PH12017500550A1 - Electrolyte compostion for a zinc-halide battery and bipolar electrode comprising a titanium carbide coated cathode box - Google Patents

Electrolyte compostion for a zinc-halide battery and bipolar electrode comprising a titanium carbide coated cathode box

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Publication number
PH12017500550A1
PH12017500550A1 PH12017500550A PH12017500550A PH12017500550A1 PH 12017500550 A1 PH12017500550 A1 PH 12017500550A1 PH 12017500550 A PH12017500550 A PH 12017500550A PH 12017500550 A PH12017500550 A PH 12017500550A PH 12017500550 A1 PH12017500550 A1 PH 12017500550A1
Authority
PH
Philippines
Prior art keywords
bipolar electrode
zinc
compostion
electrolyte
titanium carbide
Prior art date
Application number
PH12017500550A
Other languages
English (en)
Inventor
George W Adamson
Sara S Bowers
Original Assignee
Eos Energy Storage Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eos Energy Storage Llc filed Critical Eos Energy Storage Llc
Publication of PH12017500550A1 publication Critical patent/PH12017500550A1/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/0413—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
    • H01M10/0418—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes with bipolar electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/0436—Small-sized flat cells or batteries for portable equipment
    • H01M10/044—Small-sized flat cells or batteries for portable equipment with bipolar electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/0463—Cells or batteries with horizontal or inclined electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
    • H01M10/365—Zinc-halogen accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
    • H01M10/38—Construction or manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • H01M12/085—Zinc-halogen cells or batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0473—Filling tube-or pockets type electrodes; Applying active mass in cup-shaped terminals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
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    • H—ELECTRICITY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/76—Containers for holding the active material, e.g. tubes, capsules
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/431—Inorganic material
    • H—ELECTRICITY
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    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/44—Fibrous material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/46—Separators, membranes or diaphragms characterised by their combination with electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/543—Terminals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/029—Bipolar electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0002—Aqueous electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/543—Terminals
    • H01M50/552—Terminals characterised by their shape
    • H01M50/553—Terminals adapted for prismatic, pouch or rectangular cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/543—Terminals
    • H01M50/562—Terminals characterised by the material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Hybrid Cells (AREA)
  • Secondary Cells (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Primary Cells (AREA)
  • Battery Mounting, Suspending (AREA)
  • Inert Electrodes (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Fuel Cell (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
PH12017500550A 2014-10-06 2017-03-24 Electrolyte compostion for a zinc-halide battery and bipolar electrode comprising a titanium carbide coated cathode box PH12017500550A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201462060273P 2014-10-06 2014-10-06
US201562170200P 2015-06-03 2015-06-03
US201562173415P 2015-06-10 2015-06-10
PCT/US2015/054142 WO2016057457A2 (en) 2014-10-06 2015-10-06 Zinc-halide electrochemical cell

Publications (1)

Publication Number Publication Date
PH12017500550A1 true PH12017500550A1 (en) 2017-08-30

Family

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Family Applications (4)

Application Number Title Priority Date Filing Date
PH12017500550A PH12017500550A1 (en) 2014-10-06 2017-03-24 Electrolyte compostion for a zinc-halide battery and bipolar electrode comprising a titanium carbide coated cathode box
PH12017500568A PH12017500568A1 (en) 2014-10-06 2017-03-27 Terminal assembly for bipolar electrochemical cell or battery
PH12017500582A PH12017500582A1 (en) 2014-10-06 2017-03-29 Electrolyte for rechargeable electrochemical cell
PH12018502096A PH12018502096A1 (en) 2014-10-06 2018-09-28 Electrolyte for rechargeable electrochemical cell

Family Applications After (3)

Application Number Title Priority Date Filing Date
PH12017500568A PH12017500568A1 (en) 2014-10-06 2017-03-27 Terminal assembly for bipolar electrochemical cell or battery
PH12017500582A PH12017500582A1 (en) 2014-10-06 2017-03-29 Electrolyte for rechargeable electrochemical cell
PH12018502096A PH12018502096A1 (en) 2014-10-06 2018-09-28 Electrolyte for rechargeable electrochemical cell

Country Status (22)

