NO339178B1 - Grohemmende beleggsammensetning av en silylester kopolymer, en karboksylsyre, en bi- eller trivalent metallforbindelse og et dehydrerende middel, anvendelse derav samt fremgangsmåte for å hindre begroing undersjøisk med sammensetningen - Google Patents
Grohemmende beleggsammensetning av en silylester kopolymer, en karboksylsyre, en bi- eller trivalent metallforbindelse og et dehydrerende middel, anvendelse derav samt fremgangsmåte for å hindre begroing undersjøisk med sammensetningen Download PDFInfo
- Publication number
- NO339178B1 NO339178B1 NO20031003A NO20031003A NO339178B1 NO 339178 B1 NO339178 B1 NO 339178B1 NO 20031003 A NO20031003 A NO 20031003A NO 20031003 A NO20031003 A NO 20031003A NO 339178 B1 NO339178 B1 NO 339178B1
- Authority
- NO
- Norway
- Prior art keywords
- group
- acid
- carboxylic acid
- antifouling
- meth
- Prior art date
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- PQSIXYSSKXAOFE-UHFFFAOYSA-N tri(propan-2-yl)silyl prop-2-enoate Chemical compound CC(C)[Si](C(C)C)(C(C)C)OC(=O)C=C PQSIXYSSKXAOFE-UHFFFAOYSA-N 0.000 description 1
- 125000004665 trialkylsilyl group Chemical group 0.000 description 1
- LPUCKLOWOWADAC-UHFFFAOYSA-M tributylstannyl 2-methylprop-2-enoate Chemical compound CCCC[Sn](CCCC)(CCCC)OC(=O)C(C)=C LPUCKLOWOWADAC-UHFFFAOYSA-M 0.000 description 1
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 description 1
- GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 description 1
- PGQNYIRJCLTTOJ-UHFFFAOYSA-N trimethylsilyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)O[Si](C)(C)C PGQNYIRJCLTTOJ-UHFFFAOYSA-N 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
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- 239000010457 zeolite Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
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- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2002060696A JP4361239B2 (ja) | 2002-03-06 | 2002-03-06 | 防汚塗料組成物、該組成物からなる塗膜、該塗膜で被覆された基材、および防汚方法 |
Publications (3)
Publication Number | Publication Date |
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NO20031003D0 NO20031003D0 (no) | 2003-03-04 |
NO20031003L NO20031003L (no) | 2003-09-08 |
NO339178B1 true NO339178B1 (no) | 2016-11-14 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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NO20031003A NO339178B1 (no) | 2002-03-06 | 2003-03-04 | Grohemmende beleggsammensetning av en silylester kopolymer, en karboksylsyre, en bi- eller trivalent metallforbindelse og et dehydrerende middel, anvendelse derav samt fremgangsmåte for å hindre begroing undersjøisk med sammensetningen |
