KR840000588A - "살아있는" 중합체의 제조방법 - Google Patents

"살아있는" 중합체의 제조방법 Download PDF

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KR840000588A
KR840000588A KR1019820002894A KR820002894A KR840000588A KR 840000588 A KR840000588 A KR 840000588A KR 1019820002894 A KR1019820002894 A KR 1019820002894A KR 820002894 A KR820002894 A KR 820002894A KR 840000588 A KR840000588 A KR 840000588A
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substituted
alkyl
polymerization conditions
inert under
under polymerization
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KR890004083B1 (ko
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라이트 웨브스터 외 2 오웬
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원본미기재
이 아이 듀우판 디 네모아 앤드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment

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  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

“살아있는”중합체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (46)

  1. 중합조건하에서 하나 이상의 단량체를⒤ 하기구조식(3)으로 나타낸(R1)3MZ와 (ⅱ)플루오로화, 시안화, 아지드화 또는 이플루오르화 이온의 공급원 또는 적당한 루이스산인 공동촉매와 접촉시키므로써 하기구조식(1),(2) 및 이들의 혼합물로부터 선정된 단량체를 중합하여 하나 이상의 단량체의 반복 단위체를 갖는 “살아있는”중합체를 제조하는 방법.
  3. 상기식에서,
  4. X는 -CN, -CH=CHC(O)X' 또는 -C(O)X'이고;
  5. Y는 -H. -CH3, -CN 또는 -CO2R이며(단, X가 CH=CHC(O)X'일 때, Y는 -H 또는 -CH3임);
  6. X는 -OSi(R1)3,-R, -OR 또는 -NR'R"이며:
  7. R1은 C1-10알킬 및 C6-10아릴 또는 알카릴로부터 독자적으로 선정되며:
  8. R은 C1-20알킬, 알케닐, 알카디에닐 : 또는 C6-20시클로알킬, 아릴, 알카릴 또는 아랄킬이며, 이들 원자단은 지방족 분절내에 하나 이상의 에테르 산소원자와 중합조건하에서 불활성인 하나 이상의 관능 치환체를 함유하며:
  9. R' 및 R"는 C1-4알킬로부터 독자적으로 선정되며:
  10. Z는 하기 원자단 및 그들의 혼합물로부터 선정된 활성 치환체이고:
  13. R2및 R3각각은 H : C1-10알킬 및 알케닐 : C1-10아릴, 알카릴 및 아랄킬로부터 독자적으로 선정되며 H를 제외한 상기원자단들은 지방족 분절내에 하나 이상의 에테르 산소 원자와 중합조건하에서 불활성인 하나 이상의 관능 치환체를 함유하며:
  14. Z'는 O 또는 N이고:
  15. m은 2,3 또는 4이며:
  16. n은 3,4 또는 5이고 : 그리고
  17. M은 Si, Sn 또는 Ge이다(단, Z가
  18. 또는일 때, M은 Sn 또는 Ge 임)
  19. 제 1 항에 있어서 R, R2및 R3기중 적어도 하나가 지방족 분절내에 하나 이상의 에테르 산소원자를 함유하는 것을 특징으로 하는 방법.
  20. 제 1 항에 있어서, R, R2및 R3기중 적어도 하나가 중합조건하에서 불활성인 적어도 하나의 관능 치환체를 함유하는 것을 특징으로 하는 방법.
  21. 제 1 항에서 있어서, 단량체가 CH2=C(Y)X이고, M은 Si이며, 공동촉매가 플루오르화, 이플루오르화 또는 시안화 이온의 공급원, ZnI2, ZnBr2또는 ZnCl2인 것을 특징으로 하는 방법.
  22. 제 4 항에 있어서, X가 -C(O)X'인 것을 특징으로 하는 방법.
  23. 제 5 항에 있어서, Y가 -H 또는 -CH3인 것을 특징으로 하는 방법.
  24. 제 6 항에 있어서, X가 -OR인 것을 특징으로 하는 방법.
  25. 제 7 항에 있어서, R이 적어도 하나의 -OSi(R1)3또는 -C(O)OR기로 치환된 것을 특징으로 하는 방법.
  26. 제 7 항에 있어서, R이 적어도 하나의 -OC(R)(R)OR, -OC(H)(R)OR 또는기로 치환된 것을 특징으로 하는 방법.
  27. 제 7 항에 있어서, R이 옥시라닐로 치환된 것을 특징으로 하는 방법.
  28. 제 7 항에 있어서, R이 C1-20알킬, 소르빌, 2-메타크릴록시에틸 2--[(1-프로페닐)-옥시]에틸, 2-(알릴디메틸아미노)에틸 또는 아미노인 것을 특징으로 하는 방법.
  29. 제 4 항에 있어서, X가 -CN인 것을 특징으로 하는 방법.
  30. 제 4 항에 있어서, Z가 -CN인 것을 특징으로 하는 방법.
  31. 제 4 항에 있어서, Z가 -C(R2)(R3)CN인 것을 특징으로 하는 방법.
  32. 제14항에 있어서, R2및 R3중 적어도 하나가 -H인 것을 특징으로 하는 방법.
  33. 제 4 항에 있어서, Z가 -C(R2)(R3)-C(O)X′또는 -OCX'=C(R2)(R3)인 것을 특징으로 하는 방법.
  34. 제16항에 있어서, R2및 R3중 적어도 하나가 H인 것을 특징으로 하는 방법.
  35. 제16항에 있어서, R2및 R3가 CH3인 것을 특징으로 하는 방법.
  36. 제18항에 있어서, 개시제중 X1가 -OSi(CH3)3인 것을 특징으로 하는 방법.
  37. 제18항에 있어서, 개시제중 X1가 -OCH3인 것을 특징으로 하는 방법.
  38. 제 5 항에 있어서, Z가인 것을 특징으로 하는 방법.
  39. 제21항에 있어서, Z1가 산소이며, R2가 H이고 m이 2인 것을 특징으로 하는 방법.
  40. 제19항에 있어서, R2및 R3중 적어도 하나가 중합조건하에서 불활성인 적어도 하나의 관능기로 치환된 것을 특징으로 하는 방법.
  41. 제20항에 있어서, R2및 R3중 적어도 하나가 중합조건하에서 불활성인 적어도 하나의 관능기로 치환된 것을 특징으로 하는 방법.
  42. 제 1 항에 있어서, R1이-CH3인 것을 특징으로 하는 방법.
  43. 제25항에 있어서, Z가 -CH인 것을 특징으로 하는 방법.
  44. 제 1 항에 있어서, 약 -100℃내지 약 150℃에서 반응이 실시되는 것을 특징으로 하는 방법.
  45. 제27항에 있어서, 0℃내지 50℃에서 반응이 실시되는 것을 특징으로 하는 방법.
  46. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임
KR8202894A 1981-06-30 1982-06-29 "살아있는 "중합체의 제조방법 KR890004083B1 (ko)

