KR102104424B1 - 고체전해콘덴서의 제조방법 및 고체전해콘덴서 - Google Patents
고체전해콘덴서의 제조방법 및 고체전해콘덴서 Download PDFInfo
- Publication number
- KR102104424B1 KR102104424B1 KR1020157001301A KR20157001301A KR102104424B1 KR 102104424 B1 KR102104424 B1 KR 102104424B1 KR 1020157001301 A KR1020157001301 A KR 1020157001301A KR 20157001301 A KR20157001301 A KR 20157001301A KR 102104424 B1 KR102104424 B1 KR 102104424B1
- Authority
- KR
- South Korea
- Prior art keywords
- solid electrolyte
- oxide film
- dielectric oxide
- manufacturing
- conductive polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003990 capacitor Substances 0.000 title claims abstract description 112
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 79
- 238000000034 method Methods 0.000 title claims abstract description 64
- 239000007787 solid Substances 0.000 title claims description 26
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 103
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 94
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 87
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 6
- 238000005245 sintering Methods 0.000 claims abstract description 5
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 15
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 12
- 238000007654 immersion Methods 0.000 claims description 11
- 238000002407 reforming Methods 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 claims description 4
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- 239000011888 foil Substances 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 21
- 238000010438 heat treatment Methods 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- 238000005470 impregnation Methods 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 6
- 230000002542 deteriorative effect Effects 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 230000008646 thermal stress Effects 0.000 description 4
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000006355 external stress Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 239000012985 polymerization agent Substances 0.000 description 1
- -1 polyoxyethylene Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/15—Solid electrolytic capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/0029—Processes of manufacture
- H01G9/0032—Processes of manufacture formation of the dielectric layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/0029—Processes of manufacture
- H01G9/0036—Formation of the solid electrolyte layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
- H01G9/028—Organic semiconducting electrolytes, e.g. TCNQ
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/022—Electrolytes; Absorbents
- H01G9/025—Solid electrolytes
- H01G9/032—Inorganic semiconducting electrolytes, e.g. MnO2
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JPJP-P-2012-189520 | 2012-08-30 | ||
| JP2012189520A JP5933397B2 (ja) | 2012-08-30 | 2012-08-30 | 固体電解コンデンサの製造方法および固体電解コンデンサ |
| PCT/JP2013/064501 WO2014034201A1 (ja) | 2012-08-30 | 2013-05-24 | 固体電解コンデンサの製造方法および固体電解コンデンサ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20150048703A KR20150048703A (ko) | 2015-05-07 |
| KR102104424B1 true KR102104424B1 (ko) | 2020-04-24 |
Family
ID=50183027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020157001301A Active KR102104424B1 (ko) | 2012-08-30 | 2013-05-24 | 고체전해콘덴서의 제조방법 및 고체전해콘덴서 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9865401B2 (enExample) |
| EP (1) | EP2892065B1 (enExample) |
| JP (1) | JP5933397B2 (enExample) |
| KR (1) | KR102104424B1 (enExample) |
| CN (1) | CN104488050B (enExample) |
| WO (1) | WO2014034201A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2517019B (en) * | 2013-05-13 | 2018-08-29 | Avx Corp | Solid electrolytic capacitor containing conductive polymer particles |
| GB2514486B (en) * | 2013-05-13 | 2018-08-29 | Avx Corp | Solid electrolytic capacitor containing a pre-coat layer |
| US9472350B2 (en) * | 2013-05-13 | 2016-10-18 | Avx Corporation | Solid electrolytic capacitor containing a multi-layered adhesion coating |
| CN106710882B (zh) * | 2015-08-19 | 2019-03-08 | 中国科学院福建物质结构研究所 | 一种具有复合固体电解质的固体电解电容器及其制备方法 |
| EP3529816A4 (en) * | 2016-10-18 | 2020-09-02 | AVX Corporation | SOLID ELECTROLYTIC CAPACITOR WITH IMPROVED PERFORMANCE AT HIGH TEMPERATURES AND VOLTAGES |
| CN106952730B (zh) * | 2017-03-21 | 2018-10-16 | 电子科技大学 | 一种钽电容器二氧化锰被覆液及其制备方法 |
| US11270847B1 (en) | 2019-05-17 | 2022-03-08 | KYOCERA AVX Components Corporation | Solid electrolytic capacitor with improved leakage current |
| US11823846B2 (en) * | 2019-12-10 | 2023-11-21 | KYOCERA AVX Components Corporation | Solid electrolytic capacitor containing a pre-coat and intrinsically conductive polymer |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040231119A1 (en) * | 2003-05-21 | 2004-11-25 | Brenneman Keith R. | Method of electrolytic deposition of an intrinsically conductive polymer upon a non-conductive substrate |
| US20050248910A1 (en) * | 2004-05-05 | 2005-11-10 | H.C. Starck Gmbh | Process for the producing of electrolytic capacitors |
| JP4452141B2 (ja) * | 2004-08-05 | 2010-04-21 | ニチコン株式会社 | 固体電解コンデンサの製造方法 |
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Also Published As
| Publication number | Publication date |
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| EP2892065B1 (en) | 2021-12-22 |
| EP2892065A4 (en) | 2016-07-20 |
| KR20150048703A (ko) | 2015-05-07 |
| CN104488050B (zh) | 2018-06-12 |
| JP2014049520A (ja) | 2014-03-17 |
| CN104488050A (zh) | 2015-04-01 |
| US9865401B2 (en) | 2018-01-09 |
| US20150255223A1 (en) | 2015-09-10 |
| HK1203689A1 (en) | 2015-11-27 |
| JP5933397B2 (ja) | 2016-06-08 |
| WO2014034201A1 (ja) | 2014-03-06 |
| EP2892065A1 (en) | 2015-07-08 |
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