Country Status (8)
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US (1) | US6916860B2 (fr) |
EP (2) | EP1342756B2 (fr) |
JP (1) | JP4361239B2 (fr) |
KR (1) | KR100521080B1 (fr) |
CN (1) | CN1219010C (fr) |
HK (1) | HK1054563B (fr) |
NO (1) | NO339178B1 (fr) |
SG (1) | SG99418A1 (fr) |
Families Citing this family (60)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1475415A1 (fr) * | 2003-05-07 | 2004-11-10 | SigmaKalon Services B.V. | Esters silyliques, leur utilisation dans les systèmes liants et les compositions de peinture, et leur procédé de préparation |
KR101147065B1 (ko) | 2003-07-07 | 2012-05-17 | 아크조노벨코팅스인터내셔널비.브이. | 실릴 에스테르 코폴리머 조성물 |
CN1930324B (zh) * | 2004-03-05 | 2012-02-08 | 株式会社开滋 | 防止镍从铜合金的润湿设备中洗脱的方法、用于防止镍洗脱的保护膜形成剂以及用于防止镍洗脱的洗涤剂 |
US8062729B2 (en) | 2005-01-14 | 2011-11-22 | Ndsu Research Foundation | Polymeric material with surface microdomains |
JP2008543602A (ja) * | 2005-05-09 | 2008-12-04 | エヌディーエスユー リサーチ ファウンデーション | ポリアミン架橋されたポリシロキサンを含有する防汚物質 |
WO2008008077A2 (fr) * | 2005-07-29 | 2008-01-17 | Ndsu Research Foundation | Polymères de polysiloxane fonctionnalisés |
US7989074B2 (en) * | 2006-06-09 | 2011-08-02 | Ndsu Research Foundation | Thermoset siloxane-urethane fouling release coatings |
US20080044577A1 (en) * | 2006-08-18 | 2008-02-21 | Vernon Harland Batdorf | Antifouling coating for fresh-water containment |
US8372384B2 (en) * | 2007-01-08 | 2013-02-12 | Ndsu Research Foundation | Quaternary ammonium functionalized cross-linked polyalkylsiloxanes with anti-fouling activity |
MY142007A (en) | 2007-02-27 | 2010-08-16 | Nitto Kasei Co Ltd | Stain-proof coating composition, method for production of the composition, stain-proof coating film formed by using the composition, coated article having the coating film on the surface, and stain-proofing treatment method for forming the coating film |
KR20100055383A (ko) | 2007-06-11 | 2010-05-26 | 엔디에스유 리서치 파운데이션 | 고착 폴리실록산-개질 폴리우레탄 코팅 및 그의 용도 |
KR101107193B1 (ko) * | 2007-06-22 | 2012-01-25 | 닛토 가세이 가부시끼 가이샤 | 방오 도료 조성물, 상기 조성물의 제조 방법, 상기 조성물을 이용하여 형성되는 방오 도막, 상기 도막을 표면에 가지는 도장물, 및 상기 도막을 형성하는 방오 처리 방법 |
US7901485B2 (en) * | 2007-07-11 | 2011-03-08 | Mccutchen Co. | Radial counterflow carbon capture and flue gas scrubbing |
US8053535B2 (en) | 2007-07-11 | 2011-11-08 | Ndsu Research Foundation | Polysiloxanes with anti-fouling activity |
US8709394B2 (en) * | 2007-09-28 | 2014-04-29 | Ndsu Research Foundation | Antimicrobial polysiloxane materials containing metal species |
US8071706B2 (en) * | 2008-02-13 | 2011-12-06 | Ndsu Research Foundation | Siloxane polymer containing tethered levofloxacin |
