KR100444022B1 - 유체흡수용중합체,이것의제조방법및사용방법 - Google Patents
유체흡수용중합체,이것의제조방법및사용방법 Download PDFInfo
- Publication number
- KR100444022B1 KR100444022B1 KR19980703803A KR19980703803A KR100444022B1 KR 100444022 B1 KR100444022 B1 KR 100444022B1 KR 19980703803 A KR19980703803 A KR 19980703803A KR 19980703803 A KR19980703803 A KR 19980703803A KR 100444022 B1 KR100444022 B1 KR 100444022B1
- Authority
- KR
- South Korea
- Prior art keywords
- chr
- polymer
- alkyl
- branched
- polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/062—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F261/00—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00
- C08F261/02—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols
- C08F261/04—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols on to polymers of vinyl alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F267/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
- C08F267/06—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00 on to polymers of esters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Hematology (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Graft Or Block Polymers (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19543369.6 | 1995-11-21 | ||
| DE19543369 | 1995-11-21 | ||
| DE19646484A DE19646484C2 (de) | 1995-11-21 | 1996-11-11 | Flüssigkeitsabsorbierende Polymere, Verfahren zu deren Herstellung und deren Verwendung |
| DE19646484.6 | 1996-11-11 | ||
| PCT/EP1996/005075 WO1997019116A1 (de) | 1995-11-21 | 1996-11-18 | Flüssigkeitsabsorbierende polymere, verfahren zu deren herstellung und deren verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR19990071530A KR19990071530A (ko) | 1999-09-27 |
| KR100444022B1 true KR100444022B1 (ko) | 2004-11-03 |
Family
ID=26020546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR19980703803A Expired - Lifetime KR100444022B1 (ko) | 1995-11-21 | 1996-11-18 | 유체흡수용중합체,이것의제조방법및사용방법 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5837789A (https=) |
| EP (1) | EP0862590B1 (https=) |
| JP (1) | JP4001350B2 (https=) |
| KR (1) | KR100444022B1 (https=) |
| CN (1) | CN1106415C (https=) |
| AT (1) | ATE183526T1 (https=) |
| AU (1) | AU718132B2 (https=) |
| BR (1) | BR9611469A (https=) |
| CA (1) | CA2236504A1 (https=) |
| DE (2) | DE19646484C2 (https=) |
| ES (1) | ES2138385T3 (https=) |
| MX (1) | MX202050B (https=) |
| PL (1) | PL326840A1 (https=) |
| RU (1) | RU2193045C2 (https=) |
| TR (1) | TR199800900T2 (https=) |
| TW (1) | TW438821B (https=) |
| WO (1) | WO1997019116A1 (https=) |
Families Citing this family (352)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0812873B2 (en) † | 1995-12-27 | 2018-10-24 | Nippon Shokubai Co., Ltd. | Water absorbent and process and equipment for the production thereof |
| AU721524B2 (en) * | 1996-07-06 | 2000-07-06 | Stockhausen Gmbh & Co. Kg | Absorbent inserts, method of producing them and their use |
| US6596532B1 (en) | 1997-12-12 | 2003-07-22 | BIOMéRIEUX, INC. | Device for isolation and surface culture of microorganisms from bulk fluids |
| CA2346540C (en) * | 1998-10-07 | 2009-12-15 | Pirelli & C. S.P.A. | Water-resistant cable |
| US6297335B1 (en) * | 1999-02-05 | 2001-10-02 | Basf Aktiengesellschaft | Crosslinked, hydrophilic, highly swellable hydrogels, production thereof and use thereof |
| DE19909653A1 (de) | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
| AUPP939299A0 (en) * | 1999-03-23 | 1999-04-15 | University Of Melbourne, The | Polymer gels and methods for their preparation |
| DE50015912D1 (de) | 1999-07-15 | 2010-06-10 | Clariant Produkte Deutschland | Wasserlösliche Polymere und ihre Verwendung in kosmetischen und pharmazeutischen Mitteln |
| DE19941423A1 (de) * | 1999-08-30 | 2001-03-01 | Stockhausen Chem Fab Gmbh | Polymerzusammensetzung und ein Verfahren zu dessen Herstellung |