Country Link
US (5) US10305111B2 (enExample)
EP (4) EP3204970B1 (enExample)
JP (7) JP6825783B2 (enExample)
KR (4) KR20170066488A (enExample)
CN (5) CN107112491A (enExample)
AU (4) AU2015328274A1 (enExample)
BR (4) BR112017006914A2 (enExample)
CA (4) CA2963078C (enExample)
CL (4) CL2017000846A1 (enExample)
CO (3) CO2017003319A2 (enExample)
DK (3) DK3204970T3 (enExample)
EA (4) EA201790557A1 (enExample)
ES (2) ES2809574T3 (enExample)
IL (4) IL251502B (enExample)
MX (4) MX383645B (enExample)
PE (4) PE20170830A1 (enExample)
PH (4) PH12017500550A1 (enExample)
SG (5) SG11201702665XA (enExample)
TW (3) TW201628235A (enExample)
UA (4) UA123574C2 (enExample)
WO (4) WO2016057477A1 (enExample)
ZA (1) ZA201702170B (enExample)

Families Citing this family (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6825783B2 (ja) 2014-10-06 2021-02-03 エオス エナジー ストレージ， エルエルシー 双極電気化学セルまたはバッテリー用の端子アセンブリ
AU2016261702B2 (en) * 2015-05-11 2021-01-28 Bromine Compounds Ltd. An additive for a flow battery
ES2997364T3 (en) 2016-03-29 2025-02-17 Eos Energy Tech Holdings Llc Electrolyte for rechargeable electrochemical cell
USD874394S1 (en) * 2016-04-04 2020-02-04 The Raymond Corporation Battery enclosure
PH12018502415A1 (en) 2016-05-17 2019-09-23 Eos Energy Storage Llc Zinc-halide battery using a deep eutectic solvent-based electrolyte
US20200036046A1 (en) * 2016-10-11 2020-01-30 Princeton University Membrane-free non-flowing single cell zinc bromine battery with bromine-trapping composite carbon foam electrode
EP3514849B1 (en) * 2016-11-16 2020-04-29 Pacesetter, Inc. Battery with enhanced resistance to dendrite formation
US10797284B2 (en) 2017-02-14 2020-10-06 Volkswagen Ag Electric vehicle battery cell with polymer frame for battery cell components
US11362371B2 (en) 2017-02-14 2022-06-14 Volkswagen Ag Method for manufacturing electric vehicle battery cells with polymer frame support
US11870028B2 (en) * 2017-02-14 2024-01-09 Volkswagen Ag Electric vehicle battery cell with internal series connection stacking
US11362338B2 (en) 2017-02-14 2022-06-14 Volkswagen Ag Electric vehicle battery cell with solid state electrolyte
US11103878B2 (en) 2017-04-03 2021-08-31 Yale University Electrochemical separation and recovery of metals
WO2019040683A1 (en) * 2017-08-24 2019-02-28 Eos Energy Storage, Llc BATTERY FRAME ELEMENT AND RECHARGEABLE BATTERIES MADE THEREFROM
US11411225B2 (en) 2017-09-26 2022-08-09 Eos Energy Storage Llc Chambered frame insert
US10634330B1 (en) 2017-10-31 2020-04-28 Riverpoint Medical, Llc Headband assembly
CN109755618B (zh) * 2017-11-01 2021-10-29 中国科学院大连化学物理研究所 一种锌溴液流电池正极电解液在电池中的应用
AU2018375287B2 (en) * 2017-12-01 2023-07-20 EOS Energy Technology Holdings, LLC Bipolar electrode comprising a loaded carbon felt
CN108172878A (zh) * 2018-02-13 2018-06-15 青海百能汇通新能源科技有限公司 电解质添加剂、电解液及电解液的制备方法
US11228058B2 (en) 2018-04-27 2022-01-18 Kyocera Corporation Flow battery, flow battery system, and control method
CN108711633B (zh) * 2018-05-28 2021-09-10 安徽鹰龙工业设计有限公司 用于锌溴液流电池的电解液
CN108808053B (zh) * 2018-06-22 2021-10-15 浙江裕源储能科技有限公司 一种锌镍液流储能电池
