TW200922906A - Method of hydrodechlorination to produce dihydrofluorinated olefins - Google Patents

Method of hydrodechlorination to produce dihydrofluorinated olefins Download PDF

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Publication number
TW200922906A
TW200922906A TW097124919A TW97124919A TW200922906A TW 200922906 A TW200922906 A TW 200922906A TW 097124919 A TW097124919 A TW 097124919A TW 97124919 A TW97124919 A TW 97124919A TW 200922906 A TW200922906 A TW 200922906A
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TW
Taiwan
Prior art keywords
copper
catalyst
carbon
hydrogen
weight
Prior art date
Application number
TW097124919A
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English (en)
Chinese (zh)
Inventor
Mario Joseph Nappa
Ekaterina N Swearingen
Original Assignee
Du Pont
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Publication of TW200922906A publication Critical patent/TW200922906A/zh

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/628—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/23—Preparation of halogenated hydrocarbons by dehalogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
TW097124919A 2007-07-03 2008-07-02 Method of hydrodechlorination to produce dihydrofluorinated olefins TW200922906A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US95819007P 2007-07-03 2007-07-03
US451807P 2007-11-27 2007-11-27

Publications (1)

Publication Number Publication Date
TW200922906A true TW200922906A (en) 2009-06-01

Family

ID=39942915

Family Applications (1)

Application Number Title Priority Date Filing Date
TW097124919A TW200922906A (en) 2007-07-03 2008-07-02 Method of hydrodechlorination to produce dihydrofluorinated olefins

Country Status (11)

