基于纳米复合材料及其制备方法和在柔性储能器件的应用 |
| GB201016925D0 (en) * | 2010-10-07 | 2010-11-24 | Univ Manchester | Graphene oxide |
| CN102452650B (zh) * | 2010-10-27 | 2013-08-21 | 清华大学 | 一种低温化学法制备石墨烯的方法 |
| US9114999B2 (en) * | 2010-10-28 | 2015-08-25 | University Of Central Florida Research Foundation, Inc. | Oxidized graphite and carbon fiber |
| CN101966989B (zh) * | 2010-11-18 | 2012-11-07 | 东华大学 | 一种采用四角氧化锌光催化还原氧化石墨烯的方法 |
| US8796361B2 (en) | 2010-11-19 | 2014-08-05 | Ppg Industries Ohio, Inc. | Adhesive compositions containing graphenic carbon particles |
| US20140150970A1 (en) | 2010-11-19 | 2014-06-05 | Ppg Industries Ohio, Inc. | Structural adhesive compositions |
| WO2012078464A2 (en) | 2010-12-08 | 2012-06-14 | 3M Innovative Properties Company | Article and method of making and using the same |
| US9090826B2 (en) | 2010-12-24 | 2015-07-28 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Light emitting body |
| CN103282305B (zh) * | 2010-12-24 | 2015-12-09 | 株式会社丰田中央研究所 | 含氮石墨烯结构体和荧光体分散液 |
| JP5516392B2 (ja) * | 2010-12-24 | 2014-06-11 | 株式会社豊田中央研究所 | カーボン蛍光体及び蛍光体分散液 |
| JP5609789B2 (ja) * | 2011-06-23 | 2014-10-22 | 株式会社豊田中央研究所 | 窒素含有グラフェン構造体及び蛍光体分散液 |
| CN102557013B (zh) * | 2010-12-28 | 2013-10-30 | 国家纳米科学中心 | 一种还原氧化石墨烯的制备方法 |
| DE102010056562B4 (de) | 2010-12-30 | 2018-10-11 | Snaptrack, Inc. | Elektroakustisches Bauelement und Verfahren zur Herstellung des elektroakustischen Bauelements |
| DE102010056572B4 (de) * | 2010-12-30 | 2018-12-27 | Snaptrack, Inc. | Elektronisches Bauelement und Verfahren zur Herstellung des elektronischen Bauelements |
| KR101254425B1 (ko) | 2011-01-20 | 2013-04-15 | 거림테크 주식회사 | 그래핀옥사이드-폴리비닐알콜 복합체를 함유하는 그래핀 필름 및 그 제조방법 |
| CN102145882B (zh) * | 2011-02-24 | 2013-05-15 | 暨南大学 | 一种水溶性石墨烯的制备方法 |
| CN102070140B (zh) * | 2011-02-28 | 2012-08-29 | 无锡第六元素高科技发展有限公司 | 一种利用强碱化学处理得到高比表面积石墨烯材料的方法 |
| CN102249220A (zh) * | 2011-03-18 | 2011-11-23 | 太原理工大学 | 一种氧化石墨烯薄膜的快速制备方法 |
| WO2012128748A1 (en) * | 2011-03-18 | 2012-09-27 | William Marsh Rice University | Patterned graphite oxide films and methods to make and use same |
| DE112012001442T5 (de) * | 2011-03-25 | 2013-12-19 | Howard University | Verfahren und vorrichtungen zum steuern von reaktionsraten von chemischen reaktionen durch anlegen eines magnetfeldes |
| CN102730668B (zh) * | 2011-04-07 | 2015-04-29 | 东丽纤维研究所（中国）有限公司 | 一种基于芳香醇通过溶剂热制备石墨烯的方法 |
| CN102730667B (zh) * | 2011-04-08 | 2014-04-09 | 安炬科技股份有限公司 | 单层石墨的制备方法 |
| JP2012224526A (ja) * | 2011-04-21 | 2012-11-15 | Hiroshima Univ | グラフェンの製造方法 |
| JP5793704B2 (ja) * | 2011-05-16 | 2015-10-14 | パナソニックＩｐマネジメント株式会社 | 多層のグラフェン層の製造方法 |
| KR102650871B1 (ko) | 2011-06-03 | 2024-03-26 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 전극을 제조하기 위한 방법 |