US12100803B2 (en) 2018-10-10 2024-09-24 Oregon State University Aqueous zinc-metal batteries comprising “water-in-salt” electrolyte
CN111261954B (zh) * 2018-11-30 2021-07-16 中国科学院物理研究所 一种高盐水系电解液、电池及其用途
JP7219462B2 (ja) * 2019-03-26 2023-02-08 国立研究開発法人産業技術総合研究所 亜鉛二次電池
CN109962242A (zh) * 2019-04-15 2019-07-02 北京航空航天大学 一种锌基电池用的添加剂
KR102255426B1 (ko) 2019-08-30 2021-05-24 한국과학기술원 아연-브롬 전지용 양극 및 이의 제조방법
JP7649998B2 (ja) * 2019-09-27 2025-03-24 パナソニックＩｐマネジメント株式会社 二次電池
AU2020358120A1 (en) * 2019-10-04 2022-05-26 Redflow R&D Pty Ltd Welded flowing electrolyte battery cell stack
CN112687930B (zh) * 2019-10-17 2022-08-30 中国科学院大连化学物理研究所 一种添加剂在锌溴液流电池电解液中的应用
CN111364081B (zh) * 2020-04-02 2021-11-23 南京理工大学 孔径和厚度呈梯度变化的多孔氧化铝模板的制备方法
CN111370783B (zh) * 2020-04-08 2021-04-20 大连理工大学 一种高性能水系氯离子电池及其制备方法
WO2021217684A1 (zh) * 2020-05-01 2021-11-04 浙江大学 一种高浓度溶液及其应用与制备方法
WO2021217682A1 (zh) * 2020-05-01 2021-11-04 杭州高烯科技有限公司 一种纯无机胶状体的制备方法及其应用
CN111446508B (zh) * 2020-05-01 2021-07-06 浙江大学 一种高浓度溶液及其应用与制备方法
US20230075749A1 (en) * 2020-06-22 2023-03-09 Offgrid Energy Labs Private Limited Zinc based rechargeable redox static energy storage device
US12388105B2 (en) * 2020-06-22 2025-08-12 Offgrid Energy Labs Inc Eutectic electrolyte for the zinc based rechargeable redox static energy storage devices
IL300897A (en) 2020-08-28 2023-04-01 Eos Energy Tech Holdings Llc Battery final assembly and frame member for a rechargeable battery
CN114497661A (zh) * 2020-11-12 2022-05-13 中国科学院大连化学物理研究所 一种锌溴液流电池电解液及其应用
KR102459671B1 (ko) * 2020-12-01 2022-10-27 비나텍주식회사 전기에너지 저장방출모듈
CN114614038A (zh) * 2020-12-09 2022-06-10 中国科学院大连化学物理研究所 一种锌溴液流电池电解液及其在锌溴液流电池中的应用
US20220238906A1 (en) * 2021-01-28 2022-07-28 Benan Energy Bipolar aqueous intercalation battery devices and associated systems and methods
CN116941076A (zh) * 2021-02-26 2023-10-24 Ess技术有限公司 预处理双极板的方法和系统及双极板在氧化还原液流电池中的使用
CN117296189A (zh) * 2021-03-31 2023-12-26 Eos能源技术控股有限责任公司 静态卤化锌电池组中与阴极表面结合的卤素络合剂
MX2023014253A (es) 2021-06-01 2024-05-06 Nth Cycle Inc Sistema de deposicion electroquimica de metal y metodo.
CN115775903B (zh) * 2021-09-06 2025-07-25 中国科学院大连化学物理研究所 一种耐低温液流电池电解液及其应用
KR20230108580A (ko) * 2022-01-11 2023-07-18 주식회사 엘지에너지솔루션 전기화학소자
CN114725538A (zh) * 2022-05-18 2022-07-08 安徽工业大学 一种用于锌溴电池的电解液
KR20240008505A (ko) 2022-07-12 2024-01-19 에스케이온 주식회사 리튬 이차 전지용 전해액 및 이를 포함하는 리튬 이차 전지
WO2024134790A1 (ja) * 2022-12-20 2024-06-27 日産自動車株式会社 積層電池及び積層電池の製造方法
GB2616988B (en) * 2023-03-01 2024-05-08 Offgrid Energy Labs Private Ltd Electrolyte for ultra efficient static zinc-based battery
WO2024204934A1 (ko) * 2023-03-29 2024-10-03 주식회사 코스모스랩 아연-브롬 전지용 수계 전해액 및 이를 포함하는 아연-브롬 전지
JP7767362B2 (ja) * 2023-08-08 2025-11-11 プライムプラネットエナジー＆ソリューションズ株式会社 電池モジュール
CN119627256B (zh) * 2023-09-13 2025-10-21 中国科学院大连化学物理研究所 一种在硫酸锌中稳定ZnOHF保护层的方法及其在水系锌离子电池中的应用
GB2625929B (en) * 2023-11-22 2024-12-25 Offgrid Energy Labs Private Ltd Electrolyte for ultra-efficient and temperature-resilient static zinc-based battery
GB2639764A (en) * 2024-03-21 2025-10-01 Offgrid Energy Labs Inc Electrolyte of ultra efficient zinc-bromine static battery
CN119528802B (zh) * 2025-01-20 2025-05-27 君集环境科技股份有限公司 一种添加剂、锌溴液流电池电解液、其制备方法及应用

