GB974612A - Preparation of hexafluoroisopropyl alcohol - Google Patents
Preparation of hexafluoroisopropyl alcoholInfo
- Publication number
- GB974612A GB974612A GB2622863A GB2622863A GB974612A GB 974612 A GB974612 A GB 974612A GB 2622863 A GB2622863 A GB 2622863A GB 2622863 A GB2622863 A GB 2622863A GB 974612 A GB974612 A GB 974612A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- hexafluoroisopropyl alcohol
- preparation
- hydrogen
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 abstract 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 3
- 239000010949 copper Substances 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 2
- 229910001618 alkaline earth metal fluoride Inorganic materials 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 2
- 229910000431 copper oxide Inorganic materials 0.000 abstract 2
- VBZWSGALLODQNC-UHFFFAOYSA-N hexafluoroacetone Chemical compound FC(F)(F)C(=O)C(F)(F)F VBZWSGALLODQNC-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 abstract 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 2
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 abstract 1
- 229910001634 calcium fluoride Inorganic materials 0.000 abstract 1
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical class [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000011698 potassium fluoride Substances 0.000 abstract 1
- 235000003270 potassium fluoride Nutrition 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Hexafluoroisopropyl alcohol is prepared by reacting hexafluoroacetone with hydrogen at a temperature of at least 200 DEG C. in the presence of a catalyst comprising metallic copper and chromium oxide. The catalyst may be used on a support, alkaline earth metal fluorides being specified for this purpose. An Example is given.ALSO:A catalyst for the hydrogenation of hexafluoroacetone to hexafluoroisopropyl alcohol (see Division C2) comprises metallic copper and chromium oxide which may be supported on an alkaline earth metal fluoride, preferably calcium fluoride. An example describes the preparation of such a catalyst by addition of an aqueous solution of potassium fluoride and hydroxide to an aqueous solution of copper and chromium nitrates. The precipitate is separated, dried and reduced with hydrogen to give the catalyst.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US20738262A | 1962-07-03 | 1962-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB974612A true GB974612A (en) | 1964-11-04 |
Family
ID=22770315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2622863A Expired GB974612A (en) | 1962-07-03 | 1963-07-02 | Preparation of hexafluoroisopropyl alcohol |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1210772B (en) |
| ES (1) | ES289529A1 (en) |
| FR (1) | FR1361260A (en) |
| GB (1) | GB974612A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4467124A (en) * | 1980-11-11 | 1984-08-21 | Central Glass Company Limited | Preparation of 1,1,1,3,3,3-hexafluoropropane-2-ol by vapor phase catalytic reaction of hexafluoroacetone hydrate with hydrogen |
| GB2147295A (en) * | 1983-09-27 | 1985-05-09 | Central Glass Co Ltd | Preparation of 1,1,1,3,3,3-hexafluoropropane-2-ol by hydrogenolysis of hexafluoroacetone hydrate |
| EP1711449A1 (en) * | 2004-02-04 | 2006-10-18 | Halocarbon Products Corporation | Purification of 1,1,1,3,3,3-hexafluoroisopropanol |
| WO2009006358A1 (en) * | 2007-07-03 | 2009-01-08 | E. I. Du Pont De Nemours And Company | Method of hydrodechlorination to produce dihydrofluorinated olefins |
| US8399721B2 (en) | 2008-12-22 | 2013-03-19 | E I Du Pont De Nemours And Company | Method of hydrodechlorination to produce dihydrofluorinated olefins |
| CN111205166A (en) * | 2019-12-30 | 2020-05-29 | 天津市长芦化工新材料有限公司 | Method for preparing hexafluoroisopropanol by gas-phase hydrogenation |
-
1963
- 1963-07-01 DE DE1963A0043475 patent/DE1210772B/en active Pending
- 1963-07-01 FR FR940009A patent/FR1361260A/en not_active Expired
- 1963-07-01 ES ES0289529A patent/ES289529A1/en not_active Expired
- 1963-07-02 GB GB2622863A patent/GB974612A/en not_active Expired
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4467124A (en) * | 1980-11-11 | 1984-08-21 | Central Glass Company Limited | Preparation of 1,1,1,3,3,3-hexafluoropropane-2-ol by vapor phase catalytic reaction of hexafluoroacetone hydrate with hydrogen |
| GB2147295A (en) * | 1983-09-27 | 1985-05-09 | Central Glass Co Ltd | Preparation of 1,1,1,3,3,3-hexafluoropropane-2-ol by hydrogenolysis of hexafluoroacetone hydrate |
| EP2275396A3 (en) * | 2004-02-04 | 2011-03-02 | Halocarbon Products Corporation | Purification of 1,1,1,3,3,3-hexafluoroisopropanol |
| EP1711449A1 (en) * | 2004-02-04 | 2006-10-18 | Halocarbon Products Corporation | Purification of 1,1,1,3,3,3-hexafluoroisopropanol |
| EP1711449A4 (en) * | 2004-02-04 | 2008-02-20 | Halocarbon Prod Corp | Purification of 1,1,1,3,3,3-hexafluoroisopropanol |
| JP2007520561A (en) * | 2004-02-04 | 2007-07-26 | ヘイロウカーボン プロダクツ コーポレイション | Purification of 1,1,1,3,3,3-hexafluoroisopropanol |
| US7659433B2 (en) | 2004-02-04 | 2010-02-09 | Halocarbon Products Corporation | Purification of 1,1,1,3,3,3-hexafluoroisopropanol |
| RU2476414C2 (en) * | 2007-07-03 | 2013-02-27 | Е.И.Дюпон Де Немур Энд Компани | Method of hydrodechlorination for obtaining hydrofluorinated olefins |
| US7795482B2 (en) | 2007-07-03 | 2010-09-14 | E. I. Du Pont De Nemours And Company | Method of hydrodechlorination to produce dihydrofluorinated olefins |
| WO2009006358A1 (en) * | 2007-07-03 | 2009-01-08 | E. I. Du Pont De Nemours And Company | Method of hydrodechlorination to produce dihydrofluorinated olefins |
| CN101687736B (en) * | 2007-07-03 | 2013-10-30 | 纳幕尔杜邦公司 | Method of hydrodechlorination to produce dihydrofluorinated olefins |
| CN103524297A (en) * | 2007-07-03 | 2014-01-22 | 纳幕尔杜邦公司 | Method of hydrodechlorination to produce dihydrofluorinated olefins |
| USRE45076E1 (en) | 2007-07-03 | 2014-08-12 | E I Du Pont De Nemours And Company | Method of hydrodechlorination to produce dihydrofluorinated olefins |
| CN103524297B (en) * | 2007-07-03 | 2016-08-17 | 纳幕尔杜邦公司 | Hydrogenation-dechlorination prepares the method for dihydro fluorinated olefins |
| US8399721B2 (en) | 2008-12-22 | 2013-03-19 | E I Du Pont De Nemours And Company | Method of hydrodechlorination to produce dihydrofluorinated olefins |
| CN111205166A (en) * | 2019-12-30 | 2020-05-29 | 天津市长芦化工新材料有限公司 | Method for preparing hexafluoroisopropanol by gas-phase hydrogenation |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1210772B (en) | 1966-02-17 |
| FR1361260A (en) | 1964-05-15 |
| ES289529A1 (en) | 1963-11-01 |
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