JPWO2015046370A1 - アイウェア材料、アイウェアフレームおよびアイウェア - Google Patents
アイウェア材料、アイウェアフレームおよびアイウェア Download PDFInfo
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- JPWO2015046370A1 JPWO2015046370A1 JP2014548222A JP2014548222A JPWO2015046370A1 JP WO2015046370 A1 JPWO2015046370 A1 JP WO2015046370A1 JP 2014548222 A JP2014548222 A JP 2014548222A JP 2014548222 A JP2014548222 A JP 2014548222A JP WO2015046370 A1 JPWO2015046370 A1 JP WO2015046370A1
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- Prior art keywords
- eyewear
- mass
- bis
- parts
- polyol
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- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
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- VOZKAJLKRJDJLL-UHFFFAOYSA-N tolylenediamine group Chemical group CC1=C(C=C(C=C1)N)N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
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- YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
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- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47D—FURNITURE SPECIALLY ADAPTED FOR CHILDREN
- A47D1/00—Children's chairs
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/18—Separation; Purification; Stabilisation; Use of additives
- C07C263/20—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C265/00—Derivatives of isocyanic acid
- C07C265/02—Derivatives of isocyanic acid having isocyanate groups bound to acyclic carbon atoms
- C07C265/04—Derivatives of isocyanic acid having isocyanate groups bound to acyclic carbon atoms of a saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C265/00—Derivatives of isocyanic acid
- C07C265/14—Derivatives of isocyanic acid containing at least two isocyanate groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/06—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/06—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals
- C07D295/067—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by halogen atoms or nitro radicals with the ring nitrogen atoms and the substituents attached to the same carbon chain, which is not interrupted by carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/10—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms
-
- C—CHEMISTRY; METALLURGY
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Abstract
Description
[鎖伸長剤(g)+(鎖伸長剤(g)/鎖伸長剤の分子量(g/mol))×ポリイソシアネート成分の平均分子量(g/mol)]÷(ポリイソシアネート成分(g)+活性水素基含有成分(g))×100
また、ハードセグメント濃度は、例えば、熱可塑性ポリウレタンを、固体NMRや溶液NMR測定することなどにより、実測することもできる。具体的な実測方法は、例えば、Satoshi Yamasaki et.al「Effect of aggregation structure on rheological properties of thermoplastic polyurethanes」雑誌名Polymer, 48巻, 4793〜4803ページ,2007年に記載されている。
上記一般式(1)中、R1、R2およびR3で示される炭素数1〜20の炭化水素基としては、例えば、メチル、エチル、プロピル、ブチルなどのアルキル基、例えば、フェニル、トリル、キシリル、ナフチルなどのアリール基、例えば、ベンジルなどのアラルキル基などが挙げられる。
nは、好ましくは、下記式(3)を満たす正の整数である。
また、上記一般式(1)中、−(Si(R1)(R2)O)m−および−(Si(R3)(Y)O)n−で示されるシロキサン鎖は、直鎖であってもよく、あるいは、分岐していてもよい。
撹拌機、温度計、窒素導入管、塩素ガス導入管、ホスゲン導入管、ガス排気管、ガス冷却装置、および、自動圧力調整弁を装備したステンレス製反応器に、1,4−ビス(アミノメチル)シクロヘキサン(三菱ガス化社製 13C−NMR測定によるトランス/シス比が84/16)を55質量部、オルトジクロロベンゼンを700質量部仕込み、300rpmで撹拌しながら60℃に加熱した。その後、塩酸ガスを1.0mol/hr(対1,4−BAC)の流量で、1,4−BACに対して3.0モル倍導入した。反応器のジャケットには冷水を通し、内温を60〜100℃に保った。
撹拌機、温度計、還流管および窒素導入管を備えた4つ口フラスコに、PTG2000SN(P)(保土ヶ谷化学工業社製、バイオマス原料を用いたポリテトラメチレンエーテルグリコール、数平均分子量2000)24.1質量部およびPTG1000SN(P)(保土ヶ谷化学工業社製、バイオマス原料を用いたポリテトラメチレンエーテルグリコール、数平均分子量1000)23.6質量部を装入し、次いで、当量比(NCO/OH)が5.46になるように、1,4−BIC 38.0質量部を装入した。窒素雰囲気下、80℃にて1時間撹拌後、DINA(ジェイ・プラス製 ジイソノニルアジペート)にて4質量%に希釈したスタノクト(APIコーポレーション社製オクチル酸第一錫)0.011質量部を装入した。さらに、イソシアネート基含量が15.67質量%になるまで反応させ、イソシアネート基末端プレポリマー(以下、プレポリマーと略する場合がある。)(a)を得た。
表1〜4に示す配合比にて、合成例2と同様の方法によりイソシアネート基末端プレポリマー(b)〜(l)を得た。
予め80℃に調整したプレポリマー(a)85.71質量部と、イルガノックス245(BASFジャパン製 耐熱安定剤)を0.3質量部、チヌビン234(BASFジャパン社製 紫外線吸収剤)を0.1質量部、アデカスタブLA−72(ADEKA社製 耐光安定剤)を0.1質量部、および、スタノクト(APIコーポレーション製 オクチル酸第一スズ)をDINA(ジェイ・プラス製 ジイソノニルアジペート)により4質量%に希釈した触媒液を0.013質量部とを、ステンレス容器に入れ、高速ディスパーを使用して、800rpmの撹拌下、約2分間撹拌混合した。次いで、1,4−ブタンジオール(和光純薬工業製、以下、1,4−BDと略する。)を80℃に調整し、当量比(NCO/OH)が1.01になるように添加した。