Country Link
US (3) US7795482B2 (enExample)
EP (1) EP2173693B1 (enExample)
JP (3) JP5660891B2 (enExample)
KR (1) KR20100046147A (enExample)
CN (2) CN103524297B (enExample)
BR (1) BRPI0810961A2 (enExample)
CA (1) CA2686603A1 (enExample)
ES (1) ES2443024T3 (enExample)
RU (1) RU2476414C2 (enExample)
TW (1) TW200922906A (enExample)
WO (1) WO2009006358A1 (enExample)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7795482B2 (en) 2007-07-03 2010-09-14 E. I. Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins
US7641808B2 (en) * 2007-08-23 2010-01-05 E.I. Du Pont De Nemours And Company Azeotropic compositions comprising fluorinated olefins for cleaning applications
US8399721B2 (en) * 2008-12-22 2013-03-19 E I Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins
BRPI1010133A2 (pt) 2009-06-03 2016-03-15 Du Pont "aparelho resfriador, método para a produção de resfriamento no aparelho resfriador e utilização do cis-hfo-1336mzz"
US9217100B2 (en) 2009-09-16 2015-12-22 The Chemours Company Fc, Llc Chiller apparatus containing trans-1,1,1,4,4,4-hexafluoro-2-butene and methods of producing cooling therein
AU2010295712B2 (en) 2009-09-16 2014-09-25 The Chemours Company Fc, Llc. Composition comprising cis-1,1,1,4,4,4-hexafluoro-2-butene and trans-1,2-dichloroethylene, apparatus containing same and methods of producing cooling therein
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
US20110269860A1 (en) 2010-04-28 2011-11-03 E.I. Du Pont De Nemours And Company Foam expansion agent compositions containing hydrohaloolefin butene and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams
US8604257B2 (en) * 2010-05-21 2013-12-10 Honeywell International Inc. Process for the preparation of fluorinated cis-alkene
US8524955B2 (en) * 2010-05-21 2013-09-03 Honeywell International Inc. Process for the preparation of hexafluoro-2-butyne
CN101961658B (zh) * 2010-09-07 2013-03-06 西安近代化学研究所 氟化钙基氟化催化剂及其用途
US9000241B2 (en) * 2010-11-02 2015-04-07 E. I. Du Pont De Nemours And Company Use of copper-nickel catalysts for dehlogenation of chlorofluorocompounds
WO2012064477A2 (en) 2010-11-10 2012-05-18 E. I. Du Pont De Nemours And Company Compositions comprising cis-1,1,1,4,4,4-hexafluoro-2-butene and 2-difluoromethoxy-1,1,1,2-tetrafluoroethane and uses thereof
HK1198590A1 (en) 2011-08-19 2015-04-30 The Chemours Company Fc, Llc Processes and compositions for organic rankine cycles for generating mechanical energy from heat
US20130104575A1 (en) 2011-11-02 2013-05-02 E I Du Pont De Nemours And Company Use of compositions comprising 1,1,1,2,3-pentafluoropropane and optionally z-1,1,1,4,4,4-hexafluoro-2-butene in high temperature heat pumps
US9003797B2 (en) 2011-11-02 2015-04-14 E L Du Pont De Nemours And Company Use of compositions comprising 1,1,1,2,3-pentafluoropropane and optionally Z-1,1,1,4,4,4-hexafluoro-2-butene in power cycles
US20130104573A1 (en) 2011-11-02 2013-05-02 E I Du Pont De Nemours And Company Use of compositions comprising 1,1,1,2,3-pentafluoropropane and optionally z-1,1,1,4,4,4-hexafluoro-2-butene in chillers
SG11201402779UA (en) 2011-12-02 2014-06-27 Du Pont Foam expansion agent compositions containing z-1,1,1,4,4,4-hexafluoro-2-butene and their uses in the preparation of polyurethane and polyisocyanurate polymer foams
EP2802549B1 (en) * 2012-01-09 2019-03-27 The Chemours Company FC, LLC Process for reactor passivation
HK1199854A1 (en) * 2012-02-17 2015-07-24 E. I. Du Pont De Nemours And Company Azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene and e-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
JP5817591B2 (ja) * 2012-03-01 2015-11-18 旭硝子株式会社 ２，３，３，３−テトラフルオロプロペンの製造方法
CN103373896B (zh) * 2012-04-13 2015-03-18 中化蓝天集团有限公司 一种1,1,1,4,4,4-六氟-2-丁烯的制备方法
TW201413192A (zh) 2012-08-01 2014-04-01 Du Pont Ｅ－１，１，１，４，４，４－六氟－２－丁烯在熱泵的使用
ES2943357T3 (es) 2014-02-07 2023-06-12 Chemours Co Fc Llc Proceso integrado para la producción de Z-1,1,1,4,4,4-hexafluoro-2-buteno
WO2015160532A1 (en) * 2014-04-16 2015-10-22 The Chemours Company Fc, Llc Conversion of chlorofluororopanes and chlorofluropropenes to more desirable fluoropropanes and fluororopenes
JP6827810B2 (ja) * 2014-08-25 2021-02-10 Ａｇｃ株式会社 ハイドロフルオロオレフィンの製造方法
EP3187478B1 (en) * 2014-08-25 2020-03-04 AGC Inc. Method for producing hydrofluoroolefin
WO2016126792A1 (en) 2015-02-06 2016-08-11 The Chemours Company Fc, Llc Compositions comprising z-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
JP6730292B2 (ja) 2015-02-06 2020-07-29 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー Ｅ−１，１，１，４，４，４−ヘキサフルオロ−２−ブテンを含む組成物及びその使用
JP6930962B2 (ja) 2015-08-07 2021-09-01 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー Ｚ−１，１，１，４，４，４−ヘキサフルオロ−２−ブテンのｅ−１，１，１，４，４，４−ヘキサフルオロ−２−ブテンへの接触異性化
ES2909340T3 (es) * 2016-01-22 2022-05-06 Chemours Co Fc Llc Formación de espuma de un producto de reacción de un poliisocianato y de un compuesto que contiene hidrógeno activo
CN107262092B (zh) * 2017-06-16 2021-03-09 巨化集团技术中心 一种合成顺式1,1,1,4,4,4-六氟-2-丁烯的催化剂及其制备方法和用途
CN107586251A (zh) * 2017-07-26 2018-01-16 江苏蓝色星球环保科技股份有限公司 一种1，1，1，4，4，4‑六氟‑2‑丁烯的制备方法
JP7656161B2 (ja) * 2019-07-08 2025-04-03 ダイキン工業株式会社 フッ化ビニル化合物の製造方法
CN110437028B (zh) * 2019-07-30 2020-10-27 厦门大学 一种以铜为催化剂的氯代芳香化合物(R1-Xm)的脱氯方法
CN110981688B (zh) * 2019-10-31 2021-03-23 中国矿业大学(北京) 一种气相催化合成3,4,4-三氟环丁烯的方法
JP7411780B2 (ja) 2019-11-29 2024-01-11 浙江▲藍▼天▲環▼保高科技股▲ふん▼有限公司 窒素とリンで修飾された顆粒状炭素担持二元金属触媒、その作製方法およびその応用
CN112876335B (zh) * 2019-11-29 2022-05-10 浙江蓝天环保高科技股份有限公司 一种1,1,1,4,4,4-六氟-2-丁烯的制备方法
CN110975893B (zh) * 2019-12-18 2023-04-18 浙江工业大学 用于二氟一氯甲烷高温裂解制四氟乙烯和六氟丙烯的金属氟化物催化剂、其制备方法和应用
CN111574321B (zh) * 2020-06-17 2021-09-03 广东电网有限责任公司电力科学研究院 一种反式-1,1,1,4,4,4-六氟-2-丁烯的制备方法
CN116348968A (zh) 2020-10-22 2023-06-27 Ａｇｃ株式会社 电气设备
CN112657508B (zh) * 2020-12-04 2022-07-08 中化蓝天集团有限公司 一种核壳结构的加氢脱氯催化剂、其制备方法及应用
WO2022131226A1 (ja) 2020-12-16 2022-06-23 Ａｇｃ株式会社 電気設備、充填設備、および貯蔵設備
CN112745192A (zh) * 2020-12-31 2021-05-04 山东华夏神舟新材料有限公司 顺式六氟-2-丁烯的连续制备方法
CN114716297B (zh) * 2021-01-06 2023-10-27 浙江省化工研究院有限公司 一种e-1,1,1,4,4,4-六氟-2-丁烯的制备方法
CN112811975B (zh) * 2021-04-22 2021-07-30 泉州宇极新材料科技有限公司 气相异构化制备z-1-r-3,3,3-三氟丙烯的方法
CN114870858B (zh) * 2022-03-04 2024-07-16 中化蓝天集团有限公司 一种抗积碳催化剂、其制备方法及应用

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Also Published As

Publication number Publication date
JP5660891B2 (ja) 2015-01-28
WO2009006358A1 (en) 2009-01-08
US20090012335A1 (en) 2009-01-08
KR20100046147A (ko) 2010-05-06
RU2010103460A (ru) 2011-08-10
RU2476414C2 (ru) 2013-02-27
JP2017075162A (ja) 2017-04-20
ES2443024T3 (es) 2014-02-17
CN103524297A (zh) 2014-01-22
US7795481B2 (en) 2010-09-14
CN101687736B (zh) 2013-10-30
US20090240089A1 (en) 2009-09-24
JP2010532760A (ja) 2010-10-14
CA2686603A1 (en) 2009-01-08
EP2173693A1 (en) 2010-04-14
JP2015061861A (ja) 2015-04-02
BRPI0810961A2 (pt) 2016-06-07
EP2173693B1 (en) 2013-12-18
CN103524297B (zh) 2016-08-17
CN101687736A (zh) 2010-03-31
USRE45076E1 (en) 2014-08-12
US7795482B2 (en) 2010-09-14

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