| CN102275906B (zh) * | 2011-06-09 | 2012-12-26 | 西安工业大学 | 一种常温制备石墨烯的方法 |
| CN102321994A (zh) * | 2011-06-13 | 2012-01-18 | 哈尔滨工业大学 | 含有石墨烯的纳米纸制备方法 |
| CN102320595A (zh) * | 2011-06-16 | 2012-01-18 | 华南理工大学 | 一种可分散的乙醇胺功能化石墨烯及其制备方法 |
| JP2013001882A (ja) * | 2011-06-21 | 2013-01-07 | Ulvac Japan Ltd | グラフェンインク及びその製造方法 |
| CN102307024B (zh) * | 2011-06-21 | 2014-04-02 | 南京航空航天大学 | 一种基于石墨烯的流体发电装置或波动传感装置 |
| US9218916B2 (en) | 2011-06-24 | 2015-12-22 | Semiconductor Energy Laboratory Co., Ltd. | Graphene, power storage device, and electric device |
| EP2731498A4 (en) | 2011-07-14 | 2015-04-22 | Univ South Florida | LONG-TERM IMPLANTABLE NEURAL INTERFACE DEVICE MADE OF SILICON CARBIDE USING ELECTRIC FIELD EFFECTS |
| CN102320597B (zh) * | 2011-07-15 | 2012-11-07 | 天津大学 | 一种石墨烯的制备方法 |
| WO2013015229A1 (en) * | 2011-07-22 | 2013-01-31 | Semiconductor Energy Laboratory Co., Ltd. | Graphite oxide, graphene oxide or graphene, electric device using the same and method of manufacturing the same, and electrodialysis apparatus |
| CN102320598A (zh) * | 2011-07-26 | 2012-01-18 | 河南大学 | 一种石墨烯的制备方法 |
| JP5748606B2 (ja) * | 2011-08-09 | 2015-07-15 | 三菱瓦斯化学株式会社 | 導電性塗料 |
| CN103748035B (zh) * | 2011-08-18 | 2016-02-10 | 株式会社半导体能源研究所 | 形成石墨烯及氧化石墨烯盐的方法、以及氧化石墨烯盐 |
| KR101294223B1 (ko) * | 2011-08-22 | 2013-08-16 | 한국과학기술원 | 대면적 그래핀 필름의 제조방법 |
| WO2013031526A1 (en) * | 2011-08-26 | 2013-03-07 | Semiconductor Energy Laboratory Co., Ltd. | Power storage device |
| US9249524B2 (en) | 2011-08-31 | 2016-02-02 | Semiconductor Energy Laboratory Co., Ltd. | Manufacturing method of composite oxide and manufacturing method of power storage device |
| KR101303285B1 (ko) * | 2011-09-08 | 2013-09-04 | 한국기계연구원 | 환원된 산화 그래핀층 및 코팅층이 순차적으로 적층되는 그래핀 페이퍼 및 이의 제조방법 |
| JP2014527950A (ja) | 2011-09-09 | 2014-10-23 | ボード オブ トラスティーズ オブノーザン イリノイ ユニバーシティー | 結晶性グラフェンおよび結晶性グラフェンの製造方法 |
| US9988551B2 (en) | 2011-09-30 | 2018-06-05 | Ppg Industries Ohio, Inc. | Black pigments comprising graphenic carbon particles |
| US8486363B2 (en) | 2011-09-30 | 2013-07-16 | Ppg Industries Ohio, Inc. | Production of graphenic carbon particles utilizing hydrocarbon precursor materials |
| US9761903B2 (en) | 2011-09-30 | 2017-09-12 | Ppg Industries Ohio, Inc. | Lithium ion battery electrodes including graphenic carbon particles |
| US12421118B2 (en) | 2011-09-30 | 2025-09-23 | Ppg Industries Ohio, Inc. | Graphenic carbon particles |
| US10240052B2 (en) | 2011-09-30 | 2019-03-26 | Ppg Industries Ohio, Inc. | Supercapacitor electrodes including graphenic carbon particles |
| US10294375B2 (en) | 2011-09-30 | 2019-05-21 | Ppg Industries Ohio, Inc. | Electrically conductive coatings containing graphenic carbon particles |
