KR960040446A - 고활성의 이중 금속 시안화 착물 촉매 - Google Patents

고활성의 이중 금속 시안화 착물 촉매 Download PDF

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KR960040446A
KR960040446A KR1019960015896A KR19960015896A KR960040446A KR 960040446 A KR960040446 A KR 960040446A KR 1019960015896 A KR1019960015896 A KR 1019960015896A KR 19960015896 A KR19960015896 A KR 19960015896A KR 960040446 A KR960040446 A KR 960040446A
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catalyst
ray diffraction
metal cyanide
diffraction pattern
powder
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레-칵 바이
티. 바우맨 폴
알. 힌네이 해리
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존 엠. 와그너
아르코 케미칼 테크놀로지, 엘. 피.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used

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  • Organic Chemistry (AREA)
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  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Polyethers (AREA)
  • Catalysts (AREA)
  • Epoxy Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

본 발명은 개선된 이중 금속 시안화 촉매에 관한 것이다. 본 발명의 거의 무정형 촉매는 에폭시드를 중합시키는 데에 있어서, 거의 결정질 성분을 지닌 종래의 DMC 촉매보다 높은 활성을 가진다. 상기 촉매로 제조된 폴리올 생성물들은 통상 투명하고, 매우 낮은 불포화도를 가지며, 저 분자량 폴리올 불순물이 거의 없다. 본 발명은 개선된 DMC 촉매를 제조하는 방법도 기술하고 있다. 그중 한 방법에서, 반응물들은 친밀하게 결합되어 본 발명의 촉매를 생성한다. 또 다른 방법에서, 유기 착화제는 반응물 용액에 초기에 존재한다.

Description

고활성의 이중 금속 시안화 착물 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 250ppm에서 본 발명의 촉매 조성물중 하나로 중합 반응을 수행하는 동안에 시간에 대한 프로필렌옥사이드의 소비량을 플롯한 그래프이다. 제2도 내지 제10도는 각종 이중 금속 시안화 결합물의 분말 X-선 회절 패턴이다.

Claims (21)

  1. 수용성 금속염, 수용성 금속 시안화염, 및 착화제의 반응 생성물인 이중 금속 시안화 촉매로서, 이 촉매는 마무리 가공처리된 폴리에테르의 중량을 기준으로 3g PO(프로필렌 옥사이드)/분100ppm(촉매) 이상의 속도로 105℃에서 프로필렌 옥사이드의 중합반응을 수행하는 것을 특징으로 하는 이중 금속 시안화 촉매.
  2. 수용성 금속염, 수용성 금속 시안화염, 및 착화제의 반응 생성물인 이중 중금속 시안화 촉매로서, 이 촉매는 마무리 가공처리된 폴리에테르의 중량을 기준으로 5g/PO/분/250ppm(촉매) 이상의 속도로 105℃에서 프로필렌 옥사이드의 중합반응을 수행하는 것을 특징으로 하는 이중 금속 시안화 촉매.
  3. 약 70중량% 이상의 거의 무정형 이중 금속 시안화(DMC) 착물을 포함하는 촉매로서, 이 촉매는 에폭시드를 중합반응시키는데 유용하며, 상기의 거의 무정형 DMC 착물은 약 5.1(d-면간격, 옹스트롬)에서 샤프한 선이 거의 없는 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 촉매.
  4. (a) 수용성 금속염의 수용액과 수용성 금속 시안화염의 수용액을 착화제의 존재하에서 결합 및 반응시켜 침전된 DMC 착물 촉매를 포함한 수성 혼합물을 제조하는 단계; 및 (b) 상기 DMC 착물 촉매를 분리 및 건조시키는 단계를 포함하는 이중 금속 시안화(DMC) 착물을 제조하는 방법으로서, 산출된 촉매는 약 5.1(d-면간격, 옹스트롬)에서 샤프한 선이 거의 없는 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 방법.
  5. 거의 무정형 헥사시아노코발트산 아연 착물을 주성분으로 하는 촉매로서, 상기 촉매는 에탄올, 이소프로필 알코올, 3차-부틸 알코올, 2차-부틸 알코올, n-부탈 알코올, 및 이소부틸 알코올로 구성된 군에서 선택된 착화제의 존재하에서 제조되고, 거의 무정형 헥사시아노코발트산 아연 착물은 약 5.1(d-면간격, 옹스트롬)에서 샤프한 선이 거의 없는 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 촉매.
  6. 약 5.1(d-면간격, 옹스트롬)에서 샤프한 선이 거의 없는 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 이중 금속 시안화(DMC) 착물 촉매.
  7. 칙화제로서 에탄올, 이소프로필 알코올, 3차-부틸 알코올, 2차-부틸 알코올, 및 이소부틸 알코올로 구성된 군에서 선택된 수용성 지방족 알코올을 갖는 헥사시아노코발트산 아연 착물 촉매로서, 이 촉매는 40kV 및 30mA로 동력이 공급되고, 각각 0.05° 및 1.15°의 단색광기 개구 및 검출기 개구와 함께 1°의 회절계 발산 슬릿을 이용하여 2초/스텝의 계수 시간으로 0.02° 2θ의 스텝 주사 방식으로 작동하는 세이먼스(Seimens) D500 크리스톨로플렉스 회절계를 사용하여 단색화된 CuKa1방사선(λ=1.54059Å)으로 X-선 회절 분석할 때, 약 5.1(d-면간격, 옹스트롬)에서 샤프한 선이 거의 없는 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 헥사시아노코발트산 아연 착물 촉매.
  8. 제7항에 있어서, 약 5.1 및 3.6(d-면간격, 옹스트롬)에서 샤프한 선이 거의 없는 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 촉매.