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US27902581A 1981-06-30 1981-06-30
US279025 1981-06-30
US279,025 1981-06-30

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EP (2) EP0184863B1 (ko)
JP (1) JPS5813603A (ko)
KR (1) KR890004083B1 (ko)
AR (1) AR241118A1 (ko)
AT (1) ATE53593T1 (ko)
AU (1) AU565180B2 (ko)
BR (1) BR8203809A (ko)
DE (2) DE3273440D1 (ko)
DK (1) DK165456C (ko)
ES (1) ES513604A0 (ko)
GB (1) GB2102818A (ko)
HK (2) HK47987A (ko)
MX (1) MX174590B (ko)
NO (1) NO158627C (ko)
SG (1) SG22387G (ko)
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JPS5837321B2 (ja) * 1978-04-19 1983-08-16 東ソー株式会社 アニオン重合方法
US4413084A (en) * 1980-10-23 1983-11-01 Ford Motor Company Paint composition comprising hydroxy functional film former and improved stabilized flow control additive
US4396680A (en) * 1981-03-04 1983-08-02 E. I. Du Pont De Nemours And Co. Substrate coated with crater resistant acrylic enamel
US4351924A (en) * 1981-03-16 1982-09-28 E. I. Du Pont De Nemours And Company ω-, and α,ω-Hydroxyhydrocarbyl-(alkyl methacrylate) polymers and process
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US4598161A (en) * 1983-04-04 1986-07-01 E. I. Du Pont De Nemours And Company Tris(dialkylamino)sulfonium bifluoride catalysts

Also Published As

Publication number Publication date
JPS5813603A (ja) 1983-01-26
DE3273440D1 (en) 1986-10-30
MX174590B (es) 1994-05-27
EP0184863A2 (en) 1986-06-18
KR890004083B1 (ko) 1989-10-20
NO158627C (no) 1988-10-12
NO822230L (no) 1983-01-03
ATE53593T1 (de) 1990-06-15
US4681918A (en) 1987-07-21
EP0184863A3 (en) 1986-10-22
AR241118A2 (es) 1991-11-15
EP0068887A1 (en) 1983-01-05
DK292682A (da) 1982-12-31
HK47987A (en) 1987-06-26
ZA824678B (en) 1984-03-28
ES8307843A1 (es) 1983-08-01
AU8544282A (en) 1983-01-06
AR241118A1 (es) 1991-11-15
EP0184863B1 (en) 1990-06-13
AU565180B2 (en) 1987-09-10
DE3280190D1 (de) 1990-07-19
DK165456B (da) 1992-11-30
DK165456C (da) 1993-04-19
GB2102818A (en) 1983-02-09
ZW13282A1 (en) 1982-09-29
JPH0579685B2 (ko) 1993-11-04
BR8203809A (pt) 1983-07-05
SG22387G (en) 1987-07-10
ES513604A0 (es) 1983-08-01
NO158627B (no) 1988-07-04
HK80490A (en) 1990-10-12
EP0068887B1 (en) 1986-09-24

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