| US10763490B2 (en) | 2011-09-30 | 2020-09-01 | Ppg Industries Ohio, Inc. | Methods of coating an electrically conductive substrate and related electrodepositable compositions including graphenic carbon particles |
| KR102514830B1 (ko) | 2011-09-30 | 2023-03-30 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극, 리튬 이차 전지, 전기 자동차, 하이브리드 자동차, 이동체, 시스템, 및 전기 기기 |
| US9574094B2 (en) | 2013-12-09 | 2017-02-21 | Ppg Industries Ohio, Inc. | Graphenic carbon particle dispersions and methods of making same |
| US9938416B2 (en) | 2011-09-30 | 2018-04-10 | Ppg Industries Ohio, Inc. | Absorptive pigments comprising graphenic carbon particles |
| US9475946B2 (en) | 2011-09-30 | 2016-10-25 | Ppg Industries Ohio, Inc. | Graphenic carbon particle co-dispersions and methods of making same |
| US9832818B2 (en) | 2011-09-30 | 2017-11-28 | Ppg Industries Ohio, Inc. | Resistive heating coatings containing graphenic carbon particles |
| CN103035922B (zh) | 2011-10-07 | 2019-02-19 | 株式会社半导体能源研究所 | 蓄电装置 |
| US9487880B2 (en) * | 2011-11-25 | 2016-11-08 | Semiconductor Energy Laboratory Co., Ltd. | Flexible substrate processing apparatus |
| KR101297423B1 (ko) * | 2011-11-30 | 2013-08-14 | 한국전기연구원 | 양이온-파이 상호작용에 의해 고농도 분산된 산화 그래핀 환원물 및 그 제조방법 |
| JP6016597B2 (ja) | 2011-12-16 | 2016-10-26 | 株式会社半導体エネルギー研究所 | リチウムイオン二次電池用正極の製造方法 |
| US8771630B2 (en) | 2012-01-26 | 2014-07-08 | Enerage, Inc. | Method for the preparation of graphene |
| JP5806618B2 (ja) * | 2012-01-26 | 2015-11-10 | Ｄｏｗａエレクトロニクス株式会社 | 酸化グラフェンの還元方法およびその方法を利用した電極材料の製造方法 |
| WO2013115564A1 (ko) * | 2012-01-30 | 2013-08-08 | 연세대학교 산학협력단 | 3차원 구조의 그래핀 구조체 및 그 제조 방법 |
| WO2013119215A1 (en) * | 2012-02-08 | 2013-08-15 | Empire Technology Development Llc | Coating a substance with graphene |
| US9484158B2 (en) | 2012-02-17 | 2016-11-01 | The Trustees Of Princeton University | Graphene-ionic liquid composites |
| CN103255670A (zh) * | 2012-02-20 | 2013-08-21 | 海洋王照明科技股份有限公司 | 利用电场引导制备石墨烯纸的方法 |
| JP5719859B2 (ja) | 2012-02-29 | 2015-05-20 | 株式会社半導体エネルギー研究所 | 蓄電装置 |
| US9120676B2 (en) | 2012-03-06 | 2015-09-01 | Empire Technology Development Llc | Graphene production |
| CN103367696A (zh) * | 2012-03-29 | 2013-10-23 | 海洋王照明科技股份有限公司 | 正极片、其制备方法及锂离子电池 |
| EP2832688A4 (en) * | 2012-03-31 | 2015-11-25 | Oceans King Lighting Science | PROCESS FOR PREPARING GRAPHENE PAPER |
| RU2495752C1 (ru) * | 2012-04-02 | 2013-10-20 | Федеральное государственное бюджетное учреждение науки Институт неорганической химии им. А.В. Николаева Сибирского отделения Российской академии наук (ИНХ СО РАН) | Способ получения композиционного материала, содержащего слоистые материалы на основе графита и сульфида молибдена |
| US9630848B2 (en) | 2012-04-05 | 2017-04-25 | The Research Foundation for The State of New York | Three-dimensional carbon structures |