Family Cites Families (92)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2740822A (en) * 1952-10-25 1956-04-03 Carrol G Sexe Primary battery
US3408232A (en) 1965-07-06 1968-10-29 Dow Chemical Co Bromine-zinc secondary cell
GB1258502A (enExample) 1969-02-21 1971-12-30
US3640770A (en) 1969-10-20 1972-02-08 Zito Co Rechargeable metal halide battery
US3640771A (en) 1969-10-20 1972-02-08 Zito Co Metal bromide battery
US3642538A (en) 1969-10-31 1972-02-15 Zito Co Metal halide battery
US3682703A (en) 1971-02-02 1972-08-08 Zito Co Metal bromide system
US3806368A (en) 1972-11-14 1974-04-23 Zito Co Zinc bromide battery
US3912999A (en) 1973-07-11 1975-10-14 California Inst Of Techn Zinc-halide battery with molten electrolyte
US4096318A (en) * 1974-10-26 1978-06-20 Basf Aktiengesellschaft Rechargeable accumulator having a manganese dioxide electrode and an acid electrolyte
US4038459A (en) * 1976-03-17 1977-07-26 Eco-Control, Inc. Halogen complexing alcohols and nitriles
US4065601A (en) 1976-09-14 1977-12-27 Eco-Control, Inc. Two phase electrolytes used as halogen traps in metal halogen secondary cells and batteries
US4058651A (en) * 1976-10-04 1977-11-15 General Electric Company Rechargeable aqueous metal-halogen cell
US4104447A (en) * 1977-09-26 1978-08-01 Eco-Control, Inc. Halogen complexing alkyl salts for use in halogen cells
CA1129945A (en) * 1977-09-30 1982-08-17 Henry F. Gibbard Complexing agents for zinc bromine storage systems
US4147840A (en) * 1978-03-24 1979-04-03 Eco-Control, Inc. Halogen complexing homotetra-alkyl salts for use in halogen cells
US4592971A (en) 1978-12-13 1986-06-03 Tracer Technologies, Inc. Metal halogen electrochemical cell
US4246324A (en) * 1979-04-09 1981-01-20 Diamond Shamrock Technologies S.A. Consumable replaceable anodes for batteries
US4306003A (en) 1980-03-28 1981-12-15 Energy Development Associates, Inc. Zinc halogen battery electrolyte composition with lead additive
US4292380A (en) * 1980-10-23 1981-09-29 Catalyst Research Corporation Two-cell battery structure
JPS57119461A (en) * 1981-01-19 1982-07-24 Meidensha Electric Mfg Co Ltd Electrode for metal-halogen battery and its manufacture
DE3274602D1 (en) * 1982-04-14 1987-01-15 Meidensha Electric Mfg Co Ltd Metal-bromine secondary battery
JPS5928588A (ja) * 1982-08-09 1984-02-15 Meidensha Electric Mfg Co Ltd 亜鉛―臭素二次電池
JPH0636376B2 (ja) 1982-08-09 1994-05-11 東洋紡績株式会社 金属−ハロゲン二次電池
JPS59111277A (ja) * 1982-12-17 1984-06-27 Meidensha Electric Mfg Co Ltd 亜鉛―臭素二次電池
DE3372683D1 (en) * 1982-11-04 1987-08-27 Meidensha Electric Mfg Co Ltd Electrolyte for zinc-bromine storage batteries
US4482614A (en) 1982-11-15 1984-11-13 Gel, Inc. Zinc-bromine battery with long term stability
US4525439A (en) * 1983-10-07 1985-06-25 Simonton Robert D Connector aperture seal for a galvanic cell
US4491625A (en) 1984-03-26 1985-01-01 Exxon Research & Engineering Co. Zinc-bromine batteries with improved electrolyte
JPS6120847A (ja) * 1984-07-10 1986-01-29 Meidensha Electric Mfg Co Ltd 臭化亜鉛電解液中のアンモニウム塩濃度測定法
JPS61101959A (ja) * 1984-10-25 1986-05-20 Meidensha Electric Mfg Co Ltd 亜鉛／臭素電池の電極