US20100004202A1 (en) * | 2008-02-15 | 2010-01-07 | Ndsu Research Foundation | Quaternary ammonium-functionalized-POSS compounds |
JP4521589B2 (ja) | 2008-12-19 | 2010-08-11 | 日東化成株式会社 | 防汚塗料組成物、該組成物を用いて形成される防汚塗膜、該塗膜を表面に有する塗装物、及び該塗膜を形成する防汚処理方法 |
US7989521B1 (en) | 2008-12-19 | 2011-08-02 | Nitto Kasei Co., Ltd. | Antifouling coating composition, antifouling coating film formed using the composition, coated article having the coating film on the surface, and antifouling treatment method to form the coating film |
KR101133182B1 (ko) * | 2009-06-02 | 2012-04-06 | (주)조은산업 | 기화성 방청레진이 코팅된 마대 제조방법 |
KR101048482B1 (ko) * | 2009-09-14 | 2011-07-11 | 주식회사 케이씨씨 | 방오 도료 조성물 |
FR2953850B1 (fr) * | 2009-12-15 | 2012-02-10 | Total Raffinage Marketing | Melange de solvants non-aromatiques, son procede de preparation et son utilisation pour des vernis et des encres d'impression |
EP2348077B1 (fr) | 2010-01-26 | 2013-04-03 | Jotun A/S | Composition antisalissure |
EP2386608A1 (fr) * | 2010-04-20 | 2011-11-16 | PPG Coatings Europe B.V. | Composition de revêtement |
EP2576707A2 (fr) | 2010-06-04 | 2013-04-10 | Jotun A/S | Revêtement antisalissure |
JP4934851B2 (ja) | 2010-06-23 | 2012-05-23 | 日本ペイントマリン株式会社 | 防汚塗膜の形成方法 |
KR101712371B1 (ko) * | 2011-01-06 | 2017-03-07 | 주식회사 케이씨씨 | 가수분해성 금속함유 공중합체, 그 제조방법 및 이를 포함하는 방오도료 조성물 |
JP2014524443A (ja) * | 2011-08-17 | 2014-09-22 | アーチ・ケミカルズ・インコーポレーテッド | 亜鉛ピリチオンおよび銅化合物からの銅ピリチオンの合成 |
AU2012251537B2 (en) | 2011-12-02 | 2016-08-18 | Akzo Nobel Coatings International B.V. | Waterborne antifouling coating composition |
EP2708594A1 (fr) | 2012-09-18 | 2014-03-19 | Jotun A/S | Procédé de nettoyage |
EP2912120B1 (fr) | 2012-10-23 | 2017-12-20 | Jotun A/S | Composition de revêtement antisalissure |
EP2725073B1 (fr) | 2012-10-23 | 2016-08-03 | Jotun A/S | Composition de revêtement antisalissure |
CN104955828A (zh) | 2012-12-19 | 2015-09-30 | 佐敦集团 | 甲硅烷基酯共聚物 |
WO2014141927A1 (fr) * | 2013-03-15 | 2014-09-18 | 日東化成株式会社 | Composition de revêtement antisalissure, film de revêtement antisalissure formé à l'aide de ladite composition, et article enduit présentant un film de revêtement antisalissure en surface |
US20170000093A1 (en) * | 2013-06-24 | 2017-01-05 | Daikin Industries, Ltd. | Fabric for preventing adhesion of aquatic organisms |
EP2902453A1 (fr) | 2014-01-31 | 2015-08-05 | Jotun A/S | Composition antisalissure |
EP2902452A1 (fr) | 2014-01-31 | 2015-08-05 | Jotun A/S | Composition antisalissure |
CN106047173B (zh) | 2015-04-09 | 2020-12-11 | 佐敦集团 | 防污组合物 |