  9. 제7항에 있어서, 약 5.1, 3.6 및 2.5(d-면간격, 옹스트롬)에서 샤프한 선이 거의 없는 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 촉매.
  10. 제7항에 있어서, 약 5.1, 3.6, 2.5 및 2.3(d-면간격, 옹스트롬)에서 샤프한 선이 거의 없는 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 촉매.
  11. 제5도에 나타낸 바와 같이 단색화된 CuKa1방사선(λ=1.54059Å)을 사용한 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 이중 금속 시안화 착물 촉매.
  12. 약 5중량% 이하의 거의 결정질 DMC 화합물을 포함하고, 제8도에 나타낸 바와 같이 단색화된 CuKa1방사선(λ=1.54059Å)을 사용한 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 이중 금속 시안화 착물 촉매.
  13. 약 30중량% 이하의 거의 결정질 DMC 화합물을 포함하고, 제9도에 나타낸 바와 같이 단색화된 CuKa1방사선(λ=1.54059Å)을 사용한 분말 X-선 회절 패턴을 나타내는 것을 특징으로 하는 이중 금속 시안화 착물 촉매.
  14. 제11항 내지 제13항 중 어느 한 항에 있어서, 이중 금속 시안화물은 헥사시아노코발트산 아연인 것을 특징으로 하는 촉매.
  15. 노르말 히드록실 작용가가 3 이상이고, 거의 대부분이 2차 히드록실기이며, 약 0.007meq/g 미만의 불포화도를 갖는 것을 특징으로 하는 폴리에테르 폴리올.
  16. 제15항에 있어서, 폴리올은 폴리옥시프로필렌 폴리올 또는 에틸렌 옥사이드-프로필렌 옥사이드 공중합체인 것을 특징으로 하는 폴리에테르 폴리올.
  17. 제15항에 있어서, 약 0.005meq/g 미만의 불포화도를 갖는 것을 특징으로 하는 폴리에테르 폴리올.
  18. 제15항에 있어서, 약 0.004meq/g 미만의 불포화도를 갖는 것을 특징으로 하는 폴리에테르 폴리올.
  19. 3차 알코올 착화제의 존재하에서 금속염의 수용액과 금속 시안화염의 수용액을 반응시키는 것을 포함하는 이중 금속 시안화(DMC) 착물 촉매의 제조 방법으로서, 상기 반응물 용액중 하나 또는 둘다에 착화제를 포함하고, 금속 시안화염 용액을 금속염 용액에 첨가하는 것을 특징으로 하는 방법.
  20. 제19항에 있어서, DMC 착물 촉매는 헥사시아노코발트산 아연인 것을 특징으로 하는 방법.
  21. 제19항에 있어서, 3차 알코올 착화제는 3차-부틸 알코올인 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960015896A 1995-05-15 1996-05-14 고활성의이중금속시안화물착체촉매 KR100429297B1 (ko)

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US08/435,116 1995-05-15
US08/435,116 US5712216A (en) 1995-05-15 1995-05-15 Highly active double metal cyanide complex catalysts

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AR (1) AR001946A1 (ko)
AT (1) ATE210500T1 (ko)
BR (1) BR9602262A (ko)
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Families Citing this family (247)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5677413A (en) * 1995-06-15 1997-10-14 Arco Chemical Technology, L.P. Polyurethane elastomers exhibiting improved demold green strength and water absorption and haze-free polyols suitable for their preparation
DE19730467A1 (de) * 1997-07-16 1999-01-21 Bayer Ag Neue Zink/Metall-Hexacyanocobaltat-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19742978A1 (de) 1997-09-29 1999-04-01 Basf Ag Multimetallcyanidkomplexe als Katalysatoren
DE19834573A1 (de) 1998-07-31 2000-02-03 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19842382A1 (de) 1998-09-16 2000-03-23 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
EP1034035B1 (de) 1997-10-13 2003-06-04 Bayer Ag Kristalline doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen
US6624286B2 (en) 1997-10-13 2003-09-23 Bayer Aktiengesellschaft Double-metal cyanide catalysts containing polyester for preparing polyether polyols
AR019107A1 (es) 1998-04-27 2001-12-26 Dow Global Technologies Inc Polioles de alto peso molecular, proceso para su preparacion y uso de los mismos.