| CN103383898A (zh) * | 2012-05-04 | 2013-11-06 | 海洋王照明科技股份有限公司 | 石墨烯纸集流体的制备方法 |
| US9225003B2 (en) | 2012-06-15 | 2015-12-29 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing storage battery electrode, storage battery electrode, storage battery, and electronic device |
| JP5994422B2 (ja) * | 2012-06-21 | 2016-09-21 | 株式会社豊田中央研究所 | 造影剤 |
| JP6119128B2 (ja) * | 2012-06-29 | 2017-04-26 | 株式会社ニデック | 生体埋植装置 |
| CN102750998B (zh) * | 2012-07-09 | 2014-11-19 | 深圳市贝特瑞纳米科技有限公司 | 石墨烯透明导电薄膜及其制备方法 |
| CN102719803B (zh) * | 2012-07-09 | 2014-05-07 | 深圳市贝特瑞纳米科技有限公司 | 一种石墨烯透明薄膜的制备和转移方法 |
| CN102926272B (zh) * | 2012-10-09 | 2015-02-11 | 重庆大学 | 一种生物医用氧化石墨烯纸的制备方法 |
| GB201218952D0 (en) | 2012-10-22 | 2012-12-05 | Cambridge Entpr Ltd | Functional inks based on layered materials and printed layered materials |
| CN103794370A (zh) * | 2012-10-29 | 2014-05-14 | 海洋王照明科技股份有限公司 | 石墨烯/离子液体复合材料及其制备方法、复合电极及其制备方法和电化学电容器 |
| JP6159228B2 (ja) | 2012-11-07 | 2017-07-05 | 株式会社半導体エネルギー研究所 | 非水系二次電池用正極の製造方法 |
| CN103903877B (zh) * | 2012-12-26 | 2016-06-29 | 海洋王照明科技股份有限公司 | 一种石墨烯/氧化石墨烯复合集流体的制备方法 |
| US9673454B2 (en) | 2013-02-18 | 2017-06-06 | Semiconductor Energy Laboratory Co., Ltd. | Sodium-ion secondary battery |
| US10431354B2 (en) | 2013-03-15 | 2019-10-01 | Guardian Glass, LLC | Methods for direct production of graphene on dielectric substrates, and associated articles/devices |
| US9593019B2 (en) | 2013-03-15 | 2017-03-14 | Guardian Industries Corp. | Methods for low-temperature graphene precipitation onto glass, and associated articles/devices |
| US11430979B2 (en) | 2013-03-15 | 2022-08-30 | Ppg Industries Ohio, Inc. | Lithium ion battery anodes including graphenic carbon particles |
| CN103145124B (zh) * | 2013-03-27 | 2015-01-14 | 北京大学 | 高性能石墨烯纸及其制备方法 |
| US9490472B2 (en) | 2013-03-28 | 2016-11-08 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing electrode for storage battery |
| CN103233296B (zh) * | 2013-05-17 | 2015-09-30 | 山西大学 | 一种n掺杂柔性石墨烯纤维的制备方法 |
| CN103335741B (zh) * | 2013-06-19 | 2016-02-24 | 暨南大学 | 一种基于石墨烯的光纤温度传感器及其制作方法 |
| CN103337381A (zh) * | 2013-07-05 | 2013-10-02 | 电子科技大学 | 一种制造柔性电极的方法 |
| KR20150027870A (ko) * | 2013-08-29 | 2015-03-13 | 연세대학교 산학협력단 | 그래핀 기반 나노복합소재의 합성 방법 및 상기 방법을 이용하여 합성된 그래핀 기반 나노복합소재 |
| CN103466610B (zh) * | 2013-09-25 | 2015-05-20 | 中国科学院理化技术研究所 | 一种石墨烯化学修饰方法 |
| CN103570012B (zh) * | 2013-10-29 | 2016-04-27 | 安徽百特新材料科技有限公司 | 一种石墨烯的制备方法 |
| WO2015069226A1 (en) * | 2013-11-05 | 2015-05-14 | The Regents Of The University Of California | Graphene oxide and carbon nanotube ink and methods for producing the same |
| US10727465B2 (en) | 2013-11-15 | 2020-07-28 | Semiconductor Energy Laboratory Co., Ltd. | Nonaqueous secondary battery |
