RU2476414C2 - Способ гидродехлорирования для получения гидрофторированных олефинов - Google Patents

Способ гидродехлорирования для получения гидрофторированных олефинов Download PDF

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RU2476414C2
RU2476414C2 RU2010103460/04A RU2010103460A RU2476414C2 RU 2476414 C2 RU2476414 C2 RU 2476414C2 RU 2010103460/04 A RU2010103460/04 A RU 2010103460/04A RU 2010103460 A RU2010103460 A RU 2010103460A RU 2476414 C2 RU2476414 C2 RU 2476414C2
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catalyst
copper
1316mxx
nickel
hydrogen
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RU2010103460/04A
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RU2010103460A (ru
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Марио Джозеф НАППА
Екатерина Н. СВЕАРИНГЕН
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Е.И.Дюпон Де Немур Энд Компани
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/628—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/23—Preparation of halogenated hydrocarbons by dehalogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
RU2010103460/04A 2007-07-03 2008-06-30 Способ гидродехлорирования для получения гидрофторированных олефинов RU2476414C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US95819007P 2007-07-03 2007-07-03
US60/958,190 2007-07-03
US451807P 2007-11-27 2007-11-27
US61/004,518 2007-11-27
PCT/US2008/068695 WO2009006358A1 (en) 2007-07-03 2008-06-30 Method of hydrodechlorination to produce dihydrofluorinated olefins

Publications (2)

Publication Number Publication Date
RU2010103460A RU2010103460A (ru) 2011-08-10
RU2476414C2 true RU2476414C2 (ru) 2013-02-27