| DE50102334D1 (de) | 2000-03-31 | 2004-06-24 | Stockhausen Chem Fab Gmbh | Pulverförmige, an der oberfläche vernetzte polymerisate |
| DE60141204D1 (de) * | 2000-04-01 | 2010-03-18 | Qinetiq Ltd | Polymeren, Verfahren, Zusammensetzungen, Klebstoffe, Verwendungen, Produkte |
| DE10037629A1 (de) * | 2000-08-02 | 2002-02-14 | Skw Bauwerkstoffe Deutschland | Wasserlösliche oder wasserquellbare sulfogruppenhaltige assoziativverdickende Copolymere, Verfahren zu deren Herstellung und deren Verwendung |
| DE10043710B4 (de) | 2000-09-04 | 2015-01-15 | Evonik Degussa Gmbh | Verwendung pulverförmiger an der Oberfläche nachvernetzter Polymerisate und Hygieneartikel |
| US6903243B1 (en) * | 2000-09-08 | 2005-06-07 | 3M Innovative Properties Company | Multi-layer absorbent wound dressing |
| AU2002210553A1 (en) * | 2000-10-19 | 2002-04-29 | Basf Aktiengesellschaft | Cross-linked, water-swellable polymer and method for producing the same |
| US6403674B1 (en) | 2000-11-17 | 2002-06-11 | Eveready Battery Company, Inc. | Solvent-free method for synthesizing superabsorbent polymers |
| AU2002218089A1 (en) * | 2000-11-20 | 2002-05-27 | Matrix Innovation Inc. | Amphiphile solid support for peptide synthesis, bioorganic and organic chemistry |
| DE10059832A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Gepfropfte Copolymere auf Basis von Acryloyldimethyltaurinsäure |
| DE10059819A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Tensidhaltige kosmetische, dermatologische und pharmazeutische Mittel |
| DE10059821A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Tensidfreie kosmetische, dermatologische und pharmazeutische Mittel |
| DE10059830A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Kationisch modifizierte Kammpolymere auf Basis von Acryloyldimethyltaurinsäure |
| DE10059828A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Kammförmige Copolymere auf Basis von Acryloyldimethyltaurinsäure |
| DE10059829A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Gepfropfte Kammpolymere auf Basis von Acryloyldimethyltaurinsäure |
| US6998367B2 (en) | 2001-12-06 | 2006-02-14 | Kimberly-Clark Worldwide, Inc. | Absorbent composition containing transitional crosslinking points |
| WO2003051940A1 (en) * | 2001-12-19 | 2003-06-26 | Nippon Shokubai Co., Ltd. | Acrylic acid composition and its production process, and process for producing water-absorbent resin using this acrylic acid composition, and water-absorbent resin |
| DE10163543A1 (de) * | 2001-12-21 | 2003-07-31 | Basf Ag | Tocopherol-haltige Superabsorber |
| DE10163902A1 (de) * | 2001-12-22 | 2003-07-03 | Clariant Gmbh | Kristallisationsinhibitor für Pflanzenschutz-Formulierungen |
| US7101946B2 (en) * | 2002-02-14 | 2006-09-05 | Stockhausen Gmbh | Water-absorbing polymers having interstitial compounds, a process for their production, and their use |
| DE10225943A1 (de) * | 2002-06-11 | 2004-01-08 | Basf Ag | Verfahren zur Herstellung von Estern von Polyalkoholen |
| CA2488226A1 (en) * | 2002-06-11 | 2003-12-18 | Basf Aktiengesellschaft | (meth)acrylic esters of polyalkoxylated trimethylolpropane |
| MXPA04011457A (es) * | 2002-06-11 | 2005-02-14 | Basf Ag | Esteres (met)acrilicos de trimetilolpropano polialcoxilado. |
| CA2487030A1 (en) * | 2002-06-11 | 2003-12-18 | Basf Aktiengesellschaft | (meth)acrylic esters of polyalkoxylated glycerine |
| DE10249822A1 (de) * | 2002-10-25 | 2004-05-13 | Stockhausen Gmbh & Co. Kg | Zweistufiges Mischverfahren zur Herstellung eines absorbierenden Polymers |
| WO2004037900A1 (de) | 2002-10-25 | 2004-05-06 | Stockhausen Gmbh | Zweistufiges mischverfahren zur herstellung eines absorbierenden polymers |
| EP1982678B1 (en) | 2003-02-12 | 2019-03-27 | The Procter and Gamble Company | Comfortable diaper |
| ATE455528T1 (de) | 2003-02-12 | 2010-02-15 | Procter & Gamble | Saugfähiger kern für einen saugfähigen artikel |