予め80℃に調整したプレポリマー(a)85.71質量部に、シャリーヌR−170S(日信化学工業社製 アクリル変性ポリオルガノシロキサン)を0.0007質量部、イルガノックス245(BASFジャパン製 耐熱安定剤)を0.3質量部、チヌビン234(BASFジャパン社製 紫外線吸収剤)を0.1質量部、アデカスタブLA−72(ADEKA社製 耐光安定剤)を0.1質量部、スタノクト(APIコーポレーション製 オクチル酸第一スズ)をDINA(ジェイ・プラス製 ジイソノニルアジペート)により4質量%に希釈した触媒液を0.013質量部、ステンレス容器に入れ、高速ディスパーを使用して、800rpmの撹拌下、約2分間撹拌混合した。次いで、1,4−ブタンジオール(和光純薬工業製、以下、1,4−BDと略する。)を80℃に調整し、当量比(NCO/OH)が1.01になるように添加した。
表1〜4に示す配合処方に変更した以外は、実施例1または実施例2と同様にして、熱可塑性ポリウレタンC〜U、アイウェア材料C〜UおよびアイウェアフレームC〜Uを調製した。
1,4−BIC 25.6質量部、1,3−BIC 25.6質量部、PTG650(保土ヶ谷化学工業製 ポリテトラメチレンエーテルグリコール)5.7質量部、シャリーヌR−170Sを0.05質量部、イルガノックス245(BASFジャパン製 耐熱安定剤)を0.3質量部、チヌビン234(BASFジャパン社製 紫外線吸収剤)を0.1質量部、アデカスタブLA−72(ADEKA社製 耐光安定剤)を0.1質量部、1,6−ヘキサンジオール(和光純薬工業製 1,6−HDO)13.0質量部、シクロヘキサンジメタノール(和光純薬工業製 CHDM シス、トランス混合物)を23.8質量部、スタノクト(APIコーポレーション製 オクチル酸第一スズ)をDINA(ジェイ・プラス製 ジイソノニルアジペート)により4質量%に希釈した触媒液を0.013質量部、ステンレス容器に入れ、高速ディスパーを使用して、800rpmの撹拌下、約10分間全体が均一になるまで充分に撹拌し、撹拌停止後すぐに反応混合液の均一性を確認した後、予め150℃に温調したSUS製バッドに反応混合液を流し込み、150℃にて1時間、次いで、100℃にて23時間反応させ、熱可塑性ポリウレタン(U)を得た。
各実施例および各比較例において得られたアイウェアフレームおよびシートについて、下記の通り評価した。その結果を、表1〜4に示す。
JIS K7311(1995)の硬さ試験に準拠し、熱可塑性ポリウレタンのShoreD硬度を測定し、その結果を数値として示した。
アイウェア材料の比重はJIS Z8807(2012)に準拠し測定した。
バイオマス度は、ASTM D6866 METHOD−Bの規格に準拠し測定した。
ハードセグメント濃度は、各成分の配合処方(仕込)から次式により算出した。
[鎖伸長剤(g)+(鎖伸長剤(g)/鎖伸長剤の分子量(g/mol))×ポリイソシアネート成分の平均分子量(g/mol)]÷(ポリイソシアネート成分(g)+活性水素基含有成分(g))×100
また、実施例1のみ、下記方法でもハードセグメント濃度を測定した。
式1) M(t)=M(tf)exp(−t2/T2f 2)+M(ti)exp(−t/T2i)+M(ts)exp(−t/T2s)
<引張強度および破断伸び(単位:MPaおよび%)>
「JIS K7312 熱硬化性ポリウレタンエラストマー成形物の物理試験方法」に準じて、熱可塑性ウレタンシートを用いた引張試験を実施した。試験片をJIS−3号ダンベルにて打ち抜き、テンシロン(エー・アンド・デイ製、モデル:RTG−1310)を用いて、標線間20mm、引張速度500mm/分の条件で測定した。
各熱可塑性ポリウレタンのシート(2mm厚)の試験サンプルを、幅5mm、長さ50mmのサイズにダンベルで打ち抜いた。次いで、この試験サンプルに対して、動的粘弾性測定装置(アイティ計測制御製、モデル:DVA−200)を用いて、引張モード、標線間長25mm、昇温速度5℃/min、測定周波数10Hzの条件で、−100〜250℃において、試験サンプルの動的粘弾性を測定した。tanδのピーク温度をTgとして算出し、その結果を数値として示した。
アイウェアフレームを装着した際のフィット感および表面触感を評価した。評価の基準を下記する。
・フィット感評価
5:歩行時ズレなし。
4:歩行時ズレわずかにあり。
3:歩行時ズレあり。
2:歩行時ズレ大。
1:装着不可。
・表面触感評価
5:肌への貼りつき感なし。
4:肌への貼りつき感わずかにあり。
