DE3871190D1 - Polymerisationsverfahren und polymerisationskatalysator. - Google Patents

Polymerisationsverfahren und polymerisationskatalysator.

Info

Publication number
DE3871190D1
DE3871190D1 DE8888302168T DE3871190T DE3871190D1 DE 3871190 D1 DE3871190 D1 DE 3871190D1 DE 8888302168 T DE8888302168 T DE 8888302168T DE 3871190 T DE3871190 T DE 3871190T DE 3871190 D1 DE3871190 D1 DE 3871190D1
Authority
DE
Germany
Prior art keywords
alkyl group
groups
carbon atoms
compound
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE8888302168T
Other languages
English (en)
Inventor
Mamoru Kioka
Norio Kashiwa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP62056727A external-priority patent/JP2538584B2/ja
Priority claimed from JP62056726A external-priority patent/JP2537506B2/ja
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Application granted granted Critical
Publication of DE3871190D1 publication Critical patent/DE3871190D1/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE8888302168T 1987-03-13 1988-03-11 Polymerisationsverfahren und polymerisationskatalysator. Expired - Fee Related DE3871190D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP62056727A JP2538584B2 (ja) 1987-03-13 1987-03-13 オレフインの重合方法
JP62056726A JP2537506B2 (ja) 1987-03-13 1987-03-13 オレフインの重合方法

Publications (1)

Publication Number Publication Date
DE3871190D1 true DE3871190D1 (de) 1992-06-25

Family

ID=26397711

Family Applications (2)

Application Number Title Priority Date Filing Date
DE8888302168T Expired - Fee Related DE3871190D1 (de) 1987-03-13 1988-03-11 Polymerisationsverfahren und polymerisationskatalysator.
DE3855283T Expired - Fee Related DE3855283T2 (de) 1987-03-13 1988-03-11 Polymerisationsverfahren und Polymerisationskatalysator

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE3855283T Expired - Fee Related DE3855283T2 (de) 1987-03-13 1988-03-11 Polymerisationsverfahren und Polymerisationskatalysator

Country Status (7)

Country Link
US (1) US5028671A (de)
EP (2) EP0455313B1 (de)
KR (1) KR920001318B1 (de)
CN (2) CN1030990C (de)
AT (1) ATE137771T1 (de)
CA (1) CA1310955C (de)
DE (2) DE3871190D1 (de)