JPS61206180A (ja) * 1985-03-08 1986-09-12 Meidensha Electric Mfg Co Ltd 亜鉛‐臭素電池の電解液
US4637968A (en) * 1986-03-07 1987-01-20 Exxon Research And Engineering Company Solid bromine complexers
US4693946A (en) * 1986-03-11 1987-09-15 Eltech Systems Corporation Battery with modular air cathode and anode cage
JPH0367461A (ja) * 1989-08-07 1991-03-22 Meidensha Corp 積層電池の電極の製造方法
JPH07120537B2 (ja) * 1991-01-31 1995-12-20 トヨタ自動車株式会社 亜鉛ハロゲン電池
US5173362A (en) * 1991-02-01 1992-12-22 Globe-Union, Inc. Composite substrate for bipolar electrodes
AT399246B (de) 1992-12-23 1995-04-25 Elin Energieanwendung Verfahren zum laden und entladen von zink/brom-batterien
US5308718A (en) * 1993-01-15 1994-05-03 Globe-Union Inc. End block constructions for batteries
DE4413808B4 (de) * 1993-04-27 2007-06-06 Medtronic, Inc., Minneapolis Verfahren zur Herstellung einer Baugruppe für eine elektrochemische Zelle, Verfahren zum Zusammenbauen einer elektrochemischen Zelle und Knopfzelle
JPH06333611A (ja) * 1993-05-21 1994-12-02 Meidensha Corp 亜鉛−臭素電池の集電電極取出構造
JPH0765842A (ja) * 1993-08-27 1995-03-10 Shigeyuki Yasuda バッテリー
MY125003A (en) * 1993-11-17 2006-07-31 Jd Holding Inc Stabilized vanadium electrolyte solutions for all-vanadium redox cells and batteries
JPH07254400A (ja) * 1994-03-16 1995-10-03 Fuji Elelctrochem Co Ltd 無汞化アルカリボタン形電池
JPH07282795A (ja) * 1994-04-12 1995-10-27 Meidensha Corp 亜鉛−臭素電池の集電電極取出構造
US5591538A (en) * 1995-07-07 1997-01-07 Zbb Technologies, Inc. Zinc-bromine battery with non-flowing electrolyte
US5821009A (en) * 1997-03-03 1998-10-13 Space Systems/Loral, Inc. Fault tolerant bipolar gas electrode design for a rechargeable battery
TW369737B (en) * 1997-06-05 1999-09-11 Toyo Kohan Co Ltd A closing plate of a battery covered with a protection film and a battery using same
CN1132258C (zh) * 1997-11-07 2003-12-24 三洋电机株式会社 密闭式电池的制造方法及密闭式电池
US6159631A (en) * 1998-08-27 2000-12-12 Polystor Corporation Overcharge safety vents on prismatic cells
CN1163546C (zh) 1998-12-17 2004-08-25 日清纺织株式会社 离子导电型聚合物电解质组合物和离子导电型固体聚合物电解质
EP1202360A4 (en) * 1999-05-07 2004-09-22 Matsushita Electric Industrial Co Ltd RECTANGULAR BATTERY CONTAINER AND MANUFACTURING METHOD THEREOF
JP2001110461A (ja) * 1999-10-07 2001-04-20 Meidensha Corp 亜鉛−臭素電池
JP2001110460A (ja) * 1999-10-07 2001-04-20 Meidensha Corp 亜鉛−臭素電池
JP3580213B2 (ja) 2000-02-28 2004-10-20 松下電器産業株式会社 円筒形電池用封口板
TW521449B (en) * 2000-07-04 2003-02-21 Matsushita Electric Industrial Co Ltd A battery, a process for producing the battery, a process for producing a battery case, and a battery pack
AU2001292868A1 (en) * 2000-09-22 2002-04-02 Powercell Corporation Rib spacing with registration point
US7550230B2 (en) * 2001-03-15 2009-06-23 Powergenix Systems, Inc. Electrolyte composition for nickel-zinc batteries
US7008723B2 (en) * 2001-08-21 2006-03-07 Ecosol Solar Technologies Inc. Method of manufacture of an anode composition for use in a rechargeable electrochemical cell
US7348096B2 (en) * 2002-02-12 2008-03-25 Eveready Battery Company, Inc. Flexible thin printed battery and device and method of manufacturing same
US7081319B2 (en) * 2002-03-04 2006-07-25 The Gillette Company Preparation of nickel oxyhydroxide