KR101718514B1 (ko) | 2015-05-06 | 2017-03-22 | 한국해양과학기술원 | 방오 도료용 양친매성 하이드로젤 입자 및 그 제조방법 |
WO2017009301A1 (fr) | 2015-07-13 | 2017-01-19 | Jotun A/S | Composition antisalissure |
EP3584290B1 (fr) * | 2015-09-25 | 2021-07-21 | Mitsubishi Chemical Corporation | Copolymère (méth)acrylique, solution de polymère, composition contenant un polymère, composition de revêtement antisalissure et procédé de production de copolymère (méth)acrylique |
JP6907856B2 (ja) * | 2016-10-04 | 2021-07-21 | 信越化学工業株式会社 | (メタ)アクリル酸トリイソプロピルシリルと(メタ)アクリル酸誘導体の共重合体およびその製造方法 |
JP7178167B2 (ja) | 2016-11-11 | 2022-11-25 | ヨトゥン アーエス | 防汚組成物 |
CN109983083B (zh) | 2016-11-11 | 2021-08-17 | 佐敦有限公司 | 防污组合物 |
CN108070055B (zh) * | 2016-11-11 | 2022-10-04 | 佐敦公司 | 防污组合物 |
US11279835B2 (en) | 2016-11-11 | 2022-03-22 | Hempel A/S | Antifouling coating composition comprising novel carbon-based hydrolysable polymers |
DE112018000434B4 (de) | 2017-01-19 | 2024-05-29 | Jotun A/S | Verschmutzungslösungs- bzw. Fouling-Release-Beschichtungszusammensetzung und Verfahren zum Schützen eines Objekts vor Verschmutzung bzw. Fouling |
TWI758448B (zh) | 2017-03-29 | 2022-03-21 | 日商三菱化學股份有限公司 | 樹脂組成物及防污塗料組成物 |
GB201718898D0 (en) * | 2017-11-15 | 2017-12-27 | Jotun As | Antifouling composition |
CN107868182A (zh) * | 2017-11-30 | 2018-04-03 | 天津大学 | 一种多元协同防污涂料树脂及其制备方法 |
CN107987819B (zh) * | 2017-12-20 | 2020-06-19 | 卫辉市化工有限公司 | 一种固井用低毒、低泡油基泥浆冲洗剂及其制备方法 |
GB201804434D0 (en) * | 2018-03-20 | 2018-05-02 | Jotun As | Composition |
KR102103310B1 (ko) * | 2018-03-30 | 2020-04-22 | 닛뽄 페인트 마린 가부시키가이샤 | 도료 조성물 및 이것으로부터 형성되는 도막 |
WO2019203182A1 (fr) * | 2018-04-20 | 2019-10-24 | 日東化成株式会社 | Copolymère pour composition de revêtement antisalissure et composition de revêtement antisalissure contenant ledit copolymère |
JP6472562B1 (ja) | 2018-07-03 | 2019-02-20 | 日本ペイントマリン株式会社 | 防汚塗料組成物用ビヒクル樹脂及びそれを含む防汚塗料組成物 |
CA3118345A1 (fr) * | 2018-11-22 | 2020-05-28 | Basf Coatings Gmbh | Copolymeres d'organo-etain en tant que catalyseurs de reticulation polymeres |
CN109593439B (zh) * | 2018-12-14 | 2020-12-08 | 重庆绿涂腾科技有限公司 | 一种改性氧化石墨烯水性环氧富锌底漆及其制备方法 |
CN113166579B (zh) * | 2019-12-04 | 2022-09-30 | 厦门双瑞船舶涂料有限公司 | 一种环境友好型防污涂料用的有机无机纳米复合防污涂层及其制备方法 |
CN112694833A (zh) * | 2020-12-26 | 2021-04-23 | 海南大学 | 一种含玄武岩纤维粉及鳞片粉的复合低表面能防污涂料及其制备方法 |
CN115895375A (zh) * | 2022-11-26 | 2023-04-04 | 夜视丽新材料(仙居)有限公司 | 一种防水防污涂层树脂 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1016681A2 (fr) * | 1998-12-28 | 2000-07-05 | Chugoku Marine Paints, Ltd. | Copolymères (méth)acrylate de silyle, procédés pour les préparer, compositions de peintures antisalissures contenant ces copolymères, revêtements antisalissures formés à partir de ces compositions, méthodes antisalissures reposant sur ces compositions, et coques ou structures sous-marines revêtues de la pellicule obtenue |