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Country Link
US (3) US7795482B2 (enExample)
EP (1) EP2173693B1 (enExample)
JP (3) JP5660891B2 (enExample)
KR (1) KR20100046147A (enExample)
CN (2) CN103524297B (enExample)
BR (1) BRPI0810961A2 (enExample)
CA (1) CA2686603A1 (enExample)
ES (1) ES2443024T3 (enExample)
RU (1) RU2476414C2 (enExample)
TW (1) TW200922906A (enExample)
WO (1) WO2009006358A1 (enExample)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7795482B2 (en) 2007-07-03 2010-09-14 E. I. Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins
US7641808B2 (en) * 2007-08-23 2010-01-05 E.I. Du Pont De Nemours And Company Azeotropic compositions comprising fluorinated olefins for cleaning applications
US8399721B2 (en) * 2008-12-22 2013-03-19 E I Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins
ES2572206T5 (es) 2009-06-03 2019-10-28 Chemours Co Fc Llc Aparato enfriador que contiene cis-1,1,1,4,4,4-hexafluoro-2-buteno y procedimientos para producir enfriamiento en él
CA2774202C (en) 2009-09-16 2017-11-28 E. I. Du Pont De Nemours And Company Composition comprising cis-1,1,1,4,4,4-hexafluoro-2-butene and trans-1,2-dichloroethylene, apparatus containing same and methods of producing cooling therein
AU2010295687B2 (en) 2009-09-16 2014-11-06 E. I. Du Pont De Nemours And Company Chiller apparatus containing trans-1,1,1,4,4,4-hexafluoro-2-butene and methods of producing cooling therein
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
US20110269860A1 (en) 2010-04-28 2011-11-03 E.I. Du Pont De Nemours And Company Foam expansion agent compositions containing hydrohaloolefin butene and water and their uses in the preparation of polyurethane and polyisocyanurate polymer foams
US8604257B2 (en) * 2010-05-21 2013-12-10 Honeywell International Inc. Process for the preparation of fluorinated cis-alkene
US8524955B2 (en) * 2010-05-21 2013-09-03 Honeywell International Inc. Process for the preparation of hexafluoro-2-butyne
CN101961658B (zh) * 2010-09-07 2013-03-06 西安近代化学研究所 氟化钙基氟化催化剂及其用途
JP5838217B2 (ja) * 2010-11-02 2016-01-06 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ クロロフルオロ化合物の脱ハロゲン化のための銅−ニッケル触媒の使用
WO2012064477A2 (en) 2010-11-10 2012-05-18 E. I. Du Pont De Nemours And Company Compositions comprising cis-1,1,1,4,4,4-hexafluoro-2-butene and 2-difluoromethoxy-1,1,1,2-tetrafluoroethane and uses thereof
CN107327327B (zh) 2011-08-19 2020-04-17 科慕埃弗西有限公司 用于由热产生机械能的有机朗肯循环的方法和组合物
US20130104573A1 (en) 2011-11-02 2013-05-02 E I Du Pont De Nemours And Company Use of compositions comprising 1,1,1,2,3-pentafluoropropane and optionally z-1,1,1,4,4,4-hexafluoro-2-butene in chillers
US20130104575A1 (en) 2011-11-02 2013-05-02 E I Du Pont De Nemours And Company Use of compositions comprising 1,1,1,2,3-pentafluoropropane and optionally z-1,1,1,4,4,4-hexafluoro-2-butene in high temperature heat pumps
US9003797B2 (en) 2011-11-02 2015-04-14 E L Du Pont De Nemours And Company Use of compositions comprising 1,1,1,2,3-pentafluoropropane and optionally Z-1,1,1,4,4,4-hexafluoro-2-butene in power cycles
JP2015502429A (ja) 2011-12-02 2015-01-22 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ Ｚ−１，１，１，４，４，４−ヘキサフルオロ−２−ブテンを含有する泡膨張剤組成物ならびにポリウレタンおよびポリイソシアヌレートポリマー発泡体の製造におけるその使用
WO2013106305A1 (en) * 2012-01-09 2013-07-18 E.I. Du Pont De Nemours And Company Process for reactor passivation
US20150014606A1 (en) * 2012-02-17 2015-01-15 E I Du Pont De Nemours And Company Azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene and e-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
JP5817591B2 (ja) * 2012-03-01 2015-11-18 旭硝子株式会社 ２，３，３，３−テトラフルオロプロペンの製造方法
CN103373896B (zh) * 2012-04-13 2015-03-18 中化蓝天集团有限公司 一种1,1,1,4,4,4-六氟-2-丁烯的制备方法
TW201413192A (zh) 2012-08-01 2014-04-01 Du Pont Ｅ－１，１，１，４，４，４－六氟－２－丁烯在熱泵的使用
MX394632B (es) 2014-02-07 2025-03-24 Chemours Co Fc Llc Proceso integrado para la produccion de z-1,1,1,4,4,4-hexafluoro-2-buteno.
WO2015160532A1 (en) 2014-04-16 2015-10-22 The Chemours Company Fc, Llc Conversion of chlorofluororopanes and chlorofluropropenes to more desirable fluoropropanes and fluororopenes
EP3187477A4 (en) 2014-08-25 2018-04-11 Asahi Glass Company, Limited Process for producing hydrofluoroolefin
CN106660908B (zh) * 2014-08-25 2020-04-28 Ａｇｃ株式会社 氢氟烯烃的制造方法
EP3253845B1 (en) 2015-02-06 2021-08-04 The Chemours Company FC, LLC Compositions comprising e-1,1,1,4,4,4-hexafluoro-2-butene and uses thereof
CN107207948B (zh) 2015-02-06 2021-08-06 科慕埃弗西有限公司 包含z-1，1，1，4，4，4-六氟-2-丁烯的组合物及其用途
EP3331846B1 (en) 2015-08-07 2020-10-28 The Chemours Company FC, LLC Catalytic isomerization of z-1,1,1,4,4,4-hexafluoro-2-butene
MX2018008826A (es) * 2016-01-22 2018-09-17 Chemours Co Fc Llc Formacion de espuma del producto de reaccion de poliisocianato/compuesto que contiene hidrogeno activo.
CN107262092B (zh) * 2017-06-16 2021-03-09 巨化集团技术中心 一种合成顺式1,1,1,4,4,4-六氟-2-丁烯的催化剂及其制备方法和用途
CN107586251A (zh) * 2017-07-26 2018-01-16 江苏蓝色星球环保科技股份有限公司 一种1，1，1，4，4，4‑六氟‑2‑丁烯的制备方法
JP7656161B2 (ja) * 2019-07-08 2025-04-03 ダイキン工業株式会社 フッ化ビニル化合物の製造方法
CN110437028B (zh) * 2019-07-30 2020-10-27 厦门大学 一种以铜为催化剂的氯代芳香化合物(R1-Xm)的脱氯方法
CN110981688B (zh) * 2019-10-31 2021-03-23 中国矿业大学(北京) 一种气相催化合成3,4,4-三氟环丁烯的方法
WO2021104437A1 (zh) 2019-11-29 2021-06-03 浙江蓝天环保高科技股份有限公司 一种氮磷修饰的颗粒炭载双金属催化剂、制备方法及应用
CN112876335B (zh) * 2019-11-29 2022-05-10 浙江蓝天环保高科技股份有限公司 一种1,1,1,4,4,4-六氟-2-丁烯的制备方法
CN110975893B (zh) * 2019-12-18 2023-04-18 浙江工业大学 用于二氟一氯甲烷高温裂解制四氟乙烯和六氟丙烯的金属氟化物催化剂、其制备方法和应用
CN111574321B (zh) * 2020-06-17 2021-09-03 广东电网有限责任公司电力科学研究院 一种反式-1,1,1,4,4,4-六氟-2-丁烯的制备方法
WO2022085544A1 (ja) 2020-10-22 2022-04-28 Ａｇｃ株式会社 電気設備
CN112657508B (zh) * 2020-12-04 2022-07-08 中化蓝天集团有限公司 一种核壳结构的加氢脱氯催化剂、其制备方法及应用
CN116635970A (zh) 2020-12-16 2023-08-22 Ａｇｃ株式会社 电气设备、填充设备和储存设备
CN112745192A (zh) * 2020-12-31 2021-05-04 山东华夏神舟新材料有限公司 顺式六氟-2-丁烯的连续制备方法
CN114716297B (zh) * 2021-01-06 2023-10-27 浙江省化工研究院有限公司 一种e-1,1,1,4,4,4-六氟-2-丁烯的制备方法
CN112811975B (zh) * 2021-04-22 2021-07-30 泉州宇极新材料科技有限公司 气相异构化制备z-1-r-3,3,3-三氟丙烯的方法
CN114870858B (zh) * 2022-03-04 2024-07-16 中化蓝天集团有限公司 一种抗积碳催化剂、其制备方法及应用