| KR102490666B1 (ko) | 2013-11-28 | 2023-01-26 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 전력 저장 유닛 및 그를 포함하는 전자 기기 |
| JP2016013958A (ja) | 2013-12-02 | 2016-01-28 | 株式会社半導体エネルギー研究所 | 素子、膜の作製方法 |
| KR102306495B1 (ko) | 2013-12-04 | 2021-09-28 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 축전체 및 전자 기기 |
| WO2015089272A2 (en) * | 2013-12-12 | 2015-06-18 | Rensselaer Polytechnic Institute | Porous graphene network electrodes and an all-carbon lithium ion battery containing the same |
| US20150166348A1 (en) | 2013-12-18 | 2015-06-18 | Semiconductor Energy Laboratory Co., Ltd. | Graphene, graphene-including layer, electrode, and power storage device |
| EP3148934B1 (en) * | 2014-05-01 | 2023-04-12 | Royal Melbourne Institute of Technology | Graphene production process |
| DE102014007137A1 (de) * | 2014-05-16 | 2015-11-19 | Dräger Safety AG & Co. KGaA | Elektrode für einen elektronischen Gassensor, Herstellungsverfahren für eine Elektrode und Verwendung einer Elektrode |
| US10586954B2 (en) | 2014-05-23 | 2020-03-10 | Semiconductor Energy Laboratory Co., Ltd. | Electronic device including secondary battery |
| JP6745587B2 (ja) | 2014-05-29 | 2020-08-26 | 株式会社半導体エネルギー研究所 | 電極の製造方法 |
| CN104118872B (zh) * | 2014-08-04 | 2017-03-22 | 长沙赛维能源科技有限公司 | 一种氧化石墨烯/石墨烯溶液的提纯方法及装置 |
| CN104183824B (zh) * | 2014-09-09 | 2015-10-21 | 南京中储新能源有限公司 | 石墨烯/醌类化合物复合材料、制备方法和二次铝电池 |
| WO2016042437A1 (en) | 2014-09-19 | 2016-03-24 | Semiconductor Energy Laboratory Co., Ltd. | Secondary battery |
| AU2015349612A1 (en) | 2014-11-17 | 2017-06-29 | Imagine Intelligent Materials Limited | Graphene electrode |
| JP6565641B2 (ja) * | 2014-12-02 | 2019-08-28 | 大日本印刷株式会社 | 薄片状黒鉛、黒鉛材料、及び薄片状黒鉛分散液 |
| JP6437825B2 (ja) * | 2015-01-06 | 2018-12-12 | 国立大学法人広島大学 | グラフェン／シリカ複合体の製造方法およびその方法により製造されたグラフェン／シリカ複合体 |
| WO2016151628A1 (en) * | 2015-03-24 | 2016-09-29 | Kyushu University, National University Corporation | Anion exchange membrane and method for manufacturing same |
| US10541390B2 (en) | 2015-05-18 | 2020-01-21 | Semiconductor Energy Laboratory Co., Ltd. | Power storage unit and electronic device |
| WO2016191564A1 (en) | 2015-05-26 | 2016-12-01 | The Regents Of The University Of California | Dispersions of holey graphene materials and applications thereof |
| KR102543599B1 (ko) * | 2015-05-27 | 2023-06-13 | 니폰 제온 가부시키가이샤 | 탄소막 및 그 제조 방법, 그리고, 섬유상 탄소 나노 구조체 분산액 및 그 제조 방법 |
| JP2016222526A (ja) | 2015-05-29 | 2016-12-28 | 株式会社半導体エネルギー研究所 | 膜の作製方法および素子 |
| US10145005B2 (en) | 2015-08-19 | 2018-12-04 | Guardian Glass, LLC | Techniques for low temperature direct graphene growth on glass |
| CN105140045A (zh) * | 2015-08-20 | 2015-12-09 | 西安岳达植物科技有限公司 | 一种基于石墨烯聚吡咯的赝电容超级电容器的电极材料 |
| US10351661B2 (en) | 2015-12-10 | 2019-07-16 | Ppg Industries Ohio, Inc. | Method for producing an aminimide |