| US20060182706A1 (en) * | 2003-03-07 | 2006-08-17 | Basf Aktiengesellscaft Patents, Trademarkds And Licenses | Polymer products and their use in cosmetic preparations |
| CN1317308C (zh) * | 2003-03-26 | 2007-05-23 | 巴斯福股份公司 | 颜色稳定的超吸收性聚合物组合物 |
| DE10314599A1 (de) * | 2003-03-31 | 2004-10-21 | Mang, Thomas, Prof. Dr. | Verwendung einer vernetzten Polymerzusammensetzung als wasseraufnehmende Komponente in Dichtungs- und Absorptionsmaterialien |
| DE10358372A1 (de) | 2003-04-03 | 2004-10-14 | Basf Ag | Gemische von Verbindungen mit mindestens zwei Doppelbindungen und deren Verwendung |
| JP4460851B2 (ja) * | 2003-05-27 | 2010-05-12 | 株式会社日本触媒 | 吸水性樹脂の整粒方法 |
| US7960469B2 (en) | 2003-06-24 | 2011-06-14 | Nippon Shokubai Co., Ltd. | Water absorbent resin composition and production method thereof |
| DE10331450A1 (de) * | 2003-07-10 | 2005-01-27 | Basf Ag | (Meth)acrylsäureester monoalkoxilierter Polyole und deren Herstellung |
| DE10331456A1 (de) | 2003-07-10 | 2005-02-24 | Basf Ag | (Meth)acrylsäureester alkoxilierter ungesättigter Polyolether und deren Herstellung |
| JP2007501079A (ja) | 2003-08-06 | 2007-01-25 | ザ プロクター アンド ギャンブル カンパニー | コーティングされた水膨潤性ポリマー類を含む水膨潤性材料を製造する方法 |
| US7517586B2 (en) | 2003-08-06 | 2009-04-14 | Procter & Gamble Company | Absorbent structures comprising coated water-swellable material |
| EP1651706A1 (en) | 2003-08-06 | 2006-05-03 | The Procter & Gamble Company | Coated water-swellable material |
| EP1518567B1 (en) | 2003-09-25 | 2017-06-28 | The Procter & Gamble Company | Absorbent articles comprising fluid acquisition zones with coated superabsorbent particles |
| DE10355401A1 (de) | 2003-11-25 | 2005-06-30 | Basf Ag | (Meth)acrylsäureester ungesättigter Aminoalkohole und deren Herstellung |
| DE102004019264B4 (de) * | 2004-04-21 | 2008-04-10 | Stockhausen Gmbh | Verfahren zur Herstellung eines absorbierenden Polymers mittels Spreittrocknung |
| AU2005285763A1 (en) * | 2004-09-24 | 2006-03-30 | Nippon Shokubai Co., Ltd. | Particulate water-absorbing agent containing water-absorbent resin as a main component |
| DE102004051242A1 (de) | 2004-10-20 | 2006-05-04 | Basf Ag | Feinteilige wasserabsorbierende Polymerpartikel mit hoher Flüssigkeitstransport- und Absorptionsleistung |
| DE102004055765A1 (de) | 2004-11-18 | 2006-05-24 | Basf Ag | Verfahren zur Herstellung wasserabsorbierender Polymere |
| CA2492884A1 (en) * | 2005-01-13 | 2006-07-13 | Stephane Chevigny | A high efficiency process for particle size reduction of glass-like polysaccharides |
| DE102005002412A1 (de) * | 2005-01-18 | 2006-07-27 | Basf Ag | Verfahren zur Herstellung von Polymeren durch Sprühpolymerisation |
| WO2006082240A1 (en) * | 2005-02-04 | 2006-08-10 | Basf Aktiengesellschaft | Water swellable material |
| ATE487500T1 (de) * | 2005-02-04 | 2010-11-15 | Procter & Gamble | Absorbierende struktur mit verbessertem wasserabsorbierendem material |
| WO2006097389A2 (en) * | 2005-02-04 | 2006-09-21 | Basf Aktiengesellschaft | A process for producing a water-absorbing material having a coating of elastic filmforming polymers |
| JP2008538121A (ja) * | 2005-02-04 | 2008-10-09 | ビーエーエスエフ ソシエタス・ヨーロピア | 弾性膜形成ポリマーのコーティングを有する水吸収材料 |
| DE602006015422D1 (de) * | 2005-02-04 | 2010-08-26 | Basf Se | Verfahren zur herstellung eines wasserabsorbierenden materials mit einem überzug aus elastischen filmbildenden polymeren |
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| TWI353360B (en) | 2005-04-07 | 2011-12-01 | Nippon Catalytic Chem Ind | Production process of polyacrylic acid (salt) wate |
| US20060264861A1 (en) | 2005-05-20 | 2006-11-23 | Lavon Gary D | Disposable absorbent article having breathable side flaps |
| DE102005042604A1 (de) | 2005-09-07 | 2007-03-08 | Basf Ag | Neutralisationsverfahren |