CN1080590C (zh) * 1998-04-29 2002-03-13 中国科学院山西煤炭化学研究所 一种双金属氰化物催化剂及其制备方法
CN1080589C (zh) * 1998-04-29 2002-03-13 中国科学院山西煤炭化学研究所 双金属氰化物催化剂及其制备方法
US6063897A (en) * 1998-05-05 2000-05-16 Arco Chemical Technology, L.P. Acid-treated double metal cyanide complex catalysts
US6028230A (en) * 1998-06-05 2000-02-22 Arco Chemical Technology, L.P. Epoxide polymerization process
US6051680A (en) * 1998-06-08 2000-04-18 Arco Chemical Technology, L.P. Silylated double metal cyanide complex catalysts
EP1022300B1 (en) * 1998-07-10 2004-09-29 Asahi Glass Company Ltd. Catalyst for ring-opening polymerization of alkylene oxide, method for preparation thereof and use thereof
DE19834572A1 (de) 1998-07-31 2000-02-03 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19842383A1 (de) 1998-09-16 2000-03-23 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6051622A (en) * 1998-09-17 2000-04-18 Arco Chemical Technology, L.P. Low resilience, low frequency molded polyurethane foam
DE19903274A1 (de) 1999-01-28 2000-08-03 Basf Ag Verfahren zur Herstellung von Polyetherpolyolen
DE19913260C2 (de) 1999-03-24 2001-07-05 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19905611A1 (de) 1999-02-11 2000-08-17 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19906985A1 (de) 1999-02-19 2000-08-31 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6613714B2 (en) 1999-06-02 2003-09-02 Basf Aktiengesellschaft Multimetal cyanide compounds, their preparation and their use
US6800583B2 (en) 1999-06-02 2004-10-05 Basf Aktiengesellschaft Suspension of multimetal cyanide compounds, their preparation and their use
WO2001003830A1 (en) * 1999-07-09 2001-01-18 The Dow Chemical Company Metal catalysts complexed with sulfone or sulfoxide compounds
US6358877B1 (en) 1999-09-10 2002-03-19 The Dow Chemical Company Metal catalysts complexed with sulfone or sulfoxide compounds
DE19953546A1 (de) 1999-11-08 2001-05-10 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE19958355A1 (de) 1999-12-03 2001-06-07 Bayer Ag Verfahren zur Herstellung von DMC-Katalysatoren
US6359101B1 (en) 1999-12-15 2002-03-19 Synuthane International, Inc. Preparing polyether polyols with DMC catalysts
RU2002126260A (ru) * 2000-02-29 2004-01-10 БАСФ Акциенгезельшафт (DE) Способ получения соединений на основе цианидов металлов
WO2001083107A2 (en) 2000-04-28 2001-11-08 Synuthane International, Inc. Double metal cyanide catalysts containing polyglycol ether complexing agents
DE10108485A1 (de) 2001-02-22 2002-09-05 Bayer Ag Verbessertes Verfahren zur Herstellung von Polyetherpolyolen
DE10108484A1 (de) 2001-02-22 2002-09-05 Bayer Ag Verbessertes Verfahren zur Herstelung von Polyetherpolyolen
US6833431B2 (en) * 2001-05-02 2004-12-21 Bayer Aktiengesellschaft Double-metal cyanide catalysts for preparing polyether polyols
DE10122019A1 (de) * 2001-05-07 2002-11-14 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6596842B2 (en) 2001-07-16 2003-07-22 Shell Oil Company Polymerizing alkylene oxide with sound or radiation treated DMC
DE10138216A1 (de) 2001-08-03 2003-02-20 Bayer Ag Aliphatische Polycarbonathomo- und -copolymere durch DMC-Katalyse
EP1288244A1 (en) 2001-08-31 2003-03-05 Asahi Glass Company, Limited Double metal cyanide complex catalyst for ring opening polymerization of alkylene oxide and its production process
DE10142746A1 (de) 2001-08-31 2003-03-20 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE10142747A1 (de) 2001-08-31 2003-03-20 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE10156117A1 (de) * 2001-11-15 2003-05-28 Basf Ag Verfahren zur Herstellung von Polyetheralkoholen
EP1490169A1 (en) 2002-03-21 2004-12-29 Dow Global Technologies Inc. Method for preparing metal cyanide catalyst complexes using partially miscible complexing agents
DE10235130A1 (de) * 2002-08-01 2004-02-19 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US6696383B1 (en) 2002-09-20 2004-02-24 Bayer Polymers Llc Double-metal cyanide catalysts which can be used to prepare polyols and the processes related thereto
CA2518201A1 (en) * 2003-03-07 2004-09-23 Dow Global Technologies Inc. Continuous process and system of producing polyether polyols
DE10317790A1 (de) * 2003-04-16 2004-11-04 Tesa Ag Doppelseitiges Klebeband, insbesondere auch für das wiederablösbare Verkleben von flexiblen CDs auf gekrümmten Oberflächen
DE10317791A1 (de) 2003-04-16 2004-12-02 Tesa Ag Haftklebstoff aus Polyurethan für empfindliche Oberflächen
DE10317788A1 (de) * 2003-04-16 2004-12-02 Tesa Ag Wiederverwendbare, rückstands- und beschädigungsfrei wiederablösbare, elastische Klebefolie
DE10317789A1 (de) 2003-04-16 2004-12-02 Tesa Ag Haftklebstoff aus Polyurethan
US6884826B2 (en) * 2003-06-09 2005-04-26 Bayer Antwerp, N.V. Process for preparing double metal cyanide catalyzed polyols
ES2297110T3 (es) * 2003-06-30 2008-05-01 Repsol Quimica S.A. Procedimiento de purificacion de polioleteres.
DE10330971B4 (de) * 2003-07-08 2007-03-29 Beiersdorf Ag Verfahren zur Herstellung von Haut- oder Wundauflagen mit verkapselten, wundheilungsfördernden und/oder hautpflegenden Substanzen
US6855658B1 (en) * 2003-08-26 2005-02-15 Bayer Antwerp, N.V. Hydroxide containing double metal cyanide (DMC) catalysts
US20050101477A1 (en) * 2003-11-07 2005-05-12 George Combs Unsaturated tertiary alcohols as ligands for active dmc catalysts
US8470927B2 (en) 2004-02-26 2013-06-25 Bayer Materialscience Llc Process for production of polymer polyols
US7470646B2 (en) * 2004-03-09 2008-12-30 Japan Science And Technology Agency Polymer incarcerated Lewis acid metal catalyst
CN101048437B (zh) * 2004-10-25 2011-05-25 陶氏环球技术公司 由源于脂肪酸的含羟甲基的聚酯多元醇制成的预聚物
ES2405277T3 (es) * 2004-10-25 2013-05-30 Dow Global Technologies Inc. Respaldos de alfombras de poliuretano realizados con polioles de poliéster hidroximetilados
ATE482246T1 (de) * 2004-10-25 2010-10-15 Dow Global Technologies Inc Polymerpolyole und polymerdispersionen aus hydroxylhaltigen materialien auf pflanzenölbasis
MX2007004931A (es) * 2004-10-25 2007-06-12 Dow Global Technologies Inc Dispersiones acuosas de poliuretano preparadas a partir de poliester polioles que contienen hidroximetilo derivados de acidos grasos.