Families Citing this family (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5247031A (en) * 1988-09-13 1993-09-21 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, process for production thereof, olefin polymerization catalyst, and process for polymerizing olefins
KR930003891B1 (ko) * 1989-04-24 1993-05-15 미쓰이세끼유 가가꾸고오교오 가부시끼 가이샤 고급 α-올레핀계 공중합체, 그 제조방법 및 그 가황물 및 가황 가능한 고무조성물
EP0439622A4 (en) * 1989-08-18 1993-05-26 Tonen Corporation Catalytic component for alpha-olefin polymerization
US5556820A (en) * 1989-12-28 1996-09-17 Idemitsu Petrochemical Co., Ltd. Catalyst component for olefin polymerization and process for producing polyolefins
FR2658498B1 (fr) * 1990-02-19 1992-05-15 Atochem Particules de chlorure de magnesium a structure tronc conique, composante catalytique supportee sur ces particules, polyolefines obtenues a partir de cette composante catalytique, procedes de fabrication de ces produits.
FI86548C (fi) * 1990-11-07 1992-09-10 Neste Oy Foerbaettrad stereoselektiv katalysator foer polymerisation av olefiner.
FR2669915B1 (fr) * 1990-11-29 1993-01-29 Atochem Particules de chlorure de magnesium a structure polyedre, composante catalytique supportee sur ces particules, procedes de fabrication de ces produits et des polyolefines obtenues a partir de cette composante catalytique.
FI90083C (fi) * 1990-12-20 1993-12-27 Neste Oy Foer olefinpolymerisation avsett stereospecifikt katalysatorsystem
US5470812A (en) * 1991-11-06 1995-11-28 Mobil Oil Corporation High activity polyethylene catalysts prepared with alkoxysilane reagents
US6291384B1 (en) 1991-11-06 2001-09-18 Mobil Oil Corporation High activity catalyst prepared with alkoxysilanes
US5939348A (en) * 1991-11-06 1999-08-17 Mobil Oil Corporation Catalyst for the manufacture of polythylene with a narrow molecular weight distribution
TW299335B (de) * 1992-01-24 1997-03-01 Mitsui Petroleum Chemicals Ind
CA2089970A1 (en) * 1992-03-04 1993-09-05 Edwar S. Shamshoum Catalyst formulation and polymerization processes
US5773537A (en) * 1992-05-19 1998-06-30 Basf Aktiengesellschaft Ziegler-natta catalyst systems containing specific organosilicon compounds
DE4216548A1 (de) * 1992-05-19 1993-11-25 Basf Ag Ziegler-Natta-Katalysatorsysteme mit speziellen siliciumorganischen Verbindungen
US6410663B2 (en) * 1992-06-08 2002-06-25 Fina Technology, Inc. Electron donors in a Ziegler-Natta catalyst for the production of high melt flow copolymers
DE69323000T2 (de) * 1992-06-08 1999-08-05 Fina Technology Elektrondonor zur verbesserten Olefinpolymerisation
US5891817A (en) * 1992-06-08 1999-04-06 Fina Technology, Inc. Electron donors for improved olefin polymerization
BR9307390A (pt) * 1992-11-06 1999-08-31 Union Carbide Chem Plastic Processo para polimerização de alfa-olefina
US6489411B1 (en) * 1993-06-30 2002-12-03 Fina Technology, Inc. Catalyst formulation and polymerization processes
TW354792B (en) 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
JP3670010B2 (ja) * 1993-11-18 2005-07-13 モービル・オイル・コーポレーション 触媒組成物の製造方法
EP0844259B1 (de) * 1993-12-06 2002-09-25 Sumitomo Chemical Company, Limited Alphaolefinpolymere, Katalysator zur Alphaolefinpolymerisation und Verfahren zur Herstellung von Alphaolefinpolymeren
US5608018A (en) * 1993-12-08 1997-03-04 Sumitomo Chemical Company, Limited α-olefin polymerization catalyst system and process for producing α-olefin catalyst
CN1100069C (zh) * 1994-05-12 2003-01-29 昭和电工株式会社 丙烯系聚合物及其制法
US6184328B1 (en) 1994-09-07 2001-02-06 Showa Denko Kabushiki Kaisha Propylene-based polymer, method for its production, composition thereof, catalyst component for polymerization, and method for its production
EP0821012B1 (de) * 1994-05-12 1999-01-13 Showa Denko Kabushiki Kaisha Polymer auf Propylenbasis, Verfahren zu seiner Herstellung und Zusammensetzungen davon
KR0139089B1 (ko) * 1994-12-08 1998-05-01 김은영 올레핀의 중합반응용 촉매계
FR2728181B1 (fr) 1994-12-16 1997-01-31 Appryl Snc Composante catalytique pour la polymerisation des olefines, son procede de fabrication, et procede de polymerisation des olefines en presence de ladite composante catalytique
US5661095A (en) * 1995-06-06 1997-08-26 Quantum Chemical Corporation Olefin polymerization catalyst component supported on a copolymer of an olefin and an unsaturated silane
CN1098286C (zh) * 1997-04-30 2003-01-08 中国石油化工总公司 一种用于乙烯聚合或共聚合的催化剂及其制法
ATE269361T1 (de) * 1998-12-25 2004-07-15 Toho Titanium Co Ltd Feste katalysatorkomponente für die propylenpolymerisation und katalysator
