JP5660891B2 - ジヒドロフッ素化オレフィンを製造するための水素化脱塩素方法 - Google Patents

ジヒドロフッ素化オレフィンを製造するための水素化脱塩素方法 Download PDF

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JP5660891B2
JP5660891B2 JP2010515208A JP2010515208A JP5660891B2 JP 5660891 B2 JP5660891 B2 JP 5660891B2 JP 2010515208 A JP2010515208 A JP 2010515208A JP 2010515208 A JP2010515208 A JP 2010515208A JP 5660891 B2 JP5660891 B2 JP 5660891B2
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catalyst
copper
nickel
carbon
calcium fluoride
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JP2010532760A5 (enExample
JP2010532760A (ja
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マリオ・ジョウゼフ・ナッパ
エカテリーナ・エヌ・スウェリンゲン
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/628—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/23—Preparation of halogenated hydrocarbons by dehalogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2010515208A 2007-07-03 2008-06-30 ジヒドロフッ素化オレフィンを製造するための水素化脱塩素方法 Active JP5660891B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US95819007P 2007-07-03 2007-07-03
US60/958,190 2007-07-03
US451807P 2007-11-27 2007-11-27
US61/004,518 2007-11-27
PCT/US2008/068695 WO2009006358A1 (en) 2007-07-03 2008-06-30 Method of hydrodechlorination to produce dihydrofluorinated olefins

Related Child Applications (1)

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JP2014240840A Division JP2015061861A (ja) 2007-07-03 2014-11-28 ジヒドロフッ素化オレフィンを製造するための水素化脱塩素方法

Publications (3)

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JP2010532760A JP2010532760A (ja) 2010-10-14
JP2010532760A5 JP2010532760A5 (enExample) 2011-07-21
JP5660891B2 true JP5660891B2 (ja) 2015-01-28

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JP2010515208A Active JP5660891B2 (ja) 2007-07-03 2008-06-30 ジヒドロフッ素化オレフィンを製造するための水素化脱塩素方法
JP2014240840A Pending JP2015061861A (ja) 2007-07-03 2014-11-28 ジヒドロフッ素化オレフィンを製造するための水素化脱塩素方法
JP2016229714A Pending JP2017075162A (ja) 2007-07-03 2016-11-28 ジヒドロフッ素化オレフィンを製造するための水素化脱塩素方法

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JP2016229714A Pending JP2017075162A (ja) 2007-07-03 2016-11-28 ジヒドロフッ素化オレフィンを製造するための水素化脱塩素方法

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US (3) US7795482B2 (enExample)
EP (1) EP2173693B1 (enExample)
JP (3) JP5660891B2 (enExample)
KR (1) KR20100046147A (enExample)
CN (2) CN101687736B (enExample)
BR (1) BRPI0810961A2 (enExample)
CA (1) CA2686603A1 (enExample)
ES (1) ES2443024T3 (enExample)
RU (1) RU2476414C2 (enExample)
TW (1) TW200922906A (enExample)
WO (1) WO2009006358A1 (enExample)