Family Cites Families (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0131626B1 (fr) | 1983-01-17 | 1989-05-24 | M & T Chemicals, Inc. | Peintures pouvant s'eroder pour le controle de l'encrassement marin |
US4593055A (en) | 1983-01-17 | 1986-06-03 | M&T Chemicals Inc. | Erodible ship-bottom paints for control of marine fouling |
JPS6357675A (ja) | 1986-08-28 | 1988-03-12 | Chugoku Toryo Kk | 防汚性コ−テイング材 |
JPS63215780A (ja) | 1987-03-04 | 1988-09-08 | Dainippon Ink & Chem Inc | 防汚塗料用樹脂 |
GB8824003D0 (en) | 1988-10-13 | 1988-11-23 | Int Paint Plc | Coating compositions |
JPH031991A (ja) | 1989-05-30 | 1991-01-08 | Toshiba Corp | 携帯可能電子機器 |
JP2775862B2 (ja) | 1989-06-27 | 1998-07-16 | 日本油脂株式会社 | 生物付着防止塗料組成物 |
GB9006318D0 (en) | 1990-03-21 | 1990-05-16 | Courtaulds Coatings Ltd | Coating compositions |
JPH04264168A (ja) | 1991-02-18 | 1992-09-18 | Nippon Oil & Fats Co Ltd | 塗料組成物 |
JP2956262B2 (ja) | 1991-02-18 | 1999-10-04 | 日本油脂株式会社 | 塗料組成物 |
JP2956263B2 (ja) | 1991-02-18 | 1999-10-04 | 日本油脂株式会社 | 塗料組成物 |
JP2679884B2 (ja) | 1991-02-21 | 1997-11-19 | キヤノン株式会社 | 研削砥石 |
JP2747459B2 (ja) * | 1991-06-20 | 1998-05-06 | 永記造漆工業股▲分▼有限公司 | 自己研磨型の防汚塗料組成物 |
JPH051993A (ja) | 1991-06-26 | 1993-01-08 | Ishikawajima Harima Heavy Ind Co Ltd | 帯状繊維物の配向性測定装置 |
JP2500117B2 (ja) | 1991-07-30 | 1996-05-29 | セントラル硝子株式会社 | 保護被覆を施した機能性膜付ガラス |
JPH06157941A (ja) | 1992-11-17 | 1994-06-07 | Nippon Oil & Fats Co Ltd | 防汚性塗料組成物及びそれを用いた防汚性塗膜の形成方法 |
JPH06157940A (ja) | 1992-11-17 | 1994-06-07 | Nippon Oil & Fats Co Ltd | 防汚性塗料組成物及びそれを用いた防汚性塗膜の形成方法 |
JPH06340511A (ja) | 1993-05-31 | 1994-12-13 | Shinto Paint Co Ltd | 海中生物防汚剤 |
JP3261220B2 (ja) | 1993-06-30 | 2002-02-25 | 日本油脂ビーエーエスエフコーティングス株式会社 | 水中防汚塗料組成物 |
JP2790021B2 (ja) | 1993-09-30 | 1998-08-27 | 日本油脂株式会社 | 塗料組成物 |
JP3188948B2 (ja) * | 1994-04-25 | 2001-07-16 | 日東化成株式会社 | 防汚塗料用樹脂 |
JP3396349B2 (ja) | 1994-11-21 | 2003-04-14 | 日本油脂ビーエーエスエフコーティングス株式会社 | 生物付着防止用塗料組成物 |
JP3451786B2 (ja) | 1995-03-29 | 2003-09-29 | 日本油脂Basfコーティングス株式会社 | 塗料組成物 |
JP3474673B2 (ja) | 1995-03-30 | 2003-12-08 | 日本油脂Basfコーティングス株式会社 | 塗料組成物 |
JP3474672B2 (ja) | 1995-03-30 | 2003-12-08 | 日本油脂Basfコーティングス株式会社 | 塗料組成物 |
JPH08277372A (ja) | 1995-04-04 | 1996-10-22 | Nippon Oil & Fats Co Ltd | 塗料組成物 |
JP3565988B2 (ja) | 1995-05-29 | 2004-09-15 | 住友化学工業株式会社 | 表面コート剤、その硬化膜およびその硬化膜被覆の合成樹脂成形品 |