AU2005299519B2 (en) * 2004-10-25 2012-02-02 Dow Global Technologies Llc Polyurethanes made from hydroxy-methyl containing fatty acids or alkyl esters of such fatty acids
US7323605B2 (en) * 2005-11-09 2008-01-29 Bayer Materialscience Llc Double metal cyanide-catalyzed, low unsaturation polyethers from boron-containing starters
US7495063B2 (en) * 2006-02-03 2009-02-24 Dow Global Technologies Inc. Reduced oligomer concentration in high purity polyalkylene glycols
DE102006020482A1 (de) * 2006-04-28 2007-10-31 Tesa Ag Wieder ablösbarer Haftklebstoff aus Polyurethan
DE102006024025A1 (de) * 2006-05-23 2007-11-29 Bayer Materialscience Ag Verfahren zur Herstellung von Polyetherpolyolen
US7977501B2 (en) 2006-07-24 2011-07-12 Bayer Materialscience Llc Polyether carbonate polyols made via double metal cyanide (DMC) catalysis
JP5251510B2 (ja) * 2006-08-31 2013-07-31 旭硝子株式会社 ポリエーテル類の精製方法
DE102007002555A1 (de) 2007-01-17 2008-07-24 Bayer Materialscience Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE102007038436A1 (de) * 2007-08-16 2009-02-19 Bayer Materialscience Ag Verfahren zur Herstellung von Polyolen
DE102008011683A1 (de) 2008-02-28 2009-09-03 Bayer Materialscience Ag Verfahren zur Herstellung von Polyolen
DE102008023252A1 (de) 2008-05-13 2009-11-19 Tesa Se Hotmelt-Verfahren zur Herstellung eines chemisch vernetzten Polyurethanfilms
DE102008028555A1 (de) 2008-06-16 2009-12-17 Bayer Materialscience Ag Verfahren zur Herstellung von Polyolen
IL200997A0 (en) 2008-10-01 2010-06-30 Bayer Materialscience Ag Special polyether-based polyurethane formulations for the production of holographic media
IL200995A0 (en) 2008-10-01 2010-06-30 Bayer Materialscience Ag Polyether-based polyurethane formulations for the production of holographic media
DE102008051882A1 (de) 2008-10-16 2010-04-29 Bayer Materialscience Ag Verfahren zur Herstellung von Polyetheresterpolyolen
DE102009009757A1 (de) 2009-02-20 2010-08-26 Tesa Se Haftklebemasse
US20100324340A1 (en) 2009-06-23 2010-12-23 Bayer Materialscience Llc Short chain polyether polyols prepared from ultra-low water-content starters via dmc catalysis
DE102009031584A1 (de) 2009-07-03 2011-01-05 Bayer Materialscience Ag Verfahren zur Herstellung von Polyetherpolyolen mit primären Hydroxyl-Endgruppen
DE102009042190A1 (de) 2009-09-18 2011-03-24 Bayer Materialscience Ag Silangruppenhaltige Reaktivverdünner
DE102009042201A1 (de) 2009-09-18 2011-04-14 Bayer Materialscience Ag Silangruppenhaltige Polyether
DE102009043616A1 (de) 2009-09-29 2011-03-31 Bayer Materialscience Ag Verfahren zur Herstellung von aminogruppenhaltigen Polyolen
JP2013508482A (ja) 2009-10-21 2013-03-07 バイエル・マテリアルサイエンス・アクチェンゲゼルシャフト 生分解性ヒドロゲル
KR101727769B1 (ko) 2009-11-03 2017-04-17 코베스트로 도이칠란드 아게 홀로그래피 필름의 제조 방법
JP5638085B2 (ja) 2009-11-03 2014-12-10 バイエル・マテリアルサイエンス・アクチェンゲゼルシャフトＢａｙｅｒ ＭａｔｅｒｉａｌＳｃｉｅｎｃｅ ＡＧ 異なった書込コモノマーを含有する感光性ポリマー組成物
PL2317511T3 (pl) 2009-11-03 2012-08-31 Bayer Materialscience Ag Formulacje fotopolimerowe z nastawialnym mechanicznym modułem Guv
DE102009046657A1 (de) * 2009-11-12 2011-05-19 Tesa Se Haftklebstoff auf Basis von Polyurethan
CN102656209A (zh) 2009-12-09 2012-09-05 陶氏环球技术有限责任公司 仲羟基脂肪酸及其衍生物的聚醚衍生物
US9074044B2 (en) * 2009-12-14 2015-07-07 Dow Global Technologies Llc Method for continuously producing low equivalent weight polyols using double metal cyanide catalysts
CN102933637B (zh) 2010-01-20 2015-07-01 拜耳知识产权有限责任公司 活化用于制备聚醚碳酸酯多元醇的双金属氰化物催化剂的方法
DE102010008410A1 (de) 2010-02-18 2011-08-18 Bayer MaterialScience AG, 51373 Verfahren zur Herstellung von Polyethercarbonatpolyolen
EP2365019A1 (de) 2010-03-13 2011-09-14 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
US20110230581A1 (en) 2010-03-17 2011-09-22 Bayer Materialscience Llc Process for the production of polyether polyols with a high ethylene oxide content
KR20130039719A (ko) 2010-03-24 2013-04-22 바이엘 인텔렉쳐 프로퍼티 게엠베하 폴리에테르 카르보네이트 폴리올의 제조 방법
EP2372454A1 (de) 2010-03-29 2011-10-05 Bayer MaterialScience AG Photopolymer-Formulierung zur Herstellung sichtbarer Hologramme
EP2563839B1 (de) 2010-04-30 2014-12-17 Basf Se Polyetherpolyole, verfahren zur herstellung von polyetherpolyolen, sowie deren verwendung zur herstellung von polyurethanen
US9115246B2 (en) 2010-04-30 2015-08-25 Basf Se Polyether polyols, process for preparing polyether polyols and their use for producing polyurethanes
DE102010019504A1 (de) 2010-05-06 2011-11-10 Bayer Materialscience Ag Polyisocyanatprepolymere und deren Verwendung
US8946466B2 (en) 2010-05-18 2015-02-03 Bayer Intellectual Property Gmbh Method for producing polyether carbonate polyols
SG186833A1 (en) 2010-07-05 2013-02-28 Bayer Ip Gmbh Method for producing polyol mixtures
DE102010039090A1 (de) 2010-08-09 2012-02-09 Basf Se Verfahren zur Herstellung von Polyetheralkoholen
