KR960022594A - 카르바메이트-작용성 중합체의 제조 방법 - Google Patents
카르바메이트-작용성 중합체의 제조 방법 Download PDFInfo
- Publication number
- KR960022594A KR960022594A KR1019950053035A KR19950053035A KR960022594A KR 960022594 A KR960022594 A KR 960022594A KR 1019950053035 A KR1019950053035 A KR 1019950053035A KR 19950053035 A KR19950053035 A KR 19950053035A KR 960022594 A KR960022594 A KR 960022594A
- Authority
- KR
- South Korea
- Prior art keywords
- compound
- carbamate
- alkyl
- substituted
- mixture
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
Abstract
본 발명은 (A) (1) 하이드록시-작용기 또는 하이드록시 작용기로 전환될 수 있는 그룹을 포함하는 하나 이상의 아크릴계 단량체, (2) 임의의 성분으로, 하나 이상의 다른 부가 중합가능한 단량체, 및 (3) 카르바메이트 화합물을 함유하는 혼합물을 제거하는 단계; 및 (B) 상기 혼합물을 자유 라디칼 개시제 및 에스테르교환반응 촉매의 존재하에서 가열하여,카르바메이트-작용성 아크릴계 중합체를 형성하는 단계를 포함하여, 카르바메이트-작용성 아크릴계 중합체를 제조하는 방법에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- (A) (1) 하이드록시-작용기 또는 하이드록시 작용기로 전환될 수 있는 그룹을 포함하는 하나 이상의 아크릴계 단랑체, (2) 임의의 성분으로, 하나 이상의 다른 부가 중합가능한 단량체, 및 (3) 카르바메이트 화합물을 함유하는 혼합물을 제조하는 단계: 및 (B) 상기 혼합물을 자유 라디칼 개시제 및 에스테르교환반응 촉매의 존재하에서 가열하여, 카르바메이트-작용성 아크릴계 중합체를 형성하는 단계를 특징으로 하여 카르바메이트-작용성 아크릴계 중합체를 제조하는 방법.
- 제1항에 있어서. 상기 카르바메이트 화합물이 알킬 카르바메이트인 것을 특징으로 하는 방법.
- 제1항에 있어서, 상기 카르바메이트 화합물이 하기 식의 화합물인 것을 특징으로 하는 방법:R1-O-(C=0)-NHR2상기 식에서, R1은 치환 또는 비치환된 알킬이고, R2는 H, 치환 또는 비치환된 알킬, 치환 또는 비치환된 시클로알킬, 또는 치환 또는 비치환원 아릴기이다.
- 제1항에 있어서, 상기 (A) (1) 성분이 하기 식의 화합물인 것을 특징으로 하는 방법:상기 식에서, R3은 H 또는 CH3이고, R4는 탄소 원자수 1~8의 알킬 또는 아릴 이다.
- 제4항에 어서, 상기 R4가 탄소 원자수 1~4의 알킬인 것을 특징으로 하는 방법.
- 제1항에 있어서, 상기 (A) (2) 성분이 아크릴산, 메타크릴산, 아크릴레이트, 메타크린레이트 및 스티렌 단량체 중에서 선택된 하나 이상의 화합물인 것을 특징으로 하는 방법.
- 제1항 내지 제6항 중 어느 한 항에 있어서, 상기 에스테르화 촉매가 유기금속성 착물인 것을 특징으로 하는 방법.
- 제1항 내지 제6항 중 어느 한 항에 있어서, 상기 개시제가 퍼옥시드 및 아조 화합물로 이루어진 군 중에서 선택된 것을 특징으로 하는 방법.