US6358372B1 (en) 2000-07-11 2002-03-19 Union Carbide Chemicals & Plastics Technology Corporation Method of reducing formation of precipitates in solvent recovery system
CN100564400C (zh) 2001-05-29 2009-12-02 联合碳化化学及塑料技术有限责任公司 烯烃聚合催化剂组合物和制备方法
US6825146B2 (en) * 2001-05-29 2004-11-30 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preparation
CA2488140A1 (en) * 2002-06-14 2003-12-24 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition and polymerization process using mixtures of selectivity control agents
CN1788024A (zh) * 2003-05-12 2006-06-14 联合碳化化学及塑料技术公司 控制气相聚合反应中聚合物粉末的方法
DE602004024994D1 (de) * 2003-06-24 2010-02-25 Union Carbide Chem Plastic Katalysatorzusammensetzung und Polymerisationsverfahren mit einer Mischung von Silane Elektrondonoren
KR20060128827A (ko) * 2003-08-29 2006-12-14 다우 글로벌 테크놀로지스 인크. 부분적으로 건조된 쉽게 분산가능한 올레핀 중합프로촉매의 제조 방법
BR122014013907B1 (pt) 2003-09-23 2020-11-10 Dow Global Technologies Inc processo para a polimerização em fase gasosa de etileno
CN1856512B (zh) * 2003-09-23 2010-06-02 陶氏环球技术公司 含有二羧酸酯内部给体的自限制催化剂组合物和丙烯聚合方法
US7393806B2 (en) * 2003-09-23 2008-07-01 Dow Global Technologies Inc. Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process
KR20060099512A (ko) * 2003-09-23 2006-09-19 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 코포레이션 혼합된 선택성 조절제를 갖는 촉매 조성물 및 프로필렌중합 방법
WO2005035594A1 (en) 2003-09-23 2005-04-21 Union Carbide Chemicals & Plastics Technology Corporation Self-extiguishing catalyst compostion with monocarboxylic acid ester internal donor and propylene polymerization process
WO2005030815A1 (en) 2003-09-23 2005-04-07 Dow Global Technologies Inc. Self limiting catalyst composition and propylene polymerization process
CN1938340A (zh) * 2004-04-07 2007-03-28 联合碳化化学及塑料技术公司 烯烃聚合前催化剂组合物及其制备方法
ES2496140T3 (es) 2004-06-16 2014-09-18 Dow Global Technologies Llc Método para identificar cocatalizadores Ziegler-Natta
WO2006007093A1 (en) * 2004-06-16 2006-01-19 Dow Global Technologies Inc. Apparatus and method for ziegler-natta research
KR101200656B1 (ko) 2004-08-09 2012-11-12 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 강한 분무-건조된 지글러-나타 전촉매 및 이를 사용하는중합 방법
WO2006020623A1 (en) 2004-08-09 2006-02-23 Union Carbide Chemicals & Plastics Technology Corporation Robust spray-dried ziegler-natta procatalyst and polymerization process employing same
KR100612108B1 (ko) * 2004-10-29 2006-08-11 삼성토탈 주식회사 프로필렌 중합용 촉매 및 이를 이용한 프로필렌의 중합방법
KR100874089B1 (ko) 2007-04-25 2008-12-16 삼성토탈 주식회사 프로필렌 중합용 촉매의 제조방법
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
JP2012500321A (ja) * 2008-08-19 2012-01-05 ダウ グローバル テクノロジーズ エルエルシー 分級触媒組成物、装置、及び方法
EP2350143B1 (de) * 2008-11-25 2016-02-17 W.R. Grace & CO. - CONN. Prokatalysatorzusammensetzung mit multiplem internem donator mit silylester und verfahren
US8088872B2 (en) * 2008-11-25 2012-01-03 Dow Global Technologies Llc Procatalyst composition including silyl ester internal donor and method
WO2010078479A1 (en) 2008-12-31 2010-07-08 Dow Global Technologies Inc. Random propylene copolymer compositions, articles and process
PL2373702T3 (pl) 2008-12-31 2018-07-31 W.R. Grace & Co.-Conn. Kompozycja prekatalizatora z wewnętrznym donorem w postaci podstawionego aromatycznego diestru 1,2-fenylenowego oraz sposób
US8247341B2 (en) * 2009-04-17 2012-08-21 Dow Global Technologies Llc Procatalyst composition with silyl glutarate and method
WO2010123775A1 (en) * 2009-04-23 2010-10-28 Dow Global Technologies Inc. Procatalyst composition with adamantane and method
MY158466A (en) * 2009-12-02 2016-10-14 Grace W R & Co Three and four atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture
SG181482A1 (en) * 2009-12-02 2012-07-30 Dow Global Technologies Llc Two atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture
KR101126918B1 (ko) 2009-12-28 2012-03-20 호남석유화학 주식회사 폴리올레핀 중합용 촉매의 제조방법, 이에 따른 촉매 및 이를 이용한 폴리올레핀의 제조방법
KR101126946B1 (ko) 2009-12-28 2012-03-20 호남석유화학 주식회사 폴리올레핀 중합용 촉매 및 이의 제조방법
KR101169861B1 (ko) 2010-05-27 2012-07-31 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법 및 이를 이용한 고체 촉매
BR112013015875B1 (pt) 2010-12-21 2020-10-20 W. R. Grace & Co. - Conn processo de polimerização ziegler-natta para produzir um polímero baseado em propileno
CN109843939B (zh) 2016-08-30 2024-04-26 格雷斯公司 具有低灰分含量的聚烯烃及其制备方法
JP7113817B2 (ja) 2016-10-06 2022-08-05 ダブリュー・アール・グレース・アンド・カンパニー－コーン 複数の内部電子供与体の組合せを用いて作製されるプロ触媒組成物
EP3856800A1 (de) * 2018-09-28 2021-08-04 Borealis AG Verfahren zur herstellung eines vorpolymerisierten festen ziegler-natta-katalysators
KR20230073831A (ko) * 2021-11-19 2023-05-26 롯데케미칼 주식회사 기계적 물성 및 열적 특성이 우수한 이차전지 분리막용 폴리프로필렌 제조방법