MY115462A (en) | 1995-06-01 | 2003-06-30 | Chugoku Marine Paints | Antifouling coating composition, coating film formed from said antifouling coating composition, antifouling method using said antifouling coating composition and hull or underwater structure coated with said coating film |
JP3906936B2 (ja) | 1995-06-01 | 2007-04-18 | 中国塗料株式会社 | 防汚塗料組成物、この防汚塗料組成物から形成されている塗膜および該防汚塗料組成物を用いた防汚方法並びに該塗膜で被覆された船体または水中構造物 |
JP3696333B2 (ja) | 1995-06-01 | 2005-09-14 | 中国塗料株式会社 | 防汚塗料組成物、この防汚塗料組成物から形成されている塗膜および該防汚塗料組成物を用いた防汚方法並びに該塗膜で被覆された船体または水中構造物 |
JP3715713B2 (ja) | 1995-06-01 | 2005-11-16 | 中国塗料株式会社 | 防汚塗料組成物、この防汚塗料組成物から形成されている塗膜および該防汚塗料組成物を用いた防汚方法並びに該塗膜で被覆された船体または水中構造物 |
JPH091997A (ja) | 1995-06-21 | 1997-01-07 | Toru Hachisu | 折り紙立体額 |
JPH0948951A (ja) | 1995-08-08 | 1997-02-18 | Tonen Corp | 着色コーティング用組成物及びそれを用いた着色ガラスとその製造方法 |
SG60054A1 (en) | 1996-04-17 | 1999-02-22 | Nof Corp | Coating composition |
JP3874486B2 (ja) * | 1996-04-17 | 2007-01-31 | Basfコーティングスジャパン株式会社 | 塗料組成物 |
JPH10279840A (ja) | 1997-04-03 | 1998-10-20 | Chugoku Marine Paints Ltd | 防汚塗料組成物、この防汚塗料組成物から形成されている塗膜および該防汚塗料組成物を用いた防汚方法並びに該塗膜で被覆された船体、水中・水上構造物または漁業資材 |
JP3733197B2 (ja) | 1997-04-03 | 2006-01-11 | 中国塗料株式会社 | 防汚塗料組成物、この防汚塗料組成物から形成されている塗膜および該防汚塗料組成物を用いた防汚方法並びに該塗膜で被覆された船体、水中・水上構造物または漁業資材 |
GB9727261D0 (en) | 1997-12-23 | 1998-02-25 | Courtaulds Coatings Holdings | Fouling inhibition |
JPH11335619A (ja) * | 1998-05-28 | 1999-12-07 | Dainippon Toryo Co Ltd | 防汚塗料組成物 |
JPH11343451A (ja) | 1998-05-29 | 1999-12-14 | Dainippon Toryo Co Ltd | 防汚塗料組成物 |
JP2000063737A (ja) | 1998-08-18 | 2000-02-29 | Dainippon Toryo Co Ltd | 防汚塗料組成物 |
JP2000248228A (ja) * | 1998-12-28 | 2000-09-12 | Chugoku Marine Paints Ltd | 防汚塗料組成物、この防汚塗料組成物から形成されている防汚塗膜および該防汚塗料組成物を用いた防汚方法並びに該塗膜で被覆された船体または水中構造物 |
JP5072137B2 (ja) * | 1998-12-28 | 2012-11-14 | 中国塗料株式会社 | シリル(メタ)アクリレート共重合体およびその製造方法 |
JP5281218B2 (ja) * | 1999-01-11 | 2013-09-04 | 中国塗料株式会社 | 防汚塗料組成物、この防汚塗料組成物から形成されている防汚塗膜および該防汚塗料組成物を用いた防汚方法並びに該塗膜で被覆された船体または水中構造物 |
JP2000292907A (ja) | 1999-04-02 | 2000-10-20 | Nikon Corp | 荷電粒子線露光装置及びレチクル |
JP4493771B2 (ja) * | 1999-05-13 | 2010-06-30 | 中国塗料株式会社 | 防汚塗料組成物、この防汚塗料組成物から形成されている防汚塗膜および該防汚塗料組成物を用いた防汚方法並びに該塗膜で被覆された船体または水中構造物 |
EP1208167B1 (fr) | 1999-06-11 | 2003-07-30 | J.C. Hempel's Skibsfarve-Fabrik A/S | Composition de peinture antisalissures marine autopolissante comprenant des copolymeres qui contiennent du silicium et des fibres |
JP2001081147A (ja) * | 1999-09-10 | 2001-03-27 | Chugoku Marine Paints Ltd | シリル(メタ)アクリレート共重合体、該共重合体を含有する防汚塗料組成物、この防汚塗料組成物から形成されている防汚塗膜および該防汚塗料組成物を用いた防汚方法並びに該塗膜で被覆された船体または海洋構造物 |
JP5189717B2 (ja) * | 1999-10-04 | 2013-04-24 | 中国塗料株式会社 | 防汚塗料組成物、この防汚塗料組成物から形成されている塗膜および該防汚塗料組成物を用いた防汚方法並びに該塗膜で被覆された船体または水中構造物 |