- 제1항 내지 제6항 중 어느 한 항에 있어서, 상기 단계(B)가 혼합물을 100℃ 내지 140℃의 온도로 가열하는 단계를 포함하는 것을 특징으로 하는 방법.※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/365648 | 1994-12-29 | ||
US08/365,648 US5552497A (en) | 1994-12-29 | 1994-12-29 | Method of preparing carbamate-functional polymer |
US08/365,648 | 1994-12-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR960022594A true KR960022594A (ko) | 1996-07-18 |
KR100348369B1 KR100348369B1 (ko) | 2003-02-07 |
Family
ID=23439743
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950053035A KR100348369B1 (ko) | 1994-12-29 | 1995-12-20 | 카르바메이트-작용성중합체의제조방법 |
Country Status (12)
Country | Link |
---|---|
US (1) | US5552497A (ko) |
EP (1) | EP0719795B1 (ko) |
JP (1) | JP3919841B2 (ko) |
KR (1) | KR100348369B1 (ko) |
CN (1) | CN1084754C (ko) |
AT (1) | ATE169642T1 (ko) |
AU (1) | AU691373B2 (ko) |
BR (1) | BR9506118A (ko) |
CA (1) | CA2166241C (ko) |
DE (1) | DE69504025T2 (ko) |
DK (1) | DK0719795T3 (ko) |
ES (1) | ES2122428T3 (ko) |
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KR100186927B1 (ko) * | 1992-10-30 | 1999-05-15 | 피피지 인더스트리즈 인코포레이티드 | 산 내식성 필름을 제공하는 아미노플라스트 경화성 필름 형성조성물 |
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US6187376B1 (en) * | 1998-10-01 | 2001-02-13 | Basf Corporation | Method for improving the adhesion of a repair coating to a previously coated substrate |
US6075108A (en) * | 1998-10-06 | 2000-06-13 | Arco Chemical Technology, L.P. | Carbamate-functional allyl monomers and polymers therefrom |
US6106951A (en) * | 1998-11-24 | 2000-08-22 | Basf Corporation | Curable coating compositions containing carmamate-functional compounds |
US6214188B1 (en) | 1998-12-21 | 2001-04-10 | Basf Corporation | Anodic electrocoat having a carbamate functional resin |
US6048443A (en) * | 1998-12-21 | 2000-04-11 | Basf Corporation | Low bake cathodic electrocoat having dual cure mechanism |
US6165338A (en) * | 1998-12-21 | 2000-12-26 | Basf Corporation | Cathodic electrocoat having a carbamate functional resin |
US6346591B1 (en) * | 1999-05-21 | 2002-02-12 | Basf Corporation | Monomer and polymerization process |
US6331596B1 (en) * | 1999-06-28 | 2001-12-18 | Basf Corporation | Method of preparing carbamate-functional polymers |
US6362285B1 (en) | 1999-12-15 | 2002-03-26 | Basf Corporation | Curable coating compositions containing carbamate functional reactive additives |
US6380323B1 (en) | 1999-12-15 | 2002-04-30 | Basf Corporation | Electrocoat resin compositions containing carbamate functional resins having one or more quaternary ammonium groups and at least one carbamate functional reactive additive |
US6303690B1 (en) | 1999-12-15 | 2001-10-16 | Basf Corporation | Cathodic electrocoat having a carbamate functional resin and a carbamate functional reactive additive |
US6391968B1 (en) | 1999-12-15 | 2002-05-21 | Basf Corporation | Curable coating compositions containing carbamate functional polymers and carbamate functional reactive additives |
DE10004498A1 (de) * | 2000-02-02 | 2001-08-09 | Basf Coatings Ag | Diethyloctandioldicarbamate und Diethyloctandioldiallophanate, Verfahren zu ihrer Herstellung und ihre Verwendung |
US6699943B2 (en) | 2000-06-16 | 2004-03-02 | Basf Corporation | Water-based coating composition having carbamate-melamine cross-linking, method of preparing the same, and a cured film thereof |
