KR960022594A - 카르바메이트-작용성 중합체의 제조 방법 - Google Patents

카르바메이트-작용성 중합체의 제조 방법 Download PDF

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Publication number
KR960022594A
KR960022594A KR1019950053035A KR19950053035A KR960022594A KR 960022594 A KR960022594 A KR 960022594A KR 1019950053035 A KR1019950053035 A KR 1019950053035A KR 19950053035 A KR19950053035 A KR 19950053035A KR 960022594 A KR960022594 A KR 960022594A
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South Korea
Prior art keywords
compound
carbamate
alkyl
substituted
mixture
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KR1019950053035A
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English (en)
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KR100348369B1 (ko
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제이. 테일러 로버트
더블유. 레푸스 존
보스트 조세프
레섹크 폴
엘. 세인트 오빈 도날드
Original Assignee
로버트 엠. 쇼.
바스프 코오포레이숀
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Publication of KR960022594A publication Critical patent/KR960022594A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
  • Paints Or Removers (AREA)

Abstract

본 발명은 (A) (1) 하이드록시-작용기 또는 하이드록시 작용기로 전환될 수 있는 그룹을 포함하는 하나 이상의 아크릴계 단량체, (2) 임의의 성분으로, 하나 이상의 다른 부가 중합가능한 단량체, 및 (3) 카르바메이트 화합물을 함유하는 혼합물을 제거하는 단계; 및 (B) 상기 혼합물을 자유 라디칼 개시제 및 에스테르교환반응 촉매의 존재하에서 가열하여,카르바메이트-작용성 아크릴계 중합체를 형성하는 단계를 포함하여, 카르바메이트-작용성 아크릴계 중합체를 제조하는 방법에 관한 것이다.

Description

카르바메이트-작용성 중합체의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. (A) (1) 하이드록시-작용기 또는 하이드록시 작용기로 전환될 수 있는 그룹을 포함하는 하나 이상의 아크릴계 단랑체, (2) 임의의 성분으로, 하나 이상의 다른 부가 중합가능한 단량체, 및 (3) 카르바메이트 화합물을 함유하는 혼합물을 제조하는 단계: 및 (B) 상기 혼합물을 자유 라디칼 개시제 및 에스테르교환반응 촉매의 존재하에서 가열하여, 카르바메이트-작용성 아크릴계 중합체를 형성하는 단계를 특징으로 하여 카르바메이트-작용성 아크릴계 중합체를 제조하는 방법.
  2. 제1항에 있어서. 상기 카르바메이트 화합물이 알킬 카르바메이트인 것을 특징으로 하는 방법.
  3. 제1항에 있어서, 상기 카르바메이트 화합물이 하기 식의 화합물인 것을 특징으로 하는 방법:
    R1-O-(C=0)-NHR2
    상기 식에서, R1은 치환 또는 비치환된 알킬이고, R2는 H, 치환 또는 비치환된 알킬, 치환 또는 비치환된 시클로알킬, 또는 치환 또는 비치환원 아릴기이다.
  4. 제1항에 있어서, 상기 (A) (1) 성분이 하기 식의 화합물인 것을 특징으로 하는 방법:
    상기 식에서, R3은 H 또는 CH3이고, R4는 탄소 원자수 1~8의 알킬 또는 아릴 이다.
  5. 제4항에 어서, 상기 R4가 탄소 원자수 1~4의 알킬인 것을 특징으로 하는 방법.
  6. 제1항에 있어서, 상기 (A) (2) 성분이 아크릴산, 메타크릴산, 아크릴레이트, 메타크린레이트 및 스티렌 단량체 중에서 선택된 하나 이상의 화합물인 것을 특징으로 하는 방법.
  7. 제1항 내지 제6항 중 어느 한 항에 있어서, 상기 에스테르화 촉매가 유기금속성 착물인 것을 특징으로 하는 방법.
  8. 제1항 내지 제6항 중 어느 한 항에 있어서, 상기 개시제가 퍼옥시드 및 아조 화합물로 이루어진 군 중에서 선택된 것을 특징으로 하는 방법.
  9. 제1항 내지 제6항 중 어느 한 항에 있어서, 상기 단계(B)가 혼합물을 100℃ 내지 140℃의 온도로 가열하는 단계를 포함하는 것을 특징으로 하는 방법.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019950053035A 1994-12-29 1995-12-20 카르바메이트-작용성중합체의제조방법 KR100348369B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/365648 1994-12-29
US08/365,648 US5552497A (en) 1994-12-29 1994-12-29 Method of preparing carbamate-functional polymer
US08/365,648 1994-12-29

Publications (2)

Publication Number Publication Date
KR960022594A true KR960022594A (ko) 1996-07-18
KR100348369B1 KR100348369B1 (ko) 2003-02-07

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US (1) US5552497A (ko)
EP (1) EP0719795B1 (ko)
JP (1) JP3919841B2 (ko)
KR (1) KR100348369B1 (ko)
CN (1) CN1084754C (ko)
AT (1) ATE169642T1 (ko)
AU (1) AU691373B2 (ko)
BR (1) BR9506118A (ko)
CA (1) CA2166241C (ko)
DE (1) DE69504025T2 (ko)
DK (1) DK0719795T3 (ko)
ES (1) ES2122428T3 (ko)

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Publication number Publication date
EP0719795A3 (ko) 1996-08-07
US5552497A (en) 1996-09-03
AU4075795A (en) 1996-07-04
KR100348369B1 (ko) 2003-02-07
EP0719795A2 (en) 1996-07-03
ES2122428T3 (es) 1998-12-16
AU691373B2 (en) 1998-05-14
EP0719795B1 (en) 1998-08-12
CN1084754C (zh) 2002-05-15
JPH08231642A (ja) 1996-09-10
ATE169642T1 (de) 1998-08-15
CA2166241A1 (en) 1996-06-30
CA2166241C (en) 2005-06-07
BR9506118A (pt) 1997-12-23
DK0719795T3 (da) 1999-05-17
DE69504025D1 (de) 1998-09-17
DE69504025T2 (de) 1999-04-22
CN1132757A (zh) 1996-10-09
JP3919841B2 (ja) 2007-05-30

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