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2697124A (en) * 1952-02-25 1954-12-14 Kellogg M W Co Dehalogenation of fluorohalocarbons
US2774799A (en) * 1954-04-01 1956-12-18 Kellogg M W Co Selective dehydrohalogenation of fluorohaloalkanes using a copper catalyst
US2802887A (en) * 1955-08-08 1957-08-13 Allied Chem & Dye Corp Hydrogenation of chlorotrifluoroethylene
US2900423A (en) * 1957-12-13 1959-08-18 Allied Chem Manufacture of perfluoropropene
GB974612A (en) * 1962-07-03 1964-11-04 Allied Chem Preparation of hexafluoroisopropyl alcohol
EP0053657A1 (en) * 1980-12-09 1982-06-16 Allied Corporation Preparation of chlorotrifluoroethylene and trifluoroethylene
WO1990008748A1 (en) * 1989-02-03 1990-08-09 E.I. Du Pont De Nemours And Company Improved hydrogenolysis/dehydrohalogenation process
EP0471320A1 (en) * 1990-08-13 1992-02-19 F-Tech Inc. Method for producing trifluoroethylene
EP0485246A1 (fr) * 1990-11-06 1992-05-13 Elf Atochem S.A. Fabrication de fluoroéthylènes et de chlorofluoroéthylènes
US5243103A (en) * 1988-05-24 1993-09-07 Solvay S.A. Process for obtaining catalytic compositions and process for hydrogenation of chlorofluoroalkenes by means of these compositions
RU2026279C1 (ru) * 1989-02-03 1995-01-09 Е.И.Дюпон Де Немур Энд Компани Способ гидрогенолиза и/или дегидрогалогенирования фторгалоуглеродов и/или фторгалоуглеводородов
RU2053841C1 (ru) * 1993-05-26 1996-02-10 Иркутский институт органической химии СО РАН Катализатор селективного гидрирования третичных ацетиленовых спиртов
UA65595C2 (en) * 1997-11-06 2004-04-15 Beseitigung Von Umweltshaden M Supported catalyst and method for producing fluorocarbons
WO2004096737A2 (en) * 2003-04-29 2004-11-11 Central Glass Company, Limited Fluorobutene derivatives and process for producing same