BR112013003891A2 (pt) 2010-08-20 2016-07-12 Basf Se processo par a síntese de polieterester polióis
EP2441788A1 (de) 2010-10-14 2012-04-18 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
DE102010043409A1 (de) 2010-11-04 2012-05-10 Bayer Materialscience Aktiengesellschaft Verfahren zur Herstellung von Polycarbonatpolyolen durch immortale Polymerisation von cyclischen Carbonaten
WO2012062683A1 (de) 2010-11-09 2012-05-18 Basf Se Polyetherester-polyole
EP2465890A1 (de) 2010-12-17 2012-06-20 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen mit primären Hydroxyl-Endgruppen und daraus hergestellte Polyurethanpolymere
WO2012084762A1 (de) 2010-12-20 2012-06-28 Bayer Materialscience Ag Verfahren zur herstellung von polyetherpolyolen
US20140329985A1 (en) 2010-12-20 2014-11-06 Klaus Lorenz Method for producing polyether ester polyols
SG192049A1 (en) * 2011-02-24 2013-08-30 Shell Int Research Process and reactor system for the preparation of polyether polyols
RU2013147684A (ru) 2011-03-28 2015-05-10 Байер Интеллектуэль Проперти Гмбх Способ получения мягких пенополиуретанов
SA116370919B1 (ar) 2011-05-17 2017-05-08 ريبسول، اس. ايه. عملية لتحضير مُحفِّز من مُعقَّد سيانيدي مزدوج المعدن
EP2530101A1 (de) 2011-06-01 2012-12-05 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
US9139691B2 (en) 2011-06-30 2015-09-22 Bayer Intellectual Property Gmbh Process for preparing high molecular weight polyether polyols
EP2548905A1 (de) 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Aktivierung von Doppelmetallcyanidkatalysatoren zur Herstellung von Polyetherpolyolen
EP2548908A1 (de) 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
EP2548906A1 (de) 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Aktivierung von Doppelmetallcyanidkatalysatoren zur Herstellung von Polyetherpolyolen
EP2548907A1 (de) 2011-07-18 2013-01-23 Bayer MaterialScience AG Verfahren zur Herstellung von Polyetherpolyolen
CA2843048A1 (en) 2011-07-26 2013-01-31 Bayer Intellectual Property Gmbh Etherified lactate esters, method for the production thereof and use thereof for enhancing the effect of plant protecting agents
EP2604641A1 (de) 2011-12-16 2013-06-19 Bayer Intellectual Property GmbH Verfahren zur Herstellung von Polyetherestercarbonatpolyolen
EP2604642A1 (de) 2011-12-16 2013-06-19 Bayer Intellectual Property GmbH Verfahren zur Herstellung von Polyethercarbonatpolyolen
CN104144999B (zh) 2011-12-20 2016-08-17 医用粘合剂革新有限责任公司 羟基氨基聚合物及其在聚脲聚氨酯组织粘合剂中的用途
CN104039859B (zh) 2011-12-20 2017-03-01 科思创德国股份有限公司 羟基氨基聚合物及其制备方法
JP6097764B2 (ja) 2011-12-20 2017-03-15 アドヒーシス・メディカル・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＡｄｈｅｓｙｓ Ｍｅｄｉｃａｌ ＧｍｂＨ 生分解性組織接着剤用のイソシアネート官能性プレポリマー
EP2671893A1 (de) 2012-06-06 2013-12-11 Bayer MaterialScience AG Verfahren zur Herstellung von Omega-Hydroxy-Aminopolymeren
EP2703425A1 (de) 2012-08-27 2014-03-05 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
EP2703426A1 (de) 2012-08-27 2014-03-05 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
DE102012218846A1 (de) 2012-10-16 2014-04-17 Bayer Materialscience Ag Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen
DE102012218848A1 (de) 2012-10-16 2014-04-17 Bayer Materialscience Ag Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen
EP2725044B1 (de) 2012-10-24 2017-06-21 Covestro Deutschland AG Alkoxysilanterminiertes Präpolymer auf Basis von Polyethercarbonatpolyolen für Sprühschäume
EP2730602A1 (de) 2012-11-09 2014-05-14 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
CN104769008B (zh) 2012-11-09 2018-03-23 科思创德国股份有限公司 制备聚醚碳酸酯多元醇的方法
US9964583B2 (en) 2013-02-22 2018-05-08 Smartkable Llc Method and apparatus for predicting life cycle of a splice
US9957354B2 (en) 2013-09-05 2018-05-01 Covestro Deutschland Ag Higher functional polyether carbonate polyols obtained using branching molecules
EP2845871A1 (de) 2013-09-05 2015-03-11 Bayer MaterialScience AG Vernetzung von Doppelbindungen enthaltenden Polyethercarbonatpolyolen durch Addition von Mercaptanen
EP2845872A1 (de) 2013-09-05 2015-03-11 Bayer MaterialScience AG Niederviskose Polyethercarbonatpolyole mit Seitenketten
EP2845873A1 (de) 2013-09-05 2015-03-11 Bayer MaterialScience AG Radikalische Vernetzung von Polyethercarbonatpolyolen enthaltend elektronenarme und elektronenreiche Doppelbindungen
EP2851384A1 (de) 2013-09-20 2015-03-25 Bayer MaterialScience AG Verzweigte Polyethercarbonatpolyole und Verfahren zu deren Herstellung
EP2865700A1 (de) 2013-10-23 2015-04-29 Bayer MaterialScience AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
EP3063256A1 (en) 2013-10-29 2016-09-07 Dow Brasil Sudeste Industiral Ltda. A lubricant composition and a method to lubricate a mechanical device
EP2876121A1 (de) 2013-11-22 2015-05-27 Bayer MaterialScience AG Einsatz von Urethan-Alkoholen zur Herstellung von Polyetherpolyolen