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US7641808B2 (en) * 2007-08-23 2010-01-05 E.I. Du Pont De Nemours And Company Azeotropic compositions comprising fluorinated olefins for cleaning applications
US8399721B2 (en) * 2008-12-22 2013-03-19 E I Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins
CN102459498B (zh) 2009-06-03 2016-08-24 纳幕尔杜邦公司 含有顺式-1，1，1，4，4，4-六氟-2-丁烯的冷却器设备及其制冷方法
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US20110269860A1 (en) 2010-04-28 2011-11-03 E.I. Du Pont De Nemours And Company Foam expansion agent compositions containing hydrohaloolefin butene and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams
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US8604257B2 (en) * 2010-05-21 2013-12-10 Honeywell International Inc. Process for the preparation of fluorinated cis-alkene
CN101961658B (zh) * 2010-09-07 2013-03-06 西安近代化学研究所 氟化钙基氟化催化剂及其用途
WO2012061022A2 (en) * 2010-11-02 2012-05-10 E. I. Du Pont De Nemours And Company Use of copper-nickel catalyst for dehalogenation of chlorofluorocompounds
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CN103373896B (zh) * 2012-04-13 2015-03-18 中化蓝天集团有限公司 一种1,1,1,4,4,4-六氟-2-丁烯的制备方法
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JP6570078B2 (ja) 2014-02-07 2019-09-04 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー Ｚ−１，１，１，４，４，４−ヘキサフルオロ−２−ブテンを生成するための統合方法
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EP3253844B1 (en) 2015-02-06 2022-06-22 The Chemours Company FC, LLC Compositions comprising z-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
CN112920777A (zh) 2015-02-06 2021-06-08 科慕埃弗西有限公司 包含e-1,1,1,4,4,4-六氟-2-丁烯的组合物及其用途
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CN107262092B (zh) * 2017-06-16 2021-03-09 巨化集团技术中心 一种合成顺式1,1,1,4,4,4-六氟-2-丁烯的催化剂及其制备方法和用途
CN107586251A (zh) * 2017-07-26 2018-01-16 江苏蓝色星球环保科技股份有限公司 一种1，1，1，4，4，4‑六氟‑2‑丁烯的制备方法
JP7656161B2 (ja) * 2019-07-08 2025-04-03 ダイキン工業株式会社 フッ化ビニル化合物の製造方法
CN110437028B (zh) * 2019-07-30 2020-10-27 厦门大学 一种以铜为催化剂的氯代芳香化合物(R1-Xm)的脱氯方法
CN110981688B (zh) * 2019-10-31 2021-03-23 中国矿业大学(北京) 一种气相催化合成3,4,4-三氟环丁烯的方法
CN112876335B (zh) * 2019-11-29 2022-05-10 浙江蓝天环保高科技股份有限公司 一种1,1,1,4,4,4-六氟-2-丁烯的制备方法
JP7411780B2 (ja) 2019-11-29 2024-01-11 浙江▲藍▼天▲環▼保高科技股▲ふん▼有限公司 窒素とリンで修飾された顆粒状炭素担持二元金属触媒、その作製方法およびその応用
CN110975893B (zh) * 2019-12-18 2023-04-18 浙江工业大学 用于二氟一氯甲烷高温裂解制四氟乙烯和六氟丙烯的金属氟化物催化剂、其制备方法和应用
CN111574321B (zh) * 2020-06-17 2021-09-03 广东电网有限责任公司电力科学研究院 一种反式-1,1,1,4,4,4-六氟-2-丁烯的制备方法
WO2022085544A1 (ja) 2020-10-22 2022-04-28 Ａｇｃ株式会社 電気設備
CN112657508B (zh) * 2020-12-04 2022-07-08 中化蓝天集团有限公司 一种核壳结构的加氢脱氯催化剂、其制备方法及应用
CN116635970A (zh) 2020-12-16 2023-08-22 Ａｇｃ株式会社 电气设备、填充设备和储存设备
CN112745192A (zh) * 2020-12-31 2021-05-04 山东华夏神舟新材料有限公司 顺式六氟-2-丁烯的连续制备方法
CN114716297B (zh) * 2021-01-06 2023-10-27 浙江省化工研究院有限公司 一种e-1,1,1,4,4,4-六氟-2-丁烯的制备方法
CN112811975B (zh) * 2021-04-22 2021-07-30 泉州宇极新材料科技有限公司 气相异构化制备z-1-r-3,3,3-三氟丙烯的方法
CN114870858B (zh) * 2022-03-04 2024-07-16 中化蓝天集团有限公司 一种抗积碳催化剂、其制备方法及应用

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CA2686603A1 (en) 2009-01-08
KR20100046147A (ko) 2010-05-06
CN103524297B (zh) 2016-08-17
RU2476414C2 (ru) 2013-02-27
BRPI0810961A2 (pt) 2016-06-07
JP2015061861A (ja) 2015-04-02
JP2017075162A (ja) 2017-04-20
EP2173693B1 (en) 2013-12-18
US7795481B2 (en) 2010-09-14
USRE45076E1 (en) 2014-08-12
RU2010103460A (ru) 2011-08-10
WO2009006358A1 (en) 2009-01-08
CN101687736A (zh) 2010-03-31
TW200922906A (en) 2009-06-01
US20090012335A1 (en) 2009-01-08
EP2173693A1 (en) 2010-04-14
US20090240089A1 (en) 2009-09-24
ES2443024T3 (es) 2014-02-17
US7795482B2 (en) 2010-09-14
JP2010532760A (ja) 2010-10-14
CN101687736B (zh) 2013-10-30

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