US6916877B2 (en) * | 2000-06-16 | 2005-07-12 | Basf Corporation | Coating composition including a water-based copolymer cross-linking with a water-dispersible cross-linking agent, method of preparing the same, and a cured film thereof |
US6881791B2 (en) * | 2000-06-16 | 2005-04-19 | Basf Corporation | Poly-electrolyte free block copolymers and their use in crosslinking coatings applications |
DE10041634C2 (de) * | 2000-08-24 | 2002-10-17 | Basf Coatings Ag | Wäßrige Dispersion und ihre Verwendung zur Herstellung von thermisch und mit aktinischer Strahlung härtbaren Beschichtungsstoffen, Klebstoffen und Dichtungsmassen |
US6541577B2 (en) * | 2000-12-06 | 2003-04-01 | Basf Corporation | Carbamate functional polymers and oligomers |
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US6858674B2 (en) | 2002-10-31 | 2005-02-22 | Basf Corporation | Carbamate functional materials, a method of making said materials, and curable coating compositions containing said materials |
US6977309B2 (en) | 2002-10-31 | 2005-12-20 | Basf Corporation | Compounds having a secondary or tertiary hydroxy of halide group separated from a primary carbamate group by three or more carbon atoms and a method of making the same |
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US7740912B2 (en) | 2005-10-07 | 2010-06-22 | E.I. Du Pont De Nemours And Company | Method of forming multi-layer coatings on automobile bodies without a primer bake |
US7867569B2 (en) | 2005-10-07 | 2011-01-11 | E. I. Du Pont De Nemours And Company | Method of forming multi-layer coating on automobile bodies without a primer bake |
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WO2008070077A2 (en) | 2006-12-04 | 2008-06-12 | E. I. Du Pont De Nemours And Company | Coating material containing a mixture of mineral silicates and diurea |
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-
1994
- 1994-12-29 US US08/365,648 patent/US5552497A/en not_active Expired - Lifetime
-
1995
- 1995-12-14 DK DK95119690T patent/DK0719795T3/da active
- 1995-12-14 ES ES95119690T patent/ES2122428T3/es not_active Expired - Lifetime
- 1995-12-14 AT AT95119690T patent/ATE169642T1/de not_active IP Right Cessation
- 1995-12-14 EP EP95119690A patent/EP0719795B1/en not_active Expired - Lifetime
- 1995-12-14 DE DE69504025T patent/DE69504025T2/de not_active Expired - Lifetime
- 1995-12-20 KR KR1019950053035A patent/KR100348369B1/ko not_active IP Right Cessation
- 1995-12-28 JP JP34350295A patent/JP3919841B2/ja not_active Expired - Lifetime
- 1995-12-28 CN CN95121720A patent/CN1084754C/zh not_active Expired - Fee Related
- 1995-12-28 CA CA002166241A patent/CA2166241C/en not_active Expired - Lifetime
- 1995-12-28 BR BR9506118A patent/BR9506118A/pt not_active IP Right Cessation
- 1995-12-29 AU AU40757/95A patent/AU691373B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
EP0719795A3 (ko) | 1996-08-07 |
US5552497A (en) | 1996-09-03 |
AU4075795A (en) | 1996-07-04 |
KR100348369B1 (ko) | 2003-02-07 |
EP0719795A2 (en) | 1996-07-03 |
ES2122428T3 (es) | 1998-12-16 |
AU691373B2 (en) | 1998-05-14 |
EP0719795B1 (en) | 1998-08-12 |
CN1084754C (zh) | 2002-05-15 |
JPH08231642A (ja) | 1996-09-10 |
ATE169642T1 (de) | 1998-08-15 |
CA2166241A1 (en) | 1996-06-30 |
CA2166241C (en) | 2005-06-07 |
BR9506118A (pt) | 1997-12-23 |
DK0719795T3 (da) | 1999-05-17 |
DE69504025D1 (de) | 1998-09-17 |
DE69504025T2 (de) | 1999-04-22 |
CN1132757A (zh) | 1996-10-09 |
JP3919841B2 (ja) | 2007-05-30 |
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