| US10377928B2 (en) | 2015-12-10 | 2019-08-13 | Ppg Industries Ohio, Inc. | Structural adhesive compositions |
| CN105883790A (zh) * | 2016-05-26 | 2016-08-24 | 同济大学 | 一种低温剥离修饰石墨烯及其制备方法 |
| US11069890B2 (en) * | 2016-05-31 | 2021-07-20 | Rutgers, The State University Of New Jersey | Hollow particles formed from 2-dimensional materials |
| JP6809985B2 (ja) * | 2016-06-22 | 2021-01-06 | 三ツ星ベルト株式会社 | 摩擦伝動ベルト |
| JP6795466B2 (ja) * | 2016-07-19 | 2020-12-02 | 三ツ星ベルト株式会社 | 伝動ベルト及びその製造方法 |
| WO2018053496A1 (en) * | 2016-09-19 | 2018-03-22 | University Of Houston System | Orientation of materials via application of a magnetic field and use of magnetically-oriented devices and device component |
| CN106629696A (zh) * | 2016-09-20 | 2017-05-10 | 天津工业大学 | 真空蒸镀法制备还原氧化石墨烯薄膜 |
| CN107064277B (zh) * | 2017-06-23 | 2018-03-20 | 湖北民族学院 | 一种电化学传感器的制备方法及应用 |
| KR20200075353A (ko) * | 2018-12-18 | 2020-06-26 | 대주전자재료 주식회사 | 환원된 그래핀 옥사이드 및 이의 제조 방법 |
| US11588150B2 (en) | 2019-05-20 | 2023-02-21 | Nanograf Corporation | Anode active material including low-defect turbostratic carbon |
| CA3146177A1 (en) | 2019-07-08 | 2021-01-14 | Alter Biota Inc. | Preparation of hydrous graphene oxide for use as a concrete admixture |
| KR102758840B1 (ko) * | 2019-09-06 | 2025-01-23 | 로베르트 보쉬 게엠베하 | 양성자 교환 막 연료 전지용 가스 확산층 및 그 제조 방법 |
| JPWO2021130815A1 (enExample) * | 2019-12-23 | 2021-07-01 | ||
| CH717232A1 (de) | 2020-03-16 | 2021-09-30 | Shcheblanov Aleksandr | Generator zum Erzeugen rigförmiger und räumlicher Wirbel in einer Flüssigkeit. |
| KR102850997B1 (ko) * | 2020-08-12 | 2025-08-27 | 한국전기연구원 | 고내열성 그래핀-실리콘-탄소나노튜브 복합체의 제조방법, 이로부터 제조되는 복합체 및 이를 포함하는 이차전지 |
| KR102778068B1 (ko) | 2020-09-14 | 2025-03-10 | 삼성전자주식회사 | 배선 구조물, 그 형성 방법, 및 상기 배선 구조물을 포함하는 반도체 장치 |
| CN113135563A (zh) * | 2021-05-25 | 2021-07-20 | 北京航空航天大学 | 一种可连续调控水浸润性的石墨烯纸及其应用 |
| CN113311045B (zh) * | 2021-07-16 | 2022-09-20 | 福建师范大学 | 一种石墨烯纳米卷固化盐酸克仑特罗传感器制备方法 |
| CN114027320B (zh) * | 2021-12-27 | 2023-06-02 | 上海金铎禹辰水环境工程有限公司 | 一种石墨烯抗菌材料及其制备方法和应用 |
| GB2620171B (en) * | 2022-06-30 | 2024-12-25 | Toraphene Ltd | Biodegradable packaging material, use and method for manufacturing thereof |
| CN116375009B (zh) * | 2022-12-26 | 2024-06-11 | 中国科学院福建物质结构研究所 | 一种改性石墨烯的制备方法 |
| CN116004093B (zh) * | 2022-12-26 | 2023-10-03 | 中国科学院福建物质结构研究所 | 一种防腐涂层及其制备方法 |
| CN116688945A (zh) * | 2023-07-06 | 2023-09-05 | 桂林清研皓隆新材料有限公司 | 一种多孔石墨烯吸附材料及其制备方法与应用 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2798878A (en) * | 1954-07-19 | 1957-07-09 | Nat Lead Co | Preparation of graphitic acid |
| JP2690982B2 (ja) * | 1988-12-06 | 1997-12-17 | 日本化成株式会社 | 熱膨張性黒鉛及びその製造方法 |
| JP2000044219A (ja) * | 1998-07-30 | 2000-02-15 | Sumikin Chemical Co Ltd | 熱膨張性黒鉛の製造方法 |