US7491464B2 (en) * 2003-01-03 2009-02-17 The Gillette Company Alkaline cell with flat housing
US7435395B2 (en) * 2003-01-03 2008-10-14 The Gillette Company Alkaline cell with flat housing and nickel oxyhydroxide cathode
US20050074667A1 (en) * 2003-10-07 2005-04-07 Iuan-Jou Yang Lithium battery
CN1627554A (zh) 2003-12-11 2005-06-15 北京瑞源通动力电池技术有限公司 一种非循环电解液锌－溴电池的电解液
US7960057B2 (en) * 2004-05-17 2011-06-14 Toyota Motor Engineering & Manufacturing North America, Inc. Battery with molten salt electrolyte and phosphorus-containing cathode
JP2007194074A (ja) * 2006-01-19 2007-08-02 Toyota Motor Corp 燃料電池
WO2007083838A1 (ja) * 2006-01-19 2007-07-26 Toyota Jidosha Kabushiki Kaisha 燃料電池
US8048557B2 (en) * 2007-02-01 2011-11-01 Eaglepicher Energy Products Corporation Electrochemical device
JP5473615B2 (ja) * 2007-03-02 2014-04-16 アルベマール・コーポレーシヨン 亜鉛−臭素電池に使用する、超高純度臭化亜鉛および四級アンモニウムブロミド
US8293390B2 (en) * 2007-03-28 2012-10-23 Redflow Pty Ltd Cell stack for a flowing electrolyte battery
JP5420315B2 (ja) 2009-05-27 2014-02-19 三洋電機株式会社 密閉型電池及びその製造方法
US8911612B2 (en) * 2010-03-22 2014-12-16 Bromine Compounds Ltd. Method of operating metal-bromine cells
KR101172163B1 (ko) * 2010-06-24 2012-08-07 현대하이스코 주식회사 연료전지용 분리판 및 그 제조 방법
US8802304B2 (en) * 2010-08-10 2014-08-12 Eos Energy Storage, Llc Bifunctional (rechargeable) air electrodes comprising a corrosion-resistant outer layer and conductive inner layer
WO2012067977A2 (en) * 2010-11-15 2012-05-24 Zpower, Llc Polymer plasticizers for separators
CN102479968B (zh) * 2010-11-29 2014-06-11 中国科学院大连化学物理研究所 一种锌/多卤化物储能电池
KR101351903B1 (ko) * 2011-08-19 2014-01-17 주식회사 엘지화학 케이블형 이차전지
CN103947012B (zh) * 2011-09-21 2016-07-06 溴化合物有限公司 运行金属-溴电池的方法
CN103958470B (zh) * 2011-09-22 2017-07-11 溴化合物有限公司 用于制备溴化n‑乙基‑2‑甲基吡啶鎓和溴化n‑乙基‑3‑甲基吡啶鎓的方法
MX2014006903A (es) * 2011-12-14 2014-09-04 Eos Energy Storage Llc Celda y bateria de anodo metalico, electricamente recargable, sistemas y metodos.
WO2013112660A1 (en) 2012-01-27 2013-08-01 Eos Energy Storage, Llc Electrochemical cell with divalent cation electrolyte and at least one intercalation electrode
CN104350641B (zh) * 2012-05-10 2019-01-08 溴化合物有限公司 用于锌-溴无膜流动电池的添加剂
US9583779B2 (en) * 2013-02-04 2017-02-28 Massachusetts Institute Of Technology Metal sulfide electrodes and energy storage devices thereof
EP2953930B1 (en) * 2013-02-07 2016-12-07 Bromine Compounds Ltd. Processes for preparing 1-alkyl-3-alkyl-pyridinium bromide and uses thereof as additives in electrochemical cells
CN104600338A (zh) * 2013-11-01 2015-05-06 上海空间电源研究所 一种锌溴液流电池电解液添加剂及其制作方法
CN104716304B (zh) * 2013-12-15 2017-02-15 中国科学院大连化学物理研究所 一种锌镍双液液流电池
WO2015120303A1 (en) * 2014-02-06 2015-08-13 Cardiac Pacemakers, Inc. Battery for use with medical devices
JP6296542B2 (ja) * 2014-03-28 2018-03-20 日産自動車株式会社 亜鉛二次電池用電解質及び亜鉛二次電池
JP6825783B2 (ja) 2014-10-06 2021-02-03 エオス エナジー ストレージ， エルエルシー 双極電気化学セルまたはバッテリー用の端子アセンブリ
CN105336971B (zh) * 2015-09-25 2018-08-17 中国人民解放军63971部队 一种水系锌锰单液流电池
PH12018502415A1 (en) 2016-05-17 2019-09-23 Eos Energy Storage Llc Zinc-halide battery using a deep eutectic solvent-based electrolyte

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