JP2016539231A (ja) 2013-11-27 2016-12-15 コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ ポリウレタンソフト発泡体を製造するためのポリエーテルカーボネートポリオールとポリエーテルポリオールとの混合物
EP2886572A1 (de) 2013-12-17 2015-06-24 Bayer MaterialScience AG Einsatz von Urethan-Alkoholen zur Herstellung von Polyethercarbonatpolyolen
CN105814113B (zh) 2013-12-18 2018-11-23 科思创德国股份有限公司 后处理碱性聚醚多元醇的方法
EP2894180A1 (en) 2014-01-08 2015-07-15 Bayer MaterialScience AG Polymer Polyols comprising a Polyether Carbonate Polyol as the Base Polyol
EP2910585B1 (de) 2014-02-21 2018-07-04 Covestro Deutschland AG Schotterkörper sowie Verfahren zur Herstellung von Schotterkörpern
CN106414532B (zh) 2014-04-07 2019-11-01 科思创德国股份有限公司 制造聚甲醛嵌段共聚物的方法
EP3134449A1 (de) 2014-04-24 2017-03-01 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
CN107075105B (zh) 2014-09-23 2019-09-13 科思创德国股份有限公司 含烷氧基甲硅烷基的湿固化聚醚碳酸酯
EP3023447A1 (de) 2014-11-18 2016-05-25 Covestro Deutschland AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
EP3050907A1 (de) 2015-01-28 2016-08-03 Covestro Deutschland AG Verfahren zur Herstellung von Polyethercarbonatpolyolen
US20160244549A1 (en) 2015-02-25 2016-08-25 Bayer Materialscience Llc Alkoxysilane-group modified polyurethanes and low modulus sealants formed therefrom
CN107428905A (zh) 2015-02-27 2017-12-01 科思创德国股份有限公司 聚醚碳酸酯多元醇用于制造颜色稳定的聚氨酯泡沫材料的用途
EP3067376A1 (de) 2015-03-11 2016-09-14 Evonik Degussa GmbH Herstellung von Polyurethansystemen unter Einsatz von Polyetherpolycarbonatpolyolen
EP3098250A1 (de) 2015-05-26 2016-11-30 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3098251A1 (de) 2015-05-26 2016-11-30 Covestro Deutschland AG Einsatz von alkoholen, die mindestens zwei urethangruppen enthalten, zur herstellung von polyetherpolyolen
EP3098252A1 (de) 2015-05-26 2016-11-30 Covestro Deutschland AG Einsatz von alkoholen, die mindestens zwei urethangruppen enthalten, zur herstellung von polyethercarbonatpolyolen
CN107922607B (zh) 2015-08-26 2020-05-19 科思创德国股份有限公司 制备高分子量聚氧化烯多元醇的方法
JP2018536065A (ja) 2015-11-19 2018-12-06 コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ ポリエーテルカーボネートポリオール系ポリウレタンフォーム
WO2017097729A1 (de) 2015-12-09 2017-06-15 Covestro Deutschland Ag Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP3178858A1 (de) 2015-12-09 2017-06-14 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP3219741A1 (de) 2016-03-18 2017-09-20 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
CN109071795B (zh) 2016-05-13 2021-08-31 科思创德国股份有限公司 制备聚氧化烯多元醇的方法
EP3260483A1 (de) 2016-06-22 2017-12-27 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
US10119223B2 (en) 2016-07-15 2018-11-06 Covestro Llc Carpet and synthetic turf backings prepared from a polyether carbonate polyol
US10258953B2 (en) 2016-08-05 2019-04-16 Covestro Llc Systems and processes for producing polyether polyols
US11312812B2 (en) 2016-10-12 2022-04-26 Covestro Deutschland Ag Process for producing elastomers
CN109790275B (zh) 2016-10-12 2022-03-15 科思创德国股份有限公司 制备含多重键的预聚物作为弹性体前体的方法
EP3330308A1 (de) 2016-12-05 2018-06-06 Covestro Deutschland AG Verfahren zur herstellung von tdi-basierten polyurethanweichschaumstoffen enthaltend organische säureanhydride und/oder organische säurechloride
EP3330307A1 (de) 2016-12-05 2018-06-06 Covestro Deutschland AG Verwendung von acrylsäureestern und amiden zur erniedrigung von emissionen eines polyurethanschaumstoffes
EP3336115A1 (de) 2016-12-19 2018-06-20 Covestro Deutschland AG Verfahren zur erniedrigung von emissionen eines polyurethanschaumstoffes
EP3336137A1 (de) 2016-12-19 2018-06-20 Covestro Deutschland AG Verwendung von physikalischen treibmitteln zur erzeugung von polyethercarbonatpolyol-basierten polyurethanschaumstoffen mit reduzierter emission von cyclischem propylencarbonat
EP3336130A1 (de) 2016-12-19 2018-06-20 Covestro Deutschland AG Verfahren zur herstellung von polyetherthiocarbonatpolyolen
EP3385295A1 (de) 2017-04-05 2018-10-10 Covestro Deutschland AG Flammgeschützte phosphorfunktionelle polyethercarbonatpolyole und verfahren zu deren herstellung
EP3409704A1 (de) 2017-06-01 2018-12-05 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
EP3424967A1 (de) 2017-07-07 2019-01-09 Covestro Deutschland AG Verfahren zur herstellung von funktionalisierten polyoxyalkylenpolyolen
EP3461852A1 (de) 2017-09-28 2019-04-03 Covestro Deutschland AG Verfahren zur herstellung eines mehrfachbindungen enthaltenden polymers als elastomer-vorstufe
EP3473658A1 (de) 2017-10-18 2019-04-24 Covestro Deutschland AG Diblockcopolymere und deren verwendung als tenside
CN111201264A (zh) 2017-10-18 2020-05-26 科思创德国股份有限公司 二嵌段共聚物及其作为表面活性剂的用途
US20190119444A1 (en) 2017-10-25 2019-04-25 Covestro Llc Process to remove dmc catalysts from polyether carbonate polyols
EP3489278A1 (de) 2017-11-23 2019-05-29 Covestro Deutschland AG Hochmolekulare polyoxyalkylene mit tiefer glastemperatur hergestellt nach der grafting-through-methode
EP3502162A1 (de) 2017-12-19 2019-06-26 Covestro Deutschland AG Verfahren zur herstellung von polyetheresterpolyolen
EP3527606A1 (de) 2018-02-16 2019-08-21 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3533815A1 (de) 2018-02-28 2019-09-04 Covestro Deutschland AG Polyurethanweichschaumstoffe auf basis von polyoxymethylen-polyoxyalkylen-blockcopolymeren
EP3536727A1 (de) 2018-03-07 2019-09-11 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
CN111936542A (zh) 2018-03-07 2020-11-13 科思创知识产权两合公司 基于聚醚碳酸酯多元醇的聚氨酯泡沫材料
WO2019180156A1 (de) 2018-03-22 2019-09-26 Covestro Deutschland Ag Verfahren zur herstellung von polyurethanweichschaumstoffen mit hoher rohdichte
EP3543268A1 (de) 2018-03-22 2019-09-25 Covestro Deutschland AG Verfahren zur herstellung von polyurethanweichschaumstoffen
EP3549969A1 (de) 2018-04-06 2019-10-09 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
WO2019209348A1 (en) 2018-04-28 2019-10-31 Liang Wang Polyurethane elastomer with high ultimate elongation
EP3567067A1 (de) 2018-05-08 2019-11-13 Covestro Deutschland AG Abtrennung von doppelmetallcyanid-katalysator
EP3587469A1 (de) 2018-06-22 2020-01-01 Covestro Deutschland AG Verfahren zur herstellung von polyol
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EP3670557A1 (de) 2018-12-21 2020-06-24 Covestro Deutschland AG Verfahren zur herstellung eines polyoxyalkylenpolyesterpolyols
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EP3683251A1 (de) 2019-01-15 2020-07-22 Covestro Deutschland AG Verfahren zur herstellung von diol
WO2020173568A1 (de) 2019-02-28 2020-09-03 Covestro Intellectual Property Gmbh & Co. Kg Isocyanat-terminierte prepolymere für die herstellung von polyurethan-integral-schaumstoffen
EP3741788A1 (de) 2019-05-24 2020-11-25 Covestro Deutschland AG Verfahren zur herstellung von polyoxyalkylenpolyol-mischungen
EP3747927A1 (de) 2019-06-05 2020-12-09 Covestro Deutschland AG Verfahren zur kontinuierlichen herstellung von polyoxyalkylenpolyolen
EP3983473A1 (de) 2019-06-11 2022-04-20 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3750940A1 (de) 2019-06-11 2020-12-16 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
EP3760663A1 (de) 2019-07-05 2021-01-06 Covestro Deutschland AG Verfahren zur herstellung von polyetherestercarbonatpolyolen
EP3763768A1 (de) 2019-07-12 2021-01-13 Covestro Deutschland AG Polyethercarbonatpolyole mit enger segmentlängenverteilung
EP3771724A1 (de) 2019-07-31 2021-02-03 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
US20220315698A1 (en) 2019-07-31 2022-10-06 Covestro Deutschland Ag Method for producing polyether carbonate polyols
KR102124603B1 (ko) 2019-10-31 2020-06-18 한국화학연구원 폴리에테르 폴리올의 제조방법
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EP3831867A1 (de) 2019-12-04 2021-06-09 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
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WO2021165283A2 (de) 2020-02-22 2021-08-26 Covestro Deutschland Ag Verfahren zur herstellung von doppelmetallcyanid-katalysatoren
EP3878885A1 (de) 2020-03-10 2021-09-15 Covestro Deutschland AG Verfahren zur herstellung von polyethercarbonatpolyolen
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WO2023057328A1 (de) 2021-10-07 2023-04-13 Covestro Deutschland Ag Verfahren zur herstellung von polyoxyalkylenpolyesterpolyolen
US11952454B2 (en) 2021-10-18 2024-04-09 Covestro Llc Processes and production plants for producing polymer polyols
US20230147479A1 (en) 2021-11-05 2023-05-11 Covestro Llc Processes and production plants for producing polyols
EP4194476A1 (de) 2021-12-07 2023-06-14 Covestro Deutschland AG Polyurethanschaumstoffe basierend auf polyethercarbonatpolyolen
WO2023104708A1 (en) 2021-12-08 2023-06-15 Covestro Deutschland Ag Polyurethane elastomer with improved hydrolysis resistance
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EP4219579A1 (de) 2022-01-28 2023-08-02 Covestro Deutschland AG Herstellung von aliphatischen polyurethan-weichschaumstoffe in einem präpolymerverfahren basierend auf aliphatischen oligomeren polyisocyanaten und monohydroxyfunktionellen verbindungen
WO2023144058A1 (de) 2022-01-28 2023-08-03 Covestro Deutschland Ag Herstellung von aliphatischen polyurethan-weichschaumstoffen mit verkürzten abbindezeiten (klebfreizeiten) und steigzeiten
EP4219576A1 (de) 2022-01-28 2023-08-02 Covestro Deutschland AG Herstellung von aliphatischen polyurethan-polyisocyanuratschaumstoffen (pur-pir) unter verwendung eines katalysatorgemischs aus salzen organischer carbonsäuren und 1,1,3,3-tetraalkylguanidinen
EP4273185A1 (en) 2022-05-04 2023-11-08 PCC Rokita SA Method for the manufacture of a polyether diol product
EP4279534A1 (en) 2022-05-20 2023-11-22 PCC ROKITA Spolka Akcyjna A method for producing low unsaturation level oxyalkylates, an oxyalkylate, a use thereof and a polyurethane foam
EP4302874A1 (de) 2022-07-04 2024-01-10 Covestro Deutschland AG Verfahren zur herstellung von doppelmetallcyanid-katalysatoren

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3427335A (en) * 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an acyclic aliphatic saturated monoether,an ester and a cyclic ether and methods for making the same
US3278459A (en) * 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
US3278457A (en) * 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
US3427256A (en) * 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanide complex compounds
US3427334A (en) * 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity
US3278458A (en) * 1963-02-14 1966-10-11 Gen Tire & Rubber Co Method of making a polyether using a double metal cyanide complex compound
GB1063525A (en) * 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
GB1225803A (ko) * 1967-06-02 1971-03-24
US3900518A (en) * 1967-10-20 1975-08-19 Gen Tire & Rubber Co Hydroxyl or thiol terminated telomeric ethers
US3829505A (en) * 1970-02-24 1974-08-13 Gen Tire & Rubber Co Polyethers and method for making the same
US3941849A (en) * 1972-07-07 1976-03-02 The General Tire & Rubber Company Polyethers and method for making the same
CA1155871A (en) * 1980-10-16 1983-10-25 Gencorp Inc. Method for treating polypropylene ether and poly-1,2- butylene ether polyols
AU551979B2 (en) * 1982-03-31 1986-05-15 Shell Internationale Research Maatschappij B.V. Epoxy polymerisation catalysts
AU552988B2 (en) * 1982-03-31 1986-06-26 Shell Internationale Research Maatschappij B.V. Polymerizing epoxides and catalyst suspensions for this
US4843054A (en) * 1987-02-26 1989-06-27 Arco Chemical Technology, Inc. Preparation of filterable double metal cyanide complex catalyst for propylene oxide polymerization
US4721818A (en) * 1987-03-20 1988-01-26 Atlantic Richfield Company Purification of polyols prepared using double metal cyanide complex catalysts
US5300535A (en) * 1988-10-25 1994-04-05 Asahi Glass Company Ltd. Method for producing polyurethane flexible foam
US4877906A (en) * 1988-11-25 1989-10-31 Arco Chemical Technology, Inc. Purification of polyols prepared using double metal cyanide complex catalysts
US5068304A (en) * 1988-12-09 1991-11-26 Asahi Glass Company, Ltd. Moisture-curable resin composition
US4987271A (en) * 1989-02-17 1991-01-22 Asahi Glass Company, Ltd. Method for purifying a polyoxyalkylene alcohol
US5010047A (en) * 1989-02-27 1991-04-23 Arco Chemical Technology, Inc. Recovery of double metal cyanide complex catalyst from a polymer
JP2995568B2 (ja) * 1989-05-09 1999-12-27 旭硝子株式会社 ポリアルキレンオキシド誘導体の製造法
JP3097854B2 (ja) * 1989-05-12 2000-10-10 旭硝子株式会社 ポリウレタン類の製造方法
JP2960477B2 (ja) * 1990-04-27 1999-10-06 旭硝子株式会社 末端安定化エピハロヒドリン重合体の製造方法
US5136010A (en) * 1990-09-28 1992-08-04 Olin Corporation Polyurethane elastomers and polyurea elastomers made using high functionality, low unsaturation level polyols prepared with double metal cyanide catalysts
JP2653236B2 (ja) * 1990-10-05 1997-09-17 旭硝子株式会社 ポリエーテル化合物の製造方法
US5099075A (en) * 1990-11-02 1992-03-24 Olin Corporation Process for removing double metal cyanide catalyst residues from a polyol
US5185420A (en) * 1990-11-02 1993-02-09 Olin Corporation Thermoplastic polyurethane elastomers and polyurea elastomers made using low unsaturation level polyols prepared with double metal cyanide catalysts
US5144093A (en) * 1991-04-29 1992-09-01 Olin Corporation Process for purifying and end-capping polyols made using double metal cyanide catalysts
US5158922A (en) * 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
GB9312256D0 (en) * 1993-06-15 1993-07-28 Ici Plc Novel polyols
US5470813A (en) * 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US5426081A (en) * 1993-12-23 1995-06-20 Arco Chemical Technology, L.P. Polyurethane foam-supported double metal cyanide catalysts for polyol synthesis
US5482908A (en) * 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5670601A (en) * 1995-06-15 1997-09-23 Arco Chemical Technology, L.P. Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation
US5668191A (en) * 1995-12-21 1997-09-16 Arco Chemical Technology, L.P. One-shot cold molded flexible polyurethane foam from low primary hydroxyl polyols and process for the preparation thereof

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BR9602262A (pt) 1998-06-23
CN1140181A (zh) 1997-01-15
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US5712216A (en) 1998-01-27
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