| EP1072585B1 (en) * | 1999-07-29 | 2003-10-01 | Mitsubishi Gas Chemical Company, Inc. | Process for producing dimethylcyanamide |
| JP4798411B2 (ja) * | 2000-08-09 | 2011-10-19 | 三菱瓦斯化学株式会社 | 炭素からなる骨格を持つ薄膜状粒子の合成方法 |
| JP4591666B2 (ja) * | 2003-07-23 | 2010-12-01 | 三菱瓦斯化学株式会社 | 炭素からなる骨格を持つ薄膜状粒子を含む分散液、導電性塗膜および導電性複合材料ならびにこれらの製造方法 |
| JP2006015291A (ja) * | 2004-07-05 | 2006-01-19 | Hitachi Powdered Metals Co Ltd | 黒鉛系水素吸蔵材料及びその製造方法 |
| WO2006065937A2 (en) * | 2004-12-16 | 2006-06-22 | Nantero, Inc. | Aqueous carbon nanotube applicator liquids and methods for producing applicator liquids thereof |
| WO2008048295A2 (en) * | 2005-11-18 | 2008-04-24 | Northwestern University | Stable dispersions of polymer-coated graphitic nanoplatelets |
| US20080048152A1 (en) * | 2006-08-25 | 2008-02-28 | Jang Bor Z | Process for producing nano-scaled platelets and nanocompsites |
| US8132746B2 (en) * | 2007-04-17 | 2012-03-13 | Nanotek Instruments, Inc. | Low-temperature method of producing nano-scaled graphene platelets and their nanocomposites |
| US7824651B2 (en) * | 2007-05-08 | 2010-11-02 | Nanotek Instruments, Inc. | Method of producing exfoliated graphite, flexible graphite, and nano-scaled graphene platelets |
-
2008
- 2008-10-17 CN CN200880121723.XA patent/CN102066245B/zh not_active Expired - Fee Related
- 2008-10-17 JP JP2010529196A patent/JP5605650B2/ja not_active Expired - Fee Related
- 2008-10-17 AU AU2008314512A patent/AU2008314512B2/en not_active Ceased
- 2008-10-17 US US12/738,758 patent/US8715610B2/en not_active Expired - Fee Related
- 2008-10-17 WO PCT/AU2008/001543 patent/WO2009049375A1/en not_active Ceased
- 2008-10-17 EP EP08839659.3A patent/EP2212248B1/en not_active Not-in-force
Non-Patent Citations (1)
| Title |
|---|
| STANKOVICH, S et al. J. Mater. Chem. 2006, Vol. 16, pages 155-158. * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2212248B1 (en) | 2017-05-24 |
| WO2009049375A1 (en) | 2009-04-23 |
| CN102066245A (zh) | 2011-05-18 |
| EP2212248A1 (en) | 2010-08-04 |
| EP2212248A4 (en) | 2015-07-08 |
| CN102066245B (zh) | 2014-07-16 |
| JP5605650B2 (ja) | 2014-10-15 |
| AU2008314512A1 (en) | 2009-04-23 |
| US8715610B2 (en) | 2014-05-06 |
| US20100303706A1 (en) | 2010-12-02 |
| JP2011500488A (ja) | 2011-01-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU2008314512B2 (en) | Process for the preparation of graphene | |
| Chen et al. | Mechanically strong, electrically conductive, and biocompatible graphene paper | |
| Gautam et al. | Methods of hexagonal boron nitride exfoliation and its functionalization: covalent and non-covalent approaches | |
| Lee et al. | Highly controllable transparent and conducting thin films using layer-by-layer assembly of oppositely charged reduced graphene oxides | |