JP4393688B2 (ja) * | 2000-09-25 | 2010-01-06 | 中国塗料株式会社 | 防汚塗料組成物、該組成物からなる塗膜、該塗膜で被覆された基材、および防汚方法 |
SG97209A1 (en) * | 2000-10-25 | 2003-07-18 | Chugoku Marine Paints | Novel (poly) oxyalkylene block silyl ester copolymer, antifouling coating composition, antifouling coating formed from antifouling coating composition, antifouling method using antifouling coating composition and hull or underwater structure covered with antifouling coating |
EP1288234A1 (fr) | 2001-08-27 | 2003-03-05 | Sigma Coatings B.V. | Liants à faible teneur en monomères hydrolysables utilisables dans des peintures autopolissantes et antisalissures |
-
2002
- 2002-03-06 JP JP2002060696A patent/JP4361239B2/ja not_active Expired - Lifetime
-
2003
- 2003-02-28 US US10/375,005 patent/US6916860B2/en not_active Expired - Lifetime
- 2003-03-03 SG SG200302238A patent/SG99418A1/en unknown
- 2003-03-04 NO NO20031003A patent/NO339178B1/no not_active IP Right Cessation
- 2003-03-05 KR KR10-2003-0013790A patent/KR100521080B1/ko active IP Right Grant
- 2003-03-06 EP EP03251373.1A patent/EP1342756B2/fr not_active Expired - Lifetime
- 2003-03-06 CN CNB03120256XA patent/CN1219010C/zh not_active Expired - Lifetime
- 2003-03-06 EP EP06017540.3A patent/EP1724310B1/fr not_active Expired - Lifetime
- 2003-09-20 HK HK03106766.6A patent/HK1054563B/zh not_active IP Right Cessation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1016681A2 (fr) * | 1998-12-28 | 2000-07-05 | Chugoku Marine Paints, Ltd. | Copolymères (méth)acrylate de silyle, procédés pour les préparer, compositions de peintures antisalissures contenant ces copolymères, revêtements antisalissures formés à partir de ces compositions, méthodes antisalissures reposant sur ces compositions, et coques ou structures sous-marines revêtues de la pellicule obtenue |
Also Published As
Publication number | Publication date |
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KR20030074241A (ko) | 2003-09-19 |
KR100521080B1 (ko) | 2005-10-17 |
JP4361239B2 (ja) | 2009-11-11 |
EP1724310A1 (fr) | 2006-11-22 |
HK1054563A1 (en) | 2003-12-05 |
EP1724310B1 (fr) | 2018-10-31 |
CN1219010C (zh) | 2005-09-14 |
NO20031003D0 (no) | 2003-03-04 |
JP2003261816A (ja) | 2003-09-19 |
EP1342756B1 (fr) | 2006-11-15 |
NO20031003L (no) | 2003-09-08 |
US6916860B2 (en) | 2005-07-12 |
EP1342756A1 (fr) | 2003-09-10 |
HK1054563B (zh) | 2007-01-12 |
US20030207962A1 (en) | 2003-11-06 |
SG99418A1 (en) | 2003-10-27 |
CN1442461A (zh) | 2003-09-17 |
EP1342756B2 (fr) | 2015-06-24 |
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