| TWI377222B (en) | 2005-12-22 | 2012-11-21 | Nippon Catalytic Chem Ind | Method for surface crosslinking water-absorbing resin and method for manufacturing water-absorbing resin |
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| GB2454301B (en) | 2007-06-18 | 2012-03-28 | Procter & Gamble | Disposable absorbent article with sealed absorbent core with substantially continuously distributed absorbent particulate polymer material |
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| WO2010124954A1 (de) | 2009-04-30 | 2010-11-04 | Basf Se | Verfahren zur abtrennung metallischer verunreinigungen |
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| EP2277558B1 (en) | 2009-07-20 | 2014-07-02 | The Procter and Gamble Company | Superabsorbent polymer composite particles and processes therefore |
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| US20120157634A1 (en) | 2009-08-25 | 2012-06-21 | Basf Se | Soft Particulate Superabsorbent and Use Thereof |
| WO2011023572A1 (de) | 2009-08-25 | 2011-03-03 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel mit verbesserter blutabsorption durch polymerisation von tropfen einer monomerlösung |
| EP2470221B1 (de) | 2009-08-26 | 2016-03-23 | Basf Se | Geruchsinhibierende zusammensetzungen |
| JP5615365B2 (ja) | 2009-08-28 | 2014-10-29 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | トリクロサン被覆超吸収材の製造方法 |
| US8481159B2 (en) | 2009-09-04 | 2013-07-09 | Basf Se | Water-absorbent porous polymer particles having specific sphericity and high bulk density |
| WO2011032876A1 (de) | 2009-09-16 | 2011-03-24 | Basf Se | Farbstabiler superabsorber |
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-
1996
- 1996-11-11 DE DE19646484A patent/DE19646484C2/de not_active Expired - Fee Related
- 1996-11-18 MX MX9803991A patent/MX202050B/es unknown
- 1996-11-18 EP EP96939094A patent/EP0862590B1/de not_active Expired - Lifetime
- 1996-11-18 AU AU76273/96A patent/AU718132B2/en not_active Ceased
- 1996-11-18 PL PL96326840A patent/PL326840A1/xx unknown
- 1996-11-18 DE DE59602822T patent/DE59602822D1/de not_active Expired - Lifetime
- 1996-11-18 KR KR19980703803A patent/KR100444022B1/ko not_active Expired - Lifetime
- 1996-11-18 WO PCT/EP1996/005075 patent/WO1997019116A1/de not_active Ceased
- 1996-11-18 ES ES96939094T patent/ES2138385T3/es not_active Expired - Lifetime
- 1996-11-18 AT AT96939094T patent/ATE183526T1/de not_active IP Right Cessation
- 1996-11-18 BR BR9611469A patent/BR9611469A/pt not_active IP Right Cessation
- 1996-11-18 TR TR1998/00900T patent/TR199800900T2/xx unknown
- 1996-11-18 JP JP51937997A patent/JP4001350B2/ja not_active Expired - Lifetime
- 1996-11-18 CA CA002236504A patent/CA2236504A1/en not_active Abandoned
- 1996-11-18 RU RU98111755/04A patent/RU2193045C2/ru active
- 1996-11-18 CN CN96199633A patent/CN1106415C/zh not_active Expired - Lifetime
- 1996-11-19 TW TW085114159A patent/TW438821B/zh not_active IP Right Cessation
- 1996-11-20 US US08/752,889 patent/US5837789A/en not_active Expired - Lifetime
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| DE19646484A1 (de) | 1997-05-22 |
| AU718132B2 (en) | 2000-04-06 |
| CN1106415C (zh) | 2003-04-23 |
| MX9803991A (es) | 1998-09-30 |
| JP2002515079A (ja) | 2002-05-21 |
| DE59602822D1 (de) | 1999-09-23 |
| TW438821B (en) | 2001-06-07 |
| PL326840A1 (en) | 1998-10-26 |
| EP0862590A1 (de) | 1998-09-09 |
| DE19646484C2 (de) | 2000-10-19 |
| ES2138385T3 (es) | 2000-01-01 |
| WO1997019116A1 (de) | 1997-05-29 |
| US5837789A (en) | 1998-11-17 |
| KR19990071530A (ko) | 1999-09-27 |
| MX202050B (es) | 2001-05-25 |
| AU7627396A (en) | 1997-06-11 |
| ATE183526T1 (de) | 1999-09-15 |
| CN1207745A (zh) | 1999-02-10 |
| JP4001350B2 (ja) | 2007-10-31 |
| TR199800900T2 (xx) | 1999-12-21 |
| CA2236504A1 (en) | 1997-05-29 |
| EP0862590B1 (de) | 1999-08-18 |
| RU2193045C2 (ru) | 2002-11-20 |
| BR9611469A (pt) | 1999-06-15 |
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