| Kang et al. | Nylon 610 and carbon nanotube composite by in situ interfacial polymerization | |
| Zhou et al. | Scotch-tape-like exfoliation effect of graphene quantum dots for efficient preparation of graphene nanosheets in water | |
| Pan et al. | Green fabrication of chitosan films reinforced with parallel aligned graphene oxide | |
| Li et al. | Processable aqueous dispersions of graphene nanosheets | |
| Cui et al. | Exfoliation of graphite to few-layer graphene in aqueous media with vinylimidazole-based polymer as high-performance stabilizer | |
| Roy et al. | Physical and electrochemical characterization of reduced graphene oxide/silver nanocomposites synthesized by adopting a green approach | |
| Wan et al. | Highly controllable and green reduction of graphene oxide to flexible graphene film with high strength | |
| Wang et al. | Enhanced electrical and mechanical properties of rubber/graphene film through layer-by-layer electrostatic assembly | |
| Zhang et al. | Aqueous stabilization of graphene sheets using exfoliated montmorillonite nanoplatelets for multifunctional free-standing hybrid films via vacuum-assisted self-assembly | |
| US10807048B2 (en) | Compositions of graphene materials with metal nanostructures and microstructures and methods of making and using including pressure sensors | |
| US20160254070A1 (en) | Hybrid pani/carbon nano-composites for production of thin, transparent and conductive films | |
| Notley et al. | Bacterial Interaction with Graphene Particles and | |
| Li et al. | Single-step process toward achieving superhydrophobic reduced graphene oxide | |
| KR20130021051A (ko) | 대면적 그래핀 필름의 제조방법 | |
| Rani et al. | Multilayer films of cationic graphene-polyelectrolytes and anionic graphene-polyelectrolytes fabricated using layer-by-layer self-assembly | |
| Lu et al. | Stable Aqueous Suspension and Self‐Assembly of Graphite Nanoplatelets Coated with Various Polyelectrolytes | |
| Bai et al. | Preparation of stable aqueous dispersion of edge-oxidized graphene and its transparent conductive films | |
| Gurunathan et al. | An environmentally friendly approach to the reduction of graphene oxide by Escherichia fergusoni | |
| Bai et al. | NaCl and oxalic acid–assisted solvothermal exfoliation of edge-oxidized graphite to produce organic graphene dispersion for transparent conductive film application | |
| Tian et al. | The fabrication of single-walled carbon nanotube/polyelectrolyte multilayer composites bylayer-by-layer assembly and magnetic field assisted alignment | |
| Wang et al. | Synthesis, photoluminescence and bio-targeting applications of blue graphene quantum dots |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) | ||
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |