KR940021629A - 비스아실포스핀 옥사이드 광개시제를 함유하는 경화 조성물 및 에틸렌성 불포화 중합성 화합물의 경화방법 - Google Patents

비스아실포스핀 옥사이드 광개시제를 함유하는 경화 조성물 및 에틸렌성 불포화 중합성 화합물의 경화방법 Download PDF

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KR940021629A
KR940021629A KR1019940005531A KR19940005531A KR940021629A KR 940021629 A KR940021629 A KR 940021629A KR 1019940005531 A KR1019940005531 A KR 1019940005531A KR 19940005531 A KR19940005531 A KR 19940005531A KR 940021629 A KR940021629 A KR 940021629A
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alkyl
compound
ethylenically unsaturated
polymerizable compound
unsaturated polymerizable
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KR100313584B1 (ko
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지.레파드 데이비드
쾔러 만프레드
미세프 루보미어
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베르너 발데크
시바-가이기 아게
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5337—Phosphine oxides or thioxides containing the structure -C(=X)-P(=X) or NC-P(=X) (X = O, S, Se)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5397—Phosphine oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polymerisation Methods In General (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Medicinal Preparation (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

Abstract

에틸렌성 불포화 중합성 화합물은 하기 일반식(Ⅰ)의 광개시제를 경화제로서 사용하는 것에 의해 일광 또는 일광에 상당하는 광원에 의해 경화될 수 있다 :
상기식에서, R1은 C1-C12알킬, 시클로팬틸, 시클로헥실, 비치환 페닐, 나프틸 또는 비페닐이거나, 또는 C1-C12알킬 및/또는 할로겐에 의해 치환된 페닐, 나프틸 또는 비페닐이고, R2및 R3은 서로 독립해서 C1-C12알킬이며, R4는 수소 또는 C1-C12알킬이고, 또 R5는 수소 또는 메틸임.

Description

비스아실포스핀 옥사이드 광개시제를 함유하는 경화 조성물 및 에틸렌성 불포화 중합성 화합물의 경화방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 에틸렌성 불포화 중합성 화합물에 한 개 이상의 하기 일반식(Ⅰ)의 광개시제를 부가하고 이렇게 수득된 혼합물에 일광 또는 일광에 상당하는 광원을 조사하는 것을 포함하는 에틸렌 불포화 중합성 화합물의 경화방법 :
    상기식에서, R1은 C1-C12알킬, 시클로팬틸, 시클로헥실, 비치환 페닐, 나프틸 또는 비페닐이거나, 또는 C1-C12알킬 및/또는 할로겐에 의해 치환된 페닐, 나프틸 또는 비페닐이고, R2및 R3은 서로 독립해서 C1-C12알킬이며, R4는 수소 또는 C1-C12알킬이고, 또 R5는 수소 또는 메틸임.
  2. 제 1 항에 있어서, 일반식(Ⅰ)의 화합물중 R1이 C2-C10알킬, 시클로펜틸, 시클로 헥실 도는 비치환 또는 C1-C4알킬, Cl 및/또는 Br에 의해 치환된 페닐인 방법.
  3. 제 2 항에 있어서, 일반식(Ⅰ)중의 R1이 C3-C8알킬, 시클로펜틸, 시클로헥실 또는 비치환 또는 2-, 3-4- 또는 2,5-위치에서 C1-C4알킬에 의해 치환된 페닐인 방법.
  4. 제 1 항에 있어서, 일반식(Ⅰ) 화합물중의 R1이 C4-C12알킬, 시클로펜틸 또는 시클로헥실이고, R2및 R3이 서로 독립해서 C1-C12알킬이며, 또 R4가 수소 또는 C1-C12알킬인 방법.
  5. 제 1 항에 있어서, 일반식(Ⅰ) 화합물중의 R2및 R3이 C1-C4알킬이고 또 R4가 수소 또는 C1-C4알킬인 방법.
  6. 제 5 항에 있어서, 일반식(Ⅰ) 화합물중의 R1, R3및 R4가 메틸이고 또 R5가 수소인 방법.
  7. 제 1 항에 있어서, 일반식(Ⅰ) 화합물중의 R1이 C3-C8알킬, 바람직하게는 이소부틸인 방법.
  8. 제 1 항에 있어서, 일반식(Ⅰ) 화합물중의 R1이 페닐인 방법.
  9. 제 1 항에 있어서, 에틸렌성 불포화 중합성 화합물이 (ⅰ) 한 개 이상의 올리고머성 화합물 및 (ⅱ) 한 개 이상의 단량체의 혼합물인 방법.
  10. 제 9 항에 있어서, 에틸렌성 불포화 중합성 화합물이 (ⅰ) 불포화 폴리에스테르 및 (ⅱ) 아크릴레이트, 메타크릴레이트 및/또는 스티렌의 혼합물인 방법.
  11. 제10항에 있어서, 에틸렌성 불포화 중합성 화합물이 (ⅰ) 불포화 폴리에스테르 및 (ⅱ) 아크릴레이트 및/또는 메타크릴레이트의 혼합물인 방법.
  12. 제10항에 있어서, 불포화 폴리에스테르 (ⅰ)가 말레인산, 푸마르산 및/또는 프탈산 및 한 개 이상의 디올로부터 제조되고 또 분자량이 500 내지 3000인 방법.
  13. 제 9 항에 있어서, 에틸렌성 불포화 중합성 화합물이 (ⅰ) 폴리에스테르 아크릴레이트 및 (ⅱ) 아크릴레이트 및/또는 메타크릴레이트의 혼합물인 방법.
  14. 제 1 항에 있어서, 에틸렌성 불포화 중합성 화합물이 물에 용해되거나 또는 유화되는 방법.
  15. 제 1 항에 있어서, 광개시제가 0.05 내지 15중량%, 바람직하게는 0.2 내지 5중량%의 양으로 사용되는 방법.
  16. 제 1 항에 있어서, 일반식(Ⅰ)의 광개시제 이외에 다른 광개시제 및/또는 첨가제가 사용되는 방법.
  17. 에틸렌성 불포화 중합성 화합물을 일광 또는 일광에 상당하는 광원을 이용하여 경화시키기 위한 일반식(Ⅰ)의 화합물의 용도.
  18. (A) 한 개 이상의 에틸렌성 불포화 중합성 화합물 및 (B) 한 개 이상의 일반식(Ⅰ)의 광개시제를 포함하고 일광 또는 일광에 상당하는 광원을 조사시킴으로써 경화될 수 있는 조성물.
  19. 제18항에서 청구된 조성물을 표면에 도포하고 또 일광 또는 일광에 상당하는 광원을 그 층에 조사시킴으로써 경화시키는 것을 포함하는 표면의 코팅방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940005531A 1993-03-18 1994-03-17 비스아실포스핀옥사이드광개시제를함유하는경화조성물및에틸렌성불포화중합성화합물의경화방법 KR100313584B1 (ko)

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CH81693 1993-03-18
CH93-9/816 1993-03-18

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KR940021629A true KR940021629A (ko) 1994-10-19
KR100313584B1 KR100313584B1 (ko) 2001-12-28

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US (1) US5534559A (ko)
EP (1) EP0615980B1 (ko)
JP (1) JPH06298818A (ko)
KR (1) KR100313584B1 (ko)
AT (1) ATE210155T1 (ko)
AU (1) AU682334B2 (ko)
BR (1) BR9401197A (ko)
CA (1) CA2119206A1 (ko)
DE (1) DE59409985D1 (ko)
ES (1) ES2167353T3 (ko)
MA (1) MA23097A1 (ko)
ZA (1) ZA941879B (ko)

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