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3135809A (en) * 1960-07-21 1964-06-02 Southern Res Inst Isomerization process
US4295991A (en) * 1978-09-26 1981-10-20 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof
JPS5883006A (ja) * 1981-11-13 1983-05-18 Mitsui Petrochem Ind Ltd オレフインの重合方法
JPS59117509A (ja) * 1982-12-24 1984-07-06 Mitsui Petrochem Ind Ltd オレフインの重合方法
JPS59206418A (ja) * 1983-05-11 1984-11-22 Mitsui Petrochem Ind Ltd ４−メチル−１−ペンテン重合体の製法
JPS60115603A (ja) * 1983-11-29 1985-06-22 Toa Nenryo Kogyo Kk オレフインの重合方法
JPH0655780B2 (ja) * 1984-07-09 1994-07-27 東燃株式会社 オレフイン重合用触媒成分
JPS6155104A (ja) * 1984-08-24 1986-03-19 Toho Titanium Co Ltd オレフィン類重合用触媒成分
JPH0721018B2 (ja) * 1985-07-05 1995-03-08 東燃料株式会社 オレフイン重合用触媒成分の製造方法
DE3876892T2 (de) * 1987-02-17 1993-04-29 Mitsui Petrochemical Ind Verfahren zur polymerisierung von alpha-polyolefinen.

Also Published As

Publication number Publication date
CA1310955C (en) 1992-12-01
CN1030990C (zh) 1996-02-14
CN1117055A (zh) 1996-02-21
EP0455313B1 (de) 1996-05-08
KR880011205A (ko) 1988-10-27
EP0282341B1 (de) 1992-05-20
DE3855283T2 (de) 1996-10-02
CN88101916A (zh) 1988-10-26
KR920001318B1 (ko) 1992-02-10
EP0282341A1 (de) 1988-09-14
ATE137771T1 (de) 1996-05-15
DE3855283D1 (de) 1996-06-13
CN1036202C (zh) 1997-10-22
US5028671A (en) 1991-07-02
EP0455313A1 (de) 1991-11-06

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Owner name: MITSUI CHEMICALS, INC., TOKIO/TOKYO, JP

8339 Ceased/non-payment of the annual fee