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS462324B1 (enExample) * 1966-12-16 1971-01-21
IT1186307B (it) * 1985-06-10 1987-11-26 Montefluos Spa Procedimento per la preparazione di 1,2-difluoroetilene e 1-cloro-1,2-difluoro-etilene
JP2526661B2 (ja) * 1989-04-27 1996-08-21 ダイキン工業株式会社 フルオロアルキルビニル化合物の製造法
US5068472A (en) * 1989-12-19 1991-11-26 E. I. Du Pont De Nemours And Company Multistep synthesis of hexafluoropropylene
US5097082A (en) * 1990-06-05 1992-03-17 E. I. Du Pont De Nemours And Company Production of saturated halohydrocarbons
JPH04286233A (ja) * 1991-03-14 1992-10-12 Nec Corp スタッフ同期回路
JP3275338B2 (ja) 1992-01-13 2002-04-15 ダイキン工業株式会社 １，１，１，４，４，４−ヘキサフルオロブタンの製造方法
JPH05213793A (ja) 1992-02-06 1993-08-24 Daikin Ind Ltd １，１，１，４，４，４−ヘキサフルオロブタンの製造方法
JPH05215793A (ja) 1992-02-07 1993-08-24 Fujitsu Ltd 消費電流積算方式
JP2806781B2 (ja) * 1993-02-01 1998-09-30 セントラル硝子株式会社 フッ素化炭化水素の製造方法
DE4305163A1 (de) 1993-02-19 1994-08-25 Bayer Ag Verfahren zur Herstellung von Hexafluorbuten
JP2003176243A (ja) * 1993-06-10 2003-06-24 Daikin Ind Ltd １，１，１，３，３−ペンタフルオロプロパン及び／又は１，１，３，３，３−ペンタフルオロプロペンの製造方法
CA2167698A1 (en) 1993-08-16 1995-02-23 Russell Ward Johnson Process for combining chlorine-containing molecules to synthesize fluorine-containing products
US5892135A (en) * 1996-08-23 1999-04-06 E. I. Du Pont De Nemours And Company Process for the production of trifluoroethylene
JP3876951B2 (ja) * 1998-09-08 2007-02-07 日本ゼオン株式会社 フルオロシクロペンテン類の製造方法
US7795482B2 (en) 2007-07-03 2010-09-14 E. I. Du Pont De Nemours And Company Method of hydrodechlorination to produce dihydrofluorinated olefins

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2697124A (en) * 1952-02-25 1954-12-14 Kellogg M W Co Dehalogenation of fluorohalocarbons
US2774799A (en) * 1954-04-01 1956-12-18 Kellogg M W Co Selective dehydrohalogenation of fluorohaloalkanes using a copper catalyst
US2802887A (en) * 1955-08-08 1957-08-13 Allied Chem & Dye Corp Hydrogenation of chlorotrifluoroethylene
US2900423A (en) * 1957-12-13 1959-08-18 Allied Chem Manufacture of perfluoropropene
GB974612A (en) * 1962-07-03 1964-11-04 Allied Chem Preparation of hexafluoroisopropyl alcohol
EP0053657A1 (en) * 1980-12-09 1982-06-16 Allied Corporation Preparation of chlorotrifluoroethylene and trifluoroethylene
US5243103A (en) * 1988-05-24 1993-09-07 Solvay S.A. Process for obtaining catalytic compositions and process for hydrogenation of chlorofluoroalkenes by means of these compositions
WO1990008748A1 (en) * 1989-02-03 1990-08-09 E.I. Du Pont De Nemours And Company Improved hydrogenolysis/dehydrohalogenation process
RU2026279C1 (ru) * 1989-02-03 1995-01-09 Е.И.Дюпон Де Немур Энд Компани Способ гидрогенолиза и/или дегидрогалогенирования фторгалоуглеродов и/или фторгалоуглеводородов
EP0471320A1 (en) * 1990-08-13 1992-02-19 F-Tech Inc. Method for producing trifluoroethylene
EP0485246A1 (fr) * 1990-11-06 1992-05-13 Elf Atochem S.A. Fabrication de fluoroéthylènes et de chlorofluoroéthylènes
RU2053841C1 (ru) * 1993-05-26 1996-02-10 Иркутский институт органической химии СО РАН Катализатор селективного гидрирования третичных ацетиленовых спиртов
UA65595C2 (en) * 1997-11-06 2004-04-15 Beseitigung Von Umweltshaden M Supported catalyst and method for producing fluorocarbons
WO2004096737A2 (en) * 2003-04-29 2004-11-11 Central Glass Company, Limited Fluorobutene derivatives and process for producing same

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US20090012335A1 (en) 2009-01-08
TW200922906A (en) 2009-06-01
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US7795482B2 (en) 2010-09-14
CN101687736A (zh) 2010-03-31
JP2010532760A (ja) 2010-10-14
US7795481B2 (en) 2010-09-14
WO2009006358A1 (en) 2009-01-08
US20090240089A1 (en) 2009-09-24
RU2010103460A (ru) 2011-08-10
KR20100046147A (ko) 2010-05-06
CN103524297A (zh) 2014-01-22
CN103524297B (zh) 2016-08-17
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CA2686603A1 (en) 2009-01-08
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