3:肌への張り付き感あり。
2:肌への張り付き感大。
1:肌への張り付き感、不快感大。
アイウェアフレームのつる部を90°折り曲げた後、復元度合を目視にて評価した。評価基準を下記する。
5:変形しなかった。
4:やや変形した。
3:変形した。
2:変形およびクラックが生じた。
1:破断が生じた。
サンオイル(ハワイアントロピックロイヤルオイル、royaloil社製)にフレームを40℃×24時間浸漬した。その後、水道水で洗浄し、外観を目視で判定した。評価基準を下記する。
5:変化しなかった。
4:やや白化が確認された。
3:白化が確認された。
2:白化およびやや膨潤が確認された。
1:膨潤が確認された。
製造例1(1,5−ペンタメチレンジイソシアネートの製造)
電磁誘導撹拌機、自動圧力調整弁、温度計、窒素導入ライン、ホスゲン導入ライン、凝縮器、原料フィードポンプを備え付けたジャケット付き加圧反応器に、o−ジクロロベンゼン2000質量部を仕込んだ。次いで、ホスゲン2300質量部をホスゲン導入ラインから加え、撹拌を開始した。反応器のジャケットには冷水を通し、内温を約10℃に保った。
バイオマス度は、ASTM D6866 METHOD−Bの規格に準拠し測定した。
製造例2(ポリイソシアネート組成物Aの合成)
撹拌器、温度計、還流管、および窒素導入管を備えた四つ口フラスコに、製造例1で得られた1,5−ペンタメチレンジイソシアネート500質量部、イソブチルアルコールを1質量部、2,6−ジ(tert−ブチル)−4−メチルフェノールを0.3質量部、および、トリス(トリデシル)ホスファイトを0.3質量部装入し、80℃で2時間反応させた。
反応器内に、2−メルカプトエタノール51.2質量部、脱気水(溶存酸素濃度2ppm)26.5質量部、49質量%の水酸化ナトリウム水溶液0.16質量部を装入した。
Zelec UN(内部離型剤、酸性リン酸エステル:登録商標、Stepan社製)0.1質量部、viosorb583(紫外線吸収剤:登録商標、共同薬品社製)0.05質量部、および、タケネート500(三井化学社製 m−キシリレンジイソシアネート)33.5質量部を混合し、室温で30分間撹拌溶解させた。これにペンタエリスリトールテトラキス(3−メルカプトプロピオネート)(SC有機化学社製)56.5質量部を加え均一になるまで混合した。
Zelec UN(内部離型剤、酸性リン酸エステル:登録商標、Stepan社製)2.1質量部アクトコールHS−700A(三井化学社製、ポリエーテルポリオール)8.0質量部、および、グリセリン(和光純薬工業製)8.0質量部を混合し、室温で5分間撹拌分散させた。その後、ポリイソシアネート組成物A(1,5−ペンタメチレンジイソシアネートのイソシアヌレート体を含む。)32.0質量部、および、2,5(6)−ジイソシアナトメチル[2,2,1]ヘプタン(三井化学社製)13.8質量部を加え、さらに、Tinuvin292(BASFジャパン社製 紫外線吸収剤)1.6質量部を加え、室温で30分間脱泡した。その後、ガラスモールドとテープからなるモールド型へ注入した。
Zelec UN(内部離型剤、酸性リン酸エステル:登録商標、Stepan社製)0.24質量部、viosorb583(紫外線吸収剤:登録商標、共同薬品社製)3.0質量部、および、1,5−ペンタメチレンジイソシアネート48.3質量部を混合し、室温で15分間撹拌溶解させた。その後、ポリイソシアネート組成物A(1,5−ペンタメチレンジイソシアネートのイソシアヌレート体を含む。)56.3質量部を混合して、ポリイソシアネート液を調製した。
各実施例において得られた光学レンズの評価方法を下記する。
プルフリッヒ屈折計を用いて、20℃で屈折率(ne)およびアッベ数(νe)を測定した。
島津製作所製TMA−60を使用し、TMAペネトレーション法(50g荷重、ピン先0.5mmφ)でのガラス転移温度(Tg)を耐熱性とした。
20℃にてアルキメデス法により測定した。
バイオマス度は、ASTM D6866 METHOD−Bの規格に準拠し測定した。
1,5−ペンタメチレンジイソシアネートのイソシアヌレート体を含むポリイソシアネート組成物A 1.123質量部と、オレスターQ828(三井化学製 アクリルポリオール 固形分濃度53.4質量%、酢酸ブチル/メチルエチルケトン=2/1(質量部)、水酸基化12.5mgKOH/g)13.109質量部と、セレノールH2000(デュポン社製 バイオマス原料を用いたポリトリメチレンエーテルグリコール)3.0質量部と、触媒(和光純薬製 ジブチル錫ジラウリレート)0.0033質量部とを混合した後、各実施例で得られたアイウェアフレーム(光学レンズ未装着)およびシートにスプレー塗装し、50℃で1時間加熱硬化させた。
実施例22において得られたアイウェアフレームおよびシートについて、下記の通り評価した。その結果を、表1〜4に示す。
熱可塑性ポリウレタンのシートを塗装した際の塗料の光沢を測定した。光沢は光沢度計(日本電色工業(株)製、型式:Gloss Meter VG2000)にて測定した。
ポリウレタン系コーティング剤の塗膜と、熱可塑性ポリウレタンのシートとの密着性を、ASTM D3359(2007年)に準拠して評価した。
1,3−BIC:1,3−ビス(イソシアナトメチル)シクロヘキサン、商品名:タケネート600(三井化学製)
H12MDI:H12MDI、メチレンビス(シクロヘキシルイソシアネート)
PTG2000SN(P):数平均分子量2000、バイオマス原料を用いたポリテトラメチレンエーテルグリコール(保土ヶ谷化学工業社製)
PTG1000SN(P):数平均分子量1000、バイオマス原料を用いたポリテトラメチレンエーテルグリコール(保土ヶ谷化学工業社製)
PTG650SN:数平均分子量650、テトラヒドロフランからなるポリテトラメチレンエーテルグリコール(保土ヶ谷化学工業製)
テラタン250:数平均分子量250、テトラヒドロフランからなるポリテトラメチレンエーテルグリコール(INVISTA製)
セレノールH1000:バイオマス原料を用いたポリトリメチレンエーテルグリコール(デュポン社製)
1,4−BD:1,4−ブタンジオール(和光純薬工業製)
1,3−PDO:1,3−プロパンジオール(和光純薬工業製)
1,6−HDO:1,6−ヘキサンジオール(和光純薬工業製)
1,4−CHDM:1,4−シクロヘキサンジメタノール(和光純薬工業製)
シャリーヌR−170S:日信化学工業社製 アクリル変性ポリオルガノシロキサン
なお、上記発明は、本発明の例示の実施形態として提供したが、これは単なる例示に過ぎず、限定的に解釈してはならない。当該技術分野の当業者によって明らかな本発明の変形例は、後記特許請求の範囲に含まれる。
Claims (9)
- 熱可塑性ポリウレタンを含有するアイウェア材料であって、
前記アイウェア材料は、昇温速度5℃/minおよび測定周波数10Hzの測定条件にて、引張モードで動的粘弾性測定することにより観測されるtanδのピークを、0℃未満と、0℃以上70℃以下との両方に有する
ことを特徴とする、アイウェア材料。 - 前記熱可塑性ポリウレタンのハードセグメント濃度が、25質量%以上70質量%以下であることを特徴とする、請求項1に記載のアイウェア材料。
- 前記熱可塑性ポリウレタンが、
ビス(イソシアナトメチル)シクロヘキサンを含むポリイソシアネート成分と、活性水素基含有成分との反応により得られることを特徴とする、請求項1に記載のアイウェア材料。 - さらに、アクリル変性オルガノポリシロキサンを、熱可塑性ポリウレタン100質量部に対して、0.01質量部以上1質量部以下の割合で含有することを特徴とする、請求項1に記載のアイウェア材料。
- 熱可塑性ポリウレタンを含有するアイウェア材料であって、
前記アイウェア材料は、昇温速度5℃/minおよび測定周波数10Hzの測定条件にて、引張モードで動的粘弾性測定することにより観測されるtanδのピークを、0℃未満と、0℃以上70℃以下との両方に有する
アイウェア材料から形成されていることを特徴とする、アイウェアフレーム。 - 脂肪族ポリイソシアネートを含有するポリウレタン系コーティング剤によりコーティングされていることを特徴とする、請求項5に記載のアイウェアフレーム。
- 前記脂肪族ポリイソシアネートが、
ペンタメチレンジイソシアネートおよび/またはその誘導体を含有することを特徴とする、請求項6に記載のアイウェアフレーム。 - 熱可塑性ポリウレタンを含有するアイウェア材料であって、
前記アイウェア材料は、昇温速度5℃/minおよび測定周波数10Hzの測定条件にて、引張モードで動的粘弾性測定することにより観測されるtanδのピークを、0℃未満と、0℃以上70℃以下との両方に有するアイウェア材料から形成されているアイウェアフレームと、
前記アイウェアフレームに装着される光学レンズと
を備えることを特徴とする、アイウェア。 - 前記光学レンズが、バイオマス原料から形成されていることを特徴とする、請求項